CN106947415A - The strong Graft Adhesive of the cheap bonding force of environmental protection - Google Patents

The strong Graft Adhesive of the cheap bonding force of environmental protection Download PDF

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Publication number
CN106947415A
CN106947415A CN201710258341.2A CN201710258341A CN106947415A CN 106947415 A CN106947415 A CN 106947415A CN 201710258341 A CN201710258341 A CN 201710258341A CN 106947415 A CN106947415 A CN 106947415A
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parts
neoprenes
graft adhesive
antioxidant
toluene
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CN201710258341.2A
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陈建发
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/04Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/023On to modified polymers, e.g. chlorinated polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/026Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethylene-vinylester copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F289/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention relates to a kind of strong Graft Adhesive of environmentally friendly cheap bonding force, the preparing raw material of the Graft Adhesive includes following components by weight:290~330 parts of toluene, 1~3 part of ethylene vinyl acetate plastic grains, 75~90 parts of SN242 neoprenes, 6~9 parts of 320 2 neoprene, 26~30 parts of methyl methacrylate, 23~27 parts of benzoyl peroxide, 10~14 parts of 264 antioxidant, 12~16 parts of 138 rosin resin, 17~21 parts of 1515 high-performance HCPE, 2~4 parts of the domestic chlorinated rubbers of S 20.Graft Adhesive is water white transparency colloid made from the formula of the present invention, do not turn yellow, smell it is small, cheap and environmental protection, common Graft Adhesive can lift 15~25% on cementability relative market, more extensive using scope, with good promotional value.

Description

The strong Graft Adhesive of the cheap bonding force of environmental protection
Technical field
The present invention relates to a kind of adhesive, a kind of strong Graft Adhesive of environmentally friendly cheap bonding force is particularly related to.
Background technology
In the various fields such as grafting adhesive is widely used in packing, built, shoemaking, furniture, machine-building.Current city The smell of common Graft Adhesive is big on field, production cost is high, and its bonding force is also not highly desirable, is adopted so as to result in every profession and trade It is simultaneously little with the usage amount of grafting adhesive.
The content of the invention
The present invention provides a kind of environmentally friendly cheap bonding force strong Graft Adhesive, to overcome existing most grafting adhesives to exist Smell it is big, production cost is high, using it is limited the problem of.
The present invention is adopted the following technical scheme that:
The strong Graft Adhesive of the cheap bonding force of environmental protection, the preparing raw material of the Graft Adhesive includes following components by weight:Toluene 290 ~330 parts, 1~3 part of ethylene vinyl acetate plastic grains, 75~90 parts of SN242 neoprenes, 320-2 neoprenes 6~9 Part, 26~30 parts of methyl methacrylate, 23~27 parts of benzoyl peroxide, 10~14 parts of 264 antioxidant, 138 rosin resins 12~16 parts, 17~21 parts of 1515 high-performance HCPE, 2~4 parts of the domestic chlorinated rubbers of S-20.
Specifically, the preparation of the Graft Adhesive preferably following four kinds of prescriptions:
First, the preparing raw material of the Graft Adhesive is made up of following components by weight:300 parts of toluene, ethylene vinyl acetate 1.5 parts of plastic grains, 80 parts of SN242 neoprenes, 7 parts of 320-2 neoprenes, 29 parts of methyl methacrylate, benzoyl peroxide 26 parts of formyl, 11 parts of 264 antioxidant, 13 parts of 138 rosin resin, 20 parts of 1515 high-performance HCPE, S-20 states Produce 2 parts of chlorinated rubber.
Second, the preparing raw material of the Graft Adhesive is made up of following components by weight:320 parts of toluene, ethylene vinyl acetate second 2.5 parts of alkene ester plastic grains, 85 parts of SN242 neoprenes, 8 parts of 320-2 neoprenes, 27 parts of methyl methacrylate, peroxide Change 24 parts of benzoyl, 13 parts of 264 antioxidant, 15 parts of 138 rosin resin, 18 parts of 1515 high-performance HCPE, S- 20 domestic 3 parts of chlorinated rubbers.
Third, the preparing raw material of the Graft Adhesive is made up of following components by weight:330 parts of toluene, ethylene vinyl acetate second 1 part of alkene ester plastic grains, 75 parts of SN242 neoprenes, 9 parts of 320-2 neoprenes, 26 parts of methyl methacrylate, peroxidating 23 parts of benzoyl, 14 parts of 264 antioxidant, 12 parts of 138 rosin resin, 21 parts of 1515 high-performance HCPE, S-20 Domestic 4 parts of chlorinated rubber.
Fourth, the preparing raw material of the Graft Adhesive is made up of following components by weight:290 parts of toluene, ethylene vinyl acetate second 3 parts of alkene ester plastic grains, 90 parts of SN242 neoprenes, 6 parts of 320-2 neoprenes, 30 parts of methyl methacrylate, peroxidating 27 parts of benzoyl, 264 antioxidant 10,16 parts of 138 rosin resin, 1515 high-performance HCPEs 17, S-20 are domestic 2 parts of chlorinated rubber.
Further with improvement, the preparing raw material of the Graft Adhesive is made up of following components by weight:Dichloromethane 150~ 175 parts, 95~100 parts of 120# solvent naphthas, 17~22 parts of isocyanates, 22~28 parts of MEA, 13~18 parts of methyl ether, ethyl ester 77~79 parts, 290~330 parts of toluene, 1~3 part of ethylene vinyl acetate plastic grains, 75~90 parts of SN242 neoprenes, 6~9 parts of 320-2 neoprenes, 26~30 parts of methyl methacrylate, 23~27 parts of benzoyl peroxide, 264 antioxidant 10~ 14 parts, 12~16 parts of 138 rosin resin, 17~21 parts of 1515 high-performance HCPE, the domestic chlorinated rubbers 2 of S-20 ~4 parts.
Specifically, the preparation of the Graft Adhesive preferably following four kinds of prescriptions:
First, the preparing raw material of the Graft Adhesive is made up of following components by weight:170 parts of dichloromethane, 120# solvent naphthas 96 parts, 20 parts of isocyanates, 24 parts of MEA, 17 parts of methyl ether, 79 parts of ethyl ester, 300 parts of toluene, ethylene vinyl acetate plastic cement 1.5 parts of particle, 80 parts of SN242 neoprenes, 7 parts of 320-2 neoprenes, 29 parts of methyl methacrylate, benzoyl peroxide 26 parts, 11 parts of 264 antioxidant, 13 parts of 138 rosin resin, 20 parts of 1515 high-performance HCPE, the domestic chlorine of S-20 Change 2 parts of rubber.
Second, the preparing raw material of the Graft Adhesive is made up of following components by weight:160 parts of dichloromethane, 120# are molten 98 parts of agent oil, 18 parts of isocyanates, 26 parts of MEA, 15 parts of methyl ether, 78 parts of ethyl ester, 315 parts of toluene, ethylene vinyl acetate 2 parts of plastic grains, 85 parts of SN242 neoprenes, 8 parts of 320-2 neoprenes, 28 parts of methyl methacrylate, benzoyl peroxide first 25 parts of acyl, 12 parts of 264 antioxidant, 14 parts of 138 rosin resin, 19 parts of 1515 high-performance HCPE, S-20 are domestic 3 parts of chlorinated rubber.
Third, the preparing raw material of the Graft Adhesive is made up of following components by weight:150 parts of dichloromethane, 120# are molten 95 parts of agent oil, 22 parts of isocyanates, 28 parts of MEA, 18 parts of methyl ether, 77 parts of ethyl ester, 330 parts of toluene, ethylene vinyl acetate 3 parts of plastic grains, 75 parts of SN242 neoprenes, 6 parts of 320-2 neoprenes, 26 parts of methyl methacrylate, benzoyl peroxide first 27 parts of acyl, 14 parts of 264 antioxidant, 16 parts of 138 rosin resin, 17 parts of 1515 high-performance HCPE, S-20 are domestic 2 parts of chlorinated rubber.
Fourth, the preparing raw material of the Graft Adhesive is made up of following components by weight:175 parts of dichloromethane, 120# are molten 100 parts of agent oil, 17 parts of isocyanates, 22 parts of MEA, 13 parts of methyl ether, 79 parts of ethyl ester, 290 parts of toluene, ethylene-vinyl acetate 1 part of ester plastic grains, 90 parts of SN242 neoprenes, 9 parts of 320-2 neoprenes, 30 parts of methyl methacrylate, benzoyl peroxide 23 parts of formyl, 10 parts of 264 antioxidant, 12 parts of 138 rosin resin, 21 parts of 1515 high-performance HCPE, S-20 states Produce 3 parts of chlorinated rubber.
From the above-mentioned description of this invention, compared to the prior art, the invention has the advantages that:The present invention's matches somebody with somebody The obtained Graft Adhesive in side is water white transparency colloid, do not turn yellow, smell it is small, cheap and environmental protection, on cementability relative market Common Graft Adhesive can lift 15~25%, more extensive using scope, with good promotional value.
Embodiment
Embodiment one
The preparing raw material of the Graft Adhesive of present embodiment is made up of following components by weight:300 parts of toluene, ethylene vinyl acetate 1.5 parts of vinyl acetate plastic grains, 80 parts of SN242 neoprenes, 7 parts of 320-2 neoprenes, 29 parts of methyl methacrylate, mistake 26 parts of BP, 11 parts of 264 antioxidant, 13 parts of 138 rosin resin, 20 parts of 1515 high-performance HCPE, 2 parts of the domestic chlorinated rubbers of S-20.Graft Adhesive made from the formula of present embodiment be water white transparency colloid, do not turn yellow, smell it is small, Common Graft Adhesive can lift 17~19% on cheap and environmental protection, cementability relative market.
Embodiment two
The preparing raw material of the Graft Adhesive of present embodiment is made up of following components by weight:320 parts of toluene, ethylene vinyl acetate second 2.5 parts of alkene ester plastic grains, 85 parts of SN242 neoprenes, 8 parts of 320-2 neoprenes, 27 parts of methyl methacrylate, peroxide Change 24 parts of benzoyl, 13 parts of 264 antioxidant, 15 parts of 138 rosin resin, 18 parts of 1515 high-performance HCPE, S- 20 domestic 3 parts of chlorinated rubbers.Graft Adhesive made from the formula of present embodiment be water white transparency colloid, do not turn yellow, smell it is small, valency Lattice are cheap and environmental protection, and common Graft Adhesive can lift 16~18% on cementability relative market.
Embodiment three
The preparing raw material of the Graft Adhesive of present embodiment is made up of following components by weight:330 parts of toluene, ethylene vinyl acetate second 1 part of alkene ester plastic grains, 75 parts of SN242 neoprenes, 9 parts of 320-2 neoprenes, 26 parts of methyl methacrylate, peroxidating 23 parts of benzoyl, 14 parts of 264 antioxidant, 12 parts of 138 rosin resin, 21 parts of 1515 high-performance HCPE, S-20 Domestic 4 parts of chlorinated rubber.Graft Adhesive made from the formula of present embodiment be water white transparency colloid, do not turn yellow, smell it is small, price Common Graft Adhesive can lift 15~17% on cheap and environmental protection, cementability relative market.
Embodiment four
The preparing raw material of the Graft Adhesive of present embodiment is made up of following components by weight:290 parts of toluene, ethylene vinyl acetate second 3 parts of alkene ester plastic grains, 90 parts of SN242 neoprenes, 6 parts of 320-2 neoprenes, 30 parts of methyl methacrylate, peroxidating 27 parts of benzoyl, 264 antioxidant 10,16 parts of 138 rosin resin, 1515 high-performance HCPEs 17, S-20 are domestic 2 parts of chlorinated rubber.Graft Adhesive made from the formula of present embodiment be water white transparency colloid, do not turn yellow, smell it is small, it is cheap And it is environmentally friendly, common Graft Adhesive can lift 16~19% on cementability relative market.
Embodiment five
The preparing raw material of the Graft Adhesive of present embodiment is made up of following components by weight:170 parts of dichloromethane, 120# are molten 96 parts of agent oil, 20 parts of isocyanates, 24 parts of MEA, 17 parts of methyl ether, 79 parts of ethyl ester, 300 parts of toluene, ethylene vinyl acetate 1.5 parts of plastic grains, 80 parts of SN242 neoprenes, 7 parts of 320-2 neoprenes, 29 parts of methyl methacrylate, benzoyl peroxide 26 parts of formyl, 11 parts of 264 antioxidant, 13 parts of 138 rosin resin, 20 parts of 1515 high-performance HCPE, S-20 states Produce 2 parts of chlorinated rubber.Graft Adhesive made from the formula of present embodiment be water white transparency colloid, do not turn yellow, smell it is small, price is low Common Graft Adhesive can lift 22~25% on honest and clean and environmental protection, cementability relative market.
Embodiment six
The preparing raw material of the Graft Adhesive of present embodiment is made up of following components by weight:160 parts of dichloromethane, 120# are molten 98 parts of agent oil, 18 parts of isocyanates, 26 parts of MEA, 15 parts of methyl ether, 78 parts of ethyl ester, 315 parts of toluene, ethylene vinyl acetate 2 parts of plastic grains, 85 parts of SN242 neoprenes, 8 parts of 320-2 neoprenes, 28 parts of methyl methacrylate, benzoyl peroxide first 25 parts of acyl, 12 parts of 264 antioxidant, 14 parts of 138 rosin resin, 19 parts of 1515 high-performance HCPE, S-20 are domestic 3 parts of chlorinated rubber.Graft Adhesive made from the formula of present embodiment be water white transparency colloid, do not turn yellow, smell it is small, it is cheap And it is environmentally friendly, common Graft Adhesive can lift 22~24% on cementability relative market.
Embodiment seven
The preparing raw material of the Graft Adhesive of present embodiment is made up of following components by weight:150 parts of dichloromethane, 120# are molten 95 parts of agent oil, 22 parts of isocyanates, 28 parts of MEA, 18 parts of methyl ether, 77 parts of ethyl ester, 330 parts of toluene, ethylene vinyl acetate 3 parts of plastic grains, 75 parts of SN242 neoprenes, 6 parts of 320-2 neoprenes, 26 parts of methyl methacrylate, benzoyl peroxide first 27 parts of acyl, 14 parts of 264 antioxidant, 16 parts of 138 rosin resin, 17 parts of 1515 high-performance HCPE, S-20 are domestic 2 parts of chlorinated rubber.Graft Adhesive made from the formula of present embodiment be water white transparency colloid, do not turn yellow, smell it is small, it is cheap And it is environmentally friendly, common Graft Adhesive can lift 20~23% on cementability relative market.
Embodiment eight
The preparing raw material of the Graft Adhesive of present embodiment is made up of following components by weight:175 parts of dichloromethane, 120# are molten 100 parts of agent oil, 17 parts of isocyanates, 22 parts of MEA, 13 parts of methyl ether, 79 parts of ethyl ester, 290 parts of toluene, ethylene-vinyl acetate 1 part of ester plastic grains, 90 parts of SN242 neoprenes, 9 parts of 320-2 neoprenes, 30 parts of methyl methacrylate, benzoyl peroxide 23 parts of formyl, 10 parts of 264 antioxidant, 12 parts of 138 rosin resin, 21 parts of 1515 high-performance HCPE, S-20 states Produce 3 parts of chlorinated rubber.Graft Adhesive made from the formula of present embodiment be water white transparency colloid, do not turn yellow, smell it is small, price is low Common Graft Adhesive can lift 19~22% on honest and clean and environmental protection, cementability relative market.
The embodiment of the present invention is above are only, but the design concept of the present invention is not limited thereto, it is all to utilize this Conceive the change that unsubstantiality is carried out to the present invention, the behavior for invading the scope of the present invention all should be belonged to.

Claims (10)

1. the strong Graft Adhesive of environmentally friendly cheap bonding force, it is characterised in that under the preparing raw material of the Graft Adhesive is included by weight State component:290~330 parts of toluene, 1~3 part of ethylene vinyl acetate plastic grains, 75~90 parts of SN242 neoprenes, 320- 2 6~9 parts of neoprenes, 26~30 parts of methyl methacrylate, 23~27 parts of benzoyl peroxide, 264 antioxidant 10~14 Part, 12~16 parts of 138 rosin resin, 17~21 parts of 1515 high-performance HCPE, the domestic chlorinated rubbers 2 of S-20~ 4 parts.
2. the strong Graft Adhesive of environmentally friendly cheap bonding force as claimed in claim 1, it is characterised in that the preparing raw material of the Graft Adhesive It is made up of following components by weight:300 parts of toluene, 1.5 parts of ethylene vinyl acetate plastic grains, SN242 neoprenes 80 parts, 7 parts of 320-2 neoprenes, 29 parts of methyl methacrylate, 26 parts of benzoyl peroxide, 11 parts of 264 antioxidant, 138 pine 13 parts of botany bar gum, 20 parts of 1515 high-performance HCPE, 2 parts of the domestic chlorinated rubbers of S-20.
3. the strong Graft Adhesive of environmentally friendly cheap bonding force as claimed in claim 1, it is characterised in that the preparing raw material of the Graft Adhesive It is made up of following components by weight:320 parts of toluene, 2.5 parts of ethylene vinyl acetate plastic grains, SN242 neoprenes 85 parts, 8 parts of 320-2 neoprenes, 27 parts of methyl methacrylate, 24 parts of benzoyl peroxide, 13 parts of 264 antioxidant, 138 pine 15 parts of botany bar gum, 18 parts of 1515 high-performance HCPE, 3 parts of the domestic chlorinated rubbers of S-20.
4. the strong Graft Adhesive of environmentally friendly cheap bonding force as claimed in claim 1, it is characterised in that the preparing raw material of the Graft Adhesive It is made up of following components by weight:330 parts of toluene, 1 part of ethylene vinyl acetate plastic grains, SN242 neoprenes 75 Part, 9 parts of 320-2 neoprenes, 26 parts of methyl methacrylate, 23 parts of benzoyl peroxide, 14 parts of 264 antioxidant, 138 rosin 12 parts of resin, 21 parts of 1515 high-performance HCPE, 4 parts of the domestic chlorinated rubbers of S-20.
5. the strong Graft Adhesive of environmentally friendly cheap bonding force as claimed in claim 1, it is characterised in that the preparing raw material of the Graft Adhesive It is made up of following components by weight:290 parts of toluene, 3 parts of ethylene vinyl acetate plastic grains, SN242 neoprenes 90 Part, 6 parts of 320-2 neoprenes, 30 parts of methyl methacrylate, 27 parts of benzoyl peroxide, 264 antioxidant 10,138 rosin trees 16 parts of fat, 1515 high-performance HCPEs 17,2 parts of the domestic chlorinated rubbers of S-20.
6. the strong Graft Adhesive of environmentally friendly cheap bonding force as claimed in claim 1, it is characterised in that the preparing raw material of the Graft Adhesive It is made up of following components by weight:150~175 parts of dichloromethane, 95~100 parts of 120# solvent naphthas, isocyanates 17~ 22 parts, 22~28 parts of MEA, 13~18 parts of methyl ether, 77~79 parts of ethyl ester, 290~330 parts of toluene, ethylene vinyl acetate 1~3 part of plastic grains, 75~90 parts of SN242 neoprenes, 6~9 parts of 320-2 neoprenes, methyl methacrylate 26~30 Part, 23~27 parts of benzoyl peroxide, 10~14 parts of 264 antioxidant, 12~16 parts of 138 rosin resin, the high chlorine of 1515 high-performance Change 17~21 parts of polyvinyl resin, 2~4 parts of the domestic chlorinated rubbers of S-20.
7. the strong Graft Adhesive of environmentally friendly cheap bonding force as claimed in claim 6, it is characterised in that the preparing raw material of the Graft Adhesive It is made up of following components by weight:170 parts of dichloromethane, 96 parts of 120# solvent naphthas, 20 parts of isocyanates, MEA 24 Part, 17 parts of methyl ether, 79 parts of ethyl ester, 300 parts of toluene, 1.5 parts of ethylene vinyl acetate plastic grains, 80 parts of SN242 neoprenes, 7 parts of 320-2 neoprenes, 29 parts of methyl methacrylate, 26 parts of benzoyl peroxide, 11 parts of 264 antioxidant, 138 rosin trees 13 parts of fat, 20 parts of 1515 high-performance HCPE, 2 parts of the domestic chlorinated rubbers of S-20.
8. the strong Graft Adhesive of environmentally friendly cheap bonding force as claimed in claim 6, it is characterised in that the preparing raw material of the Graft Adhesive It is made up of following components by weight:160 parts of dichloromethane, 98 parts of 120# solvent naphthas, 18 parts of isocyanates, MEA 26 Part, 15 parts of methyl ether, 78 parts of ethyl ester, 315 parts of toluene, 2 parts of ethylene vinyl acetate plastic grains, 85 parts of SN242 neoprenes, 8 parts of 320-2 neoprenes, 28 parts of methyl methacrylate, 25 parts of benzoyl peroxide, 12 parts of 264 antioxidant, 138 rosin trees 14 parts of fat, 19 parts of 1515 high-performance HCPE, 3 parts of the domestic chlorinated rubbers of S-20.
9. the strong Graft Adhesive of environmentally friendly cheap bonding force as claimed in claim 6, it is characterised in that the preparing raw material of the Graft Adhesive It is made up of following components by weight:150 parts of dichloromethane, 95 parts of 120# solvent naphthas, 22 parts of isocyanates, MEA 28 Part, 18 parts of methyl ether, 77 parts of ethyl ester, 330 parts of toluene, 3 parts of ethylene vinyl acetate plastic grains, 75 parts of SN242 neoprenes, 6 parts of 320-2 neoprenes, 26 parts of methyl methacrylate, 27 parts of benzoyl peroxide, 14 parts of 264 antioxidant, 138 rosin trees 16 parts of fat, 17 parts of 1515 high-performance HCPE, 2 parts of the domestic chlorinated rubbers of S-20.
10. the strong Graft Adhesive of environmentally friendly cheap bonding force as claimed in claim 6, it is characterised in that the preparation of the Graft Adhesive is former Material is made up of following components by weight:175 parts of dichloromethane, 100 parts of 120# solvent naphthas, 17 parts of isocyanates, monoethanol 22 parts of amine, 13 parts of methyl ether, 79 parts of ethyl ester, 290 parts of toluene, 1 part of ethylene vinyl acetate plastic grains, SN242 neoprenes 90 Part, 9 parts of 320-2 neoprenes, 30 parts of methyl methacrylate, 23 parts of benzoyl peroxide, 10 parts of 264 antioxidant, 138 rosin 12 parts of resin, 21 parts of 1515 high-performance HCPE, 3 parts of the domestic chlorinated rubbers of S-20.
CN201710258341.2A 2017-04-19 2017-04-19 The strong Graft Adhesive of the cheap bonding force of environmental protection Pending CN106947415A (en)

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马兴法等: "CR-MMA-CEVA接枝共聚物的制备及其粘合性", 《合成橡胶工业》 *

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Application publication date: 20170714