CN107032449A - Hydrogen-rich hydrogenesis machine - Google Patents

Hydrogen-rich hydrogenesis machine Download PDF

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Publication number
CN107032449A
CN107032449A CN201710254797.1A CN201710254797A CN107032449A CN 107032449 A CN107032449 A CN 107032449A CN 201710254797 A CN201710254797 A CN 201710254797A CN 107032449 A CN107032449 A CN 107032449A
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China
Prior art keywords
hydrogen
waste water
oxygen
lid
cathode sheets
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CN201710254797.1A
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Chinese (zh)
Inventor
李士刚
陆旭东
邱胜
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Shenzhen Hydrogen Health Technology Holding Co Ltd
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Shenzhen Hydrogen Health Technology Holding Co Ltd
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Priority to CN201710254797.1A priority Critical patent/CN107032449A/en
Publication of CN107032449A publication Critical patent/CN107032449A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • C02F2001/46138Electrodes comprising a substrate and a coating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46152Electrodes characterised by the shape or form
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46152Electrodes characterised by the shape or form
    • C02F2001/46157Perforated or foraminous electrodes
    • C02F2001/46161Porous electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/46115Electrolytic cell with membranes or diaphragms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/30H2

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention discloses hydrogen-rich hydrogenesis machine.The hydrogen-rich hydrogenesis machine includes support and is removably installed in the hydrogen-oxygen separating film module of the support;The hydrogen-oxygen separating film module includes tank house, provided with cathode sheets, anode strip and the permeable trapping film being arranged between the cathode sheets and anode strip in the tank house, the cathode sheets, anode strip surround an electrolysis zone, and the permeable trapping film by the electrolysis zone to be separated into hydrogen-producing region and oxygen generation area.The hydrogen-oxygen separating film module of the present invention, in hydrogen manufacturing, the hydrogen-rich that cathode sheets are produced is in hydrogen-producing region, the oxygen concentration that anode strip is produced produces area in oxygen, permeable trapping film has obstructed hydrogen and has produced the diffusion in area to oxygen and obstructed diffusion of the oxygen to hydrogen-producing region, has thus reached the separation of hydrogen and oxygen.

Description

Hydrogen-rich hydrogenesis machine
Technical field
The making apparatus technical field of hydrogen rich water of the present invention, in particular to hydrogen-rich hydrogenesis machine.
Background technology
Hydrogen rich water, as the term suggests it is exactly the water rich in hydrogen.English is hydrogen rich water, and Japanese is " water element Water ".As a kind of selective polyphenoils, hydrogen has therapeutic action to many diseases, before being widely used Scape.
In recent years, the plain aquatic products of hydrogen rich water, water are gradually more on domestic market, and the cup of the plain water of hydrogen rich water, water also has finding, its The technology of middle use electrolytic hydrogen production occupies significant proportion, including related patented technology is emerged in large numbers.In these electrolytic hydrogen production cups And its in patented technology, it is common to have horizontally disposed electrode structure, such as Chinese patent:Application number 201510366113.8, application Numbers 201510126957.5,201520051049.X etc.;Also there are the electrode structure arranged up and down, such as Chinese patent:Application number 201520786526.7 wait.Its product of electrode structure of both arrangements are through experiment or practical, it has been found that its not foot phenomenon.
In the prior art, the hydrogen and oxygen Monodispersed that hydrogen-rich hydrogenesis machine generally can not be made are in water, it is impossible to real The separation of existing hydrogen and oxygen, such as Chinese patent CN106115866A disclose can a kind of point of air-flow hydrogen-rich hydrogenesis machine and its make Use method.It is the hydrogen-rich hydrogenesis machine cup includes cup body, be connected with cup body top side detachable formula lid, close with cup body bottom Seal in base, the electrolysis unit in cup body being fixedly connected, base and power supply module, pcb board are installed;Set on pcb board It is equipped with control circuit;Heating ring and temperature sensor are provided with the top of base;Lid includes water storehouse, is arranged on water storehouse bottom The filter core in portion, the bottle cap being connected with water storehouse top side detachable formula;Bottle cap top is provided with a gas bleeder valve;Electrolysis unit includes one Electrode tip holder, the gas skirt at the top of electrode tip holder and the negative electrode being arranged on from top to bottom on electrode tip holder being connected with base bottom Plate, the first division board, ionic membrane, the second division board, anode strip;Passage is offered on electrode tip holder below anode strip;Power supply Module, temperature sensor, heating ring, minus plate, anode strip are connected with control circuit respectively.However, the water containing oxygen is drunk With the rear aging to accelerating human body body, certain potential hazard is produced to human body.
The content of the invention
In view of this, the purpose of the embodiment of the present invention is to provide a kind of hydrogen-rich hydrogenesis machine, and the hydrogen-rich hydrogenesis machine exists The separation of hydrogen and oxygen can be realized during hydrogen manufacturing.
A kind of hydrogen-rich hydrogenesis machine, including support and the hydrogen-oxygen separating film module for being removably installed in the support;Institute Hydrogen-oxygen separating film module is stated including tank house, in the tank house provided with cathode sheets, anode strip and be arranged at the cathode sheets and Permeable trapping film between anode strip, the cathode sheets, anode strip surround an electrolysis zone, and the permeable trapping film is to by described in Electrolysis zone is separated into hydrogen-producing region and oxygen produces area.
Further, the permeable trapping film is from moistened membrane or microfiltration membranes.
Further, the cathode sheets and anode strip are titanium sheet.
Further, the tank house includes base and upper lid, and the base and upper lid cover accommodating described to form one The accommodating cavity of cathode sheets, permeable trapping film and anode strip.
Further, the tank house also includes the anode peace to install anode strip and be arranged at outside the electrolysis zone Capping.
Further, the tank house also includes the negative electrode peace to install cathode sheets and be arranged at outside the electrolysis zone Capping.
Further, the negative electrode, which is installed to cover to install with anode, covers logical cover with accommodating cathode sheets, permeable trapping film and sun Pole piece.
Further, in addition to waste water collection device, the waste water collection device includes waste water accommodating body and to cover The waste water lid of the opening of the waste water accommodating body.
Further, the waste water collection device also include waste water post, be arranged at waste water lid and with inner chamber convex column, Waste water post through the inner chamber of the convex column, it is sheathed on the spring of the waste water post periphery, is sheathed on outside the top of waste water post The seal cap to seal convexity post inner chamber top end opening in week, the inner chamber of the convex column is provided with defining flange, described spacing Flange is used to when waste water post is pressed to top, make one end abutting defining flange, the other end of spring abut waste water post Bottom and make limited cap depart from cover convex column inner chamber top end opening.
Further, the waste water collection device also includes being arranged on anti-between the opening of waste water lid and waste water accommodating body Hydrosphere.
The hydrogen-oxygen separating film module of the present invention, in hydrogen manufacturing, the hydrogen-rich that cathode sheets are produced is in hydrogen-producing region, anode strip The oxygen concentration of generation oxygen produce area, permeable trapping film obstructed hydrogen to oxygen produce area diffusion and obstructed oxygen to The diffusion of hydrogen-producing region, has thus reached the separation of hydrogen and oxygen.
To enable the above objects, features and advantages of the present invention to become apparent, preferred embodiment cited below particularly, and coordinate Appended accompanying drawing, is described in detail below.
Brief description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, below will be attached to what is used required in embodiment Figure is briefly described, it should be understood that, the following drawings illustrate only some embodiments of the shaped device of the present invention, therefore The restriction to scope is not construed as, for those of ordinary skill in the art, the premise of creative work is not being paid Under, other related accompanying drawings can also be obtained according to these accompanying drawings.
Fig. 1 shows the assembling schematic diagram for the hydrogen-rich hydrogenesis machine that the embodiment of the present invention is provided.
Fig. 2 shows the exploded perspective view for the hydrogen-rich hydrogenesis machine that the embodiment of the present invention is provided.
Fig. 3 shows the assembling schematic diagram for the hydrogen-oxygen separating film module that the embodiment of the present invention is provided.
Fig. 4 shows the exploded perspective view for the hydrogen-oxygen separating film module that the embodiment of the present invention is provided.
Fig. 5 shows the assembling schematic diagram for the waste water collection device that the embodiment of the present invention is provided.
Fig. 6 shows the exploded perspective view for the waste water collection device that the embodiment of the present invention is provided.
Fig. 7 shows the structure chart for the limited post that the embodiment of the present invention is provided.
Main element symbol description:
100-hydrogen-oxygen separating film module;20-cathode sheets;30-permeable trapping film;40-anode strip;50-base; 60-above cover;70-negative electrode installs lid;80-anode installs lid;200-hydrogen-rich hydrogenesis machine;210-support;220-waste water Collection device;221-waste water accommodating body;222-waste water lid;223-waste water post;224-convex column;2241-defining flange; 225-spring;226-seal cap;227-water proof ring;228-slipmat.
Embodiment
For the ease of understanding the present invention, shaped device is described more fully below with reference to relevant drawings.Accompanying drawing In give the preferred embodiment of shaped device.But, shaped device can be realized in many different forms, however it is not limited to Embodiment described herein.On the contrary, the purpose for providing these embodiments is to make the disclosure to shaped device more saturating It is thorough comprehensive.
The term used in the various embodiments of the disclosure is only used for describing the purpose of specific embodiment and not anticipated In the various embodiments of the limitation disclosure.As used herein, singulative is intended to also include plural form, unless context is clear Chu it is indicated otherwise.Unless otherwise defined, all terms (including the technical term and scientific terminology) tool being otherwise used herein There is the implication identical implication that the various embodiment one skilled in the art with the disclosure are generally understood that.The term (term such as limited in the dictionary typically used) is to be interpreted as having and the situational meaning in correlative technology field Identical implication and it will be not construed as with Utopian implication or excessively formal implication, unless in the various of the disclosure It is clearly defined in embodiment.
In the description of the invention, it is to be understood that term " longitudinal direction ", " transverse direction ", " on ", " under ", "front", "rear", The orientation or position relationship of the instruction such as "left", "right", " vertical ", " level ", " top ", " bottom ", " interior ", " outer " is based on accompanying drawing institutes The orientation or position relationship shown, is for only for ease of the description present invention and simplifies description, rather than indicate or imply signified dress Put or element there must be specific orientation, with specific azimuth configuration and operation, therefore it is not intended that to the limit of the present invention System.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means to combine specific features, structure, material or the spy that the embodiment or example are described Point is contained at least one embodiment of the present invention or example.In this manual, to the schematic representation of above-mentioned term not Necessarily refer to identical embodiment or example.Moreover, specific features, structure, material or the feature of description can be any One or more embodiments or example in combine in an appropriate manner.
In the description of the invention, unless otherwise prescribed with limit, it is necessary to explanation, term " installation ", " connected ", " connection " should be interpreted broadly, for example, it may be mechanically connect or electrical connection or the connection of two element internals, can To be to be joined directly together, it can also be indirectly connected to by intermediary, for the ordinary skill in the art, can basis Concrete condition understands the concrete meaning of above-mentioned term.
The statement (" first ", " second " etc.) used in the various embodiments of the disclosure can be modified to be implemented various Various element in example, but corresponding element can not be limited.For example, presented above be not intended to limit the suitable of the element Sequence and/or importance.The purpose presented above for being only used for differentiating an element and other elements.For example, the first user fills Put and indicate different user device with second user device, although the two is all user's set.For example, not departing from each of the disclosure In the case of the scope for planting embodiment, the first element is referred to alternatively as the second element, similarly, and the second element is also referred to as first Element.
It should be noted that:, can be by the first composition member if an element ' attach ' to another element by description Part is directly connected to the second element, and " connection " the 3rd can be constituted between the first element and the second element Element.On the contrary, when an element " being directly connected to " is arrived into another element, it will be appreciated that be in the first element And second the 3rd element is not present between element.
In addition, the indefinite article " one kind " and " one " before key element of the present invention or component are to key element or the quantitative requirement of component (i.e. occurrence number) unrestriction.Therefore " one " or " one kind " should be read as including one or at least one, and odd number The key element or component of form also include plural form, unless the obvious purport of the quantity refers to singulative.
Fig. 1 is referred to Fig. 7.The hydrogen-rich hydrogenesis machine 200 of the embodiment of the present invention, including support 210 and removably pacify Hydrogen-oxygen separating film module 100 loaded on support 210;Hydrogen-oxygen separating film module 100 includes being provided with cathode sheets in tank house, tank house 20th, anode strip 40 and the permeable trapping film 30 being arranged between cathode sheets 20 and anode strip 40, cathode sheets 20, anode strip 40 are surrounded One electrolysis zone, permeable trapping film 30 by electrolysis zone to be separated into hydrogen-producing region and oxygen generation area.
In above-described embodiment, in hydrogen manufacturing, the hydrogen-rich that cathode sheets 20 are produced in hydrogen-producing region, what anode strip 40 was produced Oxygen concentration produces area in oxygen, and permeable trapping film 30 has obstructed hydrogen and produced the diffusion in area to oxygen and obstructed oxygen and produced to hydrogen The diffusion in raw area, has thus reached the separation of hydrogen and oxygen.
Term " electrolysis zone " refers to the region passed through with electric current.Term " tank house " refers to the object for implementing electrolysis.It is cloudy Pole piece 20, anode strip 40 and permeable trapping film 30 are placed in tank house.
Above-mentioned permeable trapping film 30 refers to the film with permeable trapping function.It should be noted that trapping herein refer to every Exist from the gas existed in the form of bubbles, rather than with molecular state.The mechanism of hydrogen produced by electrolysis water is, the hydrogen in water Ion obtains electronics in cathode sheets 20 and occurs reduction reaction and produce gas phase, because the interface between gas phase and aqueous phase is poor, institute It is dispersed in water with the hydrogen of production with bubble hydrogen.Using the current density of negative electrode as 2~6mA/cm2, be electrolysed at ambient pressure and electricity Exemplified by Xie Shui is neutrality, the size of produced bubble hydrogen is distributed in 20~80 micrometer ranges in gaussian random.Anode strip 40 The oxygen of generation also exists in the form of bubble, so that anodic current density is 2~6mA/cm2 and electrolysis at ambient pressure as an example, Produced bubble distribution is in 40~100 micrometer ranges.Therefore, the way of realization of permeable trapping film 30 can have retention Size is less than any type of film of bubble hydrogen and oxygen bubbles size, i.e., with retention size (or being filter opening) 10 microns with Under.
Specifically, as one of which embodiment, permeable trapping film 30 can be retention size (or being filter opening) Filter membrane below 10 microns.For example, microfiltration membranes.Microfiltration membranes refer to filter membrane of the filter opening footpath between 0.1~1 micron.Micro-filtration Film can use inoranic membrane and organic high molecular layer.Inoranic membrane can be ceramic membrane and metal film.Organic high molecular layer can be Natural macromolecule membrane and synthetic polymeric membrane, such as Kynoar (PVDF), polysulfones (PSF), polyacrylonitrile (PAN), polychlorostyrene Ethene (PVC), polypropylene (PP) etc..Flat Membrane, tubular membrane, rolled film and hollow-fibre membrane are divided into according to the form of film again;Root According to film principle, the preparation method of polymeric membrane is divided into leaching (dry-wet method), stretching hole forming method, phase inversion, thermic phase Method, dip coating, irradiation method, surface chemical modification method, nuclear track method, power formation method etc., the preparation method of inoranic membrane mainly has Sol-gel processing, sintering process, chemical precipitation method etc..Solvent understands, the microfiltration membranes with insulating properties are used herein, Preferably organic polymer microfiltration membranes.Certainly, filter membrane can also use milipore filter etc..
As other embodiment, permeable trapping film 30 is from moistened membrane.It is that liquid water can be allowed to pass through from moistened membrane And the film that other media can not pass through.Hydrophilic substance (such as titanium dioxide, silica, three oxidations two can be used from moistened membrane The nafion films of aluminum particulate doping and modification).
Cathode sheets 20, permeable trapping film 30 and the three of anode strip 40 can not abut or side of the three to abut Formula, such as cathode sheets 20, permeable trapping film 30 and anode strip 40 are sequentially overlapped setting.
Here, " superposition is set ", which may be appreciated, refers to that multiple objects (such as film) with Rotating fields use one Fit in the stack manner on another one surface.So that A, B, C, D are sequentially overlapped setting as an example, refer to that an A surface sets B, B Surface sets C, C surface to set D, i.e., according to a direction (such as from top to bottom), A, B, C, D are arranged in order.
Cathode sheets 20 and anode strip 40 can be with titanium sheet., can be in table in order to strengthen the activity of cathode sheets 20 and anode strip 40 Face coats some oxides, as described in Chinese patent CN104562078A, is specially:Coating comprises at least primer coating and top layer Coating, the primer coating includes titanium oxide, iridium oxide and ru oxide, and the face coat includes iridium oxide, ruthenium The metal or oxide of one or both of oxide, titanium oxide and palladium, platinum element.Ruthenium, iridium and titanium in primer coating Molar percentage be:Ruthenium:Iridium:Titanium=30~50%:10~25%:30~45%;Ruthenium in face coat, iridium, titanium and palladium Molar percentage is:Ruthenium:Iridium:Titanium:Palladium=30~50%:10~25%:30~45%:2.5~20%.Ruthenium in primer coating, The molar percentage of iridium and titanium is:Ruthenium:Iridium:Titanium=30~50%:10~25%:30~45%;Ruthenium, iridium, titanium in face coat Molar percentage with platinum is:Ruthenium:Iridium:Titanium:Platinum=30~50%:10~25%:30~45%:2.5~20%.Primer coating The molar percentage of middle ruthenium, iridium and titanium is:Ruthenium:Iridium:Titanium=30~50%:10~25%:30~45%;Ruthenium in face coat, Iridium, titanium, the molar percentage of palladium and platinum are:Ruthenium:Iridium:Titanium:Palladium:Platinum=30~50%:10~25%:30~45%:2.5~ 20%:2.5~20%.Also include Zirconium oxide in primer coating, ruthenium in primer coating, iridium, the molar percentage of titanium and zirconium are: Ruthenium:Iridium:Titanium:Zirconium=30~50%:10~25%:30~45%:2~10%;Ruthenium in face coat, iridium, mole of titanium and palladium Percentage is:Ruthenium:Iridium:Titanium:Palladium=30~50%:10~25%:30~45%:2.5~20%.Also include zirconium in primer coating Ruthenium in oxide, primer coating:Iridium:The molar percentage of titanium and zirconium is:Ruthenium:Iridium:Titanium:Zirconium=30~50%:10~25%:30 ~45%:2~10%;Ruthenium in face coat, iridium, the molar percentage of titanium and platinum be, ruthenium:Iridium:Titanium:Platinum=30~50%:10 ~25%:30~45%:2.5~20%.Also include Zirconium oxide, ruthenium in primer coating in primer coating:Iridium:Titanium and zirconium rub Your percentage is ruthenium:Iridium:Titanium:Zirconium=30~50%:10~25%:30~45%:2~10%;Ruthenium in face coat, iridium, titanium, The molar percentage of palladium and platinum is, ruthenium:Iridium:Titanium:Palladium:Platinum=30~50%:10~25%:30~45%:2.5~20%:2.5 ~20%.The thickness of primer coating is 5~15 microns, and the thickness of face coat is 1~5 micron.
Anode strip 40 and cathode sheets 20 can be set it is porous, for example can be set honeycomb, with ensure contacted with water it is abundant Property.
Above-mentioned tank house can be using any object with an accommodation space.For example, tank house may include the He of base 50 Upper lid 60, base 50 and upper lid 60 cover to form the accommodating cavity of accommodating a cathode sheets 20, permeable trapping film 30 and anode strip 40. The mode that base 50 and upper lid 60 are covered can be connected by integration connection or non-removable mode.
Except this can also use removably, to facilitate to cathode sheets 20, permeable trapping film 30 and anode strip 40 more Change.Dismountable mode, can be fastener, sliding part, shackle member.Herein, fastener can include flange part, spiro connecting piece Deng.
The a kind of of above-mentioned shackle member can be enumerated and implement structure, be specially:Shackle member includes being arranged at the card of the first installed part The hole clipping of the second installed part is detained and is arranged at, the buckle is engaged with hole clipping.Buckle includes being arranged at the connection of the first installed part Around flexible holding section around portion and the elastic clamping part positioned at connecting portion one end, hole clipping.Clamping part is a spheroid, Buckle is hollow structure, is formed with and educates hole from what connecting portion extended to clamping part, so as to allow first fastener to be squeezed Shi Fasheng elastic deformations.Buckle can be integrally formed with the first installed part.Holding section is formed with multiple breach, and breach is by clamping part Separate clamping is divided into, so that holding section produces elastic deformation when being acted on by external force.The diameter of block button hole is less than The sphere diameter of clamping part.When clamping part inserts hole clipping, blocked block is occurred elastic deformation by the thrust of clamping part and expanded outwardly, and makes card Buckle passes through block button hole.Clamping part passes through hole clipping, and blocked block and clamping part restore to the original state, and clamping part is barred from card by blocked block So that the first installed part to be fixed with the second installed part outside hole.Holding section end is formed with chamfering, to dismantle the first housing and Clamping part is set to be easy to be back in hole clipping under external force during two installed parts.
Above-mentioned shackle member can also enumerate second of implementation structure (not shown).Specially:Shackle member may include block tongue And buckle.Block tongue includes the coupler body of the first neck, the second neck and the hook-type between the first neck and the second neck, and this One neck, the second neck, hook and slot are the groove of the structure of elasticity.Buckle includes the first cutting, the second cutting and inserted positioned at first Hook and slot between bar, the second cutting.First neck, the second neck, hook and slot are the groove of elasticity.First neck, the second card Groove, hook and slot are the groove of elasticity.When clamping of the block tongue to be realized with buckle, first cutting is inserted in the first neck, and second Cutting is inserted in the second neck, and coupler body insertion hook and slot, the first neck, the second neck, the elasticity of hook and slot ensure the first cutting, second Cutting and the close contact of coupler body and reached clamping effect.
Above-mentioned shackle member can also enumerate the third and implement structure (not shown).Specially:Shackle member may include deck And block tongue, the deck and block tongue are engaged.In this, the shape of deck and block tongue is not particularly limited, the embodiment party of its structure Formula has a lot.Wherein the first embodiment is the buckle applied to backpack strip.Specifically, deck includes a neck.Block tongue can For E fonts, that is to say, that the block tongue of the structure include the first cutting, the 3rd cutting, and positioned at the first cutting, the 3rd cutting it Between the second cutting, the first cutting and the 3rd cutting are elastic construction, and the two can draw close to the second cutting under external force, remove Sell after external force, the two is returned to original position.Second cutting can be elastic construction, or non-resilient.With tongue structure pair Ying Di, the front portion of neck will be wider than rear portion.Herein, " preceding " refers to along tongue approach axis.The anterior width outline of neck, which is less than, inserts The width of tongue, the rear portion width of neck will be significantly less than the width of tongue, during so may be such that block tongue insertion neck, When entering to the front portion of neck, the first cutting and the 3rd cutting are compressed and drawn close to the second cutting, when enter to neck after During portion, because the thickness of neck is open body, the first cutting and the 3rd cutting outwards flick to expose outside out of deck automatically.Card Groove when the buckle of block tongue to be realized and deck, by block tongue insert neck in, at this moment, the first cutting and the 3rd cutting are exposed to Deck;When the dismounting of block tongue to be realized and deck, the first cutting and the 3rd cutting only need to be mediated with so that block tongue is extracted in card Groove.
Sliding part may include to be arranged on sliding-tongue and coordinate the slide rail slided for sliding-tongue with the sliding-tongue.The form of slide rail can be arranged Two kinds are enumerated, the first is that the sliding cavity being caught in for sliding-tongue is formed between two parallel raised lines, raised line.In order that obtaining sliding-tongue more It is caught in sliding cavity well, sliding cavity is "convex" shaped, in this accordingly, sliding-tongue is also the "convex" shaped.Second of slide rail Form is to be opened in the slide opening inside base 50.Similarly, preferably it is caught in order that obtaining sliding-tongue in slide opening, slide opening is " convex " word Shape, in this accordingly, sliding-tongue are also the "convex" shaped.At least one of sliding-tongue and slide rail can be elastic construction.That is, sliding-tongue is can The elastically-deformable material of generation is made, with the rubber for the high elastic modulus of representative such as nitrile rubber, ethylene propylene diene rubber Material, slide rail is rigid metal material.Or ground, slide rail is made by that can occur elastically-deformable material, and sliding-tongue is rigid Metal material.Or ground, it is made both at that can occur elastically-deformable material.
Magnetic attraction fastener.Herein as the term suggests ground magnetic attraction fastener refers to promote upper lid 60 and bottom by the attraction of magnetic force A kind of structure of implementing of 50 magnetic attraction fasteners of seat is, it includes being arranged at the first magnet of lid 60 and is arranged at the of base 50 Two magnet.First magnet and the second magnet can be set in the form of bonding on upper lid 60 and base 50 respectively.Implement in this kind In structure, the attraction between the first magnet and the second magnet can fit upper lid 60 on base 50, certainly in a magnet and The distance between second magnet is in the effective range of magneticaction.
Another of magnetic attraction fastener implements structure, and it includes being arranged at a magnet of lid 60 and is arranged at base 50 Ironware (such as iron plate or iron block).Certainly, the set location of ironware and magnet is interchangeable, that is to say, that magnet may be provided at On base 50, ironware may be provided on lid 60.
Another of magnetic attraction fastener implements structure, and it includes being arranged at a magnet of lid 60 and is arranged at base 50 Electromagnetism part.Electromagnetism part, which refers to, can produce the device of magnetic effect by electric current.Electromagnetism part can also realize magnetic according to public structure Change (i.e. N poles and S poles) to produce suction and row's power to magnet, to produce the connection of the upper lid 60 of driving and base 50.
, can be using circular lid and square cover etc. as the form of base 50 and upper lid 60.
Cathode sheets 20, permeable trapping film 30 and anode strip 40 can be contained directly in tank house.Certainly can also be by setting Put installed part and three is superimposed setting.Specifically, tank house also includes to install anode strip 40 and be arranged at outside electrolysis zone Anode install lid 80.Anode strip 40 can be arranged on the surface that anode installs lid 80.Mode as installation can be by tight Firmware.The main surface area that anode installs lid 80 can be more than anode strip 40.
The negative electrode that tank house also includes to install cathode sheets 20 and be arranged at outside the electrolysis zone installs lid 70.Negative electrode Piece 20 can be arranged on the surface that negative electrode installs lid 70.Mode as installation can pass through fastener.Negative electrode installs lid 70 Main surface area can be more than cathode sheets 20.
Negative electrode installation lid 70 and anode installation lid 80, which lead to, can cover to house cathode sheets 20, permeable trapping film 30 and anode Piece 40.Base 50 and upper lid 60 can be same as the mode covered, is no longer described in detail in this.
Negative electrode is installed can set pad between lid 70 and negative electrode.Anode is installed can set pad between lid 80 and anode Piece.Negative electrode is installed can set pad between lid 70 and upper lid 60.The quantity of these pads can be one or more.Pad can Think round etc..
Above-mentioned, what the removably that hydrogen-oxygen separating film module is arranged on support can be such as base 50 and upper lid 60 is detachable Mode.
In order to realize the storage to the water produced by hydrogen-oxygen separating film module, waste water collection device 220 can be set.Waste water is received Acquisition means 220 may include waste water accommodating body 221 and to the waste water lid 222 for the opening for covering the waste water accommodating body 221.
Here, waste water accommodating body 221 can be cylindrical shape, its internal outer wall for having cavity and surrounding the cavity, cavity To collect waste water.It is understood that waste water is the steam entrained by the oxygen that hydrogen-oxygen separating film module is discharged herein, it is preceding Text is already described, and the oxygen being separated during hydrogen manufacturing is discharged in the form of bubble, and oxygen bubbles is in the process escaped from water In can carry steam.The opening of waste water accommodating body 221 can be arranged on the lower center position of waste water accommodating body 221.Waste water holds The outer wall of waste water accommodating body 221 can be arranged in the way of bulge-structure by putting the opening of body 221, and the periphery of bulge-structure can be set Screw thread is put, so that waste water lid 222 is bolted in waste water accommodating body 221.
Oxygen discharge is opened or closed in order to realize, waste water collection device 220 also includes waste water post 223, is arranged at waste water Lid 222 and with the convex column 224 of inner chamber, the waste water post 223 through the inner chamber of convex column 224, be sheathed on the periphery of waste water post 223 Spring 225, be sheathed on waste water post 223 top periphery the seal cap to the inner chamber top end opening of seal convexity post 224 226, the inner chamber of convex column 224 is provided with defining flange 2241, and defining flange 2241 when waste water post 223 to top to be pressed When, one end of spring 225 is abutted defining flange 2241, the other end and abut the bottom of waste water post 223 and depart from limited cap Cover the inner chamber top end opening of convex column 224.
So, when hydrogen-rich hydrogenesis machine 200 is placed (such as when being placed on desktop), the bottom of waste water post 223 is by table Direction pressing towards top is until spring 225 is in compressive state, and at the same time, one end of spring 225 abuts defining flange 2241, the other end abuts the bottom of waste water post 223, and seal cap 226 departs from the position for covering the inner chamber top end opening of convex column 224, Oxygen in waste water accommodating body 221 can be between waste water post 223 and convex column 224 gap discharge.When hydrogen-rich hydrogenesis machine 200 when being lifted, and the pressing effect of the bottom of rich waste water post 223 is avoided, in the big compression elasticity of spring 225 and waste water post Under 223 Action of Gravity Field of itself, waste water post 223 is to the movement of bottom direction until seal cap 226 covers the inner chamber top of convex column 224 Opening, oxygen cannot be introduced into the inner chamber of convex column 224, so that oxygen can not be discharged.
It should be noted that the bottom of waste water post 223 is limited in the outside of the inner chamber of convex column 224, waste water post all the time 223 top can freely extend into or out the inner chamber of convex column 224.Herein, the bottom of waste water post 223 is limited in convex column all the time The mode of the outside of 224 inner chamber can according to any known form, such as bottom of waste water post 223 easily imagined hat shape Body, calyptrate width is more than the inner chamber of convex column 224.
The top of waste water post 223 can be provided with annular groove, to realize being arranged for seal cap 226.Seal cap 226 can be elasticity Circle.
Above-mentioned defining flange 2241 can be installed in the inner surface of convex column 224.As one kind more preferred embodiment, The inner chamber of convex column 224 is separated into the first sub- chamber and the second sub- chamber by defining flange 2241.First sub- chamber putting spring 225, the Two sub- chambers are with so that seal cap 226 is in the position for covering the inner chamber top end opening of convex column 224.
Waste water collection device 220 also includes the water proof ring being arranged between the opening of waste water lid 222 and waste water accommodating body 221 227.It thus is avoided that the water of waste water accommodating body 221 is spilt from the gap of the opening of waste water accommodating body 221.
Also slipmat 228 can be set in the outer surface of waste water lid 222, to cause hydrogen rich water is generated when machine 200 is placed not allow Easily slide.It should be noted that the thickness of slipmat 228 can not be too high, and otherwise when hydrogen-rich hydrogenesis machine 200 is placed, waste water The bottom of post 223 just will not be pressed.
Hydrogen-rich hydrogenesis machine 200 can also include being arranged on circuit board and power supply of support 210 etc..Power supply is to for hydrogen-oxygen Separating film module is powered.Circuit board realizes the electrical connection of power supply and hydrogen-oxygen separating film module, circuit board can be provided with to realize by The input current of power supply carries out the constant-current circuit of constant current, and to realize that the constant pressure that the input voltage of power supply is carried out into constant pressure is electric Road.Constant-current circuit and constant voltage circuit are using known technology.
It is above-mentioned not address part, it is adaptable to prior art.
Although more above used the term for representing structure, such as " permeable trapping film ", " hydrogen-producing region ", " oxygen generation Area " etc., but it is not precluded from the possibility using other terms.It is used for the purpose of more easily describing and explaining using these terms The essence of the present invention;Any additional limitation is construed as all to disagree with spirit of the present invention.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any Those familiar with the art the invention discloses technical scope in, change or replacement can be readily occurred in, should all be contained Cover within protection scope of the present invention.Therefore, protection scope of the present invention described should be defined by scope of the claims.

Claims (10)

1. a kind of hydrogen-rich hydrogenesis machine, it is characterised in that separated including support with the hydrogen-oxygen for being removably installed in the support Membrane module;The hydrogen-oxygen separating film module includes being provided with cathode sheets, anode strip in tank house, the tank house and is arranged at described Permeable trapping film between cathode sheets and anode strip, the cathode sheets, anode strip surround an electrolysis zone, and the permeable trapping film is used So that the electrolysis zone is separated into hydrogen-producing region and oxygen generation area.
2. hydrogen-rich hydrogenesis machine according to claim 1, it is characterised in that the permeable trapping film is from moistened membrane or micro- Filter membrane.
3. hydrogen-rich hydrogenesis machine according to claim 1, it is characterised in that the cathode sheets and anode strip are titanium sheet.
4. hydrogen-rich hydrogenesis machine according to claim 1, it is characterised in that the tank house includes base and upper lid, institute State base and upper lid covers to form the accommodating cavity of the accommodating cathode sheets, permeable trapping film and anode strip.
5. hydrogen-rich hydrogenesis machine according to claim 1, it is characterised in that the tank house also includes to install anode Piece and the anode installation lid being arranged at outside the electrolysis zone.
6. hydrogen-rich hydrogenesis machine according to claim 5, it is characterised in that the tank house also includes to install negative electrode Piece and the negative electrode installation lid being arranged at outside the electrolysis zone.
7. hydrogen-rich hydrogenesis machine according to claim 6, it is characterised in that the negative electrode installs lid and anode is installed and covers logical Cover to house cathode sheets, permeable trapping film and anode strip.
8. hydrogen-rich hydrogenesis machine according to claim 1, it is characterised in that also received including being arranged at the waste water of the support Acquisition means, the waste water collection device includes waste water accommodating body and to the waste water lid for the opening for covering the waste water accommodating body.
9. hydrogen-rich hydrogenesis machine according to claim 8, it is characterised in that the waste water collection device also includes being arranged at Waste water lid and with the convex column of inner chamber, the waste water post through the inner chamber of the convex column, be sheathed on the waste water post periphery Spring, be sheathed on waste water post top periphery the seal cap to seal convexity post inner chamber top end opening, the convex column Inner chamber is provided with defining flange, and the defining flange is used to when waste water post is pressed to top, make one end of spring abut limit Position flange, the other end, which abut the bottom of waste water post and depart from limited cap, covers convex column inner chamber top end opening.
10. hydrogen-rich hydrogenesis machine according to claim 8, it is characterised in that the waste water collection device also includes setting Water proof ring between the opening of waste water lid and waste water accommodating body.
CN201710254797.1A 2017-04-18 2017-04-18 Hydrogen-rich hydrogenesis machine Pending CN107032449A (en)

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Application Number Priority Date Filing Date Title
CN201710254797.1A CN107032449A (en) 2017-04-18 2017-04-18 Hydrogen-rich hydrogenesis machine

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Application Number Priority Date Filing Date Title
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105220173A (en) * 2015-09-07 2016-01-06 深圳市智慧水科技有限公司 A kind of portable rich hydrogen water generating device
CN206872487U (en) * 2017-04-18 2018-01-12 深圳氢爱天下健康科技控股有限公司 Hydrogen-rich hydrogenesis machine

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105220173A (en) * 2015-09-07 2016-01-06 深圳市智慧水科技有限公司 A kind of portable rich hydrogen water generating device
CN206872487U (en) * 2017-04-18 2018-01-12 深圳氢爱天下健康科技控股有限公司 Hydrogen-rich hydrogenesis machine

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Application publication date: 20170811