CN105745314B - Laundry composition - Google Patents
Laundry composition Download PDFInfo
- Publication number
- CN105745314B CN105745314B CN201480064997.5A CN201480064997A CN105745314B CN 105745314 B CN105745314 B CN 105745314B CN 201480064997 A CN201480064997 A CN 201480064997A CN 105745314 B CN105745314 B CN 105745314B
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- China
- Prior art keywords
- polymer
- compositions
- composition
- cationic
- anion
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 96
- -1 polysiloxane Polymers 0.000 claims abstract description 128
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 81
- 150000001450 anions Chemical class 0.000 claims abstract description 43
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 30
- 239000003599 detergent Substances 0.000 claims abstract description 29
- 239000004094 surface-active agent Substances 0.000 claims abstract description 23
- 125000000129 anionic group Chemical group 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 239000004744 fabric Substances 0.000 claims abstract description 10
- 229920000642 polymer Polymers 0.000 claims description 64
- 229920001282 polysaccharide Polymers 0.000 claims description 20
- 239000005017 polysaccharide Substances 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 19
- 150000001768 cations Chemical group 0.000 claims description 19
- 229920002678 cellulose Polymers 0.000 claims description 16
- 239000001913 cellulose Substances 0.000 claims description 16
- 125000002091 cationic group Chemical group 0.000 claims description 14
- 125000001931 aliphatic group Chemical group 0.000 claims description 13
- 238000002360 preparation method Methods 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 108090000790 Enzymes Proteins 0.000 claims description 9
- 102000004190 Enzymes Human genes 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 239000002689 soil Substances 0.000 claims description 8
- 238000012546 transfer Methods 0.000 claims description 8
- 229920002907 Guar gum Polymers 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 7
- 239000000665 guar gum Substances 0.000 claims description 7
- 235000010417 guar gum Nutrition 0.000 claims description 7
- 229960002154 guar gum Drugs 0.000 claims description 7
- 239000002738 chelating agent Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 3
- 230000002401 inhibitory effect Effects 0.000 claims description 3
- 239000003605 opacifier Substances 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 23
- 229920001577 copolymer Polymers 0.000 description 13
- 150000004676 glycans Chemical class 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 229920000289 Polyquaternium Polymers 0.000 description 10
- 235000019441 ethanol Nutrition 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
- 229940088598 enzyme Drugs 0.000 description 8
- 230000003165 hydrotropic effect Effects 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- 239000003945 anionic surfactant Substances 0.000 description 7
- 239000002585 base Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 6
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 6
- 229920002125 Sokalan® Polymers 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Chemical group CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 229920000550 glycopolymer Polymers 0.000 description 5
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 5
- 150000004804 polysaccharides Polymers 0.000 description 5
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 244000303965 Cyamopsis psoralioides Species 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000001856 Ethyl cellulose Substances 0.000 description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 3
- 229920001249 ethyl cellulose Polymers 0.000 description 3
- 235000019325 ethyl cellulose Nutrition 0.000 description 3
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000012875 nonionic emulsifier Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 235000021286 stilbenes Nutrition 0.000 description 3
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000000746 allylic group Chemical group 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 238000010538 cationic polymerization reaction Methods 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000007046 ethoxylation reaction Methods 0.000 description 2
- 229930182478 glucoside Natural products 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000004355 nitrogen functional group Chemical group 0.000 description 2
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 150000004028 organic sulfates Chemical class 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
- 238000001259 photo etching Methods 0.000 description 2
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 125000001453 quaternary ammonium group Chemical class 0.000 description 2
- 239000000985 reactive dye Substances 0.000 description 2
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N rose oxide Chemical compound CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 235000020354 squash Nutrition 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 229940071104 xylenesulfonate Drugs 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 description 1
- KCZIUKYAJJEIQG-UHFFFAOYSA-N 1,3,5-triazin-2-amine Chemical compound NC1=NC=NC=N1 KCZIUKYAJJEIQG-UHFFFAOYSA-N 0.000 description 1
- CRQWZKDIVBSAJD-UHFFFAOYSA-N 1-dodecoxydodecane;sodium Chemical compound [Na].CCCCCCCCCCCCOCCCCCCCCCCCC CRQWZKDIVBSAJD-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical class C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- KAESVJOAVNADME-UHFFFAOYSA-N 1H-pyrrole Natural products C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- PZBASOPBSCAZSR-UHFFFAOYSA-N 2-ethenyl-1-methylimidazole Chemical class CN1C=CN=C1C=C PZBASOPBSCAZSR-UHFFFAOYSA-N 0.000 description 1
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- MXMWUQAFMKOTIQ-UHFFFAOYSA-N 4-(carboxymethoxy)-4-oxobutanoic acid Chemical class OC(=O)CCC(=O)OCC(O)=O MXMWUQAFMKOTIQ-UHFFFAOYSA-N 0.000 description 1
- YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102100032487 Beta-mannosidase Human genes 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
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- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 241001672694 Citrus reticulata Species 0.000 description 1
- 229920000832 Cutin Polymers 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- 229920000926 Galactomannan Polymers 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical group COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- DLKHENMIHBZMSE-UHFFFAOYSA-N OCCC[O].[Cl-].[NH4+] Chemical compound OCCC[O].[Cl-].[NH4+] DLKHENMIHBZMSE-UHFFFAOYSA-N 0.000 description 1
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- AHWXCYJGJOLNFA-UHFFFAOYSA-N [1,4]benzoxazino[2,3-b]phenoxazine Chemical compound O1C2=CC=CC=C2N=C2C1=CC1=NC3=CC=CC=C3OC1=C2 AHWXCYJGJOLNFA-UHFFFAOYSA-N 0.000 description 1
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- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000005227 alkyl sulfonate group Chemical group 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000005466 alkylenyl group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
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- 235000019418 amylase Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 108010055059 beta-Mannosidase Proteins 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
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- 239000007844 bleaching agent Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229940006460 bromide ion Drugs 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 125000001589 carboacyl group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 239000001071 citrus reticulata blanco var. mandarin Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
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- 239000007859 condensation product Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229940071118 cumenesulfonate Drugs 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 description 1
- 229930008394 dihydromyrcenol Natural products 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000005125 dioxazines Chemical class 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical class CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- VUJGKADZTYCLIL-YHPRVSEPSA-L disodium;5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 VUJGKADZTYCLIL-YHPRVSEPSA-L 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-M ethyl sulfate Chemical compound CCOS([O-])(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-M 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000004395 glucoside group Chemical group 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
- 229940006461 iodide ion Drugs 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 125000000311 mannosyl group Chemical group C1([C@@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- SPBPMWWOBCFOHX-UHFFFAOYSA-N methoxymethane;sulfuric acid Chemical compound COC.OS(O)(=O)=O SPBPMWWOBCFOHX-UHFFFAOYSA-N 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical group CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- ZOCHHNOQQHDWHG-UHFFFAOYSA-N n-hexan-3-ol Natural products CCCC(O)CC ZOCHHNOQQHDWHG-UHFFFAOYSA-N 0.000 description 1
- ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000196 poly(lauryl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 229930007790 rose oxide Natural products 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to liquid laundry compositions, it includes (a) surfactants, (b) fabric-softening anion polysiloxane, (c) cationic polymer, anionic group (one or more) wherein on fabric-softening anion polysiloxane is not located on the end position on longest linear silicones chain, and wherein the weight ratio of polysiloxanes and cationic polymer is 5:1 to 1:1, and wherein liquid detergent composition has 6 to 10 pH;And it is related to purposes of the composition for softening fabrics.
Description
Invention field
The present invention relates to laundry compositions.More particularly it relates to the laundry composition softened that is in the suds.
Background of invention
Laundry detergent has traditionally been used to clean textile fabric, including clothing.After the washing, fabric may be usually
Make us feeling coarse.This point in order to prevent, that is especially undergone after multiple wash cycles is coarse, developed technology with
Increase the pliability of fabric, including the conditioner composition added when rinsing and the softening system for being added to detergent composition.
Fabric-softening polysiloxanes has been used to provide pliability by laundry detergent composition for fabric.However, not
In terms of acceptable turbid mixed (haze), there are problems that preparation stability.
Summary of the invention
In the first aspect, the present invention relates to liquid laundry detergent compositions, it includes:
(a)The surfactant of 5 to 40 wt.%;
(b)The fabric-softening anion polysiloxane of 0.05 to 5 wt.%;With
(c)The cationic polymer of 0.05 to 2.5 wt.%,
Anionic group (one or more) wherein on fabric-softening anion polysiloxane is not located at longest straight
On end position on chain polysiloxane chain.
Wherein the weight ratio of polysiloxanes and cationic polymer is 5:1 to 1:1;Also, wherein liquid detergent combines
Object has 6 to 10 pH.
Preferably, the anionic group on fabric-softening anion polysiloxane (one or more) is located at away from longest
End position at least five Si atoms on linear silicones chain.
Preferably, anion polysiloxane has 1,000 to 100,000, is more preferable 2,000 to 50,000, even more excellent
Select 5,000 to 50,000, most preferably 10,000 to 50,000 molecular weight.Preferably, anion polysiloxane has at least 1
The anionic group content of mol%, preferably 2 mol%.
Preferably, anion polysiloxane includes carboxyl polysiloxanes.
Preferably, by polysiloxanes in the form of an emulsion, more preferably in the form of non-ionic emulsion, most preferably with branch
Nonionic emulsifier is added to preparation.
Preferably, the pH of liquid detergent composition be pH 6.5 to 9.5, most preferably pH 7 to 9, for example, pH 7.5 to
8.5。
The preferred levels of cationic polymer are 0.1 to 2 wt.%, more preferable 0.1 to 1 wt.%, most preferably 0.1 to 0.75
wt.%;And the preferred levels of anion polysiloxane are existed with the level of 0.1 to 2.5 wt.%, preferably 0.1 to 2 wt.%.
Preferably, cationic polymer is Cationic polysaccharide polymer.
Preferred Cationic polysaccharide polymer is cation guar gum and cationic cellulose polymer.Particularly preferably
The hydroxyether cellulosic (i.e. quaternized hydroxyethyl cellulose) being modified by introducing cation group.
Optionally but preferably, the composition is further included selected from aliphatic acid or its salt, dope dye (shading
Dye), enzyme, antiredeposition polymer, dye transfer inhibiting polymers, builder, chelating agent, opacifier (sunscreen), glimmering
The ingredient of photo etching, aromatic (perfume) and/or soil release polymer.
In second aspect, the present invention provides compositions according to the first aspect of the invention for the use of softening fabrics
On the way.
Detailed description of the invention
As used herein, term "comprising" indicate including (including), by ... constitute (made up of), by ...
Into (composed of), by ... form (consisting of) and/or substantially by ... form (consisting
essentially of)。
Unless otherwise stated, all percentages of citation are wt.%, based on the total amount in laundry composition.
The present invention relates to the laundry groups comprising surfactant, cationic polymer and fabric-softening anion polysiloxane
Object is closed, wherein the anionic group (one or more) on fabric-softening anion polysiloxane is not located at the end of polysiloxanes
On position.
The form of the present invention
The present invention may be used as any one of diversified forms of liquid laundry compositions (such as gel and aqueous solution
Body).Preferably, they are that master washes (main wash) product.It, which may be used, can be dilutable or not dilutable be used for
The form of the main laundry composition washed.Laundry composition may, for example, be isotropic liquid or surfactant-structured liquid
Body.The particularly preferred form of the present invention includes the product of composition, detergent/softening agent, and with offer, " being in the suds, it is soft to carry out
Change ".
Preferably, the pH of liquid detergent composition be pH 6.5 to 9.5, most preferably pH 7 to 9, such as pH 7.5 to
8.5。
Surfactant
Detergent composition includes surfactant.
Preferably, which includes nonionic surfactant and anion surfactant.
If it does, nonionic surfactant preferably includes alcohol ethoxylate.
Alcohol ethoxylate is formed by reacting for primary alconol or secondary alcohol and ethylene oxide.In general, making aliphatic C8To C18Uncle or
Secondary linear chain or branched chain alcohol is with ethylene oxide to generate mole quantitative response needed for alcohol ethoxylate.Preferred alcohol ethoxylate
With 2 to 40, preferably 3 to 30, more preferable 5 to 20 ethylene oxide units for being connected to aliphatic chain.
Surfactant can be selected from " Surface Active Agents ", roll up 1, Schwartz & Perry,
Interscience 1949, volume 2, Schwartz, Perry & Berch, Interscience 1958, by
" McCutcheon's Emulsifiers and published by Manufacturing Confectioners Company
Detergents " latest editions or " Tenside-Taschenbuch ", H. Stache, the second edition, Carl Hauser Verlag,
Surfactant described in 1981.Preferably, the surfactant used is saturation.
The suitable nonionic detergent compounds that can use particularly including there are hydrophobic grouping and hydrogen atoms
Compound(Such as aliphatic alcohol, acid, amide or alkyl phenol)With alkylene oxide (especially individual ethylene oxide or with propylene oxide one
Rise ethylene oxide) reaction product.Specific nonionic detergent compounds are C6To C22Alkyl phenol-ethylene oxide condensation
Object, usually 5 to 25 EO of per molecule, i.e. 5 to 25 ethylene oxide units, and aliphatic series C8To C18Primary or secondary linear or branched
The condensation product of alcohol and ethylene oxide, usually 5 to 40 EO.
The suitable anionic detergent compounds that can be used can be the water-soluble alkali of organo-sulfate and sulphonic acid ester
Metal salt, the organo-sulfate and sulphonic acid ester have the alkyl for including about 8 to about 22 carbon atoms, and term alkyl is for including
The moieties of higher acyl.The example of suitable synthetic anionic detergent compound is sodium alkyl sulfate and potassium, especially
The advanced C for example generated by fatty oil or coconut oil by sulphation8To C18Those of alcohol acquisition, alkyl C9To C20Benzene sulfonic acid sodium salt
And potassium, especially linear secondary alkyl C10To C15Benzene sulfonic acid sodium salt;And alkyl glyceryl ether sulphates, especially those are derived from fat
The ether of oily or coconut oil higher alcohol and the synthol derived from oil.Preferred anionic detergent compounds are C11To C15
Sodium alkyl benzene sulfonate and C12To C18Sodium alkyl sulfate.The salt for the sulphonic acid ester for including as hydrotropic agent (hydrotrobe) can
To be considered as extraly anion surfactant as defined herein.What is be also applicable to is for example in EP-A-328
Resistance to surfactant, the alkyl described in EP-A-070 074 of those of saltouing is shown described in 177 (Unilever)
Polyglucoside surfactant and alkyl monoglycosides.
The total amount of existing surfactant is 5 to 40 wt.% in the composition.The surfactant level is preferably extremely
Few 6 wt.%, more preferably at least 10 wt.%.It is highly preferred that the total amount of surfactant be 12.5 to 40 wt.%, preferably 15 to
35 wt.%。
Preferred surfactant system includes anion and nonionic surfactant.
Nonionic detergent preferably exists with the amount of 2 to 40 wt.%, preferably 5 to 35 wt.%, more preferable 6 to 20 wt.%.
Preferred nonionic surfactant is the C with average 7 to 9 moles of ethoxylation (ethoxylation)12
To C15Alkyl chain.
Anion surfactant is preferably with the amount of 4 to 40 wt.%, preferably 5 to 35 wt.%, more preferable 6 to 20 wt.%
In the presence of.
Preferably anion surfactant is:Linear alkylbenzene sulfonate (LAS), the ethyoxyl with 1 to 3 mole (average)
Or mixtures thereof lauryl ether sodium sulfonate, primary alkyl sulfonate, methyl ether sulfate and secondary alkyl sulfonate of change.
For the horizontal purpose for explaining existing surfactant in the formulation, do not wrapped in the level of surfactant
Include the salt of aliphatic acid and they.
In addition to nonionic above-mentioned and anion surfactant, there may also be other surfactants, such as two
Property, amphoteric ion and cationic surfactant.
Fabric-softening anion polysiloxane
Polysiloxanes and their chemical property are described in such as The Encyclopedia of Polymer
Science, in volume 11, page 765.
The composition includes with the water of 0.05 to 5 wt.%, preferably 0.1 to 2.5 wt.%, more preferable 0.1 to 2 wt.%
Flat fabric-softening anion polysiloxane.
The example of fabric-softening anion polysiloxane is to introduce carboxyl, sulfuric ester, sulfo group (sulphonic), phosphate
And/or the polysiloxanes of phosphonate ester degree of functionality (functionality).
Preferred anion polysiloxane is carboxy-functionalized polysiloxanes.
For the present invention disclosed herein, anion polysiloxane can sour or anion form.Such as
For carboxy-functionalized polysiloxanes, can exist in the form of carboxylic acid or carboxylate anion.
One example of commercially available material is:X22-3701E from Shin Etsu.
Preferably, anion polysiloxane has 1,000 to 100,000, is more preferable 2,000 to 50,000, even more excellent
Select 5,000 to 50,000, most preferably 10,000 to 50,000 molecular weight.
Preferably, anion polysiloxane has the anionic group content of at least 1 mol%, preferably 2 mol%.
It is poly- that anionic group (one or more) on fabric-softening anion polysiloxane is not located at longest straight chain
On the end position of siloxane chain.
This indicates that the composition includes anion polysiloxane, and wherein anionic group is located at except in polysiloxane chain
Somewhere except end.Term " end position " and " in end of polysiloxane chain " are for showing in longest linear silicones chain
Terminal (terminus) on without find anionic functionality.
When polysiloxanes is straight chain property, then they have 2 ends.Fabric-softening anion used herein
Polysiloxanes includes the anionic group not being located on the end position of polysiloxanes.
Some polysiloxanes are branch property.When for such case, term " end position " and " at the end of polysiloxane chain
End " is for showing in the terminal of longest linear silicones chain without finding anionic functionality.
Preferred anion polysiloxane is included in those of the anionic group of the chain middle position on poly- silica.
It is therefore preferred that the anionic group (one or more) on fabric-softening anion polysiloxane is located at away from longest straight
End position at least five Si atoms on chain polysiloxane chain.
Preferably, the anionic group on fabric-softening anion polysiloxane (one or more) is located at away from longest
End position at least five Si atoms on linear silicones chain.
Preferably, by polysiloxanes in the form of an emulsion, preparation is more preferably added in the form of non-ionic emulsion.It is more excellent
Selection of land, the lotion is by nonionic emulsifier, more preferable branched nonionic emulsifier such as Ecosurf EH-3 (Dow Chemical)
Or prepared by Berol 840 (Akzo Nobel).
The weight ratio of polysiloxanes and cationic polymer is 5:1 to 1:1.
Cationic polymer
The composition is with 0.05 to 2.5 wt.%, preferably 0.1 to 2 wt.%, more preferable 0.1 to 1 wt.%, most preferably
The level of 0.1 to 0.75 wt.% includes cationic polymer.
The term refers to the polymer for having overall positive charge.
Preferably, cationic polymer is selected from:Cationic polysaccharide polymer, and there is cationic protonated amine or quaternary ammonium official
The non-glycopolymers of cation of energy degree, the non-glycopolymers of cation are to be derived from the monomer comprising amino or quaternary nitrogen functional group
Homopolymer or copolymer, be polymerized by least one of following monomeric species:Acrylate, methacrylate,
Acrylamide, Methacrylamide;Allylic (including diallyl and methacrylic);Aziridine (ethylene
imine);And/or vinyl monomer type and its mixture.
It is highly preferred that cationic polymer be selected from cationic cellulose polymer, cationic guar polymer, fellatio from
The polymer of sub- quaternary diallyl ammonium, and (methyl) acrylate, (methyl) acrylic acid diethylamino second
The homopolymer or copolymer of ester or (methyl) tbutylaminoethylacrylate in the form of their quaternary amine or protonated amines, and its
Mixture.
Most preferably, cationic polymer is Cationic polysaccharide polymer.
It is highly preferred that Cationic polysaccharide polymer is cation guar gum or cationic cellulose polymer.Most preferably,
Cationic polymer is cationic cellulose polymer, such as quaternized hydroxyethyl cellulose.
The composition can include single cationic polymer or the cationic polymerization from identical or different type
The mixture of object, i.e. the composition can include Cationic polysaccharide polymer and the non-polysaccharide polymer of cation.It is suitable commercial
The non-polysaccharide polymer of cation those of is derived from preferably but not exclusively in Polyquarternium series, for example,
Polyquat 5,6,7,11,15,16,28,32,37 and 46, with Flocare, Merquat, Salcare, Mirapol,
Gafquat and Luviquat trade names are commercially available.It can be in the feelings for not following polyquaternium (Polyquaterium) nomenclature
The non-polysaccharide of cation is used under condition.
Cationic polysaccharide polymer
Term " Cationic polysaccharide polymer " refers to thering is polysaccharide skeleton and the polymer of overall positive charge.Polysaccharide be by
Pass through the polymer of the monosaccharide monomers composition of glucosides key connection together.
The polymer based on polysaccharide of existing cation has modified polysaccharide skeleton in the present compositions, changes
Property is that additional chemical group has been made to react with to modified cellulosic monomer list with some free hydroxyl groups of polysaccharide skeleton
Member provides overall positive charge.
The preferred kind of Cationic polysaccharide polymer suitable for the present invention is with being modified to introduce quaternary ammonium salt
Those of polysaccharide skeleton.Preferably, quaternary ammonium salt is connected to polysaccharide skeleton by ethoxy or hydroxypropyl.Preferably, quaternary ammonium salt
The nitrogen of electrification has one or more alkyl substituents.
The polymer based on polysaccharide of preferred cation has the skeleton based on guar gum or based on cellulose.Based on fibre
The cationic polymer of dimension element is most preferred.
Guar gum is the galactomannans of the mannose backbone with β-Isosorbide-5-Nitrae connection, and the skeleton, which has to α -1,6, to be connected
The branch point of the galactose units connect.
Suitable cationic guar derivative, such as guar hydroxypropyltrimonium ammonium chloride, specific example include
Available commercially from the Jaguar series of Rhone-Poulenc Incorporated, and available commercially from Aqualon Division of
The N-Hance series of Hercules, Inc.
An example for being preferably based on the cationic polymer of guar gum is guar gum 2- hydroxyls -3- (trimethyl ammonium) third
Base ether salt.
Cellulose is the polysaccharide for having glucose as monomer, and particularly it is the D- via β-Isosorbide-5-Nitrae glucosides key connection
The straight chain polymer of glucopyranose units, and be the polymer of linear non-branching.
Example cationic cellulose polymer is the epoxide reactive hydroxyethyl cellulose replaced with trimethyl ammonium
Salt is known as polyquaternium 10 (Polyquatemium 10) according to the international nomenclature of cosmetic composition in the art, and
And available commercially from Amerchol Corporation (subsidiary of The Dow Chemical Company), as Polymer
LR and the polymer of JR series are commercially available.Other polymer are with SoftCAT trade names by The Dow Chemical
Company is commercially available.Other suitable types of cationic cellulose include the epoxides replaced with lauryl dimethyl ammonium
The polymeric quaternary ammonium salts of the hydroxyethyl cellulose of reaction are known as poly- season according to the international nomenclature of cosmetic composition in the art
Ammonium salt 24.
The representative instance of preferred cationic cellulose polymer include coco dimethyl ammonium hydroxypropyl oxygen ethyl cellulose,
Lauryldimonium Hydroxypropyl base oxygen ethyl cellulose, ammonium chloride hydroxypropyl oxygen ethyl cellulose and g., stearyl
Base ammonium hydroxyethyl cellulose;Cellulose 2- ethoxy 2- hydroxyls 3- (trimethyl ammonium) propyl ether salt (cellulose 2-
Hydroxyethyl 2-hydroxy 3- (trimethyl ammonio) propyl ether salt), it is polyquaternium -4, poly-
Or mixtures thereof quaternary ammonium salt -10, polyquaternium -24 and Polyquaternium-67,.
It is highly preferred that cationic cellulose polymer is quaternized hydroxyether cellulosic cationic polymer.These are logical
It is commonly referred to as Polyquaternium-10.It is by The for suitable commercial cationic cellulose polymer product used according to the invention
Dow Chemical Corporation are commercially available with trade name UCARE.
Other cationic polymerization species
The cationic polymer based on non-polysaccharide can also be used.The suitable non-glycopolymers of cation include have sun from
Those of sub- protonated amines or quaternary ammonium functionality, the non-glycopolymers of cation are derived from comprising amino or quaternary nitrogen functional group
Monomer homopolymer or copolymer, be polymerized by least one of following monomeric species:Acrylate, metering system
Acid esters, acrylamide, Methacrylamide;Allylic (including diallyl and methacrylic);Aziridine;And/or
Vinyl monomer type and its mixture.
The preferred non-glycopolymers of cation include the polymer and (methyl) acrylic acid of cation quaternary diallyl ammonium
Dimethylamino ethyl ester, (methyl) acrylic acid diethylamino ethyl ester or (methyl) tbutylaminoethylacrylate with they
The homopolymer or copolymer and its mixture of quaternary amine or protonated amines form.
The other suitable cationic polymers used in the composition include l-vinyl-2-pyrrolidone and 1-
The copolymer (being referred to as polyquaternium -16) of vinyl -3- methylimidazole salts;L-vinyl-2-pyrrolidone and methyl-prop
The copolymer (being referred to as polyquaternium -11) of olefin(e) acid dimethylamino ethyl ester;The polymer of cation quaternary diallyl ammonium, packet
Include the copolymer of such as dimethyl diallyl ammonium chloride homopolymer, acrylamide and dimethyl diallyl ammonium chloride (respectively
It is referred to as polyquaternium 6 and polyquaternium 7);The ampholyte copolymer of acrylic acid, including acrylic acid and dimethyl diallyl chlorine
Change the copolymer (being referred to as polyquaternium 22) of ammonium, the ternary of acrylic acid and dimethyl diallyl ammonium chloride and acrylamide
Copolymer (being referred to as polyquaternium 39) and acrylic acid and Methacrylamide hydroxypropyltrimonium chloride and methacrylic acid
The terpolymer (being referred to as polyquaternium 47) of ester.
The monomer of preferred cation substitution is the dialkyl amido allyl acrylamide of cation substitution
(dialkylaminoallcyl acrylamide), dialkyl amido allyl methacrylamide
(dialkylaminoallcyl methacrylamide) and combinations thereof.
The counter ion counterionsl gegenions of cationic polymer are freely selected from following halogen ion:Chlorion, bromide ion and iodide ion;Or choosing
From hydroxyl, phosphate radical, sulfate radical, bisulfate ion, ethyl sulphate, methylsulfate, formate and acetate.
Many cationic polymers above-mentioned can with many different molecular weights synthesize and it is commercially available.Preferably, cation is poly-
The molecular weight for closing object is 10,000 to 2,000,000 dalton, more preferable 100,000 to 1,000,000 dalton, even more
It is preferred that 250,000 to 1,000,000 dalton.
Optional member
Detergent composition can optionally include one or more in following optional member:Aliphatic acid or its salt, toning
Dyestuff, enzyme, antiredeposition polymer, dye transfer inhibiting polymers, builder, chelating agent, opacifier, fluorescer, aromatic,
And/or soil release polymer.
Aliphatic acid
The composition can also include aliphatic acid or fatty acid salt, such as soap.Example includes C6-C22Aliphatic acid and its
Sodium salt, sylvite and ammonium salt.For the horizontal purpose for explaining existing surfactant in the formulation, the level of surfactant
In do not include the salt of aliphatic acid and they.
Aliphatic acid exists with the level of 0.25 to 12 wt.%, preferably 0.5 to 10 wt.%.
Builder and chelating agent
Detergent composition can also optionally include the Organic detergent builders or chelating agent material of low relative levels.It is real
Example includes alkali metal, citrate, succinate, malonate, carboxymethyl succinates, carboxylate, multi-carboxylate and more second
Carboxylic acyl salt (polyacetyl carboxylate).Specific example include oxygen disuccinic acid, mellitic acid, benzene polycarboxylic acid,
The sodium of ethylenediamine tetra-acetic acid, diethylenetriamine-pentaacetic acid, alkyl-or alkenyl succinic acid, nitrilotriacetic acid and citric acid
Salt, sylvite and lithium salts.Other examples are DEQUESTTM, by the organic phospho acid salt form chelating agent and alkane hydroxyl of Thermophos sale
Base phosphonate (alkanehydroxy phosphonate).
Other suitable organic washing-assisting detergents include polymer and the copolymerization of the known higher molecular weight with builder capacity
Object.For example, such material includes suitable polyacrylic acid, poly and poly propenoic acid maleic acid and they
Salt, such as by BASF with title SOKALANTMThose of sale.Another suitable builder is sodium carbonate.
If used, builder material can account for about 0.5% to 20 wt%, preferably 1 wt% to 10 of the composition
wt%.Preferred builder level is less than 10 wt% and preferably smaller than 5 wt% of the composition.
Preferably, laundry wash agent formulation is that phosphate free helps the laundry wash agent formulation for washing (built), that is, includes to be less than
The phosphate of 1 wt.%.
Dope dye
Dope dye deposits during the washing of washing process or rinse step to fabric, and visible chrominance is provided for fabric
(hue).According to the hobby of consumer, the toning to white garments can be completed with any color.Blue and purple are especially excellent
The tone of choosing, and it is therefore preferable that the mixture of dyestuff or dyestuff be provided in white fabrics blue or violet hue that
A bit.The preferred blue of dope dye or purple used.
Dope dye chromophore is preferably selected from:Monoazo, bisazo, triphenyl methane, San Ben Bing dioxazines
(triphenodioxazine), phthalocyanine, naphthalene lactams, azine and anthraquinone.Most preferably monoazo, bisazo, azine and anthraquinone.
Most preferably, dyestuff carries at least one sulfonate group (sulfonate group).
Preferred dope dye is selected from direct dyes, acid dyes, hydrophobic dye, the dye of positive ion and reactive dye
(reactive dye)。
If including dope dye is present in the composition with 0.0001 to 0.01 wt %.
Fluorescer
The composition preferably comprises fluorescer (fluorescent whitening agent).Fluorescer is well known, and many such glimmering
Photo etching is commercially available.In general, these fluorescers are supplied and are used in the form of their alkali metal salt, such as sodium salt.
The total amount of the fluorescer (one or more) used in the composition is usually 0.005 to 2 wt.%, more preferable 0.01 to 0.1
wt.%.The preferred kind of fluorescer is:Two-styrylbiphenyl compounds, such as Tinopal (trade mark) CBS-X, two-amine
Two-sulfoacid compound of stilbene, such as Tinopal DMS pure Xtra and Blankophor (trade mark) HRH and pyrazoline chemical combination
Object, such as Blankophor SN.Preferably fluorescer is:2- (4- styryl -3- sulfo groups phenyl) -2H- naphthols [1,2-d]
1-Sodium-1,2,4-Triazole (sodium 2- (4-styryl-3-sulfophenyl) -2H-napthol [1,2-d] trazole), 4,4'- are bis-
{ [(4- anilino-s -6- (N- methyl-N-2- ethoxys) amino -1,3,5- triazine -2- bases)] amino } stilbene -2-2' disulfonic acid two
Bis- { [(4- anilino-s -6- morpholinyls -1,3,5-triazines -2- bases)] amino } stilbene -2-2' disulfonates and 4 of sodium, 4,4'-,
Bis- (2- sulfostyryls) the biphenyl disodiums of 4'-.
Aromatic
Preferably, the composition includes aromatic.Aromatic is preferably 0.001 to 3 wt.%, most preferably 0.1 to 1
wt.%.Many suitable examples of aromatic by published by CFTA Publications CTFA (Cosmetic,
Toiletry and Fragrance Association) 1992 International Buyers Guide and by
1993 Chemicals Buyers Directory 80th Annual of OPD published by Schnell Publishing Co
It is provided in Edition.
Commonly a variety of fragrance components are present in preparation.In the present compositions, it is contemplated that there will be four kinds
Or more, preferably five kinds or more, more preferable six kinds or more or even seven kinds or more different fragrance components.
In fragrance blend, preferably 15 to 25 wt.% are that head is fragrant (top note).Head is fragrant to be defined by Poucher
(Journal of the Society of Cosmetic Chemists 6(2):80 [1955]).Preferred head perfume (or spice) is selected from mandarin orange
Mandarin oil, linalool, bergamio, lavender, dihydromyrcenol, rose oxide and cis-3-hexanol.
Preferably laundry treatment compositions do not include peroxygen bleach, such as SODIUM PERCARBONATE, sodium perborate and peracid.
Polymer
The composition can include one or more polymer.By helping to keep dirt scattered in solution or suspension
(retail) and/or the transfer of dyestuff is prevented, polymer can help to cleaning process.Polymer can also contribute to decontamination
Journey.Dyestuff transfer, antiredeposition and soil release polymer are described in further detail below.
The composition can include one or more polymer.Example is carboxymethyl cellulose, hydroxyethyl cellulose, hydroxyl
Propyl cellulose, poly(ethylene glycol), poly- (vinyl alcohol), ethoxylated polyamine, polycarboxylate such as polyacrylate, maleic acid/the third
Olefin(e) acid copolymer and lauryl methacrylate/acrylic copolymer.
Dye transfer inhibitor
Modern detergent compositions are usually using polymer as so-called " dye transfer inhibitor ".These polymer hinder
The migration of dyestuff is stopped, especially during long soaking time.In general, such dye transfer inhibitor includes polyvinyl pyrrole
Copolymer, the manganese phthalein of pyrrolidone polymer, polyamines N- oxide polymers, n-vinyl pyrrolidone and N- vinyl imidazoles
Cyanines, peroxidase and its mixture, and it is usually with the water of 0.01 to 10 wt.% of the total amount based on laundry composition
It is flat to exist.
Antiredeposition polymer
Antiredeposition polymer is designed to the dirt that suspends or disperse.Typically, antiredeposition polymer is ethyoxyl
Change and/or propoxylated polyethylene imine or polycarboxylate/salt material, such as the homopolymer based on acrylic acid or copolymer,
It can be obtained from Dow Chemical with trade mark ACUSOL, Akzonobel is obtained from Alcosperse or BASF is obtained from Sokolan.
Soil release polymer
The example of suitable soil release polymer includes poly- (vinyl esters), such as C1-C6The graft copolymer of vinyl esters,
It is preferred that being grafted to poly- (vinyl acetate) on polyalkylene oxide backbones.This kind of commercially available detergent includes SOKALAN types
Material, such as SOKALAN HP-22, available from BASF (Germany).Different types of other suitable decontamination polymerizations
Object includes commercially available material ZELCON 5126 (coming from DuPont) and MILEASE T (coming from ICI).If it does, can
Include soil release polymer with the level of 0.01 to 10 wt.% based on the total amount in laundry composition.Soil release polymer it is other
Example be terephthalic acid/diol copolymer, with trade name Texcare, Repel-o-tex, Gerol, Marloquest,
Cirrasol is sold.
Hydrotropic agent
It can be hindered if it is the form of liquid then liquid detergent composition can include optionally hydrotropic agent
Only Formation of liquid crystals.Therefore, hydrotropic add contributes to the clarification of composition/transparent.Suitable hydrotropic agent includes
But it is not limited to propylene glycol, ethyl alcohol, glycerine, urea, benzene sulfonate, toluene fulfonate, xylenesulfonate or cumene sulfonate.Properly
Salt include but not limited to sodium, potassium, ammonium, monoethanolamine, triethanolamine.Sulfonate may be considered as defined herein
Anion surfactant.Preferably, hydrotropic agent is selected from propylene glycol, xylenesulfonate, ethyl alcohol and urea to provide most
Best performance.Hydrotropic amount is usually 0 to 30%, preferably 0.5 to 30%, more preferable 0.5 to 30%, most preferably 1 to 15%.
Enzyme
Enzyme can also exist in preparation.Preferred enzyme includes protease, lipase, pectin lyase, amylase, cutin
Enzyme, cellulase, mannase.If it does, known enzyme stabilizers can be used, such as boric acid makes the enzyme stablize.
Embodiment
Following base formulation A-F is prepared, and is shown in Table 1.These show with across a series of component
The composition of horizontal and ratio surfactant system.
Table 1
A | B | C | D | E | F | |
Neodol 25-7 | 6.28 | 2.51 | 12.52 | 7.63 | 18.76 | 11.28 |
LAS acid | 13.04 | 5.16 | 8.52 | 5.07 | 4.31 | 2.87 |
SLES 3EO | 8.71 | 3.57 | 6.01 | 3.56 | 3.01 | 1.39 |
Propylene glycol | 15.00 | 15.00 | 15.00 | 15.00 | 15.00 | 15.00 |
Aliphatic acid | 2.51 | 1.00 | 2.51 | 1.51 | 2.00 | 1.51 |
Cationic polymer (LR400) | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
Triethanolamine | 2.44 | 0.80 | 2.52 | 1.53 | 2.53 | 1.49 |
Aromatic | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 |
Proxel GXL | 0.11 | 0.11 | 0.11 | 0.11 | 0.11 | 0.11 |
Reactive polysiloxanes | 1 | 1 | 1 | 1 | 1 | 1 |
NaOH (to pH) | 8-8.5 | 8-8.5 | 8-8.5 | 8-8.5 | 8-8.5 | 8-8.5 |
Water | To 100 | To 100 | To 100 | To 100 | To 100 | To 100 |
The method for preparing preparation
In environment temperature (about 22oC under), using Janke & Kunkel IKA RW20 overhead type stirrers with 150 rpm
Shear rate water and hydrotropic agent are mixed 2-3 minutes.Before addition surfactant and aliphatic acid, addition
Salt and alkali matter (alkalis) and mix 5 minutes.Slight heat release will be shown in the azeotropic mixture.It is allowing to cool to<
After 30 °C, cationic polymer (LR400 added as an aqueous solution) solution and any remaining ingredient, such as fragrance are added
Agent, preservative, dyestuff and polysiloxanes.The polysiloxanes is added with 1 wt.%, and it is added in the form of an emulsion.
Test 4 kinds of polysiloxanes, the PDMS and 3 kinds of anion polysiloxanes from Shin-Etsu of a kind of standard:
· 100Cst PDMS (‘X’)
The intermediate modified carboxyl polysiloxanes of X22-3710E (1)-chain has vertical or pendant in the poly- silicon of master
The carboxyl of oxygen alkane skeleton
X22-162C (' Y ')-both-end carboxyl polysiloxanes has and holds position in each of main silicone matrix
The carboxyl at place
X22-3710 (' Z ')-monofocal end carboxyl polysiloxanes has one in main silicone matrix
Hold the carboxyl at position
Polysiloxanes 1 is according to the present invention, and polysiloxanes X, Y and Z are as a comparison.
Stability/turbid mixed measurement
4 kinds of polysiloxanes are prepared in each in 6 kinds of preparations (A-F).Fetch from the sample of each preparation and by its
1cm cuvettes are added to, and are measured by UV-Vis, are taken the reading at 500nm.The UV-Vis measurements provide the turbid of product
Mixed level.Lower reading shows less turbid mixed.
Table 2
Preparation | Polysiloxanes X | Polysiloxanes 1 | Polysiloxanes Y | Polysiloxanes Z |
A | 0.574 | 0.067 | 0.218 | It is unstable |
B | 1.346 | 0.074 | 1.283 | It is unstable |
C | 0.817 | 0.058 | 0.475 | It is unstable |
D | 1.630 | 0.038 | 1.813 | It is unstable |
E | 0.903 | 0.025 | 0.490 | It is unstable |
F | 1.715 | 0.434 | 1.661 | It is unstable |
From in table 2 as a result, can be clearly seen compared to non-anion polysiloxanes (polysiloxanes X) and with end the moon
The anion polysiloxane (polysiloxanes Y and Z) of ionic group, by anion substituent functionalization among chain and in addition not
Including the anion polysiloxane (polysiloxanes 1) of terminal anionic polysiloxane group reduce turbid mixed aspect show it is best
Stability.
Claims (23)
1. liquid laundry detergent compositions, it includes:
(a) 5 to 40wt.% surfactant;
(b) 0.05 to 5wt.% fabric-softening anion polysiloxane;With
(c) 0.05 to 2.5wt.% cationic polymer,
One or more anionic groups wherein on fabric-softening anion polysiloxane are located at away from the poly- silicon of longest straight chain
End position at least five Si atoms on oxygen alkane chain;With
Wherein liquid detergent composition has 6 to 10 pH.
2. composition according to claim 1, wherein the anion polysiloxane is with 1,000 to 100,000 point
Son amount;And/or the anion polysiloxane has at least anionic group content of 1mol%.
3. composition according to claim 2, wherein the anion polysiloxane has 2,000 to 50,000 molecule
Amount.
4. composition according to claim 2, wherein the anion polysiloxane has 5,000 to 50,000 molecule
Amount.
5. composition according to claim 2, wherein the anion polysiloxane is with 10,000 to 50,000 point
Son amount.
6. composition according to claim 2, wherein the anion polysiloxane has at least anion of 2mol%
Group content.
7. according to claim 1-6 any one of them compositions, wherein the anion polysiloxane includes the poly- silica of carboxyl
Alkane.
8. according to claim 1-6 any one of them compositions, wherein the polysiloxanes is added in the form of an emulsion
Preparation.
9. according to claim 1-6 any one of them compositions, wherein by the polysiloxanes in the form of non-ionic emulsion
It is added to preparation.
10. according to claim 1-6 any one of them compositions, wherein the polysiloxanes is emulsified using branched nonionic
Agent is added to preparation.
11. according to claim 1-6 any one of them compositions, wherein the pH of the liquid detergent composition is pH 6.5
To 9.5.
12. according to claim 1-6 any one of them compositions, wherein the pH of the liquid detergent composition be pH 7 to
9。
13. according to claim 1-6 any one of them compositions, wherein the pH of the liquid detergent composition is pH 7.5
To 8.5.
14. according to claim 1-6 any one of them compositions, wherein the cationic polymer with 0.1 to 2wt.%'s
Level exists;And the anion polysiloxane exists with 0.1 to 2.5wt.% level.
15. composition according to claim 14, wherein the cationic polymer exists with 0.1 to 1wt.% level.
16. composition according to claim 14, wherein the cationic polymer exists with 0.1 to 0.75wt.% level.
17. composition according to claim 14, wherein the anion polysiloxane exists with 0.1 to 2wt.% level.
18. according to claim 1-6 any one of them compositions, wherein the cationic polymer polymerize for cationic polysaccharide
Object.
19. according to claim 1-6 any one of them compositions, wherein the cationic polymer is cation guar gum
And/or cationic cellulose polymer.
20. composition according to claim 18, wherein the Cationic polysaccharide polymer polymerize for cationic cellulose
Object.
21. composition according to claim 18, wherein the Cationic polysaccharide polymer is that quaternized ethoxy is fine
Dimension element.
22. according to claim 1-6 any one of them compositions, wherein the composition further include selected from aliphatic acid or
Its salt, dope dye, enzyme, antiredeposition polymer, dye transfer inhibiting polymers, builder, chelating agent, opacifier, fluorescence
Agent, aromatic and/or soil release polymer ingredient.
23. according to the composition of any one of claim 1 to 22 for the purposes of softening fabrics.
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PL3580318T3 (en) | 2017-02-13 | 2023-10-02 | Unilever Ip Holdings B.V. | Method of delivering a laundry composition |
WO2018146256A1 (en) * | 2017-02-13 | 2018-08-16 | Unilever Plc | Use of a silicone in a laundry composition |
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- 2014-11-12 BR BR112016011675-5A patent/BR112016011675B1/en active IP Right Grant
- 2014-11-12 WO PCT/EP2014/074345 patent/WO2015078692A1/en active Application Filing
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CN101939406A (en) * | 2008-02-05 | 2011-01-05 | 株式会社资生堂 | Cleansing composition |
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EP3074495B1 (en) | 2017-07-05 |
WO2015078692A1 (en) | 2015-06-04 |
CL2016001186A1 (en) | 2016-10-14 |
ES2642141T3 (en) | 2017-11-15 |
CN105745314A (en) | 2016-07-06 |
EP3074495A1 (en) | 2016-10-05 |
BR112016011675A2 (en) | 2017-08-08 |
BR112016011675B1 (en) | 2021-11-30 |
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