Embodiment
For the ease of understanding the present invention, shaped device is described more fully below with reference to relevant drawings.Accompanying drawing
In give the preferred embodiment of shaped device.But, shaped device can be realized in many different forms, however it is not limited to
Embodiment described herein.On the contrary, the purpose for providing these embodiments is to make the disclosure to shaped device more saturating
It is thorough comprehensive.
The term used in the various embodiments of the disclosure is only used for describing the purpose of specific embodiment and not anticipated
In the various embodiments of the limitation disclosure.As used herein, singulative is intended to also include plural form, unless context is clear
Chu it is indicated otherwise.Unless otherwise defined, all terms (including the technical term and scientific terminology) tool being otherwise used herein
There is the implication identical implication that the various embodiment one skilled in the art with the disclosure are generally understood that.The term
(term such as limited in the dictionary typically used) is to be interpreted as having and the situational meaning in correlative technology field
Identical implication and it will be not construed as with Utopian implication or excessively formal implication, unless in the various of the disclosure
It is clearly defined in embodiment.
In the description of the invention, it is to be understood that term " longitudinal direction ", " transverse direction ", " on ", " under ", "front", "rear",
The orientation or position relationship of the instruction such as "left", "right", " vertical ", " level ", " top ", " bottom ", " interior ", " outer " is based on accompanying drawing institutes
The orientation or position relationship shown, is for only for ease of the description present invention and simplifies description, rather than indicate or imply signified dress
Put or element there must be specific orientation, with specific azimuth configuration and operation, therefore it is not intended that to the limit of the present invention
System.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show
The description of example " or " some examples " etc. means to combine specific features, structure, material or the spy that the embodiment or example are described
Point is contained at least one embodiment of the present invention or example.In this manual, to the schematic representation of above-mentioned term not
Necessarily refer to identical embodiment or example.Moreover, specific features, structure, material or the feature of description can be any
One or more embodiments or example in combine in an appropriate manner.
In the description of the invention, unless otherwise prescribed with limit, it is necessary to explanation, term " installation ", " connected ",
" connection " should be interpreted broadly, for example, it may be mechanically connect or electrical connection or the connection of two element internals, can
To be to be joined directly together, it can also be indirectly connected to by intermediary, for the ordinary skill in the art, can basis
Concrete condition understands the concrete meaning of above-mentioned term.
The statement (" first ", " second " etc.) used in the various embodiments of the disclosure can be modified to be implemented various
Various element in example, but corresponding element can not be limited.For example, presented above be not intended to limit the suitable of the element
Sequence and/or importance.The purpose presented above for being only used for differentiating an element and other elements.For example, the first user fills
Put and indicate different user device with second user device, although the two is all user's set.For example, not departing from each of the disclosure
In the case of the scope for planting embodiment, the first element is referred to alternatively as the second element, similarly, and the second element is also referred to as first
Element.
It should be noted that:, can be by the first composition member if an element ' attach ' to another element by description
Part is directly connected to the second element, and " connection " the 3rd can be constituted between the first element and the second element
Element.On the contrary, when an element " being directly connected to " is arrived into another element, it will be appreciated that be in the first element
And second the 3rd element is not present between element.
In addition, the indefinite article " one kind " and " one " before key element of the present invention or component are to key element or the quantitative requirement of component
(i.e. occurrence number) unrestriction.Therefore " one " or " one kind " should be read as including one or at least one, and odd number
The key element or component of form also include plural form, unless the obvious purport of the quantity refers to singulative.
Fig. 1 is referred to Fig. 7.The hydrogen-rich hydrogenesis machine 200 of the embodiment of the present invention, including support 210 and removably pacify
Hydrogen-oxygen separating film module 100 loaded on support 210;Hydrogen-oxygen separating film module 100 includes being provided with cathode sheets in tank house, tank house
20th, anode strip 40 and the permeable trapping film 30 being arranged between cathode sheets 20 and anode strip 40, cathode sheets 20, anode strip 40 are surrounded
One electrolysis zone, permeable trapping film 30 by electrolysis zone to be separated into hydrogen-producing region and oxygen generation area.
In above-described embodiment, in hydrogen manufacturing, the hydrogen-rich that cathode sheets 20 are produced in hydrogen-producing region, what anode strip 40 was produced
Oxygen concentration produces area in oxygen, and permeable trapping film 30 has obstructed hydrogen and produced the diffusion in area to oxygen and obstructed oxygen and produced to hydrogen
The diffusion in raw area, has thus reached the separation of hydrogen and oxygen.
Term " electrolysis zone " refers to the region passed through with electric current.Term " tank house " refers to the object for implementing electrolysis.It is cloudy
Pole piece 20, anode strip 40 and permeable trapping film 30 are placed in tank house.
Above-mentioned permeable trapping film 30 refers to the film with permeable trapping function.It should be noted that trapping herein refer to every
Exist from the gas existed in the form of bubbles, rather than with molecular state.The mechanism of hydrogen produced by electrolysis water is, the hydrogen in water
Ion obtains electronics in cathode sheets 20 and occurs reduction reaction and produce gas phase, because the interface between gas phase and aqueous phase is poor, institute
It is dispersed in water with the hydrogen of production with bubble hydrogen.Using the current density of negative electrode as 2~6mA/cm2, be electrolysed at ambient pressure and electricity
Exemplified by Xie Shui is neutrality, the size of produced bubble hydrogen is distributed in 20~80 micrometer ranges in gaussian random.Anode strip 40
The oxygen of generation also exists in the form of bubble, so that anodic current density is 2~6mA/cm2 and electrolysis at ambient pressure as an example,
Produced bubble distribution is in 40~100 micrometer ranges.Therefore, the way of realization of permeable trapping film 30 can have retention
Size is less than any type of film of bubble hydrogen and oxygen bubbles size, i.e., with retention size (or being filter opening) 10 microns with
Under.
Specifically, as one of which embodiment, permeable trapping film 30 can be retention size (or being filter opening)
Filter membrane below 10 microns.For example, microfiltration membranes.Microfiltration membranes refer to filter membrane of the filter opening footpath between 0.1~1 micron.Micro-filtration
Film can use inoranic membrane and organic high molecular layer.Inoranic membrane can be ceramic membrane and metal film.Organic high molecular layer can be
Natural macromolecule membrane and synthetic polymeric membrane, such as Kynoar (PVDF), polysulfones (PSF), polyacrylonitrile (PAN), polychlorostyrene
Ethene (PVC), polypropylene (PP) etc..Flat Membrane, tubular membrane, rolled film and hollow-fibre membrane are divided into according to the form of film again;Root
According to film principle, the preparation method of polymeric membrane is divided into leaching (dry-wet method), stretching hole forming method, phase inversion, thermic phase
Method, dip coating, irradiation method, surface chemical modification method, nuclear track method, power formation method etc., the preparation method of inoranic membrane mainly has
Sol-gel processing, sintering process, chemical precipitation method etc..Solvent understands, the microfiltration membranes with insulating properties are used herein,
Preferably organic polymer microfiltration membranes.Certainly, filter membrane can also use milipore filter etc..
As other embodiment, permeable trapping film 30 is from moistened membrane.It is that liquid water can be allowed to pass through from moistened membrane
And the film that other media can not pass through.Hydrophilic substance (such as titanium dioxide, silica, three oxidations two can be used from moistened membrane
The nafion films of aluminum particulate doping and modification).
Cathode sheets 20, permeable trapping film 30 and the three of anode strip 40 can not abut or side of the three to abut
Formula, such as cathode sheets 20, permeable trapping film 30 and anode strip 40 are sequentially overlapped setting.
Here, " superposition is set ", which may be appreciated, refers to that multiple objects (such as film) with Rotating fields use one
Fit in the stack manner on another one surface.So that A, B, C, D are sequentially overlapped setting as an example, refer to that an A surface sets B, B
Surface sets C, C surface to set D, i.e., according to a direction (such as from top to bottom), A, B, C, D are arranged in order.
Cathode sheets 20 and anode strip 40 can be with titanium sheet., can be in table in order to strengthen the activity of cathode sheets 20 and anode strip 40
Face coats some oxides, as described in Chinese patent CN104562078A, is specially:Coating comprises at least primer coating and top layer
Coating, the primer coating includes titanium oxide, iridium oxide and ru oxide, and the face coat includes iridium oxide, ruthenium
The metal or oxide of one or both of oxide, titanium oxide and palladium, platinum element.Ruthenium, iridium and titanium in primer coating
Molar percentage be:Ruthenium:Iridium:Titanium=30~50%:10~25%:30~45%;Ruthenium in face coat, iridium, titanium and palladium
Molar percentage is:Ruthenium:Iridium:Titanium:Palladium=30~50%:10~25%:30~45%:2.5~20%.Ruthenium in primer coating,
The molar percentage of iridium and titanium is:Ruthenium:Iridium:Titanium=30~50%:10~25%:30~45%;Ruthenium, iridium, titanium in face coat
Molar percentage with platinum is:Ruthenium:Iridium:Titanium:Platinum=30~50%:10~25%:30~45%:2.5~20%.Primer coating
The molar percentage of middle ruthenium, iridium and titanium is:Ruthenium:Iridium:Titanium=30~50%:10~25%:30~45%;Ruthenium in face coat,
Iridium, titanium, the molar percentage of palladium and platinum are:Ruthenium:Iridium:Titanium:Palladium:Platinum=30~50%:10~25%:30~45%:2.5~
20%:2.5~20%.Also include Zirconium oxide in primer coating, ruthenium in primer coating, iridium, the molar percentage of titanium and zirconium are:
Ruthenium:Iridium:Titanium:Zirconium=30~50%:10~25%:30~45%:2~10%;Ruthenium in face coat, iridium, mole of titanium and palladium
Percentage is:Ruthenium:Iridium:Titanium:Palladium=30~50%:10~25%:30~45%:2.5~20%.Also include zirconium in primer coating
Ruthenium in oxide, primer coating:Iridium:The molar percentage of titanium and zirconium is:Ruthenium:Iridium:Titanium:Zirconium=30~50%:10~25%:30
~45%:2~10%;Ruthenium in face coat, iridium, the molar percentage of titanium and platinum be, ruthenium:Iridium:Titanium:Platinum=30~50%:10
~25%:30~45%:2.5~20%.Also include Zirconium oxide, ruthenium in primer coating in primer coating:Iridium:Titanium and zirconium rub
Your percentage is ruthenium:Iridium:Titanium:Zirconium=30~50%:10~25%:30~45%:2~10%;Ruthenium in face coat, iridium, titanium,
The molar percentage of palladium and platinum is, ruthenium:Iridium:Titanium:Palladium:Platinum=30~50%:10~25%:30~45%:2.5~20%:2.5
~20%.The thickness of primer coating is 5~15 microns, and the thickness of face coat is 1~5 micron.
Anode strip 40 and cathode sheets 20 can be set it is porous, for example can be set honeycomb, with ensure contacted with water it is abundant
Property.
Above-mentioned tank house can be using any object with an accommodation space.For example, tank house may include the He of base 50
Upper lid 60, base 50 and upper lid 60 cover to form the accommodating cavity of accommodating a cathode sheets 20, permeable trapping film 30 and anode strip 40.
The mode that base 50 and upper lid 60 are covered can be connected by integration connection or non-removable mode.
Except this can also use removably, to facilitate to cathode sheets 20, permeable trapping film 30 and anode strip 40 more
Change.Dismountable mode, can be fastener, sliding part, shackle member.Herein, fastener can include flange part, spiro connecting piece
Deng.
The a kind of of above-mentioned shackle member can be enumerated and implement structure, be specially:Shackle member includes being arranged at the card of the first installed part
The hole clipping of the second installed part is detained and is arranged at, the buckle is engaged with hole clipping.Buckle includes being arranged at the connection of the first installed part
Around flexible holding section around portion and the elastic clamping part positioned at connecting portion one end, hole clipping.Clamping part is a spheroid,
Buckle is hollow structure, is formed with and educates hole from what connecting portion extended to clamping part, so as to allow first fastener to be squeezed
Shi Fasheng elastic deformations.Buckle can be integrally formed with the first installed part.Holding section is formed with multiple breach, and breach is by clamping part
Separate clamping is divided into, so that holding section produces elastic deformation when being acted on by external force.The diameter of block button hole is less than
The sphere diameter of clamping part.When clamping part inserts hole clipping, blocked block is occurred elastic deformation by the thrust of clamping part and expanded outwardly, and makes card
Buckle passes through block button hole.Clamping part passes through hole clipping, and blocked block and clamping part restore to the original state, and clamping part is barred from card by blocked block
So that the first installed part to be fixed with the second installed part outside hole.Holding section end is formed with chamfering, to dismantle the first housing and
Clamping part is set to be easy to be back in hole clipping under external force during two installed parts.
Above-mentioned shackle member can also enumerate second of implementation structure (not shown).Specially:Shackle member may include block tongue
And buckle.Block tongue includes the coupler body of the first neck, the second neck and the hook-type between the first neck and the second neck, and this
One neck, the second neck, hook and slot are the groove of the structure of elasticity.Buckle includes the first cutting, the second cutting and inserted positioned at first
Hook and slot between bar, the second cutting.First neck, the second neck, hook and slot are the groove of elasticity.First neck, the second card
Groove, hook and slot are the groove of elasticity.When clamping of the block tongue to be realized with buckle, first cutting is inserted in the first neck, and second
Cutting is inserted in the second neck, and coupler body insertion hook and slot, the first neck, the second neck, the elasticity of hook and slot ensure the first cutting, second
Cutting and the close contact of coupler body and reached clamping effect.
Above-mentioned shackle member can also enumerate the third and implement structure (not shown).Specially:Shackle member may include deck
And block tongue, the deck and block tongue are engaged.In this, the shape of deck and block tongue is not particularly limited, the embodiment party of its structure
Formula has a lot.Wherein the first embodiment is the buckle applied to backpack strip.Specifically, deck includes a neck.Block tongue can
For E fonts, that is to say, that the block tongue of the structure include the first cutting, the 3rd cutting, and positioned at the first cutting, the 3rd cutting it
Between the second cutting, the first cutting and the 3rd cutting are elastic construction, and the two can draw close to the second cutting under external force, remove
Sell after external force, the two is returned to original position.Second cutting can be elastic construction, or non-resilient.With tongue structure pair
Ying Di, the front portion of neck will be wider than rear portion.Herein, " preceding " refers to along tongue approach axis.The anterior width outline of neck, which is less than, inserts
The width of tongue, the rear portion width of neck will be significantly less than the width of tongue, during so may be such that block tongue insertion neck,
When entering to the front portion of neck, the first cutting and the 3rd cutting are compressed and drawn close to the second cutting, when enter to neck after
During portion, because the thickness of neck is open body, the first cutting and the 3rd cutting outwards flick to expose outside out of deck automatically.Card
Groove when the buckle of block tongue to be realized and deck, by block tongue insert neck in, at this moment, the first cutting and the 3rd cutting are exposed to
Deck;When the dismounting of block tongue to be realized and deck, the first cutting and the 3rd cutting only need to be mediated with so that block tongue is extracted in card
Groove.
Sliding part may include to be arranged on sliding-tongue and coordinate the slide rail slided for sliding-tongue with the sliding-tongue.The form of slide rail can be arranged
Two kinds are enumerated, the first is that the sliding cavity being caught in for sliding-tongue is formed between two parallel raised lines, raised line.In order that obtaining sliding-tongue more
It is caught in sliding cavity well, sliding cavity is "convex" shaped, in this accordingly, sliding-tongue is also the "convex" shaped.Second of slide rail
Form is to be opened in the slide opening inside base 50.Similarly, preferably it is caught in order that obtaining sliding-tongue in slide opening, slide opening is " convex " word
Shape, in this accordingly, sliding-tongue are also the "convex" shaped.At least one of sliding-tongue and slide rail can be elastic construction.That is, sliding-tongue is can
The elastically-deformable material of generation is made, with the rubber for the high elastic modulus of representative such as nitrile rubber, ethylene propylene diene rubber
Material, slide rail is rigid metal material.Or ground, slide rail is made by that can occur elastically-deformable material, and sliding-tongue is rigid
Metal material.Or ground, it is made both at that can occur elastically-deformable material.
Magnetic attraction fastener.Herein as the term suggests ground magnetic attraction fastener refers to promote upper lid 60 and bottom by the attraction of magnetic force
A kind of structure of implementing of 50 magnetic attraction fasteners of seat is, it includes being arranged at the first magnet of lid 60 and is arranged at the of base 50
Two magnet.First magnet and the second magnet can be set in the form of bonding on upper lid 60 and base 50 respectively.Implement in this kind
In structure, the attraction between the first magnet and the second magnet can fit upper lid 60 on base 50, certainly in a magnet and
The distance between second magnet is in the effective range of magneticaction.
Another of magnetic attraction fastener implements structure, and it includes being arranged at a magnet of lid 60 and is arranged at base 50
Ironware (such as iron plate or iron block).Certainly, the set location of ironware and magnet is interchangeable, that is to say, that magnet may be provided at
On base 50, ironware may be provided on lid 60.
Another of magnetic attraction fastener implements structure, and it includes being arranged at a magnet of lid 60 and is arranged at base 50
Electromagnetism part.Electromagnetism part, which refers to, can produce the device of magnetic effect by electric current.Electromagnetism part can also realize magnetic according to public structure
Change (i.e. N poles and S poles) to produce suction and row's power to magnet, to produce the connection of the upper lid 60 of driving and base 50.
, can be using circular lid and square cover etc. as the form of base 50 and upper lid 60.
Cathode sheets 20, permeable trapping film 30 and anode strip 40 can be contained directly in tank house.Certainly can also be by setting
Put installed part and three is superimposed setting.Specifically, tank house also includes to install anode strip 40 and be arranged at outside electrolysis zone
Anode install lid 80.Anode strip 40 can be arranged on the surface that anode installs lid 80.Mode as installation can be by tight
Firmware.The main surface area that anode installs lid 80 can be more than anode strip 40.
The negative electrode that tank house also includes to install cathode sheets 20 and be arranged at outside the electrolysis zone installs lid 70.Negative electrode
Piece 20 can be arranged on the surface that negative electrode installs lid 70.Mode as installation can pass through fastener.Negative electrode installs lid 70
Main surface area can be more than cathode sheets 20.
Negative electrode installation lid 70 and anode installation lid 80, which lead to, can cover to house cathode sheets 20, permeable trapping film 30 and anode
Piece 40.Base 50 and upper lid 60 can be same as the mode covered, is no longer described in detail in this.
Negative electrode is installed can set pad between lid 70 and negative electrode.Anode is installed can set pad between lid 80 and anode
Piece.Negative electrode is installed can set pad between lid 70 and upper lid 60.The quantity of these pads can be one or more.Pad can
Think round etc..
Above-mentioned, what the removably that hydrogen-oxygen separating film module is arranged on support can be such as base 50 and upper lid 60 is detachable
Mode.
In order to realize the storage to the water produced by hydrogen-oxygen separating film module, waste water collection device 220 can be set.Waste water is received
Acquisition means 220 may include waste water accommodating body 221 and to the waste water lid 222 for the opening for covering the waste water accommodating body 221.
Here, waste water accommodating body 221 can be cylindrical shape, its internal outer wall for having cavity and surrounding the cavity, cavity
To collect waste water.It is understood that waste water is the steam entrained by the oxygen that hydrogen-oxygen separating film module is discharged herein, it is preceding
Text is already described, and the oxygen being separated during hydrogen manufacturing is discharged in the form of bubble, and oxygen bubbles is in the process escaped from water
In can carry steam.The opening of waste water accommodating body 221 can be arranged on the lower center position of waste water accommodating body 221.Waste water holds
The outer wall of waste water accommodating body 221 can be arranged in the way of bulge-structure by putting the opening of body 221, and the periphery of bulge-structure can be set
Screw thread is put, so that waste water lid 222 is bolted in waste water accommodating body 221.
Oxygen discharge is opened or closed in order to realize, waste water collection device 220 also includes waste water post 223, is arranged at waste water
Lid 222 and with the convex column 224 of inner chamber, the waste water post 223 through the inner chamber of convex column 224, be sheathed on the periphery of waste water post 223
Spring 225, be sheathed on waste water post 223 top periphery the seal cap to the inner chamber top end opening of seal convexity post 224
226, the inner chamber of convex column 224 is provided with defining flange 2241, and defining flange 2241 when waste water post 223 to top to be pressed
When, one end of spring 225 is abutted defining flange 2241, the other end and abut the bottom of waste water post 223 and depart from limited cap
Cover the inner chamber top end opening of convex column 224.
So, when hydrogen-rich hydrogenesis machine 200 is placed (such as when being placed on desktop), the bottom of waste water post 223 is by table
Direction pressing towards top is until spring 225 is in compressive state, and at the same time, one end of spring 225 abuts defining flange
2241, the other end abuts the bottom of waste water post 223, and seal cap 226 departs from the position for covering the inner chamber top end opening of convex column 224,
Oxygen in waste water accommodating body 221 can be between waste water post 223 and convex column 224 gap discharge.When hydrogen-rich hydrogenesis machine
200 when being lifted, and the pressing effect of the bottom of rich waste water post 223 is avoided, in the big compression elasticity of spring 225 and waste water post
Under 223 Action of Gravity Field of itself, waste water post 223 is to the movement of bottom direction until seal cap 226 covers the inner chamber top of convex column 224
Opening, oxygen cannot be introduced into the inner chamber of convex column 224, so that oxygen can not be discharged.
It should be noted that the bottom of waste water post 223 is limited in the outside of the inner chamber of convex column 224, waste water post all the time
223 top can freely extend into or out the inner chamber of convex column 224.Herein, the bottom of waste water post 223 is limited in convex column all the time
The mode of the outside of 224 inner chamber can according to any known form, such as bottom of waste water post 223 easily imagined hat shape
Body, calyptrate width is more than the inner chamber of convex column 224.
The top of waste water post 223 can be provided with annular groove, to realize being arranged for seal cap 226.Seal cap 226 can be elasticity
Circle.
Above-mentioned defining flange 2241 can be installed in the inner surface of convex column 224.As one kind more preferred embodiment,
The inner chamber of convex column 224 is separated into the first sub- chamber and the second sub- chamber by defining flange 2241.First sub- chamber putting spring 225, the
Two sub- chambers are with so that seal cap 226 is in the position for covering the inner chamber top end opening of convex column 224.
Waste water collection device 220 also includes the water proof ring being arranged between the opening of waste water lid 222 and waste water accommodating body 221
227.It thus is avoided that the water of waste water accommodating body 221 is spilt from the gap of the opening of waste water accommodating body 221.
Also slipmat 228 can be set in the outer surface of waste water lid 222, to cause hydrogen rich water is generated when machine 200 is placed not allow
Easily slide.It should be noted that the thickness of slipmat 228 can not be too high, and otherwise when hydrogen-rich hydrogenesis machine 200 is placed, waste water
The bottom of post 223 just will not be pressed.
Hydrogen-rich hydrogenesis machine 200 can also include being arranged on circuit board and power supply of support 210 etc..Power supply is to for hydrogen-oxygen
Separating film module is powered.Circuit board realizes the electrical connection of power supply and hydrogen-oxygen separating film module, circuit board can be provided with to realize by
The input current of power supply carries out the constant-current circuit of constant current, and to realize that the constant pressure that the input voltage of power supply is carried out into constant pressure is electric
Road.Constant-current circuit and constant voltage circuit are using known technology.
It is above-mentioned not address part, it is adaptable to prior art.
Although more above used the term for representing structure, such as " permeable trapping film ", " hydrogen-producing region ", " oxygen generation
Area " etc., but it is not precluded from the possibility using other terms.It is used for the purpose of more easily describing and explaining using these terms
The essence of the present invention;Any additional limitation is construed as all to disagree with spirit of the present invention.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
Those familiar with the art the invention discloses technical scope in, change or replacement can be readily occurred in, should all be contained
Cover within protection scope of the present invention.Therefore, protection scope of the present invention described should be defined by scope of the claims.