CN106957738A - A kind of bleaching agent containing attapulgite and preparation method thereof - Google Patents
A kind of bleaching agent containing attapulgite and preparation method thereof Download PDFInfo
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- CN106957738A CN106957738A CN201710232813.7A CN201710232813A CN106957738A CN 106957738 A CN106957738 A CN 106957738A CN 201710232813 A CN201710232813 A CN 201710232813A CN 106957738 A CN106957738 A CN 106957738A
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- parts
- bleaching agent
- attapulgite
- agent containing
- preparation
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Abstract
The present invention provides a kind of bleaching agent containing attapulgite and preparation method thereof, using attapulgite as main component, also including NaOH, AEO, acrylic acid, essence, anionic stabilizer, helps bleaching agent, blowing agent and water.The bleaching agent effect that the present invention is provided is good, stability is high, it is extensive using field, the attapulgite composition of use has environment friendly and pollution-free characteristic, and dirt-removing power is strong, and washing articles are not damaged, the present invention is with low cost, manufacture craft is simple, and exhaust emission will not be produced in production process, meets the environment-friendly and green demand for development of today's society.
Description
Technical field
The invention belongs to articles for washing technical field, and in particular to a kind of to contain the bleaching agent of attapulgite and its preparation side
Method.
Background technology
Bleaching is that coloring matter is decomposed into colour killing by chemical action, obtains the technical process of necessary whiteness.Many institutes
Known, bleaching is all widely used in multiple fields such as weaving, papermaking, washing, food, medical treatment.At present, commercially extensively
The bleach product used is generally divided into two classes：Chlorine bleach and oxygen bleaching agent.Chlorine bleach contains sodium hypochlorite, calcium hypochlorite, two
Chlorine monoxid etc.；And oxygen bleaching agent then containing hydrogen peroxide or some can discharge the compound of peroxide, for example sodium perborate or
SODIUM PERCARBONATE.With the progress and the lifting of preparation technology of material science, attapulgite material comes into the sight of people, at each
Industry is increasingly widely applied.
Attapulgite refers to a kind of clay mineral by key component of attapulgite, and attapulgite is hydrated for a kind of crystalloid
Alumina magnesia silicate, with unique layer chain structure feature, nanoscale hole passage microtexture, have specific surface area it is big,
The features such as the mesoporous material of duct development, are a kind of ideal structural materials.Attapulgite's surface is in hydrophily, is only suitable for
Used in polar system, but add and be difficult to disperse in the organic systems such as plastics, rubber, chemical fibre, solvent based coating, it is impossible to body
The specific function of existing attapulgite.The all compositions containing environmental pollution of bleaching agent currently on the market either have to washings
The composition of infringement, it is therefore desirable to which a kind of more preferable bleaching agent meets the environmental requirement of people.
The content of the invention
It is an object of the invention to provide a kind of bleaching agent containing attapulgite, the present invention is with low cost, manufacture craft letter
It is single, exhaust emission will not be produced in production process, meets the environment-friendly and green demand for development of today's society.
The invention provides following technical scheme：
A kind of bleaching agent containing attapulgite, includes the composition of following parts by weight：50-80 parts of attapulgite, NaOH 23-
41 parts, 17-24 parts of AEO, 18-28 parts of acrylic acid, 8-15 parts of essence, 12-25 parts of anionic stabilizer, help
12-22 parts of 10-14 parts of bleaching agent, 15-25 parts of blowing agent and water.
It is preferred that, include the composition of following parts by weight：55-75 parts of attapulgite, 25-34 parts of NaOH, poly alkyl alcohol
19-22 parts of oxygen vinethene, 18-26 parts of acrylic acid, 8-12 parts of essence, 16-22 parts of anionic stabilizer, help 10-12 parts of bleaching agent,
14-20 parts of 17-23 parts of blowing agent and water.
It is preferred that, include the composition of following parts by weight：64 parts of attapulgite, 30 parts of NaOH, aliphatic alcohol polyethenoxy
22 parts of ether, 18 parts of acrylic acid, 11 parts of essence, 19 parts of anionic stabilizer, help 18 parts of 11 parts of bleaching agent, 23 parts of blowing agent and water.
It is preferred that, the anionic stabilizer is polyacrylamide.
A kind of preparation method of the bleaching agent containing attapulgite, comprises the following steps：
Step 1: attapulgite is dried into 30-40min at 80-100 DEG C, 80-100 mesh sieve was crushed to；
Step 2: attapulgite powder and NaOH, AEO, acrylic acid, water are mixed, at 80-100 DEG C
It is lower to heat and stir 30-55min；
Step 3: adding essence, anionic stabilizer, helping bleaching agent and blowing agent, 2-4h is stood after stirring；
Step 4: being filtered 2-4 times after standing, you can obtain bleaching agent finished product.
It is preferred that, step one temperature is 80 DEG C, and will not destroy attapulgite composition can remove moisture removal well again.
It is preferred that, the step one sifts out number for 100 mesh, is easy to attapulgite fully to dissolve.
It is preferred that, the step 2 heating-up temperature is 100 DEG C, is conducive to the dissolving of attapulgite.
The beneficial effects of the invention are as follows：
The unique texture that the attapulgite that the present invention is used has so that with certain adsorptivity, so that prepare
Bleaching agent bleaching effect has strengthened.
The anionic stabilizer added in the present invention, helps so that the structure of bleaching agent is more stable, use time is held
Long, action effect is lasting, so as to improve bleaching effect.
The bleaching agent effect that the present invention is provided is good, and stability is high, and using field extensively, the attapulgite composition of use has
Environment friendly and pollution-free characteristic, and dirt-removing power is strong, and washing articles are not damaged, the present invention is with low cost, and manufacture craft is simple,
Exhaust emission will not be produced in production process, meets the environment-friendly and green demand for development of today's society.
Embodiment
Embodiment 1
A kind of bleaching agent containing attapulgite, includes the composition of following parts by weight：80 parts of attapulgite, 41 parts of NaOH,
24 parts of AEO, 28 parts of acrylic acid, 15 parts of essence, 25 parts of anionic stabilizer, help 14 parts of bleaching agent, blowing agent
25 parts and 22 parts of water.
Anionic stabilizer is polyacrylamide.
A kind of preparation method of the bleaching agent containing attapulgite, comprises the following steps：
Step 1: attapulgite is dried into 40min at 80 DEG C, 100 mesh sieve were crushed to；
Step 2: attapulgite powder and NaOH, AEO, acrylic acid, water are mixed, at 100 DEG C
Heat and stir 55min；
Step 3: adding essence, anionic stabilizer, helping bleaching agent and blowing agent, 4h is stood after stirring；
Step 4: being filtered 4 times after standing, you can obtain bleaching agent finished product.
Step one temperature is 80 DEG C, and will not destroy attapulgite composition can remove moisture removal well again.
Step one sifts out number for 100 mesh, is easy to attapulgite fully to dissolve.
Step 2 heating-up temperature is 100 DEG C, is conducive to the dissolving of attapulgite.
30 clothes with even depth color are taken, the market bleach of 15 and in the market is bleached with the bleaching agent of the embodiment
Agent bleaches 15, and market bleach agent of the time relative in the market that the bleaching agent bleaching of the embodiment is used will lack 60min.
Embodiment 2
A kind of bleaching agent containing attapulgite, includes the composition of following parts by weight：50 parts of attapulgite, 23 parts of NaOH,
17 parts of AEO, 18 parts of acrylic acid, 8 parts of essence, 12 parts of anionic stabilizer, help 10 parts of bleaching agent, blowing agent
15 parts and 12 parts of water.
Anionic stabilizer is polyacrylamide.
A kind of preparation method of the bleaching agent containing attapulgite, comprises the following steps：
Step 1: attapulgite is dried into 30min at 80 DEG C, 100 mesh sieve were crushed to；
Step 2: attapulgite powder and NaOH, AEO, acrylic acid, water are mixed, at 100 DEG C
Heat and stir 30min；
Step 3: adding essence, anionic stabilizer, helping bleaching agent and blowing agent, 2h is stood after stirring；
Step 4: being filtered 2 times after standing, you can obtain bleaching agent finished product.
Step one temperature is 80 DEG C, and will not destroy attapulgite composition can remove moisture removal well again.
Step one sifts out number for 100 mesh, is easy to attapulgite fully to dissolve.
Step 2 heating-up temperature is 100 DEG C, is conducive to the dissolving of attapulgite.
30 clothes with even depth color are taken, the market bleach of 15 and in the market is bleached with the bleaching agent of the embodiment
Agent bleaches 15, and market bleach agent of the time relative in the market that the bleaching agent bleaching of the embodiment is used will lack 90min.
Embodiment 3
A kind of bleaching agent containing attapulgite, includes the composition of following parts by weight：80 parts of attapulgite, 23 parts of NaOH,
24 parts of AEO, 18 parts of acrylic acid, 15 parts of essence, 12 parts of anionic stabilizer, help 14 parts of bleaching agent, blowing agent
15 parts and 22 parts of water.
Anionic stabilizer is polyacrylamide.
A kind of preparation method of the bleaching agent containing attapulgite, comprises the following steps：
Step 1: attapulgite is dried into 34min at 80 DEG C, 100 mesh sieve were crushed to；
Step 2: attapulgite powder and NaOH, AEO, acrylic acid, water are mixed, at 100 DEG C
Heat and stir 45min；
Step 3: adding essence, anionic stabilizer, helping bleaching agent and blowing agent, 3h is stood after stirring；
Step 4: being filtered 4 times after standing, you can obtain bleaching agent finished product.
Step one temperature is 80 DEG C, and will not destroy attapulgite composition can remove moisture removal well again.
Step one sifts out number for 100 mesh, is easy to attapulgite fully to dissolve.
Step 2 heating-up temperature is 100 DEG C, is conducive to the dissolving of attapulgite.
30 clothes with even depth color are taken, the market bleach of 15 and in the market is bleached with the bleaching agent of the embodiment
Agent bleaches 15, and market bleach agent of the time relative in the market that the bleaching agent bleaching of the embodiment is used will lack 70min.
Embodiment 4
A kind of bleaching agent containing attapulgite, includes the composition of following parts by weight：50 parts of attapulgite, 41 parts of NaOH,
17 parts of AEO, 28 parts of acrylic acid, 8 parts of essence, 25 parts of anionic stabilizer, help 10 parts of bleaching agent, blowing agent
25 parts and 12 parts of water.
Anionic stabilizer is polyacrylamide.
A kind of preparation method of the bleaching agent containing attapulgite, comprises the following steps：
Step 1: attapulgite is dried into 30min at 80 DEG C, 100 mesh sieve were crushed to；
Step 2: attapulgite powder and NaOH, AEO, acrylic acid, water are mixed, at 100 DEG C
Heat and stir 30min；
Step 3: adding essence, anionic stabilizer, helping bleaching agent and blowing agent, 4h is stood after stirring；
Step 4: filter 23 after standing, you can obtain bleaching agent finished product.
Step one temperature is 80 DEG C, and will not destroy attapulgite composition can remove moisture removal well again.
Step one sifts out number for 100 mesh, is easy to attapulgite fully to dissolve.
Step 2 heating-up temperature is 100 DEG C, is conducive to the dissolving of attapulgite.
30 clothes with even depth color are taken, the market bleach of 15 and in the market is bleached with the bleaching agent of the embodiment
Agent bleaches 15, and market bleach agent of the time relative in the market that the bleaching agent bleaching of the embodiment is used will lack 60min.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for a person skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic.All essences in the present invention
God is with principle, and any modifications, equivalent substitutions and improvements made etc. should be included within the scope of the present invention.
Claims (8)
1. a kind of bleaching agent containing attapulgite, it is characterised in that include the composition of following parts by weight：Attapulgite 50-80
Part, 23-41 parts of NaOH, 17-24 parts of AEO, 18-28 parts of acrylic acid, 8-15 parts of essence, anion are steady
Determine 12-25 parts of agent, help 12-22 parts of 10-14 parts of bleaching agent, 15-25 parts of blowing agent and water.
2. a kind of bleaching agent containing attapulgite according to claim 1, it is characterised in that including following parts by weight
Composition：55-75 parts of attapulgite, 25-34 parts of NaOH, 19-22 parts of AEO, 18-26 parts of acrylic acid, perfume
Smart 8-12 parts, 16-22 parts of anionic stabilizer, help 14-20 parts of 10-12 parts of bleaching agent, 17-23 parts of blowing agent and water.
3. a kind of bleaching agent containing attapulgite according to claim 1, it is characterised in that including following parts by weight
Composition：64 parts of attapulgite, 30 parts of NaOH, 22 parts of AEO, 18 parts of acrylic acid, 11 parts of essence, it is cloudy from
Sub- 19 parts of stabilizer, help 18 parts of 11 parts of bleaching agent, 23 parts of blowing agent and water.
4. a kind of bleaching agent containing attapulgite according to claim any one of 1-3, it is characterised in that it is described it is cloudy from
Sub- stabilizer is polyacrylamide.
5. a kind of preparation method of bleaching agent containing attapulgite described in claim any one of 1-3, it is characterised in that bag
Include following steps：
Step 1: attapulgite is dried into 30-40min at 80-100 DEG C, 80-100 mesh sieve was crushed to；
Step 2: attapulgite powder and NaOH, AEO, acrylic acid, water are mixed, at 80-100 DEG C
It is lower to heat and stir 30-55min；
Step 3: adding essence, anionic stabilizer, helping bleaching agent and blowing agent, 2-4h is stood after stirring；
Step 4: being filtered 2-4 times after standing, you can obtain bleaching agent finished product.
6. a kind of preparation method of bleaching agent containing attapulgite according to claim 5, it is characterised in that the step
A rapid temperature is 80 DEG C.
7. a kind of preparation method of bleaching agent containing attapulgite according to claim 5, it is characterised in that the step
Rapid one sifts out number for 100 mesh.
8. a kind of preparation method of bleaching agent containing attapulgite according to claim 5, it is characterised in that the step
Rapid two heating-up temperature is 100 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710232813.7A CN106957738A (en) | 2017-04-11 | 2017-04-11 | A kind of bleaching agent containing attapulgite and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710232813.7A CN106957738A (en) | 2017-04-11 | 2017-04-11 | A kind of bleaching agent containing attapulgite and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106957738A true CN106957738A (en) | 2017-07-18 |
Family
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710232813.7A Withdrawn CN106957738A (en) | 2017-04-11 | 2017-04-11 | A kind of bleaching agent containing attapulgite and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114635241A (en) * | 2022-03-24 | 2022-06-17 | 薛强 | Rinsing process for textile long yarns |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86104614A (en) * | 1985-07-05 | 1987-04-22 | 陶氏化学公司 | Mixed metal layer hydroxide compound-clay adducts as the thickening material of water and other hydrophylic fluids |
| US5723424A (en) * | 1996-09-23 | 1998-03-03 | Jennings; Paul E. | Concrete cleaning mixture |
| CN1325950A (en) * | 2001-07-10 | 2001-12-12 | 梁广川 | Nm-class composite detergent and its preparing process |
| CN1446893A (en) * | 2002-03-25 | 2003-10-08 | 周永璋 | Environmental protection washing power made from concavo-convex rhabdolith of nano meerschaum |
-
2017
- 2017-04-11 CN CN201710232813.7A patent/CN106957738A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86104614A (en) * | 1985-07-05 | 1987-04-22 | 陶氏化学公司 | Mixed metal layer hydroxide compound-clay adducts as the thickening material of water and other hydrophylic fluids |
| US5723424A (en) * | 1996-09-23 | 1998-03-03 | Jennings; Paul E. | Concrete cleaning mixture |
| CN1325950A (en) * | 2001-07-10 | 2001-12-12 | 梁广川 | Nm-class composite detergent and its preparing process |
| CN1446893A (en) * | 2002-03-25 | 2003-10-08 | 周永璋 | Environmental protection washing power made from concavo-convex rhabdolith of nano meerschaum |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114635241A (en) * | 2022-03-24 | 2022-06-17 | 薛强 | Rinsing process for textile long yarns |
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Application publication date: 20170718 |
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