CN107115776A - One kind CO suitable for cement kiln flue gas2The change system continuously trapped - Google Patents
One kind CO suitable for cement kiln flue gas2The change system continuously trapped Download PDFInfo
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- CN107115776A CN107115776A CN201710253279.8A CN201710253279A CN107115776A CN 107115776 A CN107115776 A CN 107115776A CN 201710253279 A CN201710253279 A CN 201710253279A CN 107115776 A CN107115776 A CN 107115776A
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- Prior art keywords
- flue gas
- trapping
- gas
- circulation
- caught
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- 239000004568 cement Substances 0.000 title claims abstract description 88
- 230000008859 change Effects 0.000 title claims abstract description 43
- 239000003546 flue gas Substances 0.000 claims abstract description 126
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 94
- 238000000746 purification Methods 0.000 claims abstract description 44
- 238000000926 separation method Methods 0.000 claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 claims abstract description 39
- 230000003647 oxidation Effects 0.000 claims abstract description 36
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 36
- 238000003860 storage Methods 0.000 claims abstract description 29
- 239000012528 membrane Substances 0.000 claims abstract description 21
- 239000000779 smoke Substances 0.000 claims abstract description 8
- 239000007789 gas Substances 0.000 claims description 67
- 239000003795 chemical substances by application Substances 0.000 claims description 49
- 239000012530 fluid Substances 0.000 claims description 27
- 238000004146 energy storage Methods 0.000 claims description 24
- 238000009825 accumulation Methods 0.000 claims description 22
- 238000001816 cooling Methods 0.000 claims description 15
- 239000002918 waste heat Substances 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 13
- 238000009826 distribution Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000007921 spray Substances 0.000 claims description 11
- 238000005086 pumping Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000002699 waste material Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 230000002000 scavenging effect Effects 0.000 claims description 7
- 239000010865 sewage Substances 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 6
- 235000019504 cigarettes Nutrition 0.000 claims description 5
- 239000000428 dust Substances 0.000 claims description 5
- 229910001385 heavy metal Inorganic materials 0.000 claims description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 238000000889 atomisation Methods 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 abstract description 11
- 230000009467 reduction Effects 0.000 abstract description 9
- 206010054949 Metaplasia Diseases 0.000 abstract description 2
- 230000015689 metaplastic ossification Effects 0.000 abstract description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 217
- 238000000034 method Methods 0.000 description 37
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 19
- 208000028659 discharge Diseases 0.000 description 19
- 239000003245 coal Substances 0.000 description 16
- 238000005516 engineering process Methods 0.000 description 13
- 238000005265 energy consumption Methods 0.000 description 12
- 238000002485 combustion reaction Methods 0.000 description 11
- 230000008569 process Effects 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 8
- 239000012466 permeate Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 238000002309 gasification Methods 0.000 description 6
- 238000006703 hydration reaction Methods 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000005611 electricity Effects 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 229960004424 carbon dioxide Drugs 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000002912 waste gas Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- 239000012465 retentate Substances 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000004425 Makrolon Substances 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- HXELGNKCCDGMMN-UHFFFAOYSA-N [F].[Cl] Chemical compound [F].[Cl] HXELGNKCCDGMMN-UHFFFAOYSA-N 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 1
- PLQRBFAACWRSKF-LJTMIZJLSA-M sodium;n-methyl-n-[(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl]carbamodithioate Chemical compound [Na+].[S-]C(=S)N(C)C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO PLQRBFAACWRSKF-LJTMIZJLSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/60—Simultaneously removing sulfur oxides and nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
- C04B7/44—Burning; Melting
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
- F27D17/004—Systems for reclaiming waste heat
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
- F27D17/008—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases cleaning gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
- F27D17/004—Systems for reclaiming waste heat
- F27D2017/007—Systems for reclaiming waste heat including regenerators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/30—Capture or disposal of greenhouse gases of perfluorocarbons [PFC], hydrofluorocarbons [HFC] or sulfur hexafluoride [SF6]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
- Y02P40/121—Energy efficiency measures, e.g. improving or optimising the production methods
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
- Y02P40/18—Carbon capture and storage [CCS]
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Treating Waste Gases (AREA)
Abstract
The present invention discloses one kind CO suitable for cement kiln flue gas2The change system continuously trapped, including cave tail's releaser, chimney, flue gas oxidation, purification device, N2/CO2Membrane separation device, cooler, flue gas compressor, CO2Circularly trapping tower, dewatering dryer, CO2Cooler, CO2Compressor, liquefaction CO2Storage tank, cave tail's releaser connects the air inlet of the flue gas oxidation, purification device, the purifying smoke outlet N of flue gas oxidation, purification device2/CO2The air inlet of membrane separation device, N2/CO2The rich N of membrane separation device2Outlet connection chimney, richness CO2Outlet passes sequentially through cooler and the CO is connected with flue gas compressor2Circularly trapping tower, CO2Circularly trapping tower includes CO2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases device B, and alternating is carried out continuously CO2Trapping and CO2From releasing.The present invention is not only simple in structure, and cost is low, industrially applicable, and realizes the purifying discharge of cement producing line flue gas, is realized the effective emission reduction and the production of low-carbon metaplasia of cement production enterprise, is also achieved the CO of high-efficiency and continuous2Trapping separation.
Description
Technical field
The invention belongs to emission-control equipment technical field, and in particular to one kind CO suitable for cement kiln flue gas2Continuously
The change system of trapping.
Background technology
One of the problem of climate change has turned into influence human survival and development, and the carbon dioxide of industrial discharge is considered as
It is to cause the main cause of climate warming, China is as developing country maximum in the world, the primary energy based on coal
With the secondary energy sources structure based on thermal power generation, with increasing rapidly for economic total volume, the CO of primary energy and secondary energy sources2
Discharge, which has, increases the characteristics of fast, total amount is big, and current carbon emission reduction and CCS (the Carbon Capture of reply climate change
And Storage, carbon capture with seal up for safekeeping) or CCUS (Carbon Capture, Utilization and Storage, carbon is caught
Obtaining, using with sealing up for safekeeping) the fortune economy of the trapping cost with high investment, high of technology becomes the serious hindrance of popularization and application, existing
The research of some CCS or CCUS technologies and Demonstration Application are concentrated mainly on and must separated except high concentration CO2Coal chemical industry, synthesis
Gas and coal electrical domain, and coal electrical domain concentrate on IGCC (Integrated Gasification Combined Cycle, it is whole
Body integrated coal gasification combined cycle system) coal gasification, in the application of integrated gas-steam combined cycle power plant technology.
Due to current maximum CO2Power plant of the point source mainly using coal as raw material is discharged, in CO2Trapping technique field or CCS
Technical elements are by CO2Capture technique method and system be referred to as pre-combustion capture, burning in trapping and post-combustion capture.
(1) pre-combustion capture：Mainly using IGCC coal gasifications, integrated gas-steam combined cycle power plant (IGCC) technology as base
Plinth, first by coal gasification, obtains CO and H2, then by vapor conversion, CO switchs to CO2, then pass through separation or CO2Capture technique,
Respectively obtain the H of high concentration2And CO2, H2Using combustion power generation or the carbon-free energy can be used as to export.Implement CO in IGCC technology2Catch
Collection will make energy resource consumption increase by 10~40%, ton CO2Cost is trapped up to 20~50 dollars, wherein CO2The trapping solution renewable sources of energy are accounted for
60%.
(2) trapped in burning：Also known as oxygen-enriched combusting trapping technique, will be contained a large amount of in air first through utilizing space division system
Nitrogen remove, obtain the O of high-purity2, then by high concentration O2Combustion system is introduced, beneficial to CO2Further capture and place
Reason, or using pure oxygen as combustion adjuvant, while in combustion to being pressurizeed in boiler so that the main component after burning in flue gas
For CO2And water, after separation water, the CO of such flue gas middle and high concentration2Gas can directly be compressed seizure.Oxygen-enriched combusting is trapped
Technology increases energy resource consumption 20~50%, ton CO in addition to investment is high, operating cost is high2Cost is trapped up to 50~90 dollars.
(3) post-combustion capture：Refer to and CO directly is implemented to the flue gas after power plant combustion2Separation and trapping, capturing device position
Downstream is discharged in power-plant flue gas, chemical absorption method, physisorphtion, membrane separation process, chemical chain partition method etc. can be divided into.Due to electricity
The CO of factory's discharge2Concentration is low, pressure is small, causes energy consumption and cost excessive, is still not suitable for large-scale promotion.
At present, CO2Trapping is CO2Separation and purification process, realized industrialized method include solvent absorption, inhale
Attached method, embrane method and low temperature processing etc., the big multipotency of these methods use clearance-type trapping.Solvent absorption therein includes
Chemical absorption method, Physical Absorption method and physical chemistry absorption process, have proven to be current all CO2Technology among absorption process
It is most ripe, most widely used, and with being appropriate for extensive CO2Catch the technical scheme of potentiality.But complex process is captured,
Investment is big, is also easy to produce secondary pollution and some solvents have toxicity, solvent needs regeneration to consume mass energy, traps cost
It is high.Membrane separation technique therein be by each component in mixed gas in film infiltration rate difference and obtain separation side
Method, currently used for separation CO2Membrane material mainly have the polymer such as cellulose acetate, polysulfones, makrolon.For large-scale
CO2Trapping system, film method also has larger gap in cost and on reliability requirement.Pressure swing adsorption method therein
The general principle of (Pressure Swing Adsorption, PSA) is with pressure using adsorbent to the adsorbance of gas with various
Change and it is different, the technology has technical process relatively easy, and energy consumption is relatively low, can remove from synthetic-ammonia transformation gas and return
Receive CO2.Low-temperature fractionation isolation technics therein is at low temperature to condense out various components in gas according to technique and requirement,
Then wherein all kinds of materials are separated one by one according to the difference of evaporating temperature with the way of distillation.This method is suitable for natural gas
CO2、H2S contents are higher, and with CO2When carrying out 3 oil recoveries, CO in produced gas2There are the feelings such as larger fluctuation in content and flow
Shape, technological equipment investment expense is larger, and energy consumption is higher.
So far, most CO2Trapping technique even implements IGCC coal gasification, combustion still in development
Gas-steam combined cycle power generating, CO2Trap power plant with the power plant that trapping technique is not carried out compared with, it is necessary to consume 10%~
40% energy, CO2The high cost of trapping causes coal-burning power plant, and also difficulty has implementation CO2The positive wish of trapping.And current various countries
The CO of CCS or CCUS technologies2Application technology also focuses on the research and application of the liquefaction C0 displacement of reservoir oils, purging, geology and ocean envelope note,
And to seal the environmental hazard that note objectively causes not expectable for geology and ocean.
So far, though field of cement production worldwide has the low-carbon emission reduction problem for emphasizing cement production enterprise, not yet
See any specific collecting carbonic anhydride, the research of closing and application or practice report.And the actual production capacity of cement of China has exceeded
3500000000 tons, dry-process rotory kiln production line is a plurality of up to 1700.Cement production enterprise is generally acknowledged highly energy-consuming high pollution enterprise, is dioxy
Change one of primary discharge source of carbon, not only primary energy (coal) and secondary energy sources (electricity) consumption are big, and have substantial amounts of discarded waste heat
And exhaust emissions, pollutant composition is fluctuated in CO mostly in the waste gas of its discharge during fume environment protection qualified discharge212~
29%th, SO280~200mg/Nm3、NOx100~400mg/Nm3, 10~30mg/Nm of dust3, and containing a small amount of hydrocarbon,
Fluorine chlorine compound and heavy metal, manufacture of cement are synthesized because of its kiln gas composition of its process characteristic and property with coal chemical industry
The electric flue gas of gas, natural gas, coal or even IGCC gas have significant difference.The CO of manufacture of cement2Discharge can be divided into material carbon hydrochlorate
Decompose the CO that the burning with fuel is produced2Direct discharge and production process consumption the generation such as external power it is indirect
Discharge.According to China Building Material Scientific Research General Institute to China cement industry CO2Emission analysis, China's cement production process raw material
The CO of decomposition, fuel combustion and power consumption2Discharge capacity accounts for 59%, 26%, the 12% of manufacture of cement total release respectively, comprehensive
CO2Emission factor is 0.8045t/t, cement industry CO2Emission factor cement produced with the dry method is 0.867t/t.China's cement production capacity exceedes 35
Hundred million tons, thus infer the CO of China's cement industry2Annual emissions are up to 3,000,000,000 tons.It can be seen that, China's cement production enterprise implements CO2Emission reduction is more
Urgent and necessity is highlighted, but because still lacking for the specific CO of cement kiln flue gas2The research and development of trapping technique, it is in addition existing
There is CO2The capacity limit that the high Cost Problems of trapping technique application can have been born far beyond cement production enterprise, and manufacture of cement
Because its kiln gas composition of its process characteristic and fluid properties and coal chemical industry synthesis gas, natural gas, the electric flue gas of coal or even
IGCC gas has significant difference, the thin cement industry of (cement price is low) low for this personal value profit, so far there is not yet any cement
CO in kiln flue gas2Trapping and the specific research of application technology and practice report.
To promote cement production enterprise energy-saving and emission-reduction, though cement production enterprise policy require to have built waste gas residual heat boiler and generate electricity system
System, but wherein more than 300 DEG C can only be typically utilized the characteristics of kiln hood due to existing application and the aqueous medium waste heat boiler of kiln tail
Waste gas residual heat, substantial amounts of 80 DEG C~300 DEG C of waste gas residual heat can not utilize and directly empty and cause thermal pollution, meanwhile, also have big
The high temperature heat radiation pollution of capital equipment-rotary kiln shell of other high-temperature services radiation waste heat such as manufacture of cement of amount, revolution
The high temperature section trunk temperature of kiln is up to 300 DEG C~500 DEG C, and low-temperature zone trunk temperature is also up to 150 DEG C~300 DEG C, the life of these cement
The existing waste heat boiler of high-temperature service in production can not be used directly to produce high-temperature high-pressure steam.
In summary, the demand of energy consumption (electricity, coal), reduction environmental contaminants to external world in reduction cement production enterprise production process
Discharge is necessary, in the urgent need to for cement production process installation feature, exploitation is a kind of to utilize big in cement production process
Measure the discarded waste heat produced, reduce cost, suitable for cement kiln flue gas CO2The technical method and change system of trapping, to realize
The energy-saving and emission-reduction problem of manufacture of cement.
The application for a patent for invention of Application No. 201510579908.7 discloses a kind of based on the coal-fired cigarette of embrane method classification trapping
CO in gas2Apparatus and method, it is, using " first enrichment, rear trapping " method, CO in desulfurization neat stress to be trapped in two steps2：It is coal-fired
Flue gas is net after desulfurizer, enters separating film module by booster fan boosting, by adjusting between booster fan and air-introduced machine
Matching relationship ensure separating film module retentate side be in barotropic state；Meanwhile, adjust per-meate side air-introduced machine, it is ensured that seperation film
The per-meate side of component keeps required negative pressure state；Under booster fan, air-introduced machine, the collective effect of per-meate side air-introduced machine,
The CO that the both sides of film are formed in pressure difference, pressure differential retentate side flue gas2Permeate, realized to CO in flue gas to per-meate side2Separation；
Retentate side gas is discharged under air-introduced machine effect by chimney, the small tolerance of per-meate side, high concentration CO2Enriched gas, in per-meate side
Air-introduced machine effect is lower to enter depth CO2Capturing device, is further captured.
Although this application is disclosed using separating film module to CO in coal-fired flue-gas2Trapped again after being separated, but should
The blast of separating film module both sides must be pressurized and provide blast just by the regulation of booster fan, air-introduced machine and per-meate side air-introduced machine
It can realize, it is excessive using the plant energy consumption cost, it should not promote the use of.
The content of the invention
The main object of the present invention is to provide one kind CO suitable for cement kiln flue gas2The change system continuously trapped, purport
Solving existing CO2The problem of capturing device is complicated, purifying inadequate, high energy consumption, cost height are difficult to promote.
To achieve the above object, the present invention proposes one kind CO suitable for cement kiln flue gas2The change system continuously trapped,
Including cave tail's releaser, chimney, flue gas oxidation, purification device, N2/CO2Membrane separation device, cooler, flue gas compressor, CO2Circulation
Trap tower, dewatering dryer, CO2Cooler, CO2Compressor, liquefaction CO2Storage tank；The exhaust outlet connection of the tail exhaust blower is described
The air inlet of flue gas oxidation, purification device, the flue gas oxidation, purification device is used to remove the SO in cement kiln flue gas2, NOx, chlorination
Thing, fluoride, hydrocarbon, heavy metal and dust pollution thing, the purifying smoke outlet of the flue gas oxidation, purification device
The N2/CO2The air inlet of membrane separation device, the N2/CO2The rich N of membrane separation device2Outlet connection chimney, richness CO2Discharge
Mouth passes sequentially through cooler and the CO is connected with flue gas compressor2Circularly trapping tower；CO2Circularly trapping tower include structure it is identical and
The CO being arranged in parallel2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases device B, the CO2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases device B friendships
For being carried out continuously CO2Trapping and CO2From releasing, the CO2Circulation, which is caught, releases device A including housing, the gas distribution located at housing bottom and discharge opeing
Device and the gas-liquid separation device being from top to bottom located in housing, atomizing sprayer, silk screen capture bed apparatus, cooling/heating
Device, the case top is additionally provided with temperature and pressure inductor；The gas distribution is connected the outlet of the flue gas compressor with pumping equipment,
For sending into richness CO into housing2Flue gas body, the atomizing sprayer, which is used to be atomized, sprays into CO2Trapping agent, the silk screen capture
Bed apparatus includes horizontal silk screen, vertical silk screen and the tilting silk screen on support frame, and the cooling/heating device connects used heat
Energy storage equipment, used heat energy storage equipment institute accumulation of heat can be the discarded waste heat that produces in cement production process, the housing A01 tops
Portion is provided with richness N2Gas discharge line and CO2Discharge line, the rich N2CO is provided with gas discharge line2Sensor；The rich N2Gas
Discharge line connects chimney or N2Storage tank, the CO2Discharge line is sequentially communicated dewatering dryer, CO2Cooler, CO2Compression
Machine, liquefaction CO2Storage tank.
Preferably, electric three passes wind is provided between the cave tail's releaser and the flue gas oxidation, purification device, the chimney
Valve, the air inlet of the electric three passes air-valve connects the cave tail's releaser, and the first row gas port of the electric three passes air-valve connects
Lead to the flue gas oxidation, purification device, the second exhaust port of the electric three passes air-valve connects the chimney.
Preferably, the flue gas oxidation, purification device includes purifier shell, the sewage purification located at purifier shell bottom
Separator, the oxidant atomizing sprayer in purifier shell and oxidation, purification separate agent set with aqueous vapor, set
The scavenging solution circulating sprayer in the middle part of agent set, the scavenging solution circulated sprinkling dress are separated with aqueous vapor in the oxidation, purification
Put the treated water outlet for connecting the sewage purification separator.
Preferably, the atomizing sprayer includes circulating line, multiple atomizers on circulating line, connection
The trapping agent feed tube of the circulating line.
Preferably, the gas distribution includes the CO located at the housing bottom with pumping equipment2Cigarette gas inlet pipe and trapping
Agent discharge pipe, the trapping agent discharge pipe is sequentially connected trapping agent circulating tank, circulating pump, and the outlet connection of the circulating pump is described
Trapping agent feed tube.
Preferably, the trapping agent feed tube is provided with trapping agent feed liquor pipe valve, the CO2Cigarette gas inlet pipe is provided with
Flue gas intake valve, the trapping agent discharge pipe discharges pipe valve, the CO provided with trapping agent2Cigarette gas inlet pipe is provided with
The inlet end of flue gas intake valve is additionally provided with flue gas main valve.
Preferably, the cooling/heating device include coil pipe, hot flowing into pipeline, hot-fluid go out pipeline, it is cold flowing into pipeline, cold
Pipeline is flowed out, the accumulation of energy fluid inlet of the coil pipe connects one end of the hot flowing into pipeline and the cold flowing into pipeline, described
The accumulation of energy fluid issuing of coil pipe connects that the hot-fluid goes out pipeline and the cold flow goes out one end of pipeline, the hot flowing into pipeline it is another
The other end that one end, the hot-fluid go out pipeline connects the two ends of the used heat energy storage equipment respectively, the cold flowing into pipeline it is another
The other end that one end, the cold flow go out pipeline connects cold-storage device respectively, and the cold-storage device uses temperature for 0 DEG C~20 DEG C
Cold energy fluid fluid, including underground water or NH3Or CO2。
Preferably, the used heat energy storage equipment includes more than the 300 DEG C discarded waste heats produced in accumulation cement production process
Or the existing aqueous medium waste heat hair of energy storage equipment, accumulation of 100 DEG C~300 DEG C discarded waste heats of energy storage equipment, accumulation of high temperature heat
150 DEG C~500 DEG C radiant heat of energy storage equipment, accumulation high-temperature service or conduct waste heat of 100 DEG C~170 DEG C discarded waste heats after electricity
At least one of energy storage equipment.
Preferably, the CO2Circularly trapping tower include structure it is identical and be arranged in parallel by the CO2Circulation catch release device A and
CO2Some sets for releasing device B compositions are caught in circulation, and the flue gas compressor connects some set CO simultaneously2Circularly trapping tower, it is each
The CO2The rich N of circularly trapping tower2Gas discharge line connects chimney or N2Storage tank, each CO2The CO of circularly trapping tower2Row
Go out pipeline and be sequentially communicated the dewatering dryer.
Preferably, the CO2Circularly trapping tower include structure it is identical and be arranged in series by the CO2Circulation catch release device A and
CO2Some sets for releasing device B compositions are caught in circulation, and the flue gas compressor is sequentially connected some set CO2Circularly trapping tower, it is each
The CO2The rich N of circularly trapping tower2Gas discharge line connects N2Storage tank, the CO positioned at upstream2The CO of circularly trapping tower2Row
Go out the CO that pipeline connection is located at downstream2The gas distribution and pumping equipment of circularly trapping tower.
Compared with prior art, the beneficial effect of technical solution of the present invention：
First, the present invention is to combine cement producing line technological equipment feature and develop, and first cement kiln flue gas is carried out to aoxidize only
Change, then mainly contain N to obtained2、CO2And O2Mixing purifying smoke carry out carbon dioxide and nitrogen separation so that sub-argument punish
Press elevated CO2Gas, then sends the gas into CO2Circularly trapping tower carries out CO2Continuous trapping, obtains pure CO2, can not only
The purifying discharge of cement producing line flue gas is realized, without secondary pollution, the effective emission reduction and low-carbon production of cement production enterprise is realized,
Solve the direct exhaust emission environment of existing cement industry flue gas and existing CO2Catching apparatus is also easy to produce secondary pollution
Problem, and equipment configuration is simpler, invests small, it is industrially applicable, suitable for promoting the use of, solve existing CO2Catch
Collection apparatus and process is complicated, investment is big, the problem of be difficult to promote the use of.
2nd, the present invention takes full advantage of high chimney of tail exhaust blower in cement production process, more than 70 rice etc. these is existing
The installations and facilities normally run, major impetus is used as by the use of its normal power consumption so that the whole change system of the present invention is new
Energization consumption is extremely low, so as to reduce operation cost, breaching existing CCS technological systems includes CO in IGCC system2The height of trapping
Investment, high energy consumption, the bottleneck of high cost, it is economical, solve existing CO2Catching apparatus high energy consumption, operation cost are big
The problem of.
3rd, CO of the present invention2Circularly trapping tower uses two-column design, as the CO2Circulation, which is caught, releases device A progress CO2Trapping
When, the CO2Circulation, which is caught, releases device B progress CO2From releasing, as the CO2Circulation, which is caught, releases device A CO2Hydration reaction is trapped close to completely
When, the CO2Circulation, which is caught, releases device B progress CO2CO continuously can be uninterruptedly made in trapping, thus alternate cycles progress2Stored,
Not only airflow is stable for whole technical process, and realizes CO2Continuous high-efficient trapping.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
There is the accompanying drawing used required in technology description to be briefly described, it should be apparent that, drawings in the following description are only this
Some embodiments of invention, for those of ordinary skill in the art, on the premise of not paying creative work, can be with
Structure according to these accompanying drawings obtains other accompanying drawings.
Fig. 1 is the CO suitable for cement kiln flue gas that the embodiment of the present invention one is proposed2The knot of the change system continuously trapped
Structure schematic diagram.
Fig. 2 is the CO suitable for cement kiln flue gas that Fig. 1 is proposed2CO in the change system continuously trapped2Circularly trapping tower
Structural representation.
Fig. 3 is the CO suitable for cement kiln flue gas that Fig. 1 is proposed2Atomizing sprayer in the change system continuously trapped
Structural representation.
Fig. 4 is the CO suitable for cement kiln flue gas that Fig. 1 is proposed2Cooling/heating device in the change system continuously trapped
Structural representation.
Fig. 5 is the CO suitable for cement kiln flue gas that the embodiment of the present invention two is proposed2The knot of the change system continuously trapped
Structure schematic diagram.
Fig. 6 is the CO suitable for cement kiln flue gas that the embodiment of the present invention three is proposed2The knot of the change system continuously trapped
Structure schematic diagram.
The drawing reference numeral explanation of the present invention：
Embodiment
The embodiment to the present invention is described further below in conjunction with the accompanying drawings.Herein it should be noted that for
The explanation of these embodiments is used to help understand the present invention, but does not constitute limitation of the invention.In addition, disclosed below
As long as each of the invention embodiment in involved technical characteristic do not constitute conflict each other and can just be mutually combined.
The present invention proposes one kind CO suitable for cement kiln flue gas2The change system continuously trapped.
Embodiment one
Fig. 1 is the CO suitable for cement kiln flue gas that the embodiment of the present invention one is proposed2The knot of the change system continuously trapped
Structure schematic diagram.Fig. 2 is the CO suitable for cement kiln flue gas that Fig. 1 is proposed2CO in the change system continuously trapped2Circularly trapping tower
Structural representation.Fig. 3 is the CO suitable for cement kiln flue gas that Fig. 1 is proposed2Atomizing spray in the change system continuously trapped
The structural representation of device.Fig. 4 is the CO suitable for cement kiln flue gas that Fig. 1 is proposed2Cooled down in the change system continuously trapped/
The structural representation of heater.
Fig. 1 is referred to Fig. 4, it is adaptable to CO in cement kiln flue gas2The change system continuously trapped, including cave tail's releaser
1st, chimney 3, flue gas oxidation, purification device 4, N2/CO2Membrane separation device 5, cooler 6, flue gas compressor 7, CO2Circularly trapping tower 8,
Dewatering dryer 10, CO2Cooler 11, CO2Compressor 12, liquefaction CO2Storage tank 13；The exhaust outlet connection institute of the tail exhaust blower 1
The air inlet of flue gas oxidation, purification device 4 is stated, the flue gas oxidation, purification device 4 is used to remove the SO in cement kiln flue gas2, NOx, chlorine
Compound, fluoride, hydrocarbon, heavy metal and dust pollution thing, the purifying smoke outlet of the flue gas oxidation, purification device 4 connect
Lead to the N2/CO2The air inlet of membrane separation device 5, the N2/CO2The rich N of membrane separation device 52Outlet connection chimney 3, richness
CO2Outlet passes sequentially through cooler 6 and connects the CO with flue gas compressor 72Circularly trapping tower 8；CO2Circularly trapping tower 8 includes
Structure is identical and the CO that is arranged in parallel2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases device B, the CO2Circulation, which is caught, releases device A and CO2Circulation
Catch release device B alternately be carried out continuously CO2Trapping and CO2From releasing, the CO2Circulation, which is caught, releases device A including housing A01/B01, located at housing
Gas-liquid separation device A06/B06, the atomizing spray of the gas distribution of bottom with pumping equipment A02/B02 and from top to bottom in housing
Device A03/B03, silk screen capture bed apparatus A04/B04, cooling/heating device A05/B05, the case top are additionally provided with temperature and pressure
Inductor A09/B09；The gas distribution is connected the outlet of the flue gas compressor 7 with pumping equipment A02/B02, for into housing
Send into richness CO2Flue gas body, the atomizing sprayer A03/B03, which is used to be atomized, sprays into CO2Trapping agent, the silk screen capture bed dress
Putting A04/B04 includes horizontal silk screen 42, vertical silk screen 43 and the tilting silk screen on support frame 41, the cooling/heating dress
A05/B05 connection used heat energy storage equipment 9 is put, described 9 accumulation of heats of used heat energy storage equipment can be useless for what is produced in cement production process
Abandon at the top of waste heat, the housing A01/B01 and be provided with richness N2Gas discharge line A07/B07 and CO2Discharge line A08/B08, the richness
N2CO is provided with gas discharge line2Sensor；The rich N2Gas discharge line connects chimney 3 or N2Storage tank 14, the CO2Discharge pipe
Road is sequentially communicated dewatering dryer 10, CO2Cooler 11, CO2Compressor 12, liquefaction CO2Storage tank 13.
One aspect of the present invention proposes one kind by flue gas oxidation, purification device 4, N2/CO2Membrane separation device 5 and CO2Circularly trapping
The new system that tower 8 is constituted, the cement kiln flue gas discharged from the cave tail's releaser 1 after the kiln tail dust-precipitator of cement plant is introduced into described
Fluorine therein, chlorine, sulphur, nitre, hydrocarbon and heavy metal are removed in flue gas oxidation, purification device 4 and dust pollution thing is contained
N2、CO2And O2Mixing purifying smoke, subsequently into the N2/CO2Carbon dioxide and nitrogen separation are carried out in membrane separation device 5,
Isolate rich CO2Flue gas body, the rich CO2Flue gas body enters back into the CO2In circularly trapping tower 8 by hydrate or physics-
Chemiadsorption carries out CO2Trapping and CO2From releasing, you can isolate pure CO2, whole change system is not only simple in structure, cost into
This is low, industrially applicable, and realizes the purifying discharge of cement producing line flue gas, realizes the effective of cement production enterprise
Emission reduction and the production of low-carbon metaplasia.
On the other hand, N of the present invention2/CO2The air inlet side of membrane separation device 5 is directly connected with the cave tail's releaser 1,
Can by the use of cave tail's releaser 1 air blast as ahead power, go out CO2Side is connected with cooler 6 and flue gas compressor 7, Ke Yili
It is power with the negative-pressure ward masterpiece of flue gas compressor, goes out N2Chimney 3 of the side directly with high more than 70 rice is connected, due to stack effect
Also rich N can be produced2The power of side, it is thus of the invention to consume other energy again to promote the infiltration point of carbon dioxide and nitrogen
From must set booster fan and air-introduced machine compared to existing membrane separation device must require the expenditure of energy, the present invention fully profit
With these existing installations and facilities normally run such as high chimney 3 of cave tail's releaser 1, more than 70 rice in cement production process,
Major impetus is used as by the use of its normal power consumption so that the newly-increased energy consumption of change system that the present invention is used is extremely low, drops significantly
Energy expenditure in low whole technical process, so as to reduce operation cost.
Another further aspect, CO of the present invention2Circularly trapping tower 8 uses two-column design, as the CO2Circulation, which is caught, releases device A progress
CO2During trapping, the CO2Circulation, which is caught, releases device B progress CO2From releasing, as the CO2Circulation, which is caught, releases in device A hydration reaction close to complete
Entirely, i.e., as the rich N2Pass through CO in gas discharge line2Sensor monitoring is to CO in tower2When content rises, the CO2Circulation is caught
Release device A and switch to CO2From program of releasing, the CO2Circulation, which is caught, releases device B switching progress CO2Trapping, thus alternate cycles progress, can connect
Continuous uninterruptedly obtained CO2Stored, not only airflow is stable for whole technical process, realizes CO2Continuous high-efficient trapping,
It is particularly suitable for use in CO in the big cement kiln discharge flue gas of gas flow2Trapping.
Provided with horizontal silk screen and vertical/tilting silk screen in further aspect, silk screen capture bed apparatus A04/B04 of the present invention
Composition trapping-and from a large space is released, combined with atomizing sprayer A03/B03, make CO2Trapping agent is in countless droplets and richness CO2
Cigarette air flow contacts, more pass through trapping-from the horizontal silk screen released in a large space and vertically/tilting silk screen and reverse flow with big flow
Dynamic liquid film contact, and directly produced between silk screen with flue gas and bury in oblivion countless cloth films and film bubble effect, it is first mandatory to change
Liquid gas running orbit and haptoreaction state are become, by means of the countless complicated liquid films and film bubble of generation, with extra specific surface area
Very thin liquid film and the CO in flue gas stream2Fully contact, quickly and efficiently carry out hydration reaction, second set by means of big silk screen space pass
Silk screen silk screen induction nucleation quickly form substantial amounts of CO2Hydrate nucleus；At the same time, with cooling/heating device
A05/B05 cold energy fluid cooling is continuous to remove a large amount of combination heats that reinforcing absorption hydration reaction is released, and maintains temperature in trapping tower A
0 DEG C~20 DEG C of degree (depending on feelings selection)；Quick and efficient hydration reaction generates a large amount of CO2Hydrate crystal is gathered in trapping tower
Silk screen large space trapping-from releasing in bed/space, last selectivity trapping separation CO2Remaining rich N afterwards2Air-flow continue up through
The liquid qi leel that gas-liquid separation device A06/B06 merges large space gas-liquid in tower extensively is from liquid is flowed down along inner wall of tower, rich N2Gas
Body is continuously discharged, until hydration reaction is close to completely.Thus the present invention uses CO2Trapping agent is to CO2Absorbed, and in reaction
CO is used as using the discarded waste heat of cement production process2From required heat energy is released, the newly-increased of whole change system is greatly reduced
Energy consumption, not only with higher purification separation effect, and has good energy-saving effect.
Further, electronic three are provided between the cave tail's releaser 1 and the flue gas oxidation, purification device 4, the chimney 3
Ventilation valve 2, the air inlet of the electric three passes air-valve 2 connects the cave tail's releaser 1, the first of the electric three passes air-valve 2
Exhaust outlet connects the flue gas oxidation, purification device 4, and the second exhaust port of the electric three passes air-valve 2 connects the chimney 3.
The electric three passes air-valve 2 CO in cement kiln flue gas is carried out2Trapping when turn on the flue gas oxidation, purification device
4th, cut-out and the connection of the chimney 3, when without CO2During trapping, the cement kiln flue gas conducting connection chimney 3 can be made, used
In the safety inspection of input and output gas passage in chimney 3.
Further, the flue gas oxidation, purification device 4 is net including purifier shell, the sewage located at purifier shell bottom
Change separator 404, the oxidant atomizing sprayer 402 in purifier shell and oxidation, purification and separate main body with aqueous vapor
Device 401, the scavenging solution circulating sprayer 403 that the middle part of agent set 401 is separated located at the oxidation, purification with aqueous vapor, it is described
Scavenging solution circulating sprayer 403 connects the treated water outlet of the sewage purification separator 404.
The oxidant atomizing sprayer 402 is used in atomizing spray oxidizing decontamination agent, the cement kiln flue gas
SO2、NOx, chloride, fluoride, hydrocarbon and a huge sum of money belong to the oxidation, purification and separated with aqueous vapor in agent set 401
Oxidative cure is main containing sulfate, nitrate, villiaumite, the discarded object of villaumite, and the discarded object is separated by sewage purification and filled
404 carry out separation of solid and liquid are put, the solid waste isolated is discharged in bottom and collected, and the purified water isolated is followed by scavenging solution
Ring spray shower device 403 is reintroduced back to the middle part of flue gas oxidation, purification device 4 and carries out circulated sprinkling, so that, oxidized solidification
The solid waste produced after decontamination can be utilized as manufacture of cement or industrial chemicals, and the purified water that decontamination is produced can be reintroduced back to
Atomizing spray is carried out in flue gas oxidation, purification device 4, the cycling and reutilization of discarded object is realized.
Further, the atomizing sprayer A03/B03 includes circulating line 31, multiple on circulating line 31
The trapping agent feed tube 33 of atomizer 32, the connection circulating line 31.
CO2Trapping agent flow at the multiple atomizer 32 by the trapping agent feed tube 33, circulating line 31
Row atomized spray.
Further, the gas distribution includes the CO located at the housing bottom with pumping equipment A02/B022Cigarette gas inlet
Pipe 21 and trapping agent discharge pipe 22, the trapping agent discharge pipe 22 are sequentially connected trapping agent circulating tank 23, circulating pump 24, described to follow
The outlet of ring pump 24 connects the trapping agent feed tube 33.
The rich CO sent from the flue gas compressor 72Flue gas body passes through the CO2Cigarette gas inlet pipe 21 enters the CO2
CO is carried out in circularly trapping tower 82Trapping, CO2Trap from releasing rear remaining CO2Trapping solution is drained into by the trapping agent discharge pipe 22
Unified collection is carried out in the trapping agent circulating tank 23, CO next time in tower is treated2Trapping be when will start, and the circulating pump 24 is by CO2Catch
Collection agent is pumped into the atomizing sprayer A03/B03 in tower and carries out CO again2The atomizing spray of trapping agent, thus achieves original
Material is recycled.
Further, the trapping agent feed tube 33 is provided with trapping agent feed liquor pipe valve 331, the CO2Cigarette gas inlet
Pipe 21 is provided with flue gas intake valve 211, and the trapping agent discharge pipe 22 discharges pipe valve 221, the CO provided with trapping agent2
Inlet end of the cigarette gas inlet pipe 21 provided with flue gas intake valve is additionally provided with flue gas main valve 212, the rich N2Gas discharge line
A07/B07 is provided with N2Gas discharges switching valve 71, the CO2Discharge line A08/B08 is provided with CO2Discharge switching valve 81.
The trapping agent feed liquor pipe valve 331 is used to control CO2The input of trapping agent, flue gas main valve 212 is used to control from institute
State the rich CO that flue gas compressor 7 is sent2Total break-make of flue gas body, the flue gas intake valve 211 is used to control the rich CO2Flue gas
Body is in the CO2Circulation, which is caught, releases device A (or CO2Circulation, which is caught, releases device B) carry out CO2Opened during trapping, carry out CO2Closed from when releasing, institute
Stating trapping agent discharge pipe valve 221 is used for CO in tower2From having released rear CO2The discharge of trapping agent and waste liquid, the N2Gas discharges switching valve
71 are used to control the rich N2Gas discharge line A07/B07 is in the CO2Circulation, which is caught, releases device A (or CO2Circulation, which is caught, releases device B) carry out
CO2Turned on during trapping, carry out CO2Cut off from when releasing, the CO2Discharge switching valve 81 is used to control the CO2Discharge line A08/
B08 is in the CO2Circulation, which is caught, releases device A (or CO2Circulation, which is caught, releases device B) carry out CO2Cut off during trapping, carry out CO2Turned on from when releasing,
Thereby guarantee that CO2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases device B stably alternately CO2Trapping and CO2From releasing, realize efficient
Continuous CO2Trapping separation.
Further, the cooling/heating device A05/B05 goes out pipeline including coil pipe 51, hot flowing into pipeline 52, hot-fluid
53rd, cold flowing into pipeline 54, cold flow go out pipeline 55, the accumulation of energy fluid inlet 51m connections hot flowing into pipeline 52 of the coil pipe 51
With one end of the cold flowing into pipeline 54, the accumulation of energy fluid issuing 51n connections hot-fluid of the coil pipe 51 goes out pipeline 53 and institute
State one end that cold flow goes out pipeline 54, the other end that the other end, the hot-fluid of the hot flowing into pipeline 52 go out pipeline 53 connects respectively
The two ends of the used heat energy storage equipment are connect, the other end of the cold flowing into pipeline 54, the cold flow go out the other end point of pipeline 55
Do not connect cold-storage device, the cold-storage device uses temperature for 0 DEG C~20 DEG C of cold energy fluid, including underground water or NH3Or CO2。
The cooling/heating device A05/B05, except that can be coil exchanger, can also be calandria heat exchanger,
The heat exchanger channels shape of heat exchanging device is not limited.The hot flowing into pipeline 52, hot-fluid go out pipeline 53, cold flowing into pipeline 54, cold
The on and off that corresponding pipeline valve carrys out control pipeline is respectively equipped with outflow pipeline 55, to carry out CO in tower2During trapping
It is input into cold energy fluid and carries out CO to being cooled in tower, in tower2Heated from heat energy fluid is inputted when releasing.
Ground is not limited, and the cold energy fluid uses temperature for 0 DEG C~20 DEG C of cold energy fluid, for absorbing CO2Trapping is released
The reaction heat put, can make temperature in tower lower.
Further, the used heat energy storage equipment 9 include in accumulation cement production process produce more than 300 DEG C it is discarded more than
The existing aqueous medium waste heat of energy storage equipment, accumulation of 100 DEG C~300 DEG C discarded waste heats of energy storage equipment, accumulation of heat or high temperature heat
150 DEG C~500 DEG C radiant heat of energy storage equipment, accumulation high-temperature service of 100 DEG C~170 DEG C discarded waste heats after generating or conduction are useless
At least one of energy storage equipment of heat.
The used heat energy storage equipment 9 make use of the discarded a large amount of waste heats of cement producing line as CO2The energy of trapping, reduction
The newly-increased energy consumption of whole change system, reduces operation cost, breaches CO in existing CCS technological systems2The high throwing of trapping
Money, high energy consumption, the bottleneck of high cost, it is economical.
Embodiment two
Fig. 5 is the CO suitable for cement kiln flue gas that the embodiment of the present invention two is proposed2The knot of the change system continuously trapped
Structure schematic diagram.
Referring to Fig. 5, the present embodiment two and the difference of embodiment one are：The CO2Circularly trapping tower includes knot
Structure it is identical and be arranged in parallel by the CO2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases two sets that device B is constituted, first set CO2Circulation
Trapping tower 8 includes CO2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases device B, second set of CO2Circularly trapping tower 8 ' includes CO2Circulation, which is caught, to be released
Device A ' and CO2Circulation, which is caught, releases device B ', each CO2The rich N for releasing device (A, B, A ', B ') is caught in circulation2Gas discharge line connects chimney
Or N2Storage tank, each CO2The CO for releasing device (A, B, A ', B ') is caught in circulation2Discharge line is sequentially communicated the dewatering dryer.
So that, through N2/CO2The rich CO that membrane separation device is isolated2Flue gas body is divided into two strands while being continuously respectively fed to
First set CO2Circularly trapping tower and second set of CO2In circularly trapping tower, first set CO2Circularly trapping tower and second set of CO2Circulation
The N that trapping tower is discharged respectively2Air-flow all passes through the smoke stack emission, first set CO2Circularly trapping tower and second set of CO2Circulation is caught
The CO of Ji Ta separation discharges2Air-flow is all continuously introduced into drier dehydration by the cooling compression set negative-pressure ward of drying of back segment, with
After carry out CO2Storage.
Using two sets of CO being arranged in parallel2Circularly trapping tower, can double rich CO2The treating capacity of flue gas, improves CO2's
Collection efficiency.
Embodiment three
Fig. 6 is the CO suitable for cement kiln flue gas that the embodiment of the present invention three is proposed2The knot of the change system continuously trapped
Structure schematic diagram.
Referring to Fig. 6, the present embodiment three and the difference of embodiment one are：The CO2Circularly trapping tower includes knot
Structure it is identical and be arranged in series by the CO2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases two sets that device B is constituted, first set CO2Circulation
Trapping tower includes CO2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases device B, second set of CO2Circularly trapping tower includes CO2Circulation, which is caught, releases device
A " and CO2Circulation, which is caught, releases device B ", and the flue gas compressor first connects first set CO2Circularly trapping tower, CO described in first set2Circulation
Trap the rich N of tower2Gas discharge line connects chimney or N2Storage tank, first set CO2The CO of circularly trapping tower2Discharge line connection the
Two sets of CO2The gas distribution and pumping equipment of circularly trapping tower, second set of CO2The rich N of circularly trapping tower2Gas discharge line connects N2Storage
Tank, second set of CO2The CO of circularly trapping tower2Discharge line connects dewatering dryer.
So that, through N2/CO2The rich CO that membrane separation device is isolated2Flue gas body all first sends into first set CO2Circulation
Trap tower (A, B) and carry out CO2Trap from releasing, trap the N isolated2Air-flow directly by smoke stack emission or delivers to N2Storage tank enters
Row storage, the rich CO that trapping separation is produced2Gas sends into second set of CO2CO is carried out in circularly trapping tower again2Trap from releasing,
Two sets of CO2The N of circularly trapping tower separation discharge2Air-flow purity height is fed directly to N2Storage tank is stored, second set of CO2Circulation is caught
The CO of Ji Ta separation discharges2Air-flow is continuously introduced into drier dehydration by the cooling compression set negative-pressure ward of drying of back segment, also enters
Row CO2Storage.
Using two sets of CO being arranged in series2Circularly trapping tower unit, further effectively increases CO2The purity of collection.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the scope of the invention, it is every at this
Under the inventive concept of invention, the equivalent structure transformation made using description of the invention and accompanying drawing content, or directly/use indirectly
It is included in other related technical fields in the scope of patent protection of the present invention.
Claims (10)
1. one kind CO suitable for cement kiln flue gas2The change system continuously trapped, it is characterised in that including cave tail's releaser, cigarette
Chimney, flue gas oxidation, purification device, N2/CO2Membrane separation device, cooler, flue gas compressor, CO2Circularly trapping tower, dewatering dryer,
CO2Cooler, CO2Compressor, liquefaction CO2Storage tank；
The exhaust outlet of the tail exhaust blower connects the air inlet of the flue gas oxidation, purification device, and the flue gas oxidation, purification device is used for
Remove the SO in cement kiln flue gas2, NOx, chloride, fluoride, hydrocarbon, heavy metal and dust pollution thing, the cigarette
N described in the purifying smoke outlet of gas oxidation, purification device2/CO2The air inlet of membrane separation device, the N2/CO2UF membrane is filled
The rich N put2Outlet connection chimney, richness CO2Outlet passes sequentially through cooler and the CO is connected with flue gas compressor2Circulation is caught
Ji Ta；
CO2Circularly trapping tower includes the CO that structure is identical and is arranged in parallel2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases device B, the CO2
Circulation, which is caught, releases device A and CO2Circulation catch release device B alternately be carried out continuously CO2Trapping and CO2From releasing, the CO2Circulation, which is caught, to be released device A and includes
Housing, gas distribution and pumping equipment located at housing bottom and gas-liquid separation device from top to bottom in housing, atomizing spray
Device, silk screen capture bed apparatus, cooling/heating device, the case top are additionally provided with temperature and pressure inductor；The gas distribution and discharge opeing
Device connects the outlet of the flue gas compressor, for sending into richness CO into housing2Flue gas body, the atomizing sprayer is used for
Atomization sprays into CO2Trapping agent, silk screen capture bed apparatus includes horizontal silk screen on support frame, vertical silk screen and tilting
Silk screen, the cooling/heating device connects used heat energy storage equipment, and used heat energy storage equipment institute accumulation of heat can be cement production process
The discarded waste heat of middle generation, the case top is provided with richness N2Gas discharge line and CO2Discharge line, the rich N2Gas discharge pipe
CO is provided with road2Sensor；
The rich N2Gas discharge line connects chimney or N2Storage tank, the CO2Discharge line is sequentially communicated dewatering dryer, CO2It is cold
But device, CO2Compressor, liquefaction CO2Storage tank.
2. the CO as claimed in claim 1 suitable for cement kiln flue gas2The change system continuously trapped, it is characterised in that described
Electric three passes air-valve, the electric three passes air-valve are provided between cave tail's releaser and the flue gas oxidation, purification device, the chimney
Air inlet connect the cave tail's releaser, the first row gas port of the electric three passes air-valve connects the flue gas oxidation, purification
Device, the second exhaust port of the electric three passes air-valve connects the chimney.
3. the CO as claimed in claim 1 suitable for cement kiln flue gas2The change system continuously trapped, it is characterised in that described
Flue gas oxidation, purification device includes purifier shell, the sewage purification separator located at purifier shell bottom, located at clarifier
Oxidant atomizing sprayer and oxidation, purification in housing separate agent set with aqueous vapor, located at the oxidation, purification and aqueous vapor
The scavenging solution circulating sprayer in the middle part of agent set is separated, the scavenging solution circulating sprayer connects the sewage purification point
From the treated water outlet of device.
4. the CO as claimed in claim 1 suitable for cement kiln flue gas2The change system continuously trapped, it is characterised in that described
Atomizing sprayer includes circulating line, multiple atomizers on circulating line, the trapping of the connection circulating line
Agent feed tube.
5. the CO as claimed in claim 4 suitable for cement kiln flue gas2The change system continuously trapped, it is characterised in that described
Gas distribution includes the CO located at the housing bottom with pumping equipment2Cigarette gas inlet pipe and trapping agent discharge pipe, the trapping agent
Discharge pipe is sequentially connected trapping agent circulating tank, circulating pump, and the outlet of the circulating pump connects the trapping agent feed tube.
6. the CO as claimed in claim 5 suitable for cement kiln flue gas2The change system continuously trapped, it is characterised in that described
Trapping agent feed tube is provided with trapping agent feed liquor pipe valve, the CO2Cigarette gas inlet pipe is provided with flue gas intake valve, the trapping
Agent discharge pipe discharges pipe valve, the CO provided with trapping agent2Cigarette gas inlet pipe is provided with the inlet end of flue gas intake valve
It is additionally provided with flue gas main valve.
7. the CO as claimed in claim 1 suitable for cement kiln flue gas2The change system continuously trapped, it is characterised in that described
Cooling/heating device includes coil pipe, hot flowing into pipeline, hot-fluid and goes out pipeline, cold flowing into pipeline, cold flow and go out pipeline, the coil pipe
Accumulation of energy fluid inlet connects one end of the hot flowing into pipeline and the cold flowing into pipeline, and the accumulation of energy fluid issuing of the coil pipe connects
Connect that the hot-fluid goes out pipeline and the cold flow goes out one end of pipeline, the other end, the hot-fluid of the hot flowing into pipeline go out pipeline
The other end connect the two ends of the used heat energy storage equipment respectively, the other end of the cold flowing into pipeline, the cold flow go out pipeline
The other end connect cold-storage device respectively, the cold-storage device uses temperature for 0 DEG C~20 DEG C of cold energy fluid fluid, including ground
Lower water or NH3Or CO2。
8. the CO as claimed in claim 1 suitable for cement kiln flue gas2The change system continuously trapped, it is characterised in that described
Used heat energy storage equipment includes more than the 300 DEG C discarded waste heats produced in accumulation cement production process or the accumulation of energy dress of high temperature heat
Put, 100 DEG C~170 DEG C after the existing aqueous medium cogeneration of energy storage equipment, accumulation of 100 DEG C~300 DEG C discarded waste heats of accumulation
In 150 DEG C~500 DEG C radiant heat of energy storage equipment, accumulation high-temperature service of discarded waste heat or the energy storage equipment of conduct waste heat at least
It is a kind of.
9. the CO as claimed in claim 1 suitable for cement kiln flue gas2The change system continuously trapped, it is characterised in that described
CO2Circularly trapping tower include structure it is identical and be arranged in parallel by the CO2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases device B compositions
Some sets, the flue gas compressor connects some set CO simultaneously2Circularly trapping tower, each CO2Circularly trapping tower
Rich N2Gas discharge line connects chimney or N2Storage tank, each CO2The CO of circularly trapping tower2Discharge line is sequentially communicated described
Dewatering dryer.
10. the CO as claimed in claim 1 suitable for cement kiln flue gas2The change system continuously trapped, it is characterised in that institute
State CO2Circularly trapping tower include structure it is identical and be arranged in series by the CO2Circulation, which is caught, releases device A and CO2Circulation, which is caught, releases device B structures
Into some sets, the flue gas compressor is sequentially connected some set CO2Circularly trapping tower, each CO2Circularly trapping tower
Rich N2Gas discharge line connects N2Storage tank, the CO positioned at upstream2The CO of circularly trapping tower2Under discharge line connection is located at
The CO of trip2The gas distribution and pumping equipment of circularly trapping tower.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710253279.8A CN107115776A (en) | 2017-04-18 | 2017-04-18 | One kind CO suitable for cement kiln flue gas2The change system continuously trapped |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710253279.8A CN107115776A (en) | 2017-04-18 | 2017-04-18 | One kind CO suitable for cement kiln flue gas2The change system continuously trapped |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107860238A (en) * | 2017-10-14 | 2018-03-30 | 上海柯来浦能源科技有限公司 | The method and commercial plant of zero-emission |
| CN107899377A (en) * | 2017-11-27 | 2018-04-13 | 北京集封环能科技有限责任公司 | The trapping retracting device and method of carbon dioxide in flue gas |
| CN107966025A (en) * | 2017-11-07 | 2018-04-27 | 登封市豫登耐火材料厂 | A kind of environmentally friendly fire resisting brickkiln facility based on sensing heating control technology |
| CN108499326A (en) * | 2018-06-13 | 2018-09-07 | 南京圣卡孚科技有限公司 | A kind of flue gas recovery device and recovery method based on silicon carbide film |
| CN108772405A (en) * | 2018-06-25 | 2018-11-09 | 安徽海螺集团有限责任公司 | A kind of cement kiln flue gas introduces the connection structure of CCUS systems |
| CN113477051A (en) * | 2021-07-02 | 2021-10-08 | 中国科学院广州能源研究所 | Device and method for continuously capturing CO2 by double-bed hydrate method |
| US12121854B2 (en) * | 2021-07-02 | 2024-10-22 | Guangzhou Institute Of Energy Conversion, Chinese Academy Of Sciences | Device and method for continuous CO2 capture by double-bed hydrate process |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101314102A (en) * | 2008-05-30 | 2008-12-03 | 西安热工研究院有限公司 | Method and apparatus for collecting carbonic anhydride in coal-fired plant flue gas |
| CN202387354U (en) * | 2011-12-23 | 2012-08-22 | 武汉凯迪工程技术研究总院有限公司 | Equipment for capturing carbon dioxide in flue gas of power station and with high efficiency and low energy consumption |
| CN105126551A (en) * | 2015-09-11 | 2015-12-09 | 东南大学 | Device and method for capturing CO2 in coal-fired flue gas by grades based on membrane method |
| CN105771559A (en) * | 2016-04-21 | 2016-07-20 | 中国石油大学(华东) | Device and method suitable for acquiring carbon dioxide before gasification and combustion of coal |
| US20160236137A1 (en) * | 2013-10-09 | 2016-08-18 | Reliance Industries Limited | A multi-compression system and process for capturing carbon dioxide |
| CN206823510U (en) * | 2017-04-18 | 2018-01-02 | 长沙紫宸科技开发有限公司 | One kind CO suitable for cement kiln flue gas2The change system continuously trapped |
-
2017
- 2017-04-18 CN CN201710253279.8A patent/CN107115776A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101314102A (en) * | 2008-05-30 | 2008-12-03 | 西安热工研究院有限公司 | Method and apparatus for collecting carbonic anhydride in coal-fired plant flue gas |
| CN202387354U (en) * | 2011-12-23 | 2012-08-22 | 武汉凯迪工程技术研究总院有限公司 | Equipment for capturing carbon dioxide in flue gas of power station and with high efficiency and low energy consumption |
| US20160236137A1 (en) * | 2013-10-09 | 2016-08-18 | Reliance Industries Limited | A multi-compression system and process for capturing carbon dioxide |
| CN105126551A (en) * | 2015-09-11 | 2015-12-09 | 东南大学 | Device and method for capturing CO2 in coal-fired flue gas by grades based on membrane method |
| CN105771559A (en) * | 2016-04-21 | 2016-07-20 | 中国石油大学(华东) | Device and method suitable for acquiring carbon dioxide before gasification and combustion of coal |
| CN206823510U (en) * | 2017-04-18 | 2018-01-02 | 长沙紫宸科技开发有限公司 | One kind CO suitable for cement kiln flue gas2The change system continuously trapped |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107860238A (en) * | 2017-10-14 | 2018-03-30 | 上海柯来浦能源科技有限公司 | The method and commercial plant of zero-emission |
| CN107860238B (en) * | 2017-10-14 | 2019-06-25 | 上海柯来浦能源科技有限公司 | The commercial plant of zero-emission |
| CN107966025A (en) * | 2017-11-07 | 2018-04-27 | 登封市豫登耐火材料厂 | A kind of environmentally friendly fire resisting brickkiln facility based on sensing heating control technology |
| CN107899377A (en) * | 2017-11-27 | 2018-04-13 | 北京集封环能科技有限责任公司 | The trapping retracting device and method of carbon dioxide in flue gas |
| CN108499326A (en) * | 2018-06-13 | 2018-09-07 | 南京圣卡孚科技有限公司 | A kind of flue gas recovery device and recovery method based on silicon carbide film |
| CN108772405A (en) * | 2018-06-25 | 2018-11-09 | 安徽海螺集团有限责任公司 | A kind of cement kiln flue gas introduces the connection structure of CCUS systems |
| CN113477051A (en) * | 2021-07-02 | 2021-10-08 | 中国科学院广州能源研究所 | Device and method for continuously capturing CO2 by double-bed hydrate method |
| WO2022096026A1 (en) * | 2021-07-02 | 2022-05-12 | 中国科学院广州能源研究所 | Device and method for two-bed hydrate continuous co2 capture |
| US20240261728A1 (en) * | 2021-07-02 | 2024-08-08 | Guangzhou Institute Of Energy Conversion, Chinese Academy Of Sciences | Device and method for continuous co2 capture by double-bed hydrate process |
| US12121854B2 (en) * | 2021-07-02 | 2024-10-22 | Guangzhou Institute Of Energy Conversion, Chinese Academy Of Sciences | Device and method for continuous CO2 capture by double-bed hydrate process |
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Application publication date: 20170901 |