CN107056116B - Cinnabar artware raw material powder and preparation method thereof - Google Patents
Cinnabar artware raw material powder and preparation method thereof Download PDFInfo
- Publication number
- CN107056116B CN107056116B CN201710322746.8A CN201710322746A CN107056116B CN 107056116 B CN107056116 B CN 107056116B CN 201710322746 A CN201710322746 A CN 201710322746A CN 107056116 B CN107056116 B CN 107056116B
- Authority
- CN
- China
- Prior art keywords
- cinnabar
- powder
- raw material
- artware
- mesh sieve
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052956 cinnabar Inorganic materials 0.000 title claims abstract description 91
- 239000000843 powder Substances 0.000 title claims abstract description 74
- 239000002994 raw material Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000007873 sieving Methods 0.000 claims description 12
- 239000008187 granular material Substances 0.000 claims description 11
- 238000010298 pulverizing process Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 7
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims 2
- 239000002932 luster Substances 0.000 abstract description 14
- 239000000126 substance Substances 0.000 abstract description 9
- 241000220317 Rosa Species 0.000 abstract description 7
- 239000002184 metal Substances 0.000 abstract description 7
- 229910052751 metal Inorganic materials 0.000 abstract description 7
- 238000012360 testing method Methods 0.000 description 7
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- QXKXDIKCIPXUPL-UHFFFAOYSA-N sulfanylidenemercury Chemical compound [Hg]=S QXKXDIKCIPXUPL-UHFFFAOYSA-N 0.000 description 1
- 230000002936 tranquilizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
- C04B40/0042—Powdery mixtures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/54—Pigments; Dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention provides cinnabar artware raw material powder and a preparation method thereof, wherein the cinnabar artware raw material powder consists of 92-97% of cinnabar powder and 3-8% of nano copper powder, is very stable in chemical property, has rose color and metal reflective luster, is bright in color and exquisite in texture, and is very suitable for being used as a cinnabar artware raw material.
Description
Technical Field
The invention belongs to the technical field of chemical industry, and particularly relates to cinnabar artware raw material powder and a preparation method thereof.
Background
Cinnabar, namely mercury sulfide, chemical name: HgS; cinnabar, also known as cinnabar, red lead and mercurous chloride, is a natural ore of mercurous sulfide, is bright red, has diamond luster to metallic luster, and belongs to the trigonal system. In the heart of Chinese people, red represents solemn weight, symbolizes the right, and has the effects of calming the nerves and tranquilizing and helping sleep, so that the cinnabar artware is deeply popular with consumers, such as cinnabar bracelets, cinnabar pendants, cinnabar stamps and the like. However, due to the lack of a sufficient scientific research basis, the color, luster and reproducibility of the inkpad prepared from the cinnabar powder are not ideal enough, and the inkpad is unstable in chemical property, easy to change color and lose luster after being stored for a long time; directly influences the beauty and the grade of the cinnabar artware.
Disclosure of Invention
In order to solve the problems, the cinnabar artware raw material powder and the preparation method thereof provided by the invention comprise cinnabar powder and nano copper powder, and the cinnabar artware raw material powder is very stable in chemical property, has rose color and metal reflective luster, bright color, clear print and fine texture, and is very suitable for being used as a cinnabar artware raw material.
Specifically, the invention provides cinnabar artware raw material powder which consists of 92-97% of cinnabar powder and 3-8% of nano copper powder.
The cinnabar powder is fine powder which is sieved by a 150-mesh sieve but not sieved by a 220-mesh sieve.
Further, cinnabar artware raw material powder consists of 94% of cinnabar powder and 6% of nano copper powder.
The cinnabar powder is fine powder which is sieved by a 180-mesh sieve but not sieved by a 200-mesh sieve.
A preparation method of cinnabar artware raw material powder comprises the following steps:
(1) cleaning Cinnabaris with water, pulverizing into granule, soaking in 30-40% sodium sulfide solution for 1-3 hr, filtering, drying Cinnabaris granule, pulverizing in pulverizer, sieving, collecting and sieving with 150 mesh sieve, and sieving with 220 mesh sieve to obtain Cinnabaris powder.
(2) And (3) uniformly mixing the cinnabar powder prepared in the step (1) with the nano copper powder to obtain cinnabar artware raw material powder.
Further: a preparation method of cinnabar artware raw material powder comprises the following steps:
(1) cleaning cinnabar with water, pulverizing into granules, soaking in 35% sodium sulfide solution for 2h, filtering, drying cinnabar granules, pulverizing in a pulverizer, sieving, collecting fine powder of 180 mesh sieve instead of 200 mesh sieve to obtain Cinnabaris powder, and keeping.
(2) And (3) uniformly mixing the cinnabar powder prepared in the step (1) with the nano copper powder to obtain cinnabar artware raw material powder.
The invention has the beneficial effects that:
through years of experience and research on the preparation of cinnabar artware, the cinnabar is 220 meshes, and the prepared artware has excellent color and luster, has rose color and metal reflective luster, and has less rose color, even brown color, dark black color and no metal luster, and cannot form obvious metal luster when being below 150 meshes compared with cinnabar powder with other meshes; above 220 meshes, the prepared artware is pink, even pale white and has no metallic luster, so that in order to ensure the color and quality of cinnabar, the cinnabar powder is preferably subdivided into 150 meshes and 220 meshes, and the prepared cinnabar artware is optimal, except that after the nano copper powder is added in the preparation process of the cinnabar powder, the chemical stability of the cinnabar powder can be obviously improved, and the prepared artware is very bright in color and high in grade.
The beneficial effects of the invention are investigated:
test group 1 is cinnabar artware raw material powder prepared by the invention.
Test group 2: is prepared by mixing 150-220-mesh cinnabar powder and 200-mesh copper powder.
Control group: pulverizing Cinnabaris into 160-220 mesh fine powder.
Carrying out an accelerated stability test under the following test conditions: under the conditions of 40 ℃ temperature and 75% relative humidity, the cover is opened and the storage is carried out for 6 months, and the examination is carried out after 6 months:
and (3) test results:
test group 1: the cinnabar artware raw material powder is bright red, has rose color and metal reflective luster, and has no obvious difference from the raw material powder before the test.
Test group 2: the cinnabar artware raw material powder is not strong in rose color, has slight dark brown color and is weak in metal luster.
Control group: the cinnabar artware raw material powder has weak rose color, even brown color, dark black color and no metallic luster.
Description of the drawings: according to the invention, after the copper powder is added in the preparation process of the cinnabar powder, the chemical stability of the cinnabar powder can be obviously improved, and the effect is optimal by adopting the nano copper powder, and the prepared nano copper powder can improve the specific surface area of the copper powder and activate copper simple substances, can passivate the cinnabar powder better, and can improve the chemical stability of cinnabar, so that a small amount of nano copper powder is preferably added in the preparation process of the cinnabar powder for protection.
The specific implementation mode is as follows:
example 1 preparation of raw powder of cinnabar artware
(1) Cleaning 92g of cinnabar with water, crushing into granular cinnabar, soaking in a 30% sodium sulfide solution for 1h, filtering, drying cinnabar granules, crushing in a crusher, sieving, collecting and sieving with a 150-mesh sieve, but not with a 220-mesh sieve to obtain cinnabar powder for later use.
(2) And (2) uniformly mixing the cinnabar powder prepared in the step (1) with 8g of nano copper powder to obtain cinnabar artware raw material powder.
Example 2 preparation of raw powder of cinnabar artware
(1) Cleaning 94g of cinnabar with water, crushing into granular cinnabar, soaking in 35% sodium sulfide solution for 2h, filtering, drying cinnabar granules, crushing in a crusher, sieving, collecting fine powder which is sieved by a 180-mesh sieve but not sieved by a 200-mesh sieve, and obtaining cinnabar powder for later use.
(2) And (2) uniformly mixing the cinnabar powder prepared in the step (1) with 6g of nano copper powder to obtain cinnabar artware raw material powder.
Example 3 preparation of raw powder of cinnabar artware
(1) 97g of cinnabar is cleaned by water, crushed into granular cinnabar, soaked in 40% sodium sulfide solution for 2 hours, filtered, dried, put into a crusher for crushing and sieving, and the cinnabar granules are collected and sieved by a 180-mesh sieve instead of a 200-mesh sieve to obtain cinnabar powder for later use.
(2) And (3) uniformly mixing the cinnabar powder prepared in the step (1) with 3g of nano copper powder to obtain cinnabar artware raw material powder.
Claims (5)
1. The raw material powder of the cinnabar artware is characterized in that: consists of 92-97% of cinnabar powder and 3-8% of nano copper powder;
the preparation method of the cinnabar artware raw material powder comprises the following steps:
(1) cleaning Cinnabaris with water, pulverizing into granule, soaking in 30-40% sodium sulfide solution for 1-3 hr, filtering, drying Cinnabaris granule, pulverizing in pulverizer, sieving, collecting and sieving with 150 mesh sieve, and sieving with 220 mesh sieve to obtain Cinnabaris powder;
(2) and (3) uniformly mixing the cinnabar powder prepared in the step (1) with the nano copper powder to obtain cinnabar artware raw material powder.
2. The raw material powder of cinnabar artware according to claim 1, characterized in that: consists of 94 percent of cinnabar powder and 6 percent of nano copper powder.
3. The raw material powder of cinnabar artware according to claim 1 or 2, characterized in that: the cinnabar powder is fine powder which is sieved by a 150-mesh sieve but not sieved by a 220-mesh sieve.
4. The raw material powder of cinnabar artware according to claim 1 or 2, characterized in that: the cinnabar powder is fine powder which is sieved by a 180-mesh sieve but not sieved by a 200-mesh sieve.
5. The method for preparing raw material powder of cinnabar artware according to claim 1, characterized in that: the method comprises the following steps:
(1) cleaning cinnabar with water, pulverizing into granules, soaking in 35% sodium sulfide solution for 2h, filtering, drying cinnabar granules, pulverizing in a pulverizer, sieving, collecting fine powder of 180 mesh sieve instead of 200 mesh sieve to obtain cinnabar powder;
(2) and (3) uniformly mixing the cinnabar powder prepared in the step (1) with the nano copper powder to obtain cinnabar artware raw material powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710322746.8A CN107056116B (en) | 2017-05-09 | 2017-05-09 | Cinnabar artware raw material powder and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710322746.8A CN107056116B (en) | 2017-05-09 | 2017-05-09 | Cinnabar artware raw material powder and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107056116A CN107056116A (en) | 2017-08-18 |
| CN107056116B true CN107056116B (en) | 2020-03-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710322746.8A Expired - Fee Related CN107056116B (en) | 2017-05-09 | 2017-05-09 | Cinnabar artware raw material powder and preparation method thereof |
Country Status (1)
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Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100745128B1 (en) * | 2005-11-03 | 2007-08-02 | 오이량 | Colored polymer paste and method for producing ornaments using the same |
| CN101885600B (en) * | 2010-07-21 | 2012-07-25 | 中南大学 | Heavy metal waste slag treatment method and sulfur building material prepared thereby |
| CN103204703B (en) * | 2013-02-04 | 2014-05-14 | 陕西师范大学 | Application of ZB-F600 two-component FEVE aqueous fluororesin in pretreatment of damage-prone pottery decorated with colored drawing before restoration |
| CN103270992B (en) * | 2013-06-20 | 2017-10-03 | 北海市源龙珍珠有限公司 | Rose-red color pearl growing method |
| CN104710573B (en) * | 2014-01-03 | 2017-07-07 | 南京爱特泰新材料科技有限公司 | A kind of preparation method of 3D printing material |
| CN104309394B (en) * | 2014-09-26 | 2017-08-01 | 厦门弼马温文化创意有限公司 | Art copper carves surface color processing method |
| KR101727373B1 (en) * | 2014-12-29 | 2017-04-17 | 서광윤 | Glaze composition for cinnabar china and method of manufacturing cinnabar china by using the same |
| CN105440775A (en) * | 2015-12-24 | 2016-03-30 | 青岛大方智慧网络科技有限公司 | Quick-dryinginkpad oil |
| CN106519793A (en) * | 2016-11-24 | 2017-03-22 | 无锡奔牛生物科技有限公司 | Nano-particle-size ink |
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| CN107056116A (en) | 2017-08-18 |
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Effective date of registration: 20200225 Address after: No. 2, floor 6, Daheng Daxia, No. 55, Hequn Road, Yunyan District, Guiyang City, Guizhou Province 550000 Applicant after: Guizhou Zhuxin Dachuang Technology Co., Ltd. Address before: 554200 standard economic development zone in Guizhou province Wanshan chemical plant Applicant before: Tongren testing center city wanshanqu Danfeng vermilion Crafts Development Co. Ltd. |
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