CN107082919A - Heat-pesistant thin film - Google Patents

Heat-pesistant thin film Download PDF

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Publication number
CN107082919A
CN107082919A CN201710278848.4A CN201710278848A CN107082919A CN 107082919 A CN107082919 A CN 107082919A CN 201710278848 A CN201710278848 A CN 201710278848A CN 107082919 A CN107082919 A CN 107082919A
Authority
CN
China
Prior art keywords
parts
nanoscale
bast fiber
nano
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710278848.4A
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Chinese (zh)
Inventor
谢绪金
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qian Yang Mechanical & Electronic Equipment Corp Ltd Of Liuzhou City
Original Assignee
Qian Yang Mechanical & Electronic Equipment Corp Ltd Of Liuzhou City
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qian Yang Mechanical & Electronic Equipment Corp Ltd Of Liuzhou City filed Critical Qian Yang Mechanical & Electronic Equipment Corp Ltd Of Liuzhou City
Priority to CN201710278848.4A priority Critical patent/CN107082919A/en
Publication of CN107082919A publication Critical patent/CN107082919A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2309/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2409/02—Copolymers with acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/329—Phosphorus containing acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

Abstract

The present invention discloses a kind of heat-pesistant thin film, is related to plastic membrane product technical field.It is made up of the raw material of following parts by weight：1 part~5 parts of 15 parts~20 parts of nitrile rubber, 20 parts~25 parts of butadiene-styrene rubber, 0.1 part~0.5 part of nano mica powder, 0.2 part~0.4 part of nanoscale Korean pine bast fiber, 0.5 part~1 part of nanoscale Schima superba bast fiber, 0.2 part~0.4 part of nano-grade glass fibre, 0.4 part~0.8 part of boric acid, 2 parts~5 parts of phosphoric acid, 1 part~5 parts of phenol, 5 parts~10 parts of vulcanizing agent, 0.5 part~1 part of accelerator and age resistor.It is of the invention main by adding nano mica powder, nanoscale Korean pine bast fiber, nanoscale Schima superba bast fiber, nano-grade glass fibre, boric acid, phosphoric acid and phenol, so as to effectively improve the heat resistance of film.

Description

Heat-pesistant thin film
Technical field
The present invention relates to plastic membrane product technical field, especially a kind of heat-pesistant thin film.
Background technology
Film is a kind of thin and flexible transparent sheet, is widely used in electronic apparatus, machinery, the industry such as printing.With science and technology Continuous progress, people are to the attention rate of film also more and more higher, and the film of exploitation difference in functionality property is film future studies One of direction.
The content of the invention
It is an object of the invention to provide a kind of film with heat resistance.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
It is made up of the raw material of following parts by weight：
15 parts~20 parts of nitrile rubber, 20 parts~25 parts of butadiene-styrene rubber, 0.1 part~0.5 part of nano mica powder, nanoscale Korean pine 0.2 part~0.4 part of bast fiber, 0.5 part~1 part of nanoscale Schima superba bast fiber, 0.2 part~0.4 part of nano-grade glass fibre, 0.4 part~0.8 part of boric acid, 2 parts~5 parts of phosphoric acid, 1 part~5 parts of phenol, 5 parts~10 parts of vulcanizing agent, 0.5 part~1 part of accelerator with And 1 part~5 parts of age resistor.
Due to using above-mentioned technical proposal, the beneficial effect that the present invention is obtained is：
It is of the invention main by adding nano mica powder, nanoscale Korean pine bast fiber, nanoscale Schima superba bast fiber, nanometer Level fiberglass, boric acid, phosphoric acid and phenol, so as to effectively improve the heat resistance of film；Wherein, boric acid, phosphoric acid and The addition of glycerine, can effectively buffer impulsive force of the high temperature to product, so as to improve the heat resistance of product.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, and protection scope of the present invention is not only limited to In following examples.
Embodiment 1 --- heat-pesistant thin film
It is made up of the raw material of following weight：
Nitrile rubber 15kg, butadiene-styrene rubber 20kg, nano mica powder 0.1kg, nanoscale Korean pine bast fiber 0.2kg, nanometer Level Schima superba bast fiber 0.5kg, nano-grade glass fibre 0.2kg, boric acid 0.4kg, phosphoric acid 2kg, phenol 1kg, vulcanizing agent 5kg, Accelerator 0.5kg and age resistor 1kg；
Above-mentioned raw materials are prepared according to the preparation method of traditional films.
By performance measurement, the product heat resistance of the present embodiment is good, and its temperature in use may be up to 250 DEG C.
Embodiment 2 --- heat-pesistant thin film
It is made up of the raw material of following weight：
Nitrile rubber 20kg, butadiene-styrene rubber 25kg, nano mica powder 0.5kg, nanoscale Korean pine bast fiber 0.4kg, nanometer Level Schima superba bast fiber 1kg, nano-grade glass fibre 0.4kg, boric acid 0.8kg, phosphoric acid 5kg, phenol 5kg, vulcanizing agent 10kg, rush Enter agent 1kg and age resistor 5kg；
Above-mentioned raw materials are prepared according to the preparation method of traditional films.
By performance measurement, the product heat resistance of the present embodiment is good, and its temperature in use may be up to 250 DEG C.
Embodiment 3 --- heat-pesistant thin film
It is made up of the raw material of following weight：
Nitrile rubber 16kg, butadiene-styrene rubber 22kg, nano mica powder 0.4kg, nanoscale Korean pine bast fiber 0.3kg, nanometer Level Schima superba bast fiber 0.9kg, nano-grade glass fibre 0.3kg, boric acid 0.7kg, phosphatase 24 kg, phenol 3kg, vulcanizing agent 7kg, Accelerator 0.9kg and age resistor 4kg；
Above-mentioned raw materials are prepared according to the preparation method of traditional films.
By performance measurement, the product heat resistance of the present embodiment is good, and its temperature in use may be up to 250 DEG C.

Claims (1)

1. a kind of heat-pesistant thin film, it is characterised in that be made up of the raw material of following parts by weight：
15 parts~20 parts of nitrile rubber, 20 parts~25 parts of butadiene-styrene rubber, 0.1 part~0.5 part of nano mica powder, nanoscale Korean pine 0.2 part~0.4 part of bast fiber, 0.5 part~1 part of nanoscale Schima superba bast fiber, 0.2 part~0.4 part of nano-grade glass fibre, 0.4 part~0.8 part of boric acid, 2 parts~5 parts of phosphoric acid, 1 part~5 parts of phenol, 5 parts~10 parts of vulcanizing agent, 0.5 part~1 part of accelerator with And 1 part~5 parts of age resistor.
CN201710278848.4A 2017-04-25 2017-04-25 Heat-pesistant thin film Pending CN107082919A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710278848.4A CN107082919A (en) 2017-04-25 2017-04-25 Heat-pesistant thin film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710278848.4A CN107082919A (en) 2017-04-25 2017-04-25 Heat-pesistant thin film

Publications (1)

Publication Number Publication Date
CN107082919A true CN107082919A (en) 2017-08-22

Family

ID=59612423

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710278848.4A Pending CN107082919A (en) 2017-04-25 2017-04-25 Heat-pesistant thin film

Country Status (1)

Country Link
CN (1) CN107082919A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1433902A (en) * 2003-01-30 2003-08-06 江西省励远化工科技实业公司 Sealing reinforced board for car and making method thereof
CN103443169A (en) * 2011-04-01 2013-12-11 第一毛织株式会社 Composite sheet, and substrate for a display element using same
US20140004364A1 (en) * 2011-10-17 2014-01-02 Tokai Rubber Industries, Ltd. Dielectric film and transducer including the same
CN104059201A (en) * 2014-06-25 2014-09-24 青岛祥海电子有限公司 Environmental protection biomass rubber
CN104693545A (en) * 2015-03-04 2015-06-10 南京理工大学 Bacterial-cellulose-containing water-response sensing rubber film and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1433902A (en) * 2003-01-30 2003-08-06 江西省励远化工科技实业公司 Sealing reinforced board for car and making method thereof
CN103443169A (en) * 2011-04-01 2013-12-11 第一毛织株式会社 Composite sheet, and substrate for a display element using same
US20140004364A1 (en) * 2011-10-17 2014-01-02 Tokai Rubber Industries, Ltd. Dielectric film and transducer including the same
CN104059201A (en) * 2014-06-25 2014-09-24 青岛祥海电子有限公司 Environmental protection biomass rubber
CN104693545A (en) * 2015-03-04 2015-06-10 南京理工大学 Bacterial-cellulose-containing water-response sensing rubber film and preparation method thereof

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
代少俊: "《高性能纤维复合材料》", 28 February 2013, 华东理工大学出版社 *
化学工业部橡胶司/科技局: "《化学工业标准汇编 第3册上 橡胶原材料》", 31 October 1986, 中国标准出版社 *
夏金童 等，: "《日常建材化工日用品生产手册》", 31 July 1994, 江西科学技术出版社 *
郭红霞: "《电线电缆材料——结构 性能 应用》", 31 July 2012, 机械工业出版社 *

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Application publication date: 20170822

RJ01 Rejection of invention patent application after publication