CN106986591A - A kind of wall high bond strength elastic water proofing paint and preparation method thereof - Google Patents
A kind of wall high bond strength elastic water proofing paint and preparation method thereof Download PDFInfo
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- CN106986591A CN106986591A CN201710195372.8A CN201710195372A CN106986591A CN 106986591 A CN106986591 A CN 106986591A CN 201710195372 A CN201710195372 A CN 201710195372A CN 106986591 A CN106986591 A CN 106986591A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
- C04B2111/00491—Primers
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
- C04B2111/00508—Cement paints
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of wall high bond strength elastic water proofing paint, including feed liquid and powder, feed liquid is made up of following raw material：Styrene-acrylic copolymer emulsion, Carboxy copolymer emulsion, nonionic surface active agent, wetting agent, hydrophober, defoamer, mould inhibitor, water；Powder is made up of following raw material：Cement, penetrant crystalline material, calcium formate, quartz sand, powdered whiting, talcum powder, lignocellulosic, auxiliary rheological agents, water reducer.The present invention solves at present that the adhesion strength of traditional polymer modified cement based waterproof coatings in wall waterproof is low, easily destroyed by shearing force, loss of properties on aging the problems such as, expand the use scope of polymer cement waterproof paint.
Description
Technical field
The invention belongs to water-repellent paint technical field, and in particular to a kind of wall with high bond strength elastic water proofing paint and
Its preparation method.
Background technology
Compared to coiled material class waterproof material, many advantages, such as water-repellent paint has easy construction, good endurance, non-series-water,
Particularly polymer cement waterproof paint also has the features such as short construction period, environmental protection, is widely used in the anti-of building
Water is moistureproof.Polymer cement waterproof paint is to make use of the hydrophobic after polymer film forming and flexible characteristic, and hydrated cementitious is hard
The advantage of high intensity, durability after change is combined, and reaches the waterproof effect coupled hardness with softness.The main function of water-repellent paint is resistance
The infiltration of sealing and water vapour oozes out to protect the safety of building or be supplied to the living environment of human health.With people
To waterproof requirement more and more higher, the waterproof problem of the wall particularly exterior wall of building is paid attention to by higher and higher.And it is traditional
Water-repellent paint be restricted in the use of wall particularly exterior wall, reason is that the outside of wall waterproof layer can bonding applique surface material
Material, such as ceramic tile, marble, true mineral varnish.These finishing materials lasting stretching can be produced to waterproof coating layer and shearing should
By that can produce creep after larger stress or even bond broken ring accident is occurred for power, waterproof layer.
The content of the invention
To make up the deficiencies in the prior art, the present invention provides a kind of good water-proof effect, the wall of service life length is glued with high
Knotting strength elastic water proofing paint and preparation method thereof.
The present invention is achieved through the following technical solutions：
A kind of wall high bond strength elastic water proofing paint, it is characterized in that：Including feed liquid and powder, feed liquid and powder
Mass ratio be 1：（2-3）；The feed liquid is prepared from the following raw materials in parts by weight：Latex of copolymer in cinnamic acrylic ester
50-65 parts, 20-30 parts of Carboxy copolymer emulsion, 0.5-1.5 parts of nonionic surface active agent, wetting agent 0.1-
0.5 part, 0.1-0.5 parts of hydrophober, 0.1-0.5 parts of defoamer, 0.05-0.1 parts of mould inhibitor, 1.9-29.15 parts of water；It is described
Powder is prepared from the following raw materials in parts by weight：25-45 parts of cement, 5-10 parts of penetrant crystalline material, calcium formate 0.2-0.8
Part, 30-50 parts of quartz sand, 5-15 parts of powdered whiting, 8-15 parts of talcum powder, 0.1-0.5 parts of lignocellulosic, rheology are helped
0.5-1 parts of agent, 0.1-0.3 parts of water reducer.
The wall high bond strength elastic water proofing paint of the present invention, the latex of copolymer in cinnamic acrylic ester is
Styrene/acrylic N-butyl/acrylic acid/methacrylic acid copolymer emulsion, styrene/acrylic N-butyl/metering system
Acid/acrylamide/trimethoxyvinyl silane copolymer emulsion, styrene/acrylic N-butyl/acrylic acid/metering system
Acid/acrylamide copolymer emulsion, styrene/acrylic N-butyl/acrylic acid/methacrylic acid/hydroxy-ethyl acrylate copolymerization
Thing emulsion, styrene/acrylic N-butyl/acrylic acid/methacrylic acid/hydroxypropyl acrylate copolymer emulsion, styrene/the third
Different monooctyl ester/acrylic acid/the methyl of olefin(e) acid N-butyl/acrylic acid/hydroxyethyl methacrylate copolymer emulsion, styrene/acrylic
AA emulsion, styrene/acrylic N-butyl/methyl methacrylate/acrylic acid/methacrylic acid copolymer breast
Liquid, one kind in styrene/acrylic N-butyl/acrylic acid/acrylamide/trimethoxyvinyl silane copolymer emulsion or
Two kinds of mixture, latex of copolymer in cinnamic acrylic ester can be effectively increased the tensile bond strength of waterproof material.
Further, wall of the invention high bond strength elastic water proofing paint, the cinnamic acrylic ester copolymerization
Thing emulsion is preferably styrene/acrylic N-butyl/methacrylic acid/acrylamide/trimethoxyvinyl silane copolymer
In emulsion, styrene/acrylic N-butyl/acrylic acid/acrylamide/trimethoxyvinyl silane copolymer emulsion at least
It is a kind of.
Further, wall of the invention high bond strength elastic water proofing paint, the cinnamic acrylic ester copolymerization
The glass transition temperature of thing emulsion is -30 DEG C to 0 DEG C, more preferably -20 DEG C to -8 DEG C, can be protected in the temperature range
Hold the optimal performance and processing performance of latex of copolymer in cinnamic acrylic ester.
The present invention wall high bond strength elastic water proofing paint, the Carboxy copolymer emulsion be butadiene/
Styrene/acrylic acid co-polymer emulsion, Butadiene/Styrene/methacrylic acid/trimethoxyvinyl silane copolymer breast
Liquid, Butadiene/Styrene/acrylic acid/methacrylic acid copolymer emulsion, Butadiene/Styrene/acrylamide copolymer breast
Liquid, Butadiene/Styrene/acrylic acid/acrylamide copolymer emulsion, Butadiene/Styrene/hydroxymethyl acrylamide copolymer
Emulsion, Butadiene/Styrene/acrylamide/hydroxymethyl acrylamide copolymer emulsion, Butadiene/Styrene/acrylic acid/the third
One kind in olefin(e) acid hydroxyl ethyl ester copolymer emulsion, Butadiene/Styrene/acrylic acid/hydroxyethyl methacrylate copolymer emulsion
Or two kinds of mixture, Carboxy copolymer emulsion and latex of copolymer in cinnamic acrylic ester collective effect, it is anti-to increase
Water material has larger contribution to tensile bond strength.
Further, wall of the invention high bond strength elastic water proofing paint, the Carboxy copolymer emulsion
Preferably Butadiene/Styrene/methacrylic acid/trimethoxyvinyl silane copolymer emulsion, Butadiene/Styrene/the third
At least one of acrylamide/hydroxymethyl acrylamide copolymer emulsion.
Further, wall of the invention high bond strength elastic water proofing paint, the Carboxy copolymer emulsion
Glass transition temperature be -10 DEG C to+20 DEG C, more preferably 0 DEG C to+15 DEG C, carboxylic can be kept in the temperature range
The optimal performance and processing performance of base butylbenzene copolymer emulsion.
The wall high bond strength elastic water proofing paint of the present invention, the nonionic surface active agent is poly- for alkyl phenol
At least one of oxygen vinethene, AEO；The wetting agent is sulfo-succinic acid diethylhexyl ester, fat
At least one of alcohol alkoxylates, silane-modified fatty alcohol alkoxy compound；The hydrophober be organic silicon hydrophober,
One kind in wax emulsion class hydrophober.
Preferably, wall of the invention high bond strength elastic water proofing paint, the cement is common silicic acid
32.5 grades of salt cement and ratings above, or 32.5 grades of white portland cement and ratings above；It is preferred that, the portland cement
From at least one of early-strength 42.5R, 52.5R, 62.5R Three Estate, or 42.5 grades of white portland cement extremely
Few one kind.
The wall high bond strength elastic water proofing paint of the present invention, the penetrant crystalline material is sodium methyl silicate, first
At least one of base potassium silicate, calcium methyl siliconate, sodium metasilicate；The auxiliary rheological agents be bentonite, attapulgite at least
It is a kind of；The water reducer is at least one in polycarboxylic acids dehydragent, naphthalenesulfonate water reducer, melamine class water reducer
Kind.
Preferably, the particle diameter of the quartz sand is 50-300 mesh；The particle diameter of the powdered whiting is 200-800
Mesh；The particle diameter of the talcum powder is 500-800 mesh.
The wall preparation method of high bond strength elastic water proofing paint of the present invention, comprises the following steps：
（1）Weigh the liquid material material of following deal：It is latex of copolymer in cinnamic acrylic ester, Carboxy copolymer emulsion, non-
Ionic surfactant, wetting agent, hydrophober, defoamer, mould inhibitor, water, are gradually added under stirring by said sequence
Enter into mixing plant and stir；
（2）Weigh the powder material of following deal：Cement, penetrant crystalline material, calcium formate, quartz sand, powdered whiting, talcum
Powder, lignocellulosic, auxiliary rheological agents, water reducer；
（3）By step under stirring（2）In powder material be added gradually to step（1）In mixed liquor material in,
Stirring forms the uniform slurry with mobile performance, as wall high bond strength elastic water proofing paint.
Preferably, the wall of the invention preparation method of high bond strength elastic water proofing paint, step（3）In
Mixture mixing time is 5 minutes.
The beneficial effects of the invention are as follows：The water-repellent paint infiltration anchorage technology of the present invention improves bonding of the coating to basic unit
Intensity simultaneously forms permanent binder course, solves polymer modified cement based waterproof coatings traditional at present in wall waterproof
Adhesion strength it is low, easily destroyed by shearing force, loss of properties on aging the problems such as, expand the use of polymer cement waterproof paint
Scope.The various finishing materials such as Pasting ceramic tile, marble, true mineral varnish on the waterproof coating layer and without the risk come off, extensively
In waterproofing work for the inner-outer wall of building, the safety and service life of building are improved.
Embodiment
With reference to embodiment, the present invention is further detailed explanation.
Embodiment 1
The weight ratio of a kind of wall high bond strength elastic water proofing paint, including liquid material and powder, liquid material and powder is 1：
2.5.In the present embodiment, the feed liquid is made up of the raw material of following weight fraction：Latex of copolymer in cinnamic acrylic ester（Benzene
Ethylene/acrylic acid N-butyl/acrylic acid/methacrylic acid copolymer emulsion）60%th, Carboxy copolymer emulsion（Butadiene/
Styrene/acrylic acid co-polymer emulsion）26%th, nonionic surface active agent 0.5%, wetting agent 0.2%, hydrophober 0.2%,
Defoamer Foamaster NXZ 0.2%, mould inhibitor LX150 0.05%, water 12.85%；The powder is by following weight fraction
Raw material is constituted：Portland cement 30%, potassium methyl silicate 8%, calcium formate 0.4%, quartz sand 50-140 mesh 40%, heavy
The mesh 9.9% of calcium carbonate 400, the mesh 10% of talcum powder 800, wood fibre Arbocel PWC500 0.5%, bentonite 1%, polycarboxylic acids
Water reducer SR 600P-H 0.2%.
The glass transition temperature of latex of copolymer in cinnamic acrylic ester described in the present embodiment is -15 DEG C, average grain
Footpath 220nm；The glass transition temperature of Carboxy copolymer emulsion is 12 DEG C, and average grain diameter is 150nm；Non-ionic surface
Activating agent is OP-40, belongs to APES class, and 20% concentration is diluted with water to when using；Wetting agent is BASF
Lumiten ISC, belong to sulfo-succinic acid diethylhexyl esters；Hydrophober is the BS205 of wacker chemicals, belongs to organosilicon
Class hydrophober；Portland cement is conch PO 42.5R；Bentonite is sodium bentonite.
The wall of the present embodiment preparation method of high bond strength elastic water proofing paint, comprises the following steps：
（1）Weigh the liquid material material of following deal：It is latex of copolymer in cinnamic acrylic ester, Carboxy copolymer emulsion, non-
Ionic surfactant, wetting agent, hydrophober, defoamer, mould inhibitor, water, are gradually added under stirring by said sequence
Enter into mixing plant and stir；
（2）Weigh the powder material of following deal：Cement, penetrant crystalline material, calcium formate, quartz sand, powdered whiting, talcum
Powder, lignocellulosic, auxiliary rheological agents, water reducer；
（3）By step under stirring（2）In powder material be added gradually to step（1）In mixed liquor material in,
Stirring forms the uniform slurry with mobile performance, as wall high bond strength elastic water proofing paint for 5 minutes.
The test performance of the present embodiment is：It is 2.8 Mpa without processing tensile strength；Without processing elongation at break 55%；Nowhere
Reason adhesion strength is 1.8 Mpa；Impermeability（0.3 Mpa hydraulic pressure, pressurize 30min）To pass through test；Other performances meet mark
The requirement of type III in quasi- GB/T 23445-2009.
Embodiment 2
The weight ratio of a kind of wall high bond strength elastic water proofing paint, including liquid material and powder, liquid material and powder is 1：2.
In the present embodiment, the feed liquid is made up of the raw material of following weight fraction：Latex of copolymer in cinnamic acrylic ester（Styrene/
N-butyl acrylate/acrylic acid/methacrylic acid/acrylamide copolymer emulsion and the different monooctyl ester/propylene of styrene/acrylic
The mixture of acid/methacrylic acid copolymer emulsion）65%th, Carboxy copolymer emulsion（Butadiene/Styrene/acryloyl
The mixture of amine copolymer thing emulsion and Butadiene/Styrene/acrylic acid/hydroxyethyl methacrylate copolymer emulsion）22%th, it is non-
Ionic surfactant 1.0%, wetting agent 0.3%, hydrophober 0.1%, defoamer Foamaster NXZ 0.3%, mould inhibitor
LX150 0.08%, water 11.22%；The powder is made up of the raw material of following weight fraction：Portland cement 35%, methyl
Potassium silicate 6%, calcium formate 0.5%, quartz sand 50-140 mesh 35%, the mesh 10.5% of powdered whiting 400, the mesh of talcum powder 800
12%th, wood fibre Arbocel PWC500 0.3%, bentonite 0.5%, polycarboxylate water-reducer SR 600P-H 0.2%.
The glass transition temperature of latex of copolymer in cinnamic acrylic ester described in the present embodiment is -20 DEG C, average grain
Footpath 220nm；The glass transition temperature of Carboxy copolymer emulsion is 15 DEG C, and average grain diameter is 150nm；Non-ionic surface
Activating agent is OP-40, belongs to APES class, and 20% concentration is diluted with water to when using；Wetting agent is BASF
Lumiten ISC, belong to sulfo-succinic acid diethylhexyl esters；Hydrophober is the BS205 of wacker chemicals, belongs to organosilicon
Class hydrophober；Portland cement is conch PO 42.5R；Bentonite is sodium bentonite.
The preparation method be the same as Example 1 of the wall of the present embodiment high bond strength elastic water proofing paint.
The test performance of the present embodiment is：It is 2.85 Mpa without processing tensile strength；Without processing elongation at break 57%；Nothing
Processing adhesion strength is 1.9 Mpa；Impermeability（0.3 Mpa hydraulic pressure, pressurize 30min）To pass through test；Other performances are met
The requirement of type III in standard GB/T 23445-2009.
Embodiment 3
The weight ratio of a kind of wall high bond strength elastic water proofing paint, including liquid material and powder, liquid material and powder is 1：3.
In the present embodiment, the feed liquid is made up of the raw material of following weight fraction：Latex of copolymer in cinnamic acrylic ester（Styrene/
N-butyl acrylate/methacrylic acid/acrylamide/trimethoxyvinyl silane copolymer emulsion and styrene/acrylic
The mixture of N-butyl/acrylic acid/acrylamide/trimethoxyvinyl silane copolymer emulsion）53%th, Carboxy copolymerization
Thing emulsion（Butadiene/Styrene/acrylic acid/methacrylic acid copolymer emulsion and Butadiene/Styrene/acrylamide copolymerization
The mixture of thing emulsion）27%th, nonionic surface active agent 1.2%, wetting agent 0.2%, hydrophober 0.3%, defoamer
Foamaster NXZ 0.2%, mould inhibitor LX150 0.1%, water 18%；The powder is made up of the raw material of following weight fraction：
Portland cement 45%, potassium methyl silicate 5%, calcium formate 0.3%, quartz sand 50-140 mesh 30%, powdered whiting 400
Mesh 8%, the mesh 10% of talcum powder 800, wood fibre Arbocel PWC500 0.2%, bentonite 0.6%, polycarboxylate water-reducer SR
600P-H 0.9%。
The glass transition temperature of latex of copolymer in cinnamic acrylic ester described in the present embodiment is -10 DEG C, average grain
Footpath 220nm；The glass transition temperature of Carboxy copolymer emulsion is 8 DEG C, and average grain diameter is 150nm；Non-ionic surface
Activating agent is OP-40, belongs to APES class, and 20% concentration is diluted with water to when using；Wetting agent is BASF
Lumiten ISC, belong to sulfo-succinic acid diethylhexyl esters；Hydrophober is the BS205 of wacker chemicals, belongs to organosilicon
Class hydrophober；Portland cement is conch PO 42.5R；Bentonite is sodium bentonite.
The preparation method be the same as Example 1 of the wall of the present embodiment high bond strength elastic water proofing paint.
The test performance of the present embodiment is：It is 2.9 Mpa without processing tensile strength；Without processing elongation at break 58%；Nowhere
Reason adhesion strength is 1.9 Mpa；Impermeability（0.3 Mpa hydraulic pressure, pressurize 30min）To pass through test；Other performances meet mark
The requirement of type III in quasi- GB/T 23445-2009.
Claims (10)
1. a kind of wall high bond strength elastic water proofing paint, it is characterised in that：Including feed liquid and powder, feed liquid and powder
Mass ratio is 1：（2-3）；
The feed liquid is prepared from the following raw materials in parts by weight：50-65 parts of latex of copolymer in cinnamic acrylic ester, carboxyl fourth
20-30 parts of benzene copolymer emulsion, 0.5-1.5 parts of nonionic surface active agent, 0.1-0.5 parts of wetting agent, hydrophober
0.1-0.5 parts, 0.1-0.5 parts of defoamer, 0.05-0.1 parts of mould inhibitor, 1.9-29.15 parts of water；
The powder is prepared from the following raw materials in parts by weight：25-45 parts of cement, 5-10 parts of penetrant crystalline material, calcium formate
0.2-0.8 parts, 30-50 parts of quartz sand, 5-15 parts of powdered whiting, 8-15 parts of talcum powder, lignocellulosic 0.1-0.5
Part, 0.5-1 parts of auxiliary rheological agents, 0.1-0.3 parts of water reducer.
2. a kind of wall high bond strength elastic water proofing paint according to claim 1, it is characterised in that：The benzene second
Alkene-acrylate copolymer emulsion is styrene/acrylic N-butyl/acrylic acid/methacrylic acid copolymer emulsion, benzene second
Alkene/n-butyl acrylate/methacrylic acid/acrylamide/trimethoxyvinyl silane copolymer emulsion, styrene/propylene
Sour N-butyl/acrylic acid/methacrylic acid/acrylamide copolymer emulsion, styrene/acrylic N-butyl/acrylic acid/methyl
Acrylic acid/hydroxyethylacrylate copolymer emulsion, styrene/acrylic N-butyl/acrylic acid/methacrylic acid/acrylic acid hydroxyl
Methacrylate-trimethoxysilyl propylmethacrylate copolymer emulsion, styrene/acrylic N-butyl/acrylic acid/hydroxyethyl methacrylate copolymer emulsion, styrene/
Isooctyl acrylate/acrylic acid/methacrylic acid copolymer emulsion, styrene/acrylic N-butyl/methyl methacrylate/
Acrylic acid/methacrylic acid copolymer emulsion, styrene/acrylic N-butyl/acrylic acid/acrylamide/trimethoxy ethene
The mixture of one or both of base silane copolymer emulsion.
3. a kind of wall high bond strength elastic water proofing paint according to claim 1 or 2, it is characterised in that：It is described
The glass transition temperature of latex of copolymer in cinnamic acrylic ester is -30 DEG C to 0 DEG C.
4. a kind of wall high bond strength elastic water proofing paint according to claim 3, it is characterised in that：The benzene second
The glass transition temperature of alkene-acrylate copolymer emulsion is -20 DEG C to -8 DEG C.
5. a kind of wall high bond strength elastic water proofing paint according to claim 1, it is characterised in that：The carboxyl
Butylbenzene copolymer emulsion is Butadiene/Styrene/AA emulsion, Butadiene/Styrene/methacrylic acid/front three
Ethoxy ethylene base silane copolymer emulsion, Butadiene/Styrene/acrylic acid/methacrylic acid copolymer emulsion, butadiene/benzene
Ethylene/propene amide copolymer emulsion, Butadiene/Styrene/acrylic acid/acrylamide copolymer emulsion, butadiene/benzene second
Alkene/hydroxymethyl acrylamide copolymer emulsion, Butadiene/Styrene/acrylamide/hydroxymethyl acrylamide copolymer emulsion,
Butadiene/Styrene/acrylic acid/hydroxyethylacrylate copolymer emulsion, Butadiene/Styrene/acrylic acid/hydroxyethyl methacrylate
The mixture of one or both of methacrylate copolymers emulsion.
6. a kind of wall high bond strength elastic water proofing paint according to claim 1 or 5, it is characterised in that：It is described
The glass transition temperature of carboxylic styrene butadiene latex is -10 DEG C to+20 DEG C.
7. a kind of wall high bond strength elastic water proofing paint according to claim 6, it is characterised in that：The carboxyl
The glass transition temperature of butylbenzene copolymer emulsion is 0 DEG C to+15 DEG C.
8. a kind of wall high bond strength elastic water proofing paint according to claim 1, it is characterised in that：It is described it is non-from
Subtype surfactant is at least one of APES, AEO；The wetting agent is sulphur
At least one of base succinic acid diethylhexyl ester, fatty alcohol alkoxy compound, silane-modified fatty alcohol alkoxy compound；Institute
It is one kind in organic silicon hydrophober, wax emulsion class hydrophober to state hydrophober.
9. a kind of wall high bond strength elastic water proofing paint according to claim 1, it is characterised in that：The infiltration
Crystalline material is at least one of sodium methyl silicate, potassium methyl silicate, calcium methyl siliconate, sodium metasilicate；The auxiliary rheological agents are
At least one of bentonite, attapulgite；The water reducer is polycarboxylic acids dehydragent, naphthalenesulfonate water reducer, trimerization
At least one of cyanamide class water reducer.
10. a kind of preparation method of wall high bond strength elastic water proofing paint according to claim 1, its feature exists
In：Comprise the following steps：
（1）Weigh the liquid material material of following deal：It is latex of copolymer in cinnamic acrylic ester, Carboxy copolymer emulsion, non-
Ionic surfactant, wetting agent, hydrophober, defoamer, mould inhibitor, water, are gradually added under stirring by said sequence
Enter into mixing plant and stir；
（2）Weigh the powder material of following deal：Cement, penetrant crystalline material, calcium formate, quartz sand, powdered whiting, talcum
Powder, lignocellulosic, auxiliary rheological agents, water reducer；
（3）By step under stirring（2）In powder material be added gradually to step（1）In mixed liquor material in,
Stirring forms the uniform slurry with mobile performance, as wall high bond strength elastic water proofing paint.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108218292A (en) * | 2018-01-23 | 2018-06-29 | 合肥峰腾节能科技有限公司 | A kind of preparation method of new waterproof composite material |
| CN108395175A (en) * | 2018-04-09 | 2018-08-14 | 福州市鸿生建材有限公司 | A kind of fly ash base composite copolymerization closes object concrete and preparation method thereof |
| CN109111167A (en) * | 2018-08-10 | 2019-01-01 | 安徽朗凯奇建材有限公司 | A kind of stretch-proof cementitious capillary waterproofing material |
| CN109485346A (en) * | 2018-12-25 | 2019-03-19 | 佛山科学技术学院 | A kind of ceramic tile marble adhesive and preparation method thereof |
| CN110145039A (en) * | 2019-06-20 | 2019-08-20 | 北京中核北研科技发展股份有限公司 | A kind of acrylate copolymer polyester blank in-place forming macromolecule coiled material and construction method |
| CN110386788A (en) * | 2019-08-05 | 2019-10-29 | 广州丽天防水材料有限公司 | A kind of JS cement base anti-counterfeit paint, Preparation method and use |
| CN110526649A (en) * | 2019-09-18 | 2019-12-03 | 重庆兴渝新材料研究院有限公司 | A kind of bi-component polymeric cement base Nano waterproof paint and preparation method thereof |
| CN110643249A (en) * | 2019-10-30 | 2020-01-03 | 广州全系建材有限公司 | Inner film-forming waterproof coating and preparation method thereof |
| CN111218179A (en) * | 2019-12-11 | 2020-06-02 | 湖南神州皓绿科技发展有限公司 | Waterproof coating and preparation method and application thereof |
| CN111378329A (en) * | 2018-12-27 | 2020-07-07 | 中路高科交通检测检验认证有限公司 | Polymer cement elastic protective coating composition and homogenization method |
| CN113174153A (en) * | 2021-03-11 | 2021-07-27 | 苏州金螳螂建筑装饰股份有限公司 | Multifunctional waterproof reinforced coating and preparation method and construction method thereof |
| CN113898143A (en) * | 2020-07-06 | 2022-01-07 | 苏州金螳螂建筑装饰股份有限公司 | Wading area stone material pathological change protection design and construction method thereof |
| CN114149197A (en) * | 2021-12-13 | 2022-03-08 | 烟台大学 | Concrete inner surface hydrophobic treatment agent and preparation method thereof |
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| CN108218292A (en) * | 2018-01-23 | 2018-06-29 | 合肥峰腾节能科技有限公司 | A kind of preparation method of new waterproof composite material |
| CN108395175A (en) * | 2018-04-09 | 2018-08-14 | 福州市鸿生建材有限公司 | A kind of fly ash base composite copolymerization closes object concrete and preparation method thereof |
| CN109111167A (en) * | 2018-08-10 | 2019-01-01 | 安徽朗凯奇建材有限公司 | A kind of stretch-proof cementitious capillary waterproofing material |
| CN109111167B (en) * | 2018-08-10 | 2020-11-24 | 安徽朗凯奇建材有限公司 | Stretch-proofing cement-based capillary crystalline waterproof material |
| CN109485346A (en) * | 2018-12-25 | 2019-03-19 | 佛山科学技术学院 | A kind of ceramic tile marble adhesive and preparation method thereof |
| CN111378329A (en) * | 2018-12-27 | 2020-07-07 | 中路高科交通检测检验认证有限公司 | Polymer cement elastic protective coating composition and homogenization method |
| CN110145039A (en) * | 2019-06-20 | 2019-08-20 | 北京中核北研科技发展股份有限公司 | A kind of acrylate copolymer polyester blank in-place forming macromolecule coiled material and construction method |
| CN110386788B (en) * | 2019-08-05 | 2021-11-09 | 丽天防水科技有限公司 | JS cement-based anti-counterfeiting coating, preparation method and application |
| CN110386788A (en) * | 2019-08-05 | 2019-10-29 | 广州丽天防水材料有限公司 | A kind of JS cement base anti-counterfeit paint, Preparation method and use |
| CN110526649A (en) * | 2019-09-18 | 2019-12-03 | 重庆兴渝新材料研究院有限公司 | A kind of bi-component polymeric cement base Nano waterproof paint and preparation method thereof |
| CN110643249A (en) * | 2019-10-30 | 2020-01-03 | 广州全系建材有限公司 | Inner film-forming waterproof coating and preparation method thereof |
| CN111218179A (en) * | 2019-12-11 | 2020-06-02 | 湖南神州皓绿科技发展有限公司 | Waterproof coating and preparation method and application thereof |
| CN113898143A (en) * | 2020-07-06 | 2022-01-07 | 苏州金螳螂建筑装饰股份有限公司 | Wading area stone material pathological change protection design and construction method thereof |
| CN113174153A (en) * | 2021-03-11 | 2021-07-27 | 苏州金螳螂建筑装饰股份有限公司 | Multifunctional waterproof reinforced coating and preparation method and construction method thereof |
| CN114149197A (en) * | 2021-12-13 | 2022-03-08 | 烟台大学 | Concrete inner surface hydrophobic treatment agent and preparation method thereof |
| CN114149197B (en) * | 2021-12-13 | 2022-06-21 | 烟台大学 | Concrete inner surface hydrophobic treatment agent and preparation method thereof |
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