CN106966457A - A kind of method that utilization feces of livestock and poultry prepares ecological reef - Google Patents

A kind of method that utilization feces of livestock and poultry prepares ecological reef Download PDF

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CN106966457A
CN106966457A CN201710113138.6A CN201710113138A CN106966457A CN 106966457 A CN106966457 A CN 106966457A CN 201710113138 A CN201710113138 A CN 201710113138A CN 106966457 A CN106966457 A CN 106966457A
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solid
liquid
livestock
poultry
feces
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CN106966457B (en
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张东
陈玉贺
宋旭
李靖
李靖一
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Yami Technology (Guangzhou) Co., Ltd
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Shenyang Ligong University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/288Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Artificial Fish Reefs (AREA)

Abstract

The present invention discloses one kind and prepares ecologic reef cubic meter of stone method using feces of livestock and poultry.It is related to marine ecology islands and reefs, seabed pasture and marine ecology and recovers to build manually reef preparation method.Step is:1st, calcium titanate, hydrogen peroxide and acid solution are added in feces of livestock and poultry, is heated, separation obtains solid A and liquid A;2nd, by solid A, vacuum calcining obtains solid B;3rd, the pH value of liquid A is adjusted, diatomite, stirring is added, separation obtains solid C and liquid C;4th, add adhesive in solid C, pelletize, calcining obtains porous ball D;5th, solid B and porous ball D are immersed in liquid C, absorption, porous ball D, solid B are mixed with cement and water again, shaping, hardening curing, obtains the concrete material with release nutriment Adsorption of Heavy Metals function, it can deliver marine, induction and promotion marine organism growth, for fast quick-recovery marine ecology, improve the yield and quality of marine product.With very high environment and economic benefit.

Description

A kind of method that utilization feces of livestock and poultry prepares ecological reef
Technical field
The invention belongs to marine ecology technical field, and in particular to a kind of utilization feces of livestock and poultry prepares the side of ecological reef Method.
Background technology
With the reinforcing and the development of marine economy of marine territory idea, each state all pays much attention to the protection to maritime rights and interests Utilized with the scientific development of marine resources.But, since last century, as environmental pollution and the transition of the mankind such as fish at the reason sea Foreign ecological environment receives heavy damage, and offshore sea waters Desertification is protruded.In order to recover marine ecology and vow ocean state Native sovereignty, each state has all carried out a series of " ecological islands and reefs " recovery project, carries out impaired island body, vegetation, water front, sandy beach and week Side marine site etc. is repaired, and has carried out islands and reefs construction project, carries out aquafarm construction.Meanwhile, implement territorial waters basic point island protection work Journey, carries out islands and reefs ecological preservation area construction etc..Either ocean islands and reefs are built, or aquafarm construction, deliver artificial reef, Abundant nutrition material is the important step for building marine organisms rapid multiplying habitat.Artificial reef be divided into collection fish shelter, induction reef, Reef, propagation reef, marine alga reef etc. are bred as, at present, constructing the material of reef includes steel, plastics, stone, concrete, rubber etc.(Tang It is bright, Zhao Jinbo, the research of high-performance sea-farming abalone Special artificial reef,《Concrete》, 2003,160(2):3-6;Zhang Jing Pine etc., patent of invention, artificial reef, ZL 201310543435.6), in these materials:Rubber, steel etc. can be to marine organisms It can cause to poison, suppress its fast-growth, and some other material, such as stone, concrete and plastics, although to marine organisms It is nontoxic, but attached algae less effective.In order to accelerate the recovery of marine ecology, promote ocean beneficial organism fast-growth, Yu Zonghe Deng by the way that the material for preparing artificial reef is mixed with slow release fertilizer, shaping is then poured, or artificial reef is poured into shaping Afterwards, the coating rich in slow release fertilizer is coated on its surface, a kind of good reef of surface algae adhesion effect is made(Yu Zonghe etc., Patent of invention, a kind of method of raising attaching effect of algas on surface of artificial reef, ZL201110118155.1), achieve certain Achievement, but the nutrition salt component of this method addition is single, promote for abundant ocean biological species it is not enough, meanwhile, cost Also it is higher, limit it and widely apply.On the other hand, due to factors such as environmental pollutions, heavy metal, radiation in some seawater The harmful substances such as property element can be exceeded, and these materials can also influence the recovery of marine ecology and the quality of marine product, but existing Artificial islands and reefs material do not possess the abilities of the harmful substances such as removing heavy metals.Exploitation one kind can discharge nutriment, again Ecological artificial reef that be capable of Adsorption harmful substance, low cost is very important.
As China's livestock and poultry breeding industry is developed rapidly, the feces of livestock and poultry of plant's discharge causes very big pressure to environment Power.In traditional agriculture, feces of livestock and poultry is all to be used for agricultural production after compost, still, in modern livestock and poultry cultivation industry, is The yield and quality of meat, eggs and milk, and needs of preventing and curing diseases are improved, can add in feed substantial amounts of rich in micro- Nutritional ingredient and various additives, after livestock and poultry feed, these materials have can greatly be arranged with fecaluria in the form of original shape Release and, so, in feces of livestock and poultry in addition to containing protein, amino acid and cellulose wood quality, it can also contain substantial amounts of copper The heavy metals such as iron zinc, and the harmful substance such as antibiotic and growth promoter.Traditional composting process, it is impossible to which effectively removing these has Evil material, these harmful substances enter soil with muck, can agricultural product and environment be caused with serious harm.It is therefore desirable to visit Feces of livestock and poultry is begged for utilize and processing new way.
In order to prepare multifunctional ecological artificial reef, feces of livestock and poultry is comprehensively utilized, the present invention prepares one using feces of livestock and poultry Plant the artificial reef with absorption and nutrition slow-release function.
The content of the invention
The purpose of the present invention, is to provide a kind of utilization feces of livestock and poultry and prepares with Adsorption of Heavy Metals and discharge nutriment The method of ecological reef.It is related to the construction of marine ecology islands and reefs, the construction of seabed pasture and marine ecology to recover to build manually reef The comprehensive utilization of stone material and feces of livestock and poultry.
The technical scheme of use is
A kind of method that utilization feces of livestock and poultry prepares ecological reef, it is characterised in that this method comprises the following steps:
1)Take fresh feces of livestock and poultry, adjust moisture content 80-88%, add the 0.1%-1% of stool quality nano barium titanate calcium and 5%-10% mass concentration is 30% hydrogen peroxide, is stirred, and micro-boiling 5-10min is heated, according still further to feces of livestock and poultry quality and nitre Acid solution and phosphoric acid solution volume ratio are 2Kg:1L:1L ratios, are separately added into salpeter solution and concentration that concentration is 1-3moL/L For 0.3-1mol/L phosphoric acid solution, stir, be heated to 60-80 DEG C of holding 10-30min, separation of solid and liquid obtains solid A And liquid A;
2)The phosphoric acid that the mass percentage concentration of the quality such as addition is 85% in the solid A obtained to step one, stirs, in 350 Under the conditions of DEG C -500 DEG C, vacuum calcining 30-70min is washed to weakly acidic pH, drying, pulverizes and sieves, and obtains particle diameter for 0.1- 2.4mm solid B;
3)The ratio between molal quantity according to calcium and magnesium is 1:1, and the ratio between total mole number and the stool quality kilogram number of calcium and magnesium are 0.25- 1:Add the compound of calcic and magnesium in 1 ratio, the liquid A obtained to step one, stirring reaction completely, then adjusts with ammoniacal liquor its pH It is worth for 6-8, adds the 5%-20% of stool quality diatomite, stirs, stand 12h, separation of solid and liquid obtains solid C and liquid Body C;
4)The solid C drying that step 3 is obtained, adds the 20%-50% of solid C mass adhesive, ball milling 0.5-6h, profit It is wet, the spherical material that particle diameter is 2.5mm-15mm is made, after drying, calcines 20min-40min in 950-1300 DEG C, obtains porous ball D;
5)The porous ball D that the solid B and step 4 that step 2 is obtained are obtained is immersed in the liquid C that step 3 is obtained respectively, 12-24h is soaked, abundant saturation is taken out, 105 DEG C of drying are 1 according to porous ball D, solid B and cement for construction in sea mass ratio: 0.03-0.2:0.2-0.3, feeding is well mixed, then by water and cement quality ratio is 0.2-0.24:1 ratio adds water, and stirring is equal It is even, mould molding is injected, the shape of needs is made, hardening curing 28 days obtains having release nutriment and Adsorption of Heavy Metals The concrete material of function, available for recover marine ecology rich water islands and reefs shore protection stone, also can as seabed pasture artificial reef Stone.
Described feces of livestock and poultry is the herbvore excrement with omnivorousness cultivated animals.
In the compound that calcic and magnesium are added in described step three, the compound of calcium is calcium oxide, calcium hydroxide, carbonic acid One or more in calcium, calcite, lime stone, the compound of magnesium is one or both of magnesia, magnesium carbonate.
The adhesive added in described step four is one kind in clay or kaolin.
Cement for construction in sea strength grade used is 42.5 low alkalinity cement in described step five.
It is an advantage of the current invention that while innoxious, comprehensive utilization of resources feces of livestock and poultry, preparing cheap having and inhaling The attached artificial reef for removing harmful heavy metal function and release nutriment, twice laid, energy-conserving and environment-protective, with very high environment Benefit and economic benefit.
Brief description of the drawings
Fig. 1 is the process chart of this method.
Embodiment
Methods and techniques of the present invention are illustrated below by example.Nano-titanium used in the embodiment of the present invention Sour calcium powder body is this laboratory by document(The preparation of Zhang Dong, Hou Ping nano barium titanate calcium powder bodies and its to lead in water and cadmium Absorption behavior [J] chemistry journals, 2009, (12): 1336-1342)Method is synthesized.
Embodiment 1:The preparation of artificial reef 1
It is 81% fresh cow dung 2Kg to take moisture content, and the nano barium titanate calcium and 100g concentration for adding 10g are 30% hydrogen peroxide, are stirred Mix uniform, heat micro-boiling 5min, add the salpeter solution that 1L concentration is 3moL/L and the phosphoric acid solution that 1L concentration is 1mol/L, Stir, 70 DEG C of insulation 20min, filtering obtains solid A and liquid A;Into solid A, the quality percentage of the quality such as addition is dense The phosphoric acid for 85% is spent, is stirred, under the conditions of 450 DEG C, vacuum calcining 60min is washed to weakly acidic pH, dries, crushed Sieve, obtains the solid B that particle diameter is 0.1-2.4mm;14g calcium oxide and 10g magnesia are added in liquid A, stirring reaction is complete, Adjust pH value to be 7 with ammoniacal liquor again, add 300g diatomite, stir, stand 12h, separation of solid and liquid obtains solid C and liquid C;Solid C is dried, the clay of solid C mass 30% is added, ball milling 6h is soaked, and it is the spherical of 2.5mm-15mm that particle diameter, which is made, Material, after drying, calcines 30min in 1000 DEG C, obtains porous ball D;By this test obtained by solid B and porous ball D submerge respectively In liquid C, 15h is soaked, abundant saturation is taken out solid B and porous ball D, dried under the conditions of 105 DEG C;It is porous in mass ratio Ball D:Solid B:No. 42.5 cement for construction in sea are 1:0.1:0.25 ratio feeding, is well mixed, then be by water and cement quality ratio 0.22:1 adds water, and stirs, a height of 150*150*50mm of injection length and width die for molding, the hardening curing of normal temperature moisture-keeping maintaining 28 days, obtain artificial reef sample 1.
Embodiment 2:The preparation of artificial reef 2
It is 82% fresh cow dung 2Kg to take adjustment moisture content, and the nano barium titanate calcium and 200g concentration for adding 2g are 30% hydrogen peroxide, Stir, heat micro-boiling 10min, add the salpeter solution that 1L concentration is 3moL/L and the phosphoric acid that 1L concentration is 0.3mol/L Solution, stirs, and 60 DEG C of insulation 30min, separation of solid and liquid obtains solid A and liquid A;The matter of the quality such as addition into solid A The phosphoric acid that percentage concentration is 85% is measured, is stirred, under the conditions of 500 DEG C, vacuum calcining 30min is washed to weakly acidic pH, is dried, Pulverize and sieve, obtain the solid B that particle diameter is 0.1-2.4mm;55g calcium hydroxides and 30g magnesia, stirring are added in liquid A React complete, then adjust pH value to be 6 with ammoniacal liquor, add 200g diatomite, stir, standing 12h, separation of solid and liquid, consolidate Body C and liquid C;Solid C is dried, 50% clay of solid C mass is added, ball milling 0.5h is soaked, particle diameter, which is made, is 2.5mm-15mm spherical material, after drying, calcines 40min in 950 DEG C, obtains porous ball D;By this test obtained by solid B and Porous ball D is immersed in liquid C respectively, soaks 12h, and abundant saturation takes out solid B and porous ball D, respectively at 105 DEG C of conditions Lower drying;Porous ball D in mass ratio:Solid B:No. 42.5 cement for construction in sea are 1:0.03:0.2 ratio feeding, is well mixed, then press Water and cement quality ratio 0.2:1 adds water, stirs, a height of 150*150*50mm of injection length and width die for molding, normal temperature Moisture-keeping maintaining hardening curing 28 days, obtains artificial reef sample 2.
Embodiment 3:The preparation of artificial reef 3
It is 82% fresh chicken manure 2Kg to take adjustment moisture content, and the nano barium titanate calcium and 200g concentration for adding 20g are 30% dioxygen Water, stirs, and heats micro-boiling 10min, and it is 0.5mol/L's to add salpeter solution that 1L concentration is 3moL/L and 1L concentration Phosphoric acid solution, stirs, and 80 DEG C of insulation 20min, separation of solid and liquid obtains solid A and liquid A;The quality such as addition into solid A Mass percentage concentration be 85% phosphoric acid, stir, under the conditions of 350 DEG C, vacuum calcining 70min is washed to weakly acidic pH, Drying, pulverizes and sieves, and obtains the solid B that particle diameter is 0.1-2.4mm;25g calcium carbonate and 21g magnesium carbonate are added in liquid A, is stirred Mix reaction complete, then adjust pH value to be 8 with ammoniacal liquor, add 350g diatomite, stir, stand 12h, separation of solid and liquid is obtained Solid C and liquid C;Solid C is dried, 20% clay of solid C mass is added, ball milling 3h is soaked, particle diameter, which is made, is 2.5mm-15mm spherical material, after drying, calcines 20min in 1300 DEG C, obtains porous ball D;By this test obtained by solid B and Porous ball D is immersed in liquid C respectively, soaks 24h, and abundant saturation takes out solid B and porous ball D, respectively at 105 DEG C of conditions Lower drying;Porous ball D in mass ratio:Solid B:No. 42.5 cement for construction in sea are 1: 0.2:0.3 ratio feeding, is well mixed, by water With cement quality ratio 0.21:1 adds water, stirs, and a height of 150*150*50mm of injection length and width die for molding, normal temperature is protected Wet curing hardening curing 28 days, obtains artificial reef sample 3.
Embodiment 4:The preparation of artificial reef 4
It is 85% fresh pig manure 2Kg to take adjustment moisture content, and the nano barium titanate calcium and 200g concentration for adding 20g are 30% dioxygen Water, stirs, and heats micro-boiling 10min, and it is 0.3mol/L's to add salpeter solution that 1L concentration is 3moL/L and 1L concentration Phosphoric acid solution, stirs, and 75 DEG C of insulation 10min, separation of solid and liquid obtains solid A and liquid A;The quality such as addition into solid A Mass percentage concentration be 85% phosphoric acid, stir, under the conditions of 400 DEG C, vacuum calcining 50min is washed to weakly acidic pH, Drying, pulverizes and sieves, and obtains the solid B that particle diameter is 0.1-2.4mm;75g agstones and 64g magnesium carbonate are added in liquid A, Stirring reaction adjusts pH value to be 6 completely, then with ammoniacal liquor, adds 100g diatomite, stirs, stand 12h, separation of solid and liquid is obtained To solid C and liquid C;Solid C is dried, 30% clay of solid C mass is added, ball milling 6h is soaked, particle diameter, which is made, is 2.5mm-15mm spherical material, after drying, calcines 30min in 1200 DEG C, obtains porous ball D;By this test obtained by solid B and Porous ball D is immersed in liquid C respectively, soaks 20h, and abundant saturation takes out solid B and porous ball D, respectively at 105 DEG C of conditions Lower drying;Porous ball D in mass ratio:Solid B:No. 42.5 cement for construction in sea are 1: 0.2:0.3 ratio feeding, is well mixed, presses Water and cement quality ratio 0.22:1 adds water, stirs, a height of 150*150*50mm of injection length and width die for molding, normal temperature Moisture-keeping maintaining hardening curing 28 days, obtains artificial reef sample 4.
Embodiment 5:The preparation of artificial reef 5
It is 80% fresh sheep manure 2Kg to take adjustment moisture content, and the nano barium titanate calcium and 100g concentration for adding 2g are 30% hydrogen peroxide, Stir, heat micro-boiling 5min, add the salpeter solution that 1L concentration is 1moL/L and the phosphoric acid that 1L concentration is 1mol/L is molten Liquid, stirs, and 60 DEG C of insulation 30min, separation of solid and liquid obtains solid A and liquid A;The matter of the quality such as addition into solid A The phosphoric acid that percentage concentration is 85% is measured, is stirred, under the conditions of 500 DEG C, vacuum calcining 70min is washed to weakly acidic pH, is dried, Pulverize and sieve, obtain the solid B that particle diameter is 0.1-2.4mm;276g dolomite dusts are added in liquid A, stirring reaction is complete, then Adjust pH value to be 6 with ammoniacal liquor, add 300g diatomite, stir, stand 12h, separation of solid and liquid obtains solid C and liquid C; Solid C is dried, 50% clay of solid C mass is added, ball milling 6h is soaked, and it is the spherical of 2.5mm-15mm that particle diameter, which is made, Material, after drying, calcines 40min in 1000 DEG C, obtains porous ball D;By this test obtained by solid B and porous ball D submerge respectively In liquid C, 18h is soaked, abundant saturation is taken out solid B and porous ball D, dried under the conditions of 105 DEG C;In mass ratio Porous ball D:Solid B:No. 42.5 cement for construction in sea are 1:0.03:0.2 ratio feeding, is well mixed, then by water and cement quality ratio 0.24:1 adds water, stirs, and a height of 150*150*50mm of injection length and width die for molding, normal temperature moisture-keeping maintaining hardening is ripe Change 28 days, obtain artificial reef sample 5.
Embodiment 6:The preparation of artificial reef 6
It is 88% fresh goose excrement 2Kg to take adjustment moisture content, and the nano barium titanate calcium and 150g concentration for adding 5g are 30% hydrogen peroxide, Stir, heat micro-boiling 10min, add the salpeter solution that 1L concentration is 1moL/L and the phosphoric acid that 1L concentration is 0.3mol/L Solution, stirs, and 60 DEG C of insulation 30min, separation of solid and liquid obtains solid A and liquid A;The matter of the quality such as addition into solid A The phosphoric acid that percentage concentration is 85% is measured, is stirred, under the conditions of 350 DEG C, vacuum calcining 30min is washed to weakly acidic pH, is dried, Pulverize and sieve, obtain the solid B that particle diameter is 0.1-2.4mm;28g calcium oxide and 20g magnesia are added in liquid A, stirring is anti- Should be complete, then adjust pH value to be 8 with ammoniacal liquor, add 400g diatomite, stir, stand 12h, separation of solid and liquid obtains solid C With liquid C;Solid C is dried, 30% kaolin of solid C mass is added, particle diameter is made for 2.5mm- in ball milling 6h, wetting 15mm spherical material, after drying, calcines 30min in 1000 DEG C, obtains porous ball D;Solid B and porous ball obtained by this is tested D is immersed in liquid C respectively, soaks 12h, and abundant saturation is taken out solid B and porous ball D, dried under the conditions of 105 DEG C; Porous ball D in mass ratio:Solid B:42.5 number cement for construction in sea is 1:0.15:0.25 ratio feeding, is well mixed, then by water and water Mud mass ratio 0.2:1 adds water, stirs, and a height of 150*150*50mm of injection length and width die for molding, normal temperature moisturizing is supported Shield hardening curing 28 days, obtains artificial reef sample 6.
Embodiment 7:Artificial reef main nutrient elements burst size
1 piece of artificial reef obtained by Example 1-6, is placed in 2000mL seawater, often soaks 1 day(24h)A water is changed, and Nitrogen phosphorus in soak is analyzed by " DB33-699 organic liquid fertilizers and the requirement of organic and inorganic composite liquid fertilizer quality safety " Content, the results are shown in Table 1
The nutrition release performance of the artificial reef of table 1(g/L)
Embodiment 8:The absorption property of artificial reef
The absorption property of artificial reef obtained by embodiment 1-6, takes 200 mg/L lead standard liquid 2000mL, in 3000 mL In beaker, adjust the pH value of solution to 6, be separately added into the artificial reef obtained in 1 piece of embodiment 1-6, stir frequently, soak 24h, The content of lead in supernatant is surveyed with Atomic absorption, by formula(1)Calculate clearance.It the results are shown in Table 2.
(1)
In formula:ηFor the clearance of lead(%);C 0For initial concentration(mg/L);C eFor equilibrium concentration(mg/L).
The absorption property of the artificial reef prepared in the embodiment 1-6 of table 2
Initial concentration,C 0(mg/L) Lead concentration (Ce) after absorption(mg/L) Adsorbance,(Mg/ blocks)
Artificial reef 1 200 12.49 375.02
Artificial reef 2 200 78.33 243.34
Artificial reef 3 200 32.69 334.62
Artificial reef 4 200 56.44 287.12
Artificial reef 5 200 18.93 362.14
Artificial reef 6 200 98.57 202.86

Claims (5)

1. a kind of method that utilization feces of livestock and poultry prepares ecological reef, it is characterised in that this method comprises the following steps:
1)Take fresh feces of livestock and poultry, adjust moisture content 80-88%, add the 0.1%-1% of stool quality nano barium titanate calcium and 5%-10% mass concentration is 30% hydrogen peroxide, is stirred, and micro-boiling 5-10min is heated, according still further to feces of livestock and poultry quality and nitre Acid solution and phosphoric acid solution volume ratio are 2Kg:1L:1L ratios, are separately added into salpeter solution and concentration that concentration is 1-3moL/L For 0.3-1mol/L phosphoric acid solution, stir, be heated to 60-80 DEG C of holding 10-30min, separation of solid and liquid obtains solid A And liquid A;
2)The phosphoric acid that the mass percentage concentration of the quality such as addition is 85% in the solid A obtained to step one, stirs, in 350 Under the conditions of DEG C -500 DEG C, vacuum calcining 30-70min is washed to weakly acidic pH, drying, pulverizes and sieves, and obtains particle diameter for 0.1- 2.4mm solid B;
3)The ratio between molal quantity according to calcium and magnesium is 1:1, and the ratio between total mole number and the stool quality kilogram number of calcium and magnesium are 0.25- 1:Add the compound of calcic and magnesium in 1 ratio, the liquid A obtained to step one, stirring reaction completely, then adjusts with ammoniacal liquor its pH It is worth for 6-8, adds the 5%-20% of stool quality diatomite, stirs, stand 12h, separation of solid and liquid obtains solid C and liquid Body C;
4)The solid C drying that step 3 is obtained, adds the 20%-50% of solid C mass adhesive, ball milling 0.5-6h, profit It is wet, the spherical material that particle diameter is 2.5mm-15mm is made, after drying, calcines 20min-40min in 950-1300 DEG C, obtains porous ball D;
5)The porous ball D that the solid B and step 4 that step 2 is obtained are obtained is immersed in the liquid C that step 3 is obtained respectively, 12-24h is soaked, abundant saturation is taken out, 105 DEG C of drying are 1 according to porous ball D, solid B and cement for construction in sea mass ratio: 0.03-0.2:0.2-0.3, feeding is well mixed, then by water and cement quality ratio is 0.2-0.24:1 ratio adds water, and stirring is equal It is even, mould molding is injected, the shape of needs is made, hardening curing 28 days obtains having release nutriment and Adsorption of Heavy Metals The ecological work reef of the people of function.
2. the method that a kind of utilization feces of livestock and poultry according to claim 1 prepares ecological reef, it is characterised in that described Feces of livestock and poultry is the herbvore excrement with omnivorousness cultivated animals.
3. the method that a kind of utilization feces of livestock and poultry according to claim 1 prepares ecological reef, it is characterised in that described The compound of the calcium added in step 3 is the one or more in calcium oxide, calcium hydroxide, calcium carbonate, calcite, lime stone, The compound of magnesium is the one or more in magnesia, magnesium carbonate.
4. the method that a kind of utilization feces of livestock and poultry according to claim 1 prepares ecological reef, it is characterised in that described The adhesive added in step 4 is one kind in clay or kaolin.
5. the method that a kind of utilization feces of livestock and poultry according to claim 1 prepares ecological reef, it is characterised in that described Cement for construction in sea strength grade used is 42.5 low alkalinity cement in step 5.
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CN112479783A (en) * 2020-11-30 2021-03-12 九江礼涞生物科技有限公司 Harmless treatment process for livestock and poultry manure and application thereof

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