CN107033395A - A kind of plasticine and preparation method and sand table can be recycled using the plasticine - Google Patents

A kind of plasticine and preparation method and sand table can be recycled using the plasticine Download PDF

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CN107033395A
CN107033395A CN201710412361.0A CN201710412361A CN107033395A CN 107033395 A CN107033395 A CN 107033395A CN 201710412361 A CN201710412361 A CN 201710412361A CN 107033395 A CN107033395 A CN 107033395A
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plasticine
parts
model
chassis
banbury
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CN107033395B (en
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戚久琳
赵振华
杨怀靓
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Henan Mechanical and Electrical Engineering College
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Henan Mechanical and Electrical Engineering College
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L5/00Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L5/00Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
    • C08L5/02Dextran; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/324Alkali metal phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
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Abstract

Sand table can be recycled the invention belongs to a kind of plasticine and preparation method and using the plasticine;The plasticine chassis being made including plasticine and plasticine model, fixed nail is provided between the plasticine chassis and plasticine model, the bottom on the plasticine chassis is provided with glass base, the surrounding of the glass base is respectively equipped with glass plate, the two ends of the fixed nail are taper, its one end is located at the internal upper part on plasticine chassis, the other end is located at the interior bottom of plasticine model, and the plasticine model includes plasticine artificial hillock model, plasticine river model, plasticine pavement model, plasticine building model and plasticine road model;Have the advantages that it is reasonable in design, easy to use and it is convenient recycle, and its model is based on plasticine, and the high and soft plasticity of viscosity is good, has the advantages that to be unlikely to deform, hardens and shrinkage factor is low, it is adaptable to which sand table makes displaying.

Description

A kind of plasticine and preparation method and sand table can be recycled using the plasticine
Technical field
The invention belongs to environment design technical field, and in particular to a kind of plasticine and preparation method and use the plasticine Sand table can be recycled.
Background technology
Sand table, is exactly the relation according to a certain percentage according to topographic map, airphoto or landform on the spot, with silt, war game and The model of other materials composting.The a certain region of understanding or building, the resemblance of groups of building that so people can just will be apparent that.
Existing sand table is divided into Simple sand table and permanent sand table.Simple sand table, is faced with silt and war game ground on the scene When composting, its order is:Prepare on figure, determining the horizontal scale and vertical scale of sand table, (generally horizontal engineer's scale is small In vertical scale), sand table size is calculated, composting landforms set atural object and military condition.Wherein it is mainly composting landforms, side Method is:Select minimum contour and relevant Topographic Feature Point, and rendition is on Shamian Island from topographic map by its position, by vertically comparing Example chi calculates the sign inserting height on mountain top, saddle, the foot of the hill etc., and control topographic map carries out composting.Permanent sand table, typically uses foam The material such as plastic plate or glued board, land plaster, paper pulp makes, and its method and composting Simple sand table are essentially identical, but modeling landforms processed, Amplify base map, the system of engraving and edge nail contour plate, heap modeling filler and cover with paint, lacquer, colour wash, etc. earth's surface color.
But although two kinds of above-mentioned sand tables have the advantages that simple in construction or precision is high, show image, it makes With rear, all can not cycling and reutilization, cause the problems such as manufacturing cost of sand table is high.
The content of the invention
The purpose of the present invention, which is that, provides its a kind of model in order to solve the above problems based on plasticine, and viscosity is high It is good with soft plasticity, with being unlikely to deform, harden and low, the easy to use and convenient plasticine recycled of shrinkage factor and system Preparation Method and sand table can be recycled using the plasticine.
The present invention is achieved through the following technical solutions above-mentioned purpose:
(1) a kind of plasticine, the raw material that the plasticine includes following parts by weight is made:20-28 parts of xanthans, the third three 11-15 parts of alcohol, 20-24 parts of Arabic gum, 9-13 parts of sodium tripolyphosphate, 10-14 parts of isopropanol, 5-9 parts of titanium dioxide, konjaku flour 20-28 parts, it is 6-10 parts of clay, 11-13 parts of atoleine, 3-5 parts of palm oil, 2-4 parts of acetyl chitin, 3-5 parts of silicone oil, organic 30-36 parts of 4-6 parts of silicon quaternary ammonium salt, 4-6 parts of sodium citrate and deionized water.
(2) a kind of plasticine, the raw material that the plasticine includes following parts by weight is made:28 parts of xanthans, glycerine 11 Part, 22 parts of Arabic gum, 10 parts of sodium tripolyphosphate, 11 parts of isopropanol, 9 parts of titanium dioxide, 28 parts of konjaku flour, 8 parts of clay, liquid stone 11 parts of wax, 5 parts of palm oil, 4 parts of acetyl chitin, 3 parts of silicone oil, 4.5 parts of organosilicon quaternary ammonium salt, 4 parts of sodium citrate and deionization 32 parts of water.
(3) a kind of plasticine, the raw material that the plasticine includes following parts by weight is made:25 parts of xanthans, glycerine 13 Part, 24 parts of Arabic gum, 13 parts of sodium tripolyphosphate, 14 parts of isopropanol, 5 parts of titanium dioxide, 20 parts of konjaku flour, 10 parts of clay, liquid 13 parts of paraffin, 4.5 parts of palm oil, 3 parts of acetyl chitin, 5 parts of silicone oil, 6 parts of organosilicon quaternary ammonium salt, 6 parts of sodium citrate and go from Sub- 35 parts of water.
(4) a kind of plasticine, the raw material that the plasticine includes following parts by weight is made:21 parts of xanthans, glycerine 14 Part, 21 parts of Arabic gum, 12 parts of sodium tripolyphosphate, 13 parts of isopropanol, 8 parts of titanium dioxide, 21 parts of konjaku flour, 7 parts of clay, liquid stone 11.5 parts of wax, 3 parts of palm oil, 2 parts of acetyl chitin, 4 parts of silicone oil, 5 parts of organosilicon quaternary ammonium salt, 5 parts of sodium citrate and deionization 34 parts of water.
A kind of preparation method of plasticine, comprises the following steps:
1) remove in ionized water injection banbury, heated 10 minutes by banbury so that deionized water is warming up to 70 DEG C, Then xanthans and Arabic gum are taken and is mixed while being added in banbury with the deionized water after heating, and start banbury with 30r/pm rotating speed rotation so that xanthans and carragheen are dissolved in deionized water, is made gel solution, standby;
2) sodium tripolyphosphate, konjaku flour, clay and titanium dioxide are taken and is mixed, mixed fillers are obtained, then will mixing Filler is ground 2 times repeatedly with grinder so that then filling material grinding enters powdered filler by the screen cloth of 50 mesh into powder Row sub-sieve, collects the powder below 50 mesh, standby;
3) by step 2) made from powder mixed fillers be put into mixer, then by with the weight of powder mixed fillers ratio 1: 2 addition water, while starting mixer, is mixed powder mixed fillers with water with 60r/pm rotating speed, and slurries are made, standby;
4) by step 3) made from slurries be added to step 1) made from gel solution, and be again started up banbury and add Heat carries out Stirring to 70 DEG C, and with 50r/pm rotating speed so that slurries are well mixed with gel solution, while taking the third three Alcohol, isopropanol, atoleine, palm oil, acetyl chitin, silicone oil, organosilicon quaternary ammonium salt and sodium citrate are added to banbury It is interior to be mixed in the lump with slurries and gel solution, plasticine raw material is made, it is standby;
5) by step 4) made from plasticine raw material take out, and send into dryer and to heat 10 points with 50 DEG C of temperature Clock, will obtain the high plasticine of viscosity, then by the plasticine after dewater treatment after 80% moisture removal in plasticine raw material It is sent in kneading machine, is rubbed repeatedly by kneading machine 20 minutes so that the bubble removal in plasticine, obtains the rubber of bubble-free Mud, it is standby;
6) by step 5) made from bubble-free plasticine by making into plasticine model of different shapes by hand, produce.
It is a kind of that sand table can be recycled using the plasticine, any one rubber including the use of above-mentioned (one)-(four) Plasticine chassis and plasticine model that skin mud is made, fixed nail is provided between the plasticine chassis and plasticine model, The bottom on the plasticine chassis is provided with glass base, and the surrounding of the glass base is respectively equipped with glass plate, the fixed nail Two ends be taper, its one end is located at the internal upper part on plasticine chassis, and the other end is located at the interior bottom of plasticine model, the rubber Skin mud mould type includes plasticine artificial hillock model, plasticine river model, plasticine pavement model, plasticine building model and rubber Skin mud road model.
Preferably, the plasticine artificial hillock model, plasticine river model, plasticine pavement model plasticine building mould The bottom of type and plasticine road model is connected by respective fixed nail with plasticine chassis respectively.
Preferably, tack coat is provided between the glass base and glass plate.
The technology of the present invention effect major embodiment is in the following areas:The plasticine chassis made by plasticine and rubber mud mould Type, can make sand table quick and easy, and facilitate it to recycle, because plasticine is by xanthans, glycerine, Arab It is glue, sodium tripolyphosphate, isopropanol, titanium dioxide, konjaku flour, clay, atoleine, palm oil, acetyl chitin, silicone oil, organic Silicon quaternary ammonium salt, sodium citrate and deionized water are made, and the high and soft plasticity of its viscosity is good, with being unlikely to deform, harden and receive The low advantage of shrinkage, it is adaptable to which sand table makes displaying, and cyclic process can be reclaimed after displaying be re-used for sand table making.
Brief description of the drawings
Fig. 1 is the structural representation of structure of the present invention.
Embodiment
In order to which technical characteristic, purpose and effect to the present invention are more clearly understood from, now control illustrates this hair Bright embodiment, in the various figures identical label represent identical part.It is only schematic in simplified form, each figure to make Ground indicates the part related to invention, and they do not represent it as the practical structures of product.
The present invention is a kind of plasticine and preparation method and the sand table that can be recycled using the plasticine, wherein plasticine Including:
(1) a kind of plasticine, the raw material that the plasticine includes following parts by weight is made:20-28 parts of xanthans, the third three 11-15 parts of alcohol, 20-24 parts of Arabic gum, 9-13 parts of sodium tripolyphosphate, 10-14 parts of isopropanol, 5-9 parts of titanium dioxide, konjaku flour 20-28 parts, it is 6-10 parts of clay, 11-13 parts of atoleine, 3-5 parts of palm oil, 2-4 parts of acetyl chitin, 3-5 parts of silicone oil, organic 30-36 parts of 4-6 parts of silicon quaternary ammonium salt, 4-6 parts of sodium citrate and deionized water.
(2) a kind of plasticine, the raw material that the plasticine includes following parts by weight is made:28 parts of xanthans, glycerine 11 Part, 22 parts of Arabic gum, 10 parts of sodium tripolyphosphate, 11 parts of isopropanol, 9 parts of titanium dioxide, 28 parts of konjaku flour, 8 parts of clay, liquid stone 11 parts of wax, 5 parts of palm oil, 4 parts of acetyl chitin, 3 parts of silicone oil, 4.5 parts of organosilicon quaternary ammonium salt, 4 parts of sodium citrate and deionization 32 parts of water.
(3) a kind of plasticine, the raw material that the plasticine includes following parts by weight is made:25 parts of xanthans, glycerine 13 Part, 24 parts of Arabic gum, 13 parts of sodium tripolyphosphate, 14 parts of isopropanol, 5 parts of titanium dioxide, 20 parts of konjaku flour, 10 parts of clay, liquid 13 parts of paraffin, 4.5 parts of palm oil, 3 parts of acetyl chitin, 5 parts of silicone oil, 6 parts of organosilicon quaternary ammonium salt, 6 parts of sodium citrate and go from Sub- 35 parts of water.
(4) a kind of plasticine, the raw material that the plasticine includes following parts by weight is made:21 parts of xanthans, glycerine 14 Part, 21 parts of Arabic gum, 12 parts of sodium tripolyphosphate, 13 parts of isopropanol, 8 parts of titanium dioxide, 21 parts of konjaku flour, 7 parts of clay, liquid stone 11.5 parts of wax, 3 parts of palm oil, 2 parts of acetyl chitin, 4 parts of silicone oil, 5 parts of organosilicon quaternary ammonium salt, 5 parts of sodium citrate and deionization 34 parts of water.
A kind of preparation method of plasticine, comprises the following steps:
1) remove in ionized water injection banbury, heated 10 minutes by banbury so that deionized water is warming up to 70 DEG C, Then xanthans and Arabic gum are taken and is mixed while being added in banbury with the deionized water after heating, and start banbury with 30r/pm rotating speed rotation so that xanthans and carragheen are dissolved in deionized water, is made gel solution, standby;
2) sodium tripolyphosphate, konjaku flour, clay and titanium dioxide are taken and is mixed, mixed fillers are obtained, then will mixing Filler is ground 2 times repeatedly with grinder so that then filling material grinding enters powdered filler by the screen cloth of 50 mesh into powder Row sub-sieve, collects the powder below 50 mesh, standby;
3) by step 2) made from powder mixed fillers be put into mixer, then by with the weight of powder mixed fillers ratio 1: 2 addition water, while starting mixer, is mixed powder mixed fillers with water with 60r/pm rotating speed, and slurries are made, standby;
4) by step 3) made from slurries be added to step 1) made from gel solution, and be again started up banbury and add Heat carries out Stirring to 70 DEG C, and with 50r/pm rotating speed so that slurries are well mixed with gel solution, while taking the third three Alcohol, isopropanol, atoleine, palm oil, acetyl chitin, silicone oil, organosilicon quaternary ammonium salt and sodium citrate are added to banbury It is interior to be mixed in the lump with slurries and gel solution, plasticine raw material is made, it is standby;
5) by step 4) made from plasticine raw material take out, and send into dryer and to heat 10 points with 50 DEG C of temperature Clock, will obtain the high plasticine of viscosity, then by the plasticine after dewater treatment after 80% moisture removal in plasticine raw material It is sent in kneading machine, is rubbed repeatedly by kneading machine 20 minutes so that the bubble removal in plasticine, obtains the rubber of bubble-free Mud, it is standby;
6) by step 5) made from bubble-free plasticine by making into plasticine model of different shapes by hand, produce.
As shown in figure 1, a kind of can be recycled sand table using the plasticine, including the use of appointing for above-mentioned (one)-(four) Plasticine chassis 2 and plasticine model that one plasticine is made, set between the plasticine chassis 2 and plasticine model Fixed nail 3 is equipped with, the bottom on the plasticine chassis 2 is provided with glass base 1, and the surrounding of the glass base 1 is respectively equipped with glass Glass plate 11, the two ends of the fixed nail 3 are taper, and its one end is located at the internal upper part on plasticine chassis 2, and the other end is located at plasticine The interior bottom of model, the plasticine model includes plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement Model 23, plasticine building model 24 and plasticine road model 25.The plasticine artificial hillock model 21, plasticine river model 22nd, the bottom of plasticine pavement model 23, plasticine building model 24 and plasticine road model 25 is respectively by respective Fixed nail 3 is connected with plasticine chassis 2.Tack coat 12 is provided between the glass base 1 and glass plate 11.
In order to more clearly explain the present invention, it is further described in conjunction with specific embodiment.It is specific real Under applying for example:
Embodiment one
A kind of plasticine, the raw material that the plasticine includes following parts by weight is made:20 parts of xanthans, 11 parts of glycerine, 20 parts of Arabic gum, 9 parts of sodium tripolyphosphate, 10 parts of isopropanol, 5 parts of titanium dioxide, 20 parts of konjaku flour, 6 parts of clay, atoleine 11 Part, 3 parts of palm oil, 2 parts of acetyl chitin, 3 parts of silicone oil, 4 parts of organosilicon quaternary ammonium salt, 4 parts of sodium citrate and deionized water 30.
A kind of preparation method of plasticine, comprises the following steps:
1) remove in ionized water injection banbury, heated 10 minutes by banbury so that deionized water is warming up to 70 DEG C, Then xanthans and Arabic gum are taken and is mixed while being added in banbury with the deionized water after heating, and start banbury with 30r/pm rotating speed rotation so that xanthans and carragheen are dissolved in deionized water, is made gel solution, standby;
2) sodium tripolyphosphate, konjaku flour, clay and titanium dioxide are taken and is mixed, mixed fillers are obtained, then will mixing Filler is ground 2 times repeatedly with grinder so that then filling material grinding enters powdered filler by the screen cloth of 50 mesh into powder Row sub-sieve, collects the powder below 50 mesh, standby;
3) by step 2) made from powder mixed fillers be put into mixer, then by with the weight of powder mixed fillers ratio 1: 2 addition water, while starting mixer, is mixed powder mixed fillers with water with 60r/pm rotating speed, and slurries are made, standby;
4) by step 3) made from slurries be added to step 1) made from gel solution, and be again started up banbury and add Heat carries out Stirring to 70 DEG C, and with 50r/pm rotating speed so that slurries are well mixed with gel solution, while taking the third three Alcohol, isopropanol, atoleine, palm oil, acetyl chitin, silicone oil, organosilicon quaternary ammonium salt and sodium citrate are added to banbury It is interior to be mixed in the lump with slurries and gel solution, plasticine raw material is made, it is standby;
5) by step 4) made from plasticine raw material take out, and send into dryer and to heat 10 points with 50 DEG C of temperature Clock, will obtain the high plasticine of viscosity, then by the plasticine after dewater treatment after 80% moisture removal in plasticine raw material It is sent in kneading machine, is rubbed repeatedly by kneading machine 20 minutes so that the bubble removal in plasticine, obtains the rubber of bubble-free Mud, it is standby;
6) by step 5) made from bubble-free plasticine by making into plasticine model of different shapes by hand, produce.
It is a kind of that sand table can be recycled using the plasticine, the plasticine chassis 2 being made including the use of above-mentioned plasticine With plasticine model, fixed nail 3, the bottom on the plasticine chassis 2 are provided between the plasticine chassis 2 and plasticine model Portion is provided with glass base 1, and the surrounding of the glass base 1 is respectively equipped with glass plate 11, and the two ends of the fixed nail 3 are taper, Its one end is located at the internal upper part on plasticine chassis 2, and the other end is located at the interior bottom of plasticine model, and the plasticine model includes Plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building model 24 and plasticine Road model 25.The plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building The bottom of disk model 24 and plasticine road model 25 is connected by respective fixed nail 3 with plasticine chassis 2 respectively.The glass Tack coat 12 is provided between glass base 1 and glass plate 11.
Embodiment two
A kind of plasticine, the raw material that the plasticine includes following parts by weight is made:28 parts of xanthans, 15 parts of glycerine, 24 parts of Arabic gum, 13 parts of sodium tripolyphosphate, 14 parts of isopropanol, 9 parts of titanium dioxide, 28 parts of konjaku flour, 10 parts of clay, atoleine 13 parts, 5 parts of palm oil, 4 parts of acetyl chitin, 5 parts of silicone oil, 6 parts of organosilicon quaternary ammonium salt, 6 parts of sodium citrate and deionized water 36 Part.
A kind of preparation method of plasticine, comprises the following steps:
1) remove in ionized water injection banbury, heated 10 minutes by banbury so that deionized water is warming up to 70 DEG C, Then xanthans and Arabic gum are taken and is mixed while being added in banbury with the deionized water after heating, and start banbury with 30r/pm rotating speed rotation so that xanthans and carragheen are dissolved in deionized water, is made gel solution, standby;
2) sodium tripolyphosphate, konjaku flour, clay and titanium dioxide are taken and is mixed, mixed fillers are obtained, then will mixing Filler is ground 2 times repeatedly with grinder so that then filling material grinding enters powdered filler by the screen cloth of 50 mesh into powder Row sub-sieve, collects the powder below 50 mesh, standby;
3) by step 2) made from powder mixed fillers be put into mixer, then by with the weight of powder mixed fillers ratio 1: 2 addition water, while starting mixer, is mixed powder mixed fillers with water with 60r/pm rotating speed, and slurries are made, standby;
4) by step 3) made from slurries be added to step 1) made from gel solution, and be again started up banbury and add Heat carries out Stirring to 70 DEG C, and with 50r/pm rotating speed so that slurries are well mixed with gel solution, while taking the third three Alcohol, isopropanol, atoleine, palm oil, acetyl chitin, silicone oil, organosilicon quaternary ammonium salt and sodium citrate are added to banbury It is interior to be mixed in the lump with slurries and gel solution, plasticine raw material is made, it is standby;
5) by step 4) made from plasticine raw material take out, and send into dryer and to heat 10 points with 50 DEG C of temperature Clock, will obtain the high plasticine of viscosity, then by the plasticine after dewater treatment after 80% moisture removal in plasticine raw material It is sent in kneading machine, is rubbed repeatedly by kneading machine 20 minutes so that the bubble removal in plasticine, obtains the rubber of bubble-free Mud, it is standby;
6) by step 5) made from bubble-free plasticine by making into plasticine model of different shapes by hand, produce.
It is a kind of that sand table can be recycled using the plasticine, the plasticine chassis 2 being made including the use of above-mentioned plasticine With plasticine model, fixed nail 3, the bottom on the plasticine chassis 2 are provided between the plasticine chassis 2 and plasticine model Portion is provided with glass base 1, and the surrounding of the glass base 1 is respectively equipped with glass plate 11, and the two ends of the fixed nail 3 are taper, Its one end is located at the internal upper part on plasticine chassis 2, and the other end is located at the interior bottom of plasticine model, and the plasticine model includes Plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building model 24 and plasticine Road model 25.The plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building The bottom of disk model 24 and plasticine road model 25 is connected by respective fixed nail 3 with plasticine chassis 2 respectively.The glass Tack coat 12 is provided between glass base 1 and glass plate 11.
Embodiment three
A kind of plasticine, the raw material that the plasticine includes following parts by weight is made:24 parts of xanthans, 13 parts of glycerine, 22 parts of Arabic gum, 11 parts of sodium tripolyphosphate, 12 parts of isopropanol, 7 parts of titanium dioxide, 24 parts of konjaku flour, 8 parts of clay, atoleine 12 parts, 4 parts of palm oil, 3 parts of acetyl chitin, 4 parts of silicone oil, 5 parts of organosilicon quaternary ammonium salt, 5 parts of sodium citrate and deionized water 33 Part.
A kind of preparation method of plasticine, comprises the following steps:
1) remove in ionized water injection banbury, heated 10 minutes by banbury so that deionized water is warming up to 70 DEG C, Then xanthans and Arabic gum are taken and is mixed while being added in banbury with the deionized water after heating, and start banbury with 30r/pm rotating speed rotation so that xanthans and carragheen are dissolved in deionized water, is made gel solution, standby;
2) sodium tripolyphosphate, konjaku flour, clay and titanium dioxide are taken and is mixed, mixed fillers are obtained, then will mixing Filler is ground 2 times repeatedly with grinder so that then filling material grinding enters powdered filler by the screen cloth of 50 mesh into powder Row sub-sieve, collects the powder below 50 mesh, standby;
3) by step 2) made from powder mixed fillers be put into mixer, then by with the weight of powder mixed fillers ratio 1: 2 addition water, while starting mixer, is mixed powder mixed fillers with water with 60r/pm rotating speed, and slurries are made, standby;
4) by step 3) made from slurries be added to step 1) made from gel solution, and be again started up banbury and add Heat carries out Stirring to 70 DEG C, and with 50r/pm rotating speed so that slurries are well mixed with gel solution, while taking the third three Alcohol, isopropanol, atoleine, palm oil, acetyl chitin, silicone oil, organosilicon quaternary ammonium salt and sodium citrate are added to banbury It is interior to be mixed in the lump with slurries and gel solution, plasticine raw material is made, it is standby;
5) by step 4) made from plasticine raw material take out, and send into dryer and to heat 10 points with 50 DEG C of temperature Clock, will obtain the high plasticine of viscosity, then by the plasticine after dewater treatment after 80% moisture removal in plasticine raw material It is sent in kneading machine, is rubbed repeatedly by kneading machine 20 minutes so that the bubble removal in plasticine, obtains the rubber of bubble-free Mud, it is standby;
6) by step 5) made from bubble-free plasticine by making into plasticine model of different shapes by hand, produce.
It is a kind of that sand table can be recycled using the plasticine, the plasticine chassis 2 being made including the use of above-mentioned plasticine With plasticine model, fixed nail 3, the bottom on the plasticine chassis 2 are provided between the plasticine chassis 2 and plasticine model Portion is provided with glass base 1, and the surrounding of the glass base 1 is respectively equipped with glass plate 11, and the two ends of the fixed nail 3 are taper, Its one end is located at the internal upper part on plasticine chassis 2, and the other end is located at the interior bottom of plasticine model, and the plasticine model includes Plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building model 24 and plasticine Road model 25.The plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building The bottom of disk model 24 and plasticine road model 25 is connected by respective fixed nail 3 with plasticine chassis 2 respectively.The glass Tack coat 12 is provided between glass base 1 and glass plate 11.
Example IV
A kind of plasticine, the raw material that the plasticine includes following parts by weight is made:28 parts of xanthans, 11 parts of glycerine, 22 parts of Arabic gum, 10 parts of sodium tripolyphosphate, 11 parts of isopropanol, 9 parts of titanium dioxide, 28 parts of konjaku flour, 8 parts of clay, atoleine 11 parts, 5 parts of palm oil, 4 parts of acetyl chitin, 3 parts of silicone oil, 4.5 parts of organosilicon quaternary ammonium salt, 4 parts of sodium citrate and deionized water 32 parts.
A kind of preparation method of plasticine, comprises the following steps:
1) remove in ionized water injection banbury, heated 10 minutes by banbury so that deionized water is warming up to 70 DEG C, Then xanthans and Arabic gum are taken and is mixed while being added in banbury with the deionized water after heating, and start banbury with 30r/pm rotating speed rotation so that xanthans and carragheen are dissolved in deionized water, is made gel solution, standby;
2) sodium tripolyphosphate, konjaku flour, clay and titanium dioxide are taken and is mixed, mixed fillers are obtained, then will mixing Filler is ground 2 times repeatedly with grinder so that then filling material grinding enters powdered filler by the screen cloth of 50 mesh into powder Row sub-sieve, collects the powder below 50 mesh, standby;
3) by step 2) made from powder mixed fillers be put into mixer, then by with the weight of powder mixed fillers ratio 1: 2 addition water, while starting mixer, is mixed powder mixed fillers with water with 60r/pm rotating speed, and slurries are made, standby;
4) by step 3) made from slurries be added to step 1) made from gel solution, and be again started up banbury and add Heat carries out Stirring to 70 DEG C, and with 50r/pm rotating speed so that slurries are well mixed with gel solution, while taking the third three Alcohol, isopropanol, atoleine, palm oil, acetyl chitin, silicone oil, organosilicon quaternary ammonium salt and sodium citrate are added to banbury It is interior to be mixed in the lump with slurries and gel solution, plasticine raw material is made, it is standby;
5) by step 4) made from plasticine raw material take out, and send into dryer and to heat 10 points with 50 DEG C of temperature Clock, will obtain the high plasticine of viscosity, then by the plasticine after dewater treatment after 80% moisture removal in plasticine raw material It is sent in kneading machine, is rubbed repeatedly by kneading machine 20 minutes so that the bubble removal in plasticine, obtains the rubber of bubble-free Mud, it is standby;
6) by step 5) made from bubble-free plasticine by making into plasticine model of different shapes by hand, produce.
It is a kind of that sand table can be recycled using the plasticine, the plasticine chassis 2 being made including the use of above-mentioned plasticine With plasticine model, fixed nail 3, the bottom on the plasticine chassis 2 are provided between the plasticine chassis 2 and plasticine model Portion is provided with glass base 1, and the surrounding of the glass base 1 is respectively equipped with glass plate 11, and the two ends of the fixed nail 3 are taper, Its one end is located at the internal upper part on plasticine chassis 2, and the other end is located at the interior bottom of plasticine model, and the plasticine model includes Plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building model 24 and plasticine Road model 25.The plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building The bottom of disk model 24 and plasticine road model 25 is connected by respective fixed nail 3 with plasticine chassis 2 respectively.The glass Tack coat 12 is provided between glass base 1 and glass plate 11.
Embodiment five
A kind of plasticine, the raw material that the plasticine includes following parts by weight is made:25 parts of xanthans, 13 parts of glycerine, 24 parts of Arabic gum, 13 parts of sodium tripolyphosphate, 14 parts of isopropanol, 5 parts of titanium dioxide, 20 parts of konjaku flour, 10 parts of clay, atoleine 13 parts, 4.5 parts of palm oil, 3 parts of acetyl chitin, 5 parts of silicone oil, 6 parts of organosilicon quaternary ammonium salt, 6 parts of sodium citrate and deionized water 35 parts.
A kind of preparation method of plasticine, comprises the following steps:
1) remove in ionized water injection banbury, heated 10 minutes by banbury so that deionized water is warming up to 70 DEG C, Then xanthans and Arabic gum are taken and is mixed while being added in banbury with the deionized water after heating, and start banbury with 30r/pm rotating speed rotation so that xanthans and carragheen are dissolved in deionized water, is made gel solution, standby;
2) sodium tripolyphosphate, konjaku flour, clay and titanium dioxide are taken and is mixed, mixed fillers are obtained, then will mixing Filler is ground 2 times repeatedly with grinder so that then filling material grinding enters powdered filler by the screen cloth of 50 mesh into powder Row sub-sieve, collects the powder below 50 mesh, standby;
3) by step 2) made from powder mixed fillers be put into mixer, then by with the weight of powder mixed fillers ratio 1: 2 addition water, while starting mixer, is mixed powder mixed fillers with water with 60r/pm rotating speed, and slurries are made, standby;
4) by step 3) made from slurries be added to step 1) made from gel solution, and be again started up banbury and add Heat carries out Stirring to 70 DEG C, and with 50r/pm rotating speed so that slurries are well mixed with gel solution, while taking the third three Alcohol, isopropanol, atoleine, palm oil, acetyl chitin, silicone oil, organosilicon quaternary ammonium salt and sodium citrate are added to banbury It is interior to be mixed in the lump with slurries and gel solution, plasticine raw material is made, it is standby;
5) by step 4) made from plasticine raw material take out, and send into dryer and to heat 10 points with 50 DEG C of temperature Clock, will obtain the high plasticine of viscosity, then by the plasticine after dewater treatment after 80% moisture removal in plasticine raw material It is sent in kneading machine, is rubbed repeatedly by kneading machine 20 minutes so that the bubble removal in plasticine, obtains the rubber of bubble-free Mud, it is standby;
6) by step 5) made from bubble-free plasticine by making into plasticine model of different shapes by hand, produce.
It is a kind of that sand table can be recycled using the plasticine, the plasticine chassis 2 being made including the use of above-mentioned plasticine With plasticine model, fixed nail 3, the bottom on the plasticine chassis 2 are provided between the plasticine chassis 2 and plasticine model Portion is provided with glass base 1, and the surrounding of the glass base 1 is respectively equipped with glass plate 11, and the two ends of the fixed nail 3 are taper, Its one end is located at the internal upper part on plasticine chassis 2, and the other end is located at the interior bottom of plasticine model, and the plasticine model includes Plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building model 24 and plasticine Road model 25.The plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building The bottom of disk model 24 and plasticine road model 25 is connected by respective fixed nail 3 with plasticine chassis 2 respectively.The glass Tack coat 12 is provided between glass base 1 and glass plate 11.
Embodiment six
A kind of plasticine, the raw material that the plasticine includes following parts by weight is made:21 parts of xanthans, 14 parts of glycerine, 21 parts of Arabic gum, 12 parts of sodium tripolyphosphate, 13 parts of isopropanol, 8 parts of titanium dioxide, 21 parts of konjaku flour, 7 parts of clay, atoleine 11.5 parts, 3 parts of palm oil, 2 parts of acetyl chitin, 4 parts of silicone oil, 5 parts of organosilicon quaternary ammonium salt, 5 parts of sodium citrate and deionized water 34 parts.
A kind of preparation method of plasticine, comprises the following steps:
1) remove in ionized water injection banbury, heated 10 minutes by banbury so that deionized water is warming up to 70 DEG C, Then xanthans and Arabic gum are taken and is mixed while being added in banbury with the deionized water after heating, and start banbury with 30r/pm rotating speed rotation so that xanthans and carragheen are dissolved in deionized water, is made gel solution, standby;
2) sodium tripolyphosphate, konjaku flour, clay and titanium dioxide are taken and is mixed, mixed fillers are obtained, then will mixing Filler is ground 2 times repeatedly with grinder so that then filling material grinding enters powdered filler by the screen cloth of 50 mesh into powder Row sub-sieve, collects the powder below 50 mesh, standby;
3) by step 2) made from powder mixed fillers be put into mixer, then by with the weight of powder mixed fillers ratio 1: 2 addition water, while starting mixer, is mixed powder mixed fillers with water with 60r/pm rotating speed, and slurries are made, standby;
4) by step 3) made from slurries be added to step 1) made from gel solution, and be again started up banbury and add Heat carries out Stirring to 70 DEG C, and with 50r/pm rotating speed so that slurries are well mixed with gel solution, while taking the third three Alcohol, isopropanol, atoleine, palm oil, acetyl chitin, silicone oil, organosilicon quaternary ammonium salt and sodium citrate are added to banbury It is interior to be mixed in the lump with slurries and gel solution, plasticine raw material is made, it is standby;
5) by step 4) made from plasticine raw material take out, and send into dryer and to heat 10 points with 50 DEG C of temperature Clock, will obtain the high plasticine of viscosity, then by the plasticine after dewater treatment after 80% moisture removal in plasticine raw material It is sent in kneading machine, is rubbed repeatedly by kneading machine 20 minutes so that the bubble removal in plasticine, obtains the rubber of bubble-free Mud, it is standby;
6) by step 5) made from bubble-free plasticine by making into plasticine model of different shapes by hand, produce.
It is a kind of that sand table can be recycled using the plasticine, the plasticine chassis 2 being made including the use of above-mentioned plasticine With plasticine model, fixed nail 3, the bottom on the plasticine chassis 2 are provided between the plasticine chassis 2 and plasticine model Portion is provided with glass base 1, and the surrounding of the glass base 1 is respectively equipped with glass plate 11, and the two ends of the fixed nail 3 are taper, Its one end is located at the internal upper part on plasticine chassis 2, and the other end is located at the interior bottom of plasticine model, and the plasticine model includes Plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building model 24 and plasticine Road model 25.The plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, plasticine building The bottom of disk model 24 and plasticine road model 25 is connected by respective fixed nail 3 with plasticine chassis 2 respectively.The glass Tack coat 12 is provided between glass base 1 and glass plate 11.
Experimental example
Experimental subjects:The plasticine as a control group one prepared from starch, from the standby plasticine of resin-made as right According to group two, experimental group is used as using the plasticine in the example IV in the application.
Requirement of experiment:The water content of plasticine of control group one, control group two and experimental group is limited as 20%, and is made Identical model, is placed in air, and the time is 1 day, and three groups of plasticine models is contrasted, its specific data such as following table institute Show:
By upper table as shown by data, obtained plasticine model is not only in viscosity, plasticity, deformation rate and receipts in the application It is better than control group one and control group two in shrinkage, and the plasticine of the application can be recycled after use, reach circulation The effect used, therefore, the high and soft plasticity of the plasticine viscosity of the application are good, with being unlikely to deform, harden and shrinkage factor Low advantage, it is adaptable to which sand table makes displaying, and cyclic process can be reclaimed after displaying be re-used for sand table making.
Heretofore described plasticine artificial hillock model 21, plasticine river model 22, plasticine pavement model 23, rubber Skin mud building model 24 and plasticine road model 25 and plasticine chassis 2 are made by plasticine, above-mentioned rubber mud mould Type and plasticine chassis 2 are reusable, and the reuse includes two layers of meaning:First, can be by above-mentioned plasticine model or rubber Mud chassis 2 is destroyed, and remakes new model;2nd, plasticine artificial hillock model 21, plasticine river model 22, rubber clay figurine row Road model 23, plasticine building model 24 and plasticine road model 25 and plasticine chassis 2 can be repeated as monomer respectively Used on different sand tables;Plasticine is by xanthans, glycerine, Arabic gum, sodium tripolyphosphate, isopropanol, titanium dioxide, evil spirit Taro powder, clay, atoleine, palm oil, acetyl chitin, silicone oil, organosilicon quaternary ammonium salt, sodium citrate and deionized water system It is good into the high and soft plasticity of, its viscosity, have the advantages that to be unlikely to deform, harden and shrinkage factor is low, it is adaptable to which sand table makes exhibition Show, and cyclic process can be reclaimed after displaying and be re-used for sand table making.Preferred plasticine artificial hillock model 21 in the present invention Close to the side of glass plate 11, its structure is advantageously in the making for improving sand table;Preferred plasticine bottom in the other present invention Fixed nail 3 between disk 2 and plasticine model monomer is two, and plasticine model monomer refers to that plasticine artificial hillock model 21 is single Body, the monomer of plasticine river model 22, the monomer of plasticine pavement model 23, the monomer of plasticine building model 24 and plasticine horse The monomer of road model 25.
The basic principles, principal features and advantages of the present invention have been shown and described above.The technical staff of the industry should Understand, the present invention is not limited to the above embodiments, the original for simply illustrating the present invention described in above-described embodiment and specification Reason, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes and improvements It all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by appended claims and its Xiao Wu circle It is fixed.

Claims (8)

1. a kind of plasticine, it is characterised in that:The raw material that the plasticine includes following parts by weight is made:20-28 parts of xanthans, 11-15 parts of glycerine, 20-24 parts of Arabic gum, 9-13 parts of sodium tripolyphosphate, 10-14 parts of isopropanol, 5-9 parts of titanium dioxide, konjaku 20-28 parts of powder, 6-10 parts of clay, 11-13 parts of atoleine, 3-5 parts of palm oil, 2-4 parts of acetyl chitin, 3-5 parts of silicone oil, have 30-36 parts of 4-6 parts of machine silicon quaternary ammonium salt, 4-6 parts of sodium citrate and deionized water.
2. a kind of plasticine according to claim 1, it is characterised in that:The plasticine includes the raw material of following parts by weight It is made:28 parts of xanthans, 11 parts of glycerine, 22 parts of Arabic gum, 10 parts of sodium tripolyphosphate, 11 parts of isopropanol, 9 parts of titanium dioxide, 28 parts of konjaku flour, 8 parts of clay, 11 parts of atoleine, 5 parts of palm oil, 4 parts of acetyl chitin, 3 parts of silicone oil, organosilicon quaternary ammonium salt 32 parts of 4.5 parts, 4 parts of sodium citrate and deionized water.
3. a kind of plasticine according to claim 1, it is characterised in that:The plasticine includes the raw material of following parts by weight It is made:25 parts of xanthans, 13 parts of glycerine, 24 parts of Arabic gum, 13 parts of sodium tripolyphosphate, 14 parts of isopropanol, 5 parts of titanium dioxide, 20 parts of konjaku flour, 10 parts of clay, 13 parts of atoleine, 4.5 parts of palm oil, 3 parts of acetyl chitin, 5 parts of silicone oil, organosilicone quaternary ammonium 35 parts of 6 parts of salt, 6 parts of sodium citrate and deionized water.
4. a kind of plasticine according to claim 1, it is characterised in that:The plasticine includes the raw material of following parts by weight It is made:21 parts of xanthans, 14 parts of glycerine, 21 parts of Arabic gum, 12 parts of sodium tripolyphosphate, 13 parts of isopropanol, 8 parts of titanium dioxide, 21 parts of konjaku flour, 7 parts of clay, 11.5 parts of atoleine, 3 parts of palm oil, 2 parts of acetyl chitin, 4 parts of silicone oil, organosilicone quaternary ammonium 34 parts of 5 parts of salt, 5 parts of sodium citrate and deionized water.
5. a kind of preparation method of plasticine as described in claim any one of 1-4, it is characterised in that:Comprise the following steps:
1) remove in ionized water injection banbury, heated 10 minutes by banbury so that deionized water is warming up to 70 DEG C, then Take xanthans and Arabic gum and mixed while being added in banbury with the deionized water after heating, and start banbury with 30r/ Pm rotating speed rotation so that xanthans and carragheen are dissolved in deionized water, is made gel solution, standby;
2) sodium tripolyphosphate, konjaku flour, clay and titanium dioxide are taken and is mixed, mixed fillers are obtained, then by mixed fillers Ground repeatedly with grinder 2 times so that then filling material grinding is divided powdered filler by the screen cloth of 50 mesh into powder Sieve, collects the powder below 50 mesh, standby;
3) by step 2) made from powder mixed fillers be put into mixer, then by the weight with powder mixed fillers than 1: 2 Water is added, while starting mixer, is mixed powder mixed fillers with water with 60r/pm rotating speed, slurries are made, it is standby;
4) by step 3) made from slurries be added to step 1) made from gel solution, and be again started up banbury and be heated to 70 DEG C, and Stirring is carried out with 50r/pm rotating speed so that slurries are well mixed with gel solution, at the same take glycerine, it is different Propyl alcohol, atoleine, palm oil, acetyl chitin, silicone oil, organosilicon quaternary ammonium salt and sodium citrate are added in banbury and slurry Liquid and gel solution are mixed in the lump, and plasticine raw material is made, standby;
5) by step 4) made from plasticine raw material take out, and send into dryer and to be heated 10 minutes with 50 DEG C of temperature, The high plasticine of viscosity will be obtained after 80% moisture removal in plasticine raw material, be then sent to the plasticine after dewater treatment In kneading machine, rubbed repeatedly by kneading machine 20 minutes so that the bubble removal in plasticine, obtain the plasticine of bubble-free, It is standby;
6) by step 5) made from bubble-free plasticine by making into plasticine model of different shapes by hand, produce.
6. a kind of can be recycled sand table using the plasticine, it is characterised in that:Including the use of appointing for the claims 1-4 Plasticine chassis (2) and plasticine model that one plasticine is made, the plasticine chassis (2) and plasticine model it Between be provided with fixed nail (3), the bottom of the plasticine chassis (2) is provided with glass base (1), the four of the glass base (1) Be respectively equipped with glass plate (11) week, the two ends of the fixed nail (3) are taper, its one end be located at plasticine chassis (2) it is interior on Portion, the other end is located at the interior bottom of plasticine model, and the plasticine model includes plasticine artificial hillock model (21), plasticine river Flow model (22), plasticine pavement model (23), plasticine building model (24) and plasticine road model (25).
7. a kind of sand table is can be recycled according to claim 6 using the plasticine, it is characterised in that:The rubber Mud artificial hillock model (21), plasticine river model (22), plasticine pavement model (23), plasticine building model (24) and rubber The bottom of skin mud road model (25) is connected by respective fixed follow closely (3) with plasticine chassis (2) respectively.
8. a kind of sand table is can be recycled according to claim 6 using the plasticine, it is characterised in that:The glass Tack coat (12) is provided between base (1) and glass plate (11).
CN201710412361.0A 2017-05-22 2017-05-22 A kind of plasticine and preparation method and sand table can be recycled using the plasticine Expired - Fee Related CN107033395B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108492700A (en) * 2018-04-04 2018-09-04 泸县兄弟工程造价服务有限公司 A kind of mixed type sand table for bidding for project file edit
CN108888971A (en) * 2018-08-16 2018-11-27 临沂市博士爱文具有限公司 A kind of preparation method of edible plasticine
CN108911687A (en) * 2018-07-03 2018-11-30 新乡学院 A kind of Environment Design sand table
CN113593391A (en) * 2021-07-20 2021-11-02 重庆市山之田模型设计有限公司 Method for manufacturing plastic sand table model

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Publication number Priority date Publication date Assignee Title
CN1352217A (en) * 2000-11-10 2002-06-05 刘毅 Method for making normal temperature plasticine
CN105440428A (en) * 2015-12-31 2016-03-30 苏州冰心文化用品有限公司 Light and antibacterial resin-clay composition and preparation method thereof
CN106674620A (en) * 2016-12-09 2017-05-17 陈忠燕 Environmental-friendly handwork plasticine

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1352217A (en) * 2000-11-10 2002-06-05 刘毅 Method for making normal temperature plasticine
CN105440428A (en) * 2015-12-31 2016-03-30 苏州冰心文化用品有限公司 Light and antibacterial resin-clay composition and preparation method thereof
CN106674620A (en) * 2016-12-09 2017-05-17 陈忠燕 Environmental-friendly handwork plasticine

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108492700A (en) * 2018-04-04 2018-09-04 泸县兄弟工程造价服务有限公司 A kind of mixed type sand table for bidding for project file edit
CN108911687A (en) * 2018-07-03 2018-11-30 新乡学院 A kind of Environment Design sand table
CN108888971A (en) * 2018-08-16 2018-11-27 临沂市博士爱文具有限公司 A kind of preparation method of edible plasticine
CN113593391A (en) * 2021-07-20 2021-11-02 重庆市山之田模型设计有限公司 Method for manufacturing plastic sand table model
CN113593391B (en) * 2021-07-20 2023-03-03 重庆市山之田模型设计有限公司 Method for manufacturing plastic sand table model

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