CN107031149A - A kind of super flexible fever tablet based on graphene - Google Patents

A kind of super flexible fever tablet based on graphene Download PDF

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Publication number
CN107031149A
CN107031149A CN201710292425.8A CN201710292425A CN107031149A CN 107031149 A CN107031149 A CN 107031149A CN 201710292425 A CN201710292425 A CN 201710292425A CN 107031149 A CN107031149 A CN 107031149A
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CN
China
Prior art keywords
pur
graphene
layer
fever tablet
super flexible
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710292425.8A
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Chinese (zh)
Inventor
周培
邓广才
朱小英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Chuan Ke Technology Co Ltd
Original Assignee
Chengdu Chuan Ke Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201710292425.8A priority Critical patent/CN107031149A/en
Publication of CN107031149A publication Critical patent/CN107031149A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024Woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54Yield strength; Tensile strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00Clothing

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  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of super flexible fever tablet based on graphene, including textile layer, substrate layer PUR, graphene film layer, electrode and encapsulated layer PUR, substrate layer PUR is above textile layer, graphene film layer is above substrate layer PUR, two electrodes are respectively arranged on above graphene film layer and are located at two ends respectively, and encapsulated layer PUR is located above two electrodes and covers two electrodes and graphene film layer comprehensively.The present invention regard this elastomer of PUR as the attachment substrate of graphene film and the encapsulation on whole fever tablet surface, and substrate layer PUR is attached to textile surface, reduce significantly planar stretch, make fever tablet that there is very excellent flex capability, suitable for the wearable product such as clothes, and washing machine cleaning can be placed directly in, significantly improve the ease of use of user.

Description

A kind of super flexible fever tablet based on graphene
Technical field
The present invention relates to a kind of flexible fever tablet, more particularly to a kind of super flexible fever tablet based on graphene.
Background technology
Wearable electronic product industry is in booming period, and fever tablet has also gradually been applied to the products such as clothes On, it is possible to achieve low-voltage long-time heating, some body illnesses of auxiliary treatment or for warming.
Existing fever tablet is heated usually using conductive metal material, is also had using novel conductive material such as graphene, nanometer Silver wire etc. is used as exothermic material, and these materials are generally required for being attached to harder substrate such as PET (poly terephthalic acid second two Alcohol ester) on sheet material, in order to avoid forming bending in use, cause conductive material damaged, the reliability of product is influenceed, so very Difficulty realizes excellent flex capability.
And for wearable application product such as clothes, the flexibility of fever tablet is important, and clothes are when changing clothes, Traditional fever tablet can only use specific cleaning way, or need to clean again after dismantling, to user using making troubles.
The content of the invention
The purpose of the present invention is that that a kind of flex capability is provided to solve the above problems is excellent and can be directly clear The super flexible fever tablet based on graphene washed.
The present invention is achieved through the following technical solutions above-mentioned purpose:
A kind of super flexible fever tablet based on graphene, including textile layer, substrate layer PUR, graphene film layer, Electrode and encapsulated layer PUR, the substrate layer PUR is above the textile layer, and the graphene film layer is set Above the substrate layer PUR, two electrodes are respectively arranged on above the graphene film layer and are located at respectively Two ends, the encapsulated layer PUR is located above two electrodes and covers two electrodes and the graphene comprehensively Film layer.
Specifically, the textile layer is terylene, polyamide fibre, pure cotton, viscose rayon, blending, spandex, fiber crops, Modal fibre It is one or more compound in dimension, composite filament, soybean fiber;Further, the textile layer is preferably woven fabric fabric, Its institutional framework is one or more compound in plain, twill, satin weave, jacquard weave, rib weave.
Specifically, the substrate layer PUR and encapsulated layer PUR be ethene and its copolymer analog, polyurethanes, It is one or more compound in polyamide-based, polyesters, amorphous state alpha-olefin copolymer species, TPO, phenylethylene;Institute The softening point temperature for stating encapsulated layer PUR is higher than the softening point temperature of the substrate layer PUR.
Preferably, the thickness of the substrate layer PUR and the encapsulated layer PUR is 1 μm of -2 ㎜;Further, institute The thickness for stating substrate layer PUR is more preferably 30 μm -200 μm, and the thickness of the encapsulated layer PUR is more preferably 10 μm -500 μm。
Preferably, the electrode is metal electrode or carbon electrode, the thickness of the electrode is 0.1 μm of -1mm;Further, The electrode is more preferably silver electrode, and the thickness of the electrode is more preferably 1 μm -50 μm.
The beneficial effects of the present invention are:
The present invention regard this elastomer of PUR as the attachment substrate of graphene film and the envelope on whole fever tablet surface Dress, and substrate layer PUR is attached to textile surface, significantly planar stretch is reduced, there is fever tablet very excellent Different flex capability, it is adaptable to the wearable product such as clothes, and washing machine cleaning can be placed directly in, significantly improve user Ease of use;Super flexible fever tablet of the present invention based on graphene can be made using ripe equipment and technique, It is easy to large-scale production and application.
Brief description of the drawings
Fig. 1 is the cross section structure diagram of the super flexible fever tablet of the present invention based on graphene.
Embodiment
The invention will be further described below in conjunction with the accompanying drawings:
Heated as shown in figure 1, the super flexible fever tablet of the present invention based on graphene includes textile layer 5, substrate layer Glue 4, graphene film layer 3, electrode 1 and encapsulated layer PUR 2, substrate layer PUR 4 is above textile layer 5, graphite Alkene film layer 3 is above substrate layer PUR 4, and two electrodes 1 are respectively arranged on above graphene film layer 3 and difference position In two ends, encapsulated layer PUR 2 is located above two electrodes 1 and covers two electrodes 1 and graphene film layer 3 comprehensively;Tool For body, textile layer 5 is terylene, polyamide fibre, pure cotton, viscose rayon, blending, spandex, fiber crops, Modal fibre, composite filament, soybean One or more compound in fiber, preferably woven fabric fabric, its institutional framework is plain, twill, satin weave, carried It is flower, one or more compound in rib weave;Substrate layer PUR 4 and encapsulated layer PUR 2 are ethene and its copolymerization One kind in species, polyurethanes, polyamide-based, polyesters, amorphous state alpha-olefin copolymer species, TPO, phenylethylene Or it is a variety of compound;The softening point temperature of encapsulated layer PUR 2 is higher than the softening point temperature of substrate layer PUR 4;Substrate layer heat The thickness of melten gel 4 and encapsulated layer PUR 2 is 1 μm of -2 ㎜;The thickness of substrate layer PUR 4 is more preferably 30 μm -200 μm, envelope The thickness of dress layer PUR 2 is more preferably 10 μm -500 μm;Electrode 1 is metal electrode or carbon electrode, preferably silver electrode, electrode Thickness be 0.1 μm of -1mm, preferably 1 μm -50 μm.
In order to illustrate the manufacturability of the super flexible fever tablet of the present invention based on graphene, its system is exemplified below Process is made, but following methods are conventional methods, are not the protection objects of the present invention.
With reference to Fig. 1, first pass through the mode of hot pressing, substrate layer PUR 4 is brought into close contact with textile layer 5 together with, so Afterwards substrate layer PUR 4 surface transfer graphene film layer 3, specifically, can using hot visbreaking glue as transfer medium, Graphene film layer 3 is shifted to the surface of substrate layer PUR 4 by corroding growth substrates method, it is thin in graphene after the completion of transfer The upper surface printing photocuring ag paste electrode of film layer 3, specifically, print thickness is 10 microns, and by ultraviolet light irradiation, is made Silver paste solidifies, and silver electrode 1 is formed after solidification;Then the side of hot pressing is passed through above electrode 1 and graphene film layer 3 Formula, laminating encapsulated layer PUR 2, hot pressing temperature now is higher than the softening temperature of encapsulated layer PUR 2, while being less than substrate layer The softening temperature of PUR 4, the super flexible fever tablet of the present invention based on graphene is obtained after laminating.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as The technical scheme that can be realized without creative work on the basis of above-described embodiment, is regarded as falling into patent of the present invention Rights protection scope in.

Claims (8)

1. a kind of super flexible fever tablet based on graphene, it is characterised in that:Including textile layer, substrate layer PUR, graphite Alkene film layer, electrode and encapsulated layer PUR, the substrate layer PUR is above the textile layer, the graphene Film layer is above the substrate layer PUR, and two electrodes are respectively arranged on above the graphene film layer simultaneously It is located at two ends respectively, the encapsulated layer PUR is located above two electrodes and covers two electrodes and institute comprehensively State graphene film layer.
2. the super flexible fever tablet according to claim 1 based on graphene, it is characterised in that:The textile layer is to wash It is one or more in synthetic fibre, polyamide fibre, pure cotton, viscose rayon, blending, spandex, fiber crops, Modal fibre, composite filament, soybean fiber It is compound.
3. the super flexible fever tablet according to claim 2 based on graphene, it is characterised in that:The textile layer is machine Woven fabric fabric, its institutional framework is one or more compound in plain, twill, satin weave, jacquard weave, rib weave.
4. the super flexible fever tablet according to claim 1 based on graphene, it is characterised in that:The substrate layer PUR It is ethene and its copolymer analog, polyurethanes, polyamide-based, polyesters, amorphous state alpha-olefin copolymer with encapsulated layer PUR It is one or more compound in species, TPO, phenylethylene;The softening point temperature of the encapsulated layer PUR is higher than institute State the softening point temperature of substrate layer PUR.
5. the super flexible fever tablet according to claim 4 based on graphene, it is characterised in that:The substrate layer PUR Thickness with the encapsulated layer PUR is 1 μm of -2 ㎜.
6. the super flexible fever tablet according to claim 5 based on graphene, it is characterised in that:The substrate layer PUR Thickness be 30 μm -200 μm, the thickness of the encapsulated layer PUR is 10 μm -500 μm.
7. the super flexible fever tablet according to claim 1 based on graphene, it is characterised in that:The electrode is metal electricity Pole or carbon electrode, the thickness of the electrode is 0.1 μm of -1mm.
8. the super flexible fever tablet according to claim 7 based on graphene, it is characterised in that:The electrode is silver electricity Pole, the thickness of the electrode is 1 μm -50 μm.
CN201710292425.8A 2017-04-28 2017-04-28 A kind of super flexible fever tablet based on graphene Pending CN107031149A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107702191A (en) * 2017-10-11 2018-02-16 苏州暖开智能地暖科技有限公司 A kind of graphene floor heating module
CN108066895A (en) * 2017-12-29 2018-05-25 广州烯旺智能科技有限公司 A kind of graphene physical therapy component and physical therapy energy cabin
CN108834241A (en) * 2018-04-25 2018-11-16 江苏工程职业技术学院 A kind of preparation method of super soft olefinic carbon Electric radiant Heating Film
TWI671453B (en) * 2018-09-14 2019-09-11 安炬科技股份有限公司 Method for manufacturing graphene conductive fabric
WO2020082498A1 (en) * 2018-10-26 2020-04-30 苏州市兴丰强纺织科技有限公司 3d inflated graphene heated warmth-retaining clothing

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CN101014218A (en) * 2007-01-30 2007-08-08 东华大学 Far infrared flexible surface heating element with high emissivity
TWM447058U (en) * 2011-03-31 2013-02-11 qi-sheng Huang Flexibly electric heater sheet
CN105764169A (en) * 2016-03-11 2016-07-13 江苏同创节能科技有限公司 Graphene electric cloth preparation method and application
CN105922669A (en) * 2016-05-10 2016-09-07 北京创新爱尚家科技股份有限公司 Graphene heating fabric and production method and system
CN106255238A (en) * 2016-02-04 2016-12-21 济南圣泉集团股份有限公司 A kind of Graphene thermo electric material and application thereof
CN206061180U (en) * 2016-08-20 2017-03-29 东莞市德鸿电器制品有限公司 For the chemical fibre matrix graphite alkene heating film of health product

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101014218A (en) * 2007-01-30 2007-08-08 东华大学 Far infrared flexible surface heating element with high emissivity
TWM447058U (en) * 2011-03-31 2013-02-11 qi-sheng Huang Flexibly electric heater sheet
CN106255238A (en) * 2016-02-04 2016-12-21 济南圣泉集团股份有限公司 A kind of Graphene thermo electric material and application thereof
CN105764169A (en) * 2016-03-11 2016-07-13 江苏同创节能科技有限公司 Graphene electric cloth preparation method and application
CN105922669A (en) * 2016-05-10 2016-09-07 北京创新爱尚家科技股份有限公司 Graphene heating fabric and production method and system
CN206061180U (en) * 2016-08-20 2017-03-29 东莞市德鸿电器制品有限公司 For the chemical fibre matrix graphite alkene heating film of health product

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107702191A (en) * 2017-10-11 2018-02-16 苏州暖开智能地暖科技有限公司 A kind of graphene floor heating module
CN108066895A (en) * 2017-12-29 2018-05-25 广州烯旺智能科技有限公司 A kind of graphene physical therapy component and physical therapy energy cabin
CN108834241A (en) * 2018-04-25 2018-11-16 江苏工程职业技术学院 A kind of preparation method of super soft olefinic carbon Electric radiant Heating Film
TWI671453B (en) * 2018-09-14 2019-09-11 安炬科技股份有限公司 Method for manufacturing graphene conductive fabric
US11313073B2 (en) 2018-09-14 2022-04-26 Enerage Inc. Method of manufacturing graphene conductive fabric
WO2020082498A1 (en) * 2018-10-26 2020-04-30 苏州市兴丰强纺织科技有限公司 3d inflated graphene heated warmth-retaining clothing

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Application publication date: 20170811

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