CN107045040A - Indoor toxic gas automatic detection and purification air interchanger - Google Patents

Indoor toxic gas automatic detection and purification air interchanger Download PDF

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CN107045040A
CN107045040A CN201611272304.9A CN201611272304A CN107045040A CN 107045040 A CN107045040 A CN 107045040A CN 201611272304 A CN201611272304 A CN 201611272304A CN 107045040 A CN107045040 A CN 107045040A
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gas
formaldehyde
electric
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led
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汪家琳
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0031General constructional details of gas analysers, e.g. portable test equipment concerning the detector comprising two or more sensors, e.g. a sensor array
    • G01N33/0032General constructional details of gas analysers, e.g. portable test equipment concerning the detector comprising two or more sensors, e.g. a sensor array using two or more different physical functioning modes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F11/00Control or safety arrangements
    • F24F11/30Control or safety arrangements for purposes related to the operation of the system, e.g. for safety or monitoring
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F2110/00Control inputs relating to air properties
    • F24F2110/50Air quality properties
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0062General constructional details of gas analysers, e.g. portable test equipment concerning the measuring method or the display, e.g. intermittent measurement or digital display
    • G01N33/0063General constructional details of gas analysers, e.g. portable test equipment concerning the measuring method or the display, e.g. intermittent measurement or digital display using a threshold to release an alarm or displaying means
    • GPHYSICS
    • G08SIGNALLING
    • G08BSIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
    • G08B21/00Alarms responsive to a single specified undesired or abnormal condition and not otherwise provided for
    • G08B21/02Alarms for ensuring the safety of persons
    • G08B21/12Alarms for ensuring the safety of persons responsive to undesired emission of substances, e.g. pollution alarms
    • G08B21/14Toxic gas alarms
    • GPHYSICS
    • G08SIGNALLING
    • G08BSIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
    • G08B21/00Alarms responsive to a single specified undesired or abnormal condition and not otherwise provided for
    • G08B21/02Alarms for ensuring the safety of persons
    • G08B21/12Alarms for ensuring the safety of persons responsive to undesired emission of substances, e.g. pollution alarms
    • G08B21/16Combustible gas alarms

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Toxicology (AREA)
  • Immunology (AREA)
  • Business, Economics & Management (AREA)
  • Analytical Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Pathology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Food Science & Technology (AREA)
  • Biochemistry (AREA)
  • Emergency Management (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Atmospheric Sciences (AREA)
  • Quality & Reliability (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)

Abstract

Indoor toxic gas automatic detection is made up of with purification air interchanger gas sensor, formaldehyde gas inductor, combustible gas detector, power supply, rectifier, inverter, amplifier, magnetic valve, electric heating piece, electric fan, control circuit, warning circuit and photocatalyst, silicon window, crust of the device;Can automatic detection, purification carbon monoxide, gas, coal gas, ethanol, the poisonous, fuel gas such as formaldehyde indoors, while using ultraviolet catalyzed photocatalyst technology self-purging formaldehyde, using the charcoal absorption through lime water process, utilizing the ventilation of silicon window;When concentration reaches capacity alarm.So as to reach the purpose of room air safety.It is more more superior than single gas detection equipment and air cleaning facility, and provided with inverter and rectifier, can DC-AC mutually use, it is applied widely, easy to use.Also, provided with screen cover is covered, uv damage can be prevented.It is widely used in house, automobile, public place of entertainment, the air detection in warehouse, purification and changed.

Description

Indoor toxic gas automatic detection and purification air interchanger
Technical field the present invention relates to field of Environment Protection, especially air detection and field of purification, particularly house, automobile, Public place of entertainment, the indoor toxic gas automatic detection in warehouse and purification air interchanger.It is sensed by gas sensor, formaldehyde gas Device, combustible gas detector, direct current and/or exchange mutually with power supply, control circuit, warning circuit and utilize ultraviolet catalyzed light to touch Matchmaker's purifier, silicon window air interchanger composition;Carbon monoxide, gas, coal gas, ethanol, formaldehyde can have been monitored automatically indoors Deng poison gas and fuel gas, and absorption PM2.5, PM10, particulate matter and nitrogen, sulphur oxygen in active carbon purifying, absorption Air haze Compound, fresh air is displaced by silicon window;When concentration reaches capacity alarm.So as to reach the purpose of room air safety;And And provided with screen cover is covered, uv damage can be prevented.
Background technology is because industrial development is too fast, exhaust emissions amount is sharply increased, and the reason such as climate warming, air is serious Contamination phenomenon is protruded very much, and haze has seriously threatened the healthy and life security of people.Have no need for reticence, in the market really Real storage is but relatively simple in some air detection equipment and air cleaning facility, and only detection is not purified, or only purifies and do not examine Survey (such as " flammable gas alarm " circuit, the advanced reader of electrophile, Fujian science tech publishing house, ISBN 7-5335- 2001-7/TN264, P:863-864)." air purifier " is mainly made up of systems such as motor, fan, airstrainers, its Operation principle is:Motor and fan in machine make circulating internal air, and the air of pollution passes through the air filtration in machine Various pollutants are removed or adsorbed after net, air is constantly ionized, a large amount of anions is produced, is sent out by gentle breeze fan, form negative Gas flow of ions, reach cleaning, purify air purpose (see:Air purifier, 360 encyclopaedias, internet).Moreover, these are net Change device for toxic gases such as formaldehyde, photocatalyst technology the most advanced should be used, but be due to that ultraviolet is harmful, And photocatalyst technology is not all used, thus their clean-up effect is not high, especially formaldehyde can not be cleaned.At present, " air cleaning The patent of device " is quite a few, mostly using filter paper, filtration core, filtering network technology or electrostatic, ozone, the purification of negative ions technology, Due to containing PM2.5, PM10, particulate matter and nitrogen, oxysulfide, PM2.5, PM10, particle in the air of pollution, especially haze Thing and nitrogen, oxysulfide and poisonous, fuel gas, car room also have the toxic gases such as formaldehyde, and amount is big, mix, only It is that can not reach the purpose of comprehensive decontamination, while ozone, negative ions are poisonous, electrostatic has by filtering, electrostatic, ozone technology Danger, has injury to human body on the contrary during with ozone, negative ions, electrostatic depuration air.Thus, these patented technologies are all very single One, it is impossible to according to fuel gas, concentration of toxic gases step automatic detection, purification, ventilation, when toxic gas, fuel gas surpass Explosion limit is crossed, can not be detected and alarm.It is hydrocarbon that the present invention contains nitrogen, sulphur, particulate matter and polycyclic aromatic hydrocarbon according to haze Compound composition, according to gas sensor principle, photocatalyst technology, and polycyclic aromatic hydrocarbon knowledge, employs gas sensor, first Aldehyde gas sensor, combustible gas detector three kinds of sensors detect to carbon monoxide, gas, coal gas, ethanol, formaldehyde, Simultaneously according to carbon monoxide, gas, coal gas, ethanol, polycyclic aromatic hydrocarbon hydrocarbon, formaldehyde chemical knowledge, employ dilution, Heating, absorption, photocatalyst (photochemical catalytic oxidation) technology, degraded, purification carbon monoxide, gas, coal gas, ethanol, polycyclic aromatic hydrocarbon (carbon Hydrogen compound), formaldehyde, and poisonous, fuel gas, and using the charcoal absorption PM2.5 through lime water process, PM10, Grain thing and nitrogen, oxysulfide;Simultaneously using silicon window (the silicon rubber film ----dimethyl silicone polymer with exchanging gas ability Base rubber membrane) to oxygen, carbon dioxide and the selective infiltration technology of nitrogen, further purify, displace fresh air (its In:Gas sensor, the composition of haze, polycyclic aromatic hydrocarbon, photocatalyst, activated carbon activated carbon, silicon window knowledge, integrate see 360 and search Rope, Baidu search, internet).
The content of the invention purpose of the present invention is to overcome existing gas detection equipment and air cleaning facility and " air cleaning Device " Patents technology is single, and only detection is not purified, or is only purified and do not detected, can not displace fresh air, some The purifier of the toxic gases such as purifying formaldehyde should use photocatalyst technology, and not use photocatalyst technology;Due to photocatalyst Technology needs ultraviolet to irradiate, but ultraviolet is poisonous to human body, and some automobiles employ direct current, without 220V exchanges Electricity, the ultraviolet lamp of photocatalyst technology can not also be installed, and all hinder the utilization of photocatalyst purification techniques, and formaldehyde can not be completely net Change, can not comprehensive decontamination nitrogen, oxysulfide and poisonous, fuel gas major defect.Present invention employs provided with exchange drop Pressure, rectification inversion of direct current, and DC inversion alternating-current technique, energy direct current, exchange are mutually used, it is adaptable to house, automobile, public place of entertainment, storehouse Air detection, purification in storehouse;Provided with ultraviolet screen is covered in the inner bag prosopyle of the coating of titanium dioxide of photocatalyst, can effectively prevented Uv damage, has purified formaldehyde, and using charcoal absorption PM2.5, PM10, particulate matter and nitrogen through lime water process, Oxysulfide, allows the air of pollution to obtain comprehensive decontamination, and displace fresh air by silicon window.Simultaneously for combustible gas physical examination When survey instrument detects that concentration exceedes the toxic gas of explosion limit, fuel gas, photocatalyst and heater circuit are automatically cut off, and report It is alert, allow indoor occupant to flee from, report professional to handle, it is to avoid dangerous generation.While air is purified, people is effectively protected Healthy and life security, single detection than background, purification equipment more comprehensively, with more superiority.
The object of the present invention is achieved like this:Indoor toxic gas automatic detection and purification air interchanger independent power source, inspection Survey, alarm, purification, five parts of ventilation;By direct current and/or exchange mutually with power supply, gas sensor, formaldehyde gas inductor, can Combustion gas detecting instrument, control circuit, warning circuit, electric fan, electric heating, photocatalyst, activated carbon, silicon window, connect electric box, crust of the device, The inner bag of coating of titanium dioxide assembles.Gas sensor, formaldehyde gas inductor, combustible gas detector for detection Parallel connection direct and/or exchange mutually use power supply;After gas sensor series-parallel connection resistance, diode, electric capacity, amplifier, with formaldehyde gas Inductor simultaneously couples magnetic valve, LED, electric fan;Combustible gas detector connects series connection magnetic valve and the loudspeaker for alarm;With Telegraph key, magnetic valve and the resistance of control main part, electric capacity, amplifier, diode, LED series-parallel connection are connected electric fan, electricity by wire respectively Backing, inverter, photocatalyst composition control circuit;Wherein:Direct current and/or exchange mutually include direct current with power supply and exchange two Point, the battery of dc source is formed by alternating current 220V civil power by transformer pressure-reducing, rectifier rectification charging;AC power by 220V civil powers and/or formed by being boosted after battery and inverter, be assembled in connecing in electric box above crust of the device, use wire Connection;Gas sensor, formaldehyde gas inductor, which are assembled in, to be exposed the ultraviolet screener of air inlet and covers, and is screwed with protecgulum;Can Combustion gas detecting instrument is assembled in connecing in electric box above crust of the device;It is equal for the photocatalyst of purification and the electric heating piece circuit of electric heating It is assembled in the inner bag of coating of titanium dioxide, electric fan is arranged on the electric fan in crust of the device and fixed on steelframe, and ultraviolet is by ultraviolet Line screening cover covers screen;Activated carbon and silicon window through lime water process are used to take a breath, particulate matter and carbon dioxide after purification By being taken a breath after the charcoal absorption of lime water process, then by silicon window;Activated carbon and the assembling of silicon window through lime water process At crust of the device rear, screwed with bonnet;Protecgulum, ultraviolet screener lid, electric fan, which fix steelframe, air admission hole;After covered out Stomata;Electric box is connect provided with LED hole and stomata;Telegraph key and resistance, electric capacity, amplifier, magnetic valve, diode, LED series-parallel connection It is assembled in and connects in circuit version in electric box;Telegraph key is from crust of the device outer control.
Technology is touched according to light:Photocatalyst can produce similar photosynthetic light-catalyzed reaction, produce under the irradiation of light Oxidability extremely strong free hydroxy and active oxygen, with very strong photoredox function, oxidable decomposition is various organic Compound and part inorganic matter, can destroy the cell membrane of bacterium and the protein of solidification virus, can kill bacterium and decompose organic Organic pollution, is resolved into free of contamination water (H by pollutant2) and carbon dioxide (CO O2), thus there is extremely strong sterilization, remove Smelly, mould proof, anti-fouling and self-cleaning, air purification function.The low molecular unstable compound of photocatalyst centering and most germs have Degrade well and killing action, including formaldehyde.(see:Photocatalyst, 360 encyclopaedias, internet).
According to photocatalysis oxidation technique:Photocatalysis oxidation reaction be using semiconductor and air as catalyst, using light as energy, It is CO by organic matter degradation2And H2O.The current reaction efficiency highest nano-TiO of semiconductor of use2Photochemical catalyst, makes pottery through honeycomb Porcelain is used after carrying attached specially treated, reaches ideal effect.In photocatalysis oxidation reaction, by ultraviolet light in nano-TiO2 Electron hole pair is produced on photochemical catalyst, the moisture content (H with adsorption2) and oxygen (O O2) reaction generation oxidisability it is very active Hydroxyl radical free radical (OH-) and ultra-oxygen anion free radical (O2-).Can various waste odour-gas bodies for example aldehydes, benzene class, Ammonia, Nitrogen oxides, sulfide and other VOC type organics, inorganic matter are reduced into carbon dioxide in the presence of photochemical catalytic oxidation (CO2), water (H2O) and other nontoxic materials, while there is deodorization, sterilization, sterilization, due in photocatalytic-oxidation Change in course of reaction without any additive, so secondary pollution will not be produced.Nano-photo catalytic catalyst material (GC-100) is one Plant and absorb after luminous energy, the material of catalytic reaction can be produced on its surface, when the ultraviolet light photocatalysis of specific nano wave length is touched During catalytic material (GC-100), photocatalytic redox reaction occurs for its surface.Photocatalysis catalyst material (GC-100) absorbs photon Afterwards electronics (e is produced on its surface-) and hole (h+), the luminous energy of absorption is changed into chemical energy, i.e., with photocatalysis.When When photocatalysis catalyst material (GC-100) is contacted with the water in air, H is just adsorbed on surface2O、O2、OH-, H2O、OH-By hole (h+) Aoxidized, O2By electronics (e-) reduction, OH-The oxidability of group is stronger, makes oxidation operation, is finally decomposed to H2O and CO2 (see:Photochemical catalytic oxidation off-gas cleaning equipment, beans fourth net, uplink time:On March 27th, 2014).Wherein:" GC-100 " light is touched Mediator is with nm-TiO2(A) it is Main Ingredients and Appearance, mixes the nanometer grade powder that some metals or metal oxide are made.Photocatalyst Agent is less than under 400nm light irradiation in wavelength, and valence-band electrons are excited to conduction band, form electronics and hole, with being adsorbed in it The O on surface2And H2O is acted on, generation superoxide anion radical O2-, O2With hydroxyl radical free radical OH-, its free radical tool There is very strong oxidative decomposition capacity, the C-C keys that can destroy in organic matter, c h bond, C-N keys, C-O keys, O-H keys, N-H keys are simultaneously killed Dead bacterium, can be widely applied to the fields such as air cleaning and sewage disposal.The product has photocatalysis Decomposition pernicious gas, organic The function of pollutant and photocatalysis antibacterial.Product cost is low, stability is good, and photocatalytic activity is high, absorbs optical wavelength range wider. (see:GC-100 photocatalyst agent, homepage > nanometer product > product introductions, Jiangsu Hehai Nanometer Technology Co., Ltd., mutually Networking).
According to the classification of gas sensor:One, the half such sensor of air guide body sensor is in gas sensor 60% is accounted for, is divided into according to its mechanism in conductivity type and non-conductivity type, conductivity type and is divided into surface type and volumetric void fraction type (1) SnO2Semiconductor is typical surface type gas sensor, and its sensing principle is SnO2For N-type semiconductor material.Upon application of a voltage, Semi-conducting material temperature is raised, and adsorbed oxygen receives in semiconductor and electronically formed O2Or in reducibility gas H2、CO、 CH4In the presence of, decline semiconductor surface resistance, conductance rises, conductance change is proportional to gas concentration.NiO is that p-type is partly led Body, oxidizing gas declines conductance, to O2It is sensitive.ZnO semiconductor transducers fall within this type.Semi-conductor gas is sensed The sensor element of device a. conductivity types is divided into surface-sensitive type and volumetric void fraction type, and surface-sensitive type sensing material is SnO2+Pd、 ZnO+Pt, AgO, V2O5, metallophthalocyanine, Pt-SnO2.Surface-sensitive type gas sensor detectable gas is various flammable gas Body CO, NO2, freon.Sensing material Pt-SnO2Gas sensor detectable gas be imflammable gas CO, H2、CH4。b. Volumetric void fraction type sensing material is Fe2O8, la1-SSrxCOO8 and TiO2、CoO-MgO-SnO2Body sensor detectable gas is Various imflammable gas CO, NO2, freon.Sensing material Pt-SnO2Volumetric void fraction type semiconductor gas sensor can detect gas Body is liquefied petroleum gas, alcohol, air-fuel ratio control, combustion furnace tail-gas.(2) volumetric void fraction type is that lattice defect change causes Conductivity variations, conductance changes relation proportional to gas concentration.Fe2O8、TiO2Belong to such a, it is sensitive to imflammable gas. (3) linear sensor, is the semiconductor transducer changed using thermal conductivity, also known as linear semiconductor transducer, is in Pt SnO is applied in wire coil2Layer, Pt except rise heat effect in addition to, also detection temperature change function.Apply voltage semiconductor to become Heat, surface oxygen uptake, declines free electronic concentration, in the presence of imflammable gas, increases because burning consumes oxygen free electronic concentration Greatly, thermal conductivity increases and increased with free electronic concentration, and rate of heat dissipation accordingly increases, and makes Pt temperature drops, and resistance reduces, Pt Change in resistance is linear relationship with gas concentration.This sensor bulk is small, stably, it is antitoxin, light concentration gas is can detect, can Combustion gas physical examination plays an important role in surveying.(4) the FET field-effect transistor gas sensors of non-conductivity type, Pd-FET. field-effects are brilliant Body tube sensor, absorbs Hz using Pd and diffusion reaches semiconductor Si and Pd interface, reduces Pd work content, this to H2、CO It is sensitive.Non- conductivity type FET field-effect transistors gas sensor small volume, be easy to it is integrated, it is multi-functional, be with development prospect Gas sensor.Two, this sensor element of solid-state electrolyte gas sensor conducts for ion pair solid electrolyte diaphragm, Referred to as electrochemical cell, is divided into cation conductive and anionic conduction, is the strong sensor of selectivity, study it is more reach it is practical Be zirconia solid electrolyte sensor, its mechanism is to utilize the potential difference between the battery of barrier film both sides two to be equal to concentration difference electricity The potential in pond.Stable chromium oxide solid electrolyte sensor has been applied successfully to the measure and engine air-fuel of steel water oxygen Than composition measurement etc..To make up the deficiency that solid electrolyte is conductive, one layer of air-sensitive film is plated on solid electrolyte in recent years, Moveable number of particles in gas molecule quantity present in all environment and medium is enclosed to connect.Three, catalytic combustion type gas Body sensor catalytic combustion type sensor is applied to flammable gas H2、CO、CH4Detection.Fuel gas contacts surface catalyst Burning, broken heat when Pt, Pd, the combustion heat are dense rich in pass with gas.It is the wide application of this kind of sensor, small volume, simple in construction, steady It is qualitative good, have the disadvantage poor selectivity.Four, the gas sensors of electrochemical gas sensor electrochemical means it is conventional have two kinds (1) invariant electric potential electro-analysis sensor is to ionize tested gas under specific electric field, and it is dense to measure gas by the Faradaic current flowed through Degree, this transducer sensitivity is high, changes the selectable cold gas of inspection of current potential, poisonous gas detection is played an important role.(2) it is former Battery type gas sensor is in KOH electrolyte solutions, Pt-Pb or Ag-Pb electrodes constitute battery, is successfully used for detecting O2, Its sensitivity is high, has the disadvantage the permeable loss moisture absorption, electrode is easily poisoned.Five, optical gas sensor (1) direct absorption gas is passed Sensor infrared gas sensor is typical absorption optical gas sensor, is respectively with each intrinsic according to gas Spectral absorption spectrum detection gas componant, non-dispersion infrared absorption spectrum is to SO2、CO、CO2, the gas such as NO have it is higher sensitive Degree.Other UV absorption, nondispersive ultraviolet absorption, associated spectroscopy, second derivative, automodulation optical absorption method are to NO, NO2、SO2、 Hydro carbons (CH4) etc. gas have higher sensitivity.(2) light reaction gas sensor light reaction gas sensor is to utilize gas Reaction produce discoloration cause luminous intensity absorb etc. optical characteristics change, sensing element be it is preferable, but gas light sensation change by To limitation, the free degree of sensor is small.(3) the new sensor Optical-Fiber Temperature Sensors of other optical characteristic are this species Type, in fiber tip coating catalyst and gas reaction, heating.Temperature changes, and causes fiber optic temperature to change.Using optical fiber temperature-measurement Degree of being practical is reached, detection gas is also successful.In addition, measuring the sensor of gas componant using other physical quantity variations Continually developing, such as surface acoustic wave sensor detects SO2、NO2、H2S、NH3、H2Also there is higher sensitivity Deng gas.(see: The classification of gas sensor, Baidu knows, internet, on 05 18th, 2016).
By 220V civil powers wire coupling transformer pressure-reducing, after bridge rectifier rectification, positive pole is connected to by LED The positive pole of battery, negative pole is connected on the negative pole of battery by telegraph key, the resistive heater input pole of gas sensor and first The resistive heater input pole of aldehyde gas sensor simultaneously couples positive pole, the output stage of gas sensor and formaldehyde gas inductor Negative pole in parallel, the anode of gas sensor and the anode of formaldehyde gas inductor and couple positive pole after output stage difference connecting resistance, The negative electrode of gas sensor and the negative electrode of formaldehyde gas inductor are separated, the negative electrode of formaldehyde gas inductor and the magnetic valve connected Wire two-way parallel connection with the wire of LED and the LED of series connection and electric fan is followed by negative pole;The negative electrode and string of gas sensor Join after variable resistor, the wire of diode and the conductor in parallel of series capacitance connecting resistance again, then parallel electrolytic electric capacity is being just Pole and the base stage of amplifier, amplifier colelctor electrode are in parallel with the negative electrode of formaldehyde gas inductor;Resistance, diode, electric capacity and electricity Solve the negative pole of electric capacity and couple negative pole;Negative pole is connect again after the emitter stage series resistance of amplifier;The sun of combustible gas detector Pole inputs pole with resistive heater and couples battery positive voltage, and resistive heater output stage series resistance connects battery terminal negative, can The negative electrode series connection loudspeaker and magnetic valve of combustion gas detecting instrument are followed by battery terminal negative;Connected between battery positive voltage and negative pole inverse Become device, and select to cut off or closing circuit by magnetic valve;Two wires of 220V civil powers are in parallel with ultraviolet lamp, heating plate, also by Circuit, ultraviolet lamp and inverter parallel are closed in magnetic valve selection cut-out.
220V civil powers, transformer, bridge rectifier, battery, telegraph key, inverter, magnetic valve, combustible gas physical examination will be carried Survey instrument, resistance, variable resistor, electric capacity, electrochemical capacitor, diode, amplifier, the operating circuit of LED and be assembled in circuit version On, it is fitted into and connects in electric box, fixed with bolt, and LED is exposed at through LED hole connects outside electric box, it is unimpeded to retain stomata, then Electric box will be connect to be fixed on above crust of the device by screw with bolt.
Electric fan is placed on the electric fan of venthole fixation steelframe and fixed with bolt by screw, wire is connected;In dioxy Change and load ultraviolet lamp and electric heating piece in the inner bag of titanium coating, electric heating piece is fixed on to the two of venthole by screw with bolt In the middle of the rear wall of the inner bag of titania coating, wire is connected;Again by the inner bag charging apparatus shell of coating of titanium dioxide, pass through Screw is fixed with bolt;Then ultraviolet screener lid is covered into the inner bag collar extension in coating of titanium dioxide, screwed by silk tooth;Use spiral shell The circuit version of gas sensor and formaldehyde gas inductor is fixed on by bolt to be exposed the ultraviolet screener of air admission hole and covers, and connection is led Line;The protecgulum of air admission hole is loaded on, and is screwed by Si Ya with crust of the device.
In the fixation of crust of the device rear after the activated carbon square of lime water process, silicon window is loaded on;Then covered out The bonnet of stomata, is screwed by Si Ya with crust of the device.
Direct current and/or exchange are mutually provided with inverter and transformer, bridge rectifier simultaneously with power supply in the circuit of the present invention, Direct-flow storage battery and/or the mutual use of alternating current 220V civil power selection, applied widely, convenient use.When interior there are 220V civil powers, cut Key is powered off, allows 220V civil powers to work;When interior does not have 220V civil powers, battery-operated, ultraviolet lamp and electric heating piece therein are allowed The 220V needed voltage is provided by inverter;220V civil powers and telegraph key are closed, is stopped;Telegraph key is not closed, while Under the work of 220V civil powers, battery is charged by transformer, bridge rectifier rectification to battery, indoor toxic gas automatic detection With purification air interchanger normal work, but during accumulator electric-quantity saturation, LED is extinguished, very important person for close in time telegraph key or Cut off 220V civil powers.
The present invention can monitor the poison gases such as carbon monoxide, gas, coal gas, ethanol, formaldehyde and combustible gas automatically indoors Body, and inner bag and ultraviolet provided with coating of titanium dioxide cover screen lid, can prevent uv damage.
Composition according to haze contains nitrogen, sulphur, particulate matter and polycyclic aromatic hydrocarbon hydrocarbon, former according to gas sensor Reason and polycyclic aromatic hydrocarbon knowledge, employ gas sensor, formaldehyde gas inductor, combustible gas detector three kinds of sensors pair Carbon monoxide, gas, coal gas, ethanol, formaldehyde are detected, while according to carbon monoxide, gas, coal gas, ethanol, polycyclic aromatic hydrocarbon The chemical knowledge of hydrocarbon, formaldehyde, employs dilution, heating, absorption, photooxidation technology, degrades, purified an oxidation Carbon, gas, coal gas, ethanol, polycyclic aromatic hydrocarbon hydrocarbon, formaldehyde are poisonous, fuel gas, and utilize the work of lime water process Property carbon activity charcoal absorption PM2.5, PM10, particulate matter, and using silicon window (silicon rubber film ----there is exchanging gas ability Dimethyl silicone polymer base rubber membrane) to oxygen, carbon dioxide and the selective infiltration technology of nitrogen, further purify, put Swap out fresh air.Indoor toxic gas automatic detection with purification air interchanger can monitor automatically indoors carbon monoxide, The poison gases such as gas, coal gas, ethanol, formaldehyde and fuel gas.Wherein:Indoor toxic gas automatic detection is set with purification air interchanger The inner bag and ultraviolet for having coating of titanium dioxide cover screen, prevent uv damage.When interior has toxic gas, combustible gas Body, but concentration it is not high when, gas sensor and formaldehyde gas inductor produce sensing, LED bright light, electric fan work, allow air Rotation is contacted with the activated carbon square through lime water process, the toxic gas such as PM2.5, PM10, particulate matter and nitrogen, oxysulfide, Then fuel gas displaces fresh air, from outlet by the activated carbon square adsorption cleaning through lime water process by silicon window Hole is appeared.When interior has toxic gas, fuel gas, but concentration is higher, beyond safety standard, and has the toxic gases such as formaldehyde When, magnetic valve opens inverter, opens ultraviolet lamp and electric heating piece, allows coating of titanium dioxide to carry out photocatalyst effect, allows poisonous Gas heated oxide, resolves into carbon dioxide and water, then by by the activated carbon square adsorption cleaning through lime water process, Then fresh air is displaced by silicon window, appeared from venthole.When interior has toxic gas, fuel gas, and concentration Very it is high exceed explosion limit when, combustible gas detector by loudspeaker alarm, and by closed electromagnetic valve have already turned on it is inverse Become device, ultraviolet lamp, electric heating piece, cut off thermal source, indoor occupant withdraws from indoor emergency, and sought help processing to the police.So as to reach To the purpose of room air safety.
Power-on, indoor toxic gas automatic detection of the invention enters detection, purification, ventilation with purification air interchanger And/or alert operation state:
When interior has toxic gas, a fuel gas, but concentration is not high is less than 500ppm, is less than《IAQ mark It is accurate》GB/T 18883-2002 safety standards:Formaldehyde HCHO mg/m30.10 1h averages, formaldehyde HCHO mg/m3≤0.08≤ 0.12;Carbon monoxide CO mg/m310 1h averages, benzene C6H6 mg/m30.11 1h averages, inhalable particles PM10 mg/m30.15 During daily mean, gas sensor produces sensing, anode, negative electrode and the formaldehyde gas of gas sensor with formaldehyde gas inductor Anode, the negative electrode of inductor produce electric signal, are amplified by amplifier, LED bright light, electric fan work, allow the air of rotation Contacted with the activated carbon square through lime water process, toxic gas, fuel gas are inhaled by the activated carbon square through lime water process Attached purification, then displaces fresh air by silicon window, is appeared from venthole.
When interior has toxic gas, fuel gas, but concentration is higher, exceeds《Indoor Air Quality standards》GB/T 18883-2002 safety standards:Formaldehyde HCHO mg/m30.10 1h averages, formaldehyde HCHO mg/m3≤0.08≤0.12;One oxidation Carbon CO mg/m310 1h averages, benzene C6H6 mg/m30.11 1h averages, inhalable particles PM10 mg/m30.15 daily mean, and When having the toxic gases such as formaldehyde, formaldehyde gas inductor produces sensing, and anode, the negative electrode of formaldehyde gas inductor produce telecommunications Number, magnetic valve connects inverter, opens ultraviolet lamp and electric heating piece, the coating of titanium dioxide allowed in the inner bag of coating of titanium dioxide The photocatalytic oxidation of photocatalyst is carried out, toxic gas heated oxide is allowed, carbon dioxide and water are resolved into, then by through stone The purification of activated carbon square, the absorption of grey water process, then displace fresh air by silicon window, are appeared from venthole.
Wherein:Formaldehyde reaction equation is, HCHO+H2O→CO2+4H++ 4e, O2+4H++ 4e → 2H2O, HCHO+H2O→CO2+ 2H2O;Nano-TiO2Photocatalytic advanced oxidation technology reaction (photocatalyst) process and reaction equation be, TiO2+hv→h++e-, h++e-→ E, H2O→H++OH-, h++OH-→ OH, h++H2O+O2-→·OH+H++·O2-, h++H2O→·OH+H+, e-+O2 →·O2-, O2-+H+→·HO2, 2HO2→O2+H2O2, H2O2+·O-2→·OH+OH+O2;(wherein:OH be hydroxyl from By base, O2-For ultra-oxygen anion free radical, H2O2For hydrogen peroxide, HO2For super oxygen hydroperoxyl radical, hv is photon energy, h+For the photo-induced hole on conduction band, e-For photoinduced electron, E is chemical energy).
Lime reaction formula in activated carbon square through lime water process is:CaO+H2O=Ca (OH)2, CaO+CO2= CaCO3, Ca (OH)2+CO2=CaCO3+H2O, CaCO3Δ=CaO+CO2
Fuel gas is respectively with the reaction equation that oxygen reacts:Carbon monoxide and coal gas reaction equation be, 2CO+O2= 2CO2;Hydrogen reaction equation is 2H2+O2=2H2O;Ethanol synthesis formula is, C2H5OH+3O2=2CO2+3H2O;Benzene reaction equation is, 2C6H6 +15O2=12CO2+6H2O;Polycyclic aromatic hydrocarbon (hydrocarbon) reaction equation is, HC+O2→CO2+H2O;Gas and methane reaction formula, CH4+2O2=CO2+2H2O.Carbon monoxide, gas, coal gas, hydrogen, ethanol, benzene, polycyclic aromatic hydrocarbon (hydrocarbon), methane CH4 CO can be generated by heating, burning or high-temperature oxydation mode2And H2O。
Toxic gas hydrogen sulfide reaction equation is:2H2S+3O2=2SO2+2H2O, toxic gas nitrogen, the reaction equation of oxysulfide For:SO2+H2O=H2SO3, H2SO3+ CaO=H2O+CaSO3, 4NO2+2Ca(OH)2=Ca (NO3)2+Ca(NO2)2+2H2O.Reaction In CaSO3、Ca(NO3)2、Ca(NO2)2With the PM2.5 in air, PM10, particulate matter by the activated carbon through lime water process Square is adsorbed.
When there is toxic gas, fuel gas in interior, and dense when exceeding explosion limit, combustible gas detector Anode A, negative electrode B produce electric signal, by loudspeaker alarm, and the inverter, ultraviolet being had already turned on by closed electromagnetic valve Line lamp, electric heating piece, cut off thermal source, indoor occupant is withdrawn from indoor emergency, and is sought help to the police, handle dangerous by professional.
When toxic gas, fuel gas is not present in interior, anode E, negative electrode F and the formaldehyde gas sensing of gas sensor The anode K of device, electric signal is not produced between negative electrode L, and the anode and negative electrode of combustible gas detector, LED does not work, electricity Fan, inverter, ultraviolet lamp, electric heating piece do not work, indoor occupant close the present invention indoor toxic gas automatic detection with The direct current and/or exchange for purifying air interchanger mutually use power supply, are stopped.
Using charcoal absorption PM2.5, PM10, particulate matter and nitrogen, oxysulfide through lime water process, depending on air pollution Situation and PM2.5, PM10, particulate matter and nitrogen, the concentration of oxysulfide, find the activated carbon through lime water process after a period of time When adsorbed PM2.5, PM10, particulate matter and nitrogen, sulfur oxide contamination are serious, the bonnet and silicon window of venthole are screwed off, will Activated carbon square through lime water process is taken out and changed, and is then reinstalled, and bonnet is revolved by Si Ya and crust of the device Tightly.
The present invention according to the concentration of toxic gas, fuel gas, respectively by gas sensor, formaldehyde gas inductor, can Gas detecting instrument detection is fired, point step purification, ventilation, or alarm, so that air has both been purified, again without uv damage, It will not more be exploded because fuel gas exceedes explosion limit, protect the healthy and life security of people, and alternating current and direct current Mutually use, it is widely used in house, automobile, public place of entertainment, the air detection in warehouse, purification and changed.Than single gas Detection device and air cleaning facility more comprehensively, it is more superior.
As a result of such scheme, the present invention can be to indoor toxic gas, combustible gas detection, purification, displacement And/or alarm.Open telegraph key, allow storage battery power supply, when there is toxic gas, combustible gas in interior, but concentration it is not high when, gas Dependent sensor and formaldehyde gas inductor produce sensing, LED bright light, electric fan work, allow rotation air with through limewash at The activated carbon square contact of reason, toxic gas, combustible gas are purified by the activated carbon square through lime water process and adsorbed, then Fresh air is displaced by silicon window, appeared from venthole;When interior has toxic gas, combustible gas, but concentration is higher, Beyond safety standard, and when having the toxic gases such as formaldehyde, magnetic valve opens inverter, opens ultraviolet lamp and electric heating piece, allows two Titania coating carries out photocatalyst effect, allows toxic gas heated oxide, carbon dioxide and water is resolved into, then by being passed through The activated carbon square purification absorption of lime water process, then displaces fresh air by silicon window, is appeared from venthole;Work as interior There is toxic gas, combustible gas, and it is dense when exceeding explosion limit, and combustible gas detector passes through loudspeaker Alarm, and inverter, ultraviolet lamp, the electric heating piece being had already turned on by closed electromagnetic valve, cut off thermal source, and indoor occupant is promptly removed From indoor and sought help processing to the police.Present invention employs gas sensor, formaldehyde gas inductor, combustible gas detector and Photocatalyst technology, active carbon purifying filtering technique, silicon window setting technique, by gas sensor, formaldehyde gas inductor, combustible gas physical examination Survey three kinds of detection device step detections of instrument and/or alarm, photocatalyst, ultraviolet and shield technology are employed again, is effectively purified Formaldehyde toxic gas, and electric fan dilution is employed, some fuel gas are oxidized to titanium dioxide by electric heating piece heated oxide technology Carbon, water and particulate matter, then using charcoal absorption and silicon window replacement technique, especially with the activated carbon through lime water process PM2.5, PM10, particulate matter and nitrogen, oxysulfide are adsorbed, so as to purify and displace fresh air.Meanwhile, in combustible gas physical examination When survey instrument detects that concentration exceedes the toxic gas of explosion limit, fuel gas, cut-out photocatalyst and heater circuit, automatic report It is alert, allow indoor occupant to flee from, handled by professional, allow indoor occupant to flee danger.Ac buck, rectification is employed to straighten Stream, and DC inversion alternating-current technique, can DC-AC mutually use, it is adaptable to house, automobile, public place of entertainment, the air inspection in warehouse Survey, purify;And the inner bag prosopyle of the coating of titanium dioxide in photocatalyst provided with ultraviolet covers screen, effectively ultraviolet can be prevented to hinder Evil;While air is purified, the healthy and life security of people is effectively protected.The present invention is than existing single Detection does not purify, only purifies the gas detection equipment not detected, air cleaning facility and " air purifier " Patents technology More fully, with more superiority.
Brief description of the drawings is below the description of the drawings
Toxic gas automatic detection and purification air interchanger functional-block diagram in Fig. 1 rooms
Toxic gas automatic detection and purification air interchanger main part compositional block diagram in Fig. 2 rooms
Toxic gas automatic detection and purification air interchanger circuit diagram in Fig. 3 rooms
Toxic gas automatic detection and purification air interchanger sectional view in Fig. 4 rooms
Toxic gas automatic detection and the purification specific part assembling figure of air interchanger in Fig. 5 rooms
1st, wire 2, transformer 3, bridge rectifier 4, battery 5, gas sensor 6, formaldehyde gas inductor 7th, resistance 8, resistance 9, amplifier 10, LED 11, inverter 12, ultraviolet lamp 13, magnetic valve 14, electric heating piece 15, LED 16, electric fan 17, resistance 18, electrochemical capacitor 19, electric capacity 20, variable resistor 21, diode 22, resistance 23, electricity Magnet valve 24, loudspeaker 25, resistance 26, combustible gas detector 27, telegraph key 28, protecgulum 29, crust of the device 30, bolt 31st, circuit version 32, connect electric box 33, bonnet 34, silicon window 35, the activated carbon square 36 through lime water process, electric fan fix steel Frame 37, the inner bag 38 of coating of titanium dioxide, ultraviolet screener lid 39, screw 40, venthole 41, bolt 42, bolt 43rd, screw 44, venthole 45, venthole 46, screw 47, bolt 48, air admission hole 49, air admission hole 50, bolt 51, gas Hole 52, LED hole 53, bolt 54, screw 55, LED 56, circuit version
Embodiment selects 220V civil powers and/or battery makees direct current and/or exchange mutually uses power supply.Selection but not It is limited to QM-N10 types gas sensor 5 and Winsensor MQ138 formaldehyde gases inductor 6, and RJ-MOT200 fuel gas Detector 26 is used as detection;Select telegraph key 27, magnetic valve 13 and magnetic valve 23 as control, selection loudspeaker 24 is used as alarm, Select electric fan, electric heating, photocatalyst, the activated carbon through lime water process as purification, selection silicon window is used as ventilation.(such as Fig. 1, figure 2nd, Fig. 3, Fig. 4, Fig. 5).
220V civil powers wire 1 is coupled into transformer 2 to be depressured, after the rectification of bridge rectifier 3, positive pole passes through LED 55 are connected to the positive pole of 24V batteries 4, and negative pole is connected to by telegraph key 27 on the negative pole of 24V batteries 4, QM-N10 type gas sensings The resistive heater input pole G of device 5 is in parallel with the resistive heater input pole M of Winsensor MQ138 formaldehyde gases inductor 6 Connect positive pole, the resistive heater output stage H connecting resistances 22 and Winsensor MQ138 formaldehyde gas of QM-N10 types gas sensor 5 Negative pole in parallel after the resistive heater output stage N connecting resistances 7 of body inductor 6, the anode E of QM-N10 types gas sensor 5 and The anode K of Winsensor MQ138 formaldehyde gases inductor 6 simultaneously couples positive pole, the negative electrode F of QM-N10 types gas sensor 5 and The negative electrode L of Winsensor MQ138 formaldehyde gases inductor 6 is separated, the moon of Winsensor MQ138 formaldehyde gases inductor 6 After pole L is in parallel with the magnetic valve 13 and the wire of LED 15 and the LED 10 of series connection and the two-way of wire 1 of electric fan 16 connected Connect negative pole;The negative electrode F of QM-N10 types gas sensor 5 and 10K Ω variable resistors 20 of connecting, the wire 1 of diode 21 and string 1K Ω resistance 8 is connect again after the parallel connection of wire 1 for joining electric capacity 19, then the positive pole and NPN amplifiers 9 of parallel connection 4.7uF electrochemical capacitors 18 Base stage, the colelctor electrode of amplifier 9 is in parallel with the negative electrode L of formaldehyde gas inductor 6;5.1 Ω resistance 22,5.1 Ω resistance 7, two poles The negative pole of pipe 21, electric capacity 19 and electrochemical capacitor 18 and couples negative pole;Connect again after the emitter stage 50 Ω resistance 17 of series connection of amplifier 9 Negative pole;The anode A of RJ-MOT200 combustible gas detectors 26 inputs pole C with resistive heater and couples the positive pole of battery 4, RJ- The resistive heater output stage D 5.1 Ω resistance 25 of series connection of MOT200 combustible gas detectors 26 connect the negative pole of battery 4, RJ- The negative electrode B series connection loudspeakers 24 and magnetic valve 23 of MOT200 combustible gas detectors 26 are followed by the negative pole of battery 4;Battery 4 is just Series inverter 11 between pole and negative pole, and select to cut off or close circuit by magnetic valve 13 and magnetic valve 23;220V civil powers two Root wire is in parallel with ultraviolet lamp 12 and heating plate 14, also selects to cut off or close circuit by magnetic valve 13 and magnetic valve 23, purple Outside line lamp 12 is in parallel with inverter 11.(such as Fig. 3).
By 220V civil powers, transformer 2, bridge rectifier 3, battery 4, telegraph key 27, inverter 11, magnetic valve 13, electromagnetism Valve 23, combustible gas detector 26, resistance 25, resistance 22, resistance 7, variable resistor 20, resistance 8, resistance 17, electric capacity 19, electrolysis Electric capacity 18, diode 21, amplifier 9, LED 10, LED 15, the operating circuit of LED 55 are assembled in circuit version 31, It is fitted into and connects in electric box 32, fixed with bolt 50, and LED 10, LED 15, LED 55 are exposed at through LED hole 52 connect electricity The outside of box 32, it is unimpeded to retain stomata 51, then will connect electric box 32 and be fixed on the top of crust of the device 29 by screw 39 with bolt 30;Electricity Key 27, which is assembled in, to be connect in electric box, and telegraph key 27 is from the outer control of crust of the device 29.(such as Fig. 3).
57BL55S02-212 direct current 24V motors 20W electric fan 16 is placed in into the electric fan of venthole 44 to fix on steelframe 36 Fixed with bolt 42 by screw 43, connect wire 1;Load 220V, 365nm ultraviolet in the inner bag 37 of coating of titanium dioxide Electric heating piece 14, the titanium dioxide of venthole 45 is fixed on bolt 47 by lamp 12 and 24V, 100W electric heating piece 14 by screw 46 In the middle of the rear wall of the inner bag 37 of coating, wire 1 is connected;Again by the charging apparatus shell 29 of inner bag 37 of coating of titanium dioxide, lead to Screw 54 is crossed to be fixed with bolt 53;Then the ultraviolet screener lid 38 for having air admission hole 48 is covered into the inner bag 37 in coating of titanium dioxide Collar extension, is screwed by silk tooth;The circuit version 56 of gas sensor 5 and formaldehyde gas inductor 6 is fixed on bolt 41 and exposed On the ultraviolet screener lid 38 of air admission hole 48, wire 1 is connected;The protecgulum 28 of air admission hole 49 is loaded on, and passes through Si Ya and dress Shell 29 is put to screw.(such as Fig. 4, Fig. 5).
In the rear fixation of crust of the device 29 after the activated carbon square 35 of lime water process, silicon window 34 is loaded on;Then cover On have the bonnet 33 of venthole 40, screwed by Si Ya with crust of the device 29.(such as Fig. 3, Fig. 4, Fig. 5).
Direct current and/or exchange are mutually with power supply simultaneously provided with inverter 11 and transformer 2, bridge rectifier in the circuit of the present invention Device 3, direct-flow storage battery 4 and/or alternating current 220V civil power, direct current and/or exchange selection, mutually use, applied widely, convenient use; When there are 220V civil powers interior, split key 27 allows 220V civil powers to work;When interior does not have 220V civil powers, the work of battery 4 is allowed Make, the 220V voltages that ultraviolet lamp 12 and electric heating piece 14 therein need are provided by inverter 11;Close 220V civil powers and telegraph key 27, it is stopped;Telegraph key 27 is not closed, while under the work of 220V civil powers, battery 4 is whole by transformer 2, bridge rectifier 3 Stream charges to battery 4, indoor toxic gas automatic detection and purification air interchanger normal work, but the electricity of battery 4 is full And when, LED 55 is extinguished, and very important person is closing telegraph key 27 in time or cut-out 220V civil powers.
The present invention can monitor the poison gases such as carbon monoxide, gas, coal gas, ethanol, formaldehyde and combustible gas automatically indoors Body, and inner bag 37 and ultraviolet provided with coating of titanium dioxide cover screen lid 38, can prevent uv damage.
Power-on, indoor toxic gas automatic detection of the invention enters detection, purification, ventilation with purification air interchanger And/or alert operation state (Fig. 1, Fig. 3).
When interior has toxic gas, fuel gas, but concentration is not high, less than 500ppm, is less than《IAQ mark It is accurate》GB/T 18883-2002 safety standards:Formaldehyde HCHO mg/m30.10 1h averages, formaldehyde HCHO mg/m3≤0.08≤ 0.12;Carbon monoxide CO mg/m310 1h averages, benzene C6H6 mg/m30.11 1h averages, inhalable particles PM10 mg/m30.15 During daily mean, gas sensor 5 produces sensing, anode E, the moon of QM-N10 types gas sensor 5 with formaldehyde gas inductor 6 Pole F and WinsensorMQ138 formaldehyde gas inductors 6 anode K, negative electrode L produce electric signal, are amplified by amplifier 9, LED 10, the bright light of LED 15, electric fan 16 work, and allow the air of rotation to be contacted with the activated carbon square 35 through lime water process, Then toxic gas, fuel gas are displaced newly by the adsorption cleaning of activated carbon square 35 through lime water process by silicon window 34 Fresh air, is appeared from venthole 40.
When interior has toxic gas, fuel gas, but concentration is higher, exceeds《Indoor Air Quality standards》GB/T 18883-2002 safety standards:Formaldehyde HCHO mg/m30.10 1h averages, formaldehyde HCHO mg/m3≤0.08≤0.12;One oxidation Carbon CO mg/m310 1h averages, benzene C6H6 mg/m30.11 1h averages, inhalable particles PM10 mg/m30.15 daily mean, and When having the toxic gases such as formaldehyde, formaldehyde gas inductor 6 produces sensing, the sun of Winsensor MQ138 formaldehyde gases inductor 6 Pole K, negative electrode L produce electric signal, and magnetic valve 13 connects inverter 11, opens ultraviolet lamp 12 and electric heating piece 14, allow titanium dioxide Coating of titanium dioxide in the inner bag 37 of coating carries out the photocatalytic oxidation of photocatalyst, allows toxic gas heated oxide, point Then solution is purified by the activated carbon square 35 through lime water process, adsorbed, then put by silicon window 34 into carbon dioxide and water Swap out fresh air, is appeared from venthole 40.
Wherein reaction equation is:Formaldehyde is HCHO+H2O→CO2+4H++ 4e, O2+4H++4e→2H2O, HCHO+H2O→CO2+ 2H2O;Nano-TiO2Photocatalytic advanced oxidation technology reaction (photocatalyst) process and reaction equation be:TiO2+hv→h++e-, h++e-→ E, H2O→H++OH-, h++OH-→ OH, h++H2O+O2-→·OH+H++·O2-, h++H2O→·OH+H+, e-+O2 →·O2-, O2-+H+→·HO2, 2HO2→O2+ H2O2, H2O2+·O-2→·OH+OH-+O2(wherein:OH be hydroxyl from By base, O2-For ultra-oxygen anion free radical, H2O2For hydrogen peroxide, HO2For super oxygen hydroperoxyl radical, hv is photon energy, h+For the photo-induced hole on conduction band, e-For photoinduced electron, E is chemical energy).
Lime reaction formula in activated carbon square 35 through lime water process is:In activated carbon square through lime water process Lime reaction formula be:CaO+H2O=Ca (OH)2, CaO+CO2=CaCO3, Ca (OH)2+CO2=CaCO3+H2O, CaCO3Δ= CaO+CO2
Fuel gas is respectively with the reaction equation that oxygen reacts:Carbon monoxide and coal gas reaction equation be, 2CO+O2= 2CO2;Hydrogen reaction equation is 2H2+O2=2H2O;Ethanol synthesis formula is, C2H5OH+3O2=2CO2+3H2O;Benzene reaction equation is, 2C6H6 +15O2=12CO2+6H2O;Polycyclic aromatic hydrocarbon (hydrocarbon) reaction equation is, HC+O2→CO2+H2O;Gas and methane reaction formula, CH4+2O2=CO2+2H2O.Carbon monoxide, gas, coal gas, hydrogen, ethanol, benzene, polycyclic aromatic hydrocarbon (hydrocarbon), methane CH4 CO can be generated by heating, burning or high-temperature oxydation mode2And H2O。
Toxic gas hydrogen sulfide reaction equation is:2H2S+3O2=2SO2+2H2O, toxic gas nitrogen, the reaction equation of oxysulfide For:SO2+H2O=H2SO3, H2SO3+ CaO=H2O+CaSO3, 4NO2+2Ca(OH)2=Ca (NO3)2+Ca(NO2)2+2H2O.Reaction In CaSO3、Ca(NO3)2、Ca(NO2)2With the PM2.5 in air, PM10, particulate matter by the activated carbon through lime water process Square is adsorbed.
When there is toxic gas, fuel gas in interior, and it is dense when exceeding explosion limit, and RJ-MOT200 is flammable The anode A of gas detecting instrument 26, negative electrode B produce electric signal, are alarmed by loudspeaker 24, and are closed and beaten by magnetic valve 23 Inverter 11, ultraviolet lamp 12, the electric heating piece 14 opened, cut off thermal source, indoor occupant is withdrawn from indoor emergency, and is asked to the police Help, handle dangerous by professional.
When interior be not present toxic gas, fuel gas when, anode E, the negative electrode F of QM-N10 types gas sensor 5 with The anode K and negative electrode L of Winsensor MQ138 formaldehyde gases inductor 6, and RJ-MOT200 combustible gas detectors 26 Electric signal is not produced between anode A and negative electrode B, LED 10, LED 15 do not work, electric fan 16, inverter 11, ultraviolet lamp 12nd, electric heating piece 14 does not work, and indoor occupant closes the indoor toxic gas automatic detection and purification air interchanger of the present invention Direct current and/or exchange mutually use power supply, are stopped.
It is dirty depending on air using the absorption of activated carbon 35 PM2.5 through lime water process, PM10, particulate matter and nitrogen, oxysulfide Dye situation and PM2.5, PM10, particulate matter and nitrogen, the concentration of oxysulfide, find the activity through lime water process after a period of time When charcoal 35 adsorbed PM2.5, PM10, particulate matter and nitrogen, sulfur oxide contamination are serious, the He of bonnet 33 of venthole 40 is screwed off Silicon window 34, the activated carbon square 35 through lime water process is taken out and changed, is then reinstalled, bonnet 33 is passed through into silk tooth Screwed with crust of the device 29.
The present invention according to the concentration of toxic gas, fuel gas, respectively by gas sensor, formaldehyde gas inductor, can Gas detecting instrument detection is fired, point step purification, ventilation, or alarm, so that air has both been purified, again without uv damage, It will not more be exploded because fuel gas exceedes explosion limit, protect the healthy and life security of people, and alternating current and direct current Mutually use, it is widely used in house, automobile, public place of entertainment, the air detection in warehouse, purification and changed.Than single gas Detection device and air cleaning facility more comprehensively, it is more superior.

Claims (10)

1. a kind of indoor toxic gas automatic detection and purification air interchanger independent power source, detection, alarm, purification, five parts of ventilation; By direct current and/or exchange mutually with power supply, gas sensor, formaldehyde gas inductor, combustible gas detector, control circuit, report Alert circuit, electric fan, electric heating, photocatalyst, activated carbon, silicon window, connect electric box, crust of the device, the inner bag assembling of coating of titanium dioxide and Into;It is characterized in that:Gas sensor, formaldehyde gas inductor, combustible gas detector parallel connection direct and/or the mutual electricity consumption of exchange Source;After gas sensor series-parallel connection resistance, diode, electric capacity, amplifier, with formaldehyde gas inductor and coupling magnetic valve, LED Lamp, electric fan;Combustible gas detector connects series connection magnetic valve and loudspeaker;With wire by telegraph key, magnetic valve and resistance, electric capacity, put Big device, diode, LED series-parallel connection connect electric fan, electric heating piece, inverter, photocatalyst composition control circuit respectively;Wherein:
Described direct current and/or exchange mutually uses power supply, by 220V cities electrical coupling transformer, and after bridge rectifier, positive pole leads to The positive pole that LED is connected to battery is crossed, negative pole connects battery terminal negative by telegraph key, then is made up of battery series inverter;Directly Stream and/or exchange are mutually assembled in connecing in electric box above crust of the device with power supply;Inverter is in parallel with ultraviolet lamp, 220V civil powers It is in parallel with ultraviolet lamp, heating plate;
The input pole of described gas sensor and the input pole of formaldehyde gas inductor simultaneously couple positive pole, gas sensor it is defeated Go out negative pole in parallel, the anode of gas sensor and formaldehyde gas sense after the output stage difference connecting resistance of pole and formaldehyde gas inductor Answer the anode of device and couple positive pole, the negative electrode of gas sensor and the negative electrode of formaldehyde gas inductor are separated, formaldehyde gas sensing The negative electrode of device is followed by bearing with the wire two-way parallel connection of the magnetic valve and the wire of LED and the LED of series connection and electric fan connected Pole;The negative electrode of gas sensor with connecing electricity again after the conductor in parallel of variable resistor of connecting, the wire of diode and series capacitance Hinder, then the base stage of the positive pole of parallel electrolytic electric capacity and amplifier, the negative electrode of amplifier colelctor electrode and formaldehyde gas inductor is simultaneously Connection;The negative pole of resistance, diode, electric capacity and electrochemical capacitor and couples negative pole;Connect again after the emitter stage series resistance of amplifier Negative pole;Gas sensor, formaldehyde gas inductor are assembled in ultraviolet screener and covered, and screw protecgulum;
The anode of described combustible gas detector is with inputting pole and coupling battery positive voltage, and output stage series resistance connects battery Negative pole, the negative electrode series connection loudspeaker and magnetic valve of combustible gas detector are followed by battery terminal negative;Combustible gas detector is assembled In electric box is connect;
Described electric fan is fixed on electric fan and fixed on steelframe, connects wire;After activated carbon square being fixed at crust of the device rear, then Load onto silicon window;Load bonnet;
The photocatalyst and electric heating piece are assembled in the inner bag of coating of titanium dioxide, and electric heating piece is fixed on into coating of titanium dioxide Inner bag rear wall in the middle of, connect wire;Again will be fixed in the inner bag charging apparatus shell of coating of titanium dioxide, by ultraviolet screen Lid is covered to cover tightly;
Described connects electric box provided with LED hole and stomata;It is 220V civil powers, transformer, bridge rectifier, battery, telegraph key, inverse Become device, magnetic valve, combustible gas detector, resistance, variable resistor, electric capacity, electrochemical capacitor, diode, amplifier, LED to mix The operating circuit of connection is assembled in circuit version, is fixed on and is connect in electric box, and LED is exposed at through LED hole connect outside electric box Face, it is unimpeded to retain stomata, then will connect electric box and be fixed on above crust of the device;Described telegraph key is from crust of the device outer control;
The circuit version of described gas sensor and formaldehyde gas inductor is fixed on ultraviolet screener and covered, and connects wire, then Load onto protecgulum;
Described protecgulum, ultraviolet screener lid, electric fan, which fix steelframe, air admission hole;After covered venthole.
2. indoor toxic gas automatic detection according to claim 1 and purification air interchanger, it is characterized in that:By 220V cities Electricity uses wire coupling transformer, and after bridge rectifier, positive pole is connected to the positive pole of battery by LED, and negative pole passes through electricity It is keyed on the negative pole of battery, resistive heater input pole (G) of gas sensor and the heating electricity of formaldehyde gas inductor Resistance silk input pole (M) simultaneously couples positive pole, resistive heater output stage (H) connecting resistance and formaldehyde gas inductor of gas sensor Resistive heater output stage (N) connecting resistance after negative pole in parallel, the anode (E) and the sun of formaldehyde gas inductor of gas sensor Pole (K) simultaneously couples positive pole, and the negative electrode (F) of gas sensor and the negative electrode (L) of formaldehyde gas inductor are separated, formaldehyde gas sensing The negative electrode (L) of device is followed by with the wire two-way parallel connection of the magnetic valve and the wire of LED and the LED of series connection and electric fan connected Negative pole;The negative electrode (F) of gas sensor with after the conductor in parallel of variable resistor of connecting, the wire of diode and series capacitance again The base stage of connecting resistance, the then positive pole of parallel electrolytic electric capacity and amplifier, the moon of amplifier colelctor electrode and formaldehyde gas inductor Pole (L) is in parallel;The negative pole of resistance (22,7), diode, electric capacity and electrochemical capacitor and couples negative pole;The emitter stage string of amplifier Negative pole is connect again after connection resistance (17);The anode (A) of combustible gas detector inputs pole (C) with resistive heater and couples battery Positive pole, resistive heater output stage (D) series resistance (25) of combustible gas detector connects battery terminal negative, fuel gas detection Negative electrode (B) the series connection loudspeaker and magnetic valve (23) of instrument are followed by battery terminal negative;Series resonant inverter between battery positive voltage and negative pole Device, and select to cut off or closing circuit by magnetic valve (13,23);
Two wires of 220V civil powers are in parallel with ultraviolet lamp, heating plate, also selected to cut off or close electricity by magnetic valve (13,23) Road, ultraviolet lamp and inverter parallel;220V civil powers, transformer, bridge rectifier, battery, telegraph key, inverter, magnetic valve (13,23), combustible gas detector, resistance (25,22,7,8,17), variable resistor 20, electric capacity, electrochemical capacitor, diode, put Big device, the operating circuit of LED (10,15,55) are assembled in circuit version (31), are fitted into and are connect in electric box, are fixed with bolt, and LED (10,15,55) is exposed at through LED hole and connect outside electric box, reservation stomata is unimpeded, then electric box will be connect and is passed through with bolt Screw is fixed on above crust of the device;Telegraph key, which is assembled in, to be connect in electric box, and telegraph key is from crust of the device outer control;Electric fan has been placed in outlet The electric fan in hole is fixed to be fixed on steelframe with bolt by screw, connects wire;Load ultraviolet in the inner bag of coating of titanium dioxide In line lamp and electric heating piece, the rear wall that electric heating piece is fixed on to the inner bag of the coating of titanium dioxide of venthole with bolt by screw Between, connect wire;Again by the inner bag charging apparatus shell of coating of titanium dioxide, fixed by screw with bolt;Then will have The ultraviolet screener lid of air admission hole covers the inner bag collar extension in coating of titanium dioxide, is screwed by silk tooth;With bolt by gas sensing The circuit version (56) of device and formaldehyde gas inductor, which is fixed on, to be exposed the ultraviolet screener of air admission hole and covers, and connects wire;Refill On have the protecgulum of air admission hole, and screwed by Si Ya with crust of the device;In work of the crust of the device rear fixation through lime water process After property charcoal square, silicon window is loaded on;Then the bonnet of venthole is covered, is screwed by Si Ya with crust of the device.
3. a kind of indoor toxic gas automatic detection and the application method of purification air interchanger, it is characterized in that:Power-on, enters Detection, purification, ventilation and/or alert operation state;
When interior has toxic gas, a fuel gas, but concentration is not high is less than 500ppm, is less than《Indoor Air Quality standards》 GB/T 18883-2002 safety standard formaldehyde HCHO mg/m30.10 1h averages, formaldehyde HCHO mg/m3≤0.08≤0.12;One Carbonoxide CO mg/m310 1h averages, benzene C6H6mg/m30.11 1h averages, inhalable particles PM10mg/m30.15 daily mean When, gas sensor produces sensing, anode (E), negative electrode (F) and the formaldehyde gas sense of gas sensor with formaldehyde gas inductor Answer the anode (K) of device, negative electrode (L) to produce electric signal, amplified by amplifier, LED bright light, electric fan work allows rotation Air is contacted with the activated carbon square through lime water process, and toxic gas, fuel gas are by the activated carbon side through lime water process Block adsorption cleaning, then displaces fresh air by silicon window, is appeared from venthole;
When interior has toxic gas, fuel gas, but concentration is higher, exceeds《Indoor Air Quality standards》GB/T 18883- 2002 safety standards:Formaldehyde HCHO mg/m30.10 1h averages, formaldehyde HCHO mg/m3≤0.08≤0.12;Carbon monoxide CO mg/m310 1h averages, benzene C6H6mg/m30.11 1h averages, inhalable particles PM10mg/m30.15 daily mean, and have formaldehyde Deng toxic gas when, formaldehyde gas inductor produces sensing, and the anode (K) of formaldehyde gas inductor, negative electrode (L) produce telecommunications Number, magnetic valve connects inverter, opens ultraviolet lamp and electric heating piece, the coating of titanium dioxide allowed in the inner bag of coating of titanium dioxide The photocatalytic oxidation of photocatalyst is carried out, toxic gas heated oxide is allowed, carbon dioxide and water are resolved into, then by through stone The purification of activated carbon square, the absorption of grey water process, then displace fresh air by silicon window, are appeared from venthole;
Wherein:Formaldehyde reaction equation is, HCHO+H2O→CO2+4H++ 4e, O2+4H++ 4e → 2H2O, HCHO+H2O→CO2+2H2O;Receive Rice TiO2Photocatalytic advanced oxidation technology reaction (photocatalyst) process and reaction equation be, TiO2+hv→h++e-, h++e-→ E, H2O→H++OH-, h++OH-→ OH, h++H2O+O2-→·OH+H++·O2-, h++H2O→·OH+H+, e-+O2→· O2-, O2-+H+→·HO2, 2HO2→O2+H2O2, H2O2+·O-2→·OH+OH-+O2;(wherein:OH is hydroxyl free Base, O2-For ultra-oxygen anion free radical, H2O2For hydrogen peroxide, HO2For super oxygen hydroperoxyl radical, hv is photon energy, h+ For the photo-induced hole on conduction band, e-For photoinduced electron, E is chemical energy);
Lime reaction formula in activated carbon square through lime water process is:CaO+H2O=Ca (OH)2, CaO+CO2=CaCO3, Ca (OH)2+CO2=CaCO3+H2O, CaCO3Δ=CaO+CO2
Fuel gas is respectively with the reaction equation that oxygen reacts:Carbon monoxide and coal gas reaction equation be, 2CO+O2=2CO2; Hydrogen reaction equation is 2H2+O2=2H2O;EthanolReaction equation is, C2H5OH+3O2=2CO2+3H2O;Benzene reaction equation is, 2C6H6+15O2 =12CO2+6H2O;Polycyclic aromatic hydrocarbon (hydrocarbon) reaction equation is, HC+O2→CO2+H2O;Gas and methane reaction formula, CH4+ 2O2=CO2+2H2O.Carbon monoxide, gas, coal gas, hydrogen,Ethanol, benzene, polycyclic aromatic hydrocarbon (hydrocarbon), methane CH4Equal energy CO is generated by heating, burning or high-temperature oxydation mode2And H2O;
Toxic gas hydrogen sulfide reaction equation is:2H2S+3O2=2SO2+2H2O, toxic gas nitrogen, the reaction equation of oxysulfide are: SO2+H2O=H2SO3, H2SO3+ CaO=H2O+CaSO3, 4NO2+2Ca(OH)2=Ca (NO3)2+Ca(NO2)2+2H2O;In reaction CaSO3、Ca(NO3)2、Ca(NO2)2With the PM2.5 in air, PM10, particulate matter by the activated carbon square through lime water process Absorption;
When there is toxic gas, fuel gas in interior, and dense when exceeding explosion limit, the sun of combustible gas detector Pole (A), negative electrode (B) produce electric signal, by loudspeaker alarm, and the inverter, ultraviolet being had already turned on by closed electromagnetic valve Line lamp, electric heating piece, cut off thermal source, indoor occupant is withdrawn from indoor emergency, and is sought help to the police, handle dangerous by professional;
When toxic gas, fuel gas is not present in interior, anode (E), the negative electrode (F) of gas sensor sense with formaldehyde gas Anode (K), the negative electrode (L) of device, and electric signal is not produced between the anode (A) and negative electrode (B) of combustible gas detector, LED does not work, and electric fan, inverter, ultraviolet lamp, electric heating piece do not work, and there is poison gas the interior that indoor occupant closes the present invention Body automatic detection mutually uses power supply with purifying the direct current of air interchanger and/or exchanging, and is stopped;
Using charcoal absorption PM2.5, PM10, particulate matter and nitrogen, oxysulfide through lime water process, depending on air pollution situation With the concentration of PM2.5, PM10, particulate matter and nitrogen, oxysulfide, find that the activated carbon through lime water process is inhaled after a period of time When attached PM2.5, PM10, particulate matter and nitrogen, sulfur oxide contamination are serious, the bonnet and silicon window of venthole are screwed off, will be through stone The activated carbon square of grey water process takes out and changed, and is then reinstalled, bonnet is screwed by Si Ya with crust of the device.
4. a kind of indoor toxic gas automatic detection according to claim 3 and the application method of purification air interchanger, its It is characterized in:Ultraviolet lamp and electric heating piece, in the inner bag of coating of titanium dioxide, coating of titanium dioxide is carried out by ultraviolet lamp The photocatalytic oxidation of photocatalyst, ultraviolet covers screen by ultraviolet screener lid.
5. a kind of indoor toxic gas automatic detection according to claim 3 and the application method of purification air interchanger, its It is characterized in:Gas sensor, formaldehyde gas inductor, combustible gas detector are used to detect, detected poisonous, fuel gas dense Degree.
6. a kind of indoor toxic gas automatic detection according to claim 3 and the application method of purification air interchanger, its It is characterized in:220V civil powers and/or battery make direct current and/or exchange mutually uses power supply, when there are 220V civil powers interior, cut-out electricity Key, allows 220V civil powers to work;When interior does not have 220V civil powers, battery-operated is allowed, ultraviolet lamp and electric heating piece therein need 220V voltages provided by inverter;220V civil powers and telegraph key are closed, is stopped;Telegraph key is not closed, while in 220V civil powers Under work, battery is charged by transformer, bridge rectifier rectification to battery;During accumulator electric-quantity saturation, LED is extinguished, Very important person is closing telegraph key in time or cut-out 220V civil powers.
7. a kind of indoor toxic gas automatic detection according to claim 3 and the application method of purification air interchanger, its It is characterized in:Loudspeaker is used to alarm.
8. a kind of indoor toxic gas automatic detection according to claim 3 and the application method of purification air interchanger, its It is characterized in:Electric fan, electric heating, photocatalyst and the activated carbon through lime water process are used to purify.
9. a kind of indoor toxic gas automatic detection according to claim 3 and the application method of purification air interchanger, its It is characterized in:Silicon window is used to take a breath.
10. a kind of indoor toxic gas automatic detection according to claim 3 and the application method of purification air interchanger, its It is characterized in:Direct current and/or exchange mutually use power supply, and by telegraph key or magnetic valve (13,23) as control main part, selection is cut off or closed Closed circuit.
CN201611272304.9A 2016-12-28 2016-12-28 Indoor toxic gas automatic detection and purification air interchanger Pending CN107045040A (en)

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CN110700874A (en) * 2019-09-26 2020-01-17 武汉理工大学 Mine self-propelled air purification equipment
CN111336600A (en) * 2020-04-04 2020-06-26 长沙贤正益祥机械科技有限公司 Fresh air system, central air conditioner, and control system and method thereof
CN111336619A (en) * 2020-04-04 2020-06-26 长沙贤正益祥机械科技有限公司 Air purifier, control method thereof and air purification method
CN111365840A (en) * 2020-04-04 2020-07-03 长沙贤正益祥机械科技有限公司 Warm air device and control system and method thereof
CN112142098A (en) * 2019-06-28 2020-12-29 东北大学 Ag coated SnO2Preparation of SO2Method for sensing material

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CN109114761A (en) * 2018-10-18 2019-01-01 广东美的制冷设备有限公司 Control method, device, air conditioner and the computer readable storage medium of air conditioner
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CN110700874A (en) * 2019-09-26 2020-01-17 武汉理工大学 Mine self-propelled air purification equipment
CN111336600A (en) * 2020-04-04 2020-06-26 长沙贤正益祥机械科技有限公司 Fresh air system, central air conditioner, and control system and method thereof
CN111336619A (en) * 2020-04-04 2020-06-26 长沙贤正益祥机械科技有限公司 Air purifier, control method thereof and air purification method
CN111365840A (en) * 2020-04-04 2020-07-03 长沙贤正益祥机械科技有限公司 Warm air device and control system and method thereof

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Application publication date: 20170815