CN107043493A - A kind of heating cable protective cover material of good heat preservation performance - Google Patents
A kind of heating cable protective cover material of good heat preservation performance Download PDFInfo
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- CN107043493A CN107043493A CN201710224481.8A CN201710224481A CN107043493A CN 107043493 A CN107043493 A CN 107043493A CN 201710224481 A CN201710224481 A CN 201710224481A CN 107043493 A CN107043493 A CN 107043493A
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- parts
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- rectorite
- heat preservation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention discloses a kind of heating cable protective cover material of good heat preservation performance, its raw material includes by weight：70 90 parts of major ingredient, 24 parts of laurate, 13 parts of polyamidoimide, 24 parts of epoxidized soybean oil, 2 2.8 parts of diethyl phthalate, 0.5 0.8 parts of TM monex TM, 12 parts of diphenylguanidine, 1,1 pair of 0.4 0.8 parts of (t-butyl peroxy) hexamethylene, 3,3 pairs of 12 parts of (t-amyl peroxy) ethyl butyrates, 75 85 parts of packing strengthening agent, 24 parts of age resistor.Rectorite compound is prepared using following technique：Peanut protein, xylose, hydroecium temperature are well mixed, regulation system pH value is 9 9.6, heating, insulation, adds glycerine and continues to stir, and adds rectorite, water stirring, regulation system pH value is 3 3.8, adds PDDA stirring, filtering, washing, adds water stirring, adds potassium carbonate and continues to stir, filtering, washing, is dried to constant weight, grinding obtains rectorite compound.
Description
Technical field
The present invention relates to the heating cable protective cover material of field of cable technology, more particularly to a kind of good heat preservation performance.
Background technology
Overheat protector temperature transducer is combined together with heating cable, realizes the upgrading that point protection is protected to face, is reduced
Difficulty of construction, but the heating cable is in use, however it remains the problem of under heating service efficiency, sheath heat insulating ability
Difference, power consumption is high during coming into operation, and makes many people hope and draw back.How a kind of good heat preservation performance, cost low shield is prepared
Jacking, it would be highly desirable to solve.
The content of the invention
The technical problem existed based on background technology, the present invention proposes a kind of heating cable sheath of good heat preservation performance
Material, good heat preservation performance, and also mechanical property is good, wear-resisting, the tear-resistant, excellent effect of resistance to dragging.
A kind of heating cable protective cover material of good heat preservation performance proposed by the present invention, its raw material includes by weight：Major ingredient 70-
90 parts, 2-4 parts of laurate, 1-3 parts of polyamidoimide, 2-4 parts of epoxidized soybean oil, 2-2.8 parts of diethyl phthalate promotees
Enter 0.5-0.8 parts of agent TMTM, 1-2 parts of diphenylguanidine, 1,1- double -0.4-0.8 part of (t-butyl peroxy) hexamethylene, 3,3- pairs -
1-2 parts of (t-amyl peroxy) ethyl butyrate, 75-85 parts of packing strengthening agent, 2-4 parts of age resistor.
Preferably, major ingredient includes by weight：80-90 parts of ethylene propylene diene rubber, 20-40 parts of neoprene, polypropylene 30-
50 parts.
Preferably, packing strengthening agent includes by weight：40-60 parts of rectorite compound, 10-18 parts of carbon fiber, kaolinite
It is native 20-30 parts, 15-25 parts of powdered whiting.
Preferably, rectorite compound is prepared using following technique：Peanut protein, xylose, hydroecium temperature are well mixed, adjusted
Section system pH is 9-9.6, is heated, insulation, adds glycerine and continues to stir, and adds rectorite, water stirring, and regulation system pH value is
3-3.8, adds PDDA stirring, filters, and washing adds water stirring, adds potassium carbonate and continues to stir,
Filtering, washing is dried to constant weight, grinding obtains rectorite compound.
Preferably, rectorite compound is prepared using following technique：By weight by 20-30 parts of peanut proteins, 4-8 parts of wood
Sugar, 60-80 parts of hydroecium temperature are well mixed, and regulation system pH value is 9-9.6, is heated, insulation, are added 30-50 parts of glycerine and are continued to stir
Mix, add 15-25 parts of rectorites, 100-140 parts of water stirrings, regulation system pH value is 3-3.8, adds 2-3 parts of poly dimethyls two
Allyl ammonium chloride is stirred, and is filtered, washing, adds 150-160 parts of water stirrings, is added 4-6 parts of potassium carbonate and is continued to stir, filtering,
Washing, is dried to constant weight, grinding obtains rectorite compound.
Preferably, rectorite compound is prepared using following technique：By weight by 20-30 parts of peanut proteins, 4-8 parts of wood
Sugar, 60-80 parts of hydroecium temperature are well mixed, and regulation system pH value is 9-9.6, are heated to 85-95 DEG C of insulation 3-4h, are added 30-50
Part glycerine continues to stir 45-65min, adds 15-25 parts of rectorites, 100-140 parts of water stirring 5-6h, mixing speed is 1000-
1200r/min, regulation system pH value is 3-3.8, adds 2-3 parts of PDDA stirring 1-2h, and filtering is washed
Wash, add 150-160 parts of water stirring 3-5h, add 4-6 parts of potassium carbonate and continue to stir 1.5-2.5h, whipping temp is 75-85 DEG C,
Filtering, washing, 145-155 DEG C of drying to constant weight, grinding obtains rectorite compound.
The present invention uses ethylene propylene diene rubber, neoprene, polypropylene compounding for major ingredient, through 3,3- pairs-(tertiary pentyl mistake
Oxygen) ethyl butyrate, 1,1- be double-(t-butyl peroxy) hexamethylene, TM monex TM, diphenylguanidine vulcanization, good heat preservation performance, Er Qieli
Learn performance good, wear-resisting, the tear-resistant, excellent effect of resistance to dragging；In rectorite compound, xylose is combined with peanut protein, is grafted journey
Degree is high, can not only strengthen peanut protein intensity, ductility and water resistance, coordinates with glycerine, good with rectorite compounding effect, warp
After peracid activation, be modified using PDDA, then with potassium carbonate ion exchange, absorption property is excellent,
It is cheap and raw material sources are wide；Coordinated with rectorite compound and carbon fiber, kaolin, powdered whiting, particle aggregation
Degree is low, improves the compactness of the present invention, further adds polyamidoimide, diethyl phthalate, epoxidized soybean oil association
Same-action, can promote toughness to be reached with hardness balanced, make the warp resistance of the present invention, tear-resistant effect high, and cost is low.This
Invention uses more cheap material, it is ensured that the isolation to interior metal heat generating core heat is incubated, and using effect is good, the later stage
Maintenance cost is relatively low.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of heating cable protective cover material of good heat preservation performance proposed by the present invention, its raw material includes by weight：Major ingredient 70
Part, 4 parts of laurate, 1 part of polyamidoimide, 4 parts of epoxidized soybean oil, 2 parts of diethyl phthalate, TM monex TM 0.8
Part, 1 part of diphenylguanidine, 1,1- double -0.8 part of (t-butyl peroxy) hexamethylene, 3,3- double -1 part of (t-amyl peroxy) ethyl butyrates,
85 parts of packing strengthening agent, 2 parts of age resistor.
Embodiment 2
A kind of heating cable protective cover material of good heat preservation performance proposed by the present invention, its raw material includes by weight：Major ingredient 90
Part, 2 parts of laurate, 3 parts of polyamidoimide, 2 parts of epoxidized soybean oil, 2.8 parts of diethyl phthalate, TM monex TM
0.5 part, 2 parts of diphenylguanidine, 1,1- double -0.4 part of (t-butyl peroxy) hexamethylene, 3,3- double-(t-amyl peroxy) ethyl butyrates 2
Part, 75 parts of packing strengthening agent, 4 parts of age resistor.
Major ingredient includes by weight：80 parts of ethylene propylene diene rubber, 40 parts of neoprene, 30 parts of polypropylene；Packing strengthening agent
Include by weight：60 parts of rectorite compound, 10 parts of carbon fiber, 30 parts of kaolin, 15 parts of powdered whiting.
Rectorite compound is prepared using following technique：Peanut protein, xylose, hydroecium temperature are well mixed, regulation system
PH value is 9-9.6, is heated, insulation, adds glycerine and continues to stir, and adds rectorite, water stirring, and regulation system pH value is 3-3.8,
PDDA stirring is added, is filtered, washing adds water stirring, potassium carbonate is added and continues to stir, filtering,
Washing, is dried to constant weight, grinding obtains rectorite compound.
Embodiment 3
A kind of heating cable protective cover material of good heat preservation performance proposed by the present invention, its raw material includes by weight：Major ingredient 75
Part, 3.5 parts of laurate, 1.5 parts of polyamidoimide, 3.5 parts of epoxidized soybean oil, 2.2 parts of diethyl phthalate, accelerator
0.7 part of TMTM, 1.2 parts of diphenylguanidine, 1,1- double -0.7 part of (t-butyl peroxy) hexamethylene, 3,3- double-(t-amyl peroxy) fourths
1.4 parts of acetoacetic ester, 83 parts of packing strengthening agent, 2.5 parts of age resistor.
Major ingredient includes by weight：90 parts of ethylene propylene diene rubber, 20 parts of neoprene, 50 parts of polypropylene；Packing strengthening agent
Include by weight：40 parts of rectorite compound, 18 parts of carbon fiber, 20 parts of kaolin, 25 parts of powdered whiting.
Rectorite compound is prepared using following technique：By weight by 25 parts of peanut proteins, 6 parts of xyloses, 70 parts of hydroeciums
Temperature is well mixed, and regulation system pH value is 9-9.6, and heating, insulation adds 40 parts of glycerine and continues to stir, 20 parts of rectorites of addition,
120 parts of water stirrings, regulation system pH value is 3-3.8, adds 2.5 parts of PDDA stirrings, and filtering is washed
Wash, add 155 parts of water stirrings, add 5 parts of potassium carbonate and continue to stir, filter, washing, dry to constant weight, grinding obtains rectorite
Compound.
Embodiment 4
A kind of heating cable protective cover material of good heat preservation performance proposed by the present invention, its raw material includes by weight：Major ingredient 85
Part, 2.5 parts of laurate, 2.5 parts of polyamidoimide, 2.5 parts of epoxidized soybean oil, 2.4 parts of diethyl phthalate, accelerator
0.6 part of TMTM, 1.8 parts of diphenylguanidine, 1,1- double -0.5 part of (t-butyl peroxy) hexamethylene, 3,3- double-(t-amyl peroxy) fourths
1.6 parts of acetoacetic ester, 78 parts of packing strengthening agent, 3.5 parts of age resistor.
Major ingredient includes by weight：82 parts of ethylene propylene diene rubber, 35 parts of neoprene, 35 parts of polypropylene；Packing strengthening agent
Include by weight：55 parts of rectorite compound, 12 parts of carbon fiber, 28 parts of kaolin, 18 parts of powdered whiting.
Rectorite compound is prepared using following technique：By weight by 20 parts of peanut proteins, 8 parts of xyloses, 60 parts of hydroeciums
Temperature is well mixed, and regulation system pH value is 9-9.6, is heated to 95 DEG C of insulation 3h, adds 50 parts of glycerine and continues to stir 45min, plus
Enter 25 parts of rectorites, 100 parts of water stirring 6h, mixing speed is 1000r/min, and regulation system pH value is 3-3.8, adds 3 parts and gathers
Dimethyl diallyl ammonium chloride stirs 1h, filters, washing, adds 160 parts of water stirring 3h, adds 6 parts of potassium carbonate and continue to stir
1.5h, whipping temp is 85 DEG C, is filtered, and washing, 145 DEG C of dryings to constant weight, grinding obtains rectorite compound.
Embodiment 5
A kind of heating cable protective cover material of good heat preservation performance proposed by the present invention, its raw material includes by weight：Major ingredient 80
Part, 3 parts of laurate, 2 parts of polyamidoimide, 3 parts of epoxidized soybean oil, 2.3 parts of diethyl phthalate, TM monex TM
0.65 part, 1.5 parts of diphenylguanidine, 1,1- double -0.6 part of (t-butyl peroxy) hexamethylene, 3,3- double-(t-amyl peroxy) butyric acid second
1.5 parts of ester, 80 parts of packing strengthening agent, 3 parts of age resistor.
Major ingredient includes by weight：88 parts of ethylene propylene diene rubber, 25 parts of neoprene, 45 parts of polypropylene；Packing strengthening agent
Include by weight：45 parts of rectorite compound, 16 parts of carbon fiber, 22 parts of kaolin, 22 parts of powdered whiting.
Rectorite compound is prepared using following technique：By weight by 30 parts of peanut proteins, 4 parts of xyloses, 80 parts of hydroeciums
Temperature is well mixed, and regulation system pH value is 9-9.6, is heated to 85 DEG C of insulation 4h, adds 30 parts of glycerine and continues to stir 65min, plus
Enter 15 parts of rectorites, 140 parts of water stirring 5h, mixing speed is 1200r/min, and regulation system pH value is 3-3.8, adds 2 parts and gathers
Dimethyl diallyl ammonium chloride stirs 2h, filters, washing, adds 150 parts of water stirring 5h, adds 4 parts of potassium carbonate and continue to stir
2.5h, whipping temp is 75 DEG C, is filtered, and washing, 155 DEG C of dryings to constant weight, grinding obtains rectorite compound.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (6)
1. the heating cable protective cover material of a kind of good heat preservation performance, it is characterised in that its raw material includes by weight：Major ingredient 70-90
Part, 2-4 parts of laurate, 1-3 parts of polyamidoimide, 2-4 parts of epoxidized soybean oil, 2-2.8 parts of diethyl phthalate promotes
0.5-0.8 parts of agent TMTM, 1-2 parts of diphenylguanidine, 1,1- double -0.4-0.8 parts of (t-butyl peroxy) hexamethylene, 3,3- double-(uncles
Amyl peroxy) 1-2 parts of ethyl butyrate, 75-85 parts of packing strengthening agent, 2-4 parts of age resistor.
2. the heating cable protective cover material of good heat preservation performance according to claim 1, it is characterised in that major ingredient is wrapped by weight
Include：80-90 parts of ethylene propylene diene rubber, 20-40 parts of neoprene, 30-50 parts of polypropylene.
3. the heating cable protective cover material of good heat preservation performance according to claim 1 or claim 2, it is characterised in that packing strengthening agent is pressed
Parts by weight include：40-60 parts of rectorite compound, 10-18 parts of carbon fiber, 20-30 parts of kaolin, 15-25 parts of powdered whiting.
4. the heating cable protective cover material of good heat preservation performance according to claim 3, it is characterised in that rectorite compound is used
It is prepared by following technique：Peanut protein, xylose, hydroecium temperature are well mixed, regulation system pH value is 9-9.6, is heated, insulation, plus
Enter glycerine to continue to stir, add rectorite, water stirring, regulation system pH value is 3-3.8, adds poly dimethyl allyl chlorination
Ammonium is stirred, and is filtered, washing, adds water stirring, is added potassium carbonate and is continued to stir, filter, washing is dried to constant weight, grinding is obtained
Rectorite compound.
5. the heating cable protective cover material of good heat preservation performance according to claim 3 or 4, it is characterised in that rectorite compound
Prepared using following technique：20-30 parts of peanut proteins, 4-8 parts of xyloses, 60-80 parts of hydroecium temperature are well mixed by weight, adjusted
Section system pH is 9-9.6, is heated, insulation, adds 30-50 parts of glycerine and continues to stir, adds 15-25 parts of rectorites, 100-140
Part water stirring, regulation system pH value is 3-3.8, adds 2-3 parts of PDDAs and stirs, filtering, washing, plus
Enter 150-160 parts of water stirrings, add 4-6 parts of potassium carbonate and continue to stir, filter, washing, dry to constant weight, grinding obtains rectorite
Compound.
6. according to the heating cable protective cover material of any one of the claim 3-5 good heat preservation performances, it is characterised in that rectorite is multiple
Compound is prepared using following technique：It is by weight that 20-30 parts of peanut proteins, 4-8 parts of xyloses, 60-80 parts of water mixed at room temperature are equal
Even, regulation system pH value is 9-9.6, is heated to 85-95 DEG C of insulation 3-4h, adds 30-50 parts of glycerine and continues to stir 45-65min,
15-25 parts of rectorites, 100-140 parts of water stirring 5-6h are added, mixing speed is 1000-1200r/min, and regulation system pH value is
3-3.8, adds 2-3 parts of PDDA stirring 1-2h, filters, washing, adds 150-160 parts of water stirring 3-
5h, adds 4-6 parts of potassium carbonate and continues to stir 1.5-2.5h, whipping temp is 75-85 DEG C, is filtered, washing, 145-155 DEG C of drying
To constant weight, grinding obtains rectorite compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710224481.8A CN107043493A (en) | 2017-04-07 | 2017-04-07 | A kind of heating cable protective cover material of good heat preservation performance |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710224481.8A CN107043493A (en) | 2017-04-07 | 2017-04-07 | A kind of heating cable protective cover material of good heat preservation performance |
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| CN107043493A true CN107043493A (en) | 2017-08-15 |
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| CN201710224481.8A Withdrawn CN107043493A (en) | 2017-04-07 | 2017-04-07 | A kind of heating cable protective cover material of good heat preservation performance |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107778877A (en) * | 2017-09-15 | 2018-03-09 | 安徽伙伴电气有限公司 | A kind of used in nuclear power station strong radiation resistant instrument cable |
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2017
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| CN103804746A (en) * | 2012-11-13 | 2014-05-21 | 安邦电气集团有限公司 | Automatic temperature control heating cable and preparation method thereof |
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| CN103289136A (en) * | 2013-06-21 | 2013-09-11 | 北京邦明生物技术研究院 | Sodium alginate and rectorite nanometer composite material preparation method |
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Application publication date: 20170815 |