CN106996035A - Fabric with conductive flame retardant coating and preparation method thereof - Google Patents
Fabric with conductive flame retardant coating and preparation method thereof Download PDFInfo
- Publication number
- CN106996035A CN106996035A CN201710160762.1A CN201710160762A CN106996035A CN 106996035 A CN106996035 A CN 106996035A CN 201710160762 A CN201710160762 A CN 201710160762A CN 106996035 A CN106996035 A CN 106996035A
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- Prior art keywords
- fabric
- flame retardant
- conductive flame
- retardant coating
- preparing
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/20—Graphene characterized by its properties
- C01B2204/22—Electronic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Abstract
The present invention relates to a kind of method for preparing the fabric with conductive flame retardant coating, comprise the following steps：The graphene oxide hydrosol that concentration is 20 30mg/mL is provided；The graphene oxide hydrosol is coated to fabric face, the fabric with graphite oxide ene coatings is obtained；Fabric with graphite oxide ene coatings is impregnated in the aqueous solution of reducing agent, raw reduction reaction is issued at 80 95 DEG C, graphene oxide is reduced into graphene, the fabric with conductive flame retardant coating is obtained.Present invention also offers the fabric with conductive flame retardant coating prepared by a kind of use above method.Using the method for the present invention, splendid electric conductivity and fire resistance are assigned simultaneously to common fabric, the fabric after processing is the excellent material for preparing fire-retardant wearable device.What the present invention was provided has the fabric preparation method of conductive flame retardant coating simple, safety, environmental protection, is adapted to produce in enormous quantities.
Description
Technical field
The present invention relates to functional textile material manufacture technical field, more particularly to a kind of knitting with conductive flame retardant coating
Thing and preparation method thereof.
Background technology
Intelligent textile is that, by electronic information, computer technology and the communication technology are integrated in textile, assigns textile
Intelligentize and informatization function.Wearable device is a big end product of intelligent textile, in fashionable dress, sports, medical treatment
The fields such as health care suffer from being widely applied.With the progress of science and technology and society, flame-retardancy requirements of the mankind to wearable device
More and more higher.For example：The wearable device that fireman uses, and technical staff prohibit what is used in the operation workshop of fire in ban on opium-smoking and the opium trade
Wearable device, all there is higher flame-retardancy requirements to wearable device.Therefore, fabric of the exploitation with conductive flame retardant coating comes
Preparing fire-retardant wearable device has broad mass market prospect.
Currently, preparing the fabric with conductive flame retardant coating typically has two methods.One exactly adds functional material
Enter into spinning solution, using the method for spinning, prepare functional fiber, then by fibrage into fabric, prepare feature and spin
Fabric.The second is the technology processed using Final finishing, directly arranges functional material to fabric face, assigns fabric functional
Property.Improve unobvious using the fabric functional prepared by the former method, and complex process, long flow path.And use the latter
Prepared fabric, feature improves notable, and technique is simple, flow is short.Wherein, coating is during fabric post-treatment is processed
A kind of very important method, its utilization rate to functional coat agent is high, and the feature of fabric improves notable, and technique is simple,
It is easily operated.Therefore, it is a very effective approach to prepare the fabric with conductive flame retardant coating using coating.
Graphene is a kind of emerging carbon material, and it has excellent electric conductivity and fire resistance simultaneously, if can be by
Graphene is arranged onto fabric, it is possible to which once arranging makes fabric obtain two kinds of functions.But, currently rarely use stone both at home and abroad
Black alkene carries out the relevant report of anti-flaming function arrangement to fabric.And the technology of conducting function arrangement is carried out to fabric using graphene
In, it is typically that the fabric for needing to arrange is immersed in graphene oxide dispersion, conductive fabric is obtained after reduction drying.But
That this method has some shortcomings, fabric can only absorb minimal amount of graphene, and graphene it is less when, the electric conductivity of fabric
It cannot significantly improve, it is impossible to reach use requirement.And if increasing stone by way of adding crosslinking agent or adhesive
Adsorbance of the black alkene on fabric, can have a strong impact on the feel of fabric.
How graphene is arranged onto fabric using suitable method for sorting, fabric can be while obtain after once arranging
Conductive and anti-flaming function；And how substantially to play the excellent properties of graphene has knitting for conductive flame retardant coating to prepare
Thing material, is functional textile material manufacture technical field urgent problem to be solved.
The content of the invention
In order to solve the above technical problems, it is an object of the invention to provide a kind of fabric with conductive flame retardant coating and its system
Preparation Method, using the method for the present invention, splendid electric conductivity and fire resistance is assigned to common fabric, the present invention is provided simultaneously
The fabric preparation method with conductive flame retardant coating it is simple, safety, environmental protection is adapted to produce in enormous quantities.
The invention provides a kind of method for preparing the fabric with conductive flame retardant coating, comprise the following steps：
(1) the graphene oxide hydrosol that concentration is 20-30mg/mL is provided；
(2) the graphene oxide hydrosol for obtaining step (1) is coated to fabric face, obtains applying with graphene oxide
The fabric of layer；
(3) fabric with graphite oxide ene coatings that step (2) is obtained is impregnated in the aqueous solution of reducing agent,
80-95 DEG C issues raw reduction reaction, graphene oxide is reduced into graphene, obtains the fabric with conductive flame retardant coating.
Further, in step (1), graphene oxide is prepared using Hummers methods are improved.
Using natural flake graphite as raw material, graphene oxide is prepared using Hummers methods are improved, after washing, dialysis 3-7 days
Obtain the graphene oxide hydrosol.The molecular cut off of the bag filter used during dialysis is 8000-14000Da.
Further, in step (2), it is coated using coating machine, coating speed is 0.2cm/s-1cm/s, coating
Thickness is 0.05mm-0.25mm.
Further, coating machine includes bracket and the scraper positioned at bracket one end, and fabric is fixed on bracket, graphite oxide
The alkene hydrosol is evenly applied to the surface of fabric under the drive of scraper.
Further, in step (2), the step of being additionally included at 60 DEG C -120 DEG C the fabric after drying coating.
Further, in step (2), dual coating is carried out to fabric.One side coating, Ran Hou are carried out first to fabric
Dried at 60 DEG C -120 DEG C, then the coating of another side is carried out to it, then dried at 60 DEG C -120 DEG C.
Further, in step (2), fabric is cotton and/or silk fabric.
Further, in step (3), reducing agent is glucose and/or L-AA, and such reducing agent is nontoxic, and
Environmental protection.
Further, in step (3), the concentration of the aqueous solution of reducing agent is 0.10mol/L-0.30mol/L.
Further, in step (3), according to 1:50-200 bath raio carries out reduction reaction.
Further, in step (3), the reduction reaction time is 1.5h-2.5h.
Present invention also offers the fabric with conductive flame retardant coating prepared by a kind of use above method.
By such scheme, the present invention at least has advantages below：
Using coating process, the graphene oxide hydrosol of high concentration is arranged onto fabric；, will again by reduction reaction
Graphene oxide is reduced into graphene, assigns fabric conduction and anti-flaming function.Fabric after arrangement is provided simultaneously with splendid conduction
Performance and fire resistance, such fabric are the excellent materials for preparing fire-retardant wearable device.The preparation that the present invention is provided has
The method of the fabric of conductive flame retardant coating is simple, and environmental protection is safe and efficient.
Brief description of the drawings
Fig. 1 is the scanning electron microscope (SEM) photograph of the silk fabric of the method processing without the present invention；
Fig. 2 is the scanning electron microscope (SEM) photograph of conductive flame-retardant silk fabric prepared by embodiment 8；
Fig. 3 is the photo in kind after conductive flame-retardant silk fabric connection LED bulb prepared by embodiment 8.
Embodiment
With reference to the accompanying drawings and examples, the embodiment to the present invention is described in further detail.Implement below
Example is used to illustrate the present invention, but is not limited to the scope of the present invention.
Embodiment 1
Using natural flake graphite as raw material, graphene oxide is prepared using Hummers methods are improved, after washing, from retention
Molecular weight is 8000-14000Da bag filter, and dialysis obtains the graphene oxide hydrosol that concentration is 25mg/mL after 3-7 days.
Wherein, Hummers method reference literatures are improved：Marcano D.C.,et al.,Improved synthesis of graphene
Oxide, ACS Nano, 4 (2010), the method in 8, pp.4806-4814 are carried out.
Common bafta is cut into 20cm × 40cm sizes, on the bracket for being fixed on coating small model machine, and by above-mentioned system
The standby graphene oxide hydrosol is placed in one end of scraper, is uniformly knitted the graphene oxide hydrosol to cotton by the motion of scraper
The surface of thing carries out one side coating, and the speed (i.e. coating speed) of wherein scraper motion is 0.2cm/s, and regulation coating layer thickness is
0.05mm, 100 DEG C of baking 10min of air dry oven are placed in by the fabric after coating.
Then it will be placed in after the positive and negative inversion of bafta after above-mentioned one side coating on coating small model machine bracket, by graphite oxide
The alkene hydrosol is uniformly inverted in scraper one end, and regulation coat speeds are 0.2cm/s, and coating layer thickness is 0.05mm.Will be two-sided equal
The fabric for being coated with the graphene oxide hydrosol is placed in 100 DEG C of baking 10min of air dry oven.Thus obtaining coating layer thickness is
0.05mm graphene oxide coated cotton fibers.
0.25mol/L insurance amidin is configured, according to 1：100 bath raio, above-mentioned graphite oxide ene coatings cotton is knitted
Thing is impregnated in insurance amidin, is reacted 2h at 90 DEG C, graphene oxide is reduced into graphene, by reducing process, obtains
To the conductive fire proofing of graphene coated cotton fibers.
Embodiment 2
Coating layer thickness is adjusted to 0.1mm by the present embodiment, and other techniques are same as Example 1, obtains graphite ene coatings
Bafta conduction fire proofing.
Embodiment 3
Coating layer thickness is adjusted to 0.2mm by the present embodiment, and other techniques are same as Example 1, obtains graphite ene coatings
Bafta conduction fire proofing.
Embodiment 4
Coating layer thickness is adjusted to 0.25mm by the present embodiment, and other techniques are same as Example 1, obtains graphite ene coatings
Bafta conduction fire proofing.
Embodiment 5
Fabric is changed to silk fabric by the present embodiment, and other techniques are same as Example 1, obtains graphite ene coatings silk
Fabric conduction fire proofing.
Embodiment 6
Fabric is changed to silk fabric by the present embodiment, and coating layer thickness is adjusted into 0.1mm, and other techniques are and embodiment
1 is identical, obtains the conductive fire proofing of graphite ene coatings silk fabric.
Embodiment 7
Fabric is changed to silk fabric by the present embodiment, and coating layer thickness is adjusted into 0.2mm, and other techniques are and embodiment
1 is identical, obtains the conductive fire proofing of graphite ene coatings silk fabric.
Embodiment 8
Fabric is changed to silk fabric by the present embodiment, and coating layer thickness is adjusted into 0.25mm, other techniques with implementation
Example 1 is identical, obtains the conductive fire proofing of graphite ene coatings silk fabric.
The electric conductivity of each graphene coated fabric obtained in above-described embodiment 1-8 is tested using four probe sheet resistance testers
Energy；Then the fire resistance of above-mentioned each graphene coated fabric, each embodiment test result table 1 are tested by limited oxygen index instrument
It is shown.
The physical parameter of the graphene coated fabric of table 1 conduction fire proofing
| Fabric texture | Coating layer thickness (mm) | Sheet resistance (Ω/sq) | Limited oxygen index (%) | |
| Embodiment 1 | Cotton | 0.05 | 4200 | 21.2 |
| Embodiment 2 | Cotton | 0.1 | 900 | 21.8 |
| Embodiment 3 | Cotton | 0.2 | 530 | 26.6 |
| Embodiment 4 | Cotton | 0.25 | 198 | 29.8 |
| Embodiment 5 | Silk | 0.05 | 3600 | 28.8 |
| Embodiment 6 | Silk | 0.1 | 700 | 29.6 |
| Embodiment 7 | Silk | 0.2 | 344 | 37.5 |
| Embodiment 8 | Silk | 0.25 | 131 | 43.5 |
As it can be seen from table 1 using the method processing fabric of the present invention, fabric can be arranged once while obtaining excellent
Fire resistance and electric conductivity, such fabric are the elite clones for preparing fire-retardant wearable device.In addition, with coating layer thickness
Increase, the sheet resistance of fabric is gradually reduced, and the limited oxygen index of fabric gradually rises.Wherein embodiment 8 obtains graphite
Ene coatings silk fabric, sheet resistance only has 131 Ω/sq, and limited oxygen index is up to 43.5%, shows that the fabric possesses splendid
Electric conductivity and fire resistance.
Fig. 1 is the scanning electron microscope (SEM) photograph of 100 times of the amplification of the silk fabric of the method processing without the present invention；Fig. 2 is to implement
The scanning electron microscope (SEM) photograph of 100 times of the amplification of conductive flame-retardant silk fabric prepared by example 8.Comparison diagram 1 and Fig. 2 can have found that graphene is passed through
Uniform adsorption is on the surface of fabric after top finish.
Fig. 3 is conductive flame-retardant silk fabric connection LED bulb photo in kind prepared by embodiment 8.Under 3V voltages, this hair
Conductive flame-retardant silk fabric prepared by bright embodiment 8 can make LED bulb work as wire.Illustrate the conductive flame-retardant silk
Fabric, which possesses, splendid electric conductivity.
Described above is only the preferred embodiment of the present invention, is not intended to limit the invention, it is noted that for this skill
For the those of ordinary skill in art field, without departing from the technical principles of the invention, can also make it is some improvement and
Modification, these improvement and modification also should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of method for preparing the fabric with conductive flame retardant coating, it is characterised in that comprise the following steps：
(1) the graphene oxide hydrosol that concentration is 20-30mg/mL is provided；
(2) the graphene oxide hydrosol that step (1) is obtained is coated to fabric face, obtains applying with graphene oxide
The fabric of layer；
(3) fabric with graphite oxide ene coatings that step (2) is obtained is impregnated in the aqueous solution of reducing agent,
80-95 DEG C issues raw reduction reaction, graphene oxide is reduced into graphene, obtains the knitting with conductive flame retardant coating
Thing.
2. the method according to claim 1 for preparing the fabric with conductive flame retardant coating, it is characterised in that：In step
(1) in, graphene oxide is prepared using Hummers methods are improved.
3. the method according to claim 1 for preparing the fabric with conductive flame retardant coating, it is characterised in that in step
(2) in, it is coated using coating machine, coating speed is 0.2cm/s-1cm/s, coating layer thickness is 0.05mm-0.25mm.
4. the method according to claim 3 for preparing the fabric with conductive flame retardant coating, it is characterised in that：The coating
Machine includes bracket and the scraper positioned at described bracket one end, and the fabric is fixed on bracket, the graphene oxide hydrosol
The surface of fabric is evenly applied under the drive of scraper.
5. the method according to claim 1 for preparing the fabric with conductive flame retardant coating, it is characterised in that：In step
(2) in, the step of being additionally included at 60 DEG C -120 DEG C the fabric after drying coating.
6. the method according to claim 1 for preparing the fabric with conductive flame retardant coating, it is characterised in that：In step
(2) in, the fabric is cotton and/or silk fabric.
7. the method according to claim 1 for preparing the fabric with conductive flame retardant coating, it is characterised in that：In step
(3) in, the reducing agent is sodium hydrosulfite and/or L-AA.
8. the method according to claim 1 for preparing the fabric with conductive flame retardant coating, it is characterised in that：In step
(3) in, the concentration of the aqueous solution of the reducing agent is 0.10mol/L-0.30mol/L.
9. the method according to claim 1 for preparing the fabric with conductive flame retardant coating, it is characterised in that：In step
(3) in, according to 1:50-200 bath raio carries out reduction reaction.
10. the fabric with conductive flame retardant coating prepared by a kind of any one of claim 1-9 method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710160762.1A CN106996035A (en) | 2017-03-17 | 2017-03-17 | Fabric with conductive flame retardant coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710160762.1A CN106996035A (en) | 2017-03-17 | 2017-03-17 | Fabric with conductive flame retardant coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN106996035A true CN106996035A (en) | 2017-08-01 |
Family
ID=59431099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201710160762.1A Pending CN106996035A (en) | 2017-03-17 | 2017-03-17 | Fabric with conductive flame retardant coating and preparation method thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107541934A (en) * | 2017-09-04 | 2018-01-05 | 西南大学 | Conductive silk fabric is prepared with the NMMO aqueous solution |
| CN107724070A (en) * | 2017-10-20 | 2018-02-23 | 浙江剑利美针织服饰有限公司 | A kind of graphene fabric and preparation method thereof |
| CN108867031A (en) * | 2018-07-30 | 2018-11-23 | 青岛大学 | A method of improving graphene adhesion amount and electric conductivity on cotton fabric |
| CN109576983A (en) * | 2019-01-04 | 2019-04-05 | 张永奇 | A kind of graphene oxide coated polyester fabric and preparation method thereof |
| CN109594328A (en) * | 2019-01-04 | 2019-04-09 | 张永奇 | A kind of graphite oxide ene coatings polyester-cotton fabric and preparation method thereof |
| CN110387740A (en) * | 2019-07-17 | 2019-10-29 | 山东沃源新型面料股份有限公司 | A kind of electric-welding protective garment fabric preparation method based on graphene heat dissipation and electric-welding protective garment fabric obtained |
| CN110453494A (en) * | 2019-08-29 | 2019-11-15 | 南通强生石墨烯科技有限公司 | A kind of Graphene antibiosis fabric and preparation method thereof |
| CN110540198A (en) * | 2019-09-25 | 2019-12-06 | 广东工业大学 | Graphene oxide-based self-repairing flame-retardant composite film, preparation thereof and fire alarm |
| CN110774682A (en) * | 2019-11-21 | 2020-02-11 | 海安锦雅纺织科技有限公司 | Composite textile fabric |
| CN113445305A (en) * | 2021-06-25 | 2021-09-28 | 南通强生石墨烯科技有限公司 | Graphene high-flame-retardance fiber and preparation method thereof |
| CN113638232A (en) * | 2021-09-03 | 2021-11-12 | 南通强生石墨烯科技有限公司 | Insulating fabric with flame-retardant coating and preparation method thereof |
| CN113718366A (en) * | 2021-09-18 | 2021-11-30 | 南通强生石墨烯科技有限公司 | Graphene super-strong flame-retardant fiber and preparation method thereof |
| CN114672993A (en) * | 2022-04-19 | 2022-06-28 | 南通大学 | Graphene oxide-based flame-retardant functional cotton fabric and preparation method thereof |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107541934A (en) * | 2017-09-04 | 2018-01-05 | 西南大学 | Conductive silk fabric is prepared with the NMMO aqueous solution |
| CN107724070A (en) * | 2017-10-20 | 2018-02-23 | 浙江剑利美针织服饰有限公司 | A kind of graphene fabric and preparation method thereof |
| CN108867031A (en) * | 2018-07-30 | 2018-11-23 | 青岛大学 | A method of improving graphene adhesion amount and electric conductivity on cotton fabric |
| CN109576983A (en) * | 2019-01-04 | 2019-04-05 | 张永奇 | A kind of graphene oxide coated polyester fabric and preparation method thereof |
| CN109594328A (en) * | 2019-01-04 | 2019-04-09 | 张永奇 | A kind of graphite oxide ene coatings polyester-cotton fabric and preparation method thereof |
| CN110387740A (en) * | 2019-07-17 | 2019-10-29 | 山东沃源新型面料股份有限公司 | A kind of electric-welding protective garment fabric preparation method based on graphene heat dissipation and electric-welding protective garment fabric obtained |
| CN110453494A (en) * | 2019-08-29 | 2019-11-15 | 南通强生石墨烯科技有限公司 | A kind of Graphene antibiosis fabric and preparation method thereof |
| CN110540198A (en) * | 2019-09-25 | 2019-12-06 | 广东工业大学 | Graphene oxide-based self-repairing flame-retardant composite film, preparation thereof and fire alarm |
| CN110774682A (en) * | 2019-11-21 | 2020-02-11 | 海安锦雅纺织科技有限公司 | Composite textile fabric |
| CN113445305A (en) * | 2021-06-25 | 2021-09-28 | 南通强生石墨烯科技有限公司 | Graphene high-flame-retardance fiber and preparation method thereof |
| CN113638232A (en) * | 2021-09-03 | 2021-11-12 | 南通强生石墨烯科技有限公司 | Insulating fabric with flame-retardant coating and preparation method thereof |
| CN113718366A (en) * | 2021-09-18 | 2021-11-30 | 南通强生石墨烯科技有限公司 | Graphene super-strong flame-retardant fiber and preparation method thereof |
| CN114672993A (en) * | 2022-04-19 | 2022-06-28 | 南通大学 | Graphene oxide-based flame-retardant functional cotton fabric and preparation method thereof |
| CN114672993B (en) * | 2022-04-19 | 2024-01-30 | 南通大学 | Graphene oxide-based flame-retardant functional cotton fabric and preparation method thereof |
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