CN107055693A - Positive osmosis industry sewage disposal device and positive osmosis industry sewage water treatment method - Google Patents

Positive osmosis industry sewage disposal device and positive osmosis industry sewage water treatment method Download PDF

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Publication number
CN107055693A
CN107055693A CN201710041042.3A CN201710041042A CN107055693A CN 107055693 A CN107055693 A CN 107055693A CN 201710041042 A CN201710041042 A CN 201710041042A CN 107055693 A CN107055693 A CN 107055693A
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calcium chloride
chloride solution
water
trade effluent
pressurized canister
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CN201710041042.3A
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CN107055693B (en
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张英华
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/445Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by forward osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/06Flash evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

The present invention discloses a kind of positive osmosis industry sewage disposal device and positive osmosis industry sewage water treatment method.Light trade effluent pump from light trade effluent pond is extracted light trade effluent out, enters forward osmosis membrane core from the upper end of positive osmosis industry sewage-treatment plant by light trade effluent pressurized canister, the trade effluent come out from the lower end of forward osmosis membrane core enters in dense trade effluent pond.The dense calcium chloride solution come out from calcium chloride solution pressurized canister enters in the space between shell and forward osmosis membrane core from the lower end of industrial sewage processing unit.In entering quick lime reactor with the water in calcium chloride solution chemical reaction generation calcium hydroxide occurs for the light calcium chloride solution that the space lower end between shell and forward osmosis membrane core comes out.The slaked lime slurry extracted out from quick lime reactor is dehydrated in being sent to lime white centrifugal dehumidifier, and the calcium chloride solution containing calcium hydroxide of abjection reacts in neutralization reaction kettle with hydrogen chloride generates calcium chloride and water.It is recycled from neutralizing dense calcium chloride solution of the temperature that comes out of the reactor very high calcium chloride solution after the concentration of atomizing calcium chloride solution multistage flash evaporation enrichment facility and entering in calcium chloride solution pressurized canister.

Description

Positive osmosis industry sewage disposal device and positive osmosis industry sewage water treatment method
Technical field:
The present invention relates to a kind of positive osmosis industry sewage disposal device and positive osmosis industry sewage water treatment method.
Background technology:
Trade effluent is usually periodically to discharge, and substantial amounts of pernicious gas is contained in many trade effluents.For example:Ammonia, Cyanogen, nitrogen dioxide, formaldehyde.So this kind of trade effluent can not be concentrated with sunlight exposure method, if carried out using hyperfiltration dense Contracting, because the metal salt concentration in this kind of trade effluent is very high, dense, it is necessary to which very high reverse osmotic pressure is, it is necessary to using very The high-pressure hydraulic pump of high request, the cost of dirty processing equipment operation is very high;If concentrated using the way of distillation, the heat energy of consumption is too many, Also uneconomical, distillation equipment is easily corroded by the aqueous metal salt in trade effluent.
Patent of invention number:201410077622.4, patent of invention title《Positive osmosis industry sewage disposal device and its technique Flow》It is middle to use ammonium bicarbonate soln as positive penetrating fluid, but the saturated concentration of ammonium bicarbonate soln is too low, can only be to low concentration Industrial fourth handled, and ammonia is needed when being separated from water being above heated to 70 DEG C, it is necessary to consume substantial amounts of fuel.Cause And, the cost that the industrial fourth low to concentration is handled in this way is than trade effluent sedan-chair of the hyperfiltration to low concentration The cost of railway carriage or compartment processing is high, so this positive osmosis industry fourth processing method is not with practical value.
The content of the invention:
The present invention can overcome the defect of existing positive osmosis industry sewage disposal device.
Positive osmosis industry sewage disposal device of the invention is main to be filled by light trade effluent pond, trade effluent precipitation with filtering Put, spiral aerator, vacuumize blower fan, active carbon filter, positive osmosis industry sewage-treatment plant, light trade effluent water inlet Electric magnetic valve and light trade effluent pump group into.The structure of the forward osmosis membrane core of positive osmosis industry sewage-treatment plant is:Graphene Forward osmosis membrane is clipped between the micropore ceramic tube of internal layer and outer foam earthenware, or forward osmosis membrane core permeates pottery using Tao Shi Porcelain tube.Light trade effluent pump 11 is the light trade effluent after filtering and active carbon deodorizing is handled from light trade effluent pond Extract out, enter by light trade effluent entering water electromagnetic valve in light trade effluent pressurized canister.The compression come out from air compressor is empty Gas enters by Non-return air valve is equipped with baroceptor at the top of air accumulator, air accumulator.The compressed air come out from air accumulator is passed through After Water Tank electromagnetic intake valve, enter light trade effluent pressurized canister from light trade effluent pressurized canister top.Light trade effluent pressurization It is canned to have at the top of sewage level sensor and sewage pressure sensor, light trade effluent pressurized canister equipped with light trade effluent pressurized canister Blast pipe, Water Tank electromagnetic exhaust valve is housed on the blast pipe of light trade effluent pressurized canister 1.From light trade effluent pressurized canister 1 The light trade effluent that bottom comes out enters a forward osmosis membrane core from the upper end of a positive osmosis industry sewage-treatment plant, from one The trade effluent that the lower end of a number forward osmosis membrane core of number positive osmosis industry sewage-treatment plant comes out is by a trade effluent Water outlet electric control valve, enters No. two forward osmosis membrane cores, from No. two just from the upper end of No. two positive osmosis industry sewage-treatment plants The trade effluent that the lower end of No. two forward osmosis membrane cores of osmosis industry sewage-treatment plant comes out is by No. two trade effluent water outlets Electric control valve, enters No. three forward osmosis membrane cores from the upper end of No. three positive osmosis industry sewage-treatment plants, from No. three positive infiltrations The trade effluent that the lower end of No. three forward osmosis membrane cores of industrial sewage processing unit comes out is electronic by No. three trade effluent water outlets In the dense trade effluent pond of regulating valve discharge.Dense calcium chloride solution is molten through superchlorination calcium after the pressurization of calcium chloride solution force (forcing) pump Liquid pressurized canister electromagnetism liquid feed valve enters in calcium chloride solution pressurized canister.The compressed air come out from air accumulator passes through calcium chloride solution After pressurized canister electromagnetic intake valve, enter calcium chloride solution pressurized canister from calcium chloride solution pressurized canister top.Calcium chloride solution pressurizes It is canned to have at the top of calcium chloride solution liquid level sensor and calcium chloride solution pressure sensor, calcium chloride solution pressurized canister equipped with chlorination It is vented on the blast pipe of calcium solution pressurized canister, the blast pipe of calcium chloride solution pressurized canister equipped with calcium chloride solution pressurized canister electromagnetism Valve.The calcium chloride solution come out from calcium chloride solution calcium chloride solution pressurization pot bottom goes out by calcium chloride solution pressurized canister electromagnetism Liquid valve enters between three extra shells and No. three forward osmosis membrane cores from the lower end of No. three positive osmosis industry sewage-treatment plants In space, brought out from the space between the three extra shells and No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants The calcium chloride solution come, through piping from the lower end of No. two positive osmosis industry sewage-treatment plants into two extra shells and No. two just In space between permeable membrane core, from two extra shells of No. two positive osmosis industry sewage-treatment plants and No. two forward osmosis membrane cores it Between the calcium chloride solution that comes out of space upper end, the lower end through piping from a positive osmosis industry sewage-treatment plant enters one In space between extra shell and a forward osmosis membrane core,.The compressed air come out from air accumulator 1 is backwashed respectively through three After electromagnetic intake valve and three unidirectional liquid valves, the lower end from three positive osmosis industry sewage-treatment plants is just being oozed into three respectively In space between the shell and forward osmosis membrane core of saturating industrial sewage processing unit.From a positive osmosis industry sewage-treatment plant An extra shell and a forward osmosis membrane core between the calcium chloride solution that comes out of space upper end pass through light calcium chloride solution electromagnetism Liquid valve enters in quick lime reactor, and calcium lime powder is delivered into quick lime reactor from quick lime pipe, quick lime reaction Lime stirrer is housed, with the water in calcium chloride solution chemical reaction generation hydrogen occurs for calcium oxide in quick lime reactor on kettle Calcium oxide simultaneously discharges substantial amounts of heat.The slaked lime slurry come out from the funnel of quick lime reactor bottom passes through lime slurry pump Lead to No. one hydraulic pressure butterfly valve after pressurization to enter in a lime white centrifugal dehumidifier, enter No. two stones by No. two hydraulic pressure butterfly valves In mortar centrifugal dehumidifier.Calcium hydroxide is slightly soluble in water, from a lime white centrifugal dehumidifier and No. two lime white centrifugations The calcium chloride solution containing calcium hydroxide that dehydration device comes out enters in neutralization reaction kettle after neutralizing pump pressurization, neutralizes anti- Answer on kettle equipped with neutralization agitator.Chlorine burns in hydrogen in burner generates hydrogen chloride gas and discharges substantial amounts of Heat, the hydrogen chloride gas produced in burner, which enters to be dissolved in neutralization reaction kettle in calcium chloride solution, turns into hydrochloric acid, salt Calcium hydroxide in hydrogen chloride and calcium chloride solution in acid occur chemical reaction generation calcium chloride and water, concurrently bear it is substantial amounts of Heat;Or hydrochloric acid pump extracts concentrated hydrochloric acid from hydrochloric acid tank, during the concentrated hydrochloric acid pumped out from hydrochloric acid enters neutralization reaction kettle, hydrochloric acid In hydrogen chloride and calcium chloride solution in calcium hydroxide occur chemical reaction generation calcium chloride and water, concurrently bear substantial amounts of heat Amount.Pass through atomizing calcium chloride solution multistage flash evaporation enrichment facility from the temperature that comes out of reactor very high calcium chloride solution is neutralized The first order flash distillation liquid feeding pump pressurization after enter atomizing calcium chloride solution multistage flash evaporation enrichment facility.It is molten from atomizing calcium chloride The pure water that liquid multistage flash evaporation enrichment facility comes out is flowed into purifying water pool, and the pure water of pure pump handle purifying water pool is extracted out Afterwards, in the lime white centrifugal dehumidifier shut down after a pure water electromagnetic water valve enters first time centrifugal dehydration, The slaked lime slurry in a lime white centrifugal dehumidifier is soaked, then to the white lime in a lime white centrifugal dehumidifier Slurry carries out second of centrifugal dehydration;After pure water pump 1 extracts the pure water in purifying water pool out, by No. two pure water electromagnetism water Valve enters in No. two lime white centrifugal dehumidifiers shut down after first time centrifugal dehydration, No. two lime white centrifugal dehydration dresses of immersion Slaked lime slurry in putting, then carries out second of centrifugal dehydration to the slaked lime slurry in No. two lime white centrifugal dehumidifiers.Through Cross twice dehydration from a lime white centrifugal dehumidifier and No. two lime white centrifugal dehumidifiers come out containing calcium chloride White lime mud is good construction material.The dense calcium chloride solution come out from atomizing calcium chloride solution multistage flash evaporation enrichment facility Pressurizeed again by calcium chloride solution pressurized canister electromagnetism liquid feed valve into calcium chloride solution after the pressurization of calcium chloride solution force (forcing) pump Tank.
Atomizing calcium chloride solution multistage flash evaporation enrichment facility structure is as follows:The top of flash tank is equipped with sprayer, spraying There are the calcium chloride solution conical pipe of several draining placing flat, each calcium chloride solution conical pipe above the structure flash tank of device Lower wall on multiple bell-shaped nozzles are equidistantly housed, have spiral rifling on bell-shaped nozzle inwall;Each calcium chloride A conical air pipe is all cased with outside solution conical pipe, each bell-shaped nozzle is cased with a tubaeform tuyere.From neutralization The temperature that reactor comes out very high calcium chloride solution enters first order sprayer after the first order flashes liquid feeding pump pressurization In the calcium chloride solution conical pipe of number draining placing flat, then from the lower wall of the calcium chloride solution conical pipe of first order sprayer On bell-shaped nozzle spray, the spiral rifling on bell-shaped nozzle inwall can make the calcium chloride solution of ejection scatter.Air blower After the Part I wind of blowout passes through a branch of plastic micro in first order condenser heated, into the number of first order sprayer In the airduct conical pipe of draining placing flat, then blown from the tubaeform tuyere in the lower wall of the conical air pipe of first order sprayer Go out, the drop that calcium chloride solution is sprayed from the bell-shaped nozzle in the lower wall of first order sprayer calcium chloride solution conical pipe Blow out vaporific.Water vapour is under the action of the forces of the wind through the first order foamed alloy filter after heating, the liquid with calcium chloride Drop in be heated through water during first order foamed alloy filter after heating and be gasificated into water vapour, solid chlorine calcium powder is stayed in On first order foamed alloy filter after heating.Through the water vapour of the first order foamed alloy filter after heating, enter In first order condenser, pure water is condensed into when being passed through outside plastic micro, is then flowed into purifying water pool.The second level Flash the number draining placing flat that liquid feeding pump extracts the calcium chloride solution in first order flash tank out feeding second level spraying after pressurization Calcium chloride solution conical pipe in, then from the tubaeform spray in the lower wall of the calcium chloride solution conical pipe of second level sprayer Mouth sprays, and the spiral rifling on bell-shaped nozzle inwall can make the calcium chloride solution of ejection scatter.Second of air blower blowout Point wind is passed through after a branch of plastic micro in the condenser of the second level is heated, into the wind of second level sprayer number draining placing flat In pipe conical pipe, then from the lower wall of second level sprayer conical air pipe tubaeform tuyere blowout, from the second level spray The drop of bell-shaped nozzle ejection calcium chloride solution in the lower wall of the calcium chloride solution conical pipe of day with fog is blown out vaporific.Water steams Vapour is under the action of the forces of the wind through the second level foamed alloy filter after heating, and the drop with calcium chloride is through after heating The second level foamed alloy filter when water be heated and be gasificated into water vapour, the second level that solid chlorine calcium powder is stayed in after heating On foamed alloy filter.Through the water vapour of the second level foamed alloy filter after heating, into the condenser of the second level, Pure water is condensed into when being passed through outside plastic micro, is then flowed into purifying water pool.The third level flashes liquid feeding pump the Calcium chloride solution in two-stage flash tank extracts the calcium chloride solution of the number draining placing flat of feeding third level sprayer after pressurization out In conical pipe, then sprayed from the bell-shaped nozzle in the lower wall of the calcium chloride solution conical pipe of third level sprayer, loudspeaker Spiral rifling in shape nozzle inner walls can make the calcium chloride solution of ejection scatter.The Part III wind of air blower blowout passes through the 3rd After a branch of plastic micro in level condenser is heated, into the airduct conical pipe of the number draining placing flat of third level sprayer In, then from the tubaeform tuyere blowout in the lower wall of the conical air pipe of third level sprayer, from third level sprayer chlorine The drop of bell-shaped nozzle ejection calcium chloride solution in the lower wall of change calcium solution conical pipe is blown out vaporific.Water vapour is in wind-force In the presence of through the third level foamed alloy filter after heating, the drop with calcium chloride is through the third level after heating Water, which is heated, during foamed alloy filter is gasificated into water vapour, the third level foamed alloy that solid chlorine calcium powder is stayed in after heating On filter.Through the water vapour of the third level foamed alloy filter after heating, into third level condenser, from plastics Pure water is condensed into when being passed through outside micro-pipe, is then flowed into purifying water pool.Pure water in pure pump handle purifying water pool After extraction through flushing electromagnetic water valve from the top of first order foamed alloy filter rinse first order foamed alloy filter, from Second level foamed alloy filter is rinsed, from the upper of third level foamed alloy filter in the top of second level foamed alloy filter Fang Chongxi third level foamed alloy filters.Calcium chloride solution force (forcing) pump extracts dense calcium chloride solution out in third level flash tank Enter after pressurization through superchlorination calcium solution pressurized canister electromagnetism liquid feed valve in calcium chloride solution pressurized canister 7.
Positive osmosis industry sewage water treatment method:Light trade effluent pump is light after filtering and active carbon deodorizing is handled Trade effluent is extracted out from light trade effluent pond, and the light trade effluent entering water electromagnetic valve by opening pressurizes into light trade effluent Tank.The compressed air come out from air compressor enters the air pressure sensing being equipped with the top of air accumulator, air accumulator by Non-return air valve The air pressure that device detects the compressed air in the tank of gas storage 1 stops the electricity of air compressor, Non-return air valve when reaching setting hyperbar value The compressed air in air accumulator can be prevented to be let out from the air compressor of internal machine, the air pressure transmission being equipped with the top of air accumulator The air pressure that sensor detects the compressed air in air accumulator then starts air compressor when reaching setting low pressure value.From air accumulator Compressed air out enters the pressurization of light trade effluent after Water Tank electromagnetic intake valve from light trade effluent pressurized canister top Tank.Light trade effluent pressurized canister detects the water level of the trade effluent in light trade effluent pressurized canister equipped with sewage level sensor Stop light trade effluent pump when reaching setting high watermark value and close light trade effluent entering water electromagnetic valve, light trade effluent pressurization is canned The water level for having sewage level sensor to detect the trade effluent in light trade effluent pressurized canister 1 stops when reaching setting low water level value Then start trade effluent pump and open light trade effluent entering water electromagnetic valve.Light trade effluent pressurized canister is equipped with sewage pressure sensor The pressure for detecting the trade effluent in light trade effluent pressurized canister opens Water Tank electromagnetism air inlet when reaching setting low pressure values Valve, compressed air enters light trade effluent pressurized canister from the light top of trade effluent pressurized canister 1, and light trade effluent pressurized canister is equipped with dirt The pressure that water pressure sensor detects the trade effluent in light trade effluent pressurized canister 1 is closed dirty when reaching setting high pressure values Water pot electromagnetic intake valve.Light trade effluent pressurized canister detects the work in light trade effluent pressurized canister equipped with sewage pressure sensor The pressure of industry sewage opens Water Tank electromagnetic exhaust valve when exceeding setting high pressure values, and compressed air is from light trade effluent pressurized canister The blast pipe discharge at top, light trade effluent pressurized canister is detected in light trade effluent pressurized canister equipped with sewage pressure sensor The pressure of trade effluent closes Water Tank electromagnetic exhaust valve when reaching setting high pressure values.Go out from light trade effluent pressurization pot bottom The light trade effluent come enters a positive osmosis industry sewage disposal dress from the upper end of a positive osmosis industry sewage-treatment plant The forward osmosis membrane core put, the work come out from the lower end of a forward osmosis membrane core of a positive osmosis industry sewage-treatment plant Industry sewage enters two by a trade effluent water outlet electric control valve from the upper end of No. two positive osmosis industry sewage-treatment plants No. two forward osmosis membrane cores of number positive osmosis industry sewage-treatment plant, from No. two of No. two positive osmosis industry sewage-treatment plants just The trade effluent that the lower end of permeable membrane core comes out is dirty from No. two positive osmosis industries by No. two trade effluent water outlet electric control valves The upper end of water treatment facilities enters No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants, from No. three positive infiltration works The trade effluent that the lower end of No. three forward osmosis membrane cores of industry sewage-treatment plant comes out is by No. three trade effluent water outlet electric adjustables In the dense trade effluent pond for saving valve discharge.It is 59.5 grams in the solubility of 0 DEG C of calcium chloride, is in the solubility of 20 DEG C of calcium chloride 74.5 grams, the concentration of saturation calcium chloride solution is at least ten times of trade effluent concentration, and calcium chloride solution is used as positive osmosis industry The positive infiltration liquation used in sewage-treatment plant, produced positive osmotic pressure be it is very big, the dense calcium chloride prepared is molten Liquid is put into calcium chloride solution pressurized canister.Dense calcium chloride solution is after the pressurization of calcium chloride solution force (forcing) pump through superchlorination calcium solution Pressurized canister electromagnetism liquid feed valve enters in calcium chloride solution pressurized canister.The compressed air come out from air accumulator passes through calcium chloride solution tank After electromagnetic intake valve, enter calcium chloride solution pressurized canister from the top of calcium chloride solution pressurized canister 7.Calcium chloride solution pressurized canister 7 is filled The liquid level that some calcium chloride solution liquid level sensors detect the calcium chloride solution in calcium chloride solution pressurized canister reaches that setting is high Stop the electricity of calcium chloride solution force (forcing) pump during liquid level and close calcium chloride solution pressurized canister electromagnetism liquid feed valve, calcium chloride solution pressurized canister The liquid level that the calcium chloride solution liquid level sensor being equipped with detects the calcium chloride solution in calcium chloride solution pressurized canister reaches setting Then start calcium chloride solution force (forcing) pump during low liquid level and open calcium chloride solution pressurized canister electromagnetism liquid feed valve.Calcium chloride solution pressurizes The pressure that the canned calcium chloride solution pressure sensor having detects the calcium chloride solution in calcium chloride solution pressurized canister, which reaches, to be set Determine to close calcium chloride solution pressurized canister electromagnetic intake valve, the calcium chloride solution pressure that calcium chloride solution pressurized canister is equipped with during high pressure The pressure that sensor detects the calcium chloride solution in calcium chloride solution pressurized canister then opens calcium chloride when reaching setting low-pressure Solution pressurized canister electromagnetic intake valve.It is molten that the calcium chloride solution pressure sensor that calcium chloride solution pressurized canister is equipped with detects calcium chloride The pressure of calcium chloride solution in liquid pressurized canister opens the electric feed liquor magnetic exhaust of calcium chloride solution pressurized canister when exceeding setting high pressure Valve, the blast pipe discharge for the calcium chloride solution pressurized canister that compressed air is equipped with from the top of calcium chloride solution pressurized canister 7, calcium chloride is molten The calcium chloride solution pressure sensor that liquid pressurized canister is equipped with detects the pressure of the calcium chloride solution in calcium chloride solution pressurized canister Calcium chloride solution pressurized canister electric feed liquor magnetic air bleeding valve is then closed when reaching setting high pressure.Go out from calcium chloride solution pressurization pot bottom The calcium chloride solution come is filled by the calcium chloride solution pressurized canister electromagnetism liquid valve opened from No. three positive osmosis industry sewage disposals The lower end put enters in the space between the three extra shells and No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants, The chlorine come out from the space upper end between the three extra shells and No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants Change calcium solution, enter No. two positive osmosis industry sewage disposals from the lower end of No. two positive osmosis industry sewage-treatment plants through piping In space between the two extra shells and No. two forward osmosis membrane cores of device, from No. two of No. two positive osmosis industry sewage-treatment plants The calcium chloride solution that space upper end between shell and No. two forward osmosis membrane cores comes out, it is dirty from a positive osmosis industry through piping The lower end of water treatment facilities enters between an extra shell and a forward osmosis membrane core for a positive osmosis industry sewage-treatment plant Space in.The chlorine in space between the three extra shells and No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants Change trade effluent concentration in the concentration of calcium solution and No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants it Pure water than being related in No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants passes through No. three positive infiltration works The positive osmotic pressure of No. three forward osmosis membrane cores of industry sewage-treatment plant, No. three of No. three positive osmosis industry sewage-treatment plants are just oozed The pressure of trade effluent in permeable membrane core is just permeating plus pure water through No. three of No. three positive osmosis industry sewage-treatment plants The positive osmotic pressure of film core, equal to the pressure for No. three forward osmosis membrane cores that pure water passes through No. three positive osmosis industry sewage-treatment plants Power.No. two trade effluent water outlet electric control valves of regulation and No. three trade effluent water outlet electric control valves namely have adjusted No. three The pressure of trade effluent in No. three forward osmosis membranes of positive osmosis industry sewage-treatment plant, so as to have adjusted pure water through three No. three forward osmosis membrane cores of number positive osmosis industry sewage-treatment plant enter No. three of No. three positive osmosis industry sewage-treatment plants The quantity in space between shell and No. three forward osmosis membrane cores, so as to have influence on into No. two positive osmosis industry sewage disposal dresses The concentration of the calcium chloride solution in space between the two extra shells and No. two forward osmosis membrane cores put.No. two positive osmosis industry sewage The concentration of the calcium chloride solution in space between the two extra shells and No. two forward osmosis membrane cores of processing unit and No. two positive infiltrations The ratio between trade effluent concentration in No. two forward osmosis membrane cores of industrial sewage processing unit is related to No. two positive osmosis industry sewage Pure water in No. two forward osmosis membrane cores of processing unit is just permeating through No. two of No. two positive osmosis industry sewage-treatment plants The pressure of trade effluent in the positive osmotic pressure of film core, No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants adds Upper pure water is worn through the positive osmotic pressure of No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants equal to pure water The pressure of No. three forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants is crossed, a trade effluent water outlet electric adjustable is adjusted Section valve and No. two trade effluent water outlet electric control valves namely have adjusted No. three of No. two positive osmosis industry sewage-treatment plants The pressure of trade effluent in forward osmosis membrane, so as to have adjusted pure water through the two of No. two positive osmosis industry sewage-treatment plants The sky that number forward osmosis membrane core enters between the two extra shells and No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants Quantity in gap, so as to have influence on the extra shell and a forward osmosis membrane core into a positive osmosis industry sewage-treatment plant Between space in calcium chloride solution concentration.If light trade effluent pressurized canister detects light equipped with sewage level sensor The water level of trade effluent in trade effluent pressurized canister 1 stops when reaching setting low water level value, starts trade effluent pump and opens light After trade effluent entering water electromagnetic valve, light trade effluent pressurized canister 1 detects light trade effluent equipped with sewage level sensor quickly The water level of trade effluent in pressurized canister just reaches setting high watermark value, illustrates the positive infiltration of positive osmosis industry sewage-treatment plant Film core has been blocked, it is necessary to which the forward osmosis membrane core for aligning osmosis industry sewage-treatment plant is backwashed.Backwash process is such as Under:Stop light trade effluent pump and close light trade effluent entering water electromagnetic valve, stop calcium chloride solution force (forcing) pump and closing calcium chloride is molten Liquid pressurized canister electromagnetism liquid feed valve, calcium chloride solution pressurized canister electromagnetism liquid valve and light calcium chloride solution electromagnetism liquid valve, open three Individual backwash electromagnetic intake valve, the compressed air come out from air accumulator passes through three backwash electromagnetic intake valves and three unidirectional liquid After valve, respectively from the lower end of three positive osmosis industry sewage-treatment plants enter three positive osmosis industry sewage-treatment plants outside In space between shell and forward osmosis membrane core, then compressed air is each passed through three positive osmosis industry sewage-treatment plants again Forward osmosis membrane core wall enters on three forward osmosis membrane cores, the forward osmosis membrane core for blowing logical three positive osmosis industry sewage-treatment plants Micropore.After backwash terminates, start light trade effluent pump and open light trade effluent entering water electromagnetic valve, start calcium chloride solution and add Press pump and opening calcium chloride solution pressurized canister electromagnetism liquid feed valve, calcium chloride solution pressurized canister electromagnetism liquid valve and light calcium chloride solution Electromagnetism liquid valve, closes three backwash electromagnetic intake valves.If just oozing for osmosis industry sewage-treatment plant need not be aligned Permeable membrane core is backwashed, between an extra shell and a forward osmosis membrane core for a positive osmosis industry sewage-treatment plant The calcium chloride solution that space upper end comes out enters in quick lime reactor by light calcium chloride solution electromagnetism liquid valve, quick lime Powder is delivered into quick lime reactor from quick lime pipe, and quick lime is accelerated in the lime stirrer work being equipped with quick lime reactor The chemical reaction of quick lime and water in reactor, with the water in calcium chloride solution chemistry occurs for calcium oxide in quick lime reactor Reaction generation calcium hydroxide simultaneously discharges substantial amounts of heat.The slaked lime slurry warp come out from the funnel of quick lime reactor bottom Entered after crossing lime slurry pump pressurization by a hydraulic pressure butterfly valve of opening in a lime white centrifugal dehumidifier, wait a lime Slurry centrifugal dehumidifier fills a number hydraulic pressure butterfly valve of closing after slaked lime slurry, then opens No. two hydraulic pressure butterfly valves, anti-from quick lime The slaked lime slurry that the funnel in bottom portion comes out is answered to enter No. two by No. two hydraulic pressure butterfly valves of opening after lime slurry pump pressurizes In lime white centrifugal dehumidifier.Start a lime white centrifugal dehumidifier, calcium hydroxide is slightly soluble in water, from a lime white The calcium chloride solution containing micro calcium hydroxide that centrifugal dehumidifier comes out enters neutralization reaction kettle after neutralizing pump pressurization In.Dehydration terminates a number lime white centrifugal dehumidifier for the first time, a lime white centrifugal dehumidifier shuts down, and starts pure Clarified water pump, pure water pump extracts pure water from purifying water pool and flows into a lime white by a pure water solenoid valve of opening The slaked lime slurry in a lime white centrifugal dehumidifier after the dehydration of the first magnetic is soaked in centrifugal dehumidifier, then starts one Number lime white centrifugal dehumidifier 4 carries out second to slaked lime slurry and is dehydrated.By twice dehydration white lime mud from a stone Released in mortar centrifugal dehumidifier, be that the charging of next round slaked lime slurry is prepared.Deng No. two lime white centrifugal dehumidifier dresses No. two hydraulic pressure butterfly valves are closed after full slaked lime slurry, a hydraulic pressure butterfly valve is then opened, goes out from the funnel of quick lime reactor bottom The slaked lime slurry come enters a lime white centrifugal dehydration by a hydraulic pressure butterfly valve of opening after lime slurry pump pressurizes and filled Put in 4.Start No. two lime white centrifugal dehumidifiers, contain micro hydroxide from what No. two lime white centrifugal dehumidifiers came out The calcium chloride solution of calcium enters in neutralization reaction kettle after neutralizing pump pressurization.No. two lime white centrifugal dehumidifiers are de- for the first time Water terminates, No. two lime white centrifugal dehumidifiers shut down, and pure water pump extracts pure water from purifying water pool and passes through opening No. two pure water electromagnetism flow into No. two lime white centrifugal dehumidifiers in immersion for the first time be dehydrated after No. two lime whites centrifugation Slaked lime slurry in dehydration device, then starts No. two lime white centrifugal dehumidifiers, to No. two lime white centrifugal dehumidifiers Slaked lime slurry carry out second and be dehydrated.The white lime mud Jing Guo twice dehydration from No. two lime white centrifugal dehumidifiers White lime mud is released, and is that the charging of next round slaked lime slurry is prepared.A number lime white centrifugal dehumidifier and No. two lime whites from Heart dehydration device is dehydrated to the slaked lime slurry come out from quick lime reactor in turn.From a lime white centrifugal dehumidifier It is good construction material, white lime with the white lime mud containing calcium chloride released in No. two lime white centrifugal dehumidifiers In have no effect on the quality of white lime containing a small amount of calcium chloride, calcium chloride is the main additive of cement, is a kind of water reducer, White lime, cement, sand are mixed in proportion with water and mud, then cover brick wall wall indoors and mixed with the mud become reconciled On solidifying soil ceiling.Chlorine burns in hydrogen in burner generates hydrogen chloride gas and discharges substantial amounts of heat, in combustion The hydrogen chloride gas produced in burner, which enters to be dissolved in neutralization reaction kettle in calcium chloride solution, turns into hydrochloric acid, the chlorination in hydrochloric acid Hydrogen occurs chemical reaction generation calcium chloride and water with the calcium hydroxide in calcium chloride solution, concurrently bears substantial amounts of heat.Or Hydrochloric acid pump extracts concentrated hydrochloric acid from hydrochloric acid tank, during the concentrated hydrochloric acid pumped out from hydrochloric acid enters neutralization reaction kettle, the chlorination in hydrochloric acid Hydrogen occurs chemical reaction generation calcium chloride and water with the calcium hydroxide in calcium chloride solution, concurrently bears substantial amounts of heat.Neutralize It can accelerate the hydrogen chloride and chlorine in neutralization reaction kettle equipped with the neutralization agitator work being equipped with neutralization agitator on reactor The calcium hydroxide changed in calcium solution chemically reacts.From the temperature that comes out of reactor very high calcium chloride solution is neutralized by spray Enter the number row of first order sprayer after the first order flash distillation liquid feeding pump pressurization of mist formula calcium chloride solution multistage flash evaporation enrichment facility In the calcium chloride solution conical pipe of horizontal positioned, then from the lower wall of the calcium chloride solution conical pipe of first order sprayer Bell-shaped nozzle sprays, and the spiral rifling on bell-shaped nozzle inwall can make the calcium chloride solution of ejection scatter.Air blower is blown out Part I wind pass through first order condenser in a branch of plastic micro be heated after, into the number draining of first order sprayer In the airduct conical pipe of placing flat, then from the tubaeform tuyere blowout in the lower wall of the conical air pipe of first order sprayer, The drop that calcium chloride solution is sprayed from the bell-shaped nozzle in the lower wall of first order sprayer calcium chloride solution conical pipe is blown Nebulize.Water vapour is under the action of the forces of the wind through the first order foamed alloy filter after heating, the drop with calcium chloride Water, which is heated, when through first order foamed alloy filter after heating is gasificated into water vapour, solid chlorine calcium powder stay in plus On first order foamed alloy filter after heat.Through the water vapour of the first order foamed alloy filter after heating, into In first-stage condenser, pure water is condensed into when being passed through outside plastic micro, is then flowed into purifying water pool.The second level is dodged Steam liquid feeding pump and the calcium chloride solution in first order flash tank is extracted out the number draining placing flat that second level sprayer is sent into after pressurization Calcium chloride solution conical pipe in, then from the tubaeform spray in the lower wall of the calcium chloride solution conical pipe of second level sprayer Mouth sprays, and the spiral rifling on bell-shaped nozzle inwall can make the calcium chloride solution of ejection scatter.Second of air blower blowout Point wind is passed through after a branch of plastic micro in the condenser of the second level is heated, into the wind of second level sprayer number draining placing flat In pipe conical pipe, then from the lower wall of second level sprayer conical air pipe tubaeform tuyere blowout, from the second level spray The drop of bell-shaped nozzle ejection calcium chloride solution in the lower wall of the calcium chloride solution conical pipe of day with fog is blown out vaporific.Water steams Vapour is under the action of the forces of the wind through the second level foamed alloy filter after heating, and the drop with calcium chloride is through after heating The second level foamed alloy filter when water be heated and be gasificated into water vapour, the second level that solid chlorine calcium powder is stayed in after heating On foamed alloy filter.Through the water vapour of the second level foamed alloy filter after heating, into the condenser of the second level, Pure water is condensed into when being passed through outside plastic micro, is then flowed into purifying water pool.The third level flashes liquid feeding pump the Calcium chloride solution in two-stage flash tank extracts the calcium chloride solution cone of feeding third level sprayer number draining placing flat after pressurization out In shape pipe, then sprayed from the bell-shaped nozzle in the lower wall of the calcium chloride solution conical pipe of third level sprayer, it is tubaeform Spiral rifling in nozzle inner walls can make the calcium chloride solution of ejection scatter.The Part III wind of air blower blowout passes through the third level After a branch of plastic micro in condenser is heated, into the airduct conical pipe of the number draining placing flat of third level sprayer, Then from the tubaeform tuyere blowout in the lower wall of the conical air pipe of third level sprayer, from third level sprayer calcium chloride The drop of bell-shaped nozzle ejection calcium chloride solution in the lower wall of solution conical pipe is blown out vaporific.Work of the water vapour in wind-force With the lower third level foamed alloy filter through after heating, the drop with calcium chloride is through the third level foam after heating Water, which is heated, during alloy filter is gasificated into water vapour, the third level foamed alloy filtering that solid chlorine calcium powder is stayed in after heating On device.Through the water vapour of the third level foamed alloy filter after heating, into third level condenser, from plastic micro Pure water is condensed into when outside is passed through, is then flowed into purifying water pool.Calcium chloride solution force (forcing) pump is in third level flash tank Dense calcium chloride solution is extracted out and entered after pressurizeing through superchlorination calcium solution pressurized canister electromagnetism liquid feed valve in calcium chloride solution pressurized canister It is recycled.Foamed alloy filter water accumulates the micropore of too many solid calcium chloride plug-back plug foamed alloy filter, needs Regularly to rinse after pure water in foamed alloy filter, pure pump handle purifying water pool is extracted out through flushing electromagnetic water valve from First order foamed alloy filter is rinsed, from the upper of second level foamed alloy filter in the top of first order foamed alloy filter Fang Chongxi second level foamed alloy filter, the top flushing third level foamed alloy filtering from third level foamed alloy filter Device.The present invention can by trade effluent 85% moisture content remove, if necessary to by trade effluent further concentration then need Atomizing trade effluent multistage flash evaporation enrichment facility is used to be concentrated, atomizing trade effluent multistage flash evaporation enrichment facility Structure is identical with the structure of atomizing calcium chloride solution multistage flash evaporation enrichment facility.
Brief description of the drawings:
Further specific detailed description is done to the present invention with reference to the accompanying drawings and detailed description.
Fig. 1 is the fundamental diagram that the present invention plants positive osmosis industry sewage disposal device.
Fig. 2 is the fundamental diagram of atomizing calcium chloride solution multistage flash evaporation enrichment facility in the present invention.
Embodiment:
Shown in Fig. 1, the positive osmosis industry sewage disposal device of the present invention is main to be precipitated by light trade effluent pond 9, trade effluent With filter, spiral aerator, vacuumize blower fan, active carbon filter, positive osmosis industry sewage-treatment plant, light industry Wastewater influent electricity magnetic valve 20 and light trade effluent pump 11 are constituted.The knot of the forward osmosis membrane core of positive osmosis industry sewage-treatment plant Structure is:Graphene forward osmosis membrane is clipped between the micropore ceramic tube of internal layer and outer foam earthenware, or forward osmosis membrane core makes With Tao Shi osmotic ceramic pipes.Light trade effluent pump 11 is the light trade effluent after filtering and active carbon deodorizing is handled from light Extract out, enter by light trade effluent entering water electromagnetic valve 20 in light trade effluent pressurized canister 1 in trade effluent pond 9.From air pressure The compressed air that contracting machine 17 comes out enters air accumulator 18 by Non-return air valve 22, and the top of air accumulator 18 is equipped with baroceptor.From The compressed air that air accumulator 18 comes out enters light after Water Tank electromagnetic intake valve 23 from the light top of trade effluent pressurized canister 1 Trade effluent pressurized canister 1.Light trade effluent pressurized canister 1 is equipped with sewage level sensor and sewage pressure sensor, and light industry is dirty The top of water pressurized canister 1 is equipped with the blast pipe of light trade effluent pressurized canister 1, the blast pipe of light trade effluent pressurized canister 1 equipped with dirt Water pot electromagnetic exhaust valve.The light trade effluent come out from the light bottom of trade effluent pressurized canister 1 is at a positive osmosis industry sewage The upper end for managing device 2 enters a forward osmosis membrane core, from a forward osmosis membrane core of a positive osmosis industry sewage-treatment plant 2 The trade effluent that comes out of lower end by a trade effluent water outlet electric control valve 21, from No. two positive osmosis industry sewage disposals The upper end of device 2 ' enters No. two forward osmosis membrane cores, from No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants 2 ' The trade effluent that comes out of lower end by No. two trade effluent water outlet electric control valves 21 ', at No. three positive osmosis industry sewage The upper end for managing device 2 " enters No. three forward osmosis membrane cores, from No. three forward osmosis membranes of No. three positive osmosis industry sewage-treatment plants 2 " The dense trade effluent pond 10 that the trade effluent that the lower end of core comes out is discharged by No. three trade effluent water outlet electric control valves 21 " In.Dense calcium chloride solution enters after the pressurization of calcium chloride solution force (forcing) pump 15 through superchlorination calcium solution pressurized canister electromagnetism liquid feed valve 28 Enter in calcium chloride solution pressurized canister 7.The compressed air come out from air accumulator 18 passes through calcium chloride solution pressurized canister electromagnetic intake valve After 24, enter calcium chloride solution pressurized canister 7 from the top of calcium chloride solution pressurized canister 7.Calcium chloride solution pressurized canister 7 is equipped with calcium chloride Solution level sensor and calcium chloride solution pressure sensor, the top of calcium chloride solution pressurized canister 7 is equipped with calcium chloride solution pressurization Calcium chloride solution pressurized canister electromagnetic exhaust valve is housed on the blast pipe of tank 7, the blast pipe of calcium chloride solution pressurized canister 7.From chlorination The calcium chloride solution that the bottom of calcium solution calcium chloride solution pressurized canister 7 comes out by calcium chloride solution pressurized canister electromagnetism liquid valve 29 from The lower end of No. three positive osmosis industry sewage-treatment plants 2 " enters the space between three extra shells and No. three forward osmosis membrane cores In, come out from the space upper end between the three extra shells and No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants 2 " Calcium chloride solution, entering two extra shells and No. two just from the lower end of No. two positive osmosis industry sewage-treatment plants 2 ' through piping In space between permeable membrane core, from the two extra shells and No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants 2 ' Between the calcium chloride solution that comes out of space upper end, the lower end through piping from a positive osmosis industry sewage-treatment plant 2 is entered Enter in the space between an extra shell and a forward osmosis membrane core,.From the compressed air of air accumulator 18 out respectively through three Backwash after electromagnetic intake valve and three unidirectional liquid valves, the lower end from three positive osmosis industry sewage-treatment plants enters three respectively In space between the shell and forward osmosis membrane core of individual positive osmosis industry sewage-treatment plant.At a positive osmosis industry sewage The calcium chloride solution that space upper end between the extra shell and a forward osmosis membrane core of reason device 2 comes out is molten by light calcium chloride Liquid electromagnetic liquid valve 25 enters in quick lime reactor 3, and calcium lime powder is delivered to quick lime reactor 3 from quick lime pipe 31 In, lime stirrer is housed, calcium oxide is sent out with the water in calcium chloride solution in quick lime reactor 3 on quick lime reactor 3 Biochemical reaction generation calcium hydroxide simultaneously discharges substantial amounts of heat.The ripe stone come out from the funnel of the bottom of quick lime reactor 3 Mortar leads to No. one hydraulic pressure butterfly valve 27 after the pressurization of lime slurry pump 12 and entered in a lime white centrifugal dehumidifier 4, passes through No. two hydraulic pressure butterfly valves 27 ' enter in No. two lime white centrifugal dehumidifiers 4 '.Calcium hydroxide is slightly soluble in water, from a lime white from The calcium chloride solution containing calcium hydroxide that heart dehydration device 4 and No. two lime white centrifugal dehumidifiers 4 ' come out is by neutralizing pump Enter after 13 pressurizations in neutralization reaction kettle 5, equipped with neutralization agitator on neutralization reaction kettle 5.Chlorine is in hydrogen in burner Burning generation hydrogen chloride gas simultaneously discharges substantial amounts of heat, and the hydrogen chloride gas produced in burner enters neutralization reaction Being dissolved in kettle 5 in calcium chloride solution turns into hydrochloric acid, the calcium hydroxide in hydrogen chloride and calcium chloride solution in hydrochloric acid Learn reaction generation calcium chloride and water, concurrently bear substantial amounts of heat;Or hydrochloric acid pump 14 extracts concentrated hydrochloric acid from hydrochloric acid tank 19, from The concentrated hydrochloric acid that hydrochloric acid pump 14 comes out enters in neutralization reaction kettle 5, the calcium hydroxide in hydrogen chloride and calcium chloride solution in hydrochloric acid Generation chemical reaction generates calcium chloride and water, concurrently bears substantial amounts of heat.From neutralizing the temperature very high chlorine that reactor 5 comes out Change calcium solution after the first order flash distillation liquid feeding pump 601 of atomizing calcium chloride solution multistage flash evaporation enrichment facility 6 pressurizes to enter In atomizing calcium chloride solution multistage flash evaporation enrichment facility 6.Come out from atomizing calcium chloride solution multistage flash evaporation enrichment facility 6 Pure water is flowed into purifying water pool 8, after pure water pump 16 extracts the pure water in purifying water pool 8 out, by a pure water power Magnetic water valve 26 enters after first time centrifugal dehydration in a lime white centrifugal dehumidifier 4 shutting down, a number lime white of immersion from Slaked lime slurry in heart dehydration device 4, then the slaked lime slurry in a lime white centrifugal dehumidifier 4 is carried out second from The heart is dehydrated;After pure water pump 16 extracts the pure water in purifying water pool 8 out, enter the by No. two pure water electromagnetic water valves 26 ' In No. two lime white centrifugal dehumidifiers 4 ' shut down after centrifugal dehydration, in No. two lime white centrifugal dehumidifiers 4 ' of immersion Slaked lime slurry, then in No. two lime white centrifugal dehumidifiers 4 ' slaked lime slurry carry out second of centrifugal dehydration.By Twice dehydration from a lime white centrifugal dehumidifier 4 and No. two lime white centrifugal dehumidifiers 4 ' come out containing calcium chloride White lime mud is good construction material.The dense calcium chloride come out from atomizing calcium chloride solution multistage flash evaporation enrichment facility 6 is molten Liquid is molten into calcium chloride by calcium chloride solution pressurized canister electromagnetism liquid feed valve 28 again after the pressurization of calcium chloride solution force (forcing) pump 15 Liquid pressurized canister 7.
The multistage flash evaporation of atomizing calcium chloride solution shown in Fig. 26 structures of enrichment facility are as follows:The top of flash tank is equipped with spraying There is the calcium chloride solution conical pipe of several draining placing flat above device, the structure flash tank of sprayer, each calcium chloride is molten Equidistantly being equipped with multiple bell-shaped nozzles, bell-shaped nozzle inwall in the lower wall of liquid conical pipe has spiral rifling;It is each A conical air pipe is all cased with outside root calcium chloride solution conical pipe, each bell-shaped nozzle is cased with a tubaeform wind Mouth.Enter the after first order flash distillation liquid feeding pump 601 pressurizes from the temperature very high calcium chloride solution that reactor 5 comes out is neutralized In the calcium chloride solution conical pipe of the number draining placing flat of one-level sprayer 603, then from the calcium chloride of first order sprayer 603 Bell-shaped nozzle in the lower wall of solution conical pipe sprays, and the spiral rifling on bell-shaped nozzle inwall can make the chlorination of ejection Calcium solution scatters.The Part I wind that air blower 606 is blown out passes through a branch of plastic micro in first order condenser 605 to be heated Afterwards, into the airduct conical pipe of the number draining placing flat of first order sprayer 603, then from the cone of first order sprayer 603 Tubaeform tuyere blowout in the lower wall of shape airduct, the lower wall from the calcium chloride solution conical pipe of first order sprayer 603 On bell-shaped nozzle spray calcium chloride solution drop blow out it is vaporific.Water vapour is under the action of the forces of the wind through the after heating One-level foamed alloy filter 604, the drop with calcium chloride is when through first order foamed alloy filter 604 after heating Water, which is heated, is gasificated into water vapour, and solid chlorine calcium powder is stayed on the first order foamed alloy filter 604 after heating.Pass through The water vapour of first order foamed alloy filter 604 after heating, into first order condenser 605, outside plastic micro Pure water is condensed into when face is passed through, is then flowed into purifying water pool 8.The second level flashes liquid feeding pump 601 ' first order flash tank Calcium chloride solution in 602 extracts the calcium chloride solution conical pipe of the number draining placing flat of feeding second level spraying 603 ' after pressurization out In, then sprayed from the bell-shaped nozzle in the lower wall of the calcium chloride solution conical pipe of second level sprayer 603 ', it is tubaeform Spiral rifling in nozzle inner walls can make the calcium chloride solution of ejection scatter.The Part II wind that air blower 606 is blown out is through the After a branch of plastic micro in secondary condenser 605 ' is heated, into the airduct of the number draining placing flat of second level sprayer 603 ' In conical pipe, then from the tubaeform tuyere blowout in the lower wall of the conical air pipe of second level sprayer 603 ', from the second level The drop that bell-shaped nozzle in the lower wall of the calcium chloride solution conical pipe of sprayer 603 ' sprays calcium chloride solution blows out mist Shape.Water vapour is under the action of the forces of the wind through the second level foamed alloy filter 604 ' after heating, the drop with calcium chloride Water, which is heated, when through second level foamed alloy filter 604 ' after heating is gasificated into water vapour, and solid chlorine calcium powder is stayed On second level foamed alloy filter 604 ' after the heating.Through the water of the second level foamed alloy filter 604 ' after heating Steam, into second level condenser 605 ', is condensed into pure water when being passed through outside plastic micro, then flows into pure In pond 8.The third level, which flashes liquid feeding pump 601 ", extracts the calcium chloride solution in second level flash tank 602 ' out the is sent into after pressurization In the calcium chloride solution conical pipe of the number draining placing flat of three-level sprayer 603 ", then from the chlorination of third level sprayer 603 " Bell-shaped nozzle in the lower wall of calcium solution conical pipe sprays, and the spiral rifling on bell-shaped nozzle inwall can make the chlorine of ejection Change calcium solution to scatter.The Part III wind that air blower 606 is blown out passes through a branch of plastic micro quilt in third level condenser 605 " After heating, into the airduct conical pipe of the number draining placing flat of third level sprayer 603 ", then from third level sprayer Tubaeform tuyere blowout in the lower wall of 603 " conical air pipe, from the calcium chloride solution conical pipe of third level sprayer 603 " Lower wall on bell-shaped nozzle spray calcium chloride solution drop blow out it is vaporific.Water vapour is passed through under the action of the forces of the wind to be added Third level foamed alloy filter 604 " after heat, the drop with calcium chloride is through the third level foamed alloy mistake after heating Water, which is heated, during filter 604 " is gasificated into water vapour, the third level foamed alloy filter that solid chlorine calcium powder is stayed in after heating On 604 ".Through the water vapour of the third level foamed alloy filter 604 " after heating, into third level condenser 605 ", Pure water is condensed into when being passed through outside from plastic micro, is then flowed into purifying water pool 8.Pure water pump 16 is purifying water pool 8 In pure water extract out after rinse first order bubble by rinsing electromagnetic water valve 30 from the top of first order foamed alloy filter 604 Foam alloy filter 604, the flushing of top 1 second level foamed alloy filter from second level foamed alloy filter 604 ' 604 ", third level foamed alloy filter 604 " is rinsed from the top of third level foamed alloy filter 604 ".Calcium chloride solution Force (forcing) pump 15 is extracted after pressurization dense calcium chloride solution through superchlorination calcium solution pressurized canister electromagnetism out in third level flash tank 602 " Liquid feed valve 28 enters in calcium chloride solution pressurized canister 7.
Shown in Fig. 1 and Fig. 2, positive osmosis industry sewage water treatment method:Light trade effluent pump 11 is by filtering and activated carbon Light trade effluent after deodorizing process is extracted out from light trade effluent pond 9, by the light trade effluent entering water electromagnetic valve of opening 20 enter light trade effluent pressurized canister 1.Enter air accumulator from the compressed air of air compressor 17 out by Non-return air valve 22 18, the air pressure that the baroceptor that the top of air accumulator 18 is equipped with detects the compressed air in the tank 8 of gas storage 1 reaches setting hyperbar Stop the electricity of air compressor 17 during value, Non-return air valve 22 can prevent air pressure of the compressed air in air accumulator 18 from internal machine Contracting machine 17 lets out, and the air pressure that the baroceptor that the top of air accumulator 18 is equipped with detects the compressed air in air accumulator 18 reaches Then start air compressor 17 during to setting low pressure value.The compressed air come out from air accumulator 18 passes through Water Tank electromagnetism air inlet After valve 23, enter light trade effluent pressurized canister 1 from the light top of trade effluent pressurized canister 1.Light trade effluent pressurized canister 1 is equipped with sewage The water level that liquid level sensor detects the trade effluent in light trade effluent pressurized canister 1 stops light industry when reaching setting high watermark value Sewage pump 11 and the light trade effluent entering water electromagnetic valve 20 of closing, light trade effluent pressurized canister 1 are detected equipped with sewage level sensor The water level of trade effluent in light trade effluent pressurized canister 1 stops when reaching setting low water level value, starts the He of trade effluent pump 11 Open light trade effluent entering water electromagnetic valve 20.It is dirty that light trade effluent pressurized canister 1 detects light industry equipped with sewage pressure sensor The pressure of trade effluent in water pressurized canister 1 opens Water Tank electromagnetic intake valve 23, compressed air when reaching setting low pressure values Enter light trade effluent pressurized canister 1 from the light top of trade effluent pressurized canister 1, light trade effluent pressurized canister 1 is passed equipped with sewage pressure The pressure that sensor detects the trade effluent in light trade effluent pressurized canister 1 closes Water Tank electromagnetism when reaching setting high pressure values Intake valve 23.The industry that light trade effluent pressurized canister 1 is detected equipped with sewage pressure sensor in light trade effluent pressurized canister 1 is dirty The pressure of water opens Water Tank electromagnetic exhaust valve when exceeding setting high pressure values, and compressed air is pushed up from light trade effluent pressurized canister 1 The blast pipe discharge in portion, light trade effluent pressurized canister 1 is detected in light trade effluent pressurized canister 1 equipped with sewage pressure sensor The pressure of trade effluent closes Water Tank electromagnetic exhaust valve when reaching setting high pressure values.From the light bottom of trade effluent pressurized canister 1 Light trade effluent out enters a positive osmosis industry sewage disposal from the upper end of a positive osmosis industry sewage-treatment plant 2 A number forward osmosis membrane core of device 2, comes out from the lower end of a forward osmosis membrane core of a positive osmosis industry sewage-treatment plant 2 Trade effluent by trade effluent water outlet electric control valve 21, from the upper of No. two positive osmosis industry sewage-treatment plants 2 ' End enters No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants 2 ', from No. two positive osmosis industry sewage disposal dresses Trade effluent that the lower ends of 2 ' No. two forward osmosis membrane cores comes out is put by No. two trade effluent water outlet electric control valves 21 ', from Just oozed into No. three of No. three positive osmosis industry sewage-treatment plants 2 " upper end of No. two positive osmosis industry sewage-treatment plants 2 ' Permeable membrane core, the trade effluent come out from the lower end of No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants 2 " passes through In the dense trade effluent pond 10 that No. three trade effluent water outlet electric control valves 21 " are discharged.It is 59.5 in the solubility of 0 DEG C of calcium chloride Gram, it is 74.5 grams in the solubility of 20 DEG C of calcium chloride, the concentration of saturation calcium chloride solution is at least ten times of trade effluent concentration, Calcium chloride solution is as the positive infiltration liquation used in positive osmosis industry sewage-treatment plant, and produced positive osmotic pressure is very Big, the dense calcium chloride solution prepared is put into calcium chloride solution pressurized canister 7.Dense calcium chloride solution adds by calcium chloride solution Press pump 15 enters in calcium chloride solution pressurized canister 7 after pressurizeing through superchlorination calcium solution pressurized canister electromagnetism liquid feed valve 28.From air accumulator 18 compressed air out enters chlorine after calcium chloride solution tank electromagnetic intake valve 24 from the top of calcium chloride solution pressurized canister 7 Change calcium solution pressurized canister 7.The calcium chloride solution liquid level sensor that calcium chloride solution pressurized canister 7 is equipped with detects calcium chloride solution and added The liquid level of calcium chloride solution in pressure tank 7 stops the electricity of calcium chloride solution force (forcing) pump 15 and closes calcium chloride when reaching setting high level Solution pressurized canister electromagnetism liquid feed valve 28, the calcium chloride solution liquid level sensor that calcium chloride solution pressurized canister 7 is equipped with detects chlorination The liquid level of calcium chloride solution in calcium solution pressurized canister 7 then starts calcium chloride solution force (forcing) pump 15 and beaten when reaching setting low liquid level Open calcium chloride solution pressurized canister electromagnetism liquid feed valve 28.The calcium chloride solution pressure sensor inspection that calcium chloride solution pressurized canister 7 is equipped with The pressure for measuring the calcium chloride solution in calcium chloride solution pressurized canister 7 closes calcium chloride solution pressurized canister when reaching setting high pressure Electromagnetic intake valve 24, the calcium chloride solution pressure sensor that calcium chloride solution pressurized canister 7 is equipped with detects calcium chloride solution pressurization The pressure of calcium chloride solution in tank 7 then opens calcium chloride solution pressurized canister electromagnetic intake valve 24 when reaching setting low-pressure.Chlorine The calcium chloride that the calcium chloride solution pressure sensor that change calcium solution pressurized canister 7 is equipped with is detected in calcium chloride solution pressurized canister 7 is molten The pressure of liquid opens calcium chloride solution pressurized canister electric feed liquor magnetic air bleeding valve when exceeding setting high pressure, compressed air is molten from calcium chloride The blast pipe discharge for the calcium chloride solution pressurized canister 7 that the top of liquid pressurized canister 7 is equipped with, the chlorination that calcium chloride solution pressurized canister 7 is equipped with Calcium solution pressure sensor detect the calcium chloride solution in calcium chloride solution pressurized canister 7 pressure reach setting high pressure when then Close the electric feed liquor magnetic air bleeding valve of calcium chloride solution pressurized canister.The calcium chloride solution warp come out from the bottom of calcium chloride solution pressurized canister 7 The calcium chloride solution pressurized canister electromagnetism liquid valve 29 opened is crossed from the lower end of No. three positive osmosis industry sewage-treatment plants 2 " to enter In space between the three extra shells and No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants 2 ", just oozed from No. three The calcium chloride solution that space upper end between the three extra shells and No. three forward osmosis membrane cores of saturating industrial sewage processing unit 2 " comes out, Enter No. two positive osmosis industry sewage-treatment plants 2 ' from the lower end of No. two positive osmosis industry sewage-treatment plants 2 ' through piping Two extra shells and No. two forward osmosis membrane cores between space in, from two extras of No. two positive osmosis industry sewage-treatment plants 2 ' The calcium chloride solution that space upper end between shell and No. two forward osmosis membrane cores comes out, through piping from a positive osmosis industry sewage The lower end of processing unit 2 enters between an extra shell and a forward osmosis membrane core for a positive osmosis industry sewage-treatment plant 2 Space in.In space between the three extra shells and No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants 2 " The concentration of calcium chloride solution and trade effluent in No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants 2 " are dense The pure water that the ratio between degree is related in No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants 2 " is passing through No. three just The positive osmotic pressure of No. three forward osmosis membrane cores of osmosis industry sewage-treatment plant 2 ", No. three positive osmosis industry sewage-treatment plants 2 " No. three forward osmosis membrane cores in trade effluent pressure plus pure water through No. three positive osmosis industry sewage-treatment plants 2 " No. three forward osmosis membrane cores positive osmotic pressure, equal to pure water through No. three of No. three positive osmosis industry sewage-treatment plants 2 " just The pressure of permeable membrane core.Adjust No. two trade effluent water outlet electric control valves 21 ' and No. three trade effluent water outlet electric control valves 21 " namely have adjusted the pressure of the trade effluent in No. three forward osmosis membranes of No. three positive osmosis industry sewage-treatment plants 2 ", So as to which No. three forward osmosis membrane cores that have adjusted pure water through No. three positive osmosis industry sewage-treatment plants 2 " just ooze into No. three The quantity in space between the three extra shells and No. three forward osmosis membrane cores of saturating industrial sewage processing unit 2 ", thus have influence on into Enter the calcium chloride in the space between the two extra shells and No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants 2 ' The concentration of solution.In space between the two extra shells and No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants 2 ' The concentration of calcium chloride solution and the trade effluent in No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants 2 ' The pure water that the ratio between concentration is related in No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants 2 ' passes through No. two The positive osmotic pressure of No. two forward osmosis membrane cores of positive osmosis industry sewage-treatment plant 2 ', No. two positive osmosis industry sewage-treatment plants The pressure of trade effluent in 2 ' No. two forward osmosis membrane cores passes through No. two positive osmosis industry sewage-treatment plants plus pure water The positive osmotic pressure of 2 ' No. two forward osmosis membrane cores, equal to No. three that pure water passes through No. two positive osmosis industry sewage-treatment plants 2 ' The pressure of forward osmosis membrane core, a number trade effluent water outlet electric control valve 21 of regulation and No. two trade effluent water outlet electric control valves 21 ' namely have adjusted the pressure of the trade effluent in No. three forward osmosis membranes of No. two positive osmosis industry sewage-treatment plants 2 ', So as to which No. two forward osmosis membrane cores that have adjusted pure water through No. two positive osmosis industry sewage-treatment plants 2 ' just ooze into No. two The quantity in space between the two extra shells and No. two forward osmosis membrane cores of saturating industrial sewage processing unit 2 ', thus have influence on into The calcium chloride entered in the space between an extra shell and a forward osmosis membrane core for a positive osmosis industry sewage-treatment plant 2 is molten The concentration of liquid.If light trade effluent pressurized canister 1 detects the work in light trade effluent pressurized canister 1 equipped with sewage level sensor The water level of industry sewage stops when reaching setting low water level value, starts trade effluent pump 11 and opens light trade effluent entering water electromagnetic valve After 20, the industry that light trade effluent pressurized canister 1 is detected equipped with sewage level sensor in light trade effluent pressurized canister 1 quickly is dirty The water level of water just reaches setting high watermark value, illustrates that the forward osmosis membrane core of positive osmosis industry sewage-treatment plant has been blocked, and needs The forward osmosis membrane core for aligning osmosis industry sewage-treatment plant is backwashed.Backwash process is as follows:Stop light trade effluent Pump 11 and the light trade effluent entering water electromagnetic valve 20 of closing, stop calcium chloride solution force (forcing) pump 15 and close calcium chloride solution pressurized canister electricity Magnetic liquid feed valve 28, calcium chloride solution pressurized canister electromagnetism liquid valve 29 and light calcium chloride solution electromagnetism liquid valve 25, open three instead Electromagnetic intake valve is rinsed, the compressed air come out from air accumulator 18 passes through three backwash electromagnetic intake valves and three unidirectional liquid valves Afterwards, the shell of three positive osmosis industry sewage-treatment plants is entered from the lower end of three positive osmosis industry sewage-treatment plants respectively In space between forward osmosis membrane core, then compressed air is being each passed through three positive osmosis industry sewage-treatment plants just again Permeable membrane core wall enters three forward osmosis membrane cores, blows micro- on the forward osmosis membrane core of logical three positive osmosis industry sewage-treatment plants Hole.After backwash terminates, start light trade effluent pump 11 and open light trade effluent entering water electromagnetic valve 20, start calcium chloride solution Force (forcing) pump 15 and opening calcium chloride solution pressurized canister electromagnetism liquid feed valve 28, calcium chloride solution pressurized canister electromagnetism liquid valve 29 and light chlorine Change calcium solution electromagnetism liquid valve 25, close three backwash electromagnetic intake valves.If osmosis industry sewage disposal need not be aligned The forward osmosis membrane core of device is backwashed, and is just being oozed with No. one from an extra shell of a positive osmosis industry sewage-treatment plant 2 It is anti-that the calcium chloride solution that space upper end between permeable membrane core comes out enters quick lime by light calcium chloride solution electromagnetism liquid valve 25 Answer in kettle 3, calcium lime powder is delivered into quick lime reactor 3 from quick lime pipe 31, the lime being equipped with quick lime reactor 3 The chemical reaction of quick lime and water in quick lime reactor 3, calcium oxide and chlorine in quick lime reactor 3 are accelerated in agitator work Change the water in calcium solution to occur chemical reaction generation calcium hydroxide and discharge substantial amounts of heat.From the bottom of quick lime reactor 3 The slaked lime slurry that comes out of funnel a lime is entered by a hydraulic pressure butterfly valve 27 of opening after the pressurization of lime slurry pump 12 Starch in centrifugal dehumidifier 4, wait a lime white centrifugal dehumidifier 4 to fill a number hydraulic pressure butterfly valve 27 of closing after slaked lime slurry, Then No. two hydraulic pressure butterfly valves 27 ' are opened, the slaked lime slurry come out from the funnel of the bottom of quick lime reactor 3 passes through lime slurry pump 12 Entered after pressurization by No. two hydraulic pressure butterfly valves 27 ' of opening in No. two lime white centrifugal dehumidifiers 4 '.Start a lime white Centrifugal dehumidifier 4, the calcium chloride solution containing micro calcium hydroxide come out from a lime white centrifugal dehumidifier 4 passes through Neutralize after pump 13 pressurizes and enter in neutralization reaction kettle 5.A number lime white centrifugal dehumidifier 4 be dehydrated for the first time terminate, a stone Mortar centrifugal dehumidifier 4 shuts down, and starts pure water pump 16, and pure water pump 16 extracts pure water from purifying water pool 8 and led to Cross the pure water solenoid valve 26 of No. one opened and flow into No. one soaked in a lime white centrifugal dehumidifier 4 after the dehydration of first magnetic Slaked lime slurry in lime white centrifugal dehumidifier 4, then starts a lime white centrifugal dehumidifier 4 and slaked lime slurry is carried out Second of dehydration.It is the ripe stone of next round being released by twice dehydration white lime mud from a lime white centrifugal dehumidifier 4 Mortar charging is prepared.No. two hydraulic pressure butterfly valves 27 ' of closing after slaked lime slurry are filled Deng No. two lime white centrifugal dehumidifiers 4 ', so A hydraulic pressure butterfly valve 27 is opened afterwards, and the slaked lime slurry come out from the funnel of the bottom of quick lime reactor 3 adds by lime slurry pump 12 Entered after pressure by a hydraulic pressure butterfly valve 27 of opening in a lime white centrifugal dehumidifier 4.Calcium hydroxide is slightly soluble in water, opens Move No. two lime white centrifugal dehumidifiers 4 ', from No. two lime white centrifugal dehumidifiers 4 ' come out containing micro calcium hydroxide Calcium chloride solution enters in neutralization reaction kettle 5 after neutralizing pump 13 and pressurizeing.No. two lime white centrifugal dehumidifiers 4 ' are for the first time Dehydration terminates, No. two lime white centrifugal dehumidifiers 4 ' shut down, and pure water pump 16 extracts pure water from purifying water pool 8 and led to Cross the pure water solenoid valve 26 ' of No. two opened and flow into No. two lime white centrifugal dehumidifiers 4 ' two soaked after being dehydrated for the first time Slaked lime slurry in number lime white centrifugal dehumidifier 4 ', then starts No. two lime white centrifugal dehumidifiers 4 ', to No. two stones The slaked lime slurry of mortar centrifugal dehumidifier 4 ' carries out second and is dehydrated.The white lime mud Jing Guo twice dehydration from No. two lime The white lime mud starched in centrifugal dehumidifier 4 ' is released, and is that the charging of next round slaked lime slurry is prepared.A number lime white centrifugation is de- Water installations 4 and No. two lime white centrifugal dehumidifiers 4 ' are dehydrated to the slaked lime slurry come out from quick lime reactor 3 in turn. The ripe stone containing calcium chloride released from a lime white centrifugal dehumidifier 4 and No. two lime white centrifugal dehumidifiers 4 ' Plaster is the quality for having no effect on white lime in good construction material, white lime containing a small amount of calcium chloride, and calcium chloride is water The main additive of mud, be a kind of water reducer, white lime, cement, sand are mixed in proportion with water and mud, then with Good mud covering is indoors on brick wall wall and concrete ceiling.Chlorine burns in hydrogen in burner generates hydrogen chloride Gas simultaneously discharges substantial amounts of heat, and the hydrogen chloride gas produced in burner, which enters in neutralization reaction kettle 5, is dissolved in chlorination Turn into the calcium hydroxide in hydrogen chloride and calcium chloride solution in hydrochloric acid, hydrochloric acid in calcium solution and occur chemical reaction generation calcium chloride With water, concurrently bear substantial amounts of heat.Or hydrochloric acid pump 14 extracts concentrated hydrochloric acid from hydrochloric acid tank 19, from hydrochloric acid pump 14 come out it is dense Hydrochloric acid enters in neutralization reaction kettle 5, and chemical reaction generation occurs for the calcium hydroxide in the hydrogen chloride and calcium chloride solution in hydrochloric acid Calcium chloride and water, concurrently bear substantial amounts of heat.Equipped with the neutralization agitator work being equipped with neutralization agitator on neutralization reaction kettle 5 The calcium hydroxide for making to accelerate in the hydrogen chloride and calcium chloride solution in neutralization reaction kettle 5 chemically reacts.It is anti-from neutralizing The temperature very high calcium chloride solution for answering kettle 5 to come out passes through the first order of atomizing calcium chloride solution multistage flash evaporation enrichment facility 6 In the calcium chloride solution conical pipe for flashing the number draining placing flat for entering first order sprayer 603 after liquid feeding pump 601 pressurizes, then Sprayed from the bell-shaped nozzle in the lower wall of the calcium chloride solution conical pipe of first order sprayer 603, bell-shaped nozzle inwall On spiral rifling the calcium chloride solution of ejection can be made to scatter.The Part I wind that air blower 606 is blown out is condensed through the first order After a branch of plastic micro in device 605 is heated, into the airduct conical pipe of the number draining placing flat of first order sprayer 603 In, then from the tubaeform tuyere blowout in the lower wall of the conical air pipe of first order sprayer 603, from first order sprayer The drop of bell-shaped nozzle ejection calcium chloride solution in the lower wall of 603 calcium chloride solution conical pipes is blown out vaporific.Water vapour Under the action of the forces of the wind through the first order foamed alloy filter 604 after heating, the drop with calcium chloride is through heating Water, which is heated, during rear first order foamed alloy filter 604 is gasificated into water vapour, and solid chlorine calcium powder is stayed in after heating On first order foamed alloy filter 604.Through the water vapour of the first order foamed alloy filter 604 after heating, into In first-stage condenser 605, pure water is condensed into when being passed through outside plastic micro, is then flowed into purifying water pool 8.Second Level flash distillation liquid feeding pump 601 ', which extracts the calcium chloride solution in first order flash tank 602 out, sends into second level sprayer 603 ' after pressurization Number draining placing flat calcium chloride solution conical pipe in, then from the calcium chloride solution conical pipe of second level sprayer 603 ' Bell-shaped nozzle in lower wall sprays, and the spiral rifling on bell-shaped nozzle inwall can make the calcium chloride solution of ejection scatter. The Part II wind that air blower 606 is blown out is passed through after a branch of plastic micro in second level condenser 605 ' is heated, into the In the airduct conical pipe of two grades of number draining placing flat of sprayer 603 ', then from the downside of the conical air pipe of second level sprayer 603 ' Tubaeform tuyere blowout on wall, from tubaeform in the lower wall of the calcium chloride solution conical pipe of second level sprayer 603 ' The drop of nozzle ejection calcium chloride solution is blown out vaporific.Water vapour is closed through the second level foam after heating under the action of the forces of the wind Gold filter device 604 ', water when through second level foamed alloy filter 604 ' after heating of the drop with calcium chloride is heated Water vapour is gasificated into, solid chlorine calcium powder is stayed on the second level foamed alloy filter 604 ' after heating.Through after heating Second level foamed alloy filter 604 ' water vapour, into second level condenser 605 ', worn outside plastic micro It is out-of-date to be condensed into pure water, then flow into purifying water pool 8.The third level flashes liquid feeding pump 601 " second level flash tank 602 ' In calcium chloride solution extract out after pressurization in the calcium chloride solution conical pipe of the number draining placing flat of feeding third level sprayer 603 ", Then sprayed from the bell-shaped nozzle in the lower wall of the calcium chloride solution conical pipe of third level sprayer 603 ", bell-shaped nozzle Spiral rifling on inwall can make the calcium chloride solution of ejection scatter.The Part III wind that air blower 606 is blown out passes through the third level After a branch of plastic micro in condenser 605 " is heated, into the airduct cone of the number draining placing flat of third level sprayer 603 " In shape pipe, then from the tubaeform tuyere blowout in the lower wall of the conical air pipe of third level sprayer 603 ", from the third level The drop of bell-shaped nozzle ejection calcium chloride solution in the lower wall of the calcium chloride solution conical pipe of sprayer 603 " is blown out vaporific. Water vapour is under the action of the forces of the wind through the third level foamed alloy filter 604 " after heating, and the drop with calcium chloride is being worn Water, which is heated, when crossing third level foamed alloy filter 604 " after heating is gasificated into water vapour, and solid chlorine calcium powder, which is stayed in, to be added On third level foamed alloy filter 604 " after heat.Water through the third level foamed alloy filter 604 " after heating steams Vapour, into third level condenser 605 ", is condensed into pure water when being passed through outside plastic micro, then flows into pure water In pond 8.Calcium chloride solution force (forcing) pump 15 is extracted after pressurization dense calcium chloride solution through superchlorination out in third level flash tank 602 " Calcium solution pressurized canister electromagnetism liquid feed valve 28 enters to be recycled in calcium chloride solution pressurized canister 7.Foamed alloy filter water is accumulated The micropore of tired too many solid calcium chloride plug-back plug foamed alloy filter is, it is necessary to which timing flushing foamed alloy filter, pure Water pump 16 pure water in purifying water pool 8 is extracted out after by rinsing electromagnetic water valve 30 from first order foamed alloy filter 604 Top rinse first order foamed alloy filter 604, rinse the second level from the top of second level foamed alloy filter 604 ' Foamed alloy filter 604 ", the top flushing third level foamed alloy filter from third level foamed alloy filter 604 " 604”.The present invention can remove 85 moisture content in trade effluent, if necessary to which the trade effluent after concentration is further dense Contracting then needs to use atomizing trade effluent multistage flash evaporation enrichment facility to be concentrated, the concentration of atomizing trade effluent multistage flash evaporation The structure of device is identical with the structure of atomizing calcium chloride solution multistage flash evaporation enrichment facility 6.

Claims (3)

1. a kind of positive osmosis industry sewage disposal device, positive osmosis industry sewage disposal device is main by light trade effluent pond, work Industry settlement of sewage and filter, spiral aerator, vacuumize blower fan, active carbon filter, positive osmosis industry sewage disposal Device, light trade effluent enter water power magnetic valve and light trade effluent pump group into the positive infiltration of positive osmosis industry sewage-treatment plant The structure of film core is:Graphene forward osmosis membrane is clipped between the micropore ceramic tube of internal layer and outer foam earthenware, or just oozed Permeable membrane core uses Tao Shi osmotic ceramic pipes;It is characterized in that:The light trade effluent pump (11) is removed filtering and activated carbon is passed through Light trade effluent after smelly processing is extracted out from the light trade effluent pond (9), by the light trade effluent water inlet electromagnetism Valve (20) enters in light trade effluent pressurized canister (1);The compressed air come out from air compressor (17) passes through Non-return air valve (22) enter and baroceptor is housed at the top of air accumulator (18), air accumulator (18), the compressed air warp come out from air accumulator (18) Cross after Water Tank electromagnetic intake valve (23), enter light trade effluent pressurized canister (1) from light trade effluent pressurized canister (1) top, it is light Trade effluent pressurized canister (1) is equipped with the top of sewage level sensor and sewage pressure sensor, light trade effluent pressurized canister (1) and filled Have on the blast pipe of light trade effluent pressurized canister (1), the blast pipe of light trade effluent pressurized canister (1) equipped with the exhaust of Water Tank electromagnetism Valve;The light trade effluent come out from light trade effluent pressurized canister (1) bottom is from positive osmosis industry sewage-treatment plant (2) Upper end enters a forward osmosis membrane core, from the lower end of a forward osmosis membrane core of a positive osmosis industry sewage-treatment plant (2) Trade effluent out is by a trade effluent water outlet electric control valve (21), from No. two positive osmosis industry sewage-treatment plants The upper end of No. two forward osmosis membrane cores of (2 ') enters No. two forward osmosis membrane cores, from No. two positive osmosis industry sewage-treatment plants (2 ') No. two forward osmosis membrane cores the trade effluent that comes out of lower end by No. two trade effluent water outlet electric control valves (21 '), from three The upper end of number positive osmosis industry sewage-treatment plant (2 ") enters No. three forward osmosis membrane cores, from No. three positive osmosis industry sewage disposals The trade effluent that the lower end of three forward osmosis membrane cores of device (2 ") comes out is by No. three trade effluent water outlet electric control valves (21 ") The dense trade effluent pond (10) of discharge is inner;Dense calcium chloride solution is after calcium chloride solution force (forcing) pump (15) pressurization through superchlorination calcium Solution pressurized canister electromagnetism liquid feed valve (28) is inner into calcium chloride solution pressurized canister (7), the compressed air come out from air accumulator (18) After calcium chloride solution pressurized canister electromagnetic intake valve (24), enter calcium chloride solution from calcium chloride solution pressurized canister (7) top Pressurized canister (7), calcium chloride solution pressurized canister (7) is equipped with calcium chloride solution liquid level sensor and calcium chloride solution pressure sensor, The blast pipe of calcium chloride solution pressurized canister (7) is housed at the top of calcium chloride solution pressurized canister (7), calcium chloride solution pressurized canister (7) Calcium chloride solution pressurized canister electromagnetic exhaust valve is housed on blast pipe;Go out from calcium chloride solution calcium chloride solution pressurized canister (7) bottom The calcium chloride solution come passes through calcium chloride solution pressurized canister electromagnetism liquid valve (29) from No. three positive osmosis industry sewage disposals The lower end of device (2 ") enters in the space between three extra shells and No. three forward osmosis membrane cores, at No. three positive osmosis industry sewage The calcium chloride solution that comes out of space upper end between the three extra shells and No. three forward osmosis membrane cores of reason device (2 "), through piping from The lower end of No. two positive osmosis industry sewage-treatment plants (2 ') enters in the space between two extra shells and No. two forward osmosis membrane cores, Come out from the space upper end between the two extra shells and No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants (2 ') Calcium chloride solution, through piping from the lower end of a positive osmosis industry sewage-treatment plant (2) enter an extra shell and No. one In space between forward osmosis membrane core;The compressed air come out from air accumulator (18) is respectively through three backwash electromagnetic intake valves After three unidirectional liquid valves, enter three positive osmosis industry sewage from the lower end of three positive osmosis industry sewage-treatment plants respectively In space between the shell and forward osmosis membrane core of processing unit;From No. one of a positive osmosis industry sewage-treatment plant (2) The calcium chloride solution that space upper end between shell and a forward osmosis membrane core comes out passes through light calcium chloride solution electromagnetism liquid valve (25) enter in quick lime reactor (3), calcium lime powder is delivered into quick lime reactor (3) from quick lime pipe (31), it is raw Lime stirrer is housed, calcium oxide occurs with the water in calcium chloride solution in quick lime reactor (3) on lime reaction kettle (3) Chemical reaction generation calcium hydroxide simultaneously discharges substantial amounts of heat;The ripe stone come out from the funnel of quick lime reactor (3) bottom Mortar leads to No. one hydraulic pressure butterfly valve (27) after lime slurry pump (12) pressurization and enters a lime white centrifugal dehumidifier (4) In, entered by No. two hydraulic pressure butterfly valves (27 ') in No. two lime white centrifugal dehumidifiers (4 ');Calcium hydroxide is slightly soluble in water, from The chlorination containing calcium hydroxide that a number lime white centrifugal dehumidifier (4) and No. two lime white centrifugal dehumidifiers (4 ') come out Calcium solution enters in neutralization reaction kettle (5) after neutralizing pump (13) pressurization, equipped with neutralization agitator on neutralization reaction kettle (5); Chlorine burns in hydrogen in burner generates hydrogen chloride gas and discharges substantial amounts of heat, is produced in burner Hydrogen chloride gas, which enters to be dissolved in neutralization reaction kettle (5) in calcium chloride solution, turns into hydrochloric acid, hydrogen chloride and chlorination in hydrochloric acid Calcium hydroxide in calcium solution occurs chemical reaction generation calcium chloride and water, concurrently bears substantial amounts of heat;Or hydrochloric acid pump (14) concentrated hydrochloric acid is extracted from hydrochloric acid tank (19), the concentrated hydrochloric acid come out from hydrochloric acid pump (14) enters in neutralization reaction kettle (5), hydrochloric acid In hydrogen chloride and calcium chloride solution in calcium hydroxide occur chemical reaction generation calcium chloride and water, concurrently bear substantial amounts of heat Amount;From reactor (5) temperature for coming out very high calcium chloride solution is neutralized by the concentration of atomizing calcium chloride solution multistage flash evaporation Enter atomizing calcium chloride solution multistage flash evaporation enrichment facility (6) after first order flash distillation liquid feeding pump (601) pressurization of device (6) In, the pure water come out from atomizing calcium chloride solution multistage flash evaporation enrichment facility (6) is flowed into purifying water pool (8), pure water After pump (16) extracts the pure water in purifying water pool (8) out, enter by a pure water electromagnetic water valve (26) and centrifuge for the first time In the lime white centrifugal dehumidifier (4) shut down after dehydration, the ripe stone in a number lime white centrifugal dehumidifier (4) of immersion Mortar, then carries out second of centrifugal dehydration to the slaked lime slurry in a lime white centrifugal dehumidifier (4);Pure water pump (16) after the pure water in purifying water pool (8) being extracted out, centrifugation for the first time is entered by No. two pure water electromagnetic water valves (26 ') de- In No. two lime white centrifugal dehumidifiers (4 ') shut down after water, the ripe stone in No. two lime white centrifugal dehumidifiers (4 ') of immersion Mortar, then carries out second of centrifugal dehydration, by twice to the slaked lime slurry in No. two lime white centrifugal dehumidifiers (4 ') Be dehydrated from a lime white centrifugal dehumidifier (4) and No. two lime white centrifugal dehumidifiers (4 ') come out containing calcium chloride White lime mud is good construction material, the dense calcium chloride come out from atomizing calcium chloride solution multistage flash evaporation enrichment facility (6) Solution enters chlorine by calcium chloride solution pressurized canister electromagnetism liquid feed valve (28) again after calcium chloride solution force (forcing) pump (15) pressurization Change calcium solution pressurized canister (7).
2. a kind of positive osmosis industry sewage disposal device according to claim 1, it is characterised in that:The atomizing calcium chloride Solution multistage flash evaporation enrichment facility (6) structure is as follows:The top of flash tank is equipped with sprayer, and the structure of sprayer is flash tank Top has in the calcium chloride solution conical pipe of several draining placing flat, the lower wall of each calcium chloride solution conical pipe equidistantly Equipped with multiple bell-shaped nozzles, have on bell-shaped nozzle inwall and all covered outside spiral rifling, each calcium chloride solution conical pipe There is a conical air pipe, each bell-shaped nozzle is cased with a tubaeform tuyere;The temperature come out from neutralization reactor (5) Very high calcium chloride solution enters the number draining of first order sprayer (603) after the first order flashes liquid feeding pump (601) pressurization In the calcium chloride solution conical pipe of placing flat, then from the lower wall of the calcium chloride solution conical pipe of first order sprayer (603) On bell-shaped nozzle spray, the spiral rifling on bell-shaped nozzle inwall can make the calcium chloride solution of ejection scatter;Air blower (606) after the Part I wind of blowout passes through a branch of plastic micro in first order condenser (605) heated, into the first order In the airduct conical pipe of the number draining placing flat of sprayer (603), then under the conical air pipe of first order sprayer (603) Tubaeform tuyere blowout on the wall of side, from the loudspeaker in the lower wall of first order sprayer (603) calcium chloride solution conical pipe The drop that shape nozzle sprays calcium chloride solution blows out vaporific, the first order foam of water vapour under the action of the forces of the wind through after heating Alloy filter (604), water quilt when through first order foamed alloy filter (604) after heating of the drop with calcium chloride Heating and gasifying is into water vapour, and solid chlorine calcium powder is stayed on the first order foamed alloy filter (604) after heating;Through adding The water vapour of first order foamed alloy filter (604) after heat, into first order condenser (605), from plastic micro Pure water is condensed into when outside is passed through, purifying water pool (8) is then flowed into inner;Second level flash distillation liquid feeding pump (601 ') is the first order The inner calcium chloride solution of flash tank (602) extracts the chlorination of the number draining placing flat of feeding second level sprayer (603) after pressurization out In calcium solution conical pipe, then from the tubaeform spray in the lower wall of the calcium chloride solution conical pipe of second level sprayer (603 ') Mouth sprays, and the spiral rifling on bell-shaped nozzle inwall can make the calcium chloride solution of ejection scatter;The of air blower (606) blowout After two part wind pass through a branch of plastic micro in second level condenser (605 ') heated, into second level sprayer (603 ') In the airduct conical pipe of number draining placing flat, then from tubaeform in the lower wall of the second level sprayer (603 ') conical air pipe Tuyere blow out, from the lower wall of the calcium chloride solution conical pipe of second level sprayer (603 ') bell-shaped nozzle ejection chlorine The drop for changing calcium solution blows out vaporific, the second level foamed alloy filter of water vapour under the action of the forces of the wind through after heating (604 '), water when through second level foamed alloy filter (604 ') after heating of the drop with calcium chloride is heated gasification Into water vapour, solid chlorine calcium powder is stayed on the second level foamed alloy filter (604 ') after heating;Through after heating The water vapour of second level foamed alloy filter (604 '), into second level condenser (605 '), outside plastic micro Through when be condensed into pure water, then flow into purifying water pool (8) it is inner;Third level flash distillation liquid feeding pump (601 ") flashes the second level The inner calcium chloride solution of tank (602 ') extracts the calcium chloride of the number draining placing flat of feeding third level sprayer (603 ") after pressurization out In solution conical pipe, then from the bell-shaped nozzle in the lower wall of the calcium chloride solution conical pipe of third level sprayer (603 ") Spray, the spiral rifling on bell-shaped nozzle inwall can make the calcium chloride solution of ejection scatter;The 3rd of air blower (606) blowout After part wind passes through a branch of plastic micro in third level condenser (605 ") heated, into third level sprayer (603 ") In the airduct conical pipe of number draining placing flat, then from the loudspeaker in the lower wall of the conical air pipe of third level sprayer (603 ") Shape tuyere blow out, from the lower wall of third level sprayer (603 ") calcium chloride solution conical pipe bell-shaped nozzle ejection chlorine The drop for changing calcium solution blows out vaporific, the third level foamed alloy filter of water vapour under the action of the forces of the wind through after heating (604 "), water when through third level foamed alloy filter (604 ") after heating of the drop with calcium chloride is heated gasification Into water vapour, solid chlorine calcium powder is stayed on the third level foamed alloy filter (604 ") after heating;Through after heating The water vapour of third level foamed alloy filter (604 "), into third level condenser (605 "), outside plastic micro Through when be condensed into pure water, then flow into purifying water pool (8) it is inner;Pure water pump (16) is inner pure of purifying water pool (8) Water is closed after extracting out by rinsing electromagnetic water valve (30) from the top flushing first order foam of first order foamed alloy filter (604) Gold filter device (604), the top flushing second level foamed alloy filter from second level foamed alloy filter (604 ') (604 "), the top flushing third level foamed alloy filter (604 ") from third level foamed alloy filter (604 ");Chlorination Calcium solution force (forcing) pump (15) is extracted after pressurization dense calcium chloride solution through superchlorination calcium solution out from third level flash tank (602 ") is inner It is inner that pressurized canister electromagnetism liquid feed valve (28) enters calcium chloride solution pressurized canister (7).
3. positive osmosis industry sewage water treatment method, it is characterised in that:Light trade effluent pump (11) is removed filtering and activated carbon is passed through Light trade effluent after smelly processing is extracted out from light trade effluent pond (9), by the light trade effluent entering water electromagnetic valve of opening (20) light trade effluent pressurized canister (1) is entered;The compressed air come out from air compressor (17) is entered by Non-return air valve (22) Enter the air pressure that the baroceptor being equipped with the top of air accumulator (18), air accumulator (18) detects the inner compressed air of air accumulator (18) Stop the electricity of air compressor (17) when reaching setting hyperbar value, Non-return air valve (22) can prevent the inner compression of air accumulator (18) Air lets out from the air compressor (17) of internal machine, and the baroceptor being equipped with the top of air accumulator (18) detects gas storage The air pressure of the inner compressed air of tank (18) then starts air compressor (17) when reaching setting low pressure value;Go out from air accumulator (18) It is dirty that the compressed air come enters light industry after Water Tank electromagnetic intake valve (23), from light trade effluent pressurized canister (1) top Water pressurized canister (1), it is inner that light trade effluent pressurized canister (1) detects light trade effluent pressurized canister (1) equipped with sewage level sensor The water level of trade effluent stop light trade effluent pump (11) when reaching setting high watermark value and close light trade effluent to intake electromagnetism Valve (20), light trade effluent pressurized canister (1) detects the inner industry of light trade effluent pressurized canister (1) equipped with sewage level sensor The water level of sewage stops when reaching setting low water level value, starts trade effluent pump (11) and opens light trade effluent entering water electromagnetic valve (20);It is dirty that light trade effluent pressurized canister (1) detects the inner industry of light trade effluent pressurized canister (1) equipped with sewage pressure sensor The pressure of water opens Water Tank electromagnetic intake valve (23) when reaching setting low pressure values, and compressed air is from light trade effluent pressurized canister (1) top enters light trade effluent pressurized canister (1), and light trade effluent pressurized canister (1) is detected light equipped with sewage pressure sensor The pressure of the inner trade effluent of trade effluent pressurized canister (1) closes Water Tank electromagnetic intake valve when reaching setting high pressure values (23);It is dirty that light trade effluent pressurized canister (1) detects the inner industry of light trade effluent pressurized canister (1) equipped with sewage pressure sensor The pressure of water opens Water Tank electromagnetic exhaust valve when exceeding setting high pressure values, and compressed air is from light trade effluent pressurized canister (1) The blast pipe discharge at top, light trade effluent pressurized canister (1) detects light trade effluent pressurized canister equipped with sewage pressure sensor (1) Water Tank electromagnetic exhaust valve is closed when the pressure of inner trade effluent reaches setting high pressure values;From the pressurization of light trade effluent The light trade effluent that tank (1) bottom comes out enters a positive infiltration from the upper end of a positive osmosis industry sewage-treatment plant (2) Film core, the trade effluent come out from the lower end of a forward osmosis membrane core of a positive osmosis industry sewage-treatment plant (2) passes through A number trade effluent water outlet electric control valve (21), enters No. two from the upper end of No. two positive osmosis industry sewage-treatment plants (2 ') Forward osmosis membrane core, the industry come out from the lower end of No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants (2 ') is dirty Water is by No. two trade effluent water outlet electric control valves (21 '), from the upper end of No. three positive osmosis industry sewage-treatment plants (2 ") Into No. three forward osmosis membrane cores, come out from the lower end of No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants (2 ") Dense trade effluent pond (10) of the trade effluent by the discharge of No. three trade effluent water outlet electric control valves (21 ") it is inner;In 0 DEG C of chlorine The solubility for changing calcium is 59.5 grams, is 74.5 grams in the solubility of 20 DEG C of calcium chloride, the concentration of saturation calcium chloride solution is at least Ten times of trade effluent concentration, calcium chloride solution is used as the positive infiltration liquation used in positive osmosis industry sewage-treatment plant, institute The positive osmotic pressure produced is very big;The dense calcium chloride solution prepared is put into calcium chloride solution pressurized canister (7) inner;Dense chlorination Calcium solution enters chlorine after calcium chloride solution force (forcing) pump (15) pressurization through superchlorination calcium solution pressurized canister electromagnetism liquid feed valve (28) Change calcium solution pressurized canister (7) is inner, and the compressed air come out from air accumulator (18) passes through calcium chloride solution tank electromagnetic intake valve (24) Afterwards, calcium chloride solution pressurized canister (7) is entered at the top of calcium chloride solution pressurized canister (7), calcium chloride solution pressurized canister (7) is equipped with The liquid level that calcium chloride solution liquid level sensor detects the inner calcium chloride solution of calcium chloride solution pressurized canister (7) reaches the high liquid of setting Stop the electricity of calcium chloride solution force (forcing) pump (15) during position and close calcium chloride solution pressurized canister electromagnetism liquid feed valve (28), calcium chloride solution The calcium chloride solution liquid level sensor that pressurized canister (7) is equipped with detects the inner calcium chloride solution of calcium chloride solution pressurized canister (7) Liquid level then starts calcium chloride solution force (forcing) pump (15) and opens calcium chloride solution pressurized canister electromagnetism feed liquor when reaching setting low liquid level Valve (28);The calcium chloride solution pressure sensor that calcium chloride solution pressurized canister (7) is equipped with detects calcium chloride solution pressurized canister (7) In calcium chloride solution pressure reach setting high pressure when close calcium chloride solution pressurized canister electromagnetic intake valve (24), calcium chloride It is molten that the calcium chloride solution pressure sensor that solution pressurized canister (7) is equipped with detects the inner calcium chloride of calcium chloride solution pressurized canister (7) The pressure of liquid then opens calcium chloride solution pressurized canister electromagnetic intake valve (24) when reaching setting low-pressure;Calcium chloride solution pressurized canister (7) pressure that the calcium chloride solution pressure sensor being equipped with detects the inner calcium chloride solution of calcium chloride solution pressurized canister (7) surpasses Open calcium chloride solution pressurized canister electric feed liquor magnetic air bleeding valve when crossing setting high pressure, compressed air is from calcium chloride solution pressurized canister (7) the blast pipe discharge for the calcium chloride solution pressurized canister (7) that top is equipped with, the calcium chloride that calcium chloride solution pressurized canister (7) is equipped with Solution pressure sensor detect the inner calcium chloride solution of calcium chloride solution pressurized canister (7) pressure reach setting high pressure when then Close the electric feed liquor magnetic air bleeding valve of calcium chloride solution pressurized canister;The calcium chloride solution come out from calcium chloride solution pressurized canister (7) bottom Calcium chloride solution pressurized canister electromagnetism liquid valve (29) by opening is under No. three positive osmosis industry sewage-treatment plants (2 ") End enters in space between three extra shells and No. three forward osmosis membrane cores, from No. three positive osmosis industry sewage-treatment plants (2 ") The calcium chloride solution that space upper end between three extra shells and No. three forward osmosis membrane cores comes out, works are just permeated through piping from No. two The lower end of industry sewage-treatment plant (2 ') enters in the space between two extra shells and No. two forward osmosis membrane cores, from No. two positive infiltrations The calcium chloride solution that space upper end between the two extra shells and No. two forward osmosis membrane cores of industrial sewage processing unit (2 ') comes out, Enter through piping from the lower end of a positive osmosis industry sewage-treatment plant (2) between an extra shell and a forward osmosis membrane core Space in;In space between the three extra shells and No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants (2 ") The concentration of calcium chloride solution and the industry dirt in No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants (2 ") The pure water that the ratio between water concentration is related in No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants (2 ") is passed through At the positive osmotic pressure of No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants (2 "), No. three positive osmosis industry sewage The pressure for managing the trade effluent in No. three forward osmosis membrane cores of device (2 ") passes through No. three positive osmosis industry sewage plus pure water The positive osmotic pressure of No. three forward osmosis membrane cores of processing unit (2 "), is filled equal to pure water through No. three positive osmosis industry sewage disposals The pressure of No. three forward osmosis membrane cores of (2 ") is put, No. two trade effluent water outlet electric control valves (21 ') of regulation and No. three industry are dirty Water water outlet electric control valve (21 ") namely have adjusted No. three forward osmosis membranes of No. three positive osmosis industry sewage-treatment plants (2 ") In trade effluent pressure, so as to have adjusted pure water through No. three of No. three positive osmosis industry sewage-treatment plants (2 ") just The sky that permeable membrane core enters between the three extra shells and No. three forward osmosis membrane cores of No. three positive osmosis industry sewage-treatment plants (2 ") Quantity in gap, so as to have influence on into two extra shells of No. two positive osmosis industry sewage-treatment plants (2 ') and No. two positive infiltrations The concentration of the calcium chloride solution in space between film core;Two extra shells of No. two positive osmosis industry sewage-treatment plants (2 ') with The concentration of the calcium chloride solution in space between No. two forward osmosis membrane cores and No. two positive osmosis industry sewage-treatment plants (2 ') No. two forward osmosis membrane cores in the ratio between trade effluent concentration be related to the two of No. two positive osmosis industry sewage-treatment plants (2 ') Pure water in number forward osmosis membrane core through No. two positive osmosis industry sewage-treatment plants (2 ') No. two forward osmosis membrane cores just The pressure of trade effluent in osmotic pressure, No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants (2 ') is plus pure Water purification is worn through the positive osmotic pressure of No. two forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants (2 ') equal to pure water The pressure of No. three forward osmosis membrane cores of No. two positive osmosis industry sewage-treatment plants (2 ') is crossed, a number trade effluent of regulation goes out water power Dynamic regulating valve (21) and No. two trade effluent water outlet electric control valves (21 ') namely have adjusted at No. two positive osmosis industry sewage The pressure of the trade effluent in No. three forward osmosis membranes of device (2 ') is managed, so as to have adjusted pure water through No. two positive osmosis industries No. two forward osmosis membrane cores of sewage-treatment plant (2 ') enter two extra shells of No. two positive osmosis industry sewage-treatment plants (2 ') The quantity in space between No. two forward osmosis membrane cores, so as to have influence on into a positive osmosis industry sewage-treatment plant (2) concentration of the calcium chloride solution in the space between an extra shell and a forward osmosis membrane core;If light trade effluent adds Pressure tank (1) reaches setting equipped with the water level that sewage level sensor detects the inner trade effluent of light trade effluent pressurized canister (1) Stop during low water level value, start trade effluent pump (11) and open after light trade effluent entering water electromagnetic valve (20), light industry is dirty quickly Water pressurized canister (1) just reaches equipped with the water level that sewage level sensor detects the inner trade effluent of light trade effluent pressurized canister (1) To setting high watermark value, illustrate that the forward osmosis membrane core of positive osmosis industry sewage-treatment plant has been blocked, it is necessary to align infiltration work The forward osmosis membrane core of industry sewage-treatment plant is backwashed;Backwash process is as follows:Stop light trade effluent pump (11) and closing Light trade effluent entering water electromagnetic valve (20), stops calcium chloride solution force (forcing) pump (15) and closes calcium chloride solution pressurized canister electromagnetism feed liquor Valve (28), calcium chloride solution pressurized canister electromagnetism liquid valve (29) and light calcium chloride solution electromagnetism liquid valve (25), open three instead Electromagnetic intake valve is rinsed, the compressed air come out from air accumulator (18) passes through three backwash electromagnetic intake valves and three unidirectional liquid After valve, respectively from the lower end of three positive osmosis industry sewage-treatment plants enter three positive osmosis industry sewage-treatment plants outside In space between shell and forward osmosis membrane core, then compressed air is each passed through three positive osmosis industry sewage-treatment plants again Forward osmosis membrane core wall enters on three forward osmosis membrane cores, the forward osmosis membrane core for blowing logical three positive osmosis industry sewage-treatment plants Micropore;After backwash terminates, start light trade effluent pump (11) and open light trade effluent entering water electromagnetic valve (20), start chlorination Calcium solution force (forcing) pump (15) and opening calcium chloride solution pressurized canister electromagnetism liquid feed valve (28), calcium chloride solution pressurized canister electromagnetism go out liquid Valve (29) and light calcium chloride solution electromagnetism liquid valve (25), close three backwash electromagnetic intake valves;Fruit need not align infiltration The forward osmosis membrane core of industrial sewage processing unit is backwashed, from No. one of a positive osmosis industry sewage-treatment plant (2) The calcium chloride solution that space upper end between shell and a forward osmosis membrane core comes out passes through light calcium chloride solution electromagnetism liquid valve (25) enter in quick lime reactor (3), calcium lime powder is delivered into quick lime reactor (3) from quick lime pipe (31), it is raw The chemical reaction of quick lime and water in quick lime reactor (3) is accelerated in the lime stirrer work being equipped with lime reaction kettle (3), Calcium oxide occurs chemical reaction generation calcium hydroxide with the water in calcium chloride solution and discharged in quick lime reactor (3) Substantial amounts of heat;The slaked lime slurry come out from the funnel of quick lime reactor (3) bottom is led to after lime slurry pump (12) pressurization Cross the hydraulic pressure butterfly valve (27) opened to enter in a lime white centrifugal dehumidifier (4), wait a lime white centrifugal dehydration Device (4) fills a number hydraulic pressure butterfly valve (27) of closing after slaked lime slurry, No. two hydraulic pressure butterfly valves (27 ') is then opened, from quick lime The slaked lime slurry that the funnel of reactor (3) bottom comes out passes through No. two hydraulic pressure butterfly valves of opening after lime slurry pump (12) pressurization (27 ') enter in No. two lime white centrifugal dehumidifiers (4 ');Start a lime white centrifugal dehumidifier (4), from a stone The calcium chloride solution containing micro calcium hydroxide that mortar centrifugal dehumidifier (4) comes out enters after neutralizing pump (13) pressurization In neutralization reaction kettle (5);The dehydration for the first time of a number lime white centrifugal dehumidifier (4) terminates, a lime white centrifugal dehydration dress Put (4) to shut down, start pure water pump (16), pure water pump (16) extracts pure water by opening from purifying water pool (8) A pure water solenoid valve (26) flow into a stone in a lime white centrifugal dehumidifier (4) after the dehydration of the first magnetic of immersion Slaked lime slurry in mortar centrifugal dehumidifier (4), then starts a lime white centrifugal dehumidifier (4) and slaked lime slurry is entered Second of dehydration of row, is next round being released by twice dehydration white lime mud from a lime white centrifugal dehumidifier (4) Slaked lime slurry charging is prepared;No. two hydraulic pressure butterfly valves of closing after slaked lime slurry are filled Deng No. two lime white centrifugal dehumidifiers (4 ') (27 '), then open a hydraulic pressure butterfly valve (27), and the slaked lime slurry come out from the funnel of quick lime reactor (3) bottom is passed through Entered after lime slurry pump (12) pressurization by a hydraulic pressure butterfly valve (27) of opening in a lime white centrifugal dehumidifier (4); Start No. two lime white centrifugal dehumidifiers (4 '), calcium hydroxide is slightly soluble in water, from No. two lime white centrifugal dehumidifiers (4 ') The calcium chloride solution containing micro calcium hydroxide out enters in neutralization reaction kettle (5) after neutralizing pump (13) pressurization;Two Dehydration terminates for the first time, No. two lime white centrifugal dehumidifiers (4 ') shut down, pure for number lime white centrifugal dehumidifier (4 ') Clarified water pump (16) extracts pure water from purifying water pool (8) and flows into No. two stones by No. two pure water solenoid valves (26 ') of opening The white lime in No. two lime white centrifugal dehumidifiers (4 ') after immersion is dehydrated for the first time in mortar centrifugal dehumidifier (4 ') Slurry, then starts No. two lime white centrifugal dehumidifiers (4 '), to the white lime in No. two lime white centrifugal dehumidifiers (4 ') Slurry carries out second and is dehydrated, the white lime mud Jing Guo twice dehydration from the ripe stone in No. two lime white centrifugal dehumidifiers (4 ') Plaster is released, prepared for the charging of next round slaked lime slurry, a lime white centrifugal dehumidifier (4) and No. two lime white centrifugations Dehydration device (4 ') is dehydrated to the slaked lime slurry come out from quick lime reactor (3) in turn;It is de- from a lime white centrifugation The white lime mud containing calcium chloride released in water installations (4) and No. two lime white centrifugal dehumidifiers (4 ') is to build well Material is built, calcium chloride is the main additive of cement, is a kind of water reducer, and white lime, cement, sand are mixed in proportion With water and mud, then with the mud covering become reconciled indoors brick wall wall and concrete ceiling;Chlorine is in hydrogen burner Burning generates hydrogen chloride gas and discharges substantial amounts of heat in gas, and the hydrogen chloride gas produced in burner, which enters, to be neutralized Being dissolved in reactor (5) in calcium chloride solution turns into hydrochloric acid, the calcium hydroxide in hydrogen chloride and calcium chloride solution in hydrochloric acid Generation chemical reaction generates calcium chloride and water, concurrently bears substantial amounts of heat;Or hydrochloric acid pump (14) is taken out from hydrochloric acid tank (19) Concentrated hydrochloric acid is taken, the concentrated hydrochloric acid come out from hydrochloric acid pump (14) enters in neutralization reaction kettle (5), and the hydrogen chloride and calcium chloride in hydrochloric acid are molten Calcium hydroxide in liquid occurs chemical reaction generation calcium chloride and water, concurrently bears substantial amounts of heat;Filled on neutralization reaction kettle (5) Have to neutralize the neutralization agitator being equipped with agitator and work and can accelerate the hydrogen chloride and calcium chloride solution in neutralization reaction kettle (5) In calcium hydroxide chemically react;Pass through atomizing from reactor (5) temperature for coming out very high calcium chloride solution is neutralized Enter first order sprayer after first order flash distillation liquid feeding pump (601) pressurization of calcium chloride solution multistage flash evaporation enrichment facility (6) (603) in the calcium chloride solution conical pipe of number draining placing flat, then from the calcium chloride solution of first level sprayer (603) Bell-shaped nozzle in the lower wall of conical pipe sprays, and the spiral rifling on bell-shaped nozzle inwall can make the calcium chloride of ejection molten Liquid scatters;The Part I wind of air blower (606) blowout passes through a branch of plastic micro in first order condenser (605) to be heated Afterwards, into the airduct conical pipe of the number draining placing flat of first order sprayer (603), then from first order sprayer (603) Conical air pipe lower wall on the blowout of tubaeform tuyere, from first order sprayer (603) calcium chloride solution conical pipe The drop that bell-shaped nozzle in lower wall sprays calcium chloride solution is blown out vaporific, and water vapour is under the action of the forces of the wind through heating First order foamed alloy filter (604) afterwards, the drop with calcium chloride is through the first order foamed alloy mistake after heating Water, which is heated, during filter (604) is gasificated into water vapour, the first order foamed alloy filtering that solid chlorine calcium powder is stayed in after heating On device (604);Through the water vapour of the first order foamed alloy filter (604) after heating, into first order condenser (605) In, pure water is condensed into when being passed through outside plastic micro, purifying water pool (8) is then flowed into inner;The second level flashes feed liquor Pump (601 ') extracts the inner calcium chloride solution of first order flash tank (602) out the number of feeding second level sprayer (603 ') after pressurization In the calcium chloride solution conical pipe of draining placing flat, then under the calcium chloride solution conical pipe of second level sprayer (603 ') Bell-shaped nozzle on the wall of side sprays, and the spiral rifling on bell-shaped nozzle inwall can make the calcium chloride solution of ejection scatter;Drum After the Part II wind of blower fan (606) blowout passes through a branch of plastic micro in second level condenser (605 ') heated, enter In the airduct conical pipe of second level sprayer (603 ') number draining placing flat, then from the second level sprayer (603 ') conical air pipe Lower wall on tubaeform tuyere blowout, from the lower wall of the calcium chloride solution conical pipe of second level sprayer (603 ') Bell-shaped nozzle spray calcium chloride solution drop blow out it is vaporific, water vapour under the action of the forces of the wind through heating after second Level foamed alloy filter (604 '), the drop with calcium chloride is through the second level foamed alloy filter after heating Water, which is heated, when (604 ') is gasificated into water vapour, the second level foamed alloy filter that solid chlorine calcium powder is stayed in after heating On (604 ');Through the water vapour of the second level foamed alloy filter (604 ') after heating, into second level condenser In (605 '), pure water is condensed into when being passed through outside plastic micro, purifying water pool (8) is then flowed into inner;The third level dodges Steam liquid feeding pump (601 ") and the inner calcium chloride solution of second level flash tank (602 ') is extracted out feeding third level sprayer after pressurization (603 ") in the calcium chloride solution conical pipe of number draining placing flat, then bored from the calcium chloride solution of third level sprayer (603 ") Bell-shaped nozzle in the lower wall of shape pipe sprays, and the spiral rifling on bell-shaped nozzle inwall can make the calcium chloride solution of ejection Scatter;The Part III wind of air blower (606) blowout passes through a branch of plastic micro in third level condenser (605 ") to be heated Afterwards, into the airduct conical pipe of the number draining placing flat of third level sprayer (603 "), then from third level sprayer In the lower wall of the conical air pipe of (603 ") tubaeform tuyere blowout, from third level sprayer (603 ") calcium chloride solution cone The drop that bell-shaped nozzle in the lower wall of shape pipe sprays calcium chloride solution is blown out vaporific, and water vapour is worn under the action of the forces of the wind The third level foamed alloy filter (604 ") crossed after heating, the drop with calcium chloride is through the third level foam after heating Water, which is heated, during alloy filter (604 ") is gasificated into water vapour, and the third level foam that solid chlorine calcium powder is stayed in after heating is closed On gold filter device (604 ");It is cold into the third level through the water vapour of the third level foamed alloy filter (604 ") after heating In condenser (605 "), pure water is condensed into when being passed through outside plastic micro, purifying water pool (8) is then flowed into inner;Chlorination Calcium solution force (forcing) pump (15) is extracted after pressurization dense calcium chloride solution through superchlorination calcium solution out from third level flash tank (602 ") is inner Pressurized canister electromagnetism liquid feed valve (28) is recycled into calcium chloride solution pressurized canister (7) is inner;Foamed alloy filter water is accumulated The micropore of too many solid calcium chloride plug-back plug foamed alloy filter is, it is necessary to which foamed alloy filter, pure water are rinsed in timing Pump (16) the inner pure water of purifying water pool (8) is extracted out after by rinsing electromagnetic water valve (30) from first order foamed alloy filter (604) top is rinsed first order foamed alloy filter (604), rushed from the top of second level foamed alloy filter (604 ') Wash second level foamed alloy filter (604 "), rinse third level foam from the top of third level foamed alloy filter (604 ") Alloy filter (604 ").
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CN109354123A (en) * 2018-11-23 2019-02-19 张英华 Positive penetration sea water desalinization equipment and control method
CN109354124A (en) * 2018-11-23 2019-02-19 张英华 Positive osmosis industry sewage disposal device and control method

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CN104150669A (en) * 2014-08-22 2014-11-19 国家电网公司 Thermal power plant desulphurization wastewater purification system and purification method
CN104402160A (en) * 2014-11-28 2015-03-11 山东省环科院环境工程有限公司 Energy-saving coal chemical engineering wastewater deep treatment system and treatment method thereof
CN204874164U (en) * 2015-07-07 2015-12-16 北京沃特尔水技术股份有限公司 Zero release processing system of desulfurization waste water

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CN103819040A (en) * 2014-02-25 2014-05-28 张英华 Forward-osmosis industrial sewage treatment equipment and technical process thereof
CN104150669A (en) * 2014-08-22 2014-11-19 国家电网公司 Thermal power plant desulphurization wastewater purification system and purification method
CN104402160A (en) * 2014-11-28 2015-03-11 山东省环科院环境工程有限公司 Energy-saving coal chemical engineering wastewater deep treatment system and treatment method thereof
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109354123A (en) * 2018-11-23 2019-02-19 张英华 Positive penetration sea water desalinization equipment and control method
CN109354124A (en) * 2018-11-23 2019-02-19 张英华 Positive osmosis industry sewage disposal device and control method

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