CN106944107A - A kind of preparation method of silver phosphate photocatalyst film - Google Patents
A kind of preparation method of silver phosphate photocatalyst film Download PDFInfo
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- CN106944107A CN106944107A CN201710201073.0A CN201710201073A CN106944107A CN 106944107 A CN106944107 A CN 106944107A CN 201710201073 A CN201710201073 A CN 201710201073A CN 106944107 A CN106944107 A CN 106944107A
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- silver
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- phosphoric acid
- quartz glass
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- FJOLTQXXWSRAIX-UHFFFAOYSA-K silver phosphate Chemical compound [Ag+].[Ag+].[Ag+].[O-]P([O-])([O-])=O FJOLTQXXWSRAIX-UHFFFAOYSA-K 0.000 title claims abstract description 27
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 16
- 229940019931 silver phosphate Drugs 0.000 title claims abstract description 15
- 229910000161 silver phosphate Inorganic materials 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 33
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 31
- NDYNABNWLRVCDO-UHFFFAOYSA-N phosphoric acid silver Chemical compound [Ag].P(O)(O)(O)=O NDYNABNWLRVCDO-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000084 colloidal system Substances 0.000 claims abstract description 19
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 18
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims abstract description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000001035 drying Methods 0.000 claims abstract description 10
- 239000011521 glass Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 7
- 230000008569 process Effects 0.000 claims abstract description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011852 carbon nanoparticle Substances 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 229910000397 disodium phosphate Inorganic materials 0.000 claims abstract description 6
- 235000019800 disodium phosphate Nutrition 0.000 claims abstract description 6
- 239000003350 kerosene Substances 0.000 claims abstract description 6
- 239000010453 quartz Substances 0.000 claims abstract description 6
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 230000002045 lasting effect Effects 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 abstract description 2
- 230000003197 catalytic effect Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000002351 wastewater Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000004042 decolorization Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 2
- YYYARFHFWYKNLF-UHFFFAOYSA-N 4-[(2,4-dimethylphenyl)diazenyl]-3-hydroxynaphthalene-2,7-disulfonic acid Chemical compound CC1=CC(C)=CC=C1N=NC1=C(O)C(S(O)(=O)=O)=CC2=CC(S(O)(=O)=O)=CC=C12 YYYARFHFWYKNLF-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229960000907 methylthioninium chloride Drugs 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 2
- 229940043267 rhodamine b Drugs 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- -1 Disodium hydrogen Chemical class 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
- B01J27/1817—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with copper, silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/084—Decomposition of carbon-containing compounds into carbon
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
Abstract
The present invention discloses a kind of preparation method of silver phosphate photocatalyst film.In turn include the following steps：Silver nitrate solution and disodium phosphate soln are mixed under 350~400 revs/min of rotating speed, yellow green colloid substance is formed, 3~4h is persistently stirred, disodium hydrogen phosphate and silver nitrate reaction, generate phosphoric acid silver colloid in whipping process；It is 10~30cm by area2Quartz glass horizontal positioned, phosphoric acid silver colloid brush is dipped with brush in the side surface of quartz glass one, one layer of brush again after drying naturally, then one layer of brush, altogether brush 4~5 times again after drying naturally obtains thin layer phosphoric acid Argent grain in the side surface of quartz glass one；Quartz glass is placed on above the kerosene lamp flame of burning and toasted, covered with silver orthophosphate facing to flame, until covering carbon nano-particle in phosphoric acid silver surface, a kind of silver phosphate photocatalyst film is made.This method covers one layer of carbon-coating in silver orthophosphate film surface, can effectively facilitate electron transmission, improves catalytic effect.
Description
Technical field
The present invention relates to a kind of preparation method for being used to handle the silver phosphate photocatalyst film of organic wastewater, belong to catalysis
Field of material preparation.
Background technology
In the industrial wastewaters such as sanitary sewage, food processing and papermaking, contain carbohydrate, protein, grease, wooden
The organic substances such as element.These materials, can be by the biological chemistry action of microorganism to suspend or dissolved state is present in sewage
And decompose.Need to consume oxygen in its decomposable process, thus be referred to as oxygen consumption pollutant.This pollutant can cause molten in water
Solve oxygen to reduce, the growth of influence fish and other aquatiles.After oxygen in water exhausts, organic matter carries out anaerobic digestion, production
The bad smells such as raw hydrogen sulfide, ammonia and mercaptan, make water quality deterioration.
With the development of production, the murder by poisoning organic pollution produced in industrial and agricultural production seriously threatens environment and people
The health of class, seeks a kind of new and effective environmental improvement technology and has great importance.Photocatalysis technology is because of its energy-conservation, height
Effect, contaminant degradation are thorough, non-secondary pollution advantage, turn into a kind of emerging environmental improvement with important application prospect at present
Technology.In recent years, the development of new and effective visible-light photocatalyst turns into an important research content in photocatalysis technology.
In June, 2010, material research institution researcher has found that silver orthophosphate has the effect of photochemical catalyst, and photooxidation effect is
It is more than the decades of times for being currently known various photochemical catalysts.Because its unique Surface Physical Chemistry property and efficient visible ray light are urged
Change one of performance, focus as research.
But nanoparticles are easily reunited, surface area is greatly reduced after reunion, decreased effectiveness.Need to use appropriate carrier
Or change catalyst macrostructure to obtain preferable catalytic effect.
The content of the invention
The purpose of the present invention be for overcome in the prior art particulate matter be easy to reunion and cause effect difference etc. not enough there is provided one kind
The preparation method of silver phosphate photocatalyst film.
The technical solution adopted by the present invention is in turn include the following steps：
1) 20~24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 6.6~8mmol phosphoric acid is weighed
Disodium hydrogen, is configured to 20mmol/L disodium phosphate soln；
2) both the above solution is mixed under 350~400 revs/min of rotating speed, forms yellow green colloid substance, continued
3~4h is stirred, disodium hydrogen phosphate and silver nitrate reaction, generate phosphoric acid silver colloid in whipping process；
3) it is 10~30cm by area2Quartz glass horizontal positioned, phosphoric acid silver colloid brush is dipped with brush in quartzy glass
The side surface of glass one, one layer of brush again after drying naturally, then one layer of brush, brush 4~5 times altogether, in quartz glass again after drying naturally
One side surface obtains thin layer phosphoric acid Argent grain；
4) quartz glass is placed on above the kerosene lamp flame of burning and toasted, covered with silver orthophosphate facing to flame,
Until covering carbon nano-particle in phosphoric acid silver surface, a kind of silver phosphate photocatalyst film is made.
The beneficial effects of the invention are as follows：
1. the concentration of strict control disodium hydrogen phosphate and silver nitrate advantageously forms silver orthophosphate in 20mmol/L during being somebody's turn to do
Colloid, rather than silver orthophosphate precipitation, colloid are stable in water, will not precipitate, and are conducive in Quartz glass surfaces formation silver orthophosphate
Film.
2. covering one layer of carbonaceous membrane in silver orthophosphate film surface, electron transmission can be accelerated, preferably degraded effect is obtained
Really.
Embodiment
3 embodiments of the present invention are provided further below：
Embodiment 1
24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 8mmol disodium hydrogen phosphates are weighed, configured
Into 20mmol/L disodium phosphate soln；Both the above solution is mixed under 400 revs/min of rotating speed, yellow green is formed
Colloid substance, persistently stirs 4h, and disodium hydrogen phosphate and silver nitrate reaction, generate phosphoric acid silver colloid in whipping process；By area
For 30cm2Quartz glass horizontal positioned, phosphoric acid silver colloid brush is dipped with brush in the side surface of quartz glass one, treats that nature dries
One layer of brush again afterwards, then one layer of brush, altogether brush 5 times again after drying naturally, thin layer phosphoric acid is obtained in the side surface of quartz glass one
Argent grain；Quartz glass is placed on above the kerosene lamp flame of burning and toasted, covered with silver orthophosphate facing to flame, until
Carbon nano-particle is covered in phosphoric acid silver surface, silver phosphate photocatalyst film is made.
Obtained silver phosphate photocatalyst film is used to handle waste water containing acid scarlet：The obtained quartz glass is put
In pending 50mL concentration in 20mg/L waste water containing acid scarlet, light irradiation is in Quartz glass surfaces, through quartz glass
Phosphoric acid silver surface is irradiated in, under the irradiation of 300W Metal halogen lamps, 40min is reacted, percent of decolourization is 96.8%.
Embodiment 2
20mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 6.6mmol disodium hydrogen phosphates is weighed, matches somebody with somebody
It is set to 20mmol/L disodium phosphate soln；Both the above solution is mixed under 350 revs/min of rotating speed, formed yellowish green
Color colloid substance, persistently stirs 3h, and disodium hydrogen phosphate and silver nitrate reaction, generate phosphoric acid silver colloid in whipping process；By face
Product is 10cm2Quartz glass horizontal positioned, phosphoric acid silver colloid brush is dipped with brush in the side surface of quartz glass one, treats that nature dries in the air
One layer of brush again after dry, then one layer of brush, brush 4 times altogether, in the side surface of quartz glass one acquisition thin layer phosphorus again after drying naturally
Sour Argent grain；Quartz glass is placed on above the kerosene lamp flame of burning and toasted, covered with silver orthophosphate facing to flame, directly
Carbon nano-particle is covered in phosphoric acid silver surface, silver phosphate photocatalyst film is made.
Obtained silver phosphate photocatalyst film is used to handle wastewater containing methylene blue：The obtained quartz glass is put
In pending 50mL concentration in 20mg/L wastewater containing methylene blue, light irradiation is in Quartz glass surfaces, through quartz glass
Phosphoric acid silver surface is irradiated in, under the irradiation of 300W Metal halogen lamps, 40min is reacted, percent of decolourization is 95.2%.
Embodiment 3
24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 8mmol disodium hydrogen phosphates are weighed, configured
Into 20mmol/L disodium phosphate soln；Both the above solution is mixed under 350~400 revs/min of rotating speed, forms yellow
Green glue material, persistently stirs 3h, and disodium hydrogen phosphate and silver nitrate reaction, generate phosphoric acid silver colloid in whipping process；Will
Area is 20cm2Quartz glass horizontal positioned, phosphoric acid silver colloid brush is dipped with brush in the side surface of quartz glass one, nature is treated
One layer of brush again after drying, then one layer of brush, altogether brush 5 times again after drying naturally, thin layer is obtained in the side surface of quartz glass one
Phosphoric acid Argent grain；Quartz glass is placed on above the kerosene lamp flame of burning and toasted, covered with silver orthophosphate facing to flame,
Until covering carbon nano-particle in phosphoric acid silver surface, silver phosphate photocatalyst film is made.
Obtained silver phosphate photocatalyst film is used to handle and contains rhodamine B：The obtained quartz glass is put
Pending 50mL concentration containing in rhodamine B for 20mg/L, light irradiation is shone through quartz glass in Quartz glass surfaces
Penetrate in phosphoric acid silver surface, under the irradiation of 300W Metal halogen lamps, react 40min, percent of decolourization is 97.3%.
Claims (1)
1. a kind of preparation method of silver phosphate photocatalyst film, it is characterized in that in turn including the following steps：
1) 20~24mmol silver nitrates are weighed, 20mmol/L silver nitrate solution is configured to, 6.6~8mmol phosphoric acid hydrogen two is weighed
Sodium, is configured to 20mmol/L disodium phosphate soln；
2) both the above solution is mixed under 350~400 revs/min of rotating speed, forms yellow green colloid substance, lasting stirring
3~4h, disodium hydrogen phosphate and silver nitrate reaction, generate phosphoric acid silver colloid in whipping process；
3) it is 10~30cm by area2Quartz glass horizontal positioned, phosphoric acid silver colloid brush is dipped with brush in quartz glass side
Surface, one layer of brush again after drying naturally, then one layer of brush, brush 4~5 times altogether, in quartz glass side table again after drying naturally
Face obtains thin layer phosphoric acid Argent grain；
4) quartz glass is placed on above the kerosene lamp flame of burning and toasted, covered with silver orthophosphate facing to flame, until
Carbon nano-particle is covered in phosphoric acid silver surface, a kind of silver phosphate photocatalyst film is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710201073.0A CN106944107A (en) | 2017-03-30 | 2017-03-30 | A kind of preparation method of silver phosphate photocatalyst film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710201073.0A CN106944107A (en) | 2017-03-30 | 2017-03-30 | A kind of preparation method of silver phosphate photocatalyst film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106944107A true CN106944107A (en) | 2017-07-14 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710201073.0A Pending CN106944107A (en) | 2017-03-30 | 2017-03-30 | A kind of preparation method of silver phosphate photocatalyst film |
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| Country | Link |
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| CN (1) | CN106944107A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134733A (en) * | 2011-01-18 | 2011-07-27 | 浙江大学 | Electrochemical preparation method of silver phosphate photocatalysed semiconductor film adopting electric deposition |
| CN102626647A (en) * | 2012-03-30 | 2012-08-08 | 常州大学 | Synthesizing method of playgouskite-loaded silver orthophosphate photochemical catalyst |
| CN104437569A (en) * | 2014-11-18 | 2015-03-25 | 中国矿业大学 | Preparation method of visible light absorption layer based on Ag3PO4 film |
| CN104624211A (en) * | 2015-01-19 | 2015-05-20 | 江苏大学 | Preparation method of complex photocatalyst responsive to visible light and application of complex photocatalyst |
| KR20150124406A (en) * | 2014-04-28 | 2015-11-05 | 이화여자대학교 산학협력단 | Silver phosphate single crystal film, preparing method thereof, and photocatalyst including the same |
-
2017
- 2017-03-30 CN CN201710201073.0A patent/CN106944107A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134733A (en) * | 2011-01-18 | 2011-07-27 | 浙江大学 | Electrochemical preparation method of silver phosphate photocatalysed semiconductor film adopting electric deposition |
| CN102626647A (en) * | 2012-03-30 | 2012-08-08 | 常州大学 | Synthesizing method of playgouskite-loaded silver orthophosphate photochemical catalyst |
| KR20150124406A (en) * | 2014-04-28 | 2015-11-05 | 이화여자대학교 산학협력단 | Silver phosphate single crystal film, preparing method thereof, and photocatalyst including the same |
| CN104437569A (en) * | 2014-11-18 | 2015-03-25 | 中国矿业大学 | Preparation method of visible light absorption layer based on Ag3PO4 film |
| CN104624211A (en) * | 2015-01-19 | 2015-05-20 | 江苏大学 | Preparation method of complex photocatalyst responsive to visible light and application of complex photocatalyst |
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