CN107094781A - A kind of composition pesticide and its application containing pyraclonil and dichloro quinolinic acid - Google Patents
A kind of composition pesticide and its application containing pyraclonil and dichloro quinolinic acid Download PDFInfo
- Publication number
- CN107094781A CN107094781A CN201710376205.3A CN201710376205A CN107094781A CN 107094781 A CN107094781 A CN 107094781A CN 201710376205 A CN201710376205 A CN 201710376205A CN 107094781 A CN107094781 A CN 107094781A
- Authority
- CN
- China
- Prior art keywords
- pyraclonil
- quinolinic acid
- dichloro quinolinic
- composition pesticide
- weed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- IHHMUBRVTJMLQO-UHFFFAOYSA-N Pyraclonil Chemical compound C#CCN(C)C1=C(C#N)C=NN1C1=NN(CCCC2)C2=C1Cl IHHMUBRVTJMLQO-UHFFFAOYSA-N 0.000 title claims abstract description 69
- LPXYXBZAXFTFKH-UHFFFAOYSA-N ClC=1C(=C(C(=NC1)C(=O)O)C(=O)O)Cl Chemical compound ClC=1C(=C(C(=NC1)C(=O)O)C(=O)O)Cl LPXYXBZAXFTFKH-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 239000000203 mixture Substances 0.000 title claims abstract description 46
- 239000000575 pesticide Substances 0.000 title claims abstract description 30
- 241000196324 Embryophyta Species 0.000 claims abstract description 46
- 239000003905 agrochemical Substances 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims description 23
- 238000002360 preparation method Methods 0.000 claims description 17
- -1 spreader-sticker Substances 0.000 claims description 15
- 230000000361 pesticidal effect Effects 0.000 claims description 11
- 239000000375 suspending agent Substances 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000009472 formulation Methods 0.000 claims description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 235000012424 soybean oil Nutrition 0.000 claims description 5
- 239000003549 soybean oil Substances 0.000 claims description 5
- 239000004563 wettable powder Substances 0.000 claims description 5
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 claims description 4
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 4
- 229920001732 Lignosulfonate Polymers 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 235000019198 oils Nutrition 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000004562 water dispersible granule Substances 0.000 claims description 4
- 239000000080 wetting agent Substances 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 3
- 239000013530 defoamer Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims description 2
- 239000001293 FEMA 3089 Substances 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 240000006240 Linum usitatissimum Species 0.000 claims description 2
- 235000004431 Linum usitatissimum Nutrition 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 230000000740 bleeding effect Effects 0.000 claims description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000007938 effervescent tablet Substances 0.000 claims description 2
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 235000004426 flaxseed Nutrition 0.000 claims description 2
- 229940073769 methyl oleate Drugs 0.000 claims description 2
- 239000004530 micro-emulsion Substances 0.000 claims description 2
- 239000003094 microcapsule Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 229940117013 triethanolamine oleate Drugs 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000008158 vegetable oil Substances 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 241001272567 Hominoidea Species 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 240000008042 Zea mays Species 0.000 claims 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 235000005822 corn Nutrition 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 230000006641 stabilisation Effects 0.000 claims 1
- 238000011105 stabilization Methods 0.000 claims 1
- 239000003814 drug Substances 0.000 abstract description 18
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 16
- 235000009566 rice Nutrition 0.000 abstract description 16
- 230000002363 herbicidal effect Effects 0.000 abstract description 10
- 229940079593 drug Drugs 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 9
- 238000005507 spraying Methods 0.000 abstract description 7
- 230000002195 synergetic effect Effects 0.000 abstract description 7
- 230000002401 inhibitory effect Effects 0.000 abstract description 4
- 230000002045 lasting effect Effects 0.000 abstract description 4
- 230000002411 adverse Effects 0.000 abstract description 2
- 230000033228 biological regulation Effects 0.000 abstract description 2
- 230000007547 defect Effects 0.000 abstract description 2
- 230000000857 drug effect Effects 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- 241001290610 Abildgaardia Species 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 241000209094 Oryza Species 0.000 description 15
- 241000192043 Echinochloa Species 0.000 description 14
- 240000000178 Monochoria vaginalis Species 0.000 description 13
- 239000004009 herbicide Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 238000011049 filling Methods 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 244000025254 Cannabis sativa Species 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000009395 breeding Methods 0.000 description 3
- 230000001488 breeding effect Effects 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 229920002577 polybenzoxazole Polymers 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- KWVNKWCJDAWNAE-UHFFFAOYSA-N 2,3-dichloroquinoline Chemical compound C1=CC=C2N=C(Cl)C(Cl)=CC2=C1 KWVNKWCJDAWNAE-UHFFFAOYSA-N 0.000 description 2
- 206010061217 Infestation Diseases 0.000 description 2
- 208000005374 Poisoning Diseases 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 150000003851 azoles Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 description 2
- 229920005551 calcium lignosulfonate Polymers 0.000 description 2
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 208000024891 symptom Diseases 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ASZRIBNKXOGEDF-UHFFFAOYSA-N 4-chloropyridine-2,3-dicarboxylic acid Chemical compound OC(=O)C1=NC=CC(Cl)=C1C(O)=O ASZRIBNKXOGEDF-UHFFFAOYSA-N 0.000 description 1
- XVVZSEXTAACTPS-UHFFFAOYSA-N 5-[hydroxy-(4-nitrophenoxy)phosphoryl]pentanoic acid Chemical compound OC(=O)CCCCP(O)(=O)OC1=CC=C([N+]([O-])=O)C=C1 XVVZSEXTAACTPS-UHFFFAOYSA-N 0.000 description 1
- 229930192334 Auxin Natural products 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 241000380130 Ehrharta erecta Species 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 229940087098 Oxidase inhibitor Drugs 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 239000002363 auxin Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229940099112 cornstarch Drugs 0.000 description 1
- 238000012272 crop production Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- LOAUVZALPPNFOQ-UHFFFAOYSA-N quinaldic acid Chemical compound C1=CC=CC2=NC(C(=O)O)=CC=C21 LOAUVZALPPNFOQ-UHFFFAOYSA-N 0.000 description 1
- FFSSWMQPCJRCRV-UHFFFAOYSA-N quinclorac Chemical compound ClC1=CN=C2C(C(=O)O)=C(Cl)C=CC2=C1 FFSSWMQPCJRCRV-UHFFFAOYSA-N 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- LENLQGBLVGGAMF-UHFFFAOYSA-N tributyl([1,2,4]triazolo[1,5-a]pyridin-6-yl)stannane Chemical compound C1=C([Sn](CCCC)(CCCC)CCCC)C=CC2=NC=NN21 LENLQGBLVGGAMF-UHFFFAOYSA-N 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
Abstract
The invention discloses a kind of composition pesticide containing pyraclonil and dichloro quinolinic acid and its application, the active component of the composition pesticide is pyraclonil and dichloro quinolinic acid, and the mass ratio of pyraclonil and dichloro quinolinic acid is 5 25: 5 80.The composition pesticide, shows obvious synergistic effect in the range of said ratio, reduces the dosage of agricultural chemicals, reduces times for spraying, reduces drug cost, reduces adverse effect of the agricultural chemicals to ecological environment；Herbicidal spectrum is expanded, a drug had both solved various weed problems, compensate for defect and limitation when single dose is used；Extend the service life of medicament, to the comprehensive regulation important in inhibiting of Weed Resistance；Drug effect plays rapid, and the lasting period is long, and use cost is low, available for preventing and treating rice terrace grassy weed, broad leaved weed and sedge weed.
Description
Technical field
The invention belongs to technical field of pesticide, and in particular to it is a kind of be used for prevent and kill off paddy field weed contain pyraclonil and two
The composition pesticide of chloro-quinolinic acid.
Background technology
World crop production is annual because of disease, worm, crop smothering loss 14% according to statistics, and the loss that wherein crop smothering is caused is about
11%, Weed infestation is the key factor for restricting crop yield.The use of chemical herbicide is the important mark of agricultural modernization
One of will.In recent years, the sales volume of herbicide increases year by year, accounts for the proportion of agricultural chemicals sales volume and increases year by year, administration area expands year by year
Greatly.Paddy rice is that Consumption of China amount is maximum, cultivated area is maximum, total output is maximum, per unit area yield highest crops, is had in the world
Consequence.But the serious of rice field crop smothering is to restrict its high yield, the major obstacle of stable yields.At present, weeds in paddy field is anti-
Carried out except many using the pattern of " envelope, two kill, three benefits ", there are different herbicide kinds to be available for making currently for different phase
With, but most kind it is difficult to ensure that a drug and keep in paddy rice whole breeding time without grass, the increase of times for spraying undoubtedly pole
The earth adds cost accounting, has also aggravated the influence to environmental ecology.Therefore, the first use of exploratory development rice terrace and keep
Safe efficient herbicide without grass in paddy rice whole breeding time is particularly important.
Pyraclonil, chemical name：1- (3- chloro- 4,5,6,7- tetrahydro-pyrazoles simultaneously [1,5-a] pyridine -2- bases) -5- [methyl
(Propargyl) amino] pyrazoles -4- nitriles.Belong to proporphyrinogen oxidase inhibitor, can be absorbed by weeds root and leaf, in plant
Conduction in vivo, is in wilting symptoms after weeds poisoning.Pyraclonil can effectively prevent and kill off a variety of annual and perennial grass of rice terrace
Section weeds and broad leaved weed.
Dichloro quinolinic acid, chemical name：3,7- bis- chloro- 8-Quinoline Carboxylic Acids, belong to hormone-type quinoline carboxylic acid herbicide, weeds
Poisoning symptom is similar to auxins effect, to above the average age for marriage barnyard grass special efficacy.
The content of the invention
Goal of the invention：For the problem that developed immunity to drugs in the prior art to farmland weed, single use prevention effect it is poor,
The problem of first use is difficult to effectively control Weed infestation in paddy rice whole breeding time, it is an object of the invention to provide one kind containing double
The composition pesticide of azoles oxalic acid dinitrile and dichloro quinolinic acid, make it have efficiently, it is wide spectrum, environmentally friendly, it is comprehensive beneficial to paddy field weed
Close the features such as administering.It is a further object of the present invention to provide a kind of above-mentioned composition pesticide containing pyraclonil and dichloro quinolinic acid
Application.
Technical scheme：In order to realize foregoing invention purpose, the technical solution adopted by the present invention is：
A kind of composition pesticide containing pyraclonil and dichloro quinolinic acid, active ingredient is pyraclonil and dichloroquinoline
The mass ratio of acid, pyraclonil and dichloro quinolinic acid is 5-25: 5-80.
The preferred mass ratio of pyraclonil and dichloro quinolinic acid is 1: 3,1: 5,9: 8,3: 5 and 3: 1.
A kind of pesticidal preparations containing pyraclonil and dichloro quinolinic acid, the preparation is by containing pyraclonil and dichloro quinolinic acid
Composition pesticide and the acceptable auxiliaries of field of pesticide preparation into any one acceptable formulation on agricultural chemicals.
The formulation of the pesticidal preparations be wettable powder, water dispersible granules, suspending agent, microemulsion, finish, missible oil,
Granula, effervescent tablet, microcapsule formulations, aqueous emulsion or oil-suspending agent.
Two kinds of herbicidal active components account for the 1-90% of pesticidal preparations gross weight in the pesticidal preparations.
The auxiliary material be selected from wetting agent, dispersant, spreader-sticker, stabilizer, bleeding agent, thickener, antifreezing agent, defoamer,
Filler, solvent；Wherein, the wetting agent be neopelex, calcium dodecyl benzene sulfonate, lauryl sodium sulfate,
Lignosulfonates, alkyl phenol formaldehyde resin polyoxyethylene ether, aliphatic alcohol sulfate, phenethyl phenol polyethenoxy ether, nonyl phenol
One or more among APEO；The dispersant is lignosulfonates, alkylbenzenesulfonate, alkyl phenol polyoxy second
Alkene ether, NPE, alkyl ethyl sulfonate, alkylnaphthalene sulfonate formaldehyde condensation products and one kind of polycarboxylic acid salt
Or it is several；Described stabilizer is the one or more in epoxidized vegetable oil such as epoxidised soybean oil, epoxidized linseed；Institute
It is the one or more in polyvinyl alcohol, alkyl diphenyl ether disulphonic acid sodium, poly- trisiloxanes, triethanolamine oleate to state spreader-sticker；
The solvent is the one or more in soybean oil, methyl oleate, white oil, turpentine oil methyl naphthalene higher aliphatic hydrocarbon ils；It is described to fill out
Expect for the one or more in white carbon, cornstarch, kaolin, diatomite, sodium sulphate, ammonium sulfate.
The described composition pesticide containing pyraclonil and dichloro quinolinic acid is in preventing and treating broad leaved weed, grassy weed
Using.When preventing and treating paddy field weed, before weeds emerge or after seedling is used.
The described pesticidal preparations containing pyraclonil and dichloro quinolinic acid answering in preventing and treating broad leaved weed, grassy weed
With.When preventing and treating broad leaved weed, grassy weed, before weeds emerge or after seedling is used.
The production technology of the various application forms of the composition pesticide containing pyraclonil and dichloro quinolinic acid belongs to existing
There is known technology.
The composition pesticide and its pesticidal preparations containing pyraclonil and dichloro quinolinic acid that the present invention is provided, generally using poison
The method of soil, poison fertilizer or spraying is used, and can also use technology using other agriculturally applied as needed.
Beneficial effect：Compared with prior art, the composition pesticide of the invention containing pyraclonil and dichloro quinolinic acid, tool
Have the following advantages：
1) composition pesticide containing pyraclonil and dichloro quinolinic acid of the invention, shows bright in certain ratio range
Aobvious synergistic effect, the prevention effect of composition is significantly improved than single dose, reduces the dosage of agricultural chemicals, reduces use
Medicine number of times, reduces drug cost, reduces adverse effect of the agricultural chemicals to ecological environment.
2) composition pesticide containing pyraclonil and dichloro quinolinic acid of the invention, the combination of two kinds of active ingredient is improved
Preventive effect, reduces consumption, a drug had both solved various weed problems, compensate for defect and limitation when single dose is used.
3) composition pesticide containing pyraclonil and dichloro quinolinic acid of the invention, both are mixed, and can effectively to prevent and kill off broad-leaved miscellaneous
Grass and grassy weed, resist the weeds such as ALS barnyard grass, Monochoria vaginalis effectively, can extend the service life of medicament, anti-to weeds
The comprehensive regulation important in inhibiting of property.
4) composition pesticide containing pyraclonil and dichloro quinolinic acid of the invention, drug effect plays rapid, and the lasting period is long, makes
Low with cost, easy to use, time saving and energy saving, its popularization and application has huge economic benefit and social benefit.
Specific embodiment
With reference to specific embodiment, the present invention is further illustrated.As described below is only that the present invention is preferably implemented
Example, is used only for the description present invention, it is impossible to be interpreted as limiting the scope of the present invention.It should be pointed out that all in the present invention
Spirit and principle within any modifications, equivalent substitutions and improvements for being done etc., should be included in protection scope of the present invention it
It is interior.
In following examples, unless otherwise indicated, all percentages are weight percentage.
Embodiment 1：20% pyraclonil dichloro quinolinic acid oil-suspending agent
The each group of composition pesticide containing pyraclonil and dichloro quinolinic acid is divided into：Pyraclonil 5%, dichloro quinolinic acid
15%, phenethyl phenol APEO 5%, sodium lignin sulfonate 8%, epoxidized soybean oil 5%, organobentonite 5%, oleic acid
Methyl esters is to 100%.
After pyraclonil is mixed with filling adsorption, then other above-mentioned materials (except organobentonite) are added to together
In reactor mixer, stir, material is injected and ground in multistage sand mill, the fineness of materials 98% after grinding passes through 1-
Discharged after 5um, material is put into high-shear emulsifying kettle together with the prior organobentonite dissolved, can be made into after emulsification
20% pyraclonil dichloro quinolinic acid oil-suspending agent.
Embodiment 2：36% pyraclonil Dichloroquinolinic acid suspending agent
The each group of composition pesticide containing pyraclonil and dichloro quinolinic acid is divided into：Pyraclonil 6%, dichloro quinolinic acid
30%, phenethyl phenol APEO 5%, sodium lignin sulfonate 8%, ethylene glycol 5%, aluminium-magnesium silicate 2%, defoamer
0.5%, preservative 0.1%, xanthans 0.1%, water to 100%.
After pyraclonil is mixed with filling adsorption, then other above-mentioned materials (except xanthans) are added to reaction together
In kettle mixer, stir, material is injected and ground in multistage sand mill, the fineness of materials 98% after grinding passes through 1-5um
After discharge, material is put into high-shear emulsifying kettle together with the xanthans that dissolve in advance, is that can be made into 36% pair after emulsification
Azoles oxalic acid dinitrile Dichloroquinolinic acid suspending agent.
Embodiment 3：34% pyraclonil dichloro quinolinic acid wettable powder
The each group of composition pesticide containing pyraclonil and dichloro quinolinic acid is divided into：Pyraclonil 18%, dichloro quinolinic acid
16%, lauryl sodium sulfate 2%, sodium butylnaphthalenesulfonate 3%, calcium lignosulfonate 5%, white carbon 5%, kaolin is extremely
100%.
After pyraclonil filling adsorption is mixed, add in cone-type mixer and be well mixed together with other above-mentioned materials,
Crushed by airslide disintegrating mill, the material after crushing is mixed through cone-type mixer again, mixed fineness of materials 98% passes through 325
Mesh standard sieve is that 33% pyraclonil dichloro quinolinic acid wettable powder is made.
Embodiment 4：60% pyraclonil dichloro quinolinic acid water dispersible granules
The each group of composition pesticide containing pyraclonil and dichloro quinolinic acid is divided into：Pyraclonil 22.5%, dichloroquinoline
Acid 37.5%, lauryl sodium sulfate 4%, metal carboxylate 5%, urea 10%, plus kaolin is to 100%.
After pyraclonil is mixed with filling adsorption, added together with other above-mentioned materials in cone-type mixer and mix equal
It is even, crushed by airslide disintegrating mill, the material after crushing is mixed through cone-type mixer again, mixed fineness of materials 98% passes through
325 mesh standard sieves, add in kneader and are kneaded into plasticity material, and this material finally is put into extruding in Squeezinggranulator makes
Grain, 60% pyraclonil dichloro quinolinic acid water dispersible granules are made after granulation through drying, screening.
Embodiment 5：72% pyraclonil dichloro quinolinic acid oil-suspending agent
The each group of composition pesticide containing pyraclonil and dichloro quinolinic acid is divided into：Pyraclonil 54%, dichloro quinolinic acid
18%, lauryl sodium sulfate 2%, sodium butylnaphthalenesulfonate 3%, calcium lignosulfonate 5%, white carbon 5%, kaolin is extremely
100%.
After pyraclonil is mixed with filling adsorption, then other above-mentioned materials (except organobentonite) are added to together
In reactor mixer, stir, material is injected and ground in multistage sand mill, the fineness of materials 98% after grinding passes through 1-
Discharged after 5um, material is put into high-shear emulsifying kettle together with the prior organobentonite dissolved, can be made into after emulsification
75% pyraclonil dichloro quinolinic acid oil-suspending agent.
Embodiment 6：Pyraclonil and the screening of dichloro quinolinic acid optimum proportioning
In order to further appreciate that the synergy of pyraclonil and dichloro quinolinic acid mixture to weeds, the present inventor is to polybenzobisoxazole
Oxalic acid dinitrile and dichloro quinolinic acid mixture have carried out formulation screening test.
Test material：Barnyard grass (Echinochloa crusglli Beauv.), Monochoria vaginalis (Monochoria
Vaginalis (Burm.F.) Presl ex Kunth), in September, 2016 is picked up from Xinghua County's rice terrace, adopts rear room temperature
Under the conditions of natural air drying, load paper bag, be placed in the preservation of 4 DEG C of ± 0.5 refrigerators.
Test apparatus：PWT-510 type spray towers, plum Teller AB135-S electronic balances, volumetric flask, triangular flask, beaker, amount
Cylinder, polypots, pipette, chi, scissors etc..
Test method：The pyraclonil and dichloro quinolinic acid active compound of certain mass are first weighed, after addition methanol fully dissolves
Diluted with the 0.1% Tween 80 aqueous solution, be configured to single dose mother liquor, series proportioning is set according to mixture purpose, each proportioning is set
Put 5-7 concentration gradient stand-by.Polypots (15cm × 11cm × 7cm) is filled into air-dried fine earth, with polypots bottom infiltrating irrigation side
Formula, makes soil moisten completely.Soil is horse liver soil, and pH6.7, the content of organic matter 1.6% is air-dried standby after sieving.Each plastics
Alms bowl broadcasts barnyard grass 25, Monochoria vaginalis 25 and broadcasts rear fine earth covering, thickness about 0.2cm respectively.Cultivated in heliogreenhouse to weeds 1-3 leaves
Phase, cauline leaf spraying treatment is watered 30kg/667m2.(precision spraying area is 0.2m to the spraying of PWT-510 type spray towers quantification2, spray
Decoction 10ml, spray value is 500L/hm2, atomisation pressure is 0.5kpa).After after decoction natural air drying on plastic bowl after spray, put
Cultivated in heliogreenhouse, keep the skin wet holding ground moistening daily.
The growing state of routine observation barnyard grass and Monochoria vaginalis seedling after medicine.30 days investigation barnyard grasses and Monochoria vaginalis overground part after medicine
Fresh weight, it is the preventive effect to target weeds to calculate fresh weight inhibition.Single dose polybenzobisoxazole grass is obtained using DPS data handling systems
The virulence regression equation of nitrile, dichloro quinolinic acid and 5 two-spot mixed agents, calculates ED50Value and 95% confidence limit.With the abundant method meters of Sun Yun
Calculate co-toxicity coefficient.Co-toxicity coefficient is expressed as synergistic effect more than 120, is expressed as representing between antagonism, 80~120 less than 80
For summation action.
Result of the test：Medicine is post-processed 20 days and observed, and pyraclonil and dichloro quinolinic acid are applied in 5-25: 5-80 ratio mixture
Barnyard grass and Monochoria vaginalis partial blade turn to be yellow to withered afterwards, to barnyard grass and the inhibitory action of Monochoria vaginalis with the increase of drug concentration on
Rise, there is very high bioactivity to barnyard grass and Monochoria vaginalis.
30 days after medicine, the 9 two-spot mixture combinations of pyraclonil and dichloro quinolinic acid have obvious suppression to the fresh weight of barnyard grass
Make and use (table 1).The co-toxicity coefficient point of 5: 5,5: 80,25: 5,25: 80,1: 3,1: 5,9: 8,3: 5 and 3: 1 proportionings in 9 proportionings
Wei not 125.5301,128.0029,134.1603,125.5109,124.2357,122.0845,127.1786,123.0561 and
129.6170, co-toxicity coefficient is more than 120, shows as synergistic effect (table 1).
1 pyraclonil of table-synergy of the dichloro quinolinic acid mixture to barnyard grass fresh weight
The 5 two-spot mixture combinations of pyraclonil and dichloro quinolinic acid also there is obvious suppression to make the fresh weight of Monochoria vaginalis
With the co-toxicity coefficient of 5: 5,5: 80,25: 5,25: 80,1: 3,1: 5,9: 8,3: 5 and 3: 1 proportionings is respectively in 9 proportionings
150.7705th, 164.4107,144.1739,157.2495,154.9100,159.2580,143.4279,147.9128 and
142.1881, co-toxicity coefficient is more than 120, shows as synergistic effect (table 2).
2 pyraclonils of table-synergy of the dichloro quinolinic acid mixture to Monochoria vaginalis fresh weight
Pyraclonil has good inhibiting effect, Quinclorac on Rice Plants to rice terrace broadleaved herb and grassy weed
Field grassy weed has preferably control effect, and both mixtures can prevent and kill off annual a variety of weeds of rice terrace simultaneously.Polybenzobisoxazole
Oxalic acid dinitrile and dichloro quinolinic acid show as synergistic effect in 5-25: 5-80 ratio mixture.
The field control effectiveness test of embodiment 7
Reagent agent：Select mixed herbicide prepared in embodiment 1~4.
Comparison medicament：3.6% pyraclonil suspending agent (purchased in market)
50% dichloro quinolinic acid wettable powder (purchased in market)
If artificial weeding and clear water control
Application method：Using spray-on process.
Spraying time：Rice terrace on November 3rd, 2015 (south stalk 9108), in the leaf phase dispenser of weeds 1~3.
Respondent and method：20d investigates the fresh weight of weeds and the fresh weight and plant height of paddy rice after barnyard grass, Monochoria vaginalis, medicine.
Test results and analysis are shown in Table 3 and table 4 respectively.
The field control effectiveness test result of table 3 (20d after medicine)
From table 3 it is observed that the present invention has obvious effect to rice terrace barnyard grass, Monochoria vaginalis, preventive effect is anti-higher than single dose
Effect, and with preferable quick-acting and lasting effect；We have observed that the present invention is higher to rice seedlings security from table 4.
20 days Plant Height of Rice and fresh weight after the medicine of table 4.
Embodiment 8
With reference to the method for embodiment 7, field control effectiveness test is carried out to mixed herbicide made from embodiment 4-5, it was demonstrated that：Respectively
Mixed herbicide has obvious synergistic effect, all has significant preventive effect to paddy field weed, effect, which is significantly better than single dose, to be made
With, and the lasting period is long.
Claims (10)
1. a kind of composition pesticide containing pyraclonil and dichloro quinolinic acid, it is characterised in that：Active component be pyraclonil and
The mass ratio of dichloro quinolinic acid, pyraclonil and dichloro quinolinic acid is 5-25: 5-80.
2. a kind of pesticidal preparations containing pyraclonil and dichloro quinolinic acid, it is characterised in that：The preparation is as described in claim 1
Composition pesticide containing pyraclonil and dichloro quinolinic acid and the acceptable auxiliaries of field of pesticide preparation into can on agricultural chemicals
Any one formulation received.
3. the pesticidal preparations according to claim 2 containing pyraclonil and dichloro quinolinic acid, it is characterised in that：The agricultural chemicals
The formulation of preparation is wettable powder, water dispersible granules, suspending agent, microemulsion, finish, missible oil, granule, effervescent tablet, micro-
Capsule, aqueous emulsion or oil-suspending agent.
4. the pesticidal preparations according to claim 2 containing pyraclonil and dichloro quinolinic acid, it is characterised in that：The preparation
Middle active ingredient accounts for the 1-90% of weight of formulation.
5. the pesticidal preparations according to claim 2 containing pyraclonil and dichloro quinolinic acid, it is characterised in that：The auxiliary material
Selected from wetting agent, dispersant, spreader-sticker, stabilizer, bleeding agent, thickener, antifreezing agent, defoamer, filler, solvent；Wherein, institute
Wetting agent is stated for neopelex, calcium dodecyl benzene sulfonate, lauryl sodium sulfate, lignosulfonates, alkyl
One among fluosite APEO, aliphatic alcohol sulfate, phenethyl phenol polyethenoxy ether, NPE
Plant or several；The dispersant is lignosulfonates, alkylbenzenesulfonate, APES, polyoxyethylene nonyl phenyl second
Alkene ether, alkyl ethyl sulfonate, alkylnaphthalene sulfonate formaldehyde condensation products and the one or more of polycarboxylic acid salt；Described stabilization
Agent is the one or more in epoxidized vegetable oil such as epoxidised soybean oil, epoxidized linseed；The spreader-sticker is polyethylene
One or more in alcohol, alkyl diphenyl ether disulphonic acid sodium, poly- trisiloxanes, triethanolamine oleate；The solvent be soybean oil,
One or more in methyl oleate, white oil, turpentine oil methyl naphthalene higher aliphatic hydrocarbon ils；The filler is white carbon, corn shallow lake
One or more in powder, kaolin, diatomite, sodium sulphate, ammonium sulfate.
6. the answering in preventing and treating paddy field weed of the composition pesticide containing pyraclonil and dichloro quinolinic acid described in claim 1
With.
7. application according to claim 6, it is characterised in that：When preventing and treating paddy field weed, before weeds emerge or seedling
After use.
8. the pesticidal preparations containing pyraclonil and dichloro quinolinic acid described in claim any one of 2-5 are in preventing and treating paddy field weed
In application.
9. application according to claim 8, it is characterised in that：When preventing and treating paddy field weed, before weeds emerge or seedling
After use.
10. the composition pesticide according to claim 1 containing pyraclonil and dichloro quinolinic acid, it is characterised in that：It is described
The mass ratio of pyraclonil and dichloro quinolinic acid is 1: 3,1: 5,9: 8,3: 5 and 3: 1.
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1201370A (en) * | 1995-11-15 | 1998-12-09 | 赫彻斯特-舍林农业发展有限公司 | Synergetic herbicidal mixture |
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2017
- 2017-05-22 CN CN201710376205.3A patent/CN107094781A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1201370A (en) * | 1995-11-15 | 1998-12-09 | 赫彻斯特-舍林农业发展有限公司 | Synergetic herbicidal mixture |
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