CN107051223A - A kind of preparation method of high stable ceramic composite membrane - Google Patents
A kind of preparation method of high stable ceramic composite membrane Download PDFInfo
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- CN107051223A CN107051223A CN201710314515.2A CN201710314515A CN107051223A CN 107051223 A CN107051223 A CN 107051223A CN 201710314515 A CN201710314515 A CN 201710314515A CN 107051223 A CN107051223 A CN 107051223A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/10—Supported membranes; Membrane supports
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
Abstract
A kind of preparation method of high stable ceramic composite membrane, it is to be added to particle diameter in organic solvent or water for 1/2 2/3 ceramic powder of supporting body surface average pore size first, by adding dispersant and thickener, prepare stabilization, finely dispersed metallic suspension slurry, porous ceramic support is put into ceramic particle suspension slurry again and carries out taking out negative pressure soaking paste absorption, ceramic particle can enter in the duct on ceramic supporting body surface, and the duct on ceramic supporting body surface is filled.Secondly, repeat above-mentioned preparation ceramic particle suspension slurry process and take out negative-pressure adsorption process 15 times, the ceramic particle particle diameter used each time is use ceramic particle diameter the last time 1/2 2/3.Finally the ceramic supporting body after modification is carried out after surface clean, is placed in Muffle furnace and is sintered, a kind of hybrid ceramic film layer containing ceramic oxide is generated.
Description
Technical field
The present invention relates to the technology of preparing of ceramic composite membrane.
Background technology
Film is small due to its floor space, and separative efficiency is high, be widely used in the features such as environmentally safe chemical industry, biology,
The fields such as medicine, the energy, environment, metallurgy.Ceramic membrane is because of its even aperture distribution, high mechanical strength, acid and alkali-resistance and corrosion resistance
Well can also it be widely used.The preparation of traditional NF membrane will be in macropore supporting body surface successively repeatedly by particle diameter from big
To the preparation of small multi-layer ceramics film, and often prepare layer of ceramic film, will be through oversintering, it is long to be prepared the cycle, energy consumption
Higher, film inter-layer bonding force is poor.Present invention process is simple, and energy consumption is low, and nanometer film is distributed in macropore support body opening,
Indivedual film properties destructions influence smaller to whole film properties.Secondly, it effectively prevent the problem of adhesion is poor between film layer.
The content of the invention
It is an object of the invention to provide a kind of preparation method of high stable ceramic composite membrane.
The present invention is a kind of preparation method of high stable ceramic composite membrane, and its step is:
(1)The ceramic particle that particle diameter is porous ceramic support mean surface pore size 1/2-2/3 is selected, with solvent for use or water
On the basis of quality, according to percentage by weight be 0.05%-20% be added in organic solvent or water, then using the quality of solvent or water as
Benchmark, sequentially adds dispersant that mass percent is respectively 0.1%-5% and 1%-5% thickener, prepares and be uniformly dispersed, surely
Fixed ceramic particle, which suspends, to be starched.
(2)Porous ceramic support after cleaning is immersed in step(1)In the slurry of preparation, using the side for taking out negative pressure
Method, the ceramic particle in slurry is adsorbed in the duct on porous ceramic support surface;Taken out negative pressure is 0.01-0.1MPa,
Dipping time is to wash the ceramic particle for being attached to excess surface after 10-300s, soaking paste.
(3)In repetition(1)、(2)Process 1-5 times, the ceramic particle particle diameter used each time is the last time to use ceramics
The 1/2-2/3 of particle diameter.
(4)By step(3)In the supporter of filling ceramic powder be put into Muffle furnace and sinter 1-20 at 400-900 DEG C
Hour, generate a kind of Ceramic Composite film layer.
Usefulness of the present invention is:The more traditional film-forming method of the present invention, filming technology is simple, easily operated.2 present invention
Method only needs once sintered, and energy consumption is relatively low, is effectively prevented from traditional film-forming process soaking paste repeatedly and sinters repeatedly to cause energy consumption
Higher the problem of.3 the inventive method film is carried out in fenestra, and prepared membrane stability preferably, effectively prevent traditional system
The problem of adhesion is poor between film layer in membrane process.
Brief description of the drawings
Fig. 1 is the preparation technology flow and common in-situ oxidation flow contrast schematic diagram of the present invention, and Fig. 2 is without high temperature
The ceramic supporting body surface SEM photograph of oxidation.
Embodiment
As shown in figure 1, the present invention is a kind of preparation method of high stable ceramic composite membrane, its step is:
(1)The ceramic particle that particle diameter is porous ceramic support mean surface pore size 1/2-2/3 is selected, with solvent for use or water
Be 0.05% ~ 20% to be added in organic solvent or water according to percentage by weight on the basis of quality, then using the quality of solvent or water as
Benchmark, sequentially adds dispersant and 1% ~ 5% thickener that mass percent is respectively 0.1% ~ 5%, prepares and be uniformly dispersed, surely
Fixed ceramic particle, which suspends, to be starched;
(2)Porous ceramic support after cleaning is immersed in step(1), will using the method for taking out negative pressure in the slurry of preparation
Ceramic particle in slurry is adsorbed in the duct on porous ceramic support surface;Taken out negative pressure is 0.01 ~ 0.1MPa, during soaking paste
Between be 10 ~ 300s, the ceramic particle for being attached to excess surface is washed after soaking paste;
(3)Repeat the above steps(1), step(2)Process 1 ~ 5 time, the ceramic particle particle diameter used each time is the last time
Use the 1/2-2/3 of ceramic particle diameter;
(4)By step(3)In the supporter of filling ceramic powder to be put into Muffle furnace at 400-900 DEG C sintering 1 ~ 20 small
When, generate a kind of Ceramic Composite film layer.
The signified ceramic particle of above-described preparation method is titanium dioxide powder, alundum (Al2O3), zirconia powder, titanium dioxide
Silicon, or two kinds of ceramic powders mixture;It selects the pottery that particle diameter is porous ceramic support mean surface pore size 1/2-2/3
Porcelain particle, addition is on the basis of the quality of solvent for use or water, and the percentage by weight of addition is 0.05%-20%.
Organic solvent described in above-described preparation method is methanol, ethanol or isopropanol, or two kinds therein or three
The mixture planted.
Dispersant described in above-described preparation method is polyethylene, or polymethylacrylic acid, or polyacrylamide, or
Hexadecanyl trimethyl quaternary ammonium salt, or lauryl sodium sulfate, or neopelex, or polyethylene glycol, or it is therein
Mixture in two kinds or three;Its addition is on the basis of the quality of solvent or water, and the mass percent of addition is 0.1%-5%;
Described thickener is methylcellulose, or ethyl cellulose, or polyvinyl alcohol, or polypropylene formic acid esters, or carboxymethyl cellulose
Plain sodium, or two of which or three kinds of mixture;Its addition is on the basis of the quality of solvent or water, the mass percent of addition
For 1%-5%.
The signified porous ceramic support of above-described preparation method is aluminium oxide ceramics, or silicon oxide ceramics, or oxygen
Change titanium ceramics, or zirconia ceramics, or the hybrid ceramic of two or more;Its pore diameter range is 1 μm ~ 15 μm.
The signified range of negative pressure of taking out of above-described preparation method is 0.01-0.1MPa, and dipping time is 10-300s.
The signified sintering temperature of above-described preparation method is 400 ~ 900 DEG C, and sintering time is 1 ~ 20 hour.
Embodiment 1:With porous α-Al2O3Flaky pottery is supporter, and its aperture is 3 μm.
(1)Using water as solvent, on the basis of water quality, it is 1.7 μm of 2%, 0.5% and 1% to be separately added into mass percent
TiO2Particle, polyethyleneimine, ethyl cellulose and sodium carboxymethylcellulose(1:1wt)Mixture, wherein polyethyleneimine are
Dispersant, ethyl cellulose and sodium carboxymethylcellulose(1:1wt)Mixture is thickener;
(2)Porous ceramic support after cleaning is immersed in step(1), will using the method for taking out negative pressure in the slurry of preparation
TiO in slurry2Particle, is adsorbed in the duct on porous ceramic support surface;Taken out negative pressure is 0.03MPa, dipping time
For 40s, the Ti particles for being attached to excess surface are washed after soaking paste;
(3)Select the TiO that particle diameter is 1.1 μm2Particle, repeat step(1), by step(2)In the ceramic support containing Ti particles
Body, which is put into the slurry prepared, to carry out taking out negative pressure soaking paste absorption, by the Ti particle absorptions in slurry in porous ceramic support table
In the duct in face;Taken out negative pressure is 0.02MPa, and dipping time is to wash the TiO for being attached to excess surface after 60s, soaking paste2Grain
Son;
(4)Selection particle diameter is 0.5 μm of TiO again2Particle, repeat step(1), by step(3)In containing two kinds of particle diameters
TiO2The ceramic supporting body of particle, which is put into the slurry prepared, to carry out taking out negative pressure soaking paste absorption, by the TiO in slurry2Particle is inhaled
In the duct for being attached to porous ceramic support surface;Taken out negative pressure is 0.01MPa, and dipping time is to wash after 100s, soaking paste
It is attached to the TiO of excess surface2Particle;
(5)By step(4)The component of middle preparation, which is put into Muffle furnace, carries out knot burning processing, and sintering temperature is 500 DEG C, and the time is
8h.Wherein warming and cooling rate is 1 DEG C/min.It has been successfully prepared out the ceramic membrane of surface compact.
Embodiment 2:Using porous pipe type titanium oxide ceramics as supporter, its aperture is 8 μm.
(1)Using absolute ethyl alcohol as solvent, on the basis of absolute ethyl alcohol quality, mass percent is separately added into for 10%, 2% and
3% 7.3 μm of Al2O3Particle, polyethylene glycol, ethyl cellulose and polyvinyl alcohol(1:1wt)Mixture, wherein polyethyleneimine
For dispersant, ethyl cellulose and sodium carboxymethylcellulose(1:1wt)Mixture is thickener;
(2)Porous ceramic support after cleaning is immersed in step(1), will using the method for taking out negative pressure in the slurry of preparation
Al in slurry2O3Particle, is adsorbed in the duct on porous ceramic support surface;Taken out negative pressure is 0.1MPa, and dipping time is
The Al for being attached to excess surface is washed after 80s, soaking paste2O3Particle;
(3)Select the Al that particle diameter is 3.5 μm2O3Particle, repeat step(1), by step(2)In contain Al2O3The ceramics branch of particle
Support body, which is put into the slurry prepared, to carry out taking out negative pressure soaking paste absorption, by the Al in slurry2O3Particle absorption is in porous ceramic support
In the duct in body surface face;Taken out negative pressure is 0.06MPa, and dipping time is to wash after 100s, soaking paste to be attached to excess surface
Al2O3Particle;
(4)Selection particle diameter is 1.7 μm of Al again2O3Particle, repeat step(1), by step(3)In containing two kinds of particle diameters
Al2O3The ceramic supporting body of particle, which is put into the slurry prepared, to carry out taking out negative pressure soaking paste absorption, by the Al in slurry2O3Particle
Absorption is in the duct on porous ceramic support surface;Taken out negative pressure is 0.03MPa, and dipping time is 150s, is cleaned after soaking paste
Fall to be attached to the Al of excess surface2O3Particle;
(5)By step(4)The component of middle preparation, which is put into Muffle furnace, carries out knot burning processing, and sintering temperature is 650 DEG C, and the time is
6h.Wherein warming and cooling rate is 1 DEG C/min.It has been successfully prepared out the ceramic membrane of surface compact.
Embodiment 3:With porous α-Al2O3Flaky pottery is supporter, and its average pore size is 14 μm.
(1)Using isopropanol as solvent, on the basis of isopropanol quality, it is 19%, 5% and 5% to be separately added into mass percent
8.9 μm of Zirconia particles, polyethyleneimine, ethyl cellulose and sodium carboxymethylcellulose(1:1wt)Mixture, wherein poly- second
Alkene imines is dispersant, ethyl cellulose and sodium carboxymethylcellulose(1:1wt)Mixture is thickener;
(2)Porous ceramic support after cleaning is immersed in step(1), will using the method for taking out negative pressure in the slurry of preparation
Zirconia particles in slurry are adsorbed in the duct on porous ceramic support surface;Taken out negative pressure is 0.3MPa, dipping time
For 150s, the Zirconia particles for being attached to excess surface are washed after soaking paste;
((3)Select the Zirconia particles that particle diameter is 5.8 μm, repeat step(1), by step(2)In the pottery containing Zirconia particles
Porcelain supporter, which is put into the slurry prepared, to be carried out taking out negative pressure soaking paste absorption, and the Zirconia particles in slurry are adsorbed in porous pottery
In the duct of porcelain supporting body surface;Taken out negative pressure is 0.15MPa, and dipping time is to wash after 200s, soaking paste to be attached to surface
Unnecessary Zirconia particles;
(4)Selection particle diameter is 3.5 μm of Zirconia particles, repeat step again(1), by step(3)In containing two kinds of particle diameters
The ceramic supporting body of Zirconia particles, which is put into the slurry prepared, to carry out taking out negative pressure soaking paste absorption, by the zirconium oxide grain in slurry
Sub- absorption is in the duct on porous ceramic support surface;Taken out negative pressure is 0.1MPa, and dipping time is 250s, clear after soaking paste
Wash the Zirconia particles for being attached to excess surface off;
(5)By step(4)The component of middle preparation, which is put into Muffle furnace, carries out knot burning processing, and sintering temperature is 650 DEG C, and the time is
5h.Wherein warming and cooling rate is 1 DEG C/min.It has been successfully prepared out the ceramic membrane of surface compact.
Embodiment 4:With porous α-Al2O3Flaky pottery is supporter, its average pore size is 3 μm.
(1)Using absolute ethyl alcohol as solvent, on the basis of absolute ethyl alcohol quality, it is 2%, 0.5% to be separately added into mass percent
With 1.7 μm of 1% of SiO2Particle, polyethylene glycol, ethyl cellulose and polyvinyl alcohol(1:1wt)Mixture, wherein polyethyleneimine
Amine is dispersant, ethyl cellulose and sodium carboxymethylcellulose(1:1wt)Mixture is thickener;
(2)Porous ceramic support after cleaning is immersed in step(1), will using the method for taking out negative pressure in the slurry of preparation
SiO in slurry2Particle absorption is in the duct on porous ceramic support surface;Taken out negative pressure is 0.03MPa, and dipping time is
The SiO for being attached to excess surface is washed after 100s, soaking paste2Particle;
(3)Select the Al particles that particle diameter is 1.1 μm, repeat step(1), by step(2)In contain SiO2The ceramic support of particle
Body, which is put into the slurry prepared, to carry out taking out negative pressure soaking paste absorption, by the SiO in slurry2Particle absorption is in porous ceramic support
In the duct on surface;Taken out negative pressure is 0.02MPa, and dipping time is to wash the SiO for being attached to excess surface after 70s, soaking paste2
Particle;
(4)The SiO that selection particle diameter is 500nm again2Particle, repeat step(1), by step(3)In containing two kinds of particle diameters
SiO2The ceramic supporting body of particle, which is put into the slurry prepared, to carry out taking out negative pressure soaking paste absorption, by the SiO in slurry2Particle is inhaled
In the duct for being attached to porous ceramic support surface;Taken out negative pressure is 0.01MPa, dipping time be wash after 50s, soaking paste it is attached
The SiO in excess surface2Particle;
(5)By step(4)The component of middle preparation, which is put into Muffle furnace, carries out knot burning processing, and sintering temperature is 500 DEG C, and the time is
8h.Wherein warming and cooling rate is 1 DEG C/min.It has been successfully prepared out the ceramic membrane of surface compact.
Embodiment 5:Using tubular type titanium oxide ceramics as supporter, its average pore size is 8 μm.
(1)Using isopropanol as solvent, on the basis of isopropanol quality, it is 10%, 2% and 3% to be separately added into mass percent
7.3 μm of SiO2Particle, polyethyleneimine, ethyl cellulose and sodium carboxymethylcellulose(1:1wt)Mixture, wherein polyethylene
Imines is dispersant, ethyl cellulose and sodium carboxymethylcellulose(1:1wt)Mixture is thickener;
(2)Porous ceramic support after cleaning is immersed in step(1), will using the method for taking out negative pressure in the slurry of preparation
SiO in slurry2Particle absorption is in the duct on porous ceramic support surface;Taken out negative pressure is 0.15MPa, and dipping time is
The SiO for being attached to excess surface is washed after 100s, soaking paste2Particle;
(3)Select the SiO that particle diameter is 3.5 μm2Particle, repeat step(1), by step(2)In contain SiO2The ceramics branch of particle
Support body, which is put into the slurry prepared, to carry out taking out negative pressure soaking paste absorption, by the SiO in slurry2Particle absorption is in porous ceramic support
In the duct in body surface face;Taken out negative pressure is 0.07MPa, and dipping time is to wash after 150s, soaking paste to be attached to excess surface
SiO2Particle;
(4)Selection particle diameter is 1.7 μm of SiO again2Particle, repeat step(1), by step(3)In containing two kinds of particle diameters
SiO2The ceramic supporting body of particle, which is put into the slurry prepared, to carry out taking out negative pressure soaking paste absorption, by the SiO in slurry2Particle is inhaled
In the duct for being attached to porous ceramic support surface;Taken out negative pressure is 0.05MPa, and dipping time is to wash after 200s, soaking paste
It is attached to the SiO of excess surface2Particle;
(5)By step(4)The component of middle preparation, which is put into Muffle furnace, carries out knot burning processing, and sintering temperature is 700 DEG C, and the time is
6h.Wherein warming and cooling rate is 1 DEG C/min.It has been successfully prepared out the ceramic membrane of surface compact.
Embodiment 6:Using tubular type zirconia ceramics as supporter, its average pore size is 14 μm.
(1)Using water as solvent, on the basis of water quality, it is 8.9 μm of 19%, 5% and 5% to be separately added into mass percent
TiO2Particle(1:1wt), polyethyleneimine, ethyl cellulose and sodium carboxymethylcellulose(1:1wt)Mixture, wherein poly-
Aziridine is dispersant, ethyl cellulose and sodium carboxymethylcellulose(1:1wt)Mixture is thickener;
(2)Porous ceramic support after cleaning is immersed in step(1), will using the method for taking out negative pressure in the slurry of preparation
TiO in slurry2Particle absorption is in the duct on porous ceramic support surface;Taken out negative pressure is 0.28MPa, and dipping time is
The TiO for being attached to excess surface is washed after 150s, soaking paste2Particle;
(3)Select the TiO that particle diameter is 5.8 μm2Particle, repeat step(1), by step(2)In contain TiO2The ceramics branch of particle
Support body, which is put into the slurry prepared, to carry out taking out negative pressure soaking paste absorption, by the TiO in slurry2Particle absorption is in porous ceramic support
In the duct in body surface face;Taken out negative pressure is 0.2MPa, and dipping time is to wash after 200s, soaking paste to be attached to excess surface
TiO2Particle;
(4)Selection particle diameter is 3.5 μm of TiO again2Particle, repeat step(1), by step(3)In containing two kinds of particle diameters
TiO2The ceramic supporting body of particle, which is put into the slurry prepared, to carry out taking out negative pressure soaking paste absorption, by the TiO in slurry2Particle is inhaled
In the duct for being attached to porous ceramic support surface;Taken out negative pressure is 0.1MPa, dipping time be wash after 250s, soaking paste it is attached
The TiO in excess surface2Particle;
(5)By step(4)The component of middle preparation, which is put into Muffle furnace, carries out knot burning processing, and sintering temperature is 800 DEG C, and the time is
5h.Wherein warming and cooling rate is 1 DEG C/min.It has been successfully prepared out the ceramic membrane of surface compact.
Claims (7)
1. a kind of preparation method of high stable ceramic composite membrane, it is characterised in that its step is:
(1)The ceramic particle that particle diameter is porous ceramic support mean surface pore size 1/2-2/3 is selected, with solvent for use or water
Be 0.05% ~ 20% to be added in organic solvent or water according to percentage by weight on the basis of quality, then using the quality of solvent or water as
Benchmark, sequentially adds dispersant and 1% ~ 5% thickener that mass percent is respectively 0.1% ~ 5%, prepares and be uniformly dispersed, surely
Fixed ceramic particle, which suspends, to be starched;
(2)Porous ceramic support after cleaning is immersed in step(1), will using the method for taking out negative pressure in the slurry of preparation
Ceramic particle in slurry is adsorbed in the duct on porous ceramic support surface;Taken out negative pressure is 0.01 ~ 0.1MPa, during soaking paste
Between be 10 ~ 300s, the ceramic particle for being attached to excess surface is washed after soaking paste;
(3)Repeat the above steps(1), step(2)Process 1 ~ 5 time, the ceramic particle particle diameter used each time is the last time
Use the 1/2-2/3 of ceramic particle diameter;
(4)By step(3)In the supporter of filling ceramic powder to be put into Muffle furnace at 400-900 DEG C sintering 1 ~ 20 small
When, generate a kind of Ceramic Composite film layer.
2. the preparation method of high stable ceramic composite membrane according to claim 1, it is characterised in that signified ceramic particle is
The mixture of titanium dioxide powder, alundum (Al2O3), zirconia powder, silica, or two kinds of ceramic powders;Its select particle diameter be
Porous ceramic support mean surface pore size 1/2-2/3 ceramic particle, addition on the basis of the quality of solvent for use or water,
The percentage by weight of addition is 0.05%-20%.
3. the preparation method of high stable ceramic composite membrane according to claim 1, it is characterised in that described organic solvent
For the mixture of methanol, ethanol or isopropanol, or two or three therein.
4. the preparation method of high stable ceramic composite membrane according to claim 1, it is characterised in that described dispersant is
Polyethylene, or polymethylacrylic acid, or polyacrylamide, or hexadecanyl trimethyl quaternary ammonium salt, or lauryl sodium sulfate, or
Mixture in neopelex, or polyethylene glycol, or two kinds therein or three;Its addition is with the matter of solvent or water
On the basis of amount, the mass percent of addition is 0.1%-5%;Described thickener is methylcellulose, or ethyl cellulose, or poly-
Vinyl alcohol, or polypropylene formic acid esters, or sodium carboxymethylcellulose, or two of which or three kinds of mixture;Its addition is with molten
On the basis of the quality of agent or water, the mass percent of addition is 1%-5%.
5. the preparation method of high stable ceramic composite membrane according to claim 1, it is characterised in that signified porous ceramics
Supporter is aluminium oxide ceramics, or silicon oxide ceramics, or titanium oxide ceramics, or zirconia ceramics, or the mixing of two or more
Ceramics;Its pore diameter range is 1 μm ~ 15 μm.
6. the preparation method of high stable ceramic composite membrane according to claim 1, it is characterised in that signified takes out negative pressure model
Enclose for 0.01-0.1MPa, dipping time is 10-300s.
7. the preparation method of high stable ceramic composite membrane according to claim 1, it is characterised in that signified sintering temperature
For 400 ~ 900 DEG C, sintering time is 1 ~ 20 hour.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109107396A (en) * | 2018-08-20 | 2019-01-01 | 南京工业大学 | A method of mine water is handled using fly ash base microfiltration membranes negative-pressure ward |
TWI770773B (en) * | 2020-12-25 | 2022-07-11 | 信紘科技股份有限公司 | Method of manufacturing overmolding material to prevent overflow loss during high frequency or ultra-high frequency signal transmission |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN101985084A (en) * | 2010-11-18 | 2011-03-16 | 南京工业大学 | Preparation method for ceramic Ti-Al alloy composite membrane |
CN104099557A (en) * | 2014-07-21 | 2014-10-15 | 兰州理工大学 | Preparation method of zero-defect porous ceramic/Ti-Al alloy composite membrane |
CN105854633A (en) * | 2016-05-27 | 2016-08-17 | 成都易态科技有限公司 | Porous film and preparation method thereof |
-
2017
- 2017-05-06 CN CN201710314515.2A patent/CN107051223B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101985084A (en) * | 2010-11-18 | 2011-03-16 | 南京工业大学 | Preparation method for ceramic Ti-Al alloy composite membrane |
CN104099557A (en) * | 2014-07-21 | 2014-10-15 | 兰州理工大学 | Preparation method of zero-defect porous ceramic/Ti-Al alloy composite membrane |
CN105854633A (en) * | 2016-05-27 | 2016-08-17 | 成都易态科技有限公司 | Porous film and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109107396A (en) * | 2018-08-20 | 2019-01-01 | 南京工业大学 | A method of mine water is handled using fly ash base microfiltration membranes negative-pressure ward |
TWI770773B (en) * | 2020-12-25 | 2022-07-11 | 信紘科技股份有限公司 | Method of manufacturing overmolding material to prevent overflow loss during high frequency or ultra-high frequency signal transmission |
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