CN103992638B - A kind of Memorability nylon rubber-plastics material and preparation method thereof - Google Patents
A kind of Memorability nylon rubber-plastics material and preparation method thereof Download PDFInfo
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- CN103992638B CN103992638B CN201410247150.2A CN201410247150A CN103992638B CN 103992638 B CN103992638 B CN 103992638B CN 201410247150 A CN201410247150 A CN 201410247150A CN 103992638 B CN103992638 B CN 103992638B
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- China
- Prior art keywords
- nylon
- memorability
- plastics material
- maleic anhydride
- rubber
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- 239000004677 Nylon Substances 0.000 title claims abstract description 83
- 229920001778 nylon Polymers 0.000 title claims abstract description 83
- 239000000463 material Substances 0.000 title claims abstract description 66
- 229920003023 plastic Polymers 0.000 title claims abstract description 58
- 239000004033 plastic Substances 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 30
- 230000004048 modification Effects 0.000 claims abstract description 23
- 238000012986 modification Methods 0.000 claims abstract description 23
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 21
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 21
- 229920002545 silicone oil Polymers 0.000 claims abstract description 20
- 229920000570 polyether Polymers 0.000 claims abstract description 19
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004970 Chain extender Substances 0.000 claims abstract description 17
- 125000003118 aryl group Chemical group 0.000 claims abstract description 17
- 239000003054 catalyst Substances 0.000 claims abstract description 17
- 239000003999 initiator Substances 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 18
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 18
- 229920001038 ethylene copolymer Polymers 0.000 claims description 16
- 239000000945 filler Substances 0.000 claims description 16
- 239000000314 lubricant Substances 0.000 claims description 16
- MSAVICZWFPQFPO-UHFFFAOYSA-N acetic acid;ethene Chemical group C=C.C=C.CC(O)=O MSAVICZWFPQFPO-UHFFFAOYSA-N 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 12
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 12
- BJZYYSAMLOBSDY-QMMMGPOBSA-N (2s)-2-butoxybutan-1-ol Chemical compound CCCCO[C@@H](CC)CO BJZYYSAMLOBSDY-QMMMGPOBSA-N 0.000 claims description 11
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims description 11
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 11
- -1 polytrimethylene Polymers 0.000 claims description 11
- 239000008116 calcium stearate Substances 0.000 claims description 10
- 235000013539 calcium stearate Nutrition 0.000 claims description 10
- 150000003504 terephthalic acids Chemical class 0.000 claims description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 9
- 239000001294 propane Substances 0.000 claims description 9
- 238000004821 distillation Methods 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 claims description 7
- 239000006229 carbon black Substances 0.000 claims description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 238000007605 air drying Methods 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 4
- 238000006068 polycondensation reaction Methods 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- ACOGMWBDRJJKNB-UHFFFAOYSA-N acetic acid;ethene Chemical group C=C.CC(O)=O ACOGMWBDRJJKNB-UHFFFAOYSA-N 0.000 claims 1
- 150000008065 acid anhydrides Chemical class 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 238000011084 recovery Methods 0.000 abstract description 8
- 229920000578 graft copolymer Polymers 0.000 abstract description 4
- 230000003446 memory effect Effects 0.000 abstract description 4
- 230000003647 oxidation Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- 239000004952 Polyamide Substances 0.000 abstract description 3
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- 229920002647 polyamide Polymers 0.000 abstract description 3
- 239000000498 cooling water Substances 0.000 description 4
- 230000006386 memory function Effects 0.000 description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000012781 shape memory material Substances 0.000 description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical group C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7461—Combinations of dissimilar mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/42—Polyamides containing atoms other than carbon, hydrogen, oxygen, and nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92561—Time, e.g. start, termination, duration or interruption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/12—Shape memory
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of Memorability nylon rubber-plastics material, it uses the component of following mass percent to make: modification of nylon, maleic anhydride graft copolymer, auxiliary agent；Wherein, described modification of nylon is by caprolactam: 35 42%；End-vinyl phenyl silicone oil: 5 25%；Initiator: 0.1 0.5%；Aromatic diacid: 1 10%；Polyethers: 15 40%；Catalyst: 0.1 1.1%；Chain extender: 1 10%；Antioxidant: 0.5 1.5% is prepared from.The invention also discloses the preparation method of above-mentioned Memorability nylon rubber-plastics material.The present invention uses the polyamide hard section of end-vinyl phenyl silicone oil modification of nylon, strengthen the combination properties such as the low-temperature flexibility of nylon, resistance to oxidation weatherability, thermostability and anti-flammability, with maleic anhydride graft copolymer toughening modifying nylon, obtain the nylon rubber-plastics material with plastics and rubber property, improve recovery of shape memory effect and comprehensive mechanical performance, overcome common nylon or its poor flexibility of plastic material, the problem of recovery of shape difference, strengthen the Memorability of the goods such as headset cord.
Description
Technical field
The present invention relates to plastic material technical field, particularly relate to headset cord Memorability nylon rubber-plastics material and system thereof
Preparation Method.
Background technology
Shape-memory material is provided simultaneously with the general character of plastics and rubber, has the character of plastics, the most firmly in the range of room temperature
Property, dimensionally stable restorative, there is under uniform temperature (so-called memory temperature) characteristic of rubber simultaneously, mainly show as material
Deformability and shape recovery, the namely memory function of material, i.e. " memory initial state fixed deformation
Recovered primary state " circulation.General macromolecular material is near its glass transition temperature (Tg), and mechanical performance can occur substantially
Change.Below Tg then shows as rigidity and fragility；More than Tg then shows as elastic and flexible.These performances by glassy state to high-elastic
Though limiting the range of macromolecular material during the change of state, but this characteristic just can utilized to give its special function, i.e.
Shape memory function.Shape-memory material has the performance of excellence, such as shape memory effect, high replys deformation, easy coloring, good
Shock resistance and adaptability, and be easily combined with other materials with the form of line, granule or fiber and form composite etc. so that it is
Development increasingly comes into one's own.
Earphone goods such as wire rod great majority are plastic material, and its folding resistance, elasticity are not enough, the most ageing-resistant, make for a long time
With can hardening, be difficult to reply shape, product is elastic and flexibility not enough.Nylon material has that mechanical strength is high, electrical insulating property is good,
Self-lubricating, nontoxic, have performances such as self-extinguishment, but poor dimensional stability, low-temperature flexibility are poor, thermostability and the deficiency etc. of toughness, make
It is few in the application of the Memorability improving wire rod.Polysiloxane has high-low temperature resistant characteristic, resistance to oxidation, weatherability, hates
The features such as aqueous, utilize polysiloxane to improve the deficiency of nylon, make nylon combination property be improved, the invention reside in and carry
For a kind of Memorability nylon rubber-plastics material, there is good dimensional stability, low temperature flexibility, folding resistance, recovery of shape, resistance
The advantages such as combustion property, improve the Memorability of wire rod.
Summary of the invention
For the deficiencies in the prior art, it is an object of the invention to provide a kind of excellent combination property, shape memory good,
The Memorability nylon rubber-plastics material that processability is good.
The present invention also aims to provide the preparation method of a kind of Memorability nylon rubber-plastics material.
The above-mentioned purpose of the present invention is achieved by the following technical solution:
A kind of Memorability nylon rubber-plastics material, was made up of forming of following percentage by weight:
Wherein, described modification of nylon is made up of the component of following percentage by weight:
Described maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer
Middle maleic anhydride grafting ratio is 1.6%.
Described antioxidant is antioxidant 1010 or 1098；Described lubricant is calcium stearate；Described filler is
One or more in calcium carbonate, silicon dioxide, white carbon black；Described catalyst is the one in triphenyl phosphite, organotin
Or it is several；Described initiator is 2,2-pair-(tert-butyl peroxide) propane.
The 0.15-0.45% Han vinyl in described end-vinyl phenyl silicone oil.
Described polyethers is one or more in PTMG, polytrimethylene ether glycol.
Described aromatic diacid is one or both in isophthalic acid, terephthalic acids.
Described chain extender is double (2-oxazoline).
The preparation method of a kind of above-mentioned Memorability nylon rubber-plastics material, comprises the steps:
(1) modification of nylon
Caprolactam 40%, end-vinyl phenyl silicone oil, initiator are added in reactor in setting ratio, 60 DEG C,
0.02MPa evacuation is dehydrated, and carries out additive reaction 1.5 hours in 100 DEG C, will residue caprolactam, antioxidant, aromatic series two
Acid, adds in reactor, is warmed up to 240 DEG C, starts stirring after material melting, reacts 2h, is cooled to 180 DEG C, takes out at 0.06MPa
Vacuum polycondensation 1h, after without obvious distillation, continues evacuation 0.5h；Under N2 protects, by polyethers, catalyst in setting ratio
Add in reactor, be heated to 240 DEG C, react 2h, evacuation 0.04MPa, react 1h, add chain extender, react 1h, evacuation
0.04MPa, after without obvious distillation, discharging.
(2) modification of nylon that step (1) prepared, maleic anhydride grafted ethene-acetate ethylene copolymer, maleic acid
Acid anhydride graft phenylethene-butadiene copolymer, antioxidant, lubricant, filler put in homogenizer in setting ratio, with
1500 revs/min, stir 20 minutes under conditions of whipping temp 80 DEG C-100 DEG C after, pour the mixture in reactor into twin screw
In granulator, mixing rear extrusion at 160-180 DEG C；
(3) by extrudate with 5-10 DEG C of circulating water, air-drying, pelletizing is packed.
Described maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer
Middle maleic anhydride grafting ratio is 1.6%；Described antioxidant is antioxidant 1010 or 1098；Described lubricant is stearic acid
Calcium；Described filler is one or more in calcium carbonate, silicon dioxide, white carbon black；Described catalyst is phosphorous acid triphen
One or more in ester, organotin；Described initiator is 2,2-pair-(tert-butyl peroxide) propane；Described end ethylene
The 0.15-0.45% Han vinyl in base phenyl silicone oil；Described polyethers is PTMG, polytrimethylene ether second two
One or more in alcohol；Described aromatic diacid is one or both in isophthalic acid, terephthalic acids；Described chain extension
Agent is double (2-oxazoline).
Compared with prior art, the invention has the beneficial effects as follows:
1, the Memorability nylon rubber-plastics material that the present invention provides, uses the polyamide of end-vinyl phenyl silicone oil modification of nylon
Hard section, is soft section with polyethers section, and chain extender increases molecular weight, and the modification of nylon obtained has the characteristic of plastics and rubber, obtains
Possess the nylon rubber-plastics material of shape memory, and enhance the low-temperature flexibility of nylon, resistance to oxidation weatherability, thermostability and resistance
The combination properties such as combustion property, simultaneously with the toughness of maleic anhydride graft copolymer further toughening modifying nylon, add other auxiliary agents,
Improve recovery of shape memory effect and the comprehensive mechanical performance of nylon rubber-plastics material further.
2, the nylon rubber-plastics material prepared with the present invention prepares Memorability wire rod, Ke Yiti for raw material and other materials are compound
The shape memory of high wire rod, overcomes common nylon or its poor flexibility of plastic material, the problem of recovery of shape difference, through reality
Test, the product that this material is made, can stably keep its shape memory in 100,000 deformation operation number of times.
3, the preparation method of Memorability nylon rubber-plastics material that the present invention provides, rational technology, easy to process, be prone to industry
Change.
4, the present invention is suitable for manufacturing and various has the products such as the cable of shape memory function, adhesive tape.
Describe the present invention in detail below in conjunction with specific embodiment, but be not the further restriction to the present invention.
Detailed description of the invention
Embodiment 1:
The Memorability nylon rubber-plastics material that the present embodiment provides, was made up of forming of following percentage by weight:
Wherein, described modification of nylon is made up of the component of following percentage by weight:
Described maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer
Middle maleic anhydride grafting ratio is 1.6%.
Described antioxidant is antioxidant 1010 or 1098；Described lubricant is calcium stearate；Described filler is
One or more in calcium carbonate, silicon dioxide, white carbon black；Described catalyst is the one in triphenyl phosphite, organotin
Or it is several；Described initiator is 2,2-pair-(tert-butyl peroxide) propane.
The 0.15-0.45% Han vinyl in described end-vinyl phenyl silicone oil.
Described polyethers is one or more in PTMG, polytrimethylene ether glycol.
Described aromatic diacid is one or both in isophthalic acid, terephthalic acids.
Described chain extender is double (2-oxazoline).
The preparation method of a kind of above-mentioned Memorability nylon rubber-plastics material, comprises the steps:
(1) modification of nylon
Caprolactam 40%, end-vinyl phenyl silicone oil, initiator are added in reactor in setting ratio, 60 DEG C,
0.02MPa evacuation is dehydrated, and carries out additive reaction 1.5 hours in 100 DEG C, will residue caprolactam, antioxidant, aromatic series two
Acid, adds in reactor, is warmed up to 240 DEG C, starts stirring after material melting, reacts 2h, is cooled to 180 DEG C, takes out at 0.06MPa
Vacuum polycondensation 1h, after without obvious distillation, continues evacuation 0.5h；Under N2 protects, by polyethers, catalyst in setting ratio
Add in reactor, be heated to 240 DEG C, react 2h, evacuation 0.04MPa, react 1h, add chain extender, react 1h, evacuation
0.04MPa, after without obvious distillation, discharging.
(2) modification of nylon that step (1) prepared, maleic anhydride grafted ethene-acetate ethylene copolymer, maleic acid
Acid anhydride graft phenylethene-butadiene copolymer, antioxidant, lubricant, filler put in homogenizer in setting ratio, with
1500 revs/min, stir 20 minutes under conditions of whipping temp 80 DEG C-100 DEG C after, pour the mixture in reactor into twin screw
In granulator, mixing rear extrusion at 160-180 DEG C；
(3) by extrudate with 5-10 DEG C of circulating water, air-drying, pelletizing is packed.
Described maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer
Middle maleic anhydride grafting ratio is 1.6%；Described antioxidant is antioxidant 1010 or 1098；Described lubricant is stearic acid
Calcium；Described filler is one or more in calcium carbonate, silicon dioxide, white carbon black；Described catalyst is phosphorous acid triphen
One or more in ester, organotin；Described initiator is 2,2-pair-(tert-butyl peroxide) propane；Described end ethylene
The 0.15-0.45% Han vinyl in base phenyl silicone oil；Described polyethers is PTMG, polytrimethylene ether second two
One or more in alcohol；Described aromatic diacid is one or both in isophthalic acid, terephthalic acids；Described chain extension
Agent is that 2,2-is double (2-oxazoline).
Embodiment 2:
Memorability nylon rubber-plastics material that the present embodiment provides and preparation method thereof, substantially the same manner as Example 1, they are different
Part is:
A kind of Memorability nylon rubber-plastics material, was made up of forming of following percentage by weight:
Wherein, described modification of nylon is made up of the component of following percentage by weight:
Described maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer
Middle maleic anhydride grafting ratio is 1.6%.
Described antioxidant is antioxidant 1010；Described lubricant is calcium stearate；Described filler is calcium carbonate；
Described catalyst is triphenyl phosphite；Described initiator is 2,2-pair-(tert-butyl peroxide) propane.
Containing vinyl 0.15% in described end-vinyl phenyl silicone oil.
Described polyethers is PTMG.
Described aromatic diacid is isophthalic acid.
Described chain extender is double (2-oxazoline).
The preparation method of a kind of above-mentioned Memorability nylon rubber-plastics material, comprises the steps:
(1) modification of nylon
Caprolactam 40%, end-vinyl phenyl silicone oil, initiator are added in reactor in setting ratio, 60 DEG C,
0.02MPa evacuation is dehydrated, and carries out additive reaction 1.5 hours in 100 DEG C, will residue caprolactam, antioxidant, aromatic series two
Acid, adds in reactor, is warmed up to 240 DEG C, starts stirring after material melting, reacts 2h, is cooled to 180 DEG C, takes out at 0.06MPa
Vacuum polycondensation 1h, after without obvious distillation, continues evacuation 0.5h；Under N2 protects, by polyethers, catalyst in setting ratio
Add in reactor, be heated to 240 DEG C, react 2h, evacuation 0.04MPa, react 1h, add chain extender, react 1h, evacuation
0.04MPa, after without obvious distillation, discharging.
(2) modification of nylon that step (1) prepared, maleic anhydride grafted ethene-acetate ethylene copolymer, maleic acid
Acid anhydride graft phenylethene-butadiene copolymer, antioxidant, lubricant, filler put in homogenizer in setting ratio, with
1500 revs/min, stir 20 minutes under conditions of whipping temp 80 DEG C after, pour the mixture in reactor into twin screw granulator
In, mixing rear extrusion at 160 DEG C；
(3) by extrudate with 5 DEG C of circulating waters, air-drying, pelletizing is packed.
Described maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer
Middle maleic anhydride grafting ratio is 1.6%；Described antioxidant is antioxidant 1010；Described lubricant is calcium stearate；Described
Filler be calcium carbonate；Described catalyst is triphenyl phosphite；Described initiator is 2,2-pair-(the tertiary fourth of peroxidating
Base) propane；Containing vinyl 0.15% in described end-vinyl phenyl silicone oil；Described polyethers is PTMG；
Described aromatic diacid is isophthalic acid；Described chain extender is double (2-oxazoline).
Embodiment 3:
Memorability nylon rubber-plastics material that the present embodiment provides and preparation method thereof, essentially identical with embodiment 1,2, it is not
It is with part:
A kind of Memorability nylon rubber-plastics material, was made up of forming of following percentage by weight:
Wherein, described modification of nylon is made up of the component of following percentage by weight:
Described maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer
Middle maleic anhydride grafting ratio is 1.6%；Described antioxidant is antioxidant 1010；Described lubricant is calcium stearate；Described
Filler be white carbon black；Described catalyst is organotin；Described initiator is 2,2-pair-(tert-butyl peroxide) propane；
Containing vinyl 0.25% in described end-vinyl phenyl silicone oil；Described polyethers is polytrimethylene ether glycol；Described
Aromatic diacid is terephthalic acids；Described chain extender is double (2-oxazoline).
A kind of above-mentioned Memorability nylon rubber-plastics material and preparation method thereof, its difference is:
Whipping temp is 100 DEG C；Mixing extrusion temperature is 170 DEG C；Cooling water temperature is 8 DEG C.
Embodiment 4:
Memorability nylon rubber-plastics material that the present embodiment provides and preparation method thereof, essentially identical with embodiment 1,2,3, its
Difference is:
A kind of Memorability nylon rubber-plastics material, was made up of forming of following percentage by weight:
Wherein, described modification of nylon is made up of the component of following percentage by weight:
Described maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer
Middle maleic anhydride grafting ratio is 1.6%；Described antioxidant is antioxidant 1010；Described lubricant is calcium stearate；Described
Filler be calcium carbonate；Described catalyst is organotin；Described initiator is 2,2-pair-(tert-butyl peroxide) third
Alkane；Containing vinyl 0.25% in described end-vinyl phenyl silicone oil；Described polyethers is PTMG；Described
Aromatic diacid is terephthalic acids；Described chain extender is double (2-oxazoline).
A kind of above-mentioned Memorability nylon rubber-plastics material and preparation method thereof, its difference is:
Whipping temp is 100 DEG C；Mixing extrusion temperature is 170 DEG C；Cooling water temperature is 6 DEG C.
Embodiment 5:
Memorability nylon rubber-plastics material that the present embodiment provides and preparation method thereof, essentially identical with embodiment 1,2,3,4,
Its difference is:
A kind of Memorability nylon rubber-plastics material, was made up of forming of following percentage by weight:
Wherein, described modification of nylon is made up of the component of following percentage by weight:
Described maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer
Middle maleic anhydride grafting ratio is 1.6%；Described antioxidant is antioxidant 1010；Described lubricant is calcium stearate；Described
Filler be silicon dioxide；Described catalyst is organotin；Described initiator is 2,2-pair-(tert-butyl peroxide) third
Alkane；Containing vinyl 0.45% in described end-vinyl phenyl silicone oil；Described polyethers is PTMG；Described
Aromatic diacid is terephthalic acids；Described chain extender is double (2-oxazoline).
A kind of above-mentioned Memorability nylon rubber-plastics material and preparation method thereof, its difference is:
Whipping temp is 100 DEG C；Mixing extrusion temperature is 180 DEG C；Cooling water temperature is 10 DEG C.
Embodiment 6:
Memorability nylon rubber-plastics material that the present embodiment provides and preparation method thereof, phase basic with embodiment 1,2,3,4,5
With, its difference is:
A kind of Memorability nylon rubber-plastics material, was made up of forming of following percentage by weight:
Wherein, described modification of nylon is made up of the component of following percentage by weight:
Described maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer
Middle maleic anhydride grafting ratio is 1.6%；Described antioxidant is antioxidant 1098；Described lubricant is calcium stearate；Described
Filler be calcium carbonate；Described catalyst is organotin；Described initiator is 2,2-pair-(tert-butyl peroxide) third
Alkane；Containing vinyl 0.35% in described end-vinyl phenyl silicone oil；Described polyethers is PTMG；Described
Aromatic diacid is terephthalic acids；Described chain extender is double (2-oxazoline).
A kind of above-mentioned Memorability nylon rubber-plastics material and preparation method thereof, its difference exists
In: whipping temp is 90 DEG C；Mixing extrusion temperature is 180 DEG C；Cooling water temperature is 5 DEG C.
The Memorability nylon rubber-plastics material that the present invention provides, the polyamide using end-vinyl phenyl silicone oil modification of nylon is hard
Section, is soft section with polyethers section, and chain extender increases molecular weight, and the modification of nylon obtained has the characteristic of plastics and rubber, had
The nylon rubber-plastics material of standby shape memory, and enhance the low-temperature flexibility of nylon, resistance to oxidation weatherability, thermostability and fire-retardant
Property etc. combination property, simultaneously with the toughness of maleic anhydride graft copolymer further toughening modifying nylon, add other auxiliary agents, enter
One step improves recovery of shape memory effect and the comprehensive mechanical performance of nylon rubber-plastics material.
Prepare Memorability wire rod with nylon rubber-plastics material prepared by the present invention for raw material and other materials are compound, can improve
The Memorability of wire rod, overcomes common nylon or its poor flexibility of plastic material, the problem of recovery of shape difference, the note that the present invention provides
The preparation method of the property recalled nylon rubber-plastics material, rational technology, easy to process, be prone to industrialization, can be widely applied to needs and possess
The various product manufacturing of shape memory function.
The present invention is not limited to above-mentioned embodiment, uses or the raw material of approximation identical with the above embodiment of the present invention and system
Preparation Method, and other the similar Memorability nylon rubber-plastics materials obtained, all within protection scope of the present invention.
Claims (9)
1. a Memorability nylon rubber-plastics material, it is characterised in that be made up of forming of following percentage by weight:
Wherein, described modification of nylon is made up of the component of following percentage by weight:
Memorability nylon rubber-plastics material the most according to claim 1, is characterised by, described maleic anhydride grafted ethene-
In acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer, maleic anhydride grafting ratio is 1.6%.
Memorability nylon rubber-plastics material the most according to claim 1, is characterised by, described antioxidant is antioxidant 1010
Or 1098；Described lubricant is calcium stearate；Described filler is the one in calcium carbonate, silicon dioxide, white carbon black or several
Kind；Described catalyst is one or more in triphenyl phosphite, organotin；Described initiator is 2,2-pair-(peroxide
Change the tert-butyl group) propane.
Memorability nylon rubber-plastics material the most according to claim 1, is characterised by, in described end-vinyl phenyl silicone oil
Containing vinyl 0.15-0.45%.
Memorability nylon rubber-plastics material the most according to claim 1, is characterised by, described polyethers is PTMG
One or more in glycol, polytrimethylene ether glycol.
Memorability nylon rubber-plastics material the most according to claim 1, is characterised by, described aromatic diacid is isophthalic two
Acid, one or both in terephthalic acids.
Memorability nylon rubber-plastics material the most according to claim 1, is characterised by, described chain extender is double (2-azoles
Quinoline).
8. the preparation method of the Memorability nylon rubber-plastics material that one of claim 1-7 is described, it is characterised in that include as
Lower step:
(1) modification of nylon is prepared:
Caprolactam 40%, end-vinyl phenyl silicone oil, initiator are added in reactor in setting ratio, 60 DEG C,
0.02MPa evacuation is dehydrated, and carries out additive reaction 1.5 hours in 100 DEG C, will residue caprolactam, antioxidant, aromatic series two
Acid, adds in reactor, is warmed up to 240 DEG C, starts stirring after material melting, reacts 2h, is cooled to 180 DEG C, takes out at 0.06MPa
Vacuum polycondensation 1h, after without obvious distillation, continues evacuation 0.5h；At N2Under protection, by polyethers, catalyst in setting ratio
Add in reactor, be heated to 240 DEG C, react 2h, evacuation 0.04MPa, react 1h, add chain extender, react 1h, evacuation
0.04MPa, after without obvious distillation, discharging；
(2) modification of nylon that step (1) prepared, maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride connect
Branch SB, antioxidant, lubricant, filler put in homogenizer in setting ratio, with 1500
Rev/min, stir 20 minutes under conditions of whipping temp 80 DEG C-100 DEG C after, the mixture in reactor is poured into twin screw and pelletizes
In machine, mixing rear extrusion at 160-180 DEG C；
(3) by extrudate with 5-10 DEG C of circulating water, air-drying, pelletizing is packed.
The preparation method of Memorability nylon rubber-plastics material the most according to claim 8, it is characterised in that described maleic acid
In acid anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride graft phenylethene-butadiene copolymer, maleic anhydride grafting ratio is
1.6%；Described antioxidant is antioxidant 1010 or 1098；Described lubricant is calcium stearate；Described filler is carbon
One or more in acid calcium, silicon dioxide, white carbon black；Described catalyst be the one in triphenyl phosphite, organotin or
Several；Described initiator is 2,2-pair-(tert-butyl peroxide) propane；Containing vinyl in described end-vinyl phenyl silicone oil
0.15-0.45%；Described polyethers is one or more in PTMG, polytrimethylene ether glycol；Institute
The aromatic diacid stated is one or both in isophthalic acid, terephthalic acids；Described chain extender is double (2-oxazoline).
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| CN104497570A (en) * | 2014-12-17 | 2015-04-08 | 江门市优巨新材料有限公司 | High-temperature-resistant halogen-free flame-retardant nylon composite material and preparation method thereof |
| CN109830335A (en) * | 2019-03-29 | 2019-05-31 | 安徽徽宁电器仪表集团有限公司 | A kind of tensile type shielded cable |
| CN113789052B (en) * | 2021-11-15 | 2022-03-08 | 富海(东营)新材料科技有限公司 | Shape memory nylon material and preparation method thereof |
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| US3470139A (en) * | 1965-01-14 | 1969-09-30 | Courtaulds Ltd | Polymerization of caprolactam in the presence of catalyst,initiator and a crystallization modifier |
| US10376461B2 (en) * | 2011-07-21 | 2019-08-13 | Croda International Plc | Branched polyether-polyamide block copolymers and methods of making and using the same |
| CN102634191A (en) * | 2012-05-15 | 2012-08-15 | 金发科技股份有限公司 | Permanent antistatic nylon elastomer material and preparation method thereof |
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