CN107090323A - 一种具有控制氧化功能的复合氧载体及其制备方法 - Google Patents
一种具有控制氧化功能的复合氧载体及其制备方法 Download PDFInfo
- Publication number
- CN107090323A CN107090323A CN201710125062.9A CN201710125062A CN107090323A CN 107090323 A CN107090323 A CN 107090323A CN 201710125062 A CN201710125062 A CN 201710125062A CN 107090323 A CN107090323 A CN 107090323A
- Authority
- CN
- China
- Prior art keywords
- oxygen carrier
- composite oxygen
- preparation
- cao
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000001301 oxygen Substances 0.000 title claims abstract description 86
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 85
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 239000002131 composite material Substances 0.000 title claims abstract description 64
- 230000001590 oxidative effect Effects 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 5
- 229910002651 NO3 Inorganic materials 0.000 claims description 26
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 26
- 239000000243 solution Substances 0.000 claims description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- 238000001354 calcination Methods 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 9
- 239000012266 salt solution Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000005416 organic matter Substances 0.000 claims description 3
- -1 oxygen ion Chemical class 0.000 claims description 3
- 238000009938 salting Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 abstract description 14
- 238000007254 oxidation reaction Methods 0.000 abstract description 14
- 239000004449 solid propellant Substances 0.000 abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 11
- 238000006243 chemical reaction Methods 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 239000000446 fuel Substances 0.000 description 13
- 238000002309 gasification Methods 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 239000011575 calcium Substances 0.000 description 11
- 229910002804 graphite Inorganic materials 0.000 description 8
- 239000010439 graphite Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000003643 water by type Substances 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 239000000567 combustion gas Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- MWEXRLZUDANQDZ-RPENNLSWSA-N (2s)-3-hydroxy-n-[11-[4-[4-[4-[11-[[2-[4-[(2r)-2-hydroxypropyl]triazol-1-yl]acetyl]amino]undecanoyl]piperazin-1-yl]-6-[2-[2-(2-prop-2-ynoxyethoxy)ethoxy]ethylamino]-1,3,5-triazin-2-yl]piperazin-1-yl]-11-oxoundecyl]-2-[4-(3-methylsulfanylpropyl)triazol-1-y Chemical compound N1=NC(CCCSC)=CN1[C@@H](CO)C(=O)NCCCCCCCCCCC(=O)N1CCN(C=2N=C(N=C(NCCOCCOCCOCC#C)N=2)N2CCN(CC2)C(=O)CCCCCCCCCCNC(=O)CN2N=NC(C[C@@H](C)O)=C2)CC1 MWEXRLZUDANQDZ-RPENNLSWSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 238000001107 thermogravimetry coupled to mass spectrometry Methods 0.000 description 4
- 239000002028 Biomass Substances 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 238000003760 magnetic stirring Methods 0.000 description 2
- 150000004682 monohydrates Chemical class 0.000 description 2
- 235000007686 potassium Nutrition 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 229910004333 CaFe2O4 Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- WNQQFQRHFNVNSP-UHFFFAOYSA-N [Ca].[Fe] Chemical compound [Ca].[Fe] WNQQFQRHFNVNSP-UHFFFAOYSA-N 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
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CN201710125062.9A CN107090323B (zh) | 2017-03-03 | 2017-03-03 | 一种具有控制氧化功能的复合氧载体及其制备方法 |
Applications Claiming Priority (1)
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CN201710125062.9A CN107090323B (zh) | 2017-03-03 | 2017-03-03 | 一种具有控制氧化功能的复合氧载体及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN107090323A true CN107090323A (zh) | 2017-08-25 |
CN107090323B CN107090323B (zh) | 2019-09-17 |
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CN201710125062.9A Active CN107090323B (zh) | 2017-03-03 | 2017-03-03 | 一种具有控制氧化功能的复合氧载体及其制备方法 |
Country Status (1)
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CN (1) | CN107090323B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110655966A (zh) * | 2018-06-29 | 2020-01-07 | 深圳市广昌达石油添加剂有限公司 | 一种油溶性负载金属氧化物清灰助燃剂及其制备方法 |
CN112811476A (zh) * | 2020-12-31 | 2021-05-18 | 华中科技大学 | 一种镍掺杂钙铁石型氧载体及其制备方法和应用 |
CN113072981A (zh) * | 2021-03-15 | 2021-07-06 | 中南大学 | 一种功能性复合载氧体化学链脱氧气化协同co2转化方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101486941A (zh) * | 2009-02-17 | 2009-07-22 | 华中科技大学 | 一种铁基氧载体的制备方法 |
CN104119984A (zh) * | 2014-08-07 | 2014-10-29 | 南京理工大学 | 一种含钙铜基复合载氧体及其制备方法 |
CN104119983A (zh) * | 2014-08-07 | 2014-10-29 | 南京理工大学 | 一种含铁铜基复合载氧体及其制备方法 |
CN105462649A (zh) * | 2014-09-05 | 2016-04-06 | 南京理工大学 | 一种含钙钴基复合载氧体及其制备方法 |
-
2017
- 2017-03-03 CN CN201710125062.9A patent/CN107090323B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101486941A (zh) * | 2009-02-17 | 2009-07-22 | 华中科技大学 | 一种铁基氧载体的制备方法 |
CN104119984A (zh) * | 2014-08-07 | 2014-10-29 | 南京理工大学 | 一种含钙铜基复合载氧体及其制备方法 |
CN104119983A (zh) * | 2014-08-07 | 2014-10-29 | 南京理工大学 | 一种含铁铜基复合载氧体及其制备方法 |
CN105462649A (zh) * | 2014-09-05 | 2016-04-06 | 南京理工大学 | 一种含钙钴基复合载氧体及其制备方法 |
Non-Patent Citations (1)
Title |
---|
王杰,等: "化学链燃烧技术中载氧体的研究进展", 《现代化工》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110655966A (zh) * | 2018-06-29 | 2020-01-07 | 深圳市广昌达石油添加剂有限公司 | 一种油溶性负载金属氧化物清灰助燃剂及其制备方法 |
CN112811476A (zh) * | 2020-12-31 | 2021-05-18 | 华中科技大学 | 一种镍掺杂钙铁石型氧载体及其制备方法和应用 |
CN113072981A (zh) * | 2021-03-15 | 2021-07-06 | 中南大学 | 一种功能性复合载氧体化学链脱氧气化协同co2转化方法 |
CN113072981B (zh) * | 2021-03-15 | 2022-05-24 | 中南大学 | 一种功能性复合载氧体化学链脱氧气化协同co2转化方法 |
Also Published As
Publication number | Publication date |
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CN107090323B (zh) | 2019-09-17 |
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Effective date of registration: 20240423 Address after: 266101 Shandong Province, Qingdao city Laoshan District Songling Road No. 189 Patentee after: QINGDAO INSTITUTE OF BIOENERGY AND BIOPROCESS TECHNOLOGY, CHINESE ACADEMY OF SCIENCES Country or region after: China Patentee after: Qingdao Green Hydrogen Chain Technology Co.,Ltd. Address before: 266101 Shandong Province, Qingdao city Laoshan District Songling Road No. 189 Patentee before: QINGDAO INSTITUTE OF BIOENERGY AND BIOPROCESS TECHNOLOGY, CHINESE ACADEMY OF SCIENCES Country or region before: China |
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