CN107056116A - A kind of cinnabar handicraft raw material powder and preparation method thereof - Google Patents
A kind of cinnabar handicraft raw material powder and preparation method thereof Download PDFInfo
- Publication number
- CN107056116A CN107056116A CN201710322746.8A CN201710322746A CN107056116A CN 107056116 A CN107056116 A CN 107056116A CN 201710322746 A CN201710322746 A CN 201710322746A CN 107056116 A CN107056116 A CN 107056116A
- Authority
- CN
- China
- Prior art keywords
- cinnabar
- raw material
- powder
- material powder
- handicraft raw
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052956 cinnabar Inorganic materials 0.000 title claims abstract description 103
- 239000000843 powder Substances 0.000 title claims abstract description 75
- 239000002994 raw material Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052802 copper Inorganic materials 0.000 claims abstract description 17
- 239000010949 copper Substances 0.000 claims abstract description 17
- 239000002105 nanoparticle Substances 0.000 claims abstract description 15
- 238000001035 drying Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 238000007873 sieving Methods 0.000 claims description 7
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 7
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 7
- 239000002184 metal Substances 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002932 luster Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 description 1
- 229910001573 adamantine Inorganic materials 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
- C04B40/0042—Powdery mixtures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/54—Pigments; Dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention provides a kind of cinnabar handicraft raw material powder and preparation method thereof, it is made up of 92 97% cinnabar powders, 3 8% copper nanoparticle, obtained cinnabar handicraft raw material powder chemical property is highly stable, with rosiness and metal reflective gloss, bright color, quality are fine and smooth, are especially suitable for being used as cinnabar handicraft raw material.
Description
Technical field
The invention belongs to chemical technology field, and in particular to a kind of cinnabar handicraft raw material powder and preparation method thereof.
Background technology
Cinnabar is mercuric sulphide, chemical name：HgS；Cinnabar is also known as cinnabar, cinnabar, Chi Dan, mercury sand, is the day of mercuric sulphide
Right ore, large red has adamantine luster to metallic luster, belongs to trigonal system.Red in the heart in Chinese represents serious, symbol
Right, and have calmness of calming the nerves, the effect conduced to sleep, therefore, cinnabar handicraft also firmly get liking for consumer, such as cinnabar
Bracelet, cinnabar pendant, cinnabar seal etc..But cinnabar powder is due to lacking sufficient scientific research basis, its ink paste color being made
Color and luster and reappearance are not ideal enough, and unstable chemcial property, preserve for a long time, and easily discoloration, tarnishes；Directly affect
The attractive in appearance and grade of cinnabar handicraft.
The content of the invention
To solve the above problems, the invention provides a kind of cinnabar handicraft raw material powder and preparation method thereof, by cinnabar powder,
Copper nanoparticle is constituted, and the cinnabar handicraft raw material powder chemical property is highly stable, with rosiness and metal reflective gloss, color and luster
Bright, trace is clear, and quality is fine and smooth, is especially suitable for being used as cinnabar handicraft raw material.
Specifically, the invention provides a kind of cinnabar handicraft raw material powder, by 92-97% cinnabar powders, 3-8% Nanometer Copper
Powder is constituted.
Described cinnabar powder was 150 mesh sieves, but 220 mesh sieve fine powders.
Further, a kind of cinnabar handicraft raw material powder, is made up of 94% cinnabar powder, 6% copper nanoparticle.
Described cinnabar powder was 180 mesh sieves, but 200 mesh sieve fine powders.
A kind of cinnabar handicraft raw material powder, preparation method thereof, comprises the following steps：
(1) take cinnabar to be cleaned up with water, be ground into graininess cinnabar, 1-3h is soaked with 30-40% sodium sulfide solution,
Filtering, cinnabar particle drying is put into pulverizer and crushed, and 150 mesh sieves were collected in sieving, but 220 mesh sieve fine powders, obtained Zhu
Emery dust, it is standby.
(2) cinnabar powder made from taking step (1) is well mixed with copper nanoparticle, produces cinnabar handicraft raw material powder.
Further：A kind of cinnabar handicraft raw material powder, preparation method thereof, comprises the following steps：
(1) take cinnabar to be cleaned up with water, be ground into graininess cinnabar, soak 2h with 35% sodium sulfide solution, filter,
Cinnabar particle drying, is put into pulverizer and crushes, and 180 mesh sieves were collected in sieving, but 200 mesh sieve fine powders, obtained cinnabar powder,
It is standby.
(2) cinnabar powder made from taking step (1) is well mixed with copper nanoparticle, produces cinnabar handicraft raw material powder.
Beneficial effects of the present invention are：
The present invention by cinnabar ornameutal handiwork experience for many years and research, find cinnabar its in 150-220 mesh, it must make
It is standby that into after handicraft, its color and luster is more excellent, with rosiness, metal reflective gloss, for the Cinnabar of other mesh numbers,
Below 150 mesh, its rosiness is not strong, even brown, furvous, no metallic luster, it is impossible to form obvious metallic luster；
More than 220 mesh, it will cause the handicraft prepared to show pink, or even show pale, no metallic luster, therefore,
To ensure cinnabar Color Quality, the present invention preferably cinnabar powder segments for 150-220 mesh, and the cinnabar handicraft being made is optimal, exception,
The present invention is added after copper nanoparticle in cinnabar powder preparation process, and it can significantly improve the chemical stability of cinnabar powder, obtained
Handicraft, color and luster is extremely brilliant, and grade is higher.
Beneficial effects of the present invention are investigated：
Test group 1:For cinnabar handicraft material powder produced by the present invention.
Test group 2：For 150-220 mesh cinnabar powder is mixed to prepare with crossing 200 mesh copper powders.
Control group：Cinnabar is ground into the subdivision of 160-220 mesh.
Accelerated stability test is carried out, experimental condition is：40 DEG C of temperature, relative humidity are under conditions of 75%, to uncap and deposit
Storage is investigated after 6 months, 6 months：
Result of the test：
Test group 1：Its cinnabar handicraft raw material powder is in large red, with nothing before rosiness, metal reflective gloss, with experiment
Significant difference.
Test group 2：Its rosiness of its cinnabar handicraft raw material powder is not strong, has slight crineous, metallic luster is weaker.
Control group：Its rosiness of cinnabar handicraft raw material powder is not strong, even brown, furvous, no metallic luster.
Explanation：The present invention is added after copper powder in cinnabar powder preparation process, and it can significantly improve the chemically stable of cinnabar powder
Property, and using copper nanoparticle its best results, its main cause be made copper nanoparticle can improve copper powder specific surface area and
Copper simple substance is activated, cinnabar powder can be preferably passivated, the chemical stability of cinnabar is improved, therefore, prepared by the present invention preferably cinnabar powder
During add a small amount of copper nanoparticle as protection.
Embodiment：
The preparation of the cinnabar handicraft raw material powder of embodiment 1
(1) take 92g cinnabar to be cleaned up with water, be ground into graininess cinnabar, 1h, mistake are soaked with 30% sodium sulfide solution
Filter, cinnabar particle drying is put into pulverizer and crushed, and 150 mesh sieves were collected in sieving, but 220 mesh sieve fine powders, obtained cinnabar
Powder, it is standby.
(2) cinnabar powder made from taking step (1) is well mixed with copper nanoparticle 8g, produces cinnabar handicraft raw material powder.
The preparation of the cinnabar handicraft raw material powder of embodiment 2
(1) take 94g cinnabar to be cleaned up with water, be ground into graininess cinnabar, 2h, mistake are soaked with 35% sodium sulfide solution
Filter, cinnabar particle drying is put into pulverizer and crushed, and 180 mesh sieves were collected in sieving, but 200 mesh sieve fine powders, obtained cinnabar
Powder, it is standby.
(2) cinnabar powder made from taking step (1) is well mixed with copper nanoparticle 6g, produces cinnabar handicraft raw material powder.
The preparation of the cinnabar handicraft raw material powder of embodiment 3
(1) take 97g cinnabar to be cleaned up with water, be ground into graininess cinnabar, 2h, mistake are soaked with 40% sodium sulfide solution
Filter, cinnabar particle drying is put into pulverizer and crushed, and 180 mesh sieves were collected in sieving, but 200 mesh sieve fine powders, obtained cinnabar
Powder, it is standby.
(2) cinnabar powder made from taking step (1) is well mixed with copper nanoparticle 3g, produces cinnabar handicraft raw material powder.
Claims (6)
1. a kind of cinnabar handicraft raw material powder, it is characterised in that：It is made up of the copper nanoparticle of 92-97% cinnabar powders and 3-8%.
2. cinnabar handicraft raw material powder according to claim 1, it is characterised in that：By 94% cinnabar powder and 6% nanometer
Copper powder is constituted.
3. cinnabar handicraft raw material powder according to claim 1 or 2, it is characterised in that：Described cinnabar powder was 150 mesh
Sieve, but 220 mesh sieve fine powders.
4. cinnabar handicraft raw material powder according to claim 1 or 2, it is characterised in that：Described cinnabar powder was 180 mesh
Sieve, but 200 mesh sieve fine powders.
5. a kind of cinnabar handicraft raw material powder, preparation method thereof, it is characterised in that：Comprise the following steps：
(1) take cinnabar to be cleaned up with water, be ground into graininess cinnabar, 1-3h, mistake are soaked with 30-40% sodium sulfide solution
Filter, cinnabar particle drying is put into pulverizer and crushed, and 150 mesh sieves were collected in sieving, but 220 mesh sieve fine powders, obtained cinnabar
Powder, it is standby.
(2) cinnabar powder made from taking step (1) is well mixed with copper nanoparticle, produces cinnabar handicraft raw material powder.
6. cinnabar handicraft raw material powder, preparation method thereof according to claim 5, it is characterised in that：Comprise the following steps：
(1) take cinnabar to be cleaned up with water, be ground into graininess cinnabar, 2h, filtering, cinnabar are soaked with 35% sodium sulfide solution
Particle drying, is put into pulverizer and crushes, and 180 mesh sieves were collected in sieving, but 200 mesh sieve fine powders, obtained cinnabar powder, standby.
(2) cinnabar powder made from taking step (1) is well mixed with copper nanoparticle, produces cinnabar handicraft raw material powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710322746.8A CN107056116B (en) | 2017-05-09 | 2017-05-09 | Cinnabar artware raw material powder and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710322746.8A CN107056116B (en) | 2017-05-09 | 2017-05-09 | Cinnabar artware raw material powder and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107056116A true CN107056116A (en) | 2017-08-18 |
| CN107056116B CN107056116B (en) | 2020-03-20 |
Family
ID=59597006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710322746.8A Expired - Fee Related CN107056116B (en) | 2017-05-09 | 2017-05-09 | Cinnabar artware raw material powder and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107056116B (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070047882A (en) * | 2005-11-03 | 2007-05-08 | 오이량 | Colored polymer paste and method for producing ornaments using the same |
| CN101885600A (en) * | 2010-07-21 | 2010-11-17 | 中南大学 | Heavy metal waste slag treatment method and sulfur building material prepared thereby |
| CN103204703A (en) * | 2013-02-04 | 2013-07-17 | 陕西师范大学 | Application of ZB-F600 two-component FEVE aqueous fluororesin in pretreatment of damage-prone pottery decorated with colored drawing before restoration |
| CN103270992A (en) * | 2013-06-20 | 2013-09-04 | 北海市源龙珍珠有限公司 | Rosy colored pearl cultivation method |
| CN104309394A (en) * | 2014-09-26 | 2015-01-28 | 厦门弼马温工艺品有限公司 | Surface color and luster treatment method of artistic copper sculpture |
| CN104710548A (en) * | 2014-01-03 | 2015-06-17 | 刘毓海 | 3D printing core material |
| CN105440775A (en) * | 2015-12-24 | 2016-03-30 | 青岛大方智慧网络科技有限公司 | Quick-dryinginkpad oil |
| KR20160080343A (en) * | 2014-12-29 | 2016-07-08 | 서광윤 | Glaze composition for cinnabar china and method of manufacturing cinnabar china by using the same |
| CN106519793A (en) * | 2016-11-24 | 2017-03-22 | 无锡奔牛生物科技有限公司 | Nano-particle-size ink |
-
2017
- 2017-05-09 CN CN201710322746.8A patent/CN107056116B/en not_active Expired - Fee Related
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070047882A (en) * | 2005-11-03 | 2007-05-08 | 오이량 | Colored polymer paste and method for producing ornaments using the same |
| CN101885600A (en) * | 2010-07-21 | 2010-11-17 | 中南大学 | Heavy metal waste slag treatment method and sulfur building material prepared thereby |
| CN103204703A (en) * | 2013-02-04 | 2013-07-17 | 陕西师范大学 | Application of ZB-F600 two-component FEVE aqueous fluororesin in pretreatment of damage-prone pottery decorated with colored drawing before restoration |
| CN103270992A (en) * | 2013-06-20 | 2013-09-04 | 北海市源龙珍珠有限公司 | Rosy colored pearl cultivation method |
| CN104710548A (en) * | 2014-01-03 | 2015-06-17 | 刘毓海 | 3D printing core material |
| CN104309394A (en) * | 2014-09-26 | 2015-01-28 | 厦门弼马温工艺品有限公司 | Surface color and luster treatment method of artistic copper sculpture |
| KR20160080343A (en) * | 2014-12-29 | 2016-07-08 | 서광윤 | Glaze composition for cinnabar china and method of manufacturing cinnabar china by using the same |
| CN105440775A (en) * | 2015-12-24 | 2016-03-30 | 青岛大方智慧网络科技有限公司 | Quick-dryinginkpad oil |
| CN106519793A (en) * | 2016-11-24 | 2017-03-22 | 无锡奔牛生物科技有限公司 | Nano-particle-size ink |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107056116B (en) | 2020-03-20 |
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Legal Events
| Date | Code | Title | Description |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200225 Address after: No. 2, floor 6, Daheng Daxia, No. 55, Hequn Road, Yunyan District, Guiyang City, Guizhou Province 550000 Applicant after: Guizhou Zhuxin Dachuang Technology Co., Ltd. Address before: 554200 standard economic development zone in Guizhou province Wanshan chemical plant Applicant before: Tongren testing center city wanshanqu Danfeng vermilion Crafts Development Co. Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20200320 Termination date: 20210509 |