CN106894041A - Hydrogen-rich hydrogenesis machine with hydrogen-oxygen separation function - Google Patents
Hydrogen-rich hydrogenesis machine with hydrogen-oxygen separation function Download PDFInfo
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- CN106894041A CN106894041A CN201710254493.5A CN201710254493A CN106894041A CN 106894041 A CN106894041 A CN 106894041A CN 201710254493 A CN201710254493 A CN 201710254493A CN 106894041 A CN106894041 A CN 106894041A
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- hydrogen
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- connecting portion
- oxygen
- cathode sheets
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/02—Diaphragms; Spacing elements characterised by shape or form
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
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- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The invention provides the hydrogen-rich hydrogenesis machine with hydrogen-oxygen separation function, including cup and device for producing hydrogen, the device for producing hydrogen includes housing, cup connecting portion and hydrogen-oxygen separation assembly, and the cup connecting portion is arranged on the side of the housing, and the hydrogen-oxygen separation assembly is arranged in the housing；The hydrogen-oxygen separation assembly includes tank house, cathode sheets, anode strip and the permeable trapping film being arranged between the cathode sheets and anode strip are provided with the tank house, the cathode sheets, anode strip surround an electrolysis zone, the permeable trapping film is used to for the electrolysis zone to be separated into hydrogen-producing region and oxygen produces area, and the hydrogen-producing region connects the cup connecting portion.Permeable trapping film in the hydrogen-rich hydrogenesis machine can hydrogen to oxygen produce area diffusion and diffusion from oxygen to hydrogen-producing region, hydrogen enters cup, thus reached the separation of hydrogen and oxygen from cup connecting portion.
Description
Technical field
The making apparatus technical field of hydrogen rich water of the present invention, in particular to hydrogen-oxygen separation function
Hydrogen-rich hydrogenesis machine.
Background technology
Hydrogen rich water, as the term suggests it is exactly the water rich in hydrogen.English is hydrogen Rich water, and Japanese is " water element
Water ".Used as a kind of selective polyphenoils, hydrogen has therapeutic action to many diseases, before being widely used
Scape.
In recent years, hydrogen rich water, water element aquatic products are gradually more on domestic market, and hydrogen rich water, the cup of water element water also have finding, its
The technology of middle use electrolytic hydrogen production occupies significant proportion, including related patented technology is emerged in large numbers.In these electrolytic hydrogen production cups
And its in patented technology, it is common to have horizontally disposed electrode structure, such as Chinese patent:Application number 201510366113.8, application
Numbers 201510126957.5,201520051049.X etc.；Also there are the electrode structure arranged up and down, such as Chinese patent:Application number
201520786526.7 etc..Its product of electrode structure of both arrangements is through experiment or practical, it has been found that its not foot phenomenon.
In the prior art, the generally made hydrogen of hydrogen-rich hydrogenesis machine and oxygen Monodispersed are in water, it is impossible to realize hydrogen
The separation of gas and oxygen, such as Chinese patent CN106115866A disclose can a kind of point of air-flow hydrogen-rich hydrogenesis machine and its user
Method.The lid and cup body sealed bottom that the hydrogen-rich hydrogenesis machine cup is connected including cup body and cup body top side detachable formula are solid
Base, the electrolysis unit in cup body of fixed connection, are provided with power supply module, pcb board in base；It is provided with pcb board
Control circuit；Heating ring and temperature sensor are provided with the top of base；Lid includes water storehouse, is arranged on water storehouse bottom
Filter core and the bottle cap of water storehouse top side detachable formula connection；Bottle cap top is provided with a gas bleeder valve；Electrolysis unit includes one and bottom
Seat bottom connection electrode tip holder, the gas skirt at the top of electrode tip holder and from top to bottom be arranged on electrode tip holder on minus plate,
First division board, ionic membrane, the second division board, anode strip；Passage is offered on electrode tip holder below anode strip；Power supply mould
Block, temperature sensor, heating ring, minus plate, anode strip are connected with control circuit respectively.However, the water containing oxygen is drunk
Afterwards to accelerating the aging of human body body, certain potential hazard is produced to human body.
The content of the invention
In order to overcome the deficiencies in the prior art, the invention provides the hydrogen-rich hydrogenesis machine with hydrogen-oxygen separation function.Tool
Body ground, its technical scheme is as follows：
Hydrogen-rich hydrogenesis machine with hydrogen-oxygen separation function, including cup and device for producing hydrogen, the device for producing hydrogen include shell
Body, cup connecting portion and hydrogen-oxygen separation assembly, the cup connecting portion are arranged on the side of the housing, the hydrogen-oxygen separation group
Part is arranged in the housing；The hydrogen-oxygen separation assembly include tank house, be provided with the tank house cathode sheets, anode strip and
The permeable trapping film between the cathode sheets and anode strip is arranged at, the cathode sheets, anode strip surround an electrolysis zone, described
Water trapping film is used to for the electrolysis zone to be separated into hydrogen-producing region and oxygen produces area, and the hydrogen-producing region connects the cup connection
Portion.
Used as the improvement to technical scheme, the cup connecting portion has the interface of ladder cellular type, for matching various chis
The cup of very little type.
Used as the improvement to technical scheme, the device for producing hydrogen also includes the cap for closing the cup connecting portion,
The cap is removably disposed on the housing.
As the improvement to technical scheme, support is provided with the housing, the tank house is set on the bracket.
Used as the improvement to technical scheme, the cathode sheets, the permeable trapping film and the anode strip are sequentially overlapped and set
Put.
Used as the improvement to technical scheme, the permeable trapping film is ionic membrane, from moistened membrane or microfiltration membranes.
Used as the improvement to technical scheme, the cathode sheets and/or the anode strip are titanium sheet.
Used as the improvement to technical scheme, the tank house includes being covered on tank house base and tank house, the tank house
Cover to form the appearance of the accommodating cathode sheets, the permeable trapping film and the anode strip on base and the tank house
Put chamber.
Used as the improvement to technical scheme, the tank house is also included for installing anode strip and being arranged at the electrolysis
Anode outside area installs lid；
The tank house also includes installing lid for the negative electrode installed cathode sheets and be arranged at outside the electrolysis zone.
Used as the improvement to technical scheme, lid and the negative electrode are provided with some pads between installing lid on the tank house
Piece；
And/or, the anode strip and the anode are installed and be provided between lid anode seal circle, cathode sheets and described
Negative electrode is provided with negative electrode sealing ring between installing lid；
And/or, electrolysis chamber cap inner seal ring, the electricity are provided between being covered on the tank house base and the tank house
Electrolysis chamber cap exterior seal ring is provided with solution room between lid and the cup connecting portion.
The present invention at least has the advantages that：
In hydrogen manufacturing, the hydrogen-rich that cathode sheets are produced is produced in hydrogen-producing region, the oxygen concentration that anode strip is produced in oxygen
Area, permeable trapping film intercepted hydrogen to oxygen produce area diffusion and intercepted diffusion of the oxygen to hydrogen-producing region, hydrogen from
Cup connecting portion enters cup, has thus reached the separation of hydrogen and oxygen.
To enable the above objects, features and advantages of the present invention to become apparent, preferred embodiment cited below particularly, and coordinate
Appended accompanying drawing, is described in detail below.
Brief description of the drawings
Technical scheme in order to illustrate more clearly the embodiments of the present invention, below will be attached to what is used needed for embodiment
Figure is briefly described, it will be appreciated that the following drawings illustrate only certain embodiments of the present invention, thus be not construed as it is right
The restriction of scope, for those of ordinary skill in the art, on the premise of not paying creative work, can also be according to this
A little accompanying drawings obtain other related accompanying drawings.
Fig. 1 is the preceding diagram of device for producing hydrogen in hydrogen-rich hydrogenesis machine in the embodiment of the present invention；
Fig. 2 is the overall explosive view of device for producing hydrogen in hydrogen-rich hydrogenesis machine in the embodiment of the present invention；
Fig. 3 is the explosive view of hydrogen-oxygen separation assembly in the embodiment of the present invention；
Fig. 4 is the schematic diagram of cup connecting portion in the embodiment of the present invention；
Fig. 5 is the schematic diagram of embodiment of the present invention middle-jiao yang, function of the spleen and stomach pole piece.
Main element symbol description：
1000- device for producing hydrogen, 0110- shells, 0120- bases, 0130- caps, 0200- cup connecting portions, 0300- hydrogen-oxygens
Separation assembly, 0310- tank house bases are covered, 0331- anode strips, 0332- cathode sheets on 0320- tank houses, 0341- anodes peace
Capping, 0342- negative electrodes install lid, and 0351- anode seal circles, 0352- negative electrode sealing rings, 0353- is electrolysed chamber cap inner seal ring,
0354- is electrolysed chamber cap exterior seal ring, 0360- pads, the permeable trapping films of 0370-, 0400- control panels, 0500- supports.
Specific embodiment
Hereinafter, various embodiments of the present invention will be described more fully.The present invention can have various embodiments, and
Can wherein adjust and change.It should be understood, however, that：It is limited to spy disclosed herein in the absence of by various embodiments of the present invention
Determine the intention of embodiment, but should invention is construed as covering falling into the spirit and scope of various embodiments of the present invention
All adjustment, equivalent and/or alternative.
Hereinafter, can use in various embodiments of the present invention term " including " or " may include " indicate it is disclosed
Function, operation or the presence of element, and do not limit the increase of one or more functions, operation or element.Additionally, such as existing
Used in various embodiments of the present invention, term " including ", " having " and its cognate be meant only to represent special characteristic, number
The combination of word, step, operation, element, component or foregoing item, and be understood not to exclude first it is one or more other
The presence of the combination of feature, numeral, step, operation, element, component or foregoing item or increase one or more features, numeral,
The possibility of the combination of step, operation, element, component or foregoing item.
In various embodiments of the present invention, statement "or" or " at least one of A or/and B " include what is listed file names with
Any combinations of word or all combinations.For example, statement " A or B " or " at least one of A or/and B " may include A, may include
B may include A and B both.
The statement (" first ", " second " etc.) for using in various embodiments of the present invention can be modified in various implementations
Various element in example, but corresponding element can not be limited.For example, presented above be not intended to limit the suitable of the element
Sequence and/or importance.The purpose for being only used for differentiating an element and other elements presented above.For example, first user is filled
Put and indicate different user device with second user device, although the two is all user's set.For example, of the invention each not departing from
In the case of planting the scope of embodiment, the first element is referred to alternatively as the second element, and similarly, the second element is also referred to as first
Element.
It should be noted that：In the present invention, unless otherwise clearly regulation and definition, the art such as " installation ", " connection ", " fixation "
Language should be interpreted broadly, for example, it may be being fixedly connected, can also be detachably connected or be integrally connected；It can be machine
Tool is connected, or electrically connected；Can be directly connected to, also can be by intermediary and be indirectly connected to；It can be two
The connection of element internal.For the ordinary skill in the art, can as the case may be understand above-mentioned term at this
Concrete meaning in invention.
In the present invention, one of ordinary skill in the art is it is to be appreciated that indicating position or position relationship in text
Term be based on orientation shown in the drawings or position relationship, be for only for ease of description the present invention and simplify describe, without
Be indicate or imply meaning device or element must have specific orientation, with specific azimuth configuration and operation, therefore
It is not considered as limiting the invention.
The term for using in various embodiments of the present invention is only used for describing the purpose of specific embodiment and not anticipating
In limitation various embodiments of the present invention.As used herein, singulative is intended to also including plural form, unless context is clear
Chu ground is indicated otherwise.Unless otherwise defined, all terms (including the technical term and scientific terminology) tool being otherwise used herein
There is the implication identical implication being generally understood that with various embodiments of the present invention one skilled in the art.The term
(term limited such as in the dictionary for generally using) is to be interpreted as to be had and the situational meaning in correlative technology field
Identical implication and will be not construed as with Utopian implication or excessively formal implication, unless of the invention various
It is clearly defined in embodiment.
Embodiment 1
Refer to Fig. 1, there is provided the hydrogen-rich hydrogenesis machine with hydrogen-oxygen separation function, including cup (not shown) and
Device for producing hydrogen 1000.Device for producing hydrogen 1000 includes housing, and in the present embodiment, housing has multiple structural forms, and Fig. 1, Fig. 2 show
A kind of exemplary structure type is gone out, it includes shell 0110 and base 0120.
Device for producing hydrogen 1000 also includes cup connecting portion 0200, and cup connecting portion 0200 is arranged on the side of housing.Such as Fig. 2
Shown, when housing includes shell 0110, base 0120 and cap 0130, cup connecting portion 0200 is arranged on the direction of shell 0110
The side of cap 0130.
Preferably, as shown in figure 4, cup connecting portion 0200 has the interface of ladder cellular type, for matching sizes class
The cup of type.Specifically, the every one-level in the interface of ladder cellular type is designed with internal thread, screw threads at different levels can respectively with corresponding chi
The external screw thread of very little rim of a cup coordinates, to realize sealing.
As shown in Figure 2 and Figure 3, device for producing hydrogen 1000 also includes hydrogen-oxygen separation assembly 0300, and hydrogen-oxygen separation assembly is arranged on shell
In vivo.Specifically, hydrogen-oxygen separation assembly is arranged in the receiving space that shell 0110, base 0120 and cap 0130 are surrounded.
Specifically, hydrogen-oxygen separation assembly 0300 includes tank house, and cathode sheets 0332, the and of anode strip 0331 are provided with tank house
It is arranged at the permeable trapping film 0370 between cathode sheets 0332 and anode strip 0331.Cathode sheets 0332, anode strip 0331 surround one
Electrolysis zone, permeable trapping film 0370 is used to for electrolysis zone to be separated into hydrogen-producing region and oxygen produces area, and hydrogen-producing region connection cup connects
Socket part 0200.
In above-described embodiment, in hydrogen manufacturing, in hydrogen-producing region, anode strip 0331 is produced the hydrogen-rich that cathode sheets 0332 are produced
Raw oxygen concentration produces area in oxygen, and permeable trapping film 0370 has intercepted hydrogen and produced the diffusion in area to oxygen and intercepted oxygen
To the diffusion of hydrogen-producing region, the separation of hydrogen and oxygen has thus been reached.
Term " electrolysis zone " refers to the region passed through with electric current.Term " tank house " refers to the object for implementing electrolysis.It is cloudy
Pole piece 0332, anode strip 0331 and permeable trapping film 0370 are placed in tank house.
Above-mentioned permeable trapping film 0370 refers to the film with permeable trapping function.It should be noted that trapping refers to herein
The gas that isolation exists in the form of bubbles, rather than exist with molecular state.The mechanism of the hydrogen produced by electrolysis water is, in water
Hydrogen ion obtains electronics and reduction reaction occurs and produces gas phase in cathode sheets 0332, due to the interface between gas phase and water phase
Difference, so the hydrogen of production is dispersed in water with bubble hydrogen.Current density with negative electrode is 2~6mA/cm2, electrolysis at ambient pressure
As a example by being neutral with electrolysis water, the size of produced bubble hydrogen is distributed in 20~80 micrometer ranges in gaussian random.Anode
The oxygen that piece is produced also exists in the form of bubble, and with anodic current density be 2~6mA/cm2 and electrolysis is at ambient pressure
Example, produced bubble distribution is in 40~100 micrometer ranges.Therefore, the way of realization of permeable trapping film can have to cut
Size is stayed less than bubble hydrogen and any type of film of oxygen bubbles size, i.e., with retention size (or being filter opening) at 10 microns
Below.
Specifically, as one of which implementation method, permeable trapping film 0370 is ionic membrane.Ionic membrane be it is a kind of contain from
Subbase group, to the ion in solution have selection through ability polymeric membrane.Because general mainly use in application
Its ion-selective permeability, so also referred to as ion-selective permeability film.Ionic membrane in the present embodiment is have to hydrogen ion
There is the ionic membrane of selective penetrated property.
As other implementation method, permeable trapping film 0370 can for retention size (or being filter opening) 10 microns with
Under filter membrane.For example, microfiltration membranes.Microfiltration membranes refer to filter membrane of the filter opening footpath between 0.1~1 micron.Microfiltration membranes can be used
Inoranic membrane and organic high molecular layer.Inoranic membrane can be ceramic membrane and metal film.Organic high molecular layer can be natural polymer
Film and synthetic polymeric membrane, such as Kynoar (PVDF), polysulfones (PSF), polyacrylonitrile (PAN), polyvinyl chloride (PVC),
Polypropylene (PP) etc..Form according to film is divided into Flat Membrane, tubular membrane, rolled film and hollow-fibre membrane again；According to masking principle,
The preparation method of polymeric membrane is divided into leaching (dry-wet method), stretching hole forming method, phase inversion, thermic phase method, dip coating, spoke
According to method, surface chemical modification method, nuclear track method, power formation method etc., the preparation method of inoranic membrane mainly have sol-gel processing,
Sintering process, chemical precipitation method etc..Solvent understanding, uses the microfiltration membranes with insulating properties herein, preferably organic high
Molecule microfiltration membranes.Certainly, filter membrane can also use milipore filter etc..
Used as other implementation method, permeable trapping film 0370 is from moistened membrane.It is that liquid water can be allowed saturating from moistened membrane
Cross and film that other media cannot pass through.Hydrophilic substance (such as titanium dioxide, silica, three oxidations can be used from moistened membrane
The nafion films of two aluminum particulate doping and modifications).
In the present embodiment, cathode sheets 0332, permeable trapping film 0370 and the three of anode strip 0331 can not abut, and also may be used
Be three in the way of abutting, for example cathode sheets 0332, permeable trapping film 0370 and anode strip 0331 are sequentially overlapped setting.
Here, it refers to that multiple objects (such as film etc.) with Rotating fields use one that " superposition is set " may be appreciated
Fit in the stack manner on another one surface.Refer to that a surface of A sets B, B so that A, B, C, D are sequentially overlapped setting as an example
The surface that surface sets C, C sets D, i.e., according to a direction (such as from top to bottom), A, B, C, D are arranged in order.
Cathode sheets 0332 and anode strip 0331 can be titanium sheet.In order to strengthen the work of cathode sheets 0332 and anode strip 0331
Property, some oxides, such as Chinese patent CN104562078A can be coated on surface, specially：Coating is applied including at least bottom
Layer and face coat, primer coating include titanium oxide, iridium oxide and ru oxide, and face coat includes iridium oxide, ruthenium
The metal or oxide of one or two elements in oxide, titanium oxide and palladium, platinum.Ruthenium, iridium and titanium in primer coating
Molar percentage be：Ruthenium：Iridium：Titanium=30~50%：10~25%：30~45%；Ruthenium, iridium, titanium and palladium in face coat
Molar percentage is：Ruthenium：Iridium：Titanium：Palladium=30~50%：10~25%：30~45%：2.5~20%.Ruthenium in primer coating,
The molar percentage of iridium and titanium is：Ruthenium：Iridium：Titanium=30~50%：10~25%：30~45%；Ruthenium, iridium, titanium in face coat
Molar percentage with platinum is：Ruthenium：Iridium：Titanium：Platinum=30~50%：10~25%：30~45%：2.5~20%.Primer coating
The molar percentage of middle ruthenium, iridium and titanium is：Ruthenium：Iridium：Titanium=30~50%：10~25%：30~45%；Ruthenium in face coat,
The molar percentage of iridium, titanium, palladium and platinum is：Ruthenium：Iridium：Titanium：Palladium：Platinum=30~50%：10~25%：30~45%：2.5~
20%：2.5~20%.Also include Zirconium oxide in primer coating, the molar percentage of ruthenium, iridium, titanium and zirconium is in primer coating：
Ruthenium：Iridium：Titanium：Zirconium=30~50%：10~25%：30~45%：2~10%；In face coat ruthenium, iridium, titanium and palladium mole
Percentage is：Ruthenium：Iridium：Titanium：Palladium=30~50%：10~25%：30~45%：2.5~20%.Also include zirconium in primer coating
Oxide, ruthenium in primer coating：Iridium：The molar percentage of titanium and zirconium is：Ruthenium：Iridium：Titanium：Zirconium=30~50%：10~25%：30
~45%：2~10%；The molar percentage of ruthenium, iridium, titanium and platinum is in face coat, ruthenium：Iridium：Titanium：Platinum=30~50%：10
~25%：30~45%：2.5~20%.Also include Zirconium oxide, ruthenium in primer coating in primer coating：Iridium：Titanium and zirconium rub
Your percentage is ruthenium：Iridium：Titanium：Zirconium=30~50%：10~25%：30~45%：2~10%；Ruthenium in face coat, iridium, titanium,
The molar percentage of palladium and platinum is, ruthenium：Iridium：Titanium：Palladium：Platinum=30~50%：10~25%：30~45%：2.5~20%：2.5
~20%.The thickness of primer coating is 5~15 microns, and the thickness of face coat is 1~5 micron.
As shown in figure 5, cathode sheets 0332 and anode strip 0331 can be set porous, such as settable honeycomb, to ensure
The adequacy contacted with water.
Preferably, device for producing hydrogen 1000 also includes the cap 0130 for closing cup connecting portion, and cap 0130 is detachable
Be arranged on housing.When housing includes shell 0110 and base 0120, cap 0130 is removably disposed in shell 0110
On.In the present embodiment, by setting cap 0130, when cup is separated with device for producing hydrogen 1000, cap 0130 can be sealed
Cup connecting portion 0200, it is to avoid be contaminated inside device for producing hydrogen 1000.
Preferably, support 0500 is provided with the receiving space that shell 0110 and base 0120 are surrounded, tank house is arranged on
On support 0500.
Preferably, tank house includes lid 0320 on tank house base 0310 and tank house, tank house base 0310 and electrolysis
Lid 0320 covers to form the accommodating cavity of accommodating a cathode sheets 0332, anode strip 0331 and permeable trapping film 0370 on room.
Preferably, tank house also includes installing lid for installing anode strip 0331 and being arranged at the anode outside electrolysis zone
0341.Tank house also includes installing lid 0342 for installing cathode sheets 0332 and being arranged at the negative electrode outside electrolysis zone.Negative electrode is pacified
Capping 0342 and anode install lid 0341 and cover to house cathode sheets 0332, anode strip 0331 and permeable trapping film 0370.
Preferably, lid 0320 and negative electrode are provided with some pads 0360 between installing lid 0342 on tank house.By setting
Pad 0360 can play anti-skidding effect.
Preferably, anode strip 0331 and anode are provided with anode seal circle 0351, cathode sheets 0332 between installing lid 0341
Negative electrode sealing ring 0352 is provided with and negative electrode installation lid 0342 between.
Preferably, electrolysis chamber cap inner seal ring 0353 is provided with tank house base 0310 and tank house between lid 0320,
Electrolysis chamber cap exterior seal ring 0354 is provided with tank house between lid 0320 and cup connecting portion 0200.
In the present embodiment, on tank house base 0310 and tank house between lid 0320, and tank house internal structure
Install, removably can be used, to facilitate the replacing to cathode sheets 0332, anode strip 0331 and permeable trapping film 0370.
Dismountable mode, can be fastener, sliding part, shackle member.Herein, fastener can include flange part, spiro connecting piece etc..
The a kind of of above-mentioned shackle member can be enumerated and implement structure, specially：Shackle member includes being arranged at the card of the first installed part
The hole clipping of the second installed part is detained and is arranged at, the buckle is engaged with hole clipping.Buckle includes being arranged at the connection of the first installed part
Portion and the elastic clamping part positioned at connecting portion one end, around resilient holding section around hole clipping.Clamping part is a spheroid,
Buckle is hollow structure, to be formed with and educate hole from what connecting portion extended to clamping part, so as to allow first fastener to be squeezed
Shi Fasheng elastic deformations.Buckle can be integrally formed with the first installed part.Holding section is formed with multiple breach, and breach is by clamping part
Separate clamping is divided into, so that holding section produces elastic deformation when being acted on by external force.The diameter of block button hole is less than
The sphere diameter of clamping part.During clamping part insertion hole clipping, blocked block is subject to the thrust generation elastic deformation of clamping part to expand outwardly, and makes card
Buckle passes through block button hole.Clamping part passes through hole clipping, and blocked block and clamping part restore to the original state, and clamping part is barred from card by blocked block
Fixed with the second installed part with by the first installed part outside hole.Holding section end is formed with chamfering, to dismantle the first housing and
Clamping part is set to be easy to be back in hole clipping under external force during two installed parts.
Above-mentioned shackle member can also enumerate second implementation structure (not shown).Specially：Shackle member may include block tongue
And buckle.Block tongue includes the coupler body of the first draw-in groove, the second draw-in groove and the hook-type between the first draw-in groove and the second draw-in groove, and this
One draw-in groove, the second draw-in groove, hook and slot are the groove of the structure of elasticity.Buckle includes the first cutting, the second cutting and is inserted positioned at first
Hook and slot between bar, the second cutting.First draw-in groove, the second draw-in groove, hook and slot are the groove of elasticity.First draw-in groove, the second card
Groove, hook and slot are the groove of elasticity.When clamping of the block tongue to be realized with buckle, first cutting is inserted in the first draw-in groove, and second
Cutting is inserted in the second draw-in groove, and coupler body insertion hook and slot, the first draw-in groove, the second draw-in groove, the elasticity of hook and slot ensure the first cutting, second
Cutting and the close contact of coupler body and reached clamping effect.
Above-mentioned shackle member can also enumerate the third and implement structure (not shown).Specially：Shackle member may include deck
And block tongue, the deck and block tongue are engaged.In this, the shape of deck and block tongue is not particularly limited, the embodiment party of its structure
Formula has a lot.Wherein the first implementation method is the buckle for being applied to backpack strip.Specifically, deck includes a draw-in groove.Block tongue can
Be E fonts, that is to say, that the block tongue of the structure include the first cutting, the 3rd cutting, and positioned at the first cutting, the 3rd cutting it
Between the second cutting, the first cutting and the 3rd cutting are elastic construction, and the two can draw close to the second cutting under external force, remove
After pin external force, the two is returned to original position.Second cutting can be elastic construction, or non-resilient.With tongue structure pair
Ying Di, the front portion of draw-in groove will be wider than rear portion.Herein, " preceding " refers to along tongue approach axis.The anterior width outline of draw-in groove is less than slotting
The width of tongue, the rear portion width of draw-in groove will be significantly less than the width of tongue, during so may be such that block tongue insertion draw-in groove,
When enter to draw-in groove it is anterior when, the first cutting and the 3rd cutting are compressed and are drawn close to the second cutting, when enter to draw-in groove after
During portion, because the thickness of draw-in groove is open body, the first cutting and the 3rd cutting are outwards flicked and exposed outside with from deck automatically.Card
Groove when the buckle of block tongue to be realized and deck, by block tongue insert draw-in groove in, at this moment, the first cutting and the 3rd cutting are exposed to
Deck；When the dismounting of block tongue to be realized and deck, the first cutting and the 3rd cutting only need to be mediated with so that block tongue is extracted in card
Groove.
Sliding part may include to be arranged on sliding-tongue and coordinate for the slide rail of sliding-tongue slip with the sliding-tongue.The form of slide rail can be arranged
Two kinds are enumerated, the first is two parallel raised lines, and the sliding cavity snapped in for sliding-tongue is formed between raised line.In order that obtaining sliding-tongue more
Snap in sliding cavity well, sliding cavity is "convex" shaped, in this accordingly, sliding-tongue is also the "convex" shaped.Second of slide rail
Form is the slide opening for being opened in chassis interior.Similarly, preferably snapped in slide opening in order that obtaining sliding-tongue, slide opening is " convex " word
Shape, in this accordingly, sliding-tongue is also the "convex" shaped.At least one of sliding-tongue and slide rail can be elastic construction.That is, sliding-tongue is for can
The elastically-deformable material of generation is made, the rubber of the high elastic modulus with nitrile rubber, ethylene propylene diene rubber etc. as representative
Material, slide rail is rigid metal material.Or, slide rail is made by elastically-deformable material can occur, and sliding-tongue is rigid
Metal material.Or ground, it is made both at elastically-deformable material can occur.
Except this, the hydrogen-rich hydrogenesis machine in the present embodiment may also include such as the other structure members in this area, for example for
Source relevant control circuit needed for electrolysis (purpose based on constant current or constant pressure), support etc. are provided.No longer described in detail in this.
It is above-mentioned not address part, it is adaptable to prior art.
Although more above used the term for representing structure, such as " permeable trapping film ", " hydrogen-producing region ", " oxygen generation
Area " etc., but it is not precluded from using the possibility of other terms.It is used for the purpose of more easily describing and explaining using these terms
Essence of the invention；Any additional limitation is construed as all to be disagreed with spirit of the present invention.
It will be appreciated by those skilled in the art that accompanying drawing is a schematic diagram for being preferable to carry out scene, module in accompanying drawing or
Flow is not necessarily implemented necessary to the present invention.
It will be appreciated by those skilled in the art that module in device in implement scene can according to implement scene describe into
Row is distributed in the device of implement scene, it is also possible to carry out one or more dresses that respective change is disposed other than this implement scene
In putting.The module of above-mentioned implement scene can merge into a module, it is also possible to be further split into multiple submodule.
The invention described above sequence number is for illustration only, and the quality of implement scene is not represented.
Disclosed above is only several specific implementation scenes of the invention, but, the present invention is not limited to this, Ren Heben
What the technical staff in field can think change should all fall into protection scope of the present invention.
Claims (10)
1. there is the hydrogen-rich hydrogenesis machine of hydrogen-oxygen separation function, including cup and device for producing hydrogen, it is characterised in that the hydrogen manufacturing dress
Put including housing, cup connecting portion and hydrogen-oxygen separation assembly, the cup connecting portion is arranged on the side of the housing, the hydrogen
Oxygen separating component is arranged in the housing；
The hydrogen-oxygen separation assembly includes tank house, and cathode sheets, anode strip are provided with the tank house and the negative electrode is arranged at
Permeable trapping film between piece and anode strip, the cathode sheets, anode strip surround an electrolysis zone, and the permeable trapping film is used for will
The electrolysis zone is separated into hydrogen-producing region and oxygen produces area, and the hydrogen-producing region connects the cup connecting portion.
2. hydrogen-rich hydrogenesis machine according to claim 1, it is characterised in that the cup connecting portion has ladder cellular type
Interface, the cup for matching sizes type.
3. hydrogen-rich hydrogenesis machine according to claim 1 and 2, it is characterised in that the device for producing hydrogen is also included for sealing
The cap of the cup connecting portion is closed, the cap is removably disposed on the housing.
4. hydrogen-rich hydrogenesis machine according to claim 1, it is characterised in that support, the electricity are provided with the housing
Solution room is set on the bracket.
5. hydrogen-rich hydrogenesis machine according to claim 1, it is characterised in that the cathode sheets, the permeable trapping film and
The anode strip is sequentially overlapped setting.
6. hydrogen-rich hydrogenesis machine according to claim 1, it is characterised in that the permeable trapping film is ionic membrane, from increasing
Wet film or microfiltration membranes.
7. hydrogen-rich hydrogenesis machine according to claim 1, it is characterised in that the cathode sheets and/or the anode strip are
Titanium sheet.
8. hydrogen-rich hydrogenesis machine according to claim 1, it is characterised in that the tank house includes tank house base and electricity
Solution is covered on room, covered on the tank house base and the tank house with formed the accommodating cathode sheets, it is described it is permeable every
The accommodating cavity of air film and the anode strip.
9. hydrogen-rich hydrogenesis machine according to claim 8, it is characterised in that the tank house is also included for installing anode
Piece and the anode installation lid being arranged at outside the electrolysis zone；
The tank house also includes installing lid for the negative electrode installed cathode sheets and be arranged at outside the electrolysis zone.
10. hydrogen-rich hydrogenesis machine according to claim 9, it is characterised in that lid and negative electrode peace on the tank house
Some pads are provided between capping；
And/or, the anode strip and the anode are installed between covering and are provided with anode seal circle, the cathode sheets and the negative electrode
Install and be provided with negative electrode sealing ring between covering；
And/or, electrolysis chamber cap inner seal ring, the tank house are provided between being covered on the tank house base and the tank house
Electrolysis chamber cap exterior seal ring is provided between upper lid and the cup connecting portion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710254493.5A CN106894041A (en) | 2017-04-18 | 2017-04-18 | Hydrogen-rich hydrogenesis machine with hydrogen-oxygen separation function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710254493.5A CN106894041A (en) | 2017-04-18 | 2017-04-18 | Hydrogen-rich hydrogenesis machine with hydrogen-oxygen separation function |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106894041A true CN106894041A (en) | 2017-06-27 |
Family
ID=59196379
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710254493.5A Pending CN106894041A (en) | 2017-04-18 | 2017-04-18 | Hydrogen-rich hydrogenesis machine with hydrogen-oxygen separation function |
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| Country | Link |
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| CN (1) | CN106894041A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108467090A (en) * | 2018-02-26 | 2018-08-31 | 深圳市量子氢生物技术有限公司 | A kind of hydrogen-oxygen separation electrolysis unit and hydrogen-rich cup, hydrogen-rich water dispenser |
| CN113769208A (en) * | 2021-09-28 | 2021-12-10 | 广东喜玛拉雅氢能科技有限公司 | Hydrogen-rich water spraying device |
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| CN206872953U (en) * | 2017-04-18 | 2018-01-12 | 深圳氢爱天下健康科技控股有限公司 | Hydrogen-rich hydrogenesis machine with hydrogen-oxygen separation function |
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| EP1078411A1 (en) * | 1998-01-12 | 2001-02-28 | Microlin, L.C. | Storage-stable zinc anode-based electrochemical cell |
| JP2007270256A (en) * | 2006-03-31 | 2007-10-18 | Ebara Corp | Apparatus for producing hydrogen, method for producing hydrogen and fuel cell power generator |
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| CN108467090A (en) * | 2018-02-26 | 2018-08-31 | 深圳市量子氢生物技术有限公司 | A kind of hydrogen-oxygen separation electrolysis unit and hydrogen-rich cup, hydrogen-rich water dispenser |
| CN113769208A (en) * | 2021-09-28 | 2021-12-10 | 广东喜玛拉雅氢能科技有限公司 | Hydrogen-rich water spraying device |
| CN113769208B (en) * | 2021-09-28 | 2023-08-15 | 广东喜玛拉雅氢能科技有限公司 | Hydrogen-rich water spraying device |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 518000 Guangdong city of Shenzhen province Nanshan District Guangdong science and Technology Street South twelve Road No. 22 lifetech 24 storey building Applicant after: Shenzhen hydrogen Health Technology Holding Co., Ltd. Address before: 518000 Guangdong city of Shenzhen province Nanshan District Qianhai Shenzhen Hong Kong cooperation zone before the Bay Road No. 1 building 201 room A (located in Shenzhen Qianhai business secretary Co. Ltd.) Applicant before: Shenzhen hydrogen Health Technology Holding Co., Ltd. |
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| CB02 | Change of applicant information | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170627 |
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| RJ01 | Rejection of invention patent application after publication |