CN106967545A - A kind of soap and preparation method thereof - Google Patents
A kind of soap and preparation method thereof Download PDFInfo
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- CN106967545A CN106967545A CN201710188648.XA CN201710188648A CN106967545A CN 106967545 A CN106967545 A CN 106967545A CN 201710188648 A CN201710188648 A CN 201710188648A CN 106967545 A CN106967545 A CN 106967545A
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- soap
- glycol
- ethylene glycol
- aeo
- soap according
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention is a kind of soap and preparation method thereof, and soap is made up of following raw material, neat soap, glycerine, essence, complexing agent, nonionic surfactant, auxiliary agent and deionized water.The preparation process of soap is as follows：Add raw materials into mixer and be uniformly mixed, mixed material is delivered to grinder and carries out homogeneous, homogenizing temperature is controlled at 30 DEG C 40 DEG C, the good material of homogeneous is delivered in duplex vacuum machine again and carries out being refining to obtain soap body, extraction temperature is controlled at 60 DEG C 70 DEG C, soap body after refined produces product through stripping and slicing.Soapy appearance of the present invention is vivid, can add more on-soap fillers, and sliver exporting speed is fast, it is not easy to ftracture；Also there is good hard water resistance performance and antiredeposition performance simultaneously, plasticity is good, and excellent combination property, the preparation method of this soap is simple to operation, convenient for production, and cost is low.
Description
Technical field
The present invention relates to a kind of soap, more particularly to a kind of soap of good combination property.The invention further relates to the soap
Preparation method.
Background technology
Soap is indispensable commodity in people's daily life.The raw material for preparing soap is various, obtained fertilizer
Soap also has various performances.In picture Publication No. CN1130922A and CN102433230A patent, what disclosed technology was used
Composition additive, price is higher, and the simply simple transparency for improving soap body, and other performance can not body well
It is existing.Also there is hard water resistance performance and antiredeposition poor performance in other existing soap bodies, sliver exporting speed is slow, easy problems of crack.
The content of the invention
The technical problems to be solved by the invention are that there is provided a kind of fertilizer of excellent combination property in view of the shortcomings of the prior art
Soap.
The invention further relates to a kind of preparation method of the soap.
The technical problems to be solved by the invention are realized by following technical scheme, and the present invention is a seed manure
Soap, is characterized in：It is made up of the raw material of following mass percent, and 63-78% neat soaps, 0.4-6% glycerine, 0.2-0.6% are fragrant
Essence, 0.05-0.4% complexing agents, 0.4-3% nonionic surfactants, 0.4-2.1% auxiliary agents, 20-25% deionized waters.
The technical problems to be solved by the invention can also further be realized by following technical scheme, described fertilizer
In soap：Described nonionic surfactant be AEO, polyethylene glycol, block copolymer, polyacrylate,
One or more in ethylene glycol distearyl acid fat, APG or APG ethoxylate.
Nonionic surfactant of the present invention can also be all conventional nonionic surfaces for manufacturing soap
Activating agent, they can be used alone, and two or more can also use cooperatively, preferably two or more to use cooperatively.
The technical problems to be solved by the invention can also further be realized by following technical scheme, described fertilizer
In soap：Described nonionic surfactant is AEO, polyethylene glycol and glycol distearate, fat
The mass percent of alcohol APEO, polyethylene glycol and glycol distearate is 0.1-0.7%：0.2-0.8%：0-
2.0%。
The technical problems to be solved by the invention can also further be realized by following technical scheme, described fertilizer
In soap：The AEO includes 8-20 carbon atom, preferably includes 12-18 carbon atom.
The technical problems to be solved by the invention can also further be realized by following technical scheme, described fertilizer
In soap：The AEO includes 3-80 oxirane（EO）, preferably include 7-60 oxirane（EO）, more
It is preferred that 30-60 oxirane（EO）.
The technical problems to be solved by the invention can also further be realized by following technical scheme, described fertilizer
In soap：The molecular weight of the polyethylene glycol includes 200-6000, most preferably more preferably 300-4000,400-1000.
The technical problems to be solved by the invention can also further be realized by following technical scheme, described fertilizer
In soap：The structural formula of described block copolymer is R-EO（Oxirane）-PO（Expoxy propane）Or R-PO-EO or EO-
PO-EO or PO-EO-PO or EO and PO random blocks, wherein R refer to diethylene glycol, natural fatty alcohol, synthetic fatty alcohol or
Branched fatty alcohol.
The technical problems to be solved by the invention can also further be realized by following technical scheme, described fertilizer
In soap：Described auxiliary agent is triethanolamine, ethylene glycol, propane diols, diethylene glycol, DPG, castor oil or trihydroxy methyl third
One or more in alkane.Auxiliary agent can be not limited to above-mentioned listed, and the product of hydroxyl structure belongs to protection domain.
The technical problems to be solved by the invention can also further be realized by following technical scheme, described fertilizer
In soap：Described auxiliary agent is triethanolamine, ethylene glycol and propane diols, the mass percent of triethanolamine, ethylene glycol and propane diols
For 0.1-0.5%：0-0.4%：0-0.4%.
The technical problems to be solved by the invention are realized by following technical scheme, the present invention be it is a kind of as above
The preparation method for the soap stated, is characterized in：Its step is as follows：By neat soap, glycerine, essence, complexing agent, non-ionic surface active
Agent, auxiliary agent and deionized water are added to be uniformly mixed in mixer, and mixed material is delivered into grinder carries out homogeneous,
Control homogenizing temperature at 30 DEG C -40 DEG C, then by the good material of homogeneous be delivered in duplex vacuum machine carry out be refining to obtain soap body, control
Extraction temperature processed is at 60 DEG C -70 DEG C, and the soap body after refining produces product through stripping and slicing.
Compared with prior art, soapy appearance of the present invention is vivid, can add more on-soap fillers, sliver exporting speed
It hurry up, it is not easy to ftracture；Also there is good hard water resistance performance and antiredeposition performance simultaneously, plasticity is good, excellent combination property, this
The preparation method of soap is simple to operation, convenient for production, and cost is low.
Embodiment
Concrete technical scheme of the invention described further below, in order to which those skilled in the art is further understood that
The present invention, without constituting the limitation to its right.
Embodiment 1, a kind of soap, it is made up of the raw material of following mass percent, 63% neat soap, 6% glycerine, 0.6% perfume
Essence, 0.4% complexing agent, 3% nonionic surfactant, 2% auxiliary agent, 25% deionized water.
Embodiment 2, a kind of soap, it is made up of the raw material of following mass percent, 78% neat soap, 0.9% glycerine,
0.2% essence, 0.1% complexing agent, 0.4% nonionic surfactant, 0.4% auxiliary agent, 20% deionized water.
Embodiment 3, a kind of soap, it is made up of the raw material of following mass percent, 70% neat soap, 3% glycerine, 0.4% perfume
Essence, 0.2% complexing agent, 1.4% nonionic surfactant, 1% auxiliary agent, 24% deionized water.
Embodiment 4, a kind of soap, it is made up of the raw material of following mass percent, 75% neat soap, 2% glycerine, 0.5% perfume
Essence, 0.25% complexing agent, 1.25% nonionic surfactant, 1% auxiliary agent, 21% deionized water.
Embodiment 5, the soap described in embodiment 1-4, described nonionic surfactant is AEO,
The sour fat of polyethylene glycol, block copolymer, polyacrylate, ethylene glycol distearyl, APG or APG ethoxylate
In one or more.
Embodiment 6, the soap described in embodiment 5, described nonionic surfactant is AEO, gathered
Ethylene glycol and glycol distearate, the quality hundred of AEO, polyethylene glycol and glycol distearate
Divide than being 0.1%：0.2%：0.5%.
Embodiment 7, the soap described in embodiment 5, described nonionic surfactant is AEO, gathered
Ethylene glycol and glycol distearate, the quality hundred of AEO, polyethylene glycol and glycol distearate
Divide than being 0.7%： 0.8%： 2%.
Embodiment 8, the soap described in embodiment 5, described nonionic surfactant is AEO, gathered
Ethylene glycol and glycol distearate, the quality hundred of AEO, polyethylene glycol and glycol distearate
Divide than being 0.5%：0.4%：1%.
Embodiment 9, the soap described in embodiment 6-8, the AEO includes 12 carbon atoms.
Embodiment 10, the soap described in embodiment 6-8, the AEO includes 18 carbon atoms.
Embodiment 11, AEO described in the soap described in embodiment 6-8 includes 30 EO.
Embodiment 12, AEO described in the soap described in embodiment 6-8 includes 60 EO.
Embodiment 13, the soap described in embodiment 5, the molecular weight of the polyethylene glycol is 400.
Embodiment 14, the soap described in embodiment 5, the molecular weight of the polyethylene glycol is 800.
Embodiment 15, the soap described in embodiment 5, the structural formula of described block copolymer is R-EO-PO or R-PO-
EO or EO-PO-EO or PO-EO-PO or EO and PO random blocks, wherein R refer to diethylene glycol, natural fatty alcohol, conjunction
Into fatty alcohol or branched fatty alcohol.
Embodiment 16, the soap described in embodiment 1-4, described auxiliary agent is triethanolamine, ethylene glycol, propane diols, diethyl
One or more in glycol, DPG, castor oil or trimethylolpropane.
Embodiment 17, the soap described in embodiment 16, described auxiliary agent is triethanolamine, ethylene glycol and propane diols, three second
The mass percent of hydramine, ethylene glycol and propane diols is 0.1%：0.1%：0.1%.
Embodiment 18, the soap described in embodiment 16, described auxiliary agent is triethanolamine, ethylene glycol and propane diols, three second
The mass percent of hydramine, ethylene glycol and propane diols is 0.5%： 0.4%： 0.4%.
Embodiment 19, the soap described in embodiment 16, described auxiliary agent is triethanolamine, ethylene glycol and propane diols, three second
The mass percent of hydramine, ethylene glycol and propane diols is 0.3%：0.2%：0.3%.
Embodiment 20, a kind of soap, it is made up of the raw material of following mass percent, 78% neat soap, 0.45% glycerine,
0.2% essence, 0.05% complexing agent, 0.85% nonionic surfactant, 0.45% auxiliary agent, 20% deionized water；The nonionic table
Face activating agent is AEO, polyethylene glycol and glycol distearate, AEO, poly- second two
The mass percent of alcohol and glycol distearate is 0.1%：0.2%：0.5%, the AEO includes 15
Carbon atom, 50 EO；The molecular weight of the polyethylene glycol is 400, and the auxiliary agent is triethanolamine, ethylene glycol and propane diols,
The mass percent of triethanolamine, ethylene glycol and propane diols is 0.1%：0.3%：0.4%.
A kind of embodiment 21, preparation method of the soap as described in embodiment 1-19, its step is as follows：By 75kg neat soaps,
0.1kg glycerine, 0.2kg essence, 0.05kg complexing agents, 0.6kg polyethylene glycol 400s, 0.24kg triethanolamines, 0.6kg fatty alcohols
APEO, 20kg deionized waters are added to be uniformly mixed in mixer, and mixed material is delivered into grinder enters
Row homogeneous, control homogenizing temperature at 35 DEG C, then by the good material of homogeneous be delivered in duplex vacuum machine carry out be refining to obtain soap body,
Extraction temperature is controlled at 65 DEG C, the soap body after refining produces product through dicer roll printing stripping and slicing.
A kind of embodiment 22, preparation method of the soap as described in embodiment 1-19, its step is as follows：By 78g neat soaps, 0.9g
Glycerine, 0.2kg essence, 0.1g complexing agents, 0.7g polyethylene glycol 400s, 0.6kg AEOs, 1kg ethylene glycol two are hard
Resin acid ester, 0.24kg triethanolamines, 0.2kg ethylene glycol, 0.3kg propane diols, 20kg deionized waters, which are added in mixer, stirs mixed
Close uniform, mixed material is delivered into grinder carries out homogeneous, control homogenizing temperature is at 35 DEG C, then by the good material of homogeneous
It is delivered in duplex vacuum machine and carries out being refining to obtain soap body, control extraction temperature is at 65 DEG C, and the soap body after refining is rolled through dicer
Stripping and slicing is printed, product is produced.
A kind of embodiment 23, preparation method of the soap as described in embodiment 1-19, its step is as follows：70g neat soaps, 3g is sweet
Oil, 0.4g essence, 0.2g complexing agents, 0.3g polyethylene glycol 400s, 0.3g block copolymers EO-PO-EO, 0.8 glycol distearyl acid
It is equal that ester, 0.24kg triethanolamines, 0.2kg ethylene glycol, 0.3kg DPGs, 24g deionized waters add stirring mixing in mixer
It is even, mixed material is delivered to grinder and carries out homogeneous, control homogenizing temperature is conveyed at 35 DEG C, then by the good material of homogeneous
Carry out being refining to obtain soap body into duplex vacuum machine, control extraction temperature is at 65 DEG C, and the soap body after refining is cut through dicer roll printing
Block, produces product.
A kind of embodiment 24, preparation method of the soap as described in embodiment 1-19, its step is as follows：By 78g neat soaps,
0.45g glycerine, 0.2g essence, 0.05g complexing agents, 0.55g polyethylene glycol 400s, 0.3kg AEOs, 0.25kg
Triethanolamine, 0.2kg ethylene glycol, 20g deionized waters are added to be uniformly mixed in mixer, and mixed material is delivered to
Grinder carries out homogeneous, and control homogenizing temperature is at 35 DEG C, then the good material of homogeneous is delivered in duplex vacuum machine refined
Soap body is obtained, control extraction temperature is at 65 DEG C, and the soap body after refining produces product through dicer roll printing stripping and slicing.
Product made from embodiment 24, its soap transparency is 22.9, and sliver exporting speed is 90s, smooth in appearance, flawless,
It is colourless non-yellowing after high temperature.
Claims (10)
1. a kind of soap, it is characterised in that：It is made up of the raw material of following mass percent, and 63-78% neat soaps, 0.4-6% are sweet
Oil, 0.2-0.6% essence, 0.05-0.4% complexing agents, 0.4-3% nonionic surfactants, 0.4-2.1% auxiliary agents, 20-25% are gone
Ionized water.
2. soap according to claim 1, it is characterised in that：Described nonionic surfactant is fatty alcohol polyoxy second
The sour fat of alkene ether, polyethylene glycol, block copolymer, polyacrylate, ethylene glycol distearyl, APG or APG ethyoxyl
One or more in compound.
3. soap according to claim 2, it is characterised in that：Described nonionic surfactant is fatty alcohol polyoxy second
Alkene ether, polyethylene glycol and glycol distearate, AEO, polyethylene glycol and glycol distearate
Mass percent is 0.1-0.7%：0.2-0.8%：0-2.0%.
4. the soap according to Claims 2 or 3, it is characterised in that：The AEO includes 8-20 carbon
Atom, preferably includes 12-18 carbon atom.
5. soap according to claim 4, it is characterised in that：The AEO includes 3-80 EO, excellent
Choosing includes 7-60 EO, more preferably 30-60 EO.
6. soap according to claim 2, it is characterised in that：The molecular weight of the polyethylene glycol includes 200-6000, more
It is preferred that 300-4000, most preferably 400-1000.
7. soap according to claim 2, it is characterised in that：The structural formula of described block copolymer be R-EO-PO or
Person R-PO-EO or EO-PO-EO or PO-EO-PO or EO and PO random blocks, wherein R refer to diethylene glycol, natural grease
Fat alcohol, synthetic fatty alcohol or branched fatty alcohol.
8. soap according to claim 1, it is characterised in that：Described auxiliary agent be triethanolamine, ethylene glycol, propane diols,
One or more in diethylene glycol, DPG, castor oil or trimethylolpropane.
9. soap according to claim 8, it is characterised in that：Described auxiliary agent be triethanolamine, ethylene glycol and propane diols,
The mass percent of triethanolamine, ethylene glycol and propane diols is 0.1-0.5%：0-0.4%：0-0.4%.
10. the preparation method of a kind of soap as described in claim any one of 1-9, it is characterised in that its step is as follows：By soap
Grain, glycerine, essence, complexing agent, nonionic surfactant, auxiliary agent and deionized water are added to be uniformly mixed in mixer,
Mixed material is delivered to grinder and carries out homogeneous, control homogenizing temperature is defeated at 30 DEG C -40 DEG C, then by the good material of homogeneous
Deliver in duplex vacuum machine and carry out being refining to obtain soap body, control extraction temperature at 60 DEG C -70 DEG C, the soap body after refining through stripping and slicing,
Produce product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710188648.XA CN106967545A (en) | 2017-03-27 | 2017-03-27 | A kind of soap and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710188648.XA CN106967545A (en) | 2017-03-27 | 2017-03-27 | A kind of soap and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106967545A true CN106967545A (en) | 2017-07-21 |
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| CN201710188648.XA Pending CN106967545A (en) | 2017-03-27 | 2017-03-27 | A kind of soap and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112574834A (en) * | 2020-12-23 | 2021-03-30 | 山东农业大学 | Sterilizing and inflammation-diminishing soap and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102433230A (en) * | 2011-10-25 | 2012-05-02 | 纳爱斯集团有限公司 | Transparent soap composition as well as production method and application thereof |
| CN102776087A (en) * | 2012-07-10 | 2012-11-14 | 广东名臣有限公司 | Multifunctional perfumed soap |
| CN103242992A (en) * | 2013-05-02 | 2013-08-14 | 广州立白企业集团有限公司 | Washing soap with functional colored granules and production method thereof |
| CN104629951A (en) * | 2015-03-03 | 2015-05-20 | 上海制皂有限公司 | Transparent soap |
-
2017
- 2017-03-27 CN CN201710188648.XA patent/CN106967545A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102433230A (en) * | 2011-10-25 | 2012-05-02 | 纳爱斯集团有限公司 | Transparent soap composition as well as production method and application thereof |
| CN102776087A (en) * | 2012-07-10 | 2012-11-14 | 广东名臣有限公司 | Multifunctional perfumed soap |
| CN103242992A (en) * | 2013-05-02 | 2013-08-14 | 广州立白企业集团有限公司 | Washing soap with functional colored granules and production method thereof |
| CN104629951A (en) * | 2015-03-03 | 2015-05-20 | 上海制皂有限公司 | Transparent soap |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112574834A (en) * | 2020-12-23 | 2021-03-30 | 山东农业大学 | Sterilizing and inflammation-diminishing soap and preparation method thereof |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 222000 Jiangsu, Lianyungang City, Xuwei District, Lianyungang District, two Road North Applicant after: Jiangsu sailboat Petrochemical Co. Ltd. Address before: 222000 room 205, building 7, Hong Kong Petrochemical, Hong Kong Road, Xuwei New District, Lianyungang, Jiangsu Applicant before: Jiangsu sailboat Petrochemical Co. Ltd. |
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170721 |