CN106958153A - A kind of compound textile auxiliary and its preparation technology - Google Patents
A kind of compound textile auxiliary and its preparation technology Download PDFInfo
- Publication number
- CN106958153A CN106958153A CN201710158628.8A CN201710158628A CN106958153A CN 106958153 A CN106958153 A CN 106958153A CN 201710158628 A CN201710158628 A CN 201710158628A CN 106958153 A CN106958153 A CN 106958153A
- Authority
- CN
- China
- Prior art keywords
- parts
- textile auxiliary
- biosurfactant
- compound textile
- rare earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65125—Compounds containing ester groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67366—Phosphates or polyphosphates
Abstract
The invention provides a kind of compound textile auxiliary and its preparation technology, the compound textile auxiliary by weight ratio, including following raw material components：α sulfo group ω octadecane epoxides APEO, biosurfactant, rare earth oxide, cocounut oil diglycollic amide, polyoxyethylene 20 sorbitan monopalmitate, double amido silicon oils, Cocoamidopropyl betaine, tartaric acid, Sodium Polyacrylate, poloxamer188, methylchloroisothiazandnone, sodium tripolyphosphate, isopropyl myristate, ethylene glycol, water.The dye-uptake of the printing and dyeing assistant of the present invention is high, and dye utilization rate is high, and overall printing and dyeing work well, color fastness, and the antibacterial and anti-static function of textile, can meet the application demand of consumers in general, application prospect is boundless after increase printing and dyeing.
Description
Technical field
The invention belongs to technical field of textile printing, and in particular to a kind of compound textile auxiliary and its preparation work
Skill.
Background technology
To textile material（Fiber, yarn and fabric）The technical process based on being chemically treated is carried out, the modern times are also commonly referred to as
Dyeing and printing process.Dyeing and finishing together, forms the overall process of yarn fabric production with spinning, woven or knitting production.Dyeing and finishing include pretreatment,
Dyeing, stamp and arrangement.The good and bad use value to textile of dyeing and finishing quality has important influence.Pretreatment is also known as scouringed and bleaching,
Its main purpose is to remove the impurity on textile material, makes follow-up dyeing, stamp, arranges and process smooth, obtains
Obtain expected processing effect.Dyeing is textile material is had one by the combination that physics or chemistry occur for dyestuff and fiber
Fixed color.Stamp is that chromatic pattern pattern is obtained on yarn fabric with mill base.Arrangement is by physical action or using chemistry
Medicament improves the outward appearances such as gloss, the form of fabric；Improve the wearability of fabric or make fabric that there is water repellent, refuse the characteristics such as oil.
In order to improve printing and dyeing effect, level-dyeing property and increase color fastness, and avoid or reduce textile material and encounter water, sweat
When stain, Exposure to Sunlight, saliva or physical friction, dyestuff easily comes off and faded, and influences attractive in appearance, also avoids or reduce the dyestuff point come off
Son or heavy metal ion may be absorbed by the body by skin and endanger health；Also for increase dye uptake, improve dyestuff and utilize
Rate, reduction dyeing cost is high, and reduces the content of organic dyestuff in dyeing and printing sewage, reduces follow-up cost of water treatment, reduces
Environmental pollution, a certain amount of printing and dyeing assistant is often added in dyeing and printing process.The species of printing and dyeing assistant now is various, but greatly
The single effect of part printing and dyeing assistant, in order to obtain multiple effect, generally requires to use substantial amounts of printing and dyeing assistant, in addition, different
Printing and dyeing assistant between be also not quite similar with the use of produced effect, it is necessary to could most by multiple sorting and proportioning test
The synergy of the printing and dyeing assistant of the performance compounding of limits, in addition, the scope of application of current printing and dyeing assistant is small, can only be applicable
In specific textile material, these all undoubtedly add printing and dyeing cost and labor intensity.Although having one in the prior art
The printing and dyeing assistant compounded a bit, but its print and dye effect, color fastness, dye uptake performance are still not ideal enough, and most of printing and dyeing assistant work(
Can be single, in the absence of antibacterial and anti-static function, it is impossible to meet increasingly increasing of the people to antibacterial and anti-static function textile material
Plus application demand.
The content of the invention
There is provided a kind of compound textile printing and dyeing for more than prior art problem to be solved by this invention at least one deficiency
Auxiliary agent and its preparation technology.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of compound textile auxiliary, by weight ratio, including following raw material components：Alpha-sulfo-ω-octadecane epoxide
It is 10-18 parts of APEO, 2-5 parts of biosurfactant, 1-3 parts of rare earth oxide, 3-6 parts of cocounut oil diglycollic amide, poly-
4-8 parts of oxygen ethene sorbitan monopalmitate, double amido silicon oil 2-6 parts, 2-5 parts of Cocoamidopropyl betaine, winestone
Sour 1-4 parts, 6-11 parts of Sodium Polyacrylate, 5-10 parts of poloxamer188,2-7 parts of methylchloroisothiazandnone, sodium tripolyphosphate
3-5 parts, 2-6 parts of isopropyl myristate, 26-38 parts of ethylene glycol, 18-30 parts of water；
The biosurfactant is at least three in Tea Saponin, sapindoside, sophorolipid, marine alga glycolipid and cysteine
The mixture planted；
The rare earth oxide is at least two mixture of lanthana, strontium oxide strontia, cobalt oxide and cerium oxide.
In the compound textile auxiliary of the present invention, by weight ratio, including following raw material components：Alpha-sulfo-
ω -14 parts of octadecane epoxide APEO, 3.5 parts of biosurfactant, 1.3 parts of rare earth oxide, cocounut oil diethanol acyl
4 parts of amine, 5 parts of polyoxyethylene 20 sorbitan monopalmitate, 3 parts of double amido silicon oils, 4 parts of Cocoamidopropyl betaine, wine
Stone acid 2.8 parts, 8 parts of Sodium Polyacrylate, 7 parts of poloxamer188,5 parts of methylchloroisothiazandnone, 3.5 parts of sodium tripolyphosphate,
4.2 parts of isopropyl myristate, 32 parts of ethylene glycol, 26 parts of water.
In the compound textile auxiliary of the present invention, the biosurfactant is Tea Saponin, sophorolipid and half
Cystine, the mass ratio of three is 4:2.8:1.4.
In the compound textile auxiliary of the present invention, the biosurfactant is sapindoside, trehalose
Fat and cysteine, the mass ratio of three is 1.5:2:1.
In the compound textile auxiliary of the present invention, the rare earth oxide is that mass ratio is 3:1:2 lanthana,
The mixture of cobalt oxide and cerium oxide.
In the compound textile auxiliary of the present invention, the molecular weight of the Sodium Polyacrylate is 1200-2000.
A kind of preparation technology of above-mentioned compound textile auxiliary, including following preparation process：
（1）By weight ratio, by double amido silicon oils, cocounut oil diglycollic amide, Cocoamidopropyl betaine, alpha-sulfo-ω-
Octadecane epoxide APEO, polyoxyethylene 20 sorbitan monopalmitate, isopropyl myristate, methyl chloroisothiazole
Quinoline ketone is mixed with ethylene glycol, is heated to 60-80 DEG C, with 200-500rpm speed stirring reaction 1-2 hours, is cooled to room temperature,
Obtain solution A；
（2）By weight ratio, by rare earth oxide, sodium tripolyphosphate, tartaric acid, biosurfactant, Sodium Polyacrylate,
Poloxamer188 is added to the water, and is heated to 30-50 DEG C, is stirred 30-60 minutes with 100-300rpm speed, is cooled to room
Temperature, obtains solution B,
（3）Above-mentioned solution A and solution B are mixed, 12-20h is stirred at room temperature, 24h is stood, produces compound textile auxiliary.
In the preparation technology of the compound textile auxiliary of the present invention, the step（1）In be heated to 72 DEG C, with
300rpm speed stirring reaction 1 hour；The step（2）In be heated to 45 DEG C, stirred 50 minutes with 180rpm speed.
As a result of above technical scheme, the present invention has the advantages that：
（1）Textile after being dyed using the textile auxiliary of the invention respectively provided, color and luster is beautiful, and color is uniform, nothing
The anomalies such as specking, dye-uptake is high, and dye utilization rate is high, and overall printing and dyeing work well.
（2）Textile auxiliary prepared by the present invention dyed after textile, washing, friction and illumination under table
Existing excellent color fastness, while the antibiotic rate of anti-Staphylococcus aureus is not less than 95.8%, antistatic half-life period is not higher than 11.5
Second, show good antibiotic property and antistatic behaviour, excellent combination property.
（3）By rational sorting and proportioning, textile auxiliary prepared by the present invention is given full play between each component
Synergy, effect is various, and function is more, it is possible to decrease the usage amount of printing and dyeing assistant, reduces printing and dyeing cost and labor intensity, increase print
The antibacterial and anti-static function of textile, can meet the application demand of consumers in general after dye, and application prospect is boundless.
Embodiment
With reference to specific embodiment, the present invention is described in further detail.Following examples are used to illustrate the present invention,
But it is not limited to protection scope of the present invention.
Raw material, instrument employed in following embodiments are commercially available.
Embodiment one
A kind of compound textile auxiliary, by weight ratio, including following raw material components：Alpha-sulfo-ω-octadecane epoxide
10 parts of APEO, 2 parts of biosurfactant, 1 part of rare earth oxide, 3 parts of cocounut oil diglycollic amide, polyoxyethylene sorbitan
4 parts of sorbierite monopalmitate, 2 parts of double amido silicon oils, 2 parts of Cocoamidopropyl betaine, 1 part of tartaric acid, molecular weight are
1200-2000 6 parts of Sodium Polyacrylate, 5 parts of poloxamer188,2 parts of methylchloroisothiazandnone, 3 parts of sodium tripolyphosphate, meat
2 parts of isopropyl myristate, 26 parts of ethylene glycol, 18 parts of water；
The biosurfactant is Tea Saponin, sapindoside, the mixture of sophorolipid, and the mass ratio of three is 4:2:
1；
The rare earth oxide is that mass ratio is 3:1 lanthana, the mixture of strontium oxide strontia.
A kind of preparation technology of above-mentioned compound textile auxiliary, including following preparation process：
（1）By weight ratio, by double amido silicon oils, cocounut oil diglycollic amide, Cocoamidopropyl betaine, alpha-sulfo-ω-
Octadecane epoxide APEO, polyoxyethylene 20 sorbitan monopalmitate, isopropyl myristate, methyl chloroisothiazole
Quinoline ketone is mixed with ethylene glycol, is heated to 60 DEG C, with 200rpm speed stirring reaction 1 hour, is cooled to room temperature, is obtained solution A；
（2）By weight ratio, by rare earth oxide, sodium tripolyphosphate, tartaric acid, biosurfactant, Sodium Polyacrylate,
Poloxamer188 is added to the water, and is heated to 30 DEG C, is stirred 30 minutes with 100rpm speed, is cooled to room temperature, obtains solution
B,
（3）Above-mentioned solution A and solution B are mixed, 12h is stirred at room temperature, 24h is stood, produces compound textile auxiliary.
Embodiment two
A kind of compound textile auxiliary, by weight ratio, including following raw material components：Alpha-sulfo-ω-octadecane epoxide
18 parts of APEO, 5 parts of biosurfactant, 3 parts of rare earth oxide, 6 parts of cocounut oil diglycollic amide, polyoxyethylene sorbitan
8 parts of sorbierite monopalmitate, 6 parts of double amido silicon oils, 5 parts of Cocoamidopropyl betaine, 4 parts of tartaric acid, molecular weight are
1200-2000 11 parts of Sodium Polyacrylate, 10 parts of poloxamer188,7 parts of methylchloroisothiazandnone, 5 parts of sodium tripolyphosphate,
6 parts of isopropyl myristate, 38 parts of ethylene glycol, 30 parts of water；
The biosurfactant is the mixture in sapindoside, sophorolipid, marine alga glycolipid and cysteine, and four
Mass ratio be 2:1.2:3.5:1；
The rare earth oxide is that mass ratio is 4:1:The mixture of 2 strontium oxide strontia, cobalt oxide and cerium oxide.
A kind of preparation technology of above-mentioned compound textile auxiliary, including following preparation process：
（1）By weight ratio, by double amido silicon oils, cocounut oil diglycollic amide, Cocoamidopropyl betaine, alpha-sulfo-ω-
Octadecane epoxide APEO, polyoxyethylene 20 sorbitan monopalmitate, isopropyl myristate, methyl chloroisothiazole
Quinoline ketone is mixed with ethylene glycol, is heated to 80 DEG C, with 500rpm speed stirring reaction 2 hours, is cooled to room temperature, is obtained solution A；
（2）By weight ratio, by rare earth oxide, sodium tripolyphosphate, tartaric acid, biosurfactant, Sodium Polyacrylate,
Poloxamer188 is added to the water, and is heated to 50 DEG C, is stirred 60 minutes with 300rpm speed, is cooled to room temperature, obtains solution
B,
（3）Above-mentioned solution A and solution B are mixed, 20h is stirred at room temperature, 24h is stood, produces compound textile auxiliary.
Embodiment three
A kind of compound textile auxiliary, by weight ratio, including following raw material components：Alpha-sulfo-ω-octadecane epoxide
14 parts of APEO, 3 parts of biosurfactant, 2 parts of rare earth oxide, 4.5 parts of cocounut oil diglycollic amide, polyoxyethylene lose
6 parts of water sorbierite monopalmitate, 4 parts of double amido silicon oils, 3.5 parts of Cocoamidopropyl betaine, 2.5 parts of tartaric acid, molecule
Measure 8 parts of the Sodium Polyacrylate for 1200-2000,7 parts of poloxamer188,4.5 parts of methylchloroisothiazandnone, sodium tripolyphosphate
4 parts, 4 parts of isopropyl myristate, 32 parts of ethylene glycol, 24 parts of water；
The biosurfactant is Tea Saponin, sophorolipid, the mixture of marine alga glycolipid, and the mass ratio of three is 2:1:5；
The rare earth oxide is that mass ratio is 4:1:The mixture of 3 lanthana, cobalt oxide and cerium oxide.
A kind of preparation technology of above-mentioned compound textile auxiliary, including following preparation process：
（1）By weight ratio, by double amido silicon oils, cocounut oil diglycollic amide, Cocoamidopropyl betaine, alpha-sulfo-ω-
Octadecane epoxide APEO, polyoxyethylene 20 sorbitan monopalmitate, isopropyl myristate, methyl chloroisothiazole
Quinoline ketone is mixed with ethylene glycol, is heated to 70 DEG C, with 350rpm speed stirring reaction 1.5 hours, is cooled to room temperature, is obtained solution
A；
（2）By weight ratio, by rare earth oxide, sodium tripolyphosphate, tartaric acid, biosurfactant, Sodium Polyacrylate,
Poloxamer188 is added to the water, and is heated to 40 DEG C, is stirred 45 minutes with 200rpm speed, is cooled to room temperature, obtains solution
B,
（3）Above-mentioned solution A and solution B are mixed, 16h is stirred at room temperature, 24h is stood, produces compound textile auxiliary.
Example IV
A kind of compound textile auxiliary, by weight ratio, including following raw material components：：Alpha-sulfo-ω-octadecane oxygen
14 parts of base APEO, 3.5 parts of biosurfactant, 1.3 parts of rare earth oxide, 4 parts of cocounut oil diglycollic amide, polyoxy second
It is 5 parts of alkene sorbitan monopalmitate, 3 parts of double amido silicon oils, 4 parts of Cocoamidopropyl betaine, 2.8 parts of tartaric acid, poly-
8 parts of PAA, 7 parts of poloxamer188,5 parts of methylchloroisothiazandnone, 3.5 parts of sodium tripolyphosphate, myristic acid isopropyl
4.2 parts of ester, 32 parts of ethylene glycol, 26 parts of water；
The biosurfactant is Tea Saponin, sophorolipid and cysteine, and the mass ratio of three is 4:2.8:1.4；
The rare earth oxide is that mass ratio is 3:1:The mixture of 2 lanthana, cobalt oxide and cerium oxide.
A kind of preparation technology of above-mentioned compound textile auxiliary, including following preparation process：
（1）By weight ratio, by double amido silicon oils, cocounut oil diglycollic amide, Cocoamidopropyl betaine, alpha-sulfo-ω-
Octadecane epoxide APEO, polyoxyethylene 20 sorbitan monopalmitate, isopropyl myristate, methyl chloroisothiazole
Quinoline ketone is mixed with ethylene glycol, is heated to 72 DEG C, with 300rpm speed stirring reaction 1 hour, is cooled to room temperature, is obtained solution A；
（2）By weight ratio, by rare earth oxide, sodium tripolyphosphate, tartaric acid, biosurfactant, Sodium Polyacrylate,
Poloxamer188 is added to the water, and is heated to 45 DEG C, is stirred 50 minutes with 180rpm speed, is cooled to room temperature, obtains solution
B,
（3）Above-mentioned solution A and solution B are mixed, 18h is stirred at room temperature, 24h is stood, produces compound textile auxiliary.
Embodiment five
A kind of compound textile auxiliary, by weight ratio, including following raw material components：Alpha-sulfo-ω-octadecane epoxide
16 parts of APEO, 4 parts of biosurfactant, 1.4 parts of rare earth oxide, 4.5 parts of cocounut oil diglycollic amide, polyoxyethylene
5 parts of sorbitan monopalmitate, 3 parts of double amido silicon oils, 2.2 parts of Cocoamidopropyl betaine, 3 parts of tartaric acid, molecule
Measure 8 parts of the Sodium Polyacrylate for 1200-2000,6.5 parts of poloxamer188,4 parts of methylchloroisothiazandnone, sodium tripolyphosphate
3.5 parts, 5 parts of isopropyl myristate, 28 parts of ethylene glycol, 24 parts of water；
The biosurfactant is sapindoside, marine alga glycolipid and cysteine, and the mass ratio of three is 1.5:2:1；
The rare earth oxide is that mass ratio is 3.6:1:2.5:2 lanthana, strontium oxide strontia, the mixing of cobalt oxide and cerium oxide
Thing.
A kind of preparation technology of above-mentioned compound textile auxiliary, including following preparation process：
（1）By weight ratio, by double amido silicon oils, cocounut oil diglycollic amide, Cocoamidopropyl betaine, alpha-sulfo-ω-
Octadecane epoxide APEO, polyoxyethylene 20 sorbitan monopalmitate, isopropyl myristate, methyl chloroisothiazole
Quinoline ketone is mixed with ethylene glycol, is heated to 65 DEG C, with 350rpm speed stirring reaction 1.5 hours, is cooled to room temperature, is obtained solution
A；
（2）By weight ratio, by rare earth oxide, sodium tripolyphosphate, tartaric acid, biosurfactant, Sodium Polyacrylate,
Poloxamer188 is added to the water, and is heated to 45 DEG C, is stirred 45 minutes with 180rpm speed, is cooled to room temperature, obtains solution
B,
（3）Above-mentioned solution A and solution B are mixed, 16h is stirred at room temperature, 24h is stood, produces compound textile auxiliary.
Comparative example one
This comparative example provides a kind of textile auxiliary, and it with being in place of the difference of embodiment one：Including alpha-sulfo-ω-
Octadecane epoxide APEO, methylchloroisothiazandnone and biosurfactant.
Comparative example two
This comparative example provides a kind of textile auxiliary, and it with being in place of the difference of embodiment one：Include sodium tripolyphosphate,
Poloxamer188, and the rare earth oxide is lanthana, strontium oxide strontia, cobalt oxide and the cerium oxide of one-component.
Textile after being dyed using the textile auxiliary of the invention provided, color and luster is beautiful, and color is uniform, no dye
The anomalies such as spot, dye-uptake is high, and dye utilization rate is high, and overall printing and dyeing work well.
Textile after being dyed according to National Textile testing standard to the above-mentioned textile auxiliary of use carries out color jail
Degree, antibiotic property and antistatic property test, for the ease of comparing, will not use the textile auxiliary prepared by the present invention to carry out
Textile after dyeing is as blank example, and test result is as shown in the table：
As seen from the above table, the textile after being dyed using the textile auxiliary of the invention prepared, in washing, friction and light
Excellent color fastness is showed according to lower, while the antibiotic rate of anti-Staphylococcus aureus is not less than 95.8%, antistatic half-life period is not
Higher than 11.5 seconds, good antibiotic property and antistatic behaviour, excellent combination property are shown.The effect of the textile auxiliary of the present invention
Really various, function is more, it is possible to decrease the usage amount of printing and dyeing assistant, reduces printing and dyeing cost and labor intensity, textile after increase printing and dyeing
Antibacterial and anti-static function, the application demand of consumers in general can be met, application prospect is boundless.
Claims (8)
1. a kind of compound textile auxiliary, it is characterised in that by weight ratio, including following raw material components：Alpha-sulfo-
ω -10-18 parts of octadecane epoxide APEO, 2-5 parts of biosurfactant, 1-3 parts of rare earth oxide, cocounut oil diethanol
3-6 parts of acid amides, 4-8 parts of polyoxyethylene 20 sorbitan monopalmitate, double amido silicon oil 2-6 parts, cocamidopropyl propyl amide beet
2-5 parts of alkali, 1-4 parts of tartaric acid, 6-11 parts of Sodium Polyacrylate, 5-10 parts of poloxamer188, methylchloroisothiazandnone 2-7
Part, 3-5 parts of sodium tripolyphosphate, 2-6 parts of isopropyl myristate, 26-38 parts of ethylene glycol, 18-30 parts of water；
The biosurfactant is at least three in Tea Saponin, sapindoside, sophorolipid, marine alga glycolipid and cysteine
The mixture planted；
The rare earth oxide is at least two mixture of lanthana, strontium oxide strontia, cobalt oxide and cerium oxide.
2. compound textile auxiliary according to claim 1, it is characterised in that the biosurfactant is tea
Saponin, sophorolipid and cysteine, the mass ratio of three is 4:2.8:1.4.
3. compound textile auxiliary according to claim 1, it is characterised in that the biosurfactant is nothing
Suffer from sub- saponin(e, marine alga glycolipid and cysteine, the mass ratio of three is 1.5:2:1.
4. compound textile auxiliary according to claim 1, it is characterised in that the rare earth oxide is mass ratio
For 3:1:The mixture of 2 lanthana, cobalt oxide and cerium oxide.
5. compound textile auxiliary according to claim 1, it is characterised in that the molecular weight of the Sodium Polyacrylate
For 1200-2000.
6. the compound textile auxiliary according to claim any one of 1-5, it is characterised in that by weight ratio, bag
Include following raw material components：Alpha-sulfo-ω -14 parts of octadecane epoxide APEO, 3.5 parts of biosurfactant, rare earth
1.3 parts of oxide, 4 parts of cocounut oil diglycollic amide, 5 parts of polyoxyethylene 20 sorbitan monopalmitate, 3 parts of double amido silicon oils,
4 parts of Cocoamidopropyl betaine, 2.8 parts of tartaric acid, 8 parts of Sodium Polyacrylate, 7 parts of poloxamer188, methyl chloroisothiazole
5 parts of quinoline ketone, 3.5 parts of sodium tripolyphosphate, 4.2 parts of isopropyl myristate, 32 parts of ethylene glycol, 26 parts of water.
7. the preparation technology of the compound textile auxiliary as described in claim any one of 1-6, it is characterised in that including with
Lower preparation process：
（1）By weight ratio, by double amido silicon oils, cocounut oil diglycollic amide, Cocoamidopropyl betaine, alpha-sulfo-ω-
Octadecane epoxide APEO, polyoxyethylene 20 sorbitan monopalmitate, isopropyl myristate, methyl chloroisothiazole
Quinoline ketone is mixed with ethylene glycol, is heated to 60-80 DEG C, with 200-500rpm speed stirring reaction 1-2 hours, is cooled to room temperature,
Obtain solution A；
（2）By weight ratio, by rare earth oxide, sodium tripolyphosphate, tartaric acid, biosurfactant, Sodium Polyacrylate,
Poloxamer188 is added to the water, and is heated to 30-50 DEG C, is stirred 30-60 minutes with 100-300rpm speed, is cooled to room
Temperature, obtains solution B,
（3）Above-mentioned solution A and solution B are mixed, 12-20h is stirred at room temperature, 24h is stood, produces compound textile auxiliary.
8. the preparation technology of compound textile auxiliary according to claim 7, it is characterised in that the step（1）
In be heated to 72 DEG C, with 300rpm speed stirring reaction 1 hour；The step（2）In be heated to 45 DEG C, with 180rpm speed
Degree stirring 50 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710158628.8A CN106958153A (en) | 2017-03-17 | 2017-03-17 | A kind of compound textile auxiliary and its preparation technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710158628.8A CN106958153A (en) | 2017-03-17 | 2017-03-17 | A kind of compound textile auxiliary and its preparation technology |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106958153A true CN106958153A (en) | 2017-07-18 |
Family
ID=59471273
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710158628.8A Pending CN106958153A (en) | 2017-03-17 | 2017-03-17 | A kind of compound textile auxiliary and its preparation technology |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106958153A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108396574A (en) * | 2018-04-09 | 2018-08-14 | 山东冬瑞高新技术开发有限公司 | A kind of green printing auxiliary agent and preparation method thereof |
| CN112694892A (en) * | 2019-10-22 | 2021-04-23 | 中国石油化工股份有限公司 | Soil leaching composition for removing mercury, application thereof and method for repairing soil |
| CN113699808A (en) * | 2021-08-27 | 2021-11-26 | 苏州橄榄枝鸿远纺织品有限公司 | Composite stable textile printing and dyeing auxiliary |
| CN113943582A (en) * | 2021-10-20 | 2022-01-18 | 淄博倍尔科新型材料有限公司 | Novel permeable surfactant for papermaking pulping |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103757944A (en) * | 2014-01-14 | 2014-04-30 | 傅科杰 | Composite printing and dyeing auxiliary as well as preparation method and application of auxiliary |
| CN104818630A (en) * | 2015-04-27 | 2015-08-05 | 苏州市吴中区甪直明达漂染厂 | Auxiliary agent for fabric dyeing pretreatment |
| CN105350357A (en) * | 2015-11-17 | 2016-02-24 | 安徽三宝棉纺针织投资有限公司 | Method using rare earth for assisted dyeing of pure cotton fabric |
| CN105463885A (en) * | 2015-12-22 | 2016-04-06 | 安徽三宝棉纺针织投资有限公司 | Pure cotton fabric dyeing assistant and preparation method thereof |
| CN105463883A (en) * | 2015-12-15 | 2016-04-06 | 桐乡市濮院羊毛衫职业技术学校 | Printing and dyeing auxiliary |
| CN106120392A (en) * | 2016-07-29 | 2016-11-16 | 芜湖华烨工业用布有限公司 | A kind of printing and dyeing assistant and preparation method thereof |
-
2017
- 2017-03-17 CN CN201710158628.8A patent/CN106958153A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103757944A (en) * | 2014-01-14 | 2014-04-30 | 傅科杰 | Composite printing and dyeing auxiliary as well as preparation method and application of auxiliary |
| CN104818630A (en) * | 2015-04-27 | 2015-08-05 | 苏州市吴中区甪直明达漂染厂 | Auxiliary agent for fabric dyeing pretreatment |
| CN105350357A (en) * | 2015-11-17 | 2016-02-24 | 安徽三宝棉纺针织投资有限公司 | Method using rare earth for assisted dyeing of pure cotton fabric |
| CN105463883A (en) * | 2015-12-15 | 2016-04-06 | 桐乡市濮院羊毛衫职业技术学校 | Printing and dyeing auxiliary |
| CN105463885A (en) * | 2015-12-22 | 2016-04-06 | 安徽三宝棉纺针织投资有限公司 | Pure cotton fabric dyeing assistant and preparation method thereof |
| CN106120392A (en) * | 2016-07-29 | 2016-11-16 | 芜湖华烨工业用布有限公司 | A kind of printing and dyeing assistant and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108396574A (en) * | 2018-04-09 | 2018-08-14 | 山东冬瑞高新技术开发有限公司 | A kind of green printing auxiliary agent and preparation method thereof |
| CN108396574B (en) * | 2018-04-09 | 2020-06-02 | 江门市新会区德盈化工有限公司 | Green printing and dyeing auxiliary and preparation method thereof |
| CN112694892A (en) * | 2019-10-22 | 2021-04-23 | 中国石油化工股份有限公司 | Soil leaching composition for removing mercury, application thereof and method for repairing soil |
| CN112694892B (en) * | 2019-10-22 | 2022-07-12 | 中国石油化工股份有限公司 | Soil leaching composition for removing mercury, application thereof and method for repairing soil |
| CN113699808A (en) * | 2021-08-27 | 2021-11-26 | 苏州橄榄枝鸿远纺织品有限公司 | Composite stable textile printing and dyeing auxiliary |
| CN113943582A (en) * | 2021-10-20 | 2022-01-18 | 淄博倍尔科新型材料有限公司 | Novel permeable surfactant for papermaking pulping |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106958153A (en) | A kind of compound textile auxiliary and its preparation technology | |
| CN101589189B (en) | Method for antimicrobially finishing textiles and fibers | |
| CN109267405B (en) | Dye-resistant stable additive composition, preparation method and application thereof, compound cellulase and application thereof | |
| CN101955691A (en) | Dispersed deep blue dye composition | |
| CN106087470B (en) | A kind of environment-friendly type terylene fabric sand washing dyeing | |
| US3471248A (en) | Dye carrier compositions | |
| CN106245371A (en) | A kind of chitin sodium chloride acid stain levelling agent | |
| CN102493227A (en) | Steaming-and-washing-free printing paste, and novel steaming-and-washing-free printing process | |
| CN104530751B (en) | A kind of dispersed ruby dye composition | |
| CN102619111B (en) | Method for dyeing conductive polyester fiber | |
| CN105926329A (en) | Acrylic color fixing agent and preparation method thereof | |
| CN110965374A (en) | Environment-friendly chlorine-resistant color fixing agent and preparation method thereof | |
| CN102372932B (en) | Disperse red dye composition | |
| CN108708016A (en) | A kind of spinning process of cation terylene modified fiber and silk/cotton blended yarn | |
| WO2014061568A1 (en) | Acid dye composition, and dyeing method using same | |
| CN104610777B (en) | A kind of red composite dye for hair brocade blend dyeing | |
| CN107164114A (en) | A kind of antifouling soaping agent of the quaternary ammonium salt of chain containing APEO and preparation method thereof | |
| CN105212290B (en) | A kind of underwear Chitin Cotton blended knitted fabric | |
| CN1420227A (en) | Process for dyeing clothing finished products | |
| CN115044229A (en) | Black dye composition for dyeing diacetate fibers, disperse dye and application thereof | |
| CN104695224B (en) | A kind of combed cotton and linen blend fabric fire retardant | |
| CN106758377A (en) | A kind of blend polyester dyeing fabric liquid | |
| CN107312359A (en) | A kind of hair removes from office black acid dyes and preparation method thereof | |
| CN113529437A (en) | Dyeing method of elastic fabric | |
| KR20180020560A (en) | Textile softener of silicone type and it's manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170718 |