CN107075422A - Laundry composition composition - Google Patents
Laundry composition composition Download PDFInfo
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- CN107075422A CN107075422A CN201580058563.9A CN201580058563A CN107075422A CN 107075422 A CN107075422 A CN 107075422A CN 201580058563 A CN201580058563 A CN 201580058563A CN 107075422 A CN107075422 A CN 107075422A
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- polysaccharide
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- Emergency Medicine (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of polysaccharide for having and being grafted to anionic functional silicone thereon, the wherein silicone has the anionic group of at least one residual；Be related to the surfactant for including 1 40 weight %, its include anion surfactant and optional nonionic surfactant, and 0.05 10 weight % polysaccharide laundry treatment compositions；And it is related to the purposes with the polysaccharide softening fabrics for being grafted with anionic functional silicone, wherein silicone has the anionic group of at least one residual.
Description
Technical field
The laundry composition for including anion silicone of the stability improved the present invention relates to display.
Background technology
Silicone is attractive composition for laundry composition, because they provide the benefit of softening washing fabric
Place.Single anion functional silicone is grafted on polysaccharide skeleton by WO 2003/020770 is known.
The content of the invention
Prior art still has the problem of grafting silicone may cause unstable laundry composition, ought particularly use
During anion silicone because they easily occur it is muddy and fuzzy.This is that consumer is unacceptable.
The purpose of the present invention is the stability for the preparation for improving the polysaccharide comprising grafting silicone.Specific object is to provide one
Plant less muddy or fuzzy preparation.
We have now discovered that, if not by the anion silicone of simple function, but by polyfunctional anion silicon
Ketone is grafted on polysaccharide, then resulting laundry detergent composition has improved stability, and less fuzzy
Or it is muddy.
Therefore, the present invention is provided with the polysaccharide for being grafted to anionic functional silicone thereon in the first aspect, its
In the silicone have at least one residual anionic group.
Preferably, polysaccharide is selected from：Polydextrose, poly- mannose, glucomannans, galactomannans and xyloglucan are more
Sugar.It is highly preferred that polysaccharide is galactomannans and/or xyloglucan.
Preferably, polysaccharide is nonionic polysaccharide or cationic polysaccharide.
Preferably, anion silicone includes carboxylate radical, sulfate radical, sulfonate radical, phosphate radical and/or phosphonate functional group.More
Preferably, anion silicone is carboxy-functionalized silicone.
Preferably, there is at least 0.1mol%, preferably 0.5mol% once anion silicone after grafting, more preferably
1mol%, most preferably 2mol% anionic group content.
Preferably, polysaccharide is with the galactomannans and/or xyloglucan for being grafted to silicone thereon, wherein silicone
There is at least one carboxyl, preferably 2 carboxyls after grafting.
The second aspect of the invention is laundry treatment compositions, and it is included：
A) 1-40 weight % surfactant, it includes anion and optional nonionic surfactant；With,
B) 0.05-10 weight %'s has the polysaccharide for being grafted to anionic functional silicone thereon, and the wherein silicone has
The anionic group of at least one residual.
Preferably, based on laundry treatment compositions washed detergent form.
Preferably, laundry treatment compositions include 2.5-25 weight %, and more preferably 4-20 weight % anionic surface is lived
Property agent.
Preferably, laundry treatment compositions include 0.5-25 weight %, more preferably 2.5-15 weight % non-ionic surface
Activating agent, and optional aliphatic acid or its soap.
Preferably, laundry treatment preparation contains 0.05-2.5 weight % cationic polymer, more preferably cationic polysaccharide,
Most preferably cationic cellulose polymer.
Preferably, laundry treatment compositions are included：
A) 6.5-38 weight % surfactant, the anion comprising 4-20 weight % and 2.5-15 weight % it is non-from
Sub- surfactant；
B) 0.05-10 weight %'s has the galactomannans and/or xyloglucan for being grafted to silicone thereon, wherein
The silicone has at least one carboxyl, preferably 2 carboxyls after grafting；
C) 0.5-2.5 weight % Cationic polysaccharide polymer；With
D) optionally 1-12 weight % aliphatic acid.
The third aspect of the invention is the use with the polysaccharide softening fabrics for being grafted to anionic functional silicone thereon
On the way, wherein the silicone has the anionic group of at least one residual.
Embodiment
It is grafted the polysaccharide of anionic functional silicone
Polysaccharide be by identical or different sugared ring group into long-chain polymer type material.Polysaccharide can be straight or branched.
The example of straight-chain polysaccharide is polydextrose and poly- galactomannan polysaccharide.The example of branched polysaccharides is glucomannans, half
Newborn mannosan and xyloglucan polysaccharide.
Preferably, polysaccharide is selected from：Polydextrose, poly- mannose, glucomannans, galactomannans and xyloglucan are more
Sugar.More preferably polysaccharide is galactomannans and/or xyloglucan.
Anion silicone
Polysaccharide has the anionic functional silicone being grafted to thereon.Anionic functional silicone refers to once being grafted on polysaccharide
Silicone just has the anionic group of at least one residual.Preferably, once being grafted on polysaccharide, silicone just has at least two
Anionic group, more preferably at least 3 anionic groups.Preferably, once being grafted on polysaccharide, silicone just has 1 to 10,
More preferably 2 to 10, most preferably 3 to 10 anionic groups.
The available method in this area such as NMR or IR spectral detections anionic group can be used.
Anion silicone is grafted into polysaccharide to usually require to be reacted by anionic group.Therefore, as the single official of use
During energy anion silicone, anionic group, which is exhausted, to be enabled to be grafted on polysaccharide.This means be once grafted to polysaccharide
Upper silicone will not have any anionic group of residual.
Application claims retain at least one anionicsite on grafting silicone.This is provided with improved stability
And less fuzzy or muddy laundry detergent composition.
Preferably, there is at least 0.1mol%, preferably 0.5mol% once anion silicone after grafting, more preferably
1mol%, most preferably 2mol% anionic group content.
The example of anion silicone includes carboxylate radical, sulfate radical, sulfonate radical, phosphate radical and/or phosphonate functional group
Silicone.
It is preferred that anion silicone be carboxy-functionalized silicone.
Preferably, the charged species at least one residual being retained on anion silicone are provided by carboxyl silicone.
Preferably, polysaccharide is with the galactomannans and/or xyloglucan for being grafted to silicone thereon, the wherein silicon
Ketone has at least one carboxyl, preferably 2 carboxyls after grafting.
For the purpose of present invention disclosed herein, anion silicone can be the form of acid or anion.For example for
Carboxy-functionalized silicone, it can exist with carboxylic acid or carboxylate anion.
Preferably, the molecular weight of anion silicone is 1,000 to 100,000, more preferably 2,000 to 50,000, even more
It is preferred that 5,000 to 50,000, most preferably 10,000 to 50,000.
Laundry treatment compositions
The invention further relates to a kind of laundry treatment compositions, it is included：
A) 1-40 weight % surfactant, it includes anion and optional nonionic surfactant；With
B) 0.05-10 weight %'s has the polysaccharide for being grafted to anionic functional silicone thereon, and the wherein silicone has
The anionic group of at least one residual.
The form of washed detergent based on laundry treatment compositions are preferred.
Master washes Betengent product form
Laundry treatment compositions can use many forms any one, example include powder, particle, rod, gel and
Liquid.Preferably, composition is the form of liquid laundry product.Preferably, they are main cleaning products.It can be used for
The form of the main laundry composition washed, it can be dilutable or not dilutable.Laundry composition can be it is for example each to
Same sex liquid or surfactant-structured liquid.Form specifically preferred according to the invention includes composition, detergent/softening agent product
To provide " softening in washing ".
Preferably, the pH of detergent composition is 6 to 10, more preferably pH 6.5 to 9.5, most preferably pH 7 to 9, example
Such as pH 7.5 to 8.5.
Surfactant
Laundry treatment compositions generally comprise surfactant, particularly when it uses the main form for washing detergent composition
When.
Laundry treatment compositions include 1-40 weight % surfactant, and it includes anion and optional nonionic table
Face activating agent.
Preferably, laundry treatment compositions include 2.5-25 weight % anion surfactant.
Preferably, in addition to above-mentioned anion surfactant, laundry treatment compositions include 0.5-25 weight %'s
Nonionic surfactant, and optional aliphatic acid or its soap.It is highly preferred that main detergent composition of washing includes 4-20 weights
Measure % anion surfactant；2.5-15 weight % nonionic surfactant, and optional aliphatic acid or its soap.
Surfactant can selected from be described in Schwartz＆Perry " Surface Active Agents " volume 1,
Schwartz, Perry＆Berch volumes 2 of Interscience 1949, Interscience 1958 (by
" the McCutcheon's Emulsifiers and that Manufacturing Confectioners Company are published
Detergents " current edition) or H.Stache " Tenside-Taschenbuch " second editions, Carl Hauser Verlag,
Surfactant in 1981.It is preferred that surfactant used is saturation.
The suitable nonionic detergent compounds that can use particularly including with hydrophobic grouping and hydrogen atoms
Compound such as aliphatic alcohol, acid, acid amides or alkyl phenol and epoxyalkane reaction product, epoxyalkane is particularly single ring
Oxidative ethane or itself and expoxy propane.Specific nonionic detergent compounds are C6-C22Alkylphenol-ethylene oxide condensate, leads to
Often it is 5 to 25 EO, i.e. 5 to 25 ethylene oxide units of per molecule；And aliphatic series C8-C18Primary or secondary linear or branched alcohols and ring
The condensation product of oxidative ethane, usually 5 to 40 EO.
If it does, nonionic surfactant preferably comprises alcohol ethoxylate.
Alcohol ethoxylate is formed by the reaction of primary or secondary alcohols and oxirane.Generally, aliphatic C8-C18Primary or secondary straight chain or
Mole quantitative response generation alcohol ethoxylate of the branched-chain alcoho with oxirane to need.It is preferred that alcohol ethoxylate have 2 to
40, preferably 3 to 30, more preferably 5 to 20 be connected to aliphatic chain ethylene oxide unit.
The suitable anionic detergent compounds that can be used can have the alkyl containing about 8 to about 22 carbon atoms
Organic sulfuric acid and sulfonic acid water-soluble alkali metal salts, term alkyl be used for include the moieties of higher acyl.It is suitable to close
Example into anionic detergent compounds is sodium alkyl sulfate and alkylsurfuric acid potassium, especially by sulphating higher C8-C18
Alcohol (for example being produced by butter or coconut oil) obtain those；Alkyl C9-C20Benzene sulfonic acid sodium salt and alkyl C9-C20Benzene sulfonic acid potassium, it is special
It is not linear secondary alkyl C10-C15Benzene sulfonic acid sodium salt；And alkyl glyceryl ether sulphates, particularly derived from butter or coconut oil
Those ethers of higher alcohol and synthol derived from oil.It is preferred that anionic detergent compounds be C11-C15Alkyl benzene sulphonate
Sodium and C12-C18Sodium alkyl sulfate.The sulfonate included as water-assisted solvent (hydrotrobes) can be additionally considered to be such as this
Anion surfactant defined in literary.Also can be using the surface-active described in such as EP-A-328 177 (Unilever)
Agent, it shows resistance to saltouing property；Alkyl polyglucoside surfactant described in EP-A-070 074；With alkyl monoglycosides class.
Surfactant system includes anion surfactant and nonionic surfactant.
Nonionic detergent is preferably with 0.5-25 weight %, preferably 1-20 weight %, more preferably 2.5-15 weight % amount
In the presence of.
It is preferred that nonionic surfactant be with C moles ethoxylated average 7-912-C15Alkyl chain.
Anion surfactant is preferably with 4-40 weight %, preferably 5-35 weight %, more preferably 6-20 weight % amount
In the presence of.
It is preferred that anion surfactant be：Linear alkylbenzene sulfonate (LAS), with 1-3 moles of (average) ethoxylation
Lauryl ether sodium sulfonate, primary alkyl sulfonate, methyl ether sulfate and secondary alkyl sulfonate or its mixture.
In order to solve the level of surfactant present in release formulation, aliphatic acid and its salt are not included in surfactant
In level.
In addition to above-mentioned nonionic surfactant and anion surfactant, there can also be other surfaces activity
Agent, such as amphoteric surfactant, zwitterionic surfactant and cationic surfactant.
Other compositions
Laundry treatment compositions also optionally include one or more following optional members：Cationic polymer, silicone,
It is aliphatic acid or its salt, masking dyestuff, enzyme, antiredeposition polymer, the polymer for suppressing dyestuff transfer, builder, chelating agent, anti-
Shine agent, fluorescer, spices, and/or soil release polymer.
Cationic polymer
Clothing processing preparation can contain 0.05-2.5 weight %, more preferably preferably 0.1-2 weight %, 0.1-1 weight %,
The most preferably cationic polymer of 0.1-0.75 weight % level.
Cationic polymer can many different molecular weight synthesis and commercially available.Preferably, cationic polymerization
The molecular weight of thing is 10,000 to 2,000,000 dalton, and more preferably 100,000 to 1,000,000 dalton is even more excellent
Elect 250,000 to 1,000,000 dalton as.
Preferably, it is Cationic polysaccharide polymer, more preferably cationic cellulose polymer, most preferably hydroxy ethyl fiber
Element.One example is the LR400 from Amerchol ex Dow.
Silicone
Clothing processing preparation can the silicone containing 0.05-5 weight % level.Example include PDMS, ethoxylation or
Propoxylation polysiloxanes, amodimethicone and anion silicone, such as comprising carboxylate radical, sulfate radical, sulfonate radical, phosphate radical and/
Or the silicone of phosphonate functional group.
Aliphatic acid
Composition can also include aliphatic acid or soap such as soap.Example includes C6-C22Aliphatic acid and its sodium salt, potassium
Salt and ammonium salt.For the purpose of the level that solves surfactant present in release formulation, aliphatic acid and its salt are not included in surface
In the level of activating agent.
If it is present the level of aliphatic acid is 0.25-12 weight %, preferably 0.5-10 weight %.
Builder and chelating agent
Detergent formulations optionally contain solid inorganic builder.Example include carbonate, sulfate, silicate and its
Salt, particular certain cancers；And zeolite.
Detergent composition can also contain or Organic detergent builders or chelating optionally containing low relative levels
Agent material.Example includes alkali metal, citrate, succinate, malonate, carboxymethyl succinates, carboxylate, polycarboxylic acid
Salt and poly- acetyl group carboxylate.Instantiation include oxo disuccinic acid, mellitic acid, the polycarboxylic acids of benzene, ethylenediamine tetra-acetic acid,
Diethylene-triamine pentaacetic acid, alkyl or alkenyl butanedioic acid, sodium salt, sylvite and the lithium salts of NTA and citric acid.Its
His example is the organic phospho acid salt form chelating agent DEQUEST sold by ThermophosTMWith alkane hydroxyethylidene diphosphonic acid salt.
Other suitable organic washing-assisting detergents include the polymer and copolymer of the known HMW with builder capacity.
For example, this kind of material includes suitable polyacrylic acid, poly and poly propenoic acid maleic acid and its salt, such as
The entitled SOKALAN sold by BASFTMThose.Another suitable builder is sodium carbonate.
If used, builder material can account for the about 0.5 weight % to 80 weight % of composition, preferably 1 weight % is extremely
70 weight %.
Preferably, laundry detergent formulations are that nonphosphate helps the laundry detergent formulations washed, i.e., containing less than 1 weight %
Phosphate.
Cover dyestuff
Deposition of dye is covered during the washing of washing process or rinse step to fabric, visible color is provided for fabric
Adjust.The masking of white garments can be carried out according to the hobby of consumer with any color.Blueness and purple are particularly preferred colors
Adjust, it is therefore preferable that dyestuff or dye mixture are the dyestuffs that blueness or violet hue are produced in white fabrics.It is used
Masking dyestuff is preferably blueness or purple.
Masking dye chromophore is preferably selected from the following group：Monoazo, bisazo, triphenylmenthane, San Ben Bing dioxazines, phthalocyanine,
Naphthalene lactim (naptholactam), azine and anthraquinone.Most preferably monoazo, bisazo, azine and anthraquinone.
Dyestuff most preferably at least has a sulfonate ester group.
It is preferred that masking dyestuff be selected from direct dyes, acid dyes, hydrophobic dye, the dye of positive ion and chemically-reactive dyes.
If including covering dyestuff in the composition in the range of 0.0001-0.01 weight % to exist.
Fluorescer
Composition preferably comprises fluorescer (fluorescent whitening agent).Fluorescer is it is well known that and many such glimmering
Photo etching is commercially available.Generally, these fluorescers are supplied and used in the form of its alkali metal salt such as sodium salt.Make in composition
The total amount of fluorescer is usually 0.005-2 weight %, more preferably 0.01-0.1 weight %.
Spices
Preferably, composition includes spices.Spices is preferably in 0.001-3 weight %, most preferably 0.1-1 weight % model
In enclosing.The example of many suitable spices provides CTFA (Cosmetic, the Toiletry and published in CFTA publishing houses
Fragrance Association) 1992International Buyers Guide and by Schnell Publishing
Co. in the annuals of OPD 1993Chemicals Buyers Directory the 80th version published.
It is common for there are a variety of perfume compositions in the formulation.In the present compositions, it is contemplated that there will be four kinds or
It is more kinds of, preferably five kinds or more kinds, more preferably six kinds or more are planted or the different perfume compositions of even seven kinds or more kinds.
Polymer
Composition can include one or more polymer.Polymer can be by helping the fragmentation in solution or suspension
(retail) dirt and/or prevent dyestuff transfer from helping to clean process.Polymer can also help dirt.Enter one below
Dyestuff transfer, antiredeposition and soil release polymer is described in detail in step.
Composition can include one or more polymer.Example is carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl
Cellulose, PEG, poly- (vinyl alcohol), ethoxylated polyamine, polycarboxylate such as polyacrylate, maleic acid/acrylic acid
Copolymer and lauryl methacrylate/acrylic copolymer.
Dye transfer inhibitor
Modern detergent compositions are used as so-called " dye transfer inhibitor " usually using polymer.These prevent dye
The migration of material, particularly during long soak time.Generally, this dye transfer inhibitor is poly- including polyvinylpyrrolidone
Compound, polyamines N- oxide polymers, the copolymer of NVP and N- vinyl imidazoles, manganese phthalocyanine, peroxidating
Thing enzyme and its mixture, and the total amount in laundry composition is typically based on 0.01-10 weight % level presence.
Antiredeposition polymer
Antiredeposition polymer is designed to the dirt that suspends or disperse.Generally, antiredeposition polymer is ethoxylation
And/or propenoxylated polyethyleneimine material.
Soil release polymer
The example of suitable soil release polymer includes poly- (vinyl esters) (such as C1-C6Vinyl esters) graft copolymer,
It is preferred that being grafted to poly- (vinyl acetate) on polyalkylene oxide backbones.Commercially available this detergent includes SOKALAN section bar material, example
The SOKALAN HP-22 that can be such as obtained from BASF (Germany).Other different types of suitable soil release polymers include commercially available material
Expect ZELCON 5126 (coming from DuPont) and MILEASE T (coming from ICI).If it is present soil release polymer can with based on
The 0.01-10 weight % of the total amount of laundry composition level by comprising.Other examples of soil release polymer are with trade name
Terephthalic acid (TPA)/glycol copolymer that Texcare, Repel-o-tex, Gerol, Marloquest, Cirrasol are sold.
Water-assisted solvent
If what in fluid form, liquid detergent composition optionally included can preventing Formation of liquid crystals helps water
Solvent.Therefore, addition water-assisted solvent contributes to clarity/transparency of composition.Suitable water-assisted solvent includes but is not limited to
Propane diols, ethanol, glycerine, urea, benzene sulfonate, toluene fulfonate, xylenesulfonate or cumene sulfonate.Suitable salt bag
Include but be not limited to sodium salt, sylvite, ammonium salt, monoethanolamine salt, triethanolamine salt.The salt of sulfonate can also be considered as herein
The anion surfactant of definition.Preferably, water-assisted solvent is selected from by propane diols, xylenesulfonate, ethanol and urea group
Into group, to provide optimum performance.The amount of water-assisted solvent is generally in 0-30%, more preferably preferably 0.5-30%, 0.5-30%, most
It is preferred that in the range of 1-15%.
Enzyme
Enzyme can also be present in preparation.It is preferred that enzyme include protease, lipase, transelminase, amylase, angle
Matter enzyme, cellulase, mannase.If it does, enzyme can be with known enzyme stabilizers such as boric acid come stable.
The present invention will be proved by following non-limiting example now.
Embodiment
Embodiment 1：Compare the compatibility of the anionic-functionalized silicone graft polysaccharide with non-anion functionalization
Synthesis 1：By in multifunctional carboxyl silicone graft to xyloglucan to provide anionic-functionalized silicone graft
Polysaccharide (embodiment of the present invention)
4ml oxalyl chlorides are added into 5g (0.28mmol) carboxyl-functionals silicone fluid (being provided by Wacker Silicone)
And be sufficiently mixed.Reaction is monitored by the release of escaping gas, reaction continues until that effervesce stops.Add sodium acid carbonate with
It is quenched unreacted oxalyl chloride.Acyl chlorides function silicone is dissolved in 25ml dichloromethane, then quick stirring, adds the wooden Portugals of 1g
Glycan powder and 5ml triethylamines.Reactant is heated to 40 DEG C, makes its reaction until dichloromethane is evaporated, leaves and be dispersed in three
Product in ethamine.
The polysaccharide of gained grafting silicone has the anionic group of residual after grafting process terminates.
Synthesize A：Simple function carboxyl silicone graft to xyloglucan is more to provide the silicone graft of non-anion functionalization
Sugared (comparative example)
Using 0.28mmol X-22-3710 (the simple function carboxyl silicone provided by Shin Etsu) and use xyloglucan
(1g such as synthesizes #1) replaces cellulose monoacetate, the step of repeating to be described in detail in WO 2003/020770.
By using the anion silicone of monofunctional, grafting method run out of this anionic functional group, to be formed
The polysaccharide of the silicone graft remained after grafting without anionic group.
Test formulation
| Composition | Wt.% |
| LAS acid | 7.0 |
| Neodol 25-7 | 10.0 |
| SLES 3EO | 3.0 |
| Propane diols | 15.0 |
| NaOH | To pH 8.5 |
| TEA | 4.0 |
| Citric acid | 1.0 |
| Prifac 5908 (aliphatic acid) | 2.0 |
| Water | To 100wt.% |
Compatibility test：
The product for synthesizing 1 or synthesis A is added in test formulation to prepare the wooden Portugal of silicone graft of 0.5% activity level
Glycan.Gained preparation is estimated in two ways.The first assessment is visually rank, observation preparation it is whether limpid or muddy/
It is fuzzy.Second of assessment is the absorbance at 500nm.By sample move into 1cm cuvettes in, then 500nm wavelength it is ultraviolet-
Definition is measured in visible spectrophotometer, result is compared with check experiment preparation.+ ve values are higher, and sample is got over unlimpid.
As a result show, the graft phase with the simple function silicone using the silicone graft polysaccharide for causing no anionic group residual
Than there is the silicone graft polysaccharide that anionic group is remained to show clear and stable in terms of less fuzzy/muddy preparation is provided
Property advantage.
Claims (14)
1. with the polysaccharide for being grafted to anionic functional silicone thereon, wherein the silicone have at least one residual it is cloudy from
Subbase group.
2. polysaccharide according to claim 1, wherein the polysaccharide is selected from polydextrose, poly- mannose, glucomannans, half
Newborn mannosan and xyloglucan polysaccharide.
3. polysaccharide according to claim 2, wherein the polysaccharide is galactomannans and/or xyloglucan.
4. polysaccharide according to any one of the preceding claims, wherein the polysaccharide is that nonionic polysaccharide or cation are more
Sugar.
5. polysaccharide according to any one of the preceding claims, wherein the anion silicon ketone comprising carboxylate radical, sulfate radical,
Sulfonate radical, phosphate radical and/or phosphonate functional group, more preferably anion silicone are carboxy-functionalized silicone.
6. polysaccharide according to any one of the preceding claims, wherein having at least Yi Dan the anion silicone after grafting
0.1mol%, preferably 0.5mol%, more preferably 1mol%, most preferably 2mol% anionic group content.
7. polysaccharide according to any one of the preceding claims, wherein the polysaccharide is with the silicone being grafted to thereon
Galactomannans and/or xyloglucan, wherein the silicone has at least one carboxyl, preferably 2 carboxyls after grafting.
8. a kind of laundry treatment compositions, it is included：
A) 1-40 weight % surfactant, it includes anion surfactant and optional nonionic surfactant；
With
B) polysaccharide any one of 0.05-10 weight % claim 1-7.
9. laundry treatment compositions according to claim 8, the form of washed detergent based on it.
10. laundry treatment compositions according to any one of the preceding claims, wherein the laundry treatment compositions bag
The % of weight containing 2.5-25, more preferably 4-20 weight % anion surfactant.
11. laundry treatment compositions according to claim 10, wherein the laundry treatment compositions additionally comprise 0.5-
25 weight %, more preferably 2.5-15 weight % nonionic surfactant, and optional aliphatic acid or its soap.
12. laundry treatment compositions according to any one of the preceding claims, wherein the laundry treatment preparation contains
0.05-2.5 weight % cationic polymer, more preferably cationic polysaccharide, most preferably cationic cellulose polymer.
13. laundry treatment compositions according to claim 8, it is included：
A) 6.5-38 weight % surfactant, the anion surfactant comprising 4-20 weight % and 2.5-15 weight %
Nonionic surfactant；
B) the 0.05-10 weight % galactomannans and/or xyloglucan that are grafted with silicone, wherein the silicone is in grafting
There is at least one carboxyl, preferably 2 carboxyls afterwards；
C) 0.5-2.5 weight % Cationic polysaccharide polymer；With
D) optionally 1-12 weight % aliphatic acid.
14. the purposes with the polysaccharide softening fabrics for being grafted to anionic functional silicone thereon.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14190414.4 | 2014-10-27 | ||
| EP14190414 | 2014-10-27 | ||
| PCT/EP2015/072727 WO2016066368A1 (en) | 2014-10-27 | 2015-10-01 | Laundry composition ingredients |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107075422A true CN107075422A (en) | 2017-08-18 |
| CN107075422B CN107075422B (en) | 2020-04-17 |
Family
ID=51795535
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580058563.9A Expired - Fee Related CN107075422B (en) | 2014-10-27 | 2015-10-01 | Laundry composition ingredients |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP3212752B1 (en) |
| CN (1) | CN107075422B (en) |
| AR (1) | AR102431A1 (en) |
| BR (1) | BR112017008583A2 (en) |
| WO (1) | WO2016066368A1 (en) |
| ZA (1) | ZA201702348B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111971377A (en) * | 2018-03-02 | 2020-11-20 | 荷兰联合利华有限公司 | Laundry method |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018060056A1 (en) * | 2016-09-29 | 2018-04-05 | Unilever Plc | Laundry composition |
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| WO2003050144A1 (en) * | 2001-12-07 | 2003-06-19 | The Procter & Gamble Company | Anti-wrinkle silicone polysaccharide compounds and compositions comprising said compounds |
| CN1549844A (en) * | 2001-08-31 | 2004-11-24 | Laundry treatment compositions | |
| CN1549827A (en) * | 2001-08-31 | 2004-11-24 | Polymers and their use | |
| US20050250904A1 (en) * | 2002-09-11 | 2005-11-10 | Tadashi Okawa | Organopolysiloxane-modified polysaccharide and process for producing the same |
| WO2005118761A1 (en) * | 2004-05-28 | 2005-12-15 | Unilever Plc | Laundry treatment compositions |
| CN1891196A (en) * | 2005-05-24 | 2007-01-10 | 莱雅公司 | Detergent cosmetic compositions comprising at least one amino silicone, and use thereof |
-
2015
- 2015-10-01 BR BR112017008583A patent/BR112017008583A2/en not_active Application Discontinuation
- 2015-10-01 CN CN201580058563.9A patent/CN107075422B/en not_active Expired - Fee Related
- 2015-10-01 EP EP15781883.2A patent/EP3212752B1/en active Active
- 2015-10-01 WO PCT/EP2015/072727 patent/WO2016066368A1/en active Application Filing
- 2015-10-26 AR ARP150103461A patent/AR102431A1/en not_active Application Discontinuation
-
2017
- 2017-04-03 ZA ZA2017/02348A patent/ZA201702348B/en unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1549844A (en) * | 2001-08-31 | 2004-11-24 | Laundry treatment compositions | |
| CN1549827A (en) * | 2001-08-31 | 2004-11-24 | Polymers and their use | |
| WO2003050144A1 (en) * | 2001-12-07 | 2003-06-19 | The Procter & Gamble Company | Anti-wrinkle silicone polysaccharide compounds and compositions comprising said compounds |
| US20050250904A1 (en) * | 2002-09-11 | 2005-11-10 | Tadashi Okawa | Organopolysiloxane-modified polysaccharide and process for producing the same |
| WO2005118761A1 (en) * | 2004-05-28 | 2005-12-15 | Unilever Plc | Laundry treatment compositions |
| CN1891196A (en) * | 2005-05-24 | 2007-01-10 | 莱雅公司 | Detergent cosmetic compositions comprising at least one amino silicone, and use thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111971377A (en) * | 2018-03-02 | 2020-11-20 | 荷兰联合利华有限公司 | Laundry method |
| US11814607B2 (en) | 2018-03-02 | 2023-11-14 | Conopco, Inc. | Laundry additive composition comprising a soil release polymer/silicone mixture |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3212752A1 (en) | 2017-09-06 |
| EP3212752B1 (en) | 2021-12-01 |
| AR102431A1 (en) | 2017-03-01 |
| CN107075422B (en) | 2020-04-17 |
| ZA201702348B (en) | 2018-08-29 |
| BR112017008583A2 (en) | 2018-01-30 |
| WO2016066368A1 (en) | 2016-05-06 |
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