CN107099156A - A kind of modified asphalt material and preparation method thereof - Google Patents

A kind of modified asphalt material and preparation method thereof Download PDF

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Publication number
CN107099156A
CN107099156A CN201710411465.XA CN201710411465A CN107099156A CN 107099156 A CN107099156 A CN 107099156A CN 201710411465 A CN201710411465 A CN 201710411465A CN 107099156 A CN107099156 A CN 107099156A
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weight
parts
automobile
modified asphalt
materials
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CN201710411465.XA
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Inventor
林雨冬
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JILIN JIARUI PITCH TECHNOLOGY Co Ltd
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JILIN JIARUI PITCH TECHNOLOGY Co Ltd
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Priority to CN201710411465.XA priority Critical patent/CN107099156A/en
Publication of CN107099156A publication Critical patent/CN107099156A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/20Recycled plastic

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Road Paving Structures (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of modified asphalt material and preparation method thereof, is related to asphalt material field, solves existing the problem of pollution environment of the automobile dismounting not present in recyclable material, high cost, waste of resource are handled by the way of directly burning.The modified asphalt material of the present invention is in terms of parts by weight including automobile dismounting not recyclable material and the SBS modified pitch of 93~97 parts by weight;Recyclable material is not selected from one or both of materials A and material B to the automobile dismounting;The materials A is 1~5 parts by weight, the one or more in roof of the vehicle, automobile trunk, automobile door plate;The material B is 2~4 parts by weight, the one or more in fascia, vehicle steering, automobile rubber foot pad.The modified asphalt material of the present invention, Rut resistance, cold-check resistance can be strong, and pavement performance is superior, have the advantages that cost is low, pollution-free, environmentally friendly, road life.

Description

A kind of modified asphalt material and preparation method thereof
Technical field
The present invention relates to asphalt material technical field, and in particular to a kind of modified asphalt material and preparation method thereof.
Background technology
With riseing year by year for China's automobile guarantee-quantity, how effectively to handle the waste and scrap after motor vehicle liquidation is disassembled turns into The technical barrier of primary solution.During motor vehicle liquidation is disassembled, what can be utilized with recycled in its entirety has imported components, steel The material such as iron and non-ferrous metal, this part accounts for 83~86%;And nonmetal object goods, materials and equipments material accounts for 14~17%, this portion of material bag Include:Roof of the vehicle, automobile trunk, automobile door plate, fascia, vehicle steering, automobile rubber foot pad, tire etc., are removed Rubber for tire can be used again outer, other materials not recoverable in this part, can only be by directly burning Mode is handled.Handled by way of directly burning automobile dismounting not recyclable material when, due to burning produce it is harmful Gas can severe contamination environment, and burn material used in equipment and workman be required for paying substantial amounts of fund, increase Ample resources is wasted again while processing cost.If this partial automobile can be disassembled to not recyclable material to be rationalized Utilize, the policy that the waste and scrap of country's promotion is recycled can not only be complied with, and can also be carried for waste and scrap processing For another effective way.
The content of the invention
In order to solve the existing pollution ring that automobile dismounting is handled by the way of directly burning not present in recyclable material The problem of border, high cost, waste of resource, the present invention provides a kind of modified asphalt material and preparation method thereof.
The present invention is as follows to solve the technical scheme that technical problem is used:
The present invention a kind of modified asphalt material, in terms of parts by weight including:Automobile dismounting not recyclable material and 93~ The SBS modified pitch of 97 parts by weight;
Recyclable material is not selected from one or both of materials A and material B to the automobile dismounting;
The materials A is 1~5 parts by weight, the one or more in roof of the vehicle, automobile trunk, automobile door plate;
The material B is 2~4 parts by weight, one kind in fascia, vehicle steering, automobile rubber foot pad Or it is a variety of.
As preferred embodiment, the SBS modified pitch is preferably 95 parts by weight.
As preferred embodiment, the materials A is preferably 3 parts by weight.
As preferred embodiment, the material B is preferably 3 parts by weight.
As preferred embodiment, recyclable material selection is not two kinds of materials A and material B to the automobile dismounting.
As preferred embodiment, a kind of modified asphalt material of the invention, in terms of parts by weight including:
The parts by weight of SBS modified pitch 95;
The parts by weight of materials A 3;
The parts by weight of material B 3;
The one kind of the materials A in roof of the vehicle, automobile trunk, automobile door plate;
The one kind of the material B in fascia, vehicle steering, automobile rubber foot pad.
Present invention also offers a kind of above-mentioned preparation method of modified asphalt material, comprise the following steps:
Step 1: SBS modified pitch is preheated into 180~185 DEG C;
Step 2: by automobile dismounting, recyclable material is not crushed to 40~60 mesh;
Step 3: step 2 products therefrom is well mixed with step one products therefrom;
Step 4: persistently stirring 2~4h, modified asphalt material is obtained.
As preferred embodiment, in step one, preheating temperature is preferably 183 DEG C.
Present invention also offers a kind of rational utilization method of automobile dismounting not recyclable material, comprise the following steps:
Step 1: by automobile dismounting, recyclable material is not crushed to 40~60 mesh;
Step 2: the matrix pitch of 90~91 parts by weight is preheated into 180~185 DEG C, adds 1~3.6 parts by weight SBS and change Property agent, 0.4 parts by weight stabilizer, add 1.6~2 parts by weight cosolvents under lasting stirring after grinding, it is broken after vapour Car disassembles not recyclable material, stirs 10min;
Step 3: blend obtained by step 2 is squeezed into finished pot, then add into finished pot 0.4 parts by weight stabilizer, 2~4h is persistently stirred under the conditions of 180 DEG C, modified asphalt material is obtained.
As preferred embodiment, the automobile dismounting not one kind in materials A and material B of recyclable material or Two kinds;
The materials A is 1~5 parts by weight, the one or more in roof of the vehicle, automobile trunk, automobile door plate;
The material B is 2~4 parts by weight, one kind in fascia, vehicle steering, automobile rubber foot pad Or it is a variety of.
The beneficial effects of the invention are as follows:
The purpose of the present invention is that the waste and scrap after being disassembled using motor vehicle liquidation prepares a kind of modified pitch new material, is solved The problem of part can not be recycled after automobile dismounting.The modified pitch new material that the present invention is obtained has the characteristics that:
1st, the road life of modified asphalt material.
2nd, the Rut resistance of modified asphalt material, cold-check resistance can strengthen, and substantially, pavement performance is superior for function.
3rd, process for preparing modified asphalt saves resource, and cost is greatly lowered, non-environmental-pollution, environmental protection.
4th, process for preparing modified asphalt effectively solves the not recovering discarded material produced during motor vehicle liquidation is disassembled Use problem, efficent use of resources turns waste into wealth, and improves Social benefit and economic benefit.
The present invention also provides a kind of rational utilization method for handling the not recyclable material after automobile dismounting, can only lead to Cross such as ceiling pad cotton, fiber, slipmat, abatvoix, flame-retarded resin felt, PET blankets and the rubber-like of directly burning processing Material is prepared into a kind of modified pitch, meets road engineering code requirement, shows good pavement performance, solves automobile dismounting What is produced can not the discarded object that utilizes of secondary recovery.Simultaneously while existing pitch every road index is changed, it is to avoid pair The problem of environmental pollution and the wasting of resources that the existing processing method of discarded object is brought, add social output and social benefit.
Embodiment
A kind of modified asphalt material of the present invention, including automobile dismounting not recyclable material and 93~97 in terms of parts by weight The SBS modified pitch of parts by weight.
Described SBS modified pitch, including following components in terms of parts by weight:The parts by weight of matrix pitch (90#) 90~91, The parts by weight of SBS modifier 1~3.6, the parts by weight of stabilizer 0.4, the parts by weight of cosolvent 1.6~2.Matrix pitch is preheated to 180 ~185 DEG C, SBS modifier, stabilizer are added, the agitated rear acquisition SBS of cosolvent is added after grinding under lasting stirring Modified pitch.
Recyclable material can not individually select materials A to described automobile dismounting, can individually select material B, can also Select materials A and two kinds of material B mixture.
By automobile dismounting, recyclable material is not divided into two classes, and a class is materials A, and materials A is 1~5 parts by weight, selected from automobile One or more in ceiling, automobile trunk, automobile door plate.This kind of material is to play the glass of sound isolating and flame-retardant in automotive trim Glass fiber-like material, polyurethane class material, the material of this part have that stronger wearability, intensity be high, corrosion-resistant, toughness It is good, fire-retardant.
Another kind of is material B, and material B is 2~4 parts by weight, selected from fascia, vehicle steering, automobile rubber pin One or more in pad.This kind of material is the rigid plastics rubber type of material shielded in automotive trim, material molecule Amount is big, and anti-high and low-temp performance is strong.Due to using automobile dismounting not recyclable material so that modified asphalt material of the invention Rut resistance, the freeze proof ability of splitting be remarkably reinforced, while its road is obviously prolonged with the life-span, pavement performance is more superior.
A kind of preparation method of above-mentioned modified asphalt material, comprises the following steps:
Step 1: SBS modified pitch is preheated into 180~185 DEG C;
Step 2: by automobile dismounting, recyclable material is not crushed to 40~60 mesh;
Step 3: step 2 products therefrom is well mixed with step one products therefrom;
Step 4: persistently stirring 2~4h, modified asphalt material is obtained.
In above-mentioned preparation process, described automobile dismounting not one kind in materials A and material B of recyclable material or Two kinds.Materials A and material B both materials can be added separately in SBS modified pitch, and SBS is added to after can also mixing In modified pitch, because the performance of both materials is different, while being used in mixed way best results.Materials A and material B are added simultaneously Into SBS modified pitch, because automobile dismounting not recyclable material itself characteristic (wear-resisting, intensity is high, corrosion-resistant, good toughness, resistance Combustion, molecular weight are big, and anti-high and low-temp performance is strong), the modified asphalt material obtained have Rut resistance, it is freeze proof split, fire-retardant, increase road The features such as using the life-span.
Present invention also offers a kind of rational utilization method of automobile dismounting not recyclable material, comprise the following steps:
Step 1: by automobile dismounting, recyclable material is not crushed to 40~60 mesh;The not recyclable material of described automobile dismounting The selection of material is same as above.
Step 2: the matrix pitch of 90~91 parts by weight is preheated into 180~185 DEG C, adds 1~3.6 parts by weight SBS and change Property agent, 0.4 parts by weight stabilizer, add 1.6~2 parts by weight cosolvents under lasting stirring after grinding, it is broken after vapour Car disassembles not recyclable material, stirs 10min.
Step 3: blend obtained by step 2 is squeezed into finished pot, then add into finished pot 0.4 parts by weight stabilizer, 2~4h is persistently stirred under the conditions of 180 DEG C, modified asphalt material is obtained.
The material that can not be recycled after being disassembled for motor vehicle liquidation, can only be handled by burning, and pollute environment, cost It is higher.This portion of material is added in SBS modified pitch in the present invention new modified asphalt material is made, applied in road engineering In, meet《JTG F40-2004 standard specification for construction and acceptance of highway asphalt pavement》Standard requirement, what solution automobile dismounting was produced can not The processing of the secondary discarded object utilized, while existing SBS modified pitch every road index is changed, it is to avoid torn open to automobile The problem of solution environmental pollution and the wasting of resources that the existing processing method of recyclable material is not brought, add economic output and society Can benefit.
The present invention is described in further detail with reference to embodiments.
Embodiment 1
A kind of modified asphalt material, in terms of parts by weight including:
The parts by weight of SBS modified pitch 95;
The parts by weight of materials A 3;
The parts by weight of material B 3;
The materials A is roof of the vehicle;The material B is fascia.
A kind of preparation method of above-mentioned modified asphalt material, comprises the following steps:
Step 1: the SBS modified pitch of 95 parts by weight is preheated into 183 DEG C;
Step 2: the roof of the vehicle of 3 parts by weight and the fascia of 3 parts by weight are crushed into 60 mesh respectively;
Step 3: step 2 products therefrom is well mixed with step one products therefrom;
Step 4: persistently stirring 3h, modified asphalt material is obtained.
To embodiment 1 obtain modified asphalt material carry out pavement performance detection, while with AC-20 modified asphalt mixtures Contrasted, as a result as shown in table 1.
Table 1
Pavement performance is carried out by the modified asphalt material for obtaining embodiment 1 to detect, modified drip of the invention Green material has all been lifted relative to the rutting resistance and high temperature performance of common AC-20 modified asphalt mixtures.
Embodiment 2
A kind of modified asphalt material, in terms of parts by weight including:
The parts by weight of SBS modified pitch 97;
The parts by weight of materials A 1;
The parts by weight of material B 4;
Two kinds of mixing of the materials A selection automobile trunk and automobile door plate, the two arbitrary proportion;The material B selections Fascia, the three kinds of mixing of vehicle steering and automobile rubber foot pad, three's arbitrary proportion.
A kind of preparation method of above-mentioned modified asphalt material, comprises the following steps:
Step 1: the SBS modified pitch of 97 parts by weight is preheated into 185 DEG C;
Step 2: the material B of the materials A of 1 parts by weight and 4 parts by weight is crushed into 40 mesh respectively;
Step 3: step 2 products therefrom is well mixed with step one products therefrom;
Step 4: persistently stirring 2h, modified asphalt material is obtained.
To embodiment 2 obtain modified asphalt material carry out pavement performance detection, while with AC-20 modified asphalt mixtures Contrasted, as a result as shown in table 2.
Table 2
Pavement performance is carried out by the modified asphalt material for obtaining embodiment 2 to detect, modified drip of the invention Green material has all been lifted relative to the rutting resistance and high temperature performance of common AC-20 modified asphalt mixtures.
Embodiment 3
A kind of modified asphalt material, in terms of parts by weight including:
The parts by weight of SBS modified pitch 93;
The parts by weight of materials A 5;
The parts by weight of material B 2;
The materials A selection roof of the vehicle, the three kinds of mixing of automobile trunk and automobile door plate, three's arbitrary proportion;It is described Material B selects the two kinds of mixing of vehicle steering and automobile rubber foot pad, the two arbitrary proportion.
A kind of preparation method of above-mentioned modified asphalt material, comprises the following steps:
Step 1: the SBS modified pitch of 93 parts by weight is preheated into 180 DEG C;
Step 2: the material B of the materials A of 5 parts by weight and 2 parts by weight is crushed into 50 mesh respectively;
Step 3: step 2 products therefrom is well mixed with step one products therefrom;
Step 4: persistently stirring 4h, modified asphalt material is obtained.
To embodiment 3 obtain modified asphalt material carry out pavement performance detection, while with AC-20 modified asphalt mixtures Contrasted, as a result as shown in table 3.
Table 3
Understood with performance detection, modified asphalt material of the invention is anti-relative to common AC-20 modified asphalt mixtures Rut ability and high temperature performance have all been lifted.
Embodiment 4
A kind of modified asphalt material, in terms of parts by weight including:
The parts by weight of SBS modified pitch 95;
The parts by weight of materials A 5;
The materials A selection roof of the vehicle, the three kinds of mixing of automobile trunk and automobile door plate, three's arbitrary proportion.
A kind of preparation method of above-mentioned modified asphalt material, comprises the following steps:
Step 1: the SBS modified pitch of 95 parts by weight is preheated into 184 DEG C;
Step 2: the materials A of 5 parts by weight is crushed into 55 mesh;
Step 3: step 2 products therefrom is well mixed with step one products therefrom;
Step 4: persistently stirring 3.5h, modified asphalt material is obtained.
To embodiment 4 obtain modified asphalt material carry out pavement performance detection, while with AC-20 modified asphalt mixtures Contrasted, as a result as shown in table 4.
Table 4
Pavement performance is carried out by the modified asphalt material for obtaining embodiment 4 to detect, modified drip of the invention Green material has all been lifted relative to the rutting resistance and high temperature performance of common AC-20 modified asphalt mixtures.
Embodiment 5
A kind of modified asphalt material, in terms of parts by weight including:
The parts by weight of SBS modified pitch 95;
The parts by weight of material B 4;
The material B selects fascia.
A kind of preparation method of above-mentioned modified asphalt material, comprises the following steps:
Step 1: the SBS modified pitch of 95 parts by weight is preheated into 182 DEG C;
Step 2: the material B of 4 parts by weight is crushed into 45 mesh;
Step 3: step 2 products therefrom is well mixed with step one products therefrom;
Step 4: persistently stirring 2.5h, modified asphalt material is obtained.
To embodiment 5 obtain modified asphalt material carry out pavement performance detection, while with AC-20 modified asphalt mixtures Contrasted, as a result as shown in table 5.
Table 5
Pavement performance is carried out by the modified asphalt material for obtaining embodiment 5 to detect, modified drip of the invention Green material has all been lifted relative to the rutting resistance and high temperature performance of common AC-20 modified asphalt mixtures.
Pavement performance is carried out by the modified asphalt material for obtaining embodiment 1 to embodiment 5 to detect, the present invention Modified asphalt material be fully applicable in the processing and fabricating of modified pitch, comply fully with《JTG F40-2004 highways are dripped Blue or green pavement construction technical specification》Standard requirement.The waste and scrap of disassembling that the present invention is produced using motor vehicle liquidation link is main Raw material, develops modified asphalt for pavement, and motor vehicle liquidation is disassembled into waste and scrap and applied on road surface, is turned waste into wealth, because it is former Expect that cost is almost nil, have profound influence with the life-span to construction costs and road.
Above content is to combine the further detailed description made for the present invention of specific preferred embodiment, it is impossible to recognized The specific implementation of the fixed present invention is confined to these explanations.For the person of ordinary skill of the art, can be according to this hair Bright technical scheme and inventive concept, make and accordingly change and substitute, and obtain and modification of the present invention with similar formulation Asphalt material, its performance is also inevitable identical, should all be considered as protection scope of the present invention.

Claims (10)

1. a kind of modified asphalt material, it is characterised in that in terms of parts by weight including:Automobile dismounting not recyclable material and 93~ The SBS modified pitch of 97 parts by weight;
Recyclable material is not selected from one or both of materials A and material B to the automobile dismounting;
The materials A is 1~5 parts by weight, the one or more in roof of the vehicle, automobile trunk, automobile door plate;
The material B is 2~4 parts by weight, one kind or many in fascia, vehicle steering, automobile rubber foot pad Kind.
2. a kind of modified asphalt material according to claim 1, it is characterised in that the SBS modified pitch is 95 weight Part.
3. a kind of modified asphalt material according to claim 1, it is characterised in that the materials A is 3 parts by weight.
4. a kind of modified asphalt material according to claim 1, it is characterised in that the material B is 3 parts by weight.
5. a kind of modified asphalt material according to claim 1, it is characterised in that the automobile dismounting not recyclable material Select two kinds of materials A and material B.
6. a kind of modified asphalt material according to claim 1, it is characterised in that in terms of parts by weight including:
The parts by weight of SBS modified pitch 95;
The parts by weight of materials A 3;
The parts by weight of material B 3;
The one kind of the materials A in roof of the vehicle, automobile trunk, automobile door plate;
The one kind of the material B in fascia, vehicle steering, automobile rubber foot pad.
7. prepare a kind of method of modified asphalt material in claim 1 to 6 described in any one, it is characterised in that including Following steps:
Step 1: SBS modified pitch is preheated into 180~185 DEG C;
Step 2: by automobile dismounting, recyclable material is not crushed to 40~60 mesh;
Step 3: step 2 products therefrom is well mixed with step one products therefrom;
Step 4: persistently stirring 2~4h, modified asphalt material is obtained.
8. preparation method according to claim 7, it is characterised in that in step one, preheating temperature is 183 DEG C.
9. the rational utilization method of a kind of automobile dismounting not recyclable material, it is characterised in that comprise the following steps:
Step 1: by automobile dismounting, recyclable material is not crushed to 40~60 mesh;
Step 2: the matrix pitch of 90~91 parts by weight is preheated into 180~185 DEG C, adds 1~3.6 parts by weight SBS and be modified Agent, 0.4 parts by weight stabilizer, add 1.6~2 parts by weight cosolvents under lasting stirring after grinding, it is broken after automobile Not recyclable material is disassembled, 10min is stirred;
Step 3: blend obtained by step 2 is squeezed into finished pot, then 0.4 parts by weight stabilizer is added into finished pot, 180 2~4h is persistently stirred under the conditions of DEG C, modified asphalt material is obtained.
10. a kind of rational utilization method of automobile dismounting according to claim 9 not recyclable material, its feature exists In recyclable material is not selected from one or both of materials A and material B to the automobile dismounting;
The materials A is 1~5 parts by weight, the one or more in roof of the vehicle, automobile trunk, automobile door plate;
The material B is 2~4 parts by weight, one kind or many in fascia, vehicle steering, automobile rubber foot pad Kind.
CN201710411465.XA 2017-06-05 2017-06-05 A kind of modified asphalt material and preparation method thereof Pending CN107099156A (en)

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Application Number Priority Date Filing Date Title
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101812234A (en) * 2010-04-16 2010-08-25 湖南路桥路翔工程有限公司 Waste rubber powder/waste plastics/SBS composite modified asphalt and preparation method thereof
CN102702607A (en) * 2012-06-29 2012-10-03 长沙理工大学 Composite asphalt modifier and preparation method thereof
CN104356662A (en) * 2014-12-02 2015-02-18 河北省高速公路邢汾管理处 Waste polymer modified asphalt composition and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101812234A (en) * 2010-04-16 2010-08-25 湖南路桥路翔工程有限公司 Waste rubber powder/waste plastics/SBS composite modified asphalt and preparation method thereof
CN102702607A (en) * 2012-06-29 2012-10-03 长沙理工大学 Composite asphalt modifier and preparation method thereof
CN104356662A (en) * 2014-12-02 2015-02-18 河北省高速公路邢汾管理处 Waste polymer modified asphalt composition and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
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李清民: "《汽车钣金工》", 31 January 2016, 国防工业出版社 *

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