CN106995556A - A kind of anti-flaming anti-static electricity polypropylene composition, sheet material and preparation method thereof - Google Patents

A kind of anti-flaming anti-static electricity polypropylene composition, sheet material and preparation method thereof Download PDF

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Publication number
CN106995556A
CN106995556A CN201710195091.2A CN201710195091A CN106995556A CN 106995556 A CN106995556 A CN 106995556A CN 201710195091 A CN201710195091 A CN 201710195091A CN 106995556 A CN106995556 A CN 106995556A
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mass parts
mixture
polypropylene
static electricity
flaming
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廖春
马雅琳
罗春明
李建学
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Sichuan Dongcai Technology Group Co Ltd
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Sichuan Dongcai Technology Group Co Ltd
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Abstract

The invention discloses a kind of anti-flaming anti-static electricity polypropylene composition, sheet material and preparation method thereof, the raw material that the anti-flaming anti-static electricity polypropylene composition is made up of the mass parts of polypropylene 40~80, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, the mass parts of fire retardant 5~30, the mass parts of fire retarding synergist 3~8, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15 is through being mixed evenly, extruder carries out melting extrusion, be made again through tie rod pelletizing；Raw material through being mixed evenly, again extruded machine melting extrusion film-making can be made into thickness be 0.1~2.0mm anti-flaming anti-static electricity polypropylene sheet material.The present invention fire-retardant quiet anti-voltolisation propylene compositions or sheet material can make fire resistance height and have the product of good antistatic behaviour, it is adaptable to the field such as electronic device, household electrical appliance, vehicle, instrument, packaging material, meet environment protection requirement.

Description

A kind of anti-flaming anti-static electricity polypropylene composition, sheet material and preparation method thereof
Technical field
The invention belongs to high molecular material compositions, sheet material and its preparation, it is related to a kind of anti-flaming anti-static electricity polypropylene combination Thing, sheet material and preparation method thereof, anti-flaming anti-static electricity polypropylene composition or sheet material of the present invention can make fire resistance height and have good The product of good antistatic behaviour, it is adaptable to the field such as electronic device, household electrical appliance, vehicle, instrument, packaging material.
Background technology
Small (the 0.90g/cm of polypropylene density3~0.91g/cm3), cost performance is high, the advantages of being easily worked, with preferable Mechanical electric performance and high frequency tolerant insulating properties, hardly absorb water, are not influenceed by humidity, do not occur with most chemical contacts Effect, larger shortcoming is that tear resistance is poor, and polypropylene after modified can be widely applied to auto industry, household electric appliances, modeling Expect tubing industry, mechanical machine part etc..It is widely used in the industries such as auto industry, household electrical appliance, electronic component.
There is polypropylene good electrical insulating property, surface resistivity to be 1014-1016Ω .cm, rubbing, peel off, wound Journey can produce electrostatic charge, and the electric charge of accumulation can not discharge, and cause dust suction, incrustation, spark discharge, be unfavorable for the processing of plastic products Use；A large amount of existing surfacings all have a static discharge phenomenon, easily produce the serious security incident such as catch fire, explode, Endanger property and life security；And polyacrylic resin material is from as combustible material, it is impossible to meet the fire prevention of field of electronics It is required that；Exploitation flame-retardant and anti-static simultaneously meets the polypropylene material of safety and environment law requirement and is particularly important.
The content of the invention
The purpose of the present invention is intended to overcome that above-mentioned of the prior art not enough there is provided a kind of combination of anti-flaming anti-static electricity polypropylene Thing, sheet material and preparation method thereof, are readily produced and electric with environmental protection, good flame-retardance energy, good mechanical so as to provide one kind Anti-flaming anti-static electricity polypropylene composition, sheet material and its manufacture method of performance.
Present disclosure is：A kind of anti-flaming anti-static electricity polypropylene composition, it is characterized in that：The anti-flaming anti-static electricity polypropylene Composition be by the mass parts of polypropylene 40~80, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, fire retardant 5~ The original that 30 mass parts, the mass parts of fire retarding synergist 3~8, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15 are constituted Material is through being mixed evenly, extruder carries out melting extrusion, be made again through tie rod pelletizing；
The polypropylene is HOPP, and crystallinity is 20~40%, and melt index (MI) is 2~15g/10min, is divided equally again Son amount Mw is 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrole The carboxylic acid sodium of pyrrolidone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and methyl Mixture more than one or both of copolymer of acrylate；
The compatilizer is stearic acid monoglyceride, the ethylene-octene height of ethylene bis stearamide, maleic anhydride grafting is poly- One kind in the SIS/SEBS of thing and glycidyl methacrylate graft or two Plant the mixture of the above；
The fire retardant is three (phospha -2,6,7- trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1) octane -4- methylene) phosphorus Acid esters, dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, It is Firebrake ZB, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double Mixture more than one or both of (tetrabromo phthalimide) ethane and double (tribromophenoxy) ethane；
The fire retarding synergist is polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nanometer illiteracy Mixture more than one or both of de- soil and dicumyl peroxide；
The antioxidant is three (the 2-methyl-2-phenylpropane bases of 2,4- bis-) phosphite esters and four [3- (3,5- di-t-butyl -4- carboxy phenyls) Propionic acid] quaternary amyl alcohol ester mass ratio be 2：1 or 3：1 mixture；
The filler is more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide mixed Compound.
The present invention another content be：A kind of anti-flaming anti-static electricity polypropylene sheet material, it is characterized in that：The flame-retardant and anti-static poly- third Alkene sheet material be by the mass parts of polypropylene 40~80, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, fire retardant 5~ The original that 30 mass parts, the mass parts of fire retarding synergist 3~8, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15 are constituted Thickness (scope) obtained from material is through being mixed evenly, extruded machine carries out melting extrusion film-making again is the fire-retardant anti-of 0.1~2.0mm Electrostatic crystalline p p sheet；
The polypropylene is HOPP, and crystallinity is 20~40%, and melt index (MI) is 2~15g/10min, is divided equally again Son amount Mw is 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrole The carboxylic acid sodium of pyrrolidone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and methyl Mixture more than one or both of copolymer of acrylate；
The compatilizer is stearic acid monoglyceride, the ethylene-octene height of ethylene bis stearamide, maleic anhydride grafting is poly- One kind in the SIS/SEBS of thing and glycidyl methacrylate graft or two Plant the mixture of the above；
The fire retardant is three (phospha -2,6,7- trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1) octane -4- methylene) phosphorus Acid esters, dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, It is Firebrake ZB, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double Mixture more than one or both of (tetrabromo phthalimide) ethane and double (tribromophenoxy) ethane；
The fire retarding synergist is polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nanometer illiteracy Mixture more than one or both of de- soil and dicumyl peroxide；
The antioxidant is three (the 2-methyl-2-phenylpropane bases of 2,4- bis-) phosphite esters and four [3- (3,5- di-t-butyl -4- carboxy phenyls) Propionic acid] quaternary amyl alcohol ester mass ratio be 2：1 or 3：1 mixture；
The filler is more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide mixed Compound.
The present invention another content be：A kind of preparation method of anti-flaming anti-static electricity polypropylene sheet material, it is characterized in that step is：
A, prepare anti-flaming anti-static electricity polypropylene mixture：
By the mass parts of raw material polypropylene 40~80, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, fire retardant 5~30 mass parts, the mass parts of fire retarding synergist 3~8, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15 mix equal It is even, that is, anti-flaming anti-static electricity polypropylene mixture is made；
The polypropylene is HOPP, and crystallinity is 20~40%, and melt index (MI) is 2~15g/10min, is divided equally again Son amount Mw is 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrole The carboxylic acid sodium of pyrrolidone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and methyl Mixture more than one or both of copolymer of acrylate；
The compatilizer is stearic acid monoglyceride, the ethylene-octene height of ethylene bis stearamide, maleic anhydride grafting is poly- One kind in the SIS/SEBS of thing and glycidyl methacrylate graft or two Plant the mixture of the above；
The fire retardant is three (phospha -2,6,7- trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1) octane -4- methylene) phosphorus Acid esters, dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, It is Firebrake ZB, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double Mixture more than one or both of (tetrabromo phthalimide) ethane and double (tribromophenoxy) ethane；
The fire retarding synergist is polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nanometer illiteracy Mixture more than one or both of de- soil and dicumyl peroxide；
The antioxidant is three (the 2-methyl-2-phenylpropane bases of 2,4- bis-) phosphite esters and four [3- (3,5- di-t-butyl -4- carboxy phenyls) Propionic acid] quaternary amyl alcohol ester mass ratio be 2：1 or 3：1 mixture；
The filler is more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide mixed Compound；
B, prepare anti-flaming anti-static electricity polypropylene sheet material：
Screw slenderness ratio L/D is used for 25~40 double screw extruder, will be fire-retardant at a temperature of 150 DEG C~220 DEG C Antistatic polypropylene mixture melting mixing is uniform；Again through single screw extrusion machine melting extrusion, control single screw extrusion machine extrusion Duan Wendu is 160 DEG C~230 DEG C, die head temperature is 180 DEG C~220 DEG C, is 10 DEG C~140 DEG C of roller temperature, and adjusting screw rod turns Speed is 20r/min~150r/min, metering revolution speed is 5r/min~70r/min and rolling speed is 5~40m/min, regulation Sheet thickness is 0.1mm~2.0mm and width is 600mm~1200mm, that is, anti-flaming anti-static electricity polypropylene sheet material is made.
Compared with prior art, the present invention has following features and beneficial effect：
(1) present invention is used as anti-flaming anti-static electricity polypropylene material using the one or more in phosphorus, nitrogen, bromine and inorganic combustion inhibitor The Main Ingredients and Appearance of material；A small amount of additive flame retardant by adding, is having substantially no effect on the premise of polypropylene bulk material performance Under, more consolidate the final anti-flammability of the articles of sheet material for the anti-flaming anti-static electricity polypropylene composition production for using the present patent application Energy；By add toughener stearic acid monoglyceride, ethylene bis stearamide, maleic anhydride be grafted ethylene-octene high polymer, The SIS/SEBS of glycidyl methacrylate graft, realizes the soft of articles of sheet material Softness, is allowed to the more easily following process of articles of sheet material and uses；
(2) using the present invention, the purpose for improving anti-flaming anti-static electricity polypropylene combination property has been reached, polypropylene material is realized The flame-retardant and anti-static mode of material, meets environment protection requirement；
(3) anti-flaming anti-static electricity polypropylene composition of the present invention has good electric property, is applicable to electric etc. Insulation film field, during particularly with the especially sensitive IC semiconductor components and devices of electrostatic, shows superior static elimination and absolutely Edge effect, it is to avoid existing product adsorbs dust, and interference electronic instrument is using causing material failure or burn, and the product can be met Diversified use requirement, it is practical.
Embodiment
The invention will be further described for example given below plan, but is not to be construed as to the scope of the present invention Limitation, some nonessential improvement and tune that person skilled in art makes according to the content of the invention described above to the present invention It is whole, still fall within protection scope of the present invention.
Part I anti-flaming anti-static electricity polypropylene composition
The formula and raw material of anti-flaming anti-static electricity polypropylene composition：
The mass parts of polypropylene 40~80, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, fire retardant 5~30 Mass parts, the mass parts of fire retarding synergist 3~8, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15.Wherein：
Polypropylene is HOPP, and crystallinity is 20~40%, and melt index (MI) is 2~15g/10min, weight average molecular weight Mw is 80000~120000；
Antistatic additive：A1 is that dodecyldimethylammonium hydroxide inner salt, A2 are the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, A3 It is that tetraalkylammonium salt, A5 are that alkylsulfonate, A6 are that poly- (2- vinylthiophenes), A7 are first for the carboxylic acid sodium of alpha-pyrrolidone -5, A4 The copolymer of epoxide polyethylene glycol and methacrylate；
Compatilizer：The ethene that B1 is stearic acid monoglyceride, B2 is ethylene bis stearamide, B3 is maleic anhydride grafting- Octene high polymer, B4 are the SIS/SEBS of glycidyl methacrylate graft；
Fire retardant：C1 is three (phospha -2,6,7- trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1) octane -4- methylene) phosphoric acid Ester, C2 be dimethyl methyl phosphonate, C3 be the phenoxy group benzene of ten tetrabromo two, C4 be brominated triazine, C5 be melamine ammonium polyphosphate, C6 be HBCD, C7 be Firebrake ZB, C8 be hibbsite, C9 be tetrabromobisphenol A (2,3- dibromopropyls) ether, C10 is that polypropylene-Dowspray 9 graft copolymer, C11 are that double (tetrabromo phthalimide) ethane, C12 are double (tribromos Phenoxy group) ethane；
Fire retarding synergist：D1 is that polysilsesquioxane, D2 are that dimethyl silicone polymer, D3 are that antimony oxide, D4 are sulphur Sour barium, D5 are that nano imvite, D6 are dicumyl peroxide；
Antioxidant：E1 is three (the 2-methyl-2-phenylpropane bases of 2,4- bis-) phosphite esters and E2 is four [3- (3,5- di-t-butyl -4- carboxylic benzene Base) propionic acid] quaternary amyl alcohol ester, its mass ratio is：E1：E2=2：1 or 3：1；
Filler：F1 is that talcum, F2 are that shepardite, F3 are that kaolin, F4 are that mica, F5 are magnesium hydroxide.
Table 1：The quality proportioning table of embodiment 1-1~1-12 anti-flaming anti-static electricity polypropylene compositions：
The preparation of Part II anti-flaming anti-static electricity polypropylene sheet material and main performance
1st, anti-flaming anti-static electricity polypropylene sheet material prepares basic technology：
Will be by the mass parts of polypropylene 40~80, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, fire retardant 5 What~30 mass parts, the mass parts of fire retarding synergist 3~8, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15 were constituted Raw material is mixed evenly (or above-mentioned anti-flaming anti-static electricity polypropylene composition), use screw slenderness ratio L/D for 25~40 double spiral shells Bar extruder, anti-flaming anti-static electricity polypropylene composition is uniformly made in melting mixing at a temperature of 150 DEG C~220 DEG C, then through single spiral shell Bar extruder melting extrusion, 160 DEG C~230 DEG C of extruding zone temperature, 180 DEG C~220 DEG C of die head temperature, 10 DEG C of roller temperature~ 140 DEG C, adjusting screw rod rotating speed 20r/min~150r/min, metering revolution speed 5r/min~70r/min and rolling speed 5~ 40m/min, adjustment sheet thickness 0.1mm~2.0mm and width 600mm~1200mm, that is, be made anti-flaming anti-static electricity polypropylene piece Material.
Each embodiment in the preparation of embodiment 2-1~2-12 anti-flaming anti-static electricity polypropylene sheet materials uses composition of raw materials Embodiment 1-1~1-12 anti-flaming anti-static electricity polypropylene compositions in correspondence " Part I anti-flaming anti-static electricity polypropylene composition " (i.e. embodiment 2-1 correspondences embodiment 1-1), its preparation technology parameter is shown in Table 2.
Table 2：The preparation technology parameter table of embodiment 2-1~2-12 anti-flaming anti-static electricity polypropylene sheet materials：
2nd, the main performance for preparing anti-flaming anti-static electricity polypropylene sheet material is shown in Table 3
Table 3：Embodiment 2-1~2-12 prepares the main performance table of anti-flaming anti-static electricity polypropylene sheet material：
Embodiment 3：
A kind of anti-flaming anti-static electricity polypropylene composition, the anti-flaming anti-static electricity polypropylene composition is by the mass of polypropylene 40 Part, the mass parts of antistatic additive 5, the mass parts of compatilizer 5, the mass parts of fire retardant 5, the mass parts of fire retarding synergist 3, the matter of antioxidant 0.1 Amount part and the raw material that is constituted of the mass parts of filler 5 are through being mixed evenly, extruder carries out melting extrusion, make again through tie rod pelletizing .
Embodiment 4：
A kind of anti-flaming anti-static electricity polypropylene composition, the anti-flaming anti-static electricity polypropylene composition is by the mass of polypropylene 80 Part, the mass parts of antistatic additive 25, the mass parts of compatilizer 10, the mass parts of fire retardant 30, the mass parts of fire retarding synergist 8, antioxidant 0.5 The raw material that mass parts and the mass parts of filler 15 are constituted is through being mixed evenly, extruder carries out melting extrusion, again through tie rod pelletizing It is made.
Embodiment 5：
A kind of anti-flaming anti-static electricity polypropylene composition, the anti-flaming anti-static electricity polypropylene composition is by the mass of polypropylene 60 Part, the mass parts of antistatic additive 15, the mass parts of compatilizer 7.5, the mass parts of fire retardant 17.5, the mass parts of fire retarding synergist 5.5, antioxygen The raw material that the mass parts of agent 0.3 and the mass parts of filler 10 are constituted is through being mixed evenly, extruder carries out melting extrusion, cut again through tie rod Grain and be made.
Embodiment 6-12：
A kind of anti-flaming anti-static electricity polypropylene composition, the anti-flaming anti-static electricity polypropylene composition is by the matter of polypropylene 40~80 Measure part, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, the mass parts of fire retardant 5~30, the matter of fire retarding synergist 3~8 The raw material that amount part, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15 are constituted is through being mixed evenly, extruder is melted Melt extrusion, be made again through tie rod pelletizing；
The specific mass parts consumption (unit of mass parts of each component raw material in each embodiment：Gram) see the table below：
In above-described embodiment 3-12：
The polypropylene is HOPP, and crystallinity is 20~40%, and melt index (MI) is 2~15g/10min, is divided equally again Son amount Mw is 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrole The carboxylic acid sodium of pyrrolidone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and methyl Mixture more than one or both of copolymer of acrylate；
The compatilizer is stearic acid monoglyceride, the ethylene-octene height of ethylene bis stearamide, maleic anhydride grafting is poly- One kind in the SIS/SEBS of thing and glycidyl methacrylate graft or two Plant the mixture of the above；
The fire retardant is three (phospha -2,6,7- trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1) octane -4- methylene) phosphorus Acid esters, dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, It is Firebrake ZB, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double Mixture more than one or both of (tetrabromo phthalimide) ethane and double (tribromophenoxy) ethane；
The fire retarding synergist is polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nanometer illiteracy Mixture more than one or both of de- soil and dicumyl peroxide；
The antioxidant is three (the 2-methyl-2-phenylpropane bases of 2,4- bis-) phosphite esters and four [3- (3,5- di-t-butyl -4- carboxy phenyls) Propionic acid] quaternary amyl alcohol ester mass ratio be 2：1 or 3：1 mixture；
The filler is more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide mixed Compound.
Embodiment 13：
A kind of anti-flaming anti-static electricity polypropylene sheet material, the anti-flaming anti-static electricity polypropylene sheet material is by the mass parts of polypropylene 40, resisted The mass parts of electrostatic agent 5, the mass parts of compatilizer 5, the mass parts of fire retardant 5, the mass parts of fire retarding synergist 3, the mass parts of antioxidant 0.1 and The raw material that the mass parts of filler 5 are constituted is through being mixed evenly, thickness obtained from extruded machine progress melting extrusion film-making is again 0.1mm anti-flaming anti-static electricity polypropylene sheet material.
Embodiment 14：
A kind of anti-flaming anti-static electricity polypropylene sheet material, the anti-flaming anti-static electricity polypropylene sheet material is by the mass parts of polypropylene 80, resisted The mass parts of electrostatic agent 25, the mass parts of compatilizer 10, the mass parts of fire retardant 30, the mass parts of fire retarding synergist 8, the mass of antioxidant 0.5 The raw material that part and the mass parts of filler 15 are constituted is through being mixed evenly, extruded machine carries out thickness obtained from melting extrusion film-making again For 2.0mm anti-flaming anti-static electricity polypropylene sheet material.
Embodiment 15：
A kind of anti-flaming anti-static electricity polypropylene sheet material, the anti-flaming anti-static electricity polypropylene sheet material is by the mass parts of polypropylene 60, resisted The mass parts of electrostatic agent 15, the mass parts of compatilizer 7.5, the mass parts of fire retardant 17.5, the mass parts of fire retarding synergist 5.5, antioxidant 0.3 Obtained from the raw material that mass parts and the mass parts of filler 10 are constituted is through being mixed evenly, extruded machine carries out melting extrusion film-making again Thickness is 1mm anti-flaming anti-static electricity polypropylene sheet material.
Embodiment 16-22：
A kind of anti-flaming anti-static electricity polypropylene sheet material, the anti-flaming anti-static electricity polypropylene sheet material is by the mass of polypropylene 40~80 Part, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, the mass parts of fire retardant 5~30, the mass of fire retarding synergist 3~8 The raw material that part, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15 are constituted is through being mixed evenly, extruded machine is carried out again Thickness obtained from melting extrusion film-making is 0.1~2.0mm anti-flaming anti-static electricity polypropylene sheet material；
The specific mass parts consumption (unit of mass parts of each component raw material in each embodiment：Gram) see the table below：
In above-described embodiment 13-22：
The polypropylene is HOPP, and crystallinity is 20~40%, and melt index (MI) is 2~15g/10min, is divided equally again Son amount Mw is 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrole The carboxylic acid sodium of pyrrolidone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and methyl Mixture more than one or both of copolymer of acrylate；
The compatilizer is stearic acid monoglyceride, the ethylene-octene height of ethylene bis stearamide, maleic anhydride grafting is poly- One kind in the SIS/SEBS of thing and glycidyl methacrylate graft or two Plant the mixture of the above；
The fire retardant is three (phospha -2,6,7- trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1) octane -4- methylene) phosphorus Acid esters, dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, It is Firebrake ZB, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double Mixture more than one or both of (tetrabromo phthalimide) ethane and double (tribromophenoxy) ethane；
The fire retarding synergist is polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nanometer illiteracy Mixture more than one or both of de- soil and dicumyl peroxide；
The antioxidant is three (the 2-methyl-2-phenylpropane bases of 2,4- bis-) phosphite esters and four [3- (3,5- di-t-butyl -4- carboxy phenyls) Propionic acid] quaternary amyl alcohol ester mass ratio be 2：1 or 3：1 mixture；
The filler is more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide mixed Compound.
Embodiment 23：
A kind of preparation method of anti-flaming anti-static electricity polypropylene sheet material, step is：
A, prepare anti-flaming anti-static electricity polypropylene mixture：
By mass parts of the raw material polypropylene 40, mass parts of antistatic additive 5, the mass parts of compatilizer 5, the mass parts of fire retardant 5, fire-retardant The mass parts of synergist 3, the mass parts of antioxidant 0.1 and the mass parts of filler 5 are mixed evenly, that is, anti-flaming anti-static electricity polypropylene mixing is made Thing；
The polypropylene is HOPP, and crystallinity is 20%, and melt index (MI) is 2g/10min, and weight average molecular weight Mw is 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrole The carboxylic acid sodium of pyrrolidone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and methyl Mixture more than one or both of copolymer of acrylate；
The compatilizer is stearic acid monoglyceride, the ethylene-octene height of ethylene bis stearamide, maleic anhydride grafting is poly- One kind in the SIS/SEBS of thing and glycidyl methacrylate graft or two Plant the mixture of the above；
The fire retardant is three (phospha -2,6,7- trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1) octane -4- methylene) phosphorus Acid esters, dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, It is Firebrake ZB, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double Mixture more than one or both of (tetrabromo phthalimide) ethane and double (tribromophenoxy) ethane；
The fire retarding synergist is polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nanometer illiteracy Mixture more than one or both of de- soil and dicumyl peroxide；
The antioxidant is three (the 2-methyl-2-phenylpropane bases of 2,4- bis-) phosphite esters and four [3- (3,5- di-t-butyl -4- carboxy phenyls) Propionic acid] quaternary amyl alcohol ester mass ratio be 2：1 or 3：1 mixture；
The filler is more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide mixed Compound；
B, prepare anti-flaming anti-static electricity polypropylene sheet material：
Use screw slenderness ratio L/D for 25 double screw extruder, by anti-flaming anti-static electricity polypropylene at a temperature of 150 DEG C Mixture melting mixing is uniform；Again through single screw extrusion machine melting extrusion, it is 160 to control single screw extrusion machine extruding zone temperature DEG C, die head temperature be 180 DEG C, be 10 DEG C of roller temperature, adjusting screw rod rotating speed be 20r/min, metering revolution speed be 5r/min and Rolling speed is 5, and adjustment sheet thickness is 0.1mm and width is 600mm, that is, anti-flaming anti-static electricity polypropylene sheet material is made.
Embodiment 24：
A kind of preparation method of anti-flaming anti-static electricity polypropylene sheet material, step is：
A, prepare anti-flaming anti-static electricity polypropylene mixture：
By the mass parts of raw material polypropylene 80, the mass parts of antistatic additive 25, the mass parts of compatilizer 10, the mass parts of fire retardant 30, The mass parts of fire retarding synergist 8, the mass parts of antioxidant 0.5 and the mass parts of filler 15 are mixed evenly, that is, flame-retardant and anti-static poly- third is made Alkene mixture；
The polypropylene is HOPP, and crystallinity is 40%, and melt index (MI) is 15g/10min, weight average molecular weight Mw For 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrole The carboxylic acid sodium of pyrrolidone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and methyl Mixture more than one or both of copolymer of acrylate；
The compatilizer is stearic acid monoglyceride, the ethylene-octene height of ethylene bis stearamide, maleic anhydride grafting is poly- One kind in the SIS/SEBS of thing and glycidyl methacrylate graft or two Plant the mixture of the above；
The fire retardant is three (phospha -2,6,7- trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1) octane -4- methylene) phosphorus Acid esters, dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, It is Firebrake ZB, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double Mixture more than one or both of (tetrabromo phthalimide) ethane and double (tribromophenoxy) ethane；
The fire retarding synergist is polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nanometer illiteracy Mixture more than one or both of de- soil and dicumyl peroxide；
The antioxidant is three (the 2-methyl-2-phenylpropane bases of 2,4- bis-) phosphite esters and four [3- (3,5- di-t-butyl -4- carboxy phenyls) Propionic acid] quaternary amyl alcohol ester mass ratio be 2：1 or 3：1 mixture；
The filler is more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide mixed Compound；
B, prepare anti-flaming anti-static electricity polypropylene sheet material：
Use screw slenderness ratio L/D for 40 double screw extruder, by anti-flaming anti-static electricity polypropylene at a temperature of 220 DEG C Mixture melting mixing is uniform；Again through single screw extrusion machine melting extrusion, it is 230 to control single screw extrusion machine extruding zone temperature DEG C, die head temperature be 220 DEG C, be 140 DEG C of roller temperature, adjusting screw rod rotating speed be 150r/min, metering revolution speed be 70r/min And rolling speed is 40m/min, adjustment sheet thickness is 2.0mm and width is 1200mm, that is, anti-flaming anti-static electricity polypropylene is made Sheet material.
Embodiment 25：
A kind of preparation method of anti-flaming anti-static electricity polypropylene sheet material, step is：
A, prepare anti-flaming anti-static electricity polypropylene mixture：
By the mass parts of raw material polypropylene 60, the mass parts of antistatic additive 15, the mass parts of compatilizer 7.5, the mass of fire retardant 17.5 Part, the mass parts of fire retarding synergist 5.5, the mass parts of antioxidant 0.3 and the mass parts of filler 10 are mixed evenly, that is, flame-retardant and anti-static is made Polypropylene miser；
The polypropylene is HOPP, and crystallinity is 30%, and melt index (MI) is 8.5g/10min, weight average molecular weight Mw For 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrole The carboxylic acid sodium of pyrrolidone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and methyl Mixture more than one or both of copolymer of acrylate；
The compatilizer is stearic acid monoglyceride, the ethylene-octene height of ethylene bis stearamide, maleic anhydride grafting is poly- One kind in the SIS/SEBS of thing and glycidyl methacrylate graft or two Plant the mixture of the above；
The fire retardant is three (phospha -2,6,7- trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1) octane -4- methylene) phosphorus Acid esters, dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, It is Firebrake ZB, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double Mixture more than one or both of (tetrabromo phthalimide) ethane and double (tribromophenoxy) ethane；
The fire retarding synergist is polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nanometer illiteracy Mixture more than one or both of de- soil and dicumyl peroxide；
The antioxidant is three (the 2-methyl-2-phenylpropane bases of 2,4- bis-) phosphite esters and four [3- (3,5- di-t-butyl -4- carboxy phenyls) Propionic acid] quaternary amyl alcohol ester mass ratio be 2：1 or 3：1 mixture；
The filler is more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide mixed Compound；
B, prepare anti-flaming anti-static electricity polypropylene sheet material：
Use screw slenderness ratio L/D for 33 double screw extruder, by anti-flaming anti-static electricity polypropylene at a temperature of 180 DEG C Mixture melting mixing is uniform；Again through single screw extrusion machine melting extrusion, it is 190 to control single screw extrusion machine extruding zone temperature DEG C, die head temperature be 200 DEG C, be 75 DEG C of roller temperature, adjusting screw rod rotating speed be 85r/min, metering revolution speed be 38r/min and Rolling speed is 23m/min, and adjustment sheet thickness is 1.0mm and width is 800mm, that is, anti-flaming anti-static electricity polypropylene piece is made Material.
Embodiment 26-32：
A kind of preparation method of anti-flaming anti-static electricity polypropylene sheet material, step is：
A, prepare anti-flaming anti-static electricity polypropylene mixture：
By the mass parts of raw material polypropylene 40~80, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, fire retardant 5~30 mass parts, the mass parts of fire retarding synergist 3~8, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15 mix equal It is even, that is, anti-flaming anti-static electricity polypropylene mixture is made；
The specific mass parts consumption (unit of mass parts of each component raw material in each embodiment：Gram) see the table below：
In above-described embodiment 26-32：
The polypropylene is HOPP, and crystallinity is 20~40%, and melt index (MI) is 2~15g/10min, is divided equally again Son amount Mw is 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrole The carboxylic acid sodium of pyrrolidone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and methyl Mixture more than one or both of copolymer of acrylate；
The compatilizer is stearic acid monoglyceride, the ethylene-octene height of ethylene bis stearamide, maleic anhydride grafting is poly- One kind in the SIS/SEBS of thing and glycidyl methacrylate graft or two Plant the mixture of the above；
The fire retardant is three (phospha -2,6,7- trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1) octane -4- methylene) phosphorus Acid esters, dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, It is Firebrake ZB, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double Mixture more than one or both of (tetrabromo phthalimide) ethane and double (tribromophenoxy) ethane；
The fire retarding synergist is polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nanometer illiteracy Mixture more than one or both of de- soil and dicumyl peroxide；
The antioxidant is three (the 2-methyl-2-phenylpropane bases of 2,4- bis-) phosphite esters and four [3- (3,5- di-t-butyl -4- carboxy phenyls) Propionic acid] quaternary amyl alcohol ester mass ratio be 2：1 or 3：1 mixture；
The filler is more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide mixed Compound；
B, prepare anti-flaming anti-static electricity polypropylene sheet material：
Screw slenderness ratio L/D is used for 25~40 double screw extruder, will be fire-retardant at a temperature of 150 DEG C~220 DEG C Antistatic polypropylene mixture melting mixing is uniform；Again through single screw extrusion machine melting extrusion, control single screw extrusion machine extrusion Duan Wendu is 160 DEG C~230 DEG C, die head temperature is 180 DEG C~220 DEG C, is 10 DEG C~140 DEG C of roller temperature, and adjusting screw rod turns Speed is 20r/min~150r/min, metering revolution speed is 5r/min~70r/min and rolling speed is 5~40m/min, regulation Sheet thickness is 0.1mm~2.0mm and width is 600mm~1200mm, that is, anti-flaming anti-static electricity polypropylene sheet material is made.
In above-described embodiment：It is especially not dated in the percentage used, be quality (weight) percentage or Well known to a person skilled in the art percentage；In the ratio used, do not indicate especially, be quality (weight) ratio； The parts by weight can be gram or kilogram.
In above-described embodiment：Technological parameter (temperature, time, rotating speed etc.) and each component numerical quantity in each step etc. are Scope, any point is applicable.
The technology contents being not specifically delineated in present invention and above-described embodiment are compared with technology, and the raw material are Commercially available prod.
It can implement the invention is not restricted to above-described embodiment, described in present invention and with the good result.

Claims (3)

1. a kind of anti-flaming anti-static electricity polypropylene composition, it is characterized in that：The anti-flaming anti-static electricity polypropylene composition is by polypropylene 40~80 mass parts, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, the mass parts of fire retardant 5~30, fire-retardant synergistic The raw material that the mass parts of agent 3~8, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15 are constituted is through being mixed evenly, extruding Machine carries out melting extrusion, is made again through tie rod pelletizing；
The polypropylene is HOPP, and crystallinity is 20~40%, and melt index (MI) is 2~15g/10min, weight average molecular weight Mw is 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrolidines The carboxylic acid sodium of ketone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and metering system Mixture more than one or both of copolymer of acid esters；
The compatilizer be stearic acid monoglyceride, ethylene bis stearamide, maleic anhydride grafting ethylene-octene high polymer, And one or both of the SIS/SEBS of glycidyl methacrylate graft with On mixture；
The fire retardant is three（Phospha -2,6,7- the trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1）Octane -4- methylene）Phosphate, Dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, boric acid Zinc, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double (four Bromine phthalimide) mixture of one or both of ethane and double (tribromophenoxy) ethane above；
The fire retarding synergist be polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nano imvite, And mixture more than one or both of dicumyl peroxide；
The antioxidant is three（The 2-methyl-2-phenylpropane bases of 2,4- bis-）Phosphite ester and four [3-（3,5- di-t-butyl -4- carboxy phenyls）Propionic acid] The mass ratio of quaternary amyl alcohol ester is 2：1 or 3：1 mixture；
The filler is mixture more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide.
2. a kind of anti-flaming anti-static electricity polypropylene sheet material, it is characterized in that：The anti-flaming anti-static electricity polypropylene sheet material be by polypropylene 40~ 80 mass parts, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, the mass parts of fire retardant 5~30, fire retarding synergist 3 The raw material that~8 mass parts, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15 are constituted is through being mixed evenly, again through squeezing Go out the anti-flaming anti-static electricity polypropylene sheet material that thickness obtained from machine carries out melting extrusion film-making is 0.1~2.0mm；
The polypropylene is HOPP, and crystallinity is 20~40%, and melt index (MI) is 2~15g/10min, weight average molecular weight Mw is 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrolidines The carboxylic acid sodium of ketone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and metering system Mixture more than one or both of copolymer of acid esters；
The compatilizer be stearic acid monoglyceride, ethylene bis stearamide, maleic anhydride grafting ethylene-octene high polymer, And one or both of the SIS/SEBS of glycidyl methacrylate graft with On mixture；
The fire retardant is three（Phospha -2,6,7- the trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1）Octane -4- methylene）Phosphate, Dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, boric acid Zinc, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double (four Bromine phthalimide) mixture of one or both of ethane and double (tribromophenoxy) ethane above；
The fire retarding synergist be polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nano imvite, And mixture more than one or both of dicumyl peroxide；
The antioxidant is three（The 2-methyl-2-phenylpropane bases of 2,4- bis-）Phosphite ester and four [3-（3,5- di-t-butyl -4- carboxy phenyls）Propionic acid] The mass ratio of quaternary amyl alcohol ester is 2：1 or 3：1 mixture；
The filler is mixture more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide.
3. a kind of preparation method of anti-flaming anti-static electricity polypropylene sheet material, it is characterized in that step is：
A, prepare anti-flaming anti-static electricity polypropylene mixture：
By the mass parts of raw material polypropylene 40~80, the mass parts of antistatic additive 5~25, the mass parts of compatilizer 5~10, fire retardant 5~ 30 mass parts, the mass parts of fire retarding synergist 3~8, the mass parts of antioxidant 0.1~0.5 and the mass parts of filler 5~15 are mixed evenly, Anti-flaming anti-static electricity polypropylene mixture is made；
The polypropylene is HOPP, and crystallinity is 20~40%, and melt index (MI) is 2~15g/10min, weight average molecular weight Mw is 80000~120000；
The antistatic additive is dodecyldimethylammonium hydroxide inner salt, the double methyl polyoxyethylene quaternary ammonium salts of octadecyl, α-pyrrolidines The carboxylic acid sodium of ketone -5, tetraalkylammonium salt, alkylsulfonate, poly- (2- vinylthiophenes) and methoxy poly (ethylene glycol) and metering system Mixture more than one or both of copolymer of acid esters；
The compatilizer be stearic acid monoglyceride, ethylene bis stearamide, maleic anhydride grafting ethylene-octene high polymer, And one or both of the SIS/SEBS of glycidyl methacrylate graft with On mixture；
The fire retardant is three（Phospha -2,6,7- the trioxa-l-phosphabicyclos [2,2,2] of 1- oxos -1）Octane -4- methylene）Phosphate, Dimethyl methyl phosphonate, the phenoxy group benzene of ten tetrabromo two, brominated triazine, melamine ammonium polyphosphate, HBCD, boric acid Zinc, hibbsite, tetrabromobisphenol A (2,3- dibromopropyls) ether, polypropylene-Dowspray 9 graft copolymer, double (four Bromine phthalimide) mixture of one or both of ethane and double (tribromophenoxy) ethane above；
The fire retarding synergist be polysilsesquioxane, dimethyl silicone polymer, antimony oxide, barium sulfate, nano imvite, And mixture more than one or both of dicumyl peroxide；
The antioxidant is three（The 2-methyl-2-phenylpropane bases of 2,4- bis-）Phosphite ester and four [3-（3,5- di-t-butyl -4- carboxy phenyls）Propionic acid] The mass ratio of quaternary amyl alcohol ester is 2：1 or 3：1 mixture；
The filler is mixture more than one or both of talcum, shepardite, kaolin, mica and magnesium hydroxide；
B, prepare anti-flaming anti-static electricity polypropylene sheet material：
Screw slenderness ratio L/D is used for 25~40 double screw extruder, will be fire-retardant anti-quiet at a temperature of 150 DEG C~220 DEG C Voltolisation propylene mixtures melting mixing is uniform；Again through single screw extrusion machine melting extrusion, single screw extrusion machine extruding zone temperature is controlled Degree is 160 DEG C~230 DEG C, die head temperature is 180 DEG C~220 DEG C, is 10 DEG C~140 DEG C of roller temperature, and adjusting screw rod rotating speed is 20r/min~150r/min, metering revolution speed are the r/min of 5r/min~70 and rolling speed is 5~40m/min, adjustment sheet Thickness is 0.1mm~2.0mm and width is 600mm~1200mm, that is, anti-flaming anti-static electricity polypropylene sheet material is made.
CN201710195091.2A 2017-03-29 2017-03-29 A kind of anti-flaming anti-static electricity polypropylene composition, sheet material and preparation method thereof Pending CN106995556A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108219270A (en) * 2017-12-06 2018-06-29 星威国际家居有限公司 Anti-static PP modified material and preparation method thereof
CN111978699A (en) * 2020-08-12 2020-11-24 中广核俊尔(浙江)新材料有限公司 High-shading thin-wall flame-retardant PC material and preparation method and application thereof
CN112592566A (en) * 2020-11-26 2021-04-02 金发科技股份有限公司 Low-smoke-density halogen-containing flame-retardant reinforced PBT/PET compound and preparation method and application thereof
CN112625405A (en) * 2020-11-26 2021-04-09 金发科技股份有限公司 Low-smoke density halogen-free flame-retardant reinforced PBT/PET compound and preparation method and application thereof
WO2021164353A1 (en) * 2020-02-20 2021-08-26 金发科技股份有限公司 Antimony-free flame-retardant polypropylene composition and preparation method therefor

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101220183A (en) * 2007-12-26 2008-07-16 深圳市科聚新材料有限公司 Environment-protection flame-proof electrostatic resistance polypropylene material and method for producing the same
CN104327380A (en) * 2014-11-19 2015-02-04 江苏悦达新材料科技有限公司 Preparation method of halogen-free flame-retarding anti-static polypropylene material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101220183A (en) * 2007-12-26 2008-07-16 深圳市科聚新材料有限公司 Environment-protection flame-proof electrostatic resistance polypropylene material and method for producing the same
CN104327380A (en) * 2014-11-19 2015-02-04 江苏悦达新材料科技有限公司 Preparation method of halogen-free flame-retarding anti-static polypropylene material

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
孔繁超: "《涤纶针织物染整》", 31 August 1982, 纺织工业出版社 *
李青山 等: "《材料加工助剂原理及应用》", 31 March 2002, 哈尔滨工程大学出版社 *
欧育湘 等: "《阻燃剂》", 30 September 2009, 国防工业出版社 *
王文广: "《塑料配方设计》", 30 September 1998, 化学工业出版社 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108219270A (en) * 2017-12-06 2018-06-29 星威国际家居有限公司 Anti-static PP modified material and preparation method thereof
WO2021164353A1 (en) * 2020-02-20 2021-08-26 金发科技股份有限公司 Antimony-free flame-retardant polypropylene composition and preparation method therefor
CN111978699A (en) * 2020-08-12 2020-11-24 中广核俊尔(浙江)新材料有限公司 High-shading thin-wall flame-retardant PC material and preparation method and application thereof
CN112592566A (en) * 2020-11-26 2021-04-02 金发科技股份有限公司 Low-smoke-density halogen-containing flame-retardant reinforced PBT/PET compound and preparation method and application thereof
CN112625405A (en) * 2020-11-26 2021-04-09 金发科技股份有限公司 Low-smoke density halogen-free flame-retardant reinforced PBT/PET compound and preparation method and application thereof
CN112592566B (en) * 2020-11-26 2022-03-22 金发科技股份有限公司 Low-smoke-density halogen-containing flame-retardant reinforced PBT/PET compound and preparation method and application thereof
CN112625405B (en) * 2020-11-26 2022-03-22 金发科技股份有限公司 Low-smoke density halogen-free flame-retardant reinforced PBT/PET compound and preparation method and application thereof

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