CN107098310A - A kind of continuous hydrogen-feeding system - Google Patents
A kind of continuous hydrogen-feeding system Download PDFInfo
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- CN107098310A CN107098310A CN201610098451.2A CN201610098451A CN107098310A CN 107098310 A CN107098310 A CN 107098310A CN 201610098451 A CN201610098451 A CN 201610098451A CN 107098310 A CN107098310 A CN 107098310A
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/065—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00018—Construction aspects
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
The invention discloses a kind of continuous hydrogen-feeding system, it includes：An at least hydrogen generating apparatus, the hydrogen generating apparatus is built-in with the first production hydrogen feedstock and the second production hydrogen feedstock, before production hydrogen reaction occurs, the first production hydrogen feedstock and the second production hydrogen feedstock are mutually separated, and after the hydrogen generating apparatus is connected with a hydrogen container, the first production hydrogen feedstock and the second production hydrogen feedstock hybrid reaction simultaneously produce hydrogen；The hydrogen container has the hydrogen input port connected with the hydrogen gas outlet of the hydrogen generating apparatus and the hydrogen gas outlet connected with the hydrogen input port of external equipment.The continuous hydrogen-feeding system that the present invention is provided can be continuous for a long time, stable output hydrogen, and simple and compact for structure, safe, the equipment such as the motor vehicle that is particularly suitable for use in.
Description
Technical field
Hydrogen storage equipment, particularly a kind of continuous hydrogen-feeding system are produced the present invention relates to one kind.
Background technology
Because the critical-temperature of hydrogen is very low, critical pressure is high, so hydrogen is very difficult to liquefaction, so hydrogen is very difficult to storage
Deposit.The high-pressure hydrogen storing tank of conventional extremely low temperature is incubated and other auxiliary devices due to needing, and its hydrogen storage capability is limited, and volume is big,
Security is poor, particularly when applied to equipment such as motor vehicles, it is impossible to realize the long-time continuous stable supply of hydrogen, non-
Often it is difficult to minimize.Although there is many documents to be related to inhale the report for putting hydrogen using material, these technologies are all without real
The property used.
Practical hydrogen storage method is exactly, using chemical method hydrogen storage, then to discharge hydrogen therein using various conditions at this stage.But
It is that these systems are extremely complex, such as NaBH4-NaOH-H2For O systems, due to needing control catalyst and solution
Contact, processing caking and NaOH alkaline problem etc. so structure is extremely complex, and also needs to many control units,
Such as the switch for controlling it to react using external power, this causes such system not minimize.
In a word, miniaturization, the simplification of hydrogen production bioreactor are always industry problem urgently to be resolved hurrily.
The content of the invention
It is a primary object of the present invention to provide a kind of simple continuous hydrogen-feeding system, to overcome deficiency of the prior art.
To realize aforementioned invention purpose, the technical solution adopted by the present invention includes：
The embodiments of the invention provide a kind of continuous hydrogen-feeding system, it includes：
An at least hydrogen generating apparatus, the hydrogen generating apparatus is built-in with the first production hydrogen feedstock and the second production hydrogen feedstock, in production hydrogen
Before reaction occurs, the first production hydrogen feedstock and the second production hydrogen feedstock are mutually separated, and are stored up when by the hydrogen generating apparatus and one
After hydrogen tank connection, the first production hydrogen feedstock and the second production hydrogen feedstock hybrid reaction simultaneously produce hydrogen；
The hydrogen container have the hydrogen input port that is connected with the hydrogen gas outlet of the hydrogen generating apparatus and with external equipment
The hydrogen gas outlet of hydrogen input port connection.
In some embodiments, the continuous hydrogen-feeding system also includes：
Air pressure monitor device, at least hydrogen gas pressure to monitor the hydrogen generating apparatus output；
Alarming device, alarm signal is sent when at least the hydrogen gas pressure for being exported in the hydrogen generating apparatus is less than setting value.
In some embodiments, the hydrogen container has more than one hydrogen input port, two or more hydrogen input port difference
Connected with the hydrogen gas outlet of a hydrogen generating apparatus.
In some embodiments, parallel connection has two or more hydrogen generating apparatus on a hydrogen input port of the hydrogen container
Hydrogen gas outlet.
In some embodiments, described continuous hydrogen-feeding system also includes：
Air pressure monitor device, at least hydrogen gas pressure to monitor the hydrogen generating apparatus output；
Control unit, at least to the signal for receiving the transmission of air pressure monitor device, and the hydrogen exported in any hydrogen generating apparatus
When air pressure is less than setting value, the hydrogen circulation pipeline between any hydrogen generating apparatus and the hydrogen container is cut off, and make another
Hydrogen generating apparatus is connected with the hydrogen container.
In some embodiments, the hydrogen formation apparatus includes the closed vessel with hydrogen gas outlet, the closed vessel
Inner chamber includes in first chamber and second chamber, the first chamber and second chamber and is equipped with the first production hydrogen feedstock respectively and in stream
Second production hydrogen feedstock of body shape, is provided with partition, the partition is provided with extremely between the first chamber and second chamber
Be available for through hole that the second production hydrogen feedstock passes through and the baffle plate or plug that coordinate with the through hole less, when by the baffle plate or plug with
After the through hole is separated from each other, the second production hydrogen feedstock flows to the first production hydrogen feedstock and produces hydrogen feedstock hybrid reaction with first and give birth to
Into hydrogen.
In some embodiments, crushing mechanism is provided with the hydrogen input port of the hydrogen container, the hydrogen formation apparatus includes
Closed vessel with hydrogen gas outlet, closed vessel inner chamber bottom be loaded with flow-like second produce hydrogen feedstock, and
The first production hydrogen feedstock in the packaging structure that is contained in and can crush is distributed with the ullage of the second production hydrogen feedstock, when by described in
After the hydrogen gas outlet of hydrogen generating apparatus is connected with the hydrogen input port of the hydrogen container, contacts and break by the crushing mechanism
The broken packaging structure, makes the first production hydrogen feedstock fall into the second production hydrogen feedstock and hybrid reaction.
Further, described continuous hydrogen-feeding system may also include：Drive mechanism, for driving the crushing mechanism to contact and breaking
The broken packaging structure.
In some embodiments, the hydrogen formation apparatus includes the closed vessel with hydrogen gas outlet, the closed vessel
Inner chamber bottom is loaded with produces hydrogen feedstock in the second of flow-like, the first production hydrogen feedstock be supported by mechanism lift or hang on it is described
The execution machine to destroy the supporting device is provided with the ullage of second production hydrogen feedstock, the hydrogen input port of the hydrogen container
Structure, after the hydrogen gas outlet of the hydrogen generating apparatus is connected with the hydrogen input port of the hydrogen container, the executing agency
Contact and destroy the supporting device, the first production hydrogen feedstock is fallen into the second production hydrogen feedstock and hybrid reaction.
Further, described continuous hydrogen-feeding system may also include：Drive mechanism, for driving the executing agency to contact and breaking
The bad supporting device.
In some embodiments, the hydrogen formation apparatus includes the closed vessel with hydrogen gas outlet, the closed vessel
Inner chamber top is provided with cryptomere packaging structure, the cryptomere packaging structure and is loaded with the first production hydrogen feedstock, the closed vessel inner chamber
The second production hydrogen feedstock is distributed with bottom, when by the hydrogen input port of the hydrogen gas outlet of the hydrogen generating apparatus and the hydrogen container
After connection, the hydrogen prestored in the hydrogen container enters the cryptomere packaging structure until being burst the cryptomere packaging structure,
The first production hydrogen feedstock is set to fall into the second production hydrogen feedstock and hybrid reaction, in the first production hydrogen feedstock and the second production hydrogen feedstock extremely
Few one is flow-like.
In some more preferred embodiment, described continuous hydrogen-feeding system also includes：
Air pressure monitor device, at least hydrogen gas pressure to monitor the hydrogen generating apparatus output；
Control unit, at least to the signal for receiving the transmission of air pressure monitor device, and the hydrogen exported in any hydrogen generating apparatus
When air pressure is less than setting value, the hydrogen circulation pipeline between any hydrogen generating apparatus and the hydrogen container is cut off, and make another
Hydrogen generating apparatus is connected with the hydrogen container, and the executing agency is worked, and then is started in another hydrogen generating apparatus
Hydrogen gas production reaction.
In some embodiments, the external equipment includes fuel cell, but not limited to this.
Compared with prior art, beneficial effects of the present invention at least that：The continuous hydrogen-feeding system can be continuous for a long time, stabilization
Hydrogen is exported, and it is simple and compact for structure, safe, be particularly suitable for use in motor-driven vehicle device and mini-plant etc..
Brief description of the drawings
Fig. 1 is a kind of schematic diagram of continuous hydrogen-feeding system in the embodiment of the present invention.
Embodiment
For the ease of understanding the present invention, the present invention is described more fully below with reference to relevant drawings.Given in accompanying drawing
The better embodiment of the present invention.But, the present invention can be realized by many different forms, however it is not limited to be retouched below
The embodiment stated.On the contrary, the purpose for providing these embodiments is made to the more thorough of the disclosure understanding
Comprehensively.
It should be noted that when element is referred to as " being arranged at " another element, it can directly on another element or
There may be element placed in the middle.When an element is considered as " connection " another element, it can be directly to another
Element may be simultaneously present centering elements.Term as used herein " vertical ", " level ", "left", "right" and
For illustrative purposes only, it is unique embodiment to be not offered as similar statement.
Unless otherwise defined, the technology people of technical field of all of technologies and scientific terms used here by the article with belonging to the present invention
The implication that member is generally understood that is identical.Term used in the description of the invention herein is intended merely to describe specific implementation
The purpose of mode, it is not intended that in the limitation present invention.Term as used herein "and/or" includes one or more related institutes
The arbitrary and all combination of list of items.
A kind of continuous hydrogen-feeding system that the first embodiment of the present invention is provided includes：
An at least hydrogen generating apparatus, the hydrogen generating apparatus is built-in with the first production hydrogen feedstock and the second production hydrogen feedstock, in production hydrogen
Before reaction occurs, the first production hydrogen feedstock and the second production hydrogen feedstock are mutually separated, and are stored up when by the hydrogen generating apparatus and one
After hydrogen tank connection, the first production hydrogen feedstock and the second production hydrogen feedstock hybrid reaction simultaneously produce hydrogen；
The hydrogen container have the hydrogen input port that is connected with the hydrogen gas outlet of the hydrogen generating apparatus and with external equipment (example
Such as fuel cell) the connection of hydrogen input port hydrogen gas outlet.
Wherein, the first production hydrogen feedstock and the second production hydrogen feedstock can be selected from Suitable chemical species known to industry, for example, typically
First production hydrogen feedstock and the second production hydrogen feedstock can be selected from, but not limited to, following combination：Metal (such as Zn) and sour (such as sulfuric acid),
Alkali metal or alkaline-earth metal and water, aluminium, zinc, beryllium and NaOH, KOH, NaSiH4With H2O, copper and sodium cyanide solution,
Etc..
Wherein, the hydrogen gas outlet of the hydrogen generating apparatus can be connected by check valve with the hydrogen input port of the hydrogen container.
By being used as hydrogen supply source from such hydrogen generating apparatus, can persistently it be produced greatly with the minimum production hydrogen feedstock of space-consuming
Hydrogen is measured, than traditional by the way of hydrogen gas cylinder etc. is as hydrogen source, hydrogen supply is safer, stably, persistently.
Further, the continuous hydrogen-feeding system may also include：
Air pressure monitor device, at least hydrogen gas pressure to monitor the hydrogen generating apparatus output；
Alarming device, alarm signal is sent when at least the hydrogen gas pressure for being exported in the hydrogen generating apparatus is less than setting value.
Wherein, by monitoring the hydrogen gas pressure that hydrogen generating apparatus is exported, the starting material left feelings in hydrogen generating apparatus can be found out
Condition, particularly when hydrogen generating apparatus export hydrogen gas pressure be less than setting value when, you can judge the hydrogen generating apparatus without
Method continues stable supply hydrogen, and now operating personnel can be according to the alarm signal, in time with the hydrogen of energy regular supply hydrogen
Generation device is replaced, to ensure the continual and steady supply of hydrogen.
Wherein, the air pressure monitor device can be using other air pressure monitors known to mechanical, air gauge of electronic type etc. or industry
Equipment, and alarming device can be using that can send the device of the form signal such as sound, light, vibration, the air pressure monitor device is with warning
It can be connected, can also be coordinated by forms such as magnetic, electricity, electromagnetic waves by suitable mechanical transmission mechanism known to industry between device.
In the second embodiment of the present invention, the hydrogen container of use can have two or more hydrogen input port, and the two or more hydrogen is defeated
Hydrogen gas outlet of the entrance respectively with a hydrogen generating apparatus connects and (for example see Fig. 1).Or, the one of the hydrogen container of use
The hydrogen gas outlet of two or more hydrogen generating apparatus can be connected in parallel on individual hydrogen input port.
Further, described continuous hydrogen-feeding system may also include：
Air pressure monitor device, at least hydrogen gas pressure to monitor the hydrogen generating apparatus output；
Control unit, at least to the signal for receiving the transmission of air pressure monitor device, and the hydrogen exported in any hydrogen generating apparatus
When air pressure is less than setting value, the hydrogen circulation pipeline between any hydrogen generating apparatus and the hydrogen container is cut off, and make another
Hydrogen generating apparatus is connected with the hydrogen container.
By using the structure of the second embodiment, it is possible to achieve the automatic switchover of each hydrogen generating apparatus, more efficiently guarantee
Continuous, the stable output of hydrogen.
Wherein, described air pressure monitor device can use previously described all kinds of air pressure monitor devices.
Wherein, described control unit can be the dress with data processing function being integrally disposed in the continuous hydrogen-feeding system
Put, can also be remotely located PC such as PLC, MCU, for example, server, etc. beyond the clouds is set.
Wherein, can be in the hydrogen circulation to cut off the hydrogen circulation pipeline between the hydrogen generating apparatus and the hydrogen container
All kinds of suitable gas valves, particularly electronic, electromagnetic drive or operated pneumatic valve etc. are set on pipeline.Wherein, control unit according to
The hydrogen gas pressure signal for each hydrogen generating apparatus output found out according to air pressure monitor device, can selectively turn on or close institute
The gas valve stated, so that the hydrogen generating apparatus that will be unable to normal work in time switches to the hydrogen for being capable of normal work to produce dress
Put, realize the continual and steady hydrogen supply to hydrogen container.
In certain application scenarios, for example, fuel cell hydrogen-feeding, to ensure that hydrogen container can supply high-quality hydrogen to fuel cell
Gas, can also be between the hydrogen input port of the hydrogen container and the hydrogen gas outlet of the hydrogen generating apparatus and/or the hydrogen container
Hydrogen gas outlet at hydrogen purification device is set, to remove the vapor in hydrogen, sour gas or other may cause fuel
The chemical substance of battery operating efficiency reduction.
Postscript, to enable hydrogen container to supply hydrogen according to the demand of fuel cell, can also set in described continuous hydrogen-feeding system
Put barometric control unit, hydrogen flow rate and/or flow that nationality is exported with the hydrogen gas outlet adjusted from the hydrogen container.
In the present invention, it is adaptable to which the hydrogen formation apparatus of previous embodiment can use a variety of suitable types known to industry.
For example, in a preferred embodiment, the closing that the hydrogen formation apparatus can include bottom and have hydrogen gas outlet is held
Hydrogen feedstock is produced in device, closed vessel inner chamber upper and lower part provided with the first production hydrogen feedstock and in the second of flow-like respectively, when by institute
State after closed vessel inversion, the second production hydrogen feedstock flows to the first production hydrogen feedstock and generated with the first production hydrogen feedstock hybrid reaction
Hydrogen.Further, in this embodiment, the hydrogen formation apparatus can use the structure of similar existing fire extinguisher.
In this embodiment, the first production hydrogen feedstock and the second production hydrogen feedstock can be as mentioned before.Wherein, the first production hydrogen is former
Material can be powder shaped, granular, liquid or block.Wherein, if block, it can directly be fixed
In closed vessel inner cavity.And if powder shaped, graininess or liquid, it can be contained in partially or fully by spy
Determine in the packaging structure of material composition, the predetermined substance can be dissolved in the second production hydrogen feedstock but not produce hydrogen with first, second
Raw material or the material of any reaction product reaction of the rwo.
In another example, in a preferred embodiment, crushing mechanism, the hydrogen hair are provided with the hydrogen input port of the hydrogen container
Generating apparatus includes the closed vessel with hydrogen gas outlet, and closed vessel inner chamber bottom is loaded with produces hydrogen in the second of flow-like
Raw material, and it is former in the first production hydrogen that the described second ullage for producing hydrogen feedstock is distributed with the packaging structure that is contained in and can crush
Material, after the hydrogen gas outlet of the hydrogen generating apparatus is connected with the hydrogen input port of the hydrogen container, by described broken
Mechanism contacts simultaneously crush the packaging structure, make the first production hydrogen feedstock because self gravitation effect is fallen into the second production hydrogen feedstock and is mixed
Reaction.
Wherein, the crushing mechanism can be directly anchored on the hydrogen input port of the hydrogen container, when the hydrogen generating apparatus
When hydrogen gas outlet is connected with the hydrogen input port of the hydrogen container, the crushing mechanism can directly contact and crush the packaging knot
Structure.
Or, wherein, the crushing mechanism is also movable to be arranged in the hydrogen gas outlet of the hydrogen generating apparatus, when described
When the hydrogen gas outlet of hydrogen generating apparatus is connected with the hydrogen input port of the hydrogen container, the crushing mechanism is contacted simultaneously by promotion
Crush the packaging structure.
More preferred, described continuous hydrogen-feeding system may also include drive mechanism, for driving the crushing mechanism to contact and breaking
The broken packaging structure.The drive mechanism can be electronic, pneumatic, electromagnetic drive, electro-hydraulic driving, hydraulic drive mechanism.
In another example, in a preferred embodiment, the hydrogen formation apparatus includes the closed vessel with hydrogen gas outlet, institute
Closed vessel inner chamber is stated comprising first chamber and second chamber, the first production hydrogen is equipped with respectively in the first chamber and second chamber
Raw material and the second production hydrogen feedstock in flow-like, are provided with partition, the separation machine between the first chamber and second chamber
Structure, which is provided with, is at least available for the through hole that the second production hydrogen feedstock passes through and the baffle plate or plug that coordinate with the through hole, when by the gear
After plate or plug are separated from each other with the through hole, the second production hydrogen feedstock flows to the first production hydrogen feedstock and mixed with the first production hydrogen feedstock
Close reaction and generate hydrogen.The partition can be baffle plate etc..To drive the baffle plate or plug to divide each other with the through hole
From drive mechanism can be set in the closed vessel, such as driving structure that described closed vessel itself has is (for example, envelope
Closing container can be comprising connection and relatively turnable two parts be sealed against each other, and partition is distributed on one of which part,
And baffle plate or plug are distributed on another part, by rotating against two parts, you can make the baffle plate or plug with
The through hole is separated from each other).Or, the drive mechanism can also be electromagnetic drive mechanism etc..
For another example in a preferred embodiment, the hydrogen formation apparatus can include the closed vessel with hydrogen gas outlet,
Closed vessel inner chamber bottom is loaded with produces hydrogen feedstock in the second of flow-like, and the first production hydrogen feedstock is supported by mechanism and lifted
Or hang at the ullage of the second production hydrogen feedstock, the hydrogen input port of the hydrogen container provided with to destroy the supporting
The executing agency of mechanism, after the hydrogen gas outlet of the hydrogen generating apparatus is connected with the hydrogen input port of the hydrogen container,
The executing agency contacts and destroys the supporting device, the first production hydrogen feedstock is fallen into the second production hydrogen feedstock and hybrid reaction.
Wherein, the executing agency can be directly anchored on the hydrogen input port of the hydrogen container, when the hydrogen generating apparatus
When hydrogen gas outlet is connected with the hydrogen input port of the hydrogen container, the executing agency can directly contact and destroy the supporting machine
Structure.
Or, wherein, the executing agency is also movable to be arranged in the hydrogen gas outlet of the hydrogen generating apparatus, when described
When the hydrogen gas outlet of hydrogen generating apparatus is connected with the hydrogen input port of the hydrogen container, the executing agency is contacted simultaneously by promotion
Destroy the supporting device.
More preferred, described continuous hydrogen-feeding system may also include drive mechanism, for driving the executing agency to contact and breaking
The bad supporting device.
In some embodiments, the hydrogen formation apparatus includes the closed vessel with hydrogen gas outlet, the closed vessel
Inner chamber top is provided with cryptomere packaging structure (can be elastic material or non-resilient material), the cryptomere packaging structure
The first production hydrogen feedstock is loaded with, the second production hydrogen feedstock is distributed with closed vessel inner chamber bottom, when by the hydrogen generating apparatus
Hydrogen gas outlet be connected with the hydrogen input port of the hydrogen container after, the hydrogen prestored in the hydrogen container enter the cryptomere bag
Assembling structure makes the first production hydrogen feedstock fall into the second production hydrogen up to making the cryptomere packaging structure be burst and (partially or fully crushed)
The interior simultaneously hybrid reaction of raw material, at least one of the first production hydrogen feedstock and second production hydrogen feedstock are flow-like.
Further, in foregoing each embodiment, to realize the intelligent operation of continuous hydrogen-feeding system, described continuous confession
Hydrogen system may also include：
Air pressure monitor device, at least hydrogen gas pressure to monitor the hydrogen generating apparatus output；
Control unit, at least to the signal for receiving the transmission of air pressure monitor device, and the hydrogen exported in any hydrogen generating apparatus
When air pressure is less than setting value, the hydrogen circulation pipeline between any hydrogen generating apparatus and the hydrogen container is cut off, and make another
Hydrogen generating apparatus is connected with the hydrogen container, and the executing agency is worked, and then is started in another hydrogen generating apparatus
Hydrogen gas production reaction.
In order to facilitate the understanding of the purposes, features and advantages of the present invention, above in conjunction with accompanying drawing to the specific of the present invention
Embodiment is described in detail.Many details are elaborated in superincumbent description to fully understand the present invention.But
The present invention can be implemented with being much different from other manner described above, and those skilled in the art can be without prejudice to the present invention
Similar improvement is done in the case of intension, therefore the present invention is not limited by particular embodiments disclosed above.Also, it is described above
Each technical characteristic of embodiment can be combined arbitrarily, to make description succinct, not special to each technology in above-described embodiment
Levy all possible combination to be all described, as long as however, the combination of these technical characteristics is all considered to be in the absence of contradiction
The scope that this specification is recorded.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and in detail, but can not be because
This and be interpreted as the limitation to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art,
On the premise of not departing from present inventive concept, a plurality of modification and improvement can also be made, these belong to protection scope of the present invention.
Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (10)
1. a kind of continuous hydrogen-feeding system, it is characterised in that including：
An at least hydrogen generating apparatus, the hydrogen generating apparatus is built-in with the first production hydrogen feedstock and the second production hydrogen feedstock, in production hydrogen
Before reaction occurs, the first production hydrogen feedstock and the second production hydrogen feedstock are mutually separated, and are stored up when by the hydrogen generating apparatus and one
After hydrogen tank connection, the first production hydrogen feedstock and the second production hydrogen feedstock hybrid reaction simultaneously produce hydrogen；
The hydrogen container have the hydrogen input port that is connected with the hydrogen gas outlet of the hydrogen generating apparatus and with external equipment
The hydrogen gas outlet of hydrogen input port connection.
2. continuous hydrogen-feeding system according to claim 1, it is characterised in that also include：
Air pressure monitor device, at least hydrogen gas pressure to monitor the hydrogen generating apparatus output；
Alarming device, alarm signal is sent when at least the hydrogen gas pressure for being exported in the hydrogen generating apparatus is less than setting value.
3. continuous hydrogen-feeding system according to claim 1, it is characterised in that：The hydrogen container has more than one hydrogen defeated
Entrance, more than one hydrogen gas outlet of the hydrogen input port respectively with a hydrogen generating apparatus is connected；Or, the hydrogen container
A hydrogen input port on parallel connection have the hydrogen gas outlet of two or more hydrogen generating apparatus.
4. continuous hydrogen-feeding system according to claim 3, it is characterised in that also include：
Air pressure monitor device, at least hydrogen gas pressure to monitor the hydrogen generating apparatus output；
Control unit, at least to the signal for receiving the transmission of air pressure monitor device, and the hydrogen exported in any hydrogen generating apparatus
When air pressure is less than setting value, the hydrogen circulation pipeline between any hydrogen generating apparatus and the hydrogen container is cut off, and make another
Hydrogen generating apparatus is connected with the hydrogen container.
5. continuous hydrogen-feeding system according to claim 1, it is characterised in that：The hydrogen formation apparatus includes having hydrogen
The closed vessel of delivery outlet, the closed vessel inner chamber includes first chamber and second chamber, the first chamber and second chamber
The first production hydrogen feedstock is inside equipped with respectively and hydrogen feedstock is produced in the second of flow-like, is provided between the first chamber and second chamber
Partition, the partition is provided with the through hole for being at least available for the second production hydrogen feedstock to pass through and the gear coordinated with the through hole
Plate or plug, after the baffle plate or plug are separated from each other with the through hole, it is former that the second production hydrogen feedstock flows to the first production hydrogen
Expect and produce hydrogen feedstock hybrid reaction with first and generate hydrogen.
6. continuous hydrogen-feeding system according to claim 1, it is characterised in that：It is provided with the hydrogen input port of the hydrogen container
Crushing mechanism, the hydrogen formation apparatus includes the closed vessel with hydrogen gas outlet, and closed vessel inner chamber bottom is contained
There is the second production hydrogen feedstock in flow-like, and the packaging that is contained in and can crush is distributed with the described second ullage for producing hydrogen feedstock
The first production hydrogen feedstock in structure, connects when by the hydrogen input port of the hydrogen gas outlet of the hydrogen generating apparatus and the hydrogen container
After connecing, contacted by the crushing mechanism and crush the packaging structure, the first production hydrogen feedstock is fallen into the second production hydrogen feedstock simultaneously
Hybrid reaction.
7. continuous hydrogen-feeding system according to claim 1, it is characterised in that：The hydrogen formation apparatus includes having hydrogen
The closed vessel of delivery outlet, closed vessel inner chamber top is provided with cryptomere packaging structure, the cryptomere packaging structure and is loaded with
First production hydrogen feedstock, the second production hydrogen feedstock is distributed with closed vessel inner chamber bottom, when by the hydrogen of the hydrogen generating apparatus
After delivery outlet is connected with the hydrogen input port of the hydrogen container, the hydrogen prestored in the hydrogen container enters the cryptomere packaging structure
Until burst the cryptomere packaging structure, the first production hydrogen feedstock is set to fall into the second production hydrogen feedstock and hybrid reaction, described the
At least one of one production hydrogen feedstock and the second production hydrogen feedstock are flow-like.
8. continuous hydrogen-feeding system according to claim 1, it is characterised in that：The hydrogen formation apparatus includes having hydrogen
The closed vessel of delivery outlet, closed vessel inner chamber bottom is loaded with produces hydrogen feedstock, the first production hydrogen in the second of flow-like
Raw material is supported by setting at the ullage that the second production hydrogen feedstock was lifted or hung in mechanism, the hydrogen input port of the hydrogen container
There is the executing agency for destroying the supporting device, when by the hydrogen gas outlet of the hydrogen generating apparatus and the hydrogen container
After the connection of hydrogen input port, the executing agency contacts and destroys the supporting device, the first production hydrogen feedstock is fallen into the second production hydrogen
The interior simultaneously hybrid reaction of raw material.
9. continuous hydrogen-feeding system according to claim 8, it is characterised in that also include：Drive mechanism, it is described for driving
Executing agency contacts and destroys the supporting device.
10. the continuous hydrogen-feeding system according to claim 7 or 9, it is characterised in that including：
Air pressure monitor device, at least hydrogen gas pressure to monitor the hydrogen generating apparatus output；
Control unit, at least to the signal for receiving the transmission of air pressure monitor device, and the hydrogen exported in any hydrogen generating apparatus
When air pressure is less than setting value, the hydrogen circulation pipeline between any hydrogen generating apparatus and the hydrogen container is cut off, and make another
Hydrogen generating apparatus is connected with the hydrogen container, and the executing agency is worked, and then is started in another hydrogen generating apparatus
Hydrogen gas production reaction.
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| CN201610098451.2A CN107098310A (en) | 2016-02-23 | 2016-02-23 | A kind of continuous hydrogen-feeding system |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610098451.2A CN107098310A (en) | 2016-02-23 | 2016-02-23 | A kind of continuous hydrogen-feeding system |
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| CN107098310A true CN107098310A (en) | 2017-08-29 |
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| CN201610098451.2A Pending CN107098310A (en) | 2016-02-23 | 2016-02-23 | A kind of continuous hydrogen-feeding system |
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| CN112209337A (en) * | 2020-09-28 | 2021-01-12 | 清华大学 | Hydrogen production and storage system and method |
| CN113646256A (en) * | 2018-04-17 | 2021-11-12 | 以列特环球能源解决方案有限公司 | Batch system and method for extracting hydrogen gas from liquid hydrogen carrier |
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Application publication date: 20170829 |