CN107091763A - The continuous abjection collection device of dissolved gas - Google Patents

The continuous abjection collection device of dissolved gas Download PDF

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Publication number
CN107091763A
CN107091763A CN201710531383.9A CN201710531383A CN107091763A CN 107091763 A CN107091763 A CN 107091763A CN 201710531383 A CN201710531383 A CN 201710531383A CN 107091763 A CN107091763 A CN 107091763A
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CN
China
Prior art keywords
gas
sample chamber
cylinder
abjection
piston portion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710531383.9A
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Chinese (zh)
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CN107091763B (en
Inventor
程思海
李燕
王金莲
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GUANGDONG PROVINCIAL ACADEMY OF ENVIRONMENTAL SCIENCE
Guangzhou Marine Geological Survey
Original Assignee
GUANGDONG PROVINCIAL ACADEMY OF ENVIRONMENTAL SCIENCE
Guangzhou Marine Geological Survey
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Application filed by GUANGDONG PROVINCIAL ACADEMY OF ENVIRONMENTAL SCIENCE, Guangzhou Marine Geological Survey filed Critical GUANGDONG PROVINCIAL ACADEMY OF ENVIRONMENTAL SCIENCE
Priority to CN201710531383.9A priority Critical patent/CN107091763B/en
Publication of CN107091763A publication Critical patent/CN107091763A/en
Application granted granted Critical
Publication of CN107091763B publication Critical patent/CN107091763B/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/2294Sampling soil gases or the like

Abstract

Continuous abjection and collection device the invention discloses a kind of dissolved gas, including:Hollow cylinder;It is arranged at the sample chamber in cylinder;The piston portion that can be moved back and forth in cylinder along the axis of cylinder is arranged at, piston portion external diameter is adapted with cylinder internal diameter;The gas production bag outside cylinder is arranged at, gas production bag is connected with flowline;It is arranged at gas abjection check valve and gas collection check valve on the wall of sample chamber side;Gas abjection check valve is used for when piston portion toward during the direction motion away from the sample chamber, gas in sample chamber is delivered in the space between piston portion and sample chamber, gas collection check valve is used to, when piston portion is toward close to the motion of the direction of the sample chamber, the gas in the space between piston portion and sample chamber is delivered in gas production bag by flowline;It is arranged at the supersonic generator in sample chamber.The present invention can realize the automatic continuous abjection and collection that dissolved gas in shape deposit or seabed muddy water is flowed to submarine surface half.

Description

The continuous abjection collection device of dissolved gas
Technical field
It is used for submarine surface half the present invention relates to the abjection of gas and collecting device manufacturing technology field, more particularly to one kind Flow the automatic continuous abjection of dissolved gas and collection device in shape deposit or seabed muddy water.
Background technology
As China's economic strength is continued to develop with scientific and technical, actively development Deep Sea Minerals (such as hydration Thing, oil and natural gas etc.) investigation and marine environment investigation etc..Semi-fluid is often presented in the sediment sample on marine bottom top layer Dynamic shape.When seabed has the mineral reserve such as natural gas, hydrate and oil, or water body environment is when being contaminated, the hydration in seabed The gases such as methane, hydrogen sulfide are had in thing, oil and gas deposit and eutrophic deposit to ooze out, the gas oozed out is in high pressure low temperature thing Under the conditions of reason, it can be dissolved in deposit or seabed muddy water that submarine surface half flows shape.The species of these dissolved gas, Component, content can detect offer for ocean gas hydrate investigation, the investigation of ocean lake environment and Marine oil and gas resource Fast and efficiently GEOCHEMICAL EVIDENCE, tool is of great significance.So, dissolved gas in deposit on marine-bottom surface Abjection and collection are the bases of follow-up oceanographic survey research, study extremely important for oceanographic survey.But because submarine surface is heavy Product composition granule is thinner, relatively more sticky, and adsorptivity is stronger, and it is difficult abjection to be dissolved in dissolved gas therein, there is no at present The means of effect can realize the automatic of from the sticky, deposit on marine-bottom surface of half flowing shape or seabed muddy water dissolved gas Continuous abjection and collection.
The content of the invention
In order to overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of automaticity it is high be used for will be molten The solution device that dissolved gas is continuously deviate from and collected in deposit on marine-bottom surface or seabed muddy water.
The purpose of the present invention is realized using following technical scheme:
The continuous abjection of dissolved gas and collection device, including:Hollow cylinder;It is arranged at the sample in the cylinder Cabin, the sample chamber is closed cavity;Be arranged at the piston portion in the cylinder, the piston portion can along the cylinder axis Move back and forth, the internal diameter of the external diameter of the piston portion and the cylinder is adapted;The gas production bag outside the cylinder is arranged at, it is described Gas production bag is connected with a flowline;The gas abjection check valve and gas collection being arranged on the wall of the sample chamber side are unidirectional Valve;The gas deviates from check valve, during for being moved when piston portion toward the direction away from the sample chamber, by the gas in sample chamber Body is delivered in the space between piston portion and sample chamber, the gas collection check valve, for when piston portion is toward close to described During the direction motion of sample chamber, the gas in the space between piston portion and sample chamber is delivered to by flowline and adopted In airbag;
It is arranged at the supersonic generator in the sample chamber.
Optionally, the piston portion uses motor or cylinder or Driven by Hydraulic Cylinder.
Optionally, the supersonic generator is arranged at the bottom of the sample chamber.
Optionally, it is provided with gas flowmeter on the flowline.
Optionally, the sample chamber is located at the bottom of the cylinder, and the piston portion is arranged at the top of the sample chamber.
Optionally, the gas abjection check valve and gas collection check valve are arranged on the roof of the sample chamber.
Optionally, the sample chamber is the closing sky being separated out by the demarcation strip being arranged in the cylinder in cylinder Between.
Optionally, the cylinder at least one end is blind end.
Compared with prior art, the beneficial effects of the present invention are:The present invention is placed using the sample chamber of closing and is dissolved with gas The deposit of body, negative pressure of vacuum environment is formed using the reciprocating motion of piston portion, is made the deposit in sample chamber in vacuum and is surpassed Under conditions of sound wave shock, dissolved gas is spun off from the deposit of half flow regime, is collected into gas production bag, it is real The abjection and collection of solution gas in existing deposit on marine-bottom surface sample, and can be further by setting gas flowmeter to determine receipts The volume of the gas of collection, so as to calculate the volume of dissolved gas in the sediment sample of unit volume.The present invention has knot The characteristics of structure is simple, easy to operate, automaticity is high.
Brief description of the drawings
Fig. 1 is the structural representation of the embodiment of the present invention.
Embodiment
Below, with reference to embodiment, the present invention is described further.
As shown in figure 1, the continuous abjection of the dissolved gas of the present embodiment and collection device include hollow cylinder 1, sample Cabin 2, piston portion 3, gas abjection check valve 4, gas collection check valve 5, gas production bag 6, gas flowmeter 7 and supersonic generator 8.At least one end of cylinder 1 is closing.
Sample chamber 2 is arranged in cylinder 1, and sample chamber 2 is closed vacuum cavity.Piston portion 3 is arranged in cylinder 1, sample The top in product cabin 2, the external diameter of piston portion 3 and the internal diameter of cylinder 1 are adapted.The external diameter of piston portion of the present invention and cylinder Internal diameter refers respectively to the external dimensions of piston portion and the inside dimension of cylinder, and when cylinder 1 is cylinder, piston portion 3 also mutually should be Circle, the external diameter of piston portion just refers to the external diameter of circle, and the internal diameter of cylinder just refers to the internal diameter of cylinder, when cylinder be square tube or During other polygons cylinder, piston portion also mutually should be square or other polygons, and the external diameter of piston portion just refers to square or other are more The external dimensions of side shape, the internal diameter of cylinder just refers to the shape of square tube or other polygons logical inside dimension, i.e. piston portion 3 It is identical with the shapes and sizes inside cylinder 1 with size.Piston portion 3 can be moved back and forth up and down along the axis direction of cylinder 1, piston Portion 3 can use motor or cylinder or Driven by Hydraulic Cylinder.
Gas deviates from check valve 4 and gas collection check valve 5 is arranged on the roof of sample chamber 2, wherein, gas abjection is single It is arranged to valve 4 in connection sample chamber 2 and cylinder 1 between the roof of sample chamber 2 and piston portion 3 in the passage in space, gas collection Check valve 5 is arranged in connection cylinder 1 between the roof of sample chamber 2 and piston portion 3 in the passage of space and flowline 9, gas production Another termination gas production bag 6 of pipeline 9.Gas flowmeter 7 is arranged on flowline 9, can be adopted to flowing through the entrance of flowline 9 The flow of the gas of airbag 6 is counted.The roof of sample chamber 2 is actual to be arranged at the demarcation strip in cylinder 1, and demarcation strip is in cylinder A closing space is separated out in body 1 as sample chamber, its complementary space in sample chamber and cylinder is isolated.
Supersonic generator 8 is provided with sample chamber 2, the supersonic generator 8 of the present embodiment is arranged at sample chamber 2 Bottom, that is, the bottom of cylinder 1.Gas abjection check valve 4 is used to control gas interior to sample chamber 2 and living from sample chamber 2 Space outflow between piston part 3, gas collection check valve 5 is used to control the sky that gas can only be between sample chamber 2 and piston portion 3 Between into flowline 9 flow out.
The operation principle to the gas abjection collection device of the present invention is illustrated below:
Half flowing shape deposit is full of sample chamber 2, piston portion 3 is moved to the roof of sample chamber 2, the bottom of piston portion 3 Face is closely set in the gas abjection check valve 4 and gas collection check valve 5 of the roof of sample chamber 2, while gas production bag 6 is taken out into true It is empty;
During work, start supersonic generator 8 first, then drive piston portion 3 to move upwards, in piston portion 3 from sample During the roof of cabin 2 is moved up, one can be formed in the space below the inner carrier portion 3 of cylinder 1 between the roof of sample chamber 2 The environment of individual negative pressure, now opens gas abjection check valve 4, gas collection check valve 5 is closed, in negative pressure and ultrasound In the presence of ripple, the dissolved gas in half flowing shape deposit in sample chamber 2 will be deviate from, and check valve 4 is deviate from through gas In the space for diffusing to the lower section of piston portion 3;
When piston portion 3 is moved to top, during piston portion 3 is moved down, gas abjection check valve 4 is closed, is beaten Gas collection check valve 5 is opened, piston portion 3 can be by the gas of the abjection out of sample chamber 2 through gas collection check valve 5 and flowline 9 are expressed in gas production bag 6, and the gas flowmeter 7 being arranged on flowline 9 can be recorded to the gas volume of abjection;
When piston portion 3 is moved down on earth, piston portion 3, which is started again at, to move up, and repeats abovementioned steps, starts next Individual degassing and the process collected;When the reading of gas flowmeter 7 is not further added by, you can think in sample chamber 2 in deposit Dissolved gas is all deviate from.
Previous embodiment is vertically set with cylinder, and piston region is in the top of sample chamber, above sample bin Move back and forth up and down, but cylinder can also be horizontally disposed, and when cylinder horizontal positioned, piston portion can be located at sample chamber Left side or right side, and left and right is moved back and forth in the horizontal direction.
Apparatus of the present invention can realize the company of dissolved gas in deposit in sample chamber using the reciprocating motion of piston portion Continuous abjection and collection work, automaticity are high, provide basis for the constituent analysis research of subsequent dissolution gas, can be applied to ocean Sample collection in the fields such as scientific investigation, ocean water body environmental survey, marine oil and gas investigation and exploitation, before wide application Scape.
For those skilled in the art, technical scheme that can be as described above and design, make other each It is kind corresponding to change and deform, and all these change and deformation should all belong to the protection model of the claims in the present invention Within enclosing.

Claims (8)

1. the continuous abjection of dissolved gas and collection device, it is characterised in that including:
Hollow cylinder;
The sample chamber in the cylinder is arranged at, the sample chamber is closed cavity;
The piston portion in the cylinder is arranged at, the piston portion can be moved back and forth along the axis of the cylinder, the piston portion The internal diameter of external diameter and the cylinder be adapted;
The gas production bag outside the cylinder is arranged at, the gas production bag is connected with a flowline;
It is arranged at gas abjection check valve and gas collection check valve on the wall of the sample chamber side;The gas abjection is unidirectional Valve, for, toward during the direction motion away from the sample chamber, the gas in sample chamber being delivered into piston portion and sample when piston portion In space between product cabin, the gas collection check valve, during for being moved when piston portion toward the direction close to the sample chamber, Gas in space between piston portion and sample chamber is delivered in gas production bag by flowline;
It is arranged at the supersonic generator in the sample chamber.
2. the continuous abjection of dissolved gas according to claim 1 and collection device, it is characterised in that:The piston portion Using motor or cylinder or Driven by Hydraulic Cylinder.
3. the continuous abjection of dissolved gas according to claim 1 or 2 and collection device, it is characterised in that:It is described super Sonic generator is arranged at the bottom of the sample chamber.
4. the continuous abjection of dissolved gas according to claim 1 or 2 and collection device, it is characterised in that:It is described to adopt Gas flowmeter is provided with feed channel.
5. the continuous abjection of dissolved gas according to claim 1 and collection device, it is characterised in that:The sample chamber Positioned at the bottom of the cylinder, the piston portion is arranged at the top of the sample chamber.
6. the continuous abjection of dissolved gas according to claim 5 and collection device, it is characterised in that:The gas takes off Go out check valve and gas collection check valve is arranged on the roof of the sample chamber.
7. continuous abjection and the collection device of the dissolved gas according to claim 1 or 5 or 6, it is characterised in that:It is described Sample chamber is the closing space being separated out by the demarcation strip being arranged in the cylinder in cylinder.
8. the continuous abjection of dissolved gas according to claim 1 and collection device, it is characterised in that:The cylinder is extremely Rare one end is blind end.
CN201710531383.9A 2017-07-03 2017-07-03 The continuous abjection collection device of dissolved gas Active CN107091763B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710531383.9A CN107091763B (en) 2017-07-03 2017-07-03 The continuous abjection collection device of dissolved gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710531383.9A CN107091763B (en) 2017-07-03 2017-07-03 The continuous abjection collection device of dissolved gas

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CN107091763A true CN107091763A (en) 2017-08-25
CN107091763B CN107091763B (en) 2018-06-15

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108318655A (en) * 2018-01-25 2018-07-24 广州海洋地质调查局 Liquid nitrogen frozen hydrate sample decomposes gas quantitative sample injection system
CN108318100A (en) * 2018-01-25 2018-07-24 广州海洋地质调查局 Measure the system and method that liquid nitrogen frozen hydrate sample decomposes release gas volume

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004300721A (en) * 2003-03-31 2004-10-28 Nishimatsu Constr Co Ltd Dissolved gas detection method, dissolve gas detection device, slurry shield driving method using dissolved gas detection device, and slurry shield machine
US20080216591A1 (en) * 2006-02-17 2008-09-11 Ryan M Cathryn Method and system for sampling dissolved gas
CN102478470A (en) * 2010-11-26 2012-05-30 中国石油化工股份有限公司 Piston type vacuum degasser and its degassing method
CN102749228A (en) * 2012-06-18 2012-10-24 河海大学 Shallow lake greenhouse gas in-situ collection device
CN103157301A (en) * 2011-12-19 2013-06-19 恩德莱斯和豪瑟尔测量及调节技术分析仪表两合公司 Method and apparatus for degassing a liquid and analytical device having the apparatus

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004300721A (en) * 2003-03-31 2004-10-28 Nishimatsu Constr Co Ltd Dissolved gas detection method, dissolve gas detection device, slurry shield driving method using dissolved gas detection device, and slurry shield machine
US20080216591A1 (en) * 2006-02-17 2008-09-11 Ryan M Cathryn Method and system for sampling dissolved gas
CN102478470A (en) * 2010-11-26 2012-05-30 中国石油化工股份有限公司 Piston type vacuum degasser and its degassing method
CN103157301A (en) * 2011-12-19 2013-06-19 恩德莱斯和豪瑟尔测量及调节技术分析仪表两合公司 Method and apparatus for degassing a liquid and analytical device having the apparatus
CN102749228A (en) * 2012-06-18 2012-10-24 河海大学 Shallow lake greenhouse gas in-situ collection device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108318655A (en) * 2018-01-25 2018-07-24 广州海洋地质调查局 Liquid nitrogen frozen hydrate sample decomposes gas quantitative sample injection system
CN108318100A (en) * 2018-01-25 2018-07-24 广州海洋地质调查局 Measure the system and method that liquid nitrogen frozen hydrate sample decomposes release gas volume
CN108318655B (en) * 2018-01-25 2023-09-26 广州海洋地质调查局 Liquid nitrogen frozen hydrate sample decomposition gas quantitative sampling system
CN108318100B (en) * 2018-01-25 2023-10-10 广州海洋地质调查局 System and method for measuring volume of gas released by decomposing liquid nitrogen frozen hydrate sample

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