CN107022176A - A kind of 3D printing wood materials and preparation method thereof - Google Patents
A kind of 3D printing wood materials and preparation method thereof Download PDFInfo
- Publication number
- CN107022176A CN107022176A CN201610068060.6A CN201610068060A CN107022176A CN 107022176 A CN107022176 A CN 107022176A CN 201610068060 A CN201610068060 A CN 201610068060A CN 107022176 A CN107022176 A CN 107022176A
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The present invention provides a kind of 3D printing wood materials and preparation method thereof, it is characterised in that the component of the composite and the mass fraction of each component are as follows：70-100 parts of PLA；8-10 parts of wood powder；3-5 parts of compatilizer；2-5 parts of coupling agent；2-4 parts of lubricant；2-3 parts of glass microballoon；White 1-3 parts of mother.The material low-carbon environment-friendly, very circulation and stress it can recycle, can be produced when the natural friendliness with timber, printing natural wood aromatic odor, good stability of the dimension, not plug-hole, non-warpage, processing conditions requirement it is low, and the product weatherability such as have preferable physical and mechanical properties and acid and alkali-resistance, Anti-moth-eating, ultraviolet-resistent property ability strong.
Description
Technical field
The present invention relates to a kind of 3D printing consumptive material, specially 3D printing is prepared with wood materials.
Background technology
3D printing technique occurs having more than 20 years history so far, and the technology is based on discrete dynamics models principle, is a kind of advanced
Increases material manufacturing technology.Current existing 3D printing consumptive material is mainly single PLA, ABS, the material such as PVA, but above material is deposited
In the limitation of itself, the cost of PLA material is higher, material is easy for deformation, easy occluding device nozzle more than 55 DEG C；
ABS material is more sensitive to temperature and shear rate, and smell is heavy in process, yielding and weatherability is poor；And PVA is water-soluble
Material is mainly used in printing support type material, and consumption is few, and can produce toxic gas during PVA decomposition.And tradition 3D printing is wooden
Material, exist wood powder be easily carbonized blocking printing plug, the shortcomings of product is more crisp.In a word, widely used 3D in the market
Printing consumables has the shortcomings that price height, high energy consumption, complicated harsh, the difficult shaping of processing conditions requirement, easy fracture.
It is, thus, sought for a kind of 3D printing consumptive material, it is not only cheap, green low-carbon environment-friendly, good stability of the dimension,
Intensity is high, have the advantages that in process not plug-hole, not fracture of wire, without buckling deformation, and the product produced have it is preferable
Physical and mechanical properties and weatherability.
The content of the invention
For the problems of above-mentioned prior art, it is an object of the invention to provide a kind of cheap, low-carbon environment-friendly,
It circulation and stress can very recycle, natural wood aromatic odor, size can be produced when the natural friendliness with timber, printing
Stability is good, not plug-hole, non-warpage, processing conditions require low, and product have preferable physical and mechanical properties and acid and alkali-resistance,
The 3D printing consumptive material of weatherability and preparation method thereof such as Anti-moth-eating, ultraviolet-resistent property ability be strong.
To reach above-mentioned purpose, the technical solution adopted in the present invention is：
One kind is used for 3D printing environment-friendly materials, it is characterised in that the component of the composite and the mass fraction of each component are such as
Under：70-100 parts of PLA；8-10 parts of wood powder；3-5 parts of compatilizer；2-5 parts of coupling agent；2-4 parts of lubricant；2-3 parts of glass microballoon；
White 1-3 parts of mother.
As preferred technical scheme is invented, PLA is melt index 2-9 PLA.
As preferred technical scheme is invented, wood powder particle diameter is 80-200 mesh.
As preferred technical scheme is invented, compatilizer is that maleic anhydride is grafted PLA compatilizers；Described coupling agent is silicon
One kind in alkane coupling agent；Described lubricant is paraffin, Tissuemat E, ethylene bis stearic acid amide, ethylene-acrylic acid copolymer
The mixture of two or more in thing, stearic acid, zinc stearate；Described toughener is poly- (hexanedioic acid-succinic acid) fourth two
Alcohol copolyesters.
Present invention also offers a kind of preparation method for 3D printing wood materials, it is characterised in that the tool of this method
Body step is as follows：
1) wood powder is put into microwave dryer and dried more than 6 hours with 70 DEG C -80 DEG C of temperature, its water content is down to 1%
Below；
2) wood powder being dried to obtain, glass microballoon, coupling agent are added in high-speed mixer and carry out activation process, be sufficiently mixed
5-8 minutes, obtain mixture；
3) mixture obtained in step 2 is added to double-cone type and mixed with PLA, compatilizer, lubricant, glass microballoon, white mother
50 minutes are mixed in conjunction machine to being uniformly dispersed, premix is obtained；
4) premix made from step 3 is added into 3D printing production line and extrudes wire drawing, control a diameter of 1.75mm of silk material.Wherein
Charge door is followed successively by the barrel heat temperature in each area of head：One 150 DEG C -160 DEG C of area, 160 DEG C -170 DEG C of 2nd area, three areas 170
DEG C -180 DEG C, 160 DEG C -170 DEG C of 4th area；
The present invention's has advantages below for bio-based wood materials of 3D printing and preparation method thereof：
1) wood powder is added in component and causes the characteristics of product has timber, the i.e. fragrance with timber, can followed closely, can bore, can dig, can
Japanning；
2) wood powder is added in component, the raw material sources are wide, easily reclaimed, it is degradable therefore with low cost；, can be with and draw ratio is big
Significantly improve the dimensional stability and mechanical property of product；
3) in composite preparation process, according to the physical property of different component, different mixing apparatus are selected to carry out in two times
Mixing, is conducive to the surface active of wood powder and inorganic matter, improves the interface compatibility of material；
Embodiment
Embodiment one
The wood powder of 10 part of 100 mesh is weighed by mass fraction, is put into microwave dryer and is dried 6 hours with 70 DEG C of temperature, made
Its water content is down to 1%；By be dried to obtain 10 parts of wood powders；4 parts of silane couplers are added in high-speed mixer and carried out at activation
Reason, is sufficiently mixed 10 minutes, obtains mixture；PLA, 5 parts of maleic anhydride grafting PLA by said mixture, melt index for 5
Lubricant, 2 parts of poly- (succinic acid of the hexanedioic acid one) butanediols of the double stearic acid phthalein amine mixing of compatilizer, 2 parts of Tissuemat Es and ethylene
Copolyesters toughener, which is added in duoble cone-type blender, mixes 50 minutes to being uniformly dispersed, and obtains premix；Will be obtained above
Premix carries out extrusion wire drawing, controls a diameter of 1.75mm of silk material；Wherein barrel heat temperature of the charge door to each area of head
It is followed successively by：One 150 DEG C -160 DEG C of area, 160 DEG C -170 DEG C of 2nd area, 170 DEG C -180 DEG C of 3rd area, 160 DEG C -170 DEG C of 4th area；It is described
Silk material is wound into finished product after being cooled down by tank into coil winder.
Claims (5)
1. a kind of 3D printing wood materials and preparation method thereof, it is characterised in that the component of the composite and each component
Mass fraction is as follows：70-100 parts of PLA；8-10 parts of wood powder；3-5 parts of compatilizer；2-5 parts of coupling agent；2-4 parts of lubricant；Glass
2-3 parts of microballon；White 1-3 parts of mother.
2. according to claim 1 be used for 3D printing wood materials, it is characterised in that：Described PLA is melt index
2-9 PLA.
3. according to claim 1 be used for 3D printing wood materials, it is characterised in that：Described wood powder particle diameter is 80-
200 mesh.
4. according to claim 1 be used for 3D printing wood materials, it is characterised in that：Described compatilizer is maleic acid
Acid anhydride is grafted PLA compatilizers；Described coupling agent is one kind in silane coupler；Described lubricant be paraffin, Tissuemat E,
The mixture of two or more in ethylene bis stearic acid amide, ethene-olefin(e) acid copolymer, stearic acid, zinc stearate.
5. the preparation method for 3D printing wood materials according to any one of claim 1, it is characterised in that should
Method is comprised the following steps that：
1) wood powder is put into microwave dryer and dried more than 6 hours with 70 DEG C -80 DEG C of temperature, its water content is down to 1%
Below；
2) wood powder being dried to obtain, coupling agent are added in high-speed mixer and carry out activation process, be sufficiently mixed 5-8 minutes,
Obtain mixture；
3) mixture obtained in step 2 is added to double-cone type and mixed with PLA, compatilizer, lubricant, glass microballoon, white mother
50 minutes are mixed in conjunction machine to being uniformly dispersed, premix is obtained；
4) premix made from step 3 is added into 3D printing production line and extrudes wire drawing, control a diameter of 1.75mm of silk material, wherein
Charge door is followed successively by the barrel heat temperature in each area of head：One 150 DEG C -160 DEG C of area, 160 DEG C -170 DEG C of 2nd area, three areas 170
DEG C -180 DEG C, 160 DEG C -170 DEG C of 4th area.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610068060.6A CN107022176A (en) | 2016-02-01 | 2016-02-01 | A kind of 3D printing wood materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610068060.6A CN107022176A (en) | 2016-02-01 | 2016-02-01 | A kind of 3D printing wood materials and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107022176A true CN107022176A (en) | 2017-08-08 |
Family
ID=59525142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610068060.6A Pending CN107022176A (en) | 2016-02-01 | 2016-02-01 | A kind of 3D printing wood materials and preparation method thereof |
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| CN (1) | CN107022176A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110105735A (en) * | 2019-06-04 | 2019-08-09 | 东莞职业技术学院 | 3D printing polydactyl acid wood flour composite material and preparation method |
| CN111630116A (en) * | 2018-01-07 | 2020-09-04 | 耶路撒冷希伯来大学伊森姆研究发展有限公司 | Wood paste and object made of wood paste |
| CN115558265A (en) * | 2022-10-13 | 2023-01-03 | 东北林业大学 | 3D printing human organ model material with steel toughness and manufacturing method thereof |
-
2016
- 2016-02-01 CN CN201610068060.6A patent/CN107022176A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111630116A (en) * | 2018-01-07 | 2020-09-04 | 耶路撒冷希伯来大学伊森姆研究发展有限公司 | Wood paste and object made of wood paste |
| CN111630116B (en) * | 2018-01-07 | 2022-10-04 | 耶路撒冷希伯来大学伊森姆研究发展有限公司 | Wood paste and object made of wood paste |
| CN110105735A (en) * | 2019-06-04 | 2019-08-09 | 东莞职业技术学院 | 3D printing polydactyl acid wood flour composite material and preparation method |
| CN115558265A (en) * | 2022-10-13 | 2023-01-03 | 东北林业大学 | 3D printing human organ model material with steel toughness and manufacturing method thereof |
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| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170808 |
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| WD01 | Invention patent application deemed withdrawn after publication |