CN106947646A - A kind of Novel desk arraying biomolecule sterilizes cold wash liquid - Google Patents

A kind of Novel desk arraying biomolecule sterilizes cold wash liquid Download PDF

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Publication number
CN106947646A
CN106947646A CN201610002601.5A CN201610002601A CN106947646A CN 106947646 A CN106947646 A CN 106947646A CN 201610002601 A CN201610002601 A CN 201610002601A CN 106947646 A CN106947646 A CN 106947646A
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China
Prior art keywords
tablecloth
proportionally
wash
bacterium
washing
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CN201610002601.5A
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Chinese (zh)
Inventor
孙善家
纪晓岚
崔瑛
王翠
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Qingdao Jie Jie Lin Biotechnology Co Ltd
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Qingdao Jie Jie Lin Biotechnology Co Ltd
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Priority to CN201610002601.5A priority Critical patent/CN106947646A/en
Publication of CN106947646A publication Critical patent/CN106947646A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Cold wash liquid is sterilized the present invention relates to a kind of Novel desk arraying biomolecule, formula main component is that EM bacterium, sea grass polysaccharide, marine organisms cytokines and neutral surface active agent compounding process special process are made, and is mainly used under cold water wash conditions the decontamination of the tablecloth and degerming;With following features:(1), wash under cold water environment, without heating, infringement of the reduction high temperature to the tablecloth;(2), the catalysis of bion, decomposition, accelerate removal of the surfactant to spot;(3), the decontamination of washing the tablecloth and a degerming step complete, contained biological degerming component can quickly remove the bacterium and mould grown on the tablecloth, not stay mildew;(4), break traditions tablecloth washing process, only need to once lead wash and twice rinsing, without prewashing and neutralization procedure;(5), neutral wash environment, reduced infringement of the alkali to cloth grass, the cost of reduction washing material;(6), material composition there is the effect that purifies water, reduce the pollution to environment.

Description

A kind of Novel desk arraying biomolecule sterilizes cold wash liquid
Technical field sterilizes cold wash liquid the present invention relates to a kind of Novel desk arraying biomolecule, and formula main component is EM bacterium, west Pyrrole oronain, sea grass polysaccharide, marine organisms cytokines, NPE, fatty acid potassium soap, fatty alcohol ether sulfosuccinic acid list Ester disodium is formed by special process configuration, is mainly used under cold water wash conditions the decontamination of the tablecloth and degerming.The tablecloth is paving A class textile on the table, it is in addition to easy cleaning is tidied up, or one kind can give people Comfortable attractive, graceful magnificent sensation Ornament, but be also a kind of fabric of the difficult washing of comparison.Because the species of its dirt is very more, there are drinks and beverage stain, move Plant greasy dirt, the various spots such as dish stain, salt, sugar, soy sauce, cigarette ash, and hotel can also use the tablecloth to wipe visitor in order to easy to clean Desktop after people's use, more aggravates the greasy dirt scope on the tablecloth.The condition of different Fouling Cleanings and the decontamination composition being directed to Also it is different, but washing factory is difficult by the tablecloth Wash Separately of a variety of dirts, in order to cost-effective by all kinds, various dirts Dirt or the tablecloth in different hotels are all put in washing in a washing cage, and it is difficult by various spots to be so under normal acid-base condition Get rid of, therefore wash temperature will be increased to greater than to 70 DEG C, then put into substantial amounts of alkaline components to reach removal oiliness The effect of dirt, but the service life of so tablecloth will be reduced;It it is also one and the tablecloth is the article on dining table Bacterial infection source, is very easy to cause cross pollution, it is easy to cause the Escherichia coli of old man, children to propagate.Therefore, it is a both Tablecloth heavy oil can be removed dirty, again can be cost-effective, the careless service life of cloth is improved, the tablecloth cleaning solution of degerming sterilization is washing The eager demand in market.Of the present invention is that biological enzyme composition is mutually compounded with surfactant, is not heating cold water Under wash conditions, the washing times of the tablecloth drop in the quick grease for removing tablecloth contamination, spot, infringement of no high temperature to fabric Wash and rinse twice for once master, shorten wash time, save washing cost.
The cleaning solution species that the tablecloth is washed in background technology market is very more, and used mode is all in tablecloth prewashing Master afterwards washes and middle could added, in addition it is also necessary to its effect of high-temperature heating competence exertion.And these detergent be all it is overbasic, General cleaning solution pH value all > 12, caustic soda content reaches 60 %, then grease fusing, filament expansion at high temperature, by grease and Dirt is got rid of, but so high-alkali and high temperature has very big damage to fiber, is unfavorable for the maintenance of fabric.And due to Master with the addition of excessive alkaline components in washing, and the number of times of rinsing will increase, not only waste water resource, and increase tablecloth fabric The infringement of mechanical force is added;The last step neutralized in acid, is to neutralize the alkaline components of tablecloth remained on surface, makes cloth grass The final pH value that presents will add substantial amounts of acid, injury of the acid to tablecloth fabric in neutrality in order to neutralize too high alkali Very big, and because the oil-dirt of the tablecloth is relatively more, acid, alkali amount can will than the washing addition of other fabrics Greatly, the service life of such tablecloth can be reduced seriously, and breakage rate can be very high, not only adds cost, if sorting carelessness, makes Damaged cloth grass is upper on desktop, will also result in impression decline of the guest to hotel, causes damage.The traditional handicraft of tablecloth washing There are shortcomings, highly energy-consuming, high cost, not environmentally, without specific sterilization component, therefore, people need one kind can in a hurry Do not heat, it is strong for oil-dirt removal, it is cost-effective, small cold water tablecloth personal cleansing liquid is damaged to the tablecloth.The present invention Purpose be just to provide one kind specifically designed for tablecloth oil-dirt, decontamination and sterilization are combined as a whole, do not heated, cold water is used The tablecloth personal cleansing liquid of washing.
The content of the invention the method is characterized in that addition can be gentle with property surfactant mutually compound, and have quickening The activation enzyme component of surfactant and spot fusion faculty, promotes the dissolving to spot of surfactant under cryogenic Speed, while cytokines composition of the addition with bactericidal action, degerming purpose is reached to the tablecloth while washing.Present invention choosing The formula selected is as follows(Component and its percentage by weight %):EM bacterium 0.5-1.0, Cetylpyridinium Chloride 3.0-5.0, sea grass polysaccharide 4.0- 6.0th, marine organisms cytokines 0.8-1.5, NPE 12.0-15.0, fatty acid potassium soap 6.0-9.0, fatty alcohol ether Sulfosuccinic acid monoesters disodium 11.0-13.0, purified water add to 100.
EM bacterium are to include the beneficial mushroom such as photosynthetic bacteria, saccharomycete, lactic acid bacteria to be occasionally grouped together in the flora formed together, this A little bacteriums can decompose the animal and vegetable oil on the tablecloth, have special efficacy to animal oil decomposition.On the tablecloth based on animal and vegetable oil spot, It is very easy to inside infiltrated fiber, and alkalescence and acidic chemical raw material are difficult to penetrate into, is just very easy to leave the marking after washing, and EM Bacterium is then dissolved in surfactant based on bacterium after oil components are decomposed, just can quickly be rinsed, and do not stay The marking;EM bacterium can also suppress the breeding of other pathogens simultaneously, eliminate the peculiar smell left on the tablecloth, the tablecloth is kept salubrious.
Cetylpyridinium Chloride belongs to cationic nitrogenous surfactant, and it has efficient bactericidal action.The tablecloth exists as people Hotel has a meal the article for making hand directly contact, and especially makes old man and child be easy to go the hand of the handled tablecloth again to grab food Thing, such pathogenic bacteria will be easily advanced into people's body interior, therefore sterilization of the tablecloth in washing process is very heavy Want.And Cetylpyridinium Chloride is better than other cationic surfactants, such as use in 10mg/L to the killing rate bacterium of bacterium, mould Under amount, the killing rate to heterotroph, iron bacteria and sulfate reducing bacteria is respectively 99.9%, 99.9%% and 99.99%.Cetylpyridinium Chloride The effect of the sterilization algae removal, slimes dispersant and the cleaning systems that also have, sewage is discharged into sewage disposal system and made after by washing, Cetylpyridinium Chloride can also play the role of purification to the holding vessel of long term storage sewage.Cetylpyridinium Chloride or one kind have efficient simultaneously The surfactant of cleaning action, it quickly can decompose the spot of solidification and soluble in water after mutually being compounded with EM bacterium, and And the foam of Cetylpyridinium Chloride, emulsibility are very high, can increase the soil release performance to the tablecloth.
Sea grass polysaccharide is the polysaccharide component extracted from marine organisms Enteromorpha, can suppress the breeding of various pathogens, The cohesive of its height can reach the permanent fungistatic effect to the tablecloth.Sea grass polysaccharide, which has, simultaneously improves surfactant work Property effect, in addition sea grass polysaccharide and system without sea grass polysaccharide, under equal conditions, with the cleaning solution of same amount Wash the tablecloth of equivalent weight, add the cleaning solution of sea grass polysaccharide than without cleaning solution washing quality be higher by three/ One.
Marine organisms cytokines is the cytokines composition refined from marine organisms algae, with very high bactericidal action.By Do not heated, without high-alkali, peracid in using this cold water cleaning solution, it is therefore desirable to which special sterilization component could be by the pathogenic bacteria of cloth grass Get rid of comprehensively.Marine organisms cytokines is a kind of efficient, comprehensive bactericide, for Escherichia coli, staphylococcus aureus Sterilizing rate can reach more than 99.999%, more than 99.99% can be reached to Candida albicans and the sterilizing rate of mould, and do not stay Mildew.
NPE is with the nonionic table of nonyl phenol and the oxirane condensation reaction under catalyst action Face activating agent, with good infiltration, emulsification, scattered, antiacid, alkali resistant, hard water resistance, anti-reduction, oxidation resistant ability, its pH value Between 5.0-7.0, neutral state is presented, the damage of fabric will not be caused because of alkali is crossed, and live in sea grass polysaccharide and biology Under the catalytic action of element, clean effect will improve 30%.
Fatty acid potassium soap is a kind of anion surfactant, is a kind of main body active matter of efficient remover, in meta-alkali Property under the conditions of, can arbitrarily with anion, nonionic and high polymer cationic surfactant compound, at a temperature of 40 DEG C -60 DEG C, It mutually compounds and can be completely combined with NPE and fatty alcohol ether sulfosuccinic acid monoesters disodium, is formed very steady Fixed system, and clean effect is double.
Fatty alcohol ether sulfosuccinic acid monoesters disodium has excellent washing, emulsification, scattered, wetting, the performance of solubilising;Thorn Sharp property is low, and has irritating effect of reduction other surfaces activating agent, damage of the reduction detergent to the tablecloth;And this into The pH value divided is between 5.0-6.0, and the property of its meta-acid just neutralizes the property of fatty acid potassium soap meta-alkali, makes cleaning solution system whole Body presents neutral.
The preparation method of product of the present invention is:
1), sea grass polysaccharide extraction:
(1), by Enteromorpha through over cleaning, go after impurity removing to carry out 37 DEG C of -40 DEG C of drying;
(2), by the Enteromorpha after drying through crushing, grinding after, immersion purified water in, soak 1 hour;
(3), the soak suction filtration of Enteromorpha obtained into suction filtration clarified solution;
(4), proportionally add 95% ethanol to ethanol and reach 75%, refrigerate static 12 hours;
(5), suction filtration obtain sediment, residual ethanol is washed away, vacuum drying i.e. can obtain sea grass polysaccharide.
2), marine organisms cytokines extraction:
(1), by marine algae through over cleaning, decontamination;
(2), by algae substances and purified water 1:2 ratio mixing, water heats temperature control in 40-60 DEG C after opening, and slow fire is decocted Endure 4 hours, obtain active component;
(3), centrifuging and taking supernatant, obtain bios composition.
3), the biological cold wash liquid of the tablecloth preparation:
(1), proportionally purified water added in emulsion tank, be heated to 40 DEG C, keep 40 DEG C of constant temperature;
(2), proportionally by NPE, fatty acid potassium soap, fatty alcohol ether sulfosuccinic acid monoesters disodium distinguish It is added in emulsion tank, stirs 30 minutes;
(3), Cetylpyridinium Chloride is proportionally added slowly in emulsion tank, be heated to 50 DEG C, stir 10 minutes;
(4), stop heating, proportionally sea grass polysaccharide, marine organisms cytokines are added in emulsion tank, stir 5 minutes;
(5), finally EM bacterium are proportionally added in emulsion tank, stir;
(6), stand and recover room temperature, dispense under gnotobasis and use.
The present invention has advantages below:
(1), the tablecloth is washed under cold water environment, without heating, infringement of the reduction high temperature to the tablecloth;
(2), bion catalytic action, and decomposition of the EM bacterium to fats spot accelerate surfactant to spot Removal;
(3), the decontamination of washing the tablecloth and a degerming step complete, contained biological degerming component can quickly remove the tablecloth The bacterium and mould of upper growth, do not stay mildew;
(4), break traditions tablecloth washing process, only need to once lead wash and twice rinsing, without prewashing and neutralization procedure;
(5), neutral wash environment, reduced infringement of the alkali to cloth grass, the cost of reduction washing material;
(6), material composition there is the effect that purifies water, reduce the pollution to environment.
Embodiment:With reference to embodiment, the present invention is described in further detail:
1. according to data listed in Table(Percentage by weight %)And its step is configured:
Formula one:EM bacterium 0.5-1.0, Cetylpyridinium Chloride 3.0-5.0, sea grass polysaccharide 4.0-6.0, marine organisms cytokines 0.8-1.5, nonyl Base phenol polyethenoxy ether 12.0-15.0, fatty acid potassium soap 6.0-9.0, fatty alcohol ether sulfosuccinic acid monoesters disodium 11.0- 13.0th, purified water adds to 100.
Formula two:EM bacterium 0.5-0.7, Cetylpyridinium Chloride 3.0-4.0, sea grass polysaccharide 4.0-5.0, marine organisms cytokines 1.2- 1.5th, NPE 12.0-13.5, fatty acid potassium soap 6.0-7.5, fatty alcohol ether sulfosuccinic acid monoesters disodium 11.0-12.0, purified water add to 100.
Formula three:EM bacterium 0.7-1.0, Cetylpyridinium Chloride 4.0-5.0, sea grass polysaccharide 5.0-6.0, marine organisms cytokines 1.2- 1.5th, NPE 13.5-15.0, fatty acid potassium soap 7.5-9.0, fatty alcohol ether sulfosuccinic acid monoesters disodium 12.0-13.0, purified water add to 100.

Claims (2)

1. sterilize cold wash liquid the present invention relates to a kind of Novel desk arraying biomolecule, it is characterised in that with following formula(Component and its Percentage by weight %):EM bacterium 0.5-1.0, Cetylpyridinium Chloride 3.0-5.0, sea grass polysaccharide 4.0-6.0, marine organisms cytokines 0.8-1.5, NPE 12.0-15.0, fatty acid potassium soap 6.0-9.0, fatty alcohol ether sulfosuccinic acid monoesters disodium 11.0- 13.0th, purified water adds to 100.
2. Novel desk arraying biomolecule described in a kind of claim 1 sterilizes cold wash liquid, it is characterised in that with the steps:
1), sea grass polysaccharide extraction:
(1), by Enteromorpha through over cleaning, go after impurity removing to carry out 37 DEG C of -40 DEG C of drying;
(2), by the Enteromorpha after drying through crushing, grinding after, immersion purified water in, soak 1 hour;
(3), the soak suction filtration of Enteromorpha obtained into suction filtration clarified solution;
(4), proportionally add 95% ethanol to ethanol and reach 75%, refrigerate static 12 hours;
(5), suction filtration obtain sediment, residual ethanol is washed away, vacuum drying i.e. can obtain sea grass polysaccharide;
2), marine organisms cytokines extraction:
(1), by marine algae through over cleaning, decontamination;
(2), by algae substances and purified water 1:2 ratio mixing, water heats temperature control in 40-60 DEG C after opening, and slow fire is decocted Endure 4 hours, obtain active component;
(3), centrifuging and taking supernatant, obtain bios composition;
3), the biological cold wash liquid of the tablecloth preparation:
(1), proportionally purified water added in emulsion tank, be heated to 40 DEG C, keep 40 DEG C of constant temperature;
(2), proportionally by NPE, fatty acid potassium soap, fatty alcohol ether sulfosuccinic acid monoesters disodium distinguish It is added in emulsion tank, stirs 30 minutes;
(3), Cetylpyridinium Chloride is proportionally added slowly in emulsion tank, be heated to 50 DEG C, stir 10 minutes;
(4), stop heating, proportionally sea grass polysaccharide, marine organisms cytokines are added in emulsion tank, stir 5 minutes;
(5), finally EM bacterium are proportionally added in emulsion tank, stir;
(6), stand and recover room temperature, dispense under gnotobasis and use.
CN201610002601.5A 2016-01-06 2016-01-06 A kind of Novel desk arraying biomolecule sterilizes cold wash liquid Pending CN106947646A (en)

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Application Number Priority Date Filing Date Title
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1519312A (en) * 2003-01-23 2004-08-11 中国科学院微生物研究所 Erythro micrococcus Em and usage for generating biologic emulsifier as well as degrading polycyclic aromatic hydrocarbon
CN101023973A (en) * 2006-12-01 2007-08-29 广州中医药大学第二附属医院 Extract of polysaccharide of lithospermum erthrorhizon and composition containing same and use thereof
CN101684435A (en) * 2008-09-28 2010-03-31 福建恒安集团有限公司 Sterilization hand washing solution
CN101760346A (en) * 2009-12-17 2010-06-30 陈政 Multi-component concentrated dish cleanser
CN102391917A (en) * 2011-09-22 2012-03-28 澄思源生物科技(上海)有限公司 Microbial cleaning agent for pesticides on fruits and vegetables and preparation method for microbial cleaning agent
CN102703249A (en) * 2012-06-28 2012-10-03 澳宝化妆品(惠州)有限公司 Cleaning and protecting integrated infant laundry detergent
CN104250586A (en) * 2013-06-26 2014-12-31 青岛道合生物科技有限公司 Enteromorpha prolifera-containing tableware cleaning agent

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1519312A (en) * 2003-01-23 2004-08-11 中国科学院微生物研究所 Erythro micrococcus Em and usage for generating biologic emulsifier as well as degrading polycyclic aromatic hydrocarbon
CN101023973A (en) * 2006-12-01 2007-08-29 广州中医药大学第二附属医院 Extract of polysaccharide of lithospermum erthrorhizon and composition containing same and use thereof
CN101684435A (en) * 2008-09-28 2010-03-31 福建恒安集团有限公司 Sterilization hand washing solution
CN101760346A (en) * 2009-12-17 2010-06-30 陈政 Multi-component concentrated dish cleanser
CN102391917A (en) * 2011-09-22 2012-03-28 澄思源生物科技(上海)有限公司 Microbial cleaning agent for pesticides on fruits and vegetables and preparation method for microbial cleaning agent
CN102703249A (en) * 2012-06-28 2012-10-03 澳宝化妆品(惠州)有限公司 Cleaning and protecting integrated infant laundry detergent
CN104250586A (en) * 2013-06-26 2014-12-31 青岛道合生物科技有限公司 Enteromorpha prolifera-containing tableware cleaning agent

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