CN107057140A - A kind of function protective gear material being used in sports field and preparation method thereof - Google Patents
A kind of function protective gear material being used in sports field and preparation method thereof Download PDFInfo
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- CN107057140A CN107057140A CN201710348531.3A CN201710348531A CN107057140A CN 107057140 A CN107057140 A CN 107057140A CN 201710348531 A CN201710348531 A CN 201710348531A CN 107057140 A CN107057140 A CN 107057140A
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- protective gear
- sports field
- gear material
- carbon black
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of function protective gear material being used in sports field and preparation method thereof, belong to protective gear material technical field.A kind of function protective gear material being used in sports field that the present invention is provided, is made up of the raw material of following percentage by weight:Nitrile rubber 30 45%, natural rubber 15 25%, polyvinyl chloride 15 25%, tourmaline 0.5 3%, germanite 0.5 2%, six ring stones 0.5 3%, green longevity stone 0.5 3%, zinc oxide 2 5%, sulphur 0.5 5%, high wear-resistant carbon black 2 6%, white carbon 10 20%, accelerator 1 3%, age resistor 1 3%, glass fibre 2 6%.Provided by the present invention for the function protective gear material in sports field, the demand of mechanical property can not only be met, and wearability, heat resistance, chemical stability, anti ageing property are good, while it is bad that blood can be promoted to follow, with permanent negative ion generating function.
Description
Technical field
The invention belongs to protective gear material technical field, a kind of function protector material being used in sports field is more particularly related to
Material and preparation method thereof.
Background technology
Chinese invention patent (CN 102558740B) discloses a kind of function protective gear material being used in sports field, should
Invention is achieved by following technical proposals, and the component mass percent of raw material is, protector master batch 10~30%, SBS surpluses;
Described protector master batch, the component mass percent of its raw material is, nanometer radium 1~3%, tourmaline 5~10%, the oxygen of nanoscale three
Change two antimony 0.5~1.5%, chitin 10~20%, Nano Silver 1.5~3.5%, nano modified bamboo charcoal 2.5~4.5%, more than SBS
Amount.Though the function protective gear material can play certain positive role to health, it is as protective gear material in motion
Protective action when using is unsatisfactory, and service life is not also permanent.
The content of the invention
, can it is an object of the invention to provide a kind of function protective gear material being used in sports field and preparation method thereof
Improve material protection effect and service life.
The present invention is achieved in that a kind of function protective gear material being used in sports field, by following percentage by weight
Raw material be made:Nitrile rubber 30-45%, natural rubber 15-25%, polyvinyl chloride 15-25%, tourmaline 0.5-3%, germanite
0.5-2%, six ring stone 0.5-3%, green longevity stone 0.5-3%, zinc oxide 2-5%, sulphur 0.5-5%, high wear-resistant carbon black 2-6%,
White carbon 10-20%, accelerator 1-3%, age resistor 1-3%, glass fibre 2-6%.
Further, the accelerator is the mixture of altax and acceterator TE, altax therein and accelerator
TE weight ratio is 4:3.
Further, the age resistor is the mixture of antioxidant 4010 and anti-aging agent RD, antioxidant 4010 therein and anti-
Old agent RD weight ratio is 3:2.
Further, the high wear-resistant carbon black is high abrasion furnace carbon black N330.
Further, the tourmaline, germanite, six ring stones, the size controlling of green longevity stone are in 50-100nm.
Present invention also offers a kind of preparation method of the above-mentioned function protective gear material being used in sports field, step is such as
Under:
Polyvinyl chloride and nitrile rubber are placed and carry out heating premixing at 150 DEG C in the heater, 55 are subsequently cooled to
DEG C, natural rubber is added, after being well mixed, is transferred on banbury and is kneaded 3 minutes in 90-105 DEG C, sulphur, oxidation is added
Zinc, white carbon are kneaded 3 minutes, are then added high wear-resistant carbon black, tourmaline, germanite, six ring stones, green longevity stone, glass fibre and are mixed
Refining 5 minutes;The material kneaded is placed in the heater, accelerator, age resistor is then added, mixes and adds at 80-90 DEG C
After hot 50-120 minutes, it is made into after sizing material, is produced after injection mould molding.
Relative to prior art, the present invention has the advantages that:
Provided by the present invention for the function protective gear material in sports field, the demand of mechanical property can not only be met,
And wearability, heat resistance, chemical stability, anti ageing property are good, while it is bad that blood can be promoted to follow, with it is permanent bear from
Sub- generating function.
Embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that described reality
It is only a part of embodiment of the invention to apply example, rather than whole embodiments.Based on the embodiment in the present invention, this area is general
The every other embodiment that logical technical staff is obtained under the premise of creative work is not made, belongs to what the present invention was protected
Scope.
A kind of function protective gear material being used in sports field provided in an embodiment of the present invention, by following percentage by weight
Raw material is made:Nitrile rubber 30-45%, natural rubber 15-25%, polyvinyl chloride 15-25%, tourmaline 0.5-3%, germanite
0.5-2%, six ring stone 0.5-3%, green longevity stone 0.5-3%, zinc oxide 2-5%, sulphur 0.5-5%, high wear-resistant carbon black 2-6%,
White carbon 10-20%, accelerator 1-3%, age resistor 1-3%, glass fibre 2-6%.
In embodiments of the present invention, accelerator is the mixture of altax and acceterator TE, altax therein and
The weight ratio of acceterator TE is 4:3.
In embodiments of the present invention, age resistor is the mixture of antioxidant 4010 and anti-aging agent RD, age resistor therein
4010 and anti-aging agent RD weight ratio be 3:2.
In embodiments of the present invention, high wear-resistant carbon black is high abrasion furnace carbon black N330.
In embodiments of the present invention, tourmaline, germanite, six ring stones, the size controlling of green longevity stone are in 50-100nm.
The preparation method of the above-mentioned function protective gear material being used in sports field provided in an embodiment of the present invention, step is such as
Under:
Polyvinyl chloride and nitrile rubber are placed and carry out heating premixing at 150 DEG C in the heater, 55 are subsequently cooled to
DEG C, natural rubber is added, after being well mixed, is transferred on banbury and is kneaded 3 minutes in 90-105 DEG C, sulphur, oxidation is added
Zinc, white carbon are kneaded 3 minutes, are then added high wear-resistant carbon black, tourmaline, germanite, six ring stones, green longevity stone, glass fibre and are mixed
Refining 5 minutes;The material kneaded is placed in the heater, accelerator, age resistor is then added, mixes and adds at 80-90 DEG C
After hot 50-120 minutes, it is made into after sizing material, is produced after injection mould molding.
The present invention is to provide preferable high temperature degradation resistance, water resistance, Yi Jiyou for product using the purpose of nitrile rubber
Good adhesive property.Polyvinylchloride used, is white powder, nontoxic, odorless is applied in the protector material in raw material of the present invention
In material, high chemical stability (such as acidproof, alkaline-resisting, salt tolerant) and good plasticity and resistance to ag(e)ing is resulted in, at this
Universal polyvinyl chloride resin is preferably used in inventive embodiments.The use of the purpose of natural rubber carried for product in the protective gear material
For good elastic, anti-skidding and water resistance.Natural rubber is divided into standard rubber, rubber smoked sheet, concentration glue, white crepe, the clear rubber of glue
Glue and air-dried rubber sheet etc., most commonly standard rubber and rubber smoked sheet.These all can be used for the present invention.The present invention is by butyronitrile rubber
Glue, natural rubber are used together with PVC to be used in protective gear material, as the material of main part of protective gear material, in the heat-resisting of product
Property, wearability, chemical stability and elasticity aspect reached needs.Meanwhile, enhancing is used as using glass fibre in the protective gear material
Phase, it is possible to increase the mechanical property and heat aging performance of material.And by adding suitable accelerator, age resistor, sulphur etc.
Heat resistance, resistance to ag(e)ing, impact resistance, the elasticity of material are further increased, bradyseism effect is improved, so as to preferably be used as
Protective gear material is protected.High abrasion furnace carbon black N330 used is that a kind of reinforcing property is good in the raw material of protective gear material of the present invention
Carbon black, the preferable strength and extension property of sizing material, tear resistance, wearability and elasticity can be assigned.Added in protective gear material of the present invention
Altax, it is possible to increase nitrile rubber, natural rubber resistance to ag(e)ing, adds acceterator TE, had not only made accelerator but also made vulcanizing agent,
In addition, the anti-incipient scorch of acceterator TE is excellent, process safety.Anti-aging agent RD, it is splendid to aging protection effect caused by heat and oxygen, but
It is poor to flexion aging protection effect, and antioxidant 4010 has protective action to empty air and heat and flexion aging, can make up anti-
Old agent RD deficiency.Therefore, anti-aging agent RD and antioxidant 4010 are used in combination, have splendid anti-to empty air and heat and flexion aging
Shield is acted on, in addition, antioxidant 4010 also has the effect of curing agent.Tourmaline, germanium have been used in the raw material of protective gear material of the present invention
Stone, six ring stones and green longevity stone, tourmaline therein have multiple efficacies, can promote and improve blood circulation.Germanite contains someone
More than the 30 kinds of trace elements beneficial to human body, the startup ripple that these elements are distributed such as selenium, zinc, nickel, cobalt, manganese, magnesium, calcium needed for body
Startup ripple with human body cell is same fluctuation status, and human body cell is as the fluctuation given out from germanite is empathized and is total to
Shake, make human cell tissue more vigor, and promote blood to follow bad, enhancing metabolism and enter to exclude bodily waste.Germanium can make
Drinking Water and Natural Water become active water, help human body to improve immunity.Six ring stones are the condensates with four big energy,
Six ring stones can be emitting far-infrared, and being capable of forever generating negative ions, and six ring stones contain micro- " germanium " and human body
The nutrients such as required calcium, magnesium, sodium, potassium, iron, selenium, zinc, while six ring stones can produce biological electricity, it, which has, promotes blood
Circulation, improves microcirculating state, enhancing and improvement body immunity, dispelling fatigue, eliminates nervous function.The green longevity used
Stone has bioactivity, can improve the effect of the physiological function and bidirectional modulation acid-base value of body, it may have anion and remote red
Outer emission function.
In summary, provided by the present invention for the function protective gear material in sports field, mechanical property can not only be met
The demand of energy, and wearability, heat resistance, chemical stability, anti ageing property are good, while it is bad that blood can be promoted to follow, have
Permanent negative ion generating function.
With reference to specific embodiment, the invention will be further described:
Embodiment 1
A kind of function protective gear material being used in sports field, is made up of the raw material of following percentage by weight:Nitrile rubber
32%th, natural rubber 18%, polyvinyl chloride 16%, tourmaline 1%, germanite 1%, six ring stones 1%, green longevity stone 1%, zinc oxide
3%th, sulphur 2%, high wear-resistant carbon black 5%, white carbon 12%, accelerator 2%, age resistor 2%, glass fibre 4%.
Accelerator used is altax and acceterator TE according to weight ratio 4:The mixtures of 3 compositions, age resistor used is
Antioxidant 4010 and anti-aging agent RD are according to weight ratio 3:The mixture of 2 compositions, further, high wear-resistant carbon black used are high abrasion charcoal
Black N330.Tourmaline, germanite, six ring stones, the size controlling of green longevity stone are in 50-100nm.
The above-mentioned function protective gear material being used in sports field is prepared as follows:
Polyvinyl chloride and nitrile rubber are placed and carry out heating premixing at 150 DEG C in the heater, 55 are subsequently cooled to
DEG C, add natural rubber, be well mixed after, be transferred on banbury in 100 DEG C knead 3 minutes, add sulphur, zinc oxide,
White carbon is kneaded 3 minutes, then adds high wear-resistant carbon black, tourmaline, germanite, six ring stones, green longevity stone, glass fibre mixing 5
Minute;The material kneaded is placed in the heater, accelerator, age resistor is then added, 80 points of heating is mixed at 80 DEG C
Zhong Hou, is made into after sizing material, is produced after injection mould molding.
Embodiment 2
A kind of function protective gear material being used in sports field, is made up of the raw material of following percentage by weight:Nitrile rubber
40%th, natural rubber 15%, polyvinyl chloride 15%, tourmaline 0.5%, germanite 0.5%, six ring stones 0.5%, green longevity stone 0.5%,
Zinc oxide 2%, sulphur 5%, high wear-resistant carbon black 6%, white carbon 10%, accelerator 1%, age resistor 1%, glass fibre 3%.
Accelerator used is altax and acceterator TE according to weight ratio 4:The mixtures of 3 compositions, age resistor used is
Antioxidant 4010 and anti-aging agent RD are according to weight ratio 3:The mixture of 2 compositions, further, high wear-resistant carbon black used are high abrasion charcoal
Black N330.Tourmaline, germanite, six ring stones, the size controlling of green longevity stone are in 50-100nm.
The above-mentioned function protective gear material being used in sports field is prepared as follows:
Polyvinyl chloride and nitrile rubber are placed and carry out heating premixing at 150 DEG C in the heater, 55 are subsequently cooled to
DEG C, natural rubber is added, after being well mixed, is transferred on banbury and is kneaded 3 minutes in 90 DEG C, sulphur is added, zinc oxide, white
Carbon black is kneaded 3 minutes, is then added high wear-resistant carbon black, tourmaline, germanite, six ring stones, green longevity stone, glass fibre and is kneaded 5 points
Clock;The material kneaded is placed in the heater, accelerator, age resistor is then added, heating 60 minutes is mixed at 90 DEG C
Afterwards, it is made into after sizing material, is produced after injection mould molding.
Embodiment 3
A kind of function protective gear material being used in sports field, is made up of the raw material of following percentage by weight:Nitrile rubber
30%th, natural rubber 15.5%, polyvinyl chloride 20%, tourmaline 1.5%, germanite 1.5%, six ring stones 1.5%%, green longevity stone
1.5%%th, zinc oxide 2.5%, sulphur 1%, high wear-resistant carbon black 2%, white carbon 15%, accelerator 3%, age resistor 3%, glass
Fiber 2%.
Accelerator used is altax and acceterator TE according to weight ratio 4:The mixtures of 3 compositions, age resistor used is
Antioxidant 4010 and anti-aging agent RD are according to weight ratio 3:The mixture of 2 compositions, further, high wear-resistant carbon black used are high abrasion charcoal
Black N330.Tourmaline, germanite, six ring stones, the size controlling of green longevity stone are in 50-100nm.
The above-mentioned function protective gear material being used in sports field is prepared as follows:
Polyvinyl chloride and nitrile rubber are placed and carry out heating premixing at 150 DEG C in the heater, 55 are subsequently cooled to
DEG C, add natural rubber, be well mixed after, be transferred on banbury in 105 DEG C knead 3 minutes, add sulphur, zinc oxide,
White carbon is kneaded 3 minutes, then adds high wear-resistant carbon black, tourmaline, germanite, six ring stones, green longevity stone, glass fibre mixing 5
Minute;The material kneaded is placed in the heater, accelerator, age resistor is then added, 90 points of heating is mixed at 80 DEG C
Zhong Hou, is made into after sizing material, is produced after injection mould molding.
Embodiment 4
A kind of function protective gear material being used in sports field, is made up of the raw material of following percentage by weight:Nitrile rubber
41%th, natural rubber 15%, polyvinyl chloride 18%, tourmaline 2%, germanite 0.5%, six ring stones 1%, green longevity stone 0.5%, oxidation
Zinc 2%, sulphur 2%, high wear-resistant carbon black 2%, white carbon 12%, accelerator 1%, age resistor 1%, glass fibre 2%.
Accelerator used is altax and acceterator TE according to weight ratio 4:The mixtures of 3 compositions, age resistor used is
Antioxidant 4010 and anti-aging agent RD are according to weight ratio 3:The mixture of 2 compositions, further, high wear-resistant carbon black used are high abrasion charcoal
Black N330.Tourmaline, germanite, six ring stones, the size controlling of green longevity stone are in 50-100nm.
The above-mentioned function protective gear material being used in sports field is prepared as follows:
Polyvinyl chloride and nitrile rubber are placed and carry out heating premixing at 150 DEG C in the heater, 55 are subsequently cooled to
DEG C, natural rubber is added, after being well mixed, is transferred on banbury and is kneaded 3 minutes in 90 DEG C, sulphur is added, zinc oxide, white
Carbon black is kneaded 3 minutes, is then added high wear-resistant carbon black, tourmaline, germanite, six ring stones, green longevity stone, glass fibre and is kneaded 5 points
Clock;The material kneaded is placed in the heater, accelerator, age resistor is then added, heating 70 minutes is mixed at 85 DEG C
Afterwards, it is made into after sizing material, is produced after injection mould molding.
Embodiment 5
A kind of function protective gear material being used in sports field, is made up of the raw material of following percentage by weight:Nitrile rubber
35%th, natural rubber 19%, polyvinyl chloride 15%, tourmaline 1%, germanite 1.5%, six ring stones 2%, green longevity stone 0.5%, oxidation
Zinc 3%, sulphur 2%, high wear-resistant carbon black 3%, white carbon 10%, accelerator 1%, age resistor 1%, glass fibre 6%.
Accelerator used is altax and acceterator TE according to weight ratio 4:The mixtures of 3 compositions, age resistor used is
Antioxidant 4010 and anti-aging agent RD are according to weight ratio 3:The mixture of 2 compositions, further, high wear-resistant carbon black used are high abrasion charcoal
Black N330.Tourmaline, germanite, six ring stones, the size controlling of green longevity stone are in 50-100nm.
The above-mentioned function protective gear material being used in sports field is prepared as follows:
Polyvinyl chloride and nitrile rubber are placed and carry out heating premixing at 150 DEG C in the heater, 55 are subsequently cooled to
DEG C, add natural rubber, be well mixed after, be transferred on banbury in 102 DEG C knead 3 minutes, add sulphur, zinc oxide,
White carbon is kneaded 3 minutes, then adds high wear-resistant carbon black, tourmaline, germanite, six ring stones, green longevity stone, glass fibre mixing 5
Minute;The material kneaded is placed in the heater, accelerator, age resistor is then added, 50 points of heating is mixed at 90 DEG C
Zhong Hou, is made into after sizing material, is produced after injection mould molding.
Present invention also offers a kind of preparation method of the above-mentioned function protective gear material being used in sports field, step is such as
Under:
Polyvinyl chloride and nitrile rubber are placed and carry out heating premixing at 150 DEG C in the heater, 55 are subsequently cooled to
DEG C, natural rubber is added, after being well mixed, is transferred on banbury and is kneaded 3 minutes in 90-105 DEG C, sulphur, oxidation is added
Zinc, white carbon are kneaded 3 minutes, are then added high wear-resistant carbon black, tourmaline, germanite, six ring stones, green longevity stone, glass fibre and are mixed
Refining 5 minutes;The material kneaded is placed in the heater, accelerator, age resistor is then added, mixes and adds at 80-90 DEG C
After hot 50-120 minutes, it is made into after sizing material, is produced after injection mould molding.
, but those skilled in the art once know basic creation although preferred embodiments of the present invention have been described
Property concept, then can make other change and modification to these embodiments.So, appended claims are intended to be construed to include excellent
Select embodiment and fall into having altered and changing for the scope of the invention.
Obviously, those skilled in the art can carry out the essence of various changes and modification without departing from the present invention to the present invention
God and scope.So, if these modifications and variations of the present invention belong to the scope of the claims in the present invention and its equivalent technologies
Within, then the present invention is also intended to comprising including these changes and modification.
Claims (6)
1. a kind of function protective gear material being used in sports field, it is characterised in that be made up of the raw material of following percentage by weight:
Nitrile rubber 30-45%, natural rubber 15-25%, polyvinyl chloride 15-25%, tourmaline 0.5-3%, germanite 0.5-2%, six
Ring stone 0.5-3%, green longevity stone 0.5-3%, zinc oxide 2-5%, sulphur 0.5-5%, high wear-resistant carbon black 2-6%, white carbon 10-
20%th, accelerator 1-3%, age resistor 1-3%, glass fibre 2-6%.
2. a kind of function protective gear material being used in sports field as claimed in claim 1, it is characterised in that the accelerator
For altax and the mixture of acceterator TE, the weight ratio of altax and acceterator TE therein is 4:3.
3. a kind of function protective gear material being used in sports field as claimed in claim 1, it is characterised in that the age resistor
For antioxidant 4010 and the mixture of anti-aging agent RD, the weight ratio of antioxidant 4010 and anti-aging agent RD therein is 3:2.
4. a kind of function protective gear material being used in sports field as claimed in claim 1, it is characterised in that the high abrasion
Carbon black is high abrasion furnace carbon black N330.
5. a kind of function protective gear material being used in sports field as claimed in claim 1, it is characterised in that described electric
Stone, germanite, six ring stones, the size controlling of green longevity stone are in 50-100nm.
6. a kind of preparation method for preparing any function protective gear materials being used in sports field of claim 1-5, it is special
Levy and be, step is as follows:
Polyvinyl chloride and nitrile rubber are placed and carry out heating premixings at 150 DEG C in the heater, 55 DEG C are subsequently cooled to, plus
Enter natural rubber, after being well mixed, be transferred on banbury and kneaded 3 minutes in 90-105 DEG C, add sulphur, zinc oxide, white
Carbon black is kneaded 3 minutes, is then added high wear-resistant carbon black, tourmaline, germanite, six ring stones, green longevity stone, glass fibre and is kneaded 5 points
Clock;The material kneaded is placed in the heater, accelerator, age resistor is then added, heating 50- is mixed at 80-90 DEG C
After 120 minutes, it is made into after sizing material, is produced after injection mould molding.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110951131A (en) * | 2019-10-21 | 2020-04-03 | 盐城市艾斯特体育器材有限公司 | Preparation method of protective clothing material for skating training |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105670056A (en) * | 2016-04-11 | 2016-06-15 | 泉州盛达轻工有限公司 | High-strength low-temperature-resistant material for shoes and preparation method of high-strength low-temperature-resistant material |
CN105918351A (en) * | 2016-05-11 | 2016-09-07 | 沈平 | Nano anion function material and preparing method thereof |
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2017
- 2017-05-17 CN CN201710348531.3A patent/CN107057140B/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105670056A (en) * | 2016-04-11 | 2016-06-15 | 泉州盛达轻工有限公司 | High-strength low-temperature-resistant material for shoes and preparation method of high-strength low-temperature-resistant material |
CN105918351A (en) * | 2016-05-11 | 2016-09-07 | 沈平 | Nano anion function material and preparing method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110951131A (en) * | 2019-10-21 | 2020-04-03 | 盐城市艾斯特体育器材有限公司 | Preparation method of protective clothing material for skating training |
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