CN106946474A - A kind of electronical display glues the online minimizing technology of tin with float flat glass - Google Patents
A kind of electronical display glues the online minimizing technology of tin with float flat glass Download PDFInfo
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- CN106946474A CN106946474A CN201710229444.6A CN201710229444A CN106946474A CN 106946474 A CN106946474 A CN 106946474A CN 201710229444 A CN201710229444 A CN 201710229444A CN 106946474 A CN106946474 A CN 106946474A
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- China
- Prior art keywords
- tin
- frequency induction
- high frequency
- induction heater
- gas
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/0075—Cleaning of glass
Abstract
The online minimizing technology of tin is glued with float flat glass the present invention relates to a kind of electronical display, is comprised the following steps:Step 1: setting high frequency induction heater after tin groove forming process;Step 2: the frequency of adjustment high frequency induction heater, is allowed to heat metallic tin;Step 3: metallic tin is oxidized into stannous oxide gas or tin oxide solid;Step 4: stannous oxide gas or tin oxide solid are blown off plate glass.Advantages of the present invention:This method sets high frequency induction heater between molten tin bath and cutting, by adjusting electromagnetism working frequency, realize to metallic tin heating without being heated to nonmetallic glass, the viscous tin of oxidation, under poor oxygen condition, make viscous tin oxidation generation stannous oxide gas, under oxygen-enriched state, make viscous tin oxidation generation tin oxide solid powder, metallic tin is departed from plate glass belt upper and lower surface, during except tin, it can effectively prevent that glass surface is scratched.
Description
Technical field
The present invention relates to plate glass float process technical field, more particularly to a kind of electronical display float flat glass
The online minimizing technology of viscous tin.
Background technology
In float flat glass technique, master operation be raw material proportioning, melting furnaces fusing, tin groove forming, annealing kiln anneal,
Cold end cutting etc., is coupled with flow liquid road between melting furnaces and molten tin bath, is coupled between molten tin bath and annealing kiln with transition roller table, molten tin bath is into
Type equipment, the tin liquor for containing fusing, the glass metal of fusing enters molten tin bath, and the plate glass outlet molten tin bath of shaping, shaping is former
Reason is to swim in glass metal in tin liquor to shakeout and form plate glass.
Because tin liquor is oxidizable, therefore the protective gas that nitrogen is mixed with hydrogen must be injected into molten tin bath, make the beginning in molten tin bath
Malleation is kept eventually, protective gas injects from tin groove roof, import and export blowout from molten tin bath and gap is oozed out.
In actual use, always have a small amount of oxygen reversely to penetrate into molten tin bath, aoxidize tin liquor, produced in molten tin bath many
Plant chemical reaction.Under high temperature and Hypoxic habitats, the oxidizable generation stannous oxide of tin liquor(SnO)Gas, floats towards the low temperature of end
Qu Hou, after temperature is down to below 870 DEG C, stannous oxide gas can become the solid powder of sn-containing compound;In high temperature and richness
Under oxygen environment, the oxidizable generation tin oxide of tin liquor(SnO2)Solid powder;Stannous oxide and tin oxide can also be reduced into tiny
Tin drips;These stanniferous things are shed on plate glass band, will result in the pollution of plate glass belt upper surface.
With the development of electronical display industry, electronical display is manufactured with plate glass as trend using floating process.
But, the plate glass produced with floating process, the lower surface meeting minimal residue contacted with tin liquor glues tin, as electronic product
When can influence glass electric property, thus be necessary to remove the viscous tin of residual.
High frequency induction heater by electromagnetic induction principle, using electromagnetic eddy to metal and nonmetallic progress rapidly, it is non-
Contact heating, the body surface that is particularly suitable for use in heating.To non-metallic object heat, electromagnetism working frequency 240MHZ and more than, energy
Make the vibration per second of its interior molecules atom, rub as many as more than one hundred million time heating using microwaves.Metal object is heated, electromagnetism working frequency
For several KHzs(KHZ)To more than hundreds of KHzs, hardware heating and precious metal smelting are commonly used for.For example, using microwave
Stove, using two same porcelain cups, one empty, a dress water, while after heating 1 minute, empty cup is not warm, dress cup and water are equal
Heat, that is can to penetrate porcelain cup heating water because of microwave, and water heats porcelain cup.It can be seen that, can be fast using specific electromagnetic frequency
Speed heating predetermined substance, without heating or heating other materials slowly.
A kind of ideal method for removing the viscous tin of residual on plate glass is not yet found at this stage through retrieval extensively, by
In the special property of high frequency induction heater, the applicant devises a kind of method for removing the viscous tin of plate glass residual to make
With.
The content of the invention
The invention aims to solve to remain viscous tin present in float glass technology at this stage, the follow-up production of influence
The shortcoming of product electric property, and a kind of electronical display proposed glues the online minimizing technology of tin with float flat glass.
To achieve these goals, present invention employs following technical scheme:
A kind of electronical display glues the online minimizing technology of tin with float flat glass, it is characterised in that comprise the following steps:
Step 1: setting high frequency induction heater after tin groove forming process;
Step 2: the frequency of adjustment high frequency induction heater, is allowed to specific and metallic tin is heated;
Step 3: metallic tin is oxidized into stannous oxide gas or tin oxide solid;
Step 4: stannous oxide gas or tin oxide solid are blown off plate glass.
On the basis of above-mentioned technical proposal, there can be technical scheme further below:
The high frequency induction heater is arranged on plate glass belt below or above, and high frequency induction heater is arranged on and cuts out work
Before sequence.
Under oxygen-enriched state:
Oxidizing gas channel is provided between a, the high frequency induction heater and plate glass belt, oxidizing gas is air or oxygen
Gas;
B, adjustment high frequency induction heater power, instant heating glue more than tin to oxidizing temperature, make metallic tin oxidation generation oxidation
Tin solid powder;
C, ventilate and tin oxide solid powder is blown off plate glass;
D, the electromagnetism working frequency of online fixed holding high frequency induction heater and power.
Under poor oxygen condition:
A, above and below plate glass belt, set box-like seal closure, oxide regions are sealed, the high-frequency induction heating
Device is arranged in seal closure, and gap is left between seal closure and plate glass belt;
B, positive pressure protection gas is passed through in seal closure;
More than c, adjustment high frequency induction heater power, quick viscous tin to the oxidizing temperature of heating residual, make metallic tin oxidation generation
Stannous oxide gas;
D, ventilation are the blowout of stannous oxide gas, and temperature can be down to less than 870 DEG C, make stannous oxide gas become solid powder and
Fall;
E, the electromagnetism working frequency of online fixed holding high frequency induction heater and power.
Connecting pipe on the seal closure, the positive pressure protection gas is passed through in pipeline, intake valve is connected on pipeline,
Reverse osmosis valve is connected on seal closure.
The seal closure, intake valve, pipeline and reverse osmosis valve are nonmetallic materials.
The advantage of the invention is that:This method sets high-frequency induction heating between tin groove forming process and cutting process
Device, by adjusting electromagnetism working frequency, is realized to metallic tin heating without being heated to nonmetallic glass, the viscous tin of oxidation;In oxygen deprivation
Under state, using high frequency induction heater, instant heating glues more than tin to oxidizing temperature, makes viscous tin oxidation generation stannous oxide gas
Body;Under oxygen-enriched state, using high frequency induction heater, instant heating glues more than tin to oxidizing temperature, makes viscous tin oxidation generation
Tin oxide solid powder, makes metallic tin depart from plate glass belt upper and lower surface.During except tin, glass table can be effectively prevented
Face is scratched.
Embodiment
In order that the present invention is more clearly understood, describe in detail with reference to embodiments, it is described herein only to solve
The present invention is released, is not intended to limit the present invention.
A kind of electronical display float flat glass that embodiment one, the present invention are provided glues the online minimizing technology of tin,
To remove the viscous tin of pollution of the viscous tin of residual of the float flat glass with lower surface and upper surface, tin is removed in plate glass belt
After groove, before cutting is moved to, in mobile plate glass belt below or above, high frequency induction heater is set, electromagnetism work is adjusted
Working frequency, it is best to be allowed to predetermined substance metallic tin heating effect, is realized to metallic tin heating without adding to nonmetallic glass
Heat, under oxygen-enriched state, using high frequency induction heater, instant heating glues more than tin to oxidizing temperature, makes viscous tin oxidation generation
Tin oxide solid powder, is allowed to depart from plate glass belt lower surface.
Specifically use following steps:
Step 1: high frequency induction heater is set after tin groove forming process, between high frequency induction heater and plate glass belt
Provided with gap, gap not only increases heating effect, and effectively prevents that glass from abrading;
Step 2: being provided with oxidizing gas channel between high frequency induction heater and plate glass belt, oxidizing gas is air or oxygen
Gas so that plate glass is under oxygen-enriched state;
Step 3: adjustment high frequency induction heater power, instant heating glues more than tin to oxidizing temperature, make metallic tin oxidation generation
Tin oxide solid powder;
Step 4: ventilation blows off tin oxide solid powder plate glass;
Step 5: the electromagnetism working frequency and power of online fixed holding high frequency induction heater.
Embodiment two, on the basis of embodiment one, under poor oxygen condition, use high frequency induction heater, instant heating
More than viscous tin to oxidizing temperature, make viscous tin oxidation generation stannous oxide gas, be allowed to depart from plate glass belt upper and lower surface, in oxygen
Change stannous Gas drift to go out after heating region, temperature can be down to less than 870 DEG C, become solid powder and fall, so as to remove flat
Viscous tin of the glass sheet with upper and lower surface.To reduce the heat affecting to glass, power and electromagnetism the work frequency of high frequency induction heater
Rate all should be adjustable.
To build Hypoxic habitats, seal closure is set, oxide regions are sealed, pipeline is provided with seal closure, in pipeline
Positive pressure protection gas is passed through, gap is left between seal closure and plate glass belt, for the protective gas and stannous oxide of entrance
Gas overflowing.Intake valve is connected on pipeline, reverse osmosis valve, the seal closure, intake valve, pipeline and reverse osmosis are connected on seal closure
Valve is nonmetallic materials.
Reverse osmosis valve can meet the demand to a small amount of oxygen, after unlatching, while protective gas flows out seal closure, oxygen meeting
Reversely penetrate into seal closure, open different size, for adjusting flow of oxygen in seal closure, make viscous tin oxidation generation stannous oxide
Gas, without generating tin oxide solid.
Comprise the following steps that:
A, above and below plate glass belt, set box-like seal closure, oxide regions are sealed, the high-frequency induction heating
Device is arranged in seal closure, and gap is left between seal closure and plate glass belt,;
B, positive pressure protection gas is passed through in seal closure;
More than c, adjustment high frequency induction heater power, quick viscous tin to the oxidizing temperature of heating residual, make metallic tin oxidation generation
Stannous oxide gas;
D, ventilation are the blowout of stannous oxide gas, and temperature can be down to less than 870 DEG C, make stannous oxide gas become solid powder and
Fall;
E, the electromagnetism working frequency of online fixed holding high frequency induction heater and power.
Claims (6)
1. a kind of electronical display glues the online minimizing technology of tin with float flat glass, it is characterised in that comprise the following steps:
Step 1: setting high frequency induction heater after tin groove forming process;
Step 2: the frequency of adjustment high frequency induction heater, is allowed to heat metallic tin;
Step 3: metallic tin is oxidized into stannous oxide gas or tin oxide solid;
Step 4: stannous oxide gas or tin oxide solid are blown off plate glass.
2. a kind of electronical display according to claim 1 glues the online minimizing technology of tin with float flat glass, its feature exists
In:The high frequency induction heater is arranged on plate glass belt below or above, and high frequency induction heater is arranged on and cuts out work
Before sequence.
3. a kind of electronical display according to claim 1 glues the online minimizing technology of tin with float flat glass, its feature exists
In under oxygen-enriched state:
Oxidizing gas channel is provided between a, the high frequency induction heater and plate glass belt, oxidizing gas is air or oxygen
Gas;
B, adjustment high frequency induction heater power, instant heating glue more than tin to oxidizing temperature, make metallic tin oxidation generation oxidation
Tin solid powder;
C, ventilate and tin oxide solid powder is blown off plate glass;
D, online holding Motionless electromagnetic working frequency and power.
4. a kind of electronical display according to claim 1 glues the online minimizing technology of tin with float flat glass, its feature exists
In under poor oxygen condition:
A, above and below plate glass belt, set box-like seal closure, oxide regions are sealed, the high-frequency induction heating
Device is arranged in seal closure, and gap is left between seal closure and plate glass belt,;
B, positive pressure protection gas is passed through in seal closure;
More than c, adjustment high frequency induction heater power, quick viscous tin to the oxidizing temperature of heating residual, make metallic tin oxidation generation
Stannous oxide gas;
D, ventilation are the blowout of stannous oxide gas, and temperature can be down to less than 870 DEG C, make stannous oxide gas become solid powder and
Fall;
E, the electromagnetism working frequency of online fixed holding high frequency induction heater and power.
5. a kind of electronical display according to claim 4 glues the online minimizing technology of tin with float flat glass, its feature exists
In:Connecting pipe on the seal closure, the positive pressure protection gas is passed through in pipeline, intake valve is connected on pipeline, close
Reverse osmosis valve is connected on sealing cover.
6. a kind of electronical display according to claim 5 glues the online minimizing technology of tin with float flat glass, its feature exists
In:The seal closure, intake valve, reverse osmosis valve and pipeline are nonmetallic materials.
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CN201710229444.6A CN106946474B (en) | 2017-04-10 | 2017-04-10 | A kind of electronical display glues the online minimizing technology of tin with float flat glass |
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CN106946474A true CN106946474A (en) | 2017-07-14 |
CN106946474B CN106946474B (en) | 2019-06-28 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108409112A (en) * | 2018-05-08 | 2018-08-17 | 东台中玻特种玻璃有限公司 | Online float glass process coated glass annealing kiln SO2Protect gas system and operating method |
CN108975661A (en) * | 2018-08-31 | 2018-12-11 | 山东孟友玻璃科技有限公司 | Tin method is moved back on a kind of float glass tin stripping liquid and surface |
CN112645582A (en) * | 2020-12-24 | 2021-04-13 | 蚌埠凯盛工程技术有限公司 | Electromagnetic holding type tin wiping device |
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GB1107883A (en) * | 1964-06-23 | 1968-03-27 | Pilkington Brothers Ltd | Improvements in or relating to flat glass |
JPH04202028A (en) * | 1990-11-30 | 1992-07-22 | Central Glass Co Ltd | Method of cleaning plate glass |
US20060032842A1 (en) * | 2003-02-04 | 2006-02-16 | Kuniaki Hiromatsu | Method for removing foreign matter on glass substrate surface |
CN101553439A (en) * | 2006-12-08 | 2009-10-07 | 旭硝子株式会社 | Process for producing glass sheet |
CN104230176A (en) * | 2014-09-22 | 2014-12-24 | 胡久波 | Ultrathin soda-lime glass reinforced processing method |
CN105143132A (en) * | 2013-04-24 | 2015-12-09 | 旭硝子株式会社 | Method for producing float plate glass |
WO2016063046A1 (en) * | 2014-10-21 | 2016-04-28 | Pilkington Group Limited | Glass treatment |
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2017
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Patent Citations (7)
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GB1107883A (en) * | 1964-06-23 | 1968-03-27 | Pilkington Brothers Ltd | Improvements in or relating to flat glass |
JPH04202028A (en) * | 1990-11-30 | 1992-07-22 | Central Glass Co Ltd | Method of cleaning plate glass |
US20060032842A1 (en) * | 2003-02-04 | 2006-02-16 | Kuniaki Hiromatsu | Method for removing foreign matter on glass substrate surface |
CN101553439A (en) * | 2006-12-08 | 2009-10-07 | 旭硝子株式会社 | Process for producing glass sheet |
CN105143132A (en) * | 2013-04-24 | 2015-12-09 | 旭硝子株式会社 | Method for producing float plate glass |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108409112A (en) * | 2018-05-08 | 2018-08-17 | 东台中玻特种玻璃有限公司 | Online float glass process coated glass annealing kiln SO2Protect gas system and operating method |
CN108975661A (en) * | 2018-08-31 | 2018-12-11 | 山东孟友玻璃科技有限公司 | Tin method is moved back on a kind of float glass tin stripping liquid and surface |
CN108975661B (en) * | 2018-08-31 | 2021-04-13 | 山东孟友玻璃科技有限公司 | Tin stripping liquid for float glass and surface tin stripping method |
CN112645582A (en) * | 2020-12-24 | 2021-04-13 | 蚌埠凯盛工程技术有限公司 | Electromagnetic holding type tin wiping device |
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CN106946474B (en) | 2019-06-28 |
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