CN106984095B - Air filter and air purifier including air filter - Google Patents

Air filter and air purifier including air filter Download PDF

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Publication number
CN106984095B
CN106984095B CN201611258936.XA CN201611258936A CN106984095B CN 106984095 B CN106984095 B CN 106984095B CN 201611258936 A CN201611258936 A CN 201611258936A CN 106984095 B CN106984095 B CN 106984095B
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China
Prior art keywords
air filter
layer
air
catalyst
activated carbon
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CN201611258936.XA
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Chinese (zh)
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CN106984095A (en
Inventor
王藜
黄凯
刘海林
曹新华
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Honeywell Environmental and Combustion Controls Tianjin Co Ltd
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Honeywell Environmental and Combustion Controls Tianjin Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8668Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/88Handling or mounting catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0407Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/08Special characteristics of binders
    • B01D2239/083Binders between layers of the filter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Filtering Materials (AREA)

Abstract

The present invention relates to air filter and including the air purifier of air filter.Specifically, the present invention relates to air filters, it includes the first tissue layer, the second tissue layer, the filtering material being arranged between the first and second tissue layers, and jointing material, wherein the filtering material includes the combination of formaldehyde catalyst, modified activated carbon or both, and wherein the jointing material includes polyolefin hot-melt.

Description

Air filter and air purifier including air filter
Technical field
The present invention relates to a kind of air filter and the air purifier including the air filter.Specifically Ground, the present invention relates to the combined air filter for including modified activated carbon, formaldehyde catalyst or both and including described The air purifier of air filter.
Background technique
Today's society, air pollution is increasingly severe, this seriously affects the health of people.People generally use air Clarifier removes the pollutant in air.Filter device is the important component in some air purifiers, passes through filter device Harmful substance in air such as particle and pernicious gas are removed.Air purifier including filter device be in this field Know.
Although air filter be it is known, the more outstanding air filter of performance is provided and is advantageous.This Invention provides performance and obtains improved air filter.
Summary of the invention
One aspect of the present invention is related to air filter, such as folder charcoal cloth comprising the first tissue layer, the second fabric Layer, the filtering material and jointing material being arranged between the first and second tissue layers, wherein the filtering material includes that formaldehyde is urged The combination of agent, modified activated carbon or both, and wherein the jointing material includes polyolefin hot-melt.
Another aspect of the present invention is related to air purifier comprising air filter of the invention.
Specific embodiment
Air filter of the invention includes the first tissue layer, the second tissue layer, between the first and second tissue layers The filtering material and jointing material of setting, wherein the filtering material includes the group of formaldehyde catalyst, modified activated carbon or both It closes, and wherein the jointing material includes polyolefin hot-melt.Air filter of the invention generally can be used for sky Tune, air purifier etc., such as Household Air Purifier.
In air filter of the invention, the jointing material is for making first tissue layer, the second tissue layer It is combined together to form the filter device with filtering material etc..The jointing material of the invention includes polyolefin hot melt Glue, the preferably described jointing material are selected from polyolefin hot-melt.Various hot melt adhesive as known in the art can be used.Generally Ground, the polyolefin hot-melt can be selected from polyethylene hot-melt adhesive, polypropylene thermal melten gel and amorphous state alpha olefin copolymer (Amorphous poly alpha olefin, APAO) hot melt adhesive.According to a preferred embodiment, the jointing material is Polyethylene hot-melt adhesive.As would be known to one of skill in the art, hot melt adhesive is other than making binder resin as main component, It may also include some other ingredients, such as tackifier, antioxidant etc..For polyethylene hot-melt adhesive, low-density can be used Polyethylene or high density polyethylene (HDPE).According to a preferred embodiment, polyethylene hot-melt adhesive of the invention uses low molecular weight Polyethylene is as resin raw material.The relative molecular weight of the low molecular weight polyethylene can be about 500- about 5000 and melt Index (ASTM D 1238) can be about 2- about 100g/10min.According to an embodiment, the density of polyethylene hot-melt adhesive < 0.94g/cm3, softening point are about 120 DEG C of about 60-.
The present inventor in air filter surprisingly it has been found that by using polyolefin hot-melt, phase For using other hot melt adhesive, such as it is now generally used for the EVA glue etc. of air filter preparation, air mistake can be improved The strainability for filtering device especially can significantly improve air filter and place or be removed using formaldehyde after a period of time The reduction of performance.
In air filter of the invention, the amount of the jointing material is typically about about 35 weight % of 5-, preferably from about About 25 weight % of 10-, by air filter be 100 weight % in terms of.
In air filter of the invention, first tissue layer and the second tissue layer are for accommodating or supporting to filter Material.First and second tissue layer can be various fabrics, including woven fabric, knitted fabric, adhesive-bonded fabric etc..Example Such as, first tissue layer and the second tissue layer can be the tissue layer commonly used in air filter.Described first and Two tissue layers can be identical or different.Preferably, the described first and/or second tissue layer is nonwoven fabric layer.As an example, nothing Fabric layer can be selected from PET nonwoven fabric layer, PP nonwoven fabric layer and PET/PE composite nonwoven fabric nitride layer.The system of these fabrics Standby is all known in the art.
It can also include other in addition to the first tissue layer and the second tissue layer in air filter of the invention Layer, such as other tissue layer or functional layer.In one embodiment, air filter of the invention further include one layer or Multi-layer H EPA (High-efficiency particulate arrestance) layer.Preferably, the HEPA layer choosing autohemagglutination third HEPA layers of alkene (PP), HEPA layers of polyethylene terephthalate (PET), HEPA layers of glass fibre, polytetrafluoroethylene (PTFE) (PTFE) HEPA layers and their combination.These HEPA layers is known in the art.For example, HEPA layers can be set The inner or outer side of one tissue layer and/or the second tissue layer.
In air filter of the invention, the total amount of the tissue layer is typically about about 60 weight % of 15-, preferably from about About 50 weight % of 25-, by air filter be 100 weight % in terms of.
In air filter of the invention, the filtering material includes formaldehyde catalyst, modified activated carbon or both Combination.The filtering material is usually arranged between the first tissue layer and the second tissue layer with stratiform.
Filtering material of the invention may include formaldehyde catalyst.For human health, the formaldehyde right and wrong in air are removed It is often necessary.Formaldehyde catalyst is usually used for catalysis formaldehyde and reacts, such as oxidation reaction occurs, to remove formaldehyde. Usual formaldehyde catalyst can be selected from noble metal catalyst and catalyst of transition metal oxide etc..Noble metal catalyst is for example It is the noble metals such as Pt, Pd, Au, Ag, can be optionally supported on different types of carrier.SiO can be used in carrier2、Al2O3、 TiO2、CeO2、Fe2O3、Co3O4、MnO2With molecular sieve etc..Transition metal in catalyst of transition metal oxide for example can be with It is Mn, Co, Fe, Cr etc..MnO can be used for example in catalyst of transition metal oxide2、Co3O4And Cr2O3Deng.It can be to mistake Metal oxide is crossed to be doped to be made O composite metallic oxide catalyst, for example, can with the elements such as Ce, Sn, Cu and Zr into Row doping.Formaldehyde catalyst of the invention can be powder, particle, rodlike, column etc..This field has can be used in the present invention The various formaldehyde catalysts known.It is, for example, possible to use the purifying formaldehyde particles of flourishing age health Environmental Protection Technology Co., Ltd or powder to make For formaldehyde catalyst.
In air filter of the invention, the amount of the formaldehyde catalyst is typically about about 55 weight % of 15-, preferably About 45 weight % of about 20-, by air filter be 100 weight % in terms of.
In air filter of the invention, the filtering material may include modified activated carbon.Modified activated carbon is The material well known by persons skilled in the art that can be used for air purifier.Modified activated carbon used in the present invention can be this Commonly used in the modified activated carbon in air filter in field.It can be selected from for the modified activated carbon in the present invention wooden Active carbon is preferably selected from sawdust class active carbon, shell class active carbon, coconut husk class active carbon and biomass class active carbon, most preferably Coconut husk class active carbon.Modified activated carbon of the invention can have various shape, including powder, particle, column etc..Active carbon Modification be known in the art.Preferably, the modified activated carbon that the present invention uses is to remove and be modified for formaldehyde.Needle The modification carried out to active carbon can carry out in many ways, such as may include: that (1) is strong by potassium permanganate or manganese dioxide etc. Oxidant loads on the activated carbon;(2) being modified to active carbon makes its surface have amino-NH2Or imino group=NH active group Group;(3) on the activated carbon by ammonium salt load;Etc..
In air filter of the invention, the amount of the modified activated carbon is typically about about 35 weight % of 2-, preferably from about About 25 weight % of 5-, by air filter be 100 weight % in terms of.
According to a preferred embodiment of the invention, filtering material of the invention includes simultaneously formaldehyde catalyst and modification Active carbon.
In a preferred embodiment, the air filter of the invention is folder charcoal cloth.Pressing from both sides charcoal cloth is ability Known to domain, tissue layer and the active carbon layer between tissue layer are generally included.Folder charcoal cloth of the invention includes of the invention First tissue layer, the second tissue layer, the filtering material of the invention being arranged between the first and second tissue layers and of the invention Jointing material, wherein the filtering material includes at least one modified activated carbon and formaldehyde catalyst, and the wherein bonding Material includes polyolefin hot-melt, and the preferably described jointing material is selected from polyolefin hot-melt.First tissue layer, second are knitted Nitride layer, jointing material, active carbon and formaldehyde catalyst can be as described above.Ability can be used in folder charcoal cloth of the invention The preparation of method known to domain.Generally, press from both sides charcoal cloth preparation include setting tissue layer, between tissue layer be arranged filtering material and Jointing material is heated later and is suppressed.It can also be folded after obtaining folder charcoal cloth to obtain required construction and shape Shape.
Air filter of the invention, such as folder charcoal cloth can select suitable shape according to the requirement of air evolution device Shape, such as can be flat shape, or other shapes, such as tubular.
The invention further relates to air purifiers, use the air filter of the invention.Air purifier is this Known to field, shell, filter device, air transport device, control device etc. are generally included.Air filtration dress of the invention It sets when for air purifier, can for longer periods keep the formaldehyde removal capacity of air purifier.
Below the present invention will be further illustrated by following non-limiting examples.
Embodiment
Equipment
Methylene oxide detecting instrument: PPM company, Britain methylene oxide detecting instrument, model htv-m
Raw material
PP spun-bonded non-woven fabrics 50g/m2
EVA glue: EVA rubber powder, Guangzhou Wei Wang Plastic Products Co., Ltd
Polyamide hot-melt adhesive powder: T0556, Foshan Yi get adhesive Co., Ltd
Polyethylene glue: PE hot-melt adhesive powder SD-775, Shenzhen is as deep as Environmental-friendhot hot melt adhesive factory
Formaldehyde catalyst: model F1.5Z-2.0, flourishing age health Environmental Protection Technology Co., Ltd
Modified activated carbon: QX- charcoal, Demos Environmental Protection Technology Co., Ltd, Shenzhen
The preparation of sample (air filter)
Place one layer of PP non-woven fabrics;Filtering material and jointing material are laid on PP non-woven fabrics;It is put on filtering material layer Set second layer PP non-woven fabrics;It heats and suppresses.In terms of being 100 weight % by sample, non-woven fabrics gross weight 50%, jointing material weight is 15%, filter material weight 35%.
The test of sample
Use 3m3The formaldehyde removal efficiency of closed environment test chamber test sample.
Sample (10 × 10cm made above is provided2).Sample is fixed in the blower in test chamber.In test chamber Formaldehyde is added.The concentration (initial concentration, 0 minute) of formaldehyde in test chamber is measured before blower starts.It is opened while blower starts Beginning timing.Blower, which starts, makes the air in test chamber cycle through sample with 1.5m/s.It measures at regular intervals and records survey Try the concentration of formaldehyde in cabin.
The formaldehyde removal rate of 1. sample of table
From upper table it can be clearly seen that unexpectedly, when using polyethylene glue, the formaldehyde of sample after 60 days is gone Except efficiency is kept substantially;Wherein for formaldehyde catalyst, formaldehyde removal rate is only down to 70% by 72%;For modified active Charcoal, formaldehyde removal rate are only down to 58% by 62%.Different from polyethylene glue, gone using the formaldehyde of EVA glue and the sample of polyamide glue Except efficiency significantly reduces after 60 days.

Claims (16)

1. a kind of air filter comprising the first tissue layer, the second tissue layer are arranged between the first and second tissue layers Filtering material and jointing material, wherein the filtering material includes the combination of formaldehyde catalyst, modified activated carbon or both, And wherein the jointing material includes polyolefin hot-melt.
2. air filter as described in claim 1, wherein the polyolefin hot-melt is selected from polyethylene hot-melt adhesive, poly- third Alkene hot melt adhesive and APAO hot melt adhesive.
3. air filter as described in claim 1, wherein the jointing material is polyethylene hot-melt adhesive.
4. air filter as claimed in any one of claims 1-3, wherein the described first and/or second tissue layer is nothing Fabric layer.
5. air filter as claimed in claim 4, wherein the described first and/or second tissue layer is selected from PET on-woven Nitride layer, PP nonwoven fabric layer and PET/PE composite nonwoven fabric nitride layer.
6. air filter as claimed in any one of claims 1-3 further includes HEPA layers.
7. air filter as claimed in claim 6, wherein the HEPA layer choosing is from HEPA layers of PP, HEPA layers of PET, glass HEPA layers of glass fiber, HEPA layers of PTFE and their combination.
8. air filter as claimed in any one of claims 1-3, wherein the modified activated carbon is selected from wooden activity Charcoal.
9. air filter as claimed in claim 8, wherein the modified activated carbon is selected from sawdust class active carbon, shell class Active carbon, coconut husk class active carbon and biomass class active carbon.
10. air filter as claimed in claim 9, wherein the modified activated carbon is selected from coconut husk class active carbon.
11. air filter as claimed in any one of claims 1-3, wherein the modified activated carbon is gone for formaldehyde It removes and is modified.
12. air filter as claimed in any one of claims 1-3, wherein the formaldehyde catalyst is urged selected from noble metal Agent and catalyst of transition metal oxide.
13. air filter as claimed in claim 12, wherein the noble metal catalyst is selected from Pt, Pd, Au and Ag, institute The transition metal stated in catalyst of transition metal oxide is selected from Mn, Co, Fe and Cr, and the transition metal oxide is optional It is doped.
14. air filter as claimed in claim 13, wherein the transition metal oxide optionally by selected from Ce, Sn, The element doping of Cu and Zr.
15. air filter as claimed in any one of claims 1-3, wherein the air filter is folder charcoal cloth.
16. a kind of air purifier comprising the air filter as described in any one of claim 1-15.
CN201611258936.XA 2016-12-30 2016-12-30 Air filter and air purifier including air filter Active CN106984095B (en)

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CN106984095B true CN106984095B (en) 2019-10-18

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107569967B (en) * 2017-08-21 2019-10-29 杭州创克洛环境科技有限公司 It is a kind of for formaldehyde adsorption and the vehicle-mounted air purification piece of TVOC and preparation method thereof
GB201812655D0 (en) * 2018-08-03 2018-09-19 Dyson Technology Ltd A filter assembly for a fan
CN109260823A (en) * 2018-11-07 2019-01-25 北京福田戴姆勒汽车有限公司 A kind of filter core of automotive air-conditioner activated carbon filtering cloth material and its preparation process
CN109603407A (en) * 2018-11-30 2019-04-12 广东骏亚电子科技股份有限公司 A kind of wiring board production waste gas processing method
CN111714965A (en) * 2020-06-09 2020-09-29 艾易西(中国)环保科技有限公司 Sterilization and disinfection composite filter material and preparation method and application thereof

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Publication number Priority date Publication date Assignee Title
JP2002017832A (en) * 2000-07-03 2002-01-22 Tennex Corp Deodorizing filter and its manufacturing method
DE10318053B4 (en) * 2003-04-17 2008-08-14 BLüCHER GMBH Adsorption filter material with high adsorption capacity and low penetration behavior and its use
CN104258636B (en) * 2014-05-19 2016-08-24 中材科技股份有限公司 A kind of air purification filter material and preparation method thereof
CN105066320A (en) * 2015-08-27 2015-11-18 北京米微环保科技有限公司 Method for purifying indoor air
CN205295805U (en) * 2015-12-03 2016-06-08 北京亚都环保科技有限公司 Compound air purification filter paper and use its filter core

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