CN107117879A - One kind can light high intensity Ecological Road well lid and preparation method thereof - Google Patents

One kind can light high intensity Ecological Road well lid and preparation method thereof Download PDF

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Publication number
CN107117879A
CN107117879A CN201710410302.XA CN201710410302A CN107117879A CN 107117879 A CN107117879 A CN 107117879A CN 201710410302 A CN201710410302 A CN 201710410302A CN 107117879 A CN107117879 A CN 107117879A
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China
Prior art keywords
parts
well lid
minutes
high intensity
light
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CN201710410302.XA
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Chinese (zh)
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刘伍
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Hefei Huilin Building Materials Co Ltd
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Hefei Huilin Building Materials Co Ltd
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Priority to CN201710410302.XA priority Critical patent/CN107117879A/en
Publication of CN107117879A publication Critical patent/CN107117879A/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38—Fibrous materials; Whiskers
    • C04B14/48—Metal
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04—Waste materials; Refuse
    • C04B18/06—Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/08—Flue dust, i.e. fly ash
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04—Waste materials; Refuse
    • C04B18/12—Waste materials; Refuse from quarries, mining or the like
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04—Waste materials; Refuse
    • C04B18/14—Waste materials; Refuse from metallurgical processes
    • C04B18/141—Slags
    • C04B18/142—Steelmaking slags, converter slags
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/0093—Aluminates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08—Acids or salts thereof
    • C04B22/14—Acids or salts thereof containing sulfur in the anion, e.g. sulfides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/005—Halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/02—Alcohols; Phenols; Ethers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/12—Nitrogen containing compounds organic derivatives of hydrazine
    • C04B24/121—Amines, polyamines
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/28—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/281—Polyepoxides
    • E—FIXED CONSTRUCTIONS
    • E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D29/00—Independent underground or underwater structures; Retaining walls
    • E02D29/12—Manhole shafts; Other inspection or access chambers; Accessories therefor
    • E02D29/14—Covers for manholes or the like; Frames for covers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00008—Obtaining or using nanotechnology related materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mining & Mineral Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Paleontology (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Road Paving Structures (AREA)

Abstract

It can be lighted high intensity Ecological Road well lid the invention discloses one kind, it is characterised in that include the raw material of following parts by weight：6 12 parts of steel fibre, 28 32 parts of cement, 5 15 parts of light-storing and emitting material, 20 30 parts of gangue, 65 75 parts of electroslag, 15 25 parts of flyash, 26 parts of nano titanium oxide, 15 25 parts of propanepoxy resin, 0.5 1 parts of HBB, 0.1 0.5 parts of 2,6 BHT, 5 10 parts of ethylenediamine.The high intensity Ecological Road well lid that lights of the present invention has very high toughness, shock resistance is good, high mechanical strength, antifatigue, the preparation method of the high intensity Ecological Road well lid that lights of the present invention employs a large amount of industrial wastes simultaneously, economize on resources, material cost is relatively low, raw material is easy to get and preparation method simple process, with higher practical value and good application prospect.

Description

One kind can light high intensity Ecological Road well lid and preparation method thereof
Technical field
The present invention relates to concrete manhole cover technical field, and in particular to one kind can light high intensity Ecological Road well lid and its Preparation method.
Background technology
Well lid is the top seal thing towards underground installation gateway, as long as installing running water, telecommunications, electric power, combustion gas disappears Prevent, heating power, the place of the public utility such as environmental sanitation can use well lid.According to the technical characterstic of pipe engineering, to meet its installation Direction is buried in the requirement that equipment, maintenance repair are safeguarded well, engineering along pipeline, and inspection shaft, manhole cover are set at a certain distance It is the main auxiliary products of inspection shaft, its function is load-bearing, closing, opens inspection shaft, and it can bear vehicular traffic big flow Run at high speed, be also possible to prevent the entrance of vehicle, pedestrian and foreign matter, ensure that underground utilities and equipment are normally run.Conventional well Lid has the advantages that intensity height, good rigidity, shock resistance, corrosion-resistant, but its cost is high, recovery value height, causes well lid easy It is stolen；Existing well seat peripheral path structure sheaf is thin, and road surface cracky, well seat is small with well room contact area, and anti-pressure ability is weak, by Cause broken along brick body on the lower inspection shaft of well seat in rolling for vehicle, so that the unstable, frangible of well seat is caused, in the course of time, Well will be involved and sit the loosening, built on the sand on periphery road surface, so as to cause periphery road surface to sink, traditional well lid design is single, works as well Lid is stolen or run into underground pipe network impeded drainage by top displacement and well lid, runs into rain, gushes outside sewage, well lid is by top displacement and road Area water is serious, it is necessary to move well lid away so as to Quick drainage, and potential safety hazard is brought to pedestrian and vehicle.
Fabric reinforcement concrete manhole cover, typically steel fiber reinforced concrete are embedding to be constituted with framework of steel reinforcement, steel fiber reinforced concrete Then with concrete addition steel fibre composition, this alternative castiron well cover of manhole cover.Generally, well lid periphery, which is surrounded by, is used to Strengthen stirrup.With the fabric reinforcement concrete manhole cover of manufactured by common concrete, its intensity is still not enough to be used for big specification check well Lid rolls to carry oversize vehicle, therefore proposes that the fabric reinforcement concrete manhole cover of higher intensity obtains most attention.
In addition, the metal or cement well lid that use at present all have the shortcomings that one it is common be equal no-reflection function, this makes
Pedestrian or vehicle can not recognize the location of well lid, particularly night some protrusion or recessed road surface well lid Walked to night pedestrian and the traveling of vehicle brings very big potential safety hazard, night upkeep operation is carried out under inspection shaft while also giving Workman leave hidden danger.
The content of the invention
For the defect of prior art, it can be lighted high intensity Ecological Road well lid it is an object of the invention to provide one kind, should Manhole has very high toughness, and shock resistance is good, high mechanical strength, antifatigue, while lighting for the present invention is high-strength Degree Ecological Road well lid preparation method employ a large amount of industrial wastes, economize on resources, material cost is relatively low, raw material is easy to get and Preparation method simple process, with higher practical value and good application prospect.
The present invention solves technical problem and adopted the following technical scheme that：
It can be lighted high intensity Ecological Road well lid the invention provides one kind, include the raw material of following parts by weight：
6-12 parts of steel fibre, 28-32 parts of cement, 5-15 parts of light-storing and emitting material, 20-30 parts of gangue, electroslag 65-75 Part, 15-25 parts of flyash, 2-6 parts of nano titanium oxide, 15-25 parts of propanepoxy resin, 0.5-1 parts of HBB, 2, 0.1-0.5 parts of 6- BHTs, 5-10 parts of ethylenediamine.
Preferably, the high intensity Ecological Road well lid that lights, includes the raw material of following parts by weight：
9 parts of steel fibre, 30 parts of cement, 10 parts of light-storing and emitting material, 25 parts of gangue, 70 parts of electroslag, 20 parts of flyash, receive 4 parts of titanium dioxide of rice, 20 parts of propanepoxy resin, 0.8 part of HBB, 0.3 part of BHT, second 8 parts of diamines.
Preferably, the preparation method of the steel fibre is steel ingot milling method.
Preferably, the light-storing and emitting material is the light storage type self luminous material of sulfide systems, aluminates system storage light One or more in the light storage type self luminous material of type self-luminescent material, silicate systems.
Present invention also offers a kind of preparation method for the high intensity Ecological Road well lid that lights, comprise the following steps：
Step one, will gangue, electroslag, volcanic ash mix add pulverizer in crush, cross 60 mesh sieves, feeding calcining furnace in At 850-950 DEG C calcine 15-35 minute, cooling, washing, filtering feeding ball mill in be ground to carefully 200 mesh sieves mixed Thing A；
Step 2, by propanepoxy resin, HBB, BHT mix add mixer in 150-250r/min is stirred 15-25 minutes, adds curing agent, is continued stirring and is obtained mixture B in 10-15 minutes；
Step 3, mixer is added by mixture A, nano titanium oxide, light-storing and emitting material, cement made from step one In, appropriate water is added, is stirred 5-10 minutes with 80-100r/min, steel fibre is added and continues to stir 3-5 minutes, add Mixture B prepared by step 2, continues to stir 10-20 minutes, compound is poured in the mould of the good framework of steel reinforcement of cloth and vibrated 1-2 minutes, conserved 3-5 hours under the conditions of 160-180 DEG C, 1.3-1.5MPa, natural curing 10-12 hours after cooling, the demoulding Obtain luminous high intensity Ecological Road well lid.
Preferably, in the step one calcining heat be 900 DEG C, calcination time be 25 minutes.
Preferably, the step 2 is：Propanepoxy resin, HBB, BHT are mixed Close and add in mixer with 200r/min stirrings 20 minutes, add curing agent, continue stirring and obtain mixture B in 12 minutes.
Preferably, the step 3 is：By the luminous material of mixture A, nano titanium oxide, light accumulation type made from step one Material, cement are added in mixer, add appropriate water, are stirred 5-10 minutes with 80-100r/min, are added steel fibre and continue to stir Mix 3-5 minutes, add the mixture B of step 2 preparation, continue to stir 10-20 minutes, compound is poured into the good reinforcing bar of cloth Vibrated 1-2 minutes in the mould of skeleton, conserve 3-5 hours, supported naturally after cooling under the conditions of 160-180 DEG C, 1.3-1.5MPa Shield 10-12 hours, the demoulding obtains luminous high intensity Ecological Road well lid.
Compared with prior art, the present invention has following beneficial effect：
（1）The high intensity Ecological Road well lid that lights of the present invention with the addition of steel fibre in concrete, and be steel ingot milling The steel fibre that method is produced, plastic deformation of the steel fibre by generation very during cutting, between centers is distorted, can increased and concrete Cohesive force, considerably increase tension, the compression strength of concrete.
（2）The high intensity Ecological Road well lid that lights of the present invention with the addition of propanepoxy resin, HBB, 2, 6- BHTs, ethylenediamine, these additives can increase the toughness of concrete, Kang Chong Ji Eng abilities, also can reach Increase the corrosion resistance and quietness of well lid.
（3）The present invention the high intensity Ecological Road well lid that lights using gangue, electroslag, flyash as main component, Solid waste is taken full advantage of, has on the one hand accomplished twice laid, resource has on the other hand been saved, has reduced environmental pollution, Recycling economy is realized, meets the theory of sustainable development.
（4）The high intensity Ecological Road well lid that lights of the present invention, which with the addition of light-storing and emitting material material active and inhale, to be stored After the visible ray such as sunshine, light, ultraviolet light, veiling glare 5-10min, excite luminous energy to store this, stop when light is excited After only, so that it may more than continuous illumination 12h in the dark, well lid is intentionally avoided when driver's night can be reminded to drive a vehicle, it is reduced The number of times being rolled increases its service life, can also play a part of beautifying city.
（5）The present invention the high intensity Ecological Road well lid that lights employ a large amount of industrial wastes, economize on resources, material into This relatively low, raw material is easy to get and preparation method simple process, with higher practical value and good application prospect.
Embodiment
With reference to specific embodiment, the technical scheme in the embodiment of the present invention is clearly and completely described, shown So, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the reality in the present invention Example is applied, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made all belongs to In the scope of protection of the invention.
Embodiment 1.
The high intensity Ecological Road well lid that lights of the present embodiment, includes the raw material of following parts by weight：
6 parts of steel fibre, 28 parts of cement, 5 parts of light-storing and emitting material, 20 parts of gangue, 65 parts of electroslag, 15 parts of flyash, receive 2 parts of titanium dioxide of rice, 15 parts of propanepoxy resin, 0.5 part of HBB, 0.1 part of BHT, second 5 parts of diamines.
The preparation method of steel fibre is steel ingot milling method in the present embodiment.
Light-storing and emitting material is the light storage type self luminous material of sulfide systems in the present embodiment.
The preparation method of the high intensity Ecological Road well lid that lights of the present embodiment, comprises the following steps：
Step one, will gangue, electroslag, volcanic ash mix add pulverizer in crush, cross 60 mesh sieves, feeding calcining furnace in At 850 DEG C calcine 15 minutes, cooling, washing, filtering feeding ball mill in be ground to carefully cross 200 mesh sieves obtain mixture A；
Step 2, by propanepoxy resin, HBB, BHT mix add mixer in 150r/min is stirred 15 minutes, adds curing agent, is continued stirring and is obtained mixture B in 10 minutes；
Step 3, mixer is added by mixture A, nano titanium oxide, light-storing and emitting material, cement made from step one In, appropriate water is added, is stirred 5 minutes with 80r/min, steel fibre is added and continues to stir 3 minutes, add step 2 preparation Mixture B, continue stir 10 minutes, compound is poured in the mould of the good framework of steel reinforcement of cloth vibrate 1 minute, 160 DEG C, Conserved 3 hours under the conditions of 1.3MPa, natural curing 10 hours after cooling, the demoulding obtains the high intensity Ecological Road well lid that can light.
Embodiment 2.
The high intensity Ecological Road well lid that lights of the present embodiment, includes the raw material of following parts by weight：
12 parts of steel fibre, 32 parts of cement, 15 parts of light-storing and emitting material, 30 parts of gangue, 75 parts of electroslag, 25 parts of flyash, 6 parts of nano titanium oxide, 25 parts of propanepoxy resin, 1 part of HBB, 0.5 part of BHT, second 10 parts of diamines.
The preparation method of steel fibre is steel ingot milling method in the present embodiment.
Light-storing and emitting material is the light storage type self luminous material of aluminates system in the present embodiment.
The preparation method of the high intensity Ecological Road well lid that lights of the present embodiment, comprises the following steps：
Step one, will gangue, electroslag, volcanic ash mix add pulverizer in crush, cross 60 mesh sieves, feeding calcining furnace in At 950 DEG C calcine 35 minutes, cooling, washing, filtering feeding ball mill in be ground to carefully cross 200 mesh sieves obtain mixture A；
Step 2, by propanepoxy resin, HBB, BHT mix add mixer in 250r/min is stirred 25 minutes, adds curing agent, is continued stirring and is obtained mixture B in 15 minutes；
Step 3, mixer is added by mixture A, nano titanium oxide, light-storing and emitting material, cement made from step one In, appropriate water is added, is stirred 10 minutes with 100r/min, steel fibre is added and continues to stir 5 minutes, add step 2 system Standby mixture B, continues to stir 20 minutes, compound is poured in the mould of the good framework of steel reinforcement of cloth and vibrated 2 minutes, 180 DEG C, conserve 5 hours under the conditions of 1.5MPa, natural curing 12 hours after cooling, the demoulding obtains the high intensity Ecological Road well that can light Lid.
Embodiment 3.
The high intensity Ecological Road well lid that lights of the present embodiment, includes the raw material of following parts by weight：
9 parts of steel fibre, 30 parts of cement, 10 parts of light-storing and emitting material, 25 parts of gangue, 70 parts of electroslag, 20 parts of flyash, receive 4 parts of titanium dioxide of rice, 20 parts of propanepoxy resin, 0.8 part of HBB, 0.3 part of BHT, second 8 parts of diamines.
The preparation method of steel fibre is steel ingot milling method in the present embodiment.
Light-storing and emitting material is the light storage type self luminous material of silicate systems in the present embodiment.
The preparation method of the high intensity Ecological Road well lid that lights of the present embodiment, comprises the following steps：
Step one, will gangue, electroslag, volcanic ash mix add pulverizer in crush, cross 60 mesh sieves, feeding calcining furnace in At 900 DEG C calcine 25 minutes, cooling, washing, filtering feeding ball mill in be ground to carefully cross 200 mesh sieves obtain mixture A；
Step 2, by propanepoxy resin, HBB, BHT mix add mixer in 200r/min is stirred 20 minutes, adds curing agent, is continued stirring and is obtained mixture B in 12 minutes；
Step 3, mixer is added by mixture A, nano titanium oxide, light-storing and emitting material, cement made from step one In, appropriate water is added, is stirred 8 minutes with 90r/min, steel fibre is added and continues to stir 4 minutes, add step 2 preparation Mixture B, continue stir 15 minutes, compound is poured in the mould of the good framework of steel reinforcement of cloth vibrate 1.5 minutes, 170 DEG C, conserve 4 hours under the conditions of 1.4MPa, natural curing 11 hours after cooling, the demoulding obtains the high intensity Ecological Road well that can light Lid.
The performance test results of the high intensity Ecological Road well lid that lights prepared by various embodiments above are as follows：
Notch impact strength（KJ/m2） Tensile yield strength（MPa） Bending strength（MPa）
Embodiment 1 7.9 83 108
Embodiment 2 8.1 94 107
Embodiment 3 8.4 87 111
Comparative example 7.2 65 99
The high intensity Ecological Road well lid toughness that lights of the present invention is high, and shock resistance is good, high mechanical strength, antifatigue, together When preparation method of the present invention employ a large amount of industrial wastes, economize on resources, material cost is relatively low, raw material is easy to get and preparation method Simple process, with higher practical value and good application prospect.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, nothing By from the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by institute Attached claim rather than described above are limited, it is intended that will fall in the implication and scope of the equivalency of claim All changes include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It may be appreciated other embodiment.

Claims (8)

  1. The high intensity Ecological Road well lid 1. one kind can light, it is characterised in that include the raw material of following parts by weight：
    6-12 parts of steel fibre, 28-32 parts of cement, 5-15 parts of light-storing and emitting material, 20-30 parts of gangue, electroslag 65-75 Part, 15-25 parts of flyash, 2-6 parts of nano titanium oxide, 15-25 parts of propanepoxy resin, 0.5-1 parts of HBB, 2, 0.1-0.5 parts of 6- BHTs, 5-10 parts of ethylenediamine.
  2. 2. the high intensity Ecological Road well lid according to claim 1 that lights, it is characterised in that the high intensity that lights Ecological Road well lid, includes the raw material of following parts by weight：
    9 parts of steel fibre, 30 parts of cement, 10 parts of light-storing and emitting material, 25 parts of gangue, 70 parts of electroslag, 20 parts of flyash, receive 4 parts of titanium dioxide of rice, 20 parts of propanepoxy resin, 0.8 part of HBB, 0.3 part of BHT, second 8 parts of diamines.
  3. 3. the high intensity Ecological Road well lid according to claim 1 or 2 that lights, it is characterised in that the steel fibre Preparation method is steel ingot milling method.
  4. 4. the high intensity Ecological Road well lid according to claim 1 or 2 that lights, it is characterised in that the light accumulation type hair Luminescent material is the light storage type self luminous material of sulfide systems, the light storage type self luminous material of aluminates system, silicate systems storage light One or more in type self-luminescent material.
  5. 5. a kind of preparation method of the high intensity Ecological Road well lid according to claim 1 or 2 that lights, its feature exists In comprising the following steps：
    Step one, will gangue, electroslag, volcanic ash mix add pulverizer in crush, cross 60 mesh sieves, feeding calcining furnace in At 850-950 DEG C calcine 15-35 minute, cooling, washing, filtering feeding ball mill in be ground to carefully 200 mesh sieves mixed Thing A；
    Step 2, by propanepoxy resin, HBB, BHT mix add mixer in 150-250r/min is stirred 15-25 minutes, adds curing agent, is continued stirring and is obtained mixture B in 10-15 minutes；
    Step 3, mixer is added by mixture A, nano titanium oxide, light-storing and emitting material, cement made from step one In, appropriate water is added, is stirred 5-10 minutes with 80-100r/min, steel fibre is added and continues to stir 3-5 minutes, add Mixture B prepared by step 2, continues to stir 10-20 minutes, compound is poured in the mould of the good framework of steel reinforcement of cloth and vibrated 1-2 minutes, conserved 3-5 hours under the conditions of 160-180 DEG C, 1.3-1.5MPa, natural curing 10-12 hours after cooling, the demoulding Obtain the high intensity Ecological Road well lid that can light.
  6. 6. the preparation method of the high intensity Ecological Road well lid according to claim 5 that lights, it is characterised in that the step In rapid one calcining heat be 900 DEG C, calcination time be 25 minutes.
  7. 7. the preparation method of the high intensity Ecological Road well lid according to claim 5 that lights, it is characterised in that the step Rapid two are：Propanepoxy resin, HBB, BHT are mixed and added in mixer with 200r/ Min is stirred 20 minutes, adds curing agent, is continued stirring and is obtained mixture B in 12 minutes.
  8. 8. the preparation method of the high intensity Ecological Road well lid according to claim 5 that lights, it is characterised in that the step Rapid three are：Mixture A, nano titanium oxide, light-storing and emitting material, cement made from step one are added in mixer, plus Enter appropriate water, stirred 8 minutes with 90r/min, add steel fibre and continue to stir 4 minutes, add the mixed of step 2 preparation Compound B, continue stir 15 minutes, compound is poured in the mould of the good framework of steel reinforcement of cloth vibrate 1.5 minutes, 170 DEG C, 1.4MPa under the conditions of conserve 4 hours, natural curing 11 hours after cooling, the demoulding obtain the high intensity Ecological Road well lid that can light.
CN201710410302.XA 2017-06-03 2017-06-03 One kind can light high intensity Ecological Road well lid and preparation method thereof Withdrawn CN107117879A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112081138A (en) * 2019-06-13 2020-12-15 中国华西企业有限公司 Light-transmitting and self-luminous integrated manhole cover and manufacturing method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153321A (en) * 2010-12-27 2011-08-17 攀枝花环业冶金渣开发有限责任公司 High-titanium slag well cover and production method thereof
CN105801034A (en) * 2016-06-02 2016-07-27 南京工程学院 Steel-fiber light-emitting-concrete maintenance well lid and production method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153321A (en) * 2010-12-27 2011-08-17 攀枝花环业冶金渣开发有限责任公司 High-titanium slag well cover and production method thereof
CN105801034A (en) * 2016-06-02 2016-07-27 南京工程学院 Steel-fiber light-emitting-concrete maintenance well lid and production method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112081138A (en) * 2019-06-13 2020-12-15 中国华西企业有限公司 Light-transmitting and self-luminous integrated manhole cover and manufacturing method thereof

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