CN106942250A - A kind of composition and application process that alternaria leaf spot of crucifers is treated based on guaiacol - Google Patents

A kind of composition and application process that alternaria leaf spot of crucifers is treated based on guaiacol Download PDF

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Publication number
CN106942250A
CN106942250A CN201710235353.3A CN201710235353A CN106942250A CN 106942250 A CN106942250 A CN 106942250A CN 201710235353 A CN201710235353 A CN 201710235353A CN 106942250 A CN106942250 A CN 106942250A
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CN
China
Prior art keywords
guaiacol
crucifers
leaf spot
composition
alternaria leaf
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710235353.3A
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Chinese (zh)
Inventor
黄朝纲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Golden Phoenix Agrochemical Co Ltd
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Jiangsu Golden Phoenix Agrochemical Co Ltd
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Publication date
Application filed by Jiangsu Golden Phoenix Agrochemical Co Ltd filed Critical Jiangsu Golden Phoenix Agrochemical Co Ltd
Priority to CN201710235353.3A priority Critical patent/CN106942250A/en
Publication of CN106942250A publication Critical patent/CN106942250A/en
Withdrawn legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A01N47/14Di-thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/16Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom

Abstract

The invention discloses a kind of composition and application process that alternaria leaf spot of crucifers is treated based on guaiacol, guaiacol is applied to agriculture field, composition is made by a certain percentage with Mancozeb, for treating alternaria leaf spot of crucifers, guaiacol new application is developed, alternaria leaf spot of crucifers can effectively be treated, the resistance against diseases of crop is improved, and it is compared with other existing agricultural chemicals single doses, and prevention effect is more preferable, production cost is relatively low, is worthy to be popularized.

Description

A kind of composition and application process that alternaria leaf spot of crucifers is treated based on guaiacol
Technical field
Preventing and treating the application of alternaria leaf spot of crucifers the present invention relates to pesticide field, more particularly to guaiacol mixture and applying Use method.
Background technology
Guaiacol is a kind of white or slightly yellow crystallization or colourless to pale yellow transparent oily liquids, there is special aroma Taste, scientific name guaiacol, glycerin ether, guaiacol glycerol ether, adjacent hydroxyl glycerin ether etc., guaiaci lignum is present in nature It is a kind of important fine-chemical intermediate in resin, pine tar and hardwood empyreumatic oil, is widely used in medicine, spices and dyestuff Synthesis, rarely have the document and technology for using it for other field in existing production and living.
The content of the invention
The present invention develops guaiacol in agriculture field, the application especially in terms of alternaria leaf spot of crucifers is prevented and treated, And there is provided its application process, blank of the guaiacol in the field purposes has been filled up, it is of the invention by guaiacol and Dai Sen Composition is made in MnZn, and phase composition includes guaiacol and Mancozeb, and the mass ratio of the guaiacol and Mancozeb is 1/10-10。
Preferably, the guaiacol and Mancozeb ratio are 1/3-3.
Preferably, wherein Determination of Guaiacol is 30%, Mancozeb content is 10%.
Preferably, also including the one or more in dispersant, sticker, bleeding agent, emulsifying agent, preservative, antifreezing agent.
Preferably, the Mancozeb and guaiacol mixture are processed into one in suspending agent, aqua, soluble liquid Kind.
Preferably, the suspending agent includes sodium alginate 0.1%-25%, anion surfactant;The anion table Face activating agent includes lignosulfonates 0.1%-25%.
Preferably, treating the application process of the composition of alternaria leaf spot of crucifers based on guaiacol;Comprise the following steps:
S1., the Mancozeb and guaiacol mixture are processed into one kind in suspending agent, aqua, soluble liquid;
S2. dispenser, takes the guaiacol decoction that step S1 is configured to carry out spray pesticide to brassicaceous vegetable.
Preferably, spray value is 200~500L/ hm in the step S22, atomisation pressure is 0.3~0.8kPa, dispenser Number of times is 1~2 time.
The guaiacol decoction mechanism of action:
(1)Suppress RNA reverse transcriptase RTASE activity, prevent virion from synthesizing;
(2)Absorption of the virion on cell is prevented, virus is reduced and contaminates probability;
(3) oxidation resistance in enhancing plant, reduces injury of the virus dip-dye to plant;
(4) resistance against diseases of plant is improved.
The present invention develops guaiacol in preventive and therapeutic effect of the agriculture field particularly with alternaria leaf spot of crucifers, can be made into Common pesticides formulation, it is mashed up in proportion with Mancozeb, prevention effect more more preferable than single dose is reached, while adding chitosan and its His auxiliary agent makes the increase of guaiacol decoction viscosity, can preferably be attached to crop surface, beneficial to drug absorption, meanwhile, chitosan Also there is certain auxiliary antibacterial, the effect of desinsection, and moderate cost, it is worthy to be popularized.
Embodiment
Embodiment one
Guaiacol and Mancozeb are made to the composition for the treatment of alternaria leaf spot of crucifers, its composition includes guaiacol and generation Gloomy MnZn, the mass ratio of the guaiacol and Mancozeb is 1/10-10.
More specifically, the guaiacol and Mancozeb mass ratio are 1/3-3.
More specifically, wherein Determination of Guaiacol is 30%, and Mancozeb content is 10%.
More specifically, also including one kind in dispersant, sticker, bleeding agent, emulsifying agent, preservative, antifreezing agent or It is a variety of.
More specifically, Mancozeb and the guaiacol mixture is processed into suspending agent, aqua, soluble liquid It is a kind of.
More specifically, the suspending agent includes sodium alginate 0.1%-25%, anion surfactant;It is described it is cloudy from Sub- surfactant includes lignosulfonates 0.1%-25%.
More specifically, the application process of the composition of alternaria leaf spot of crucifers is treated based on guaiacol;Including following Step:
S1., the Mancozeb and guaiacol mixture are processed into one kind in suspending agent, aqua, soluble liquid;
S2. dispenser, takes the guaiacol decoction that step S1 is configured to carry out spray pesticide to brassicaceous vegetable.
More specifically, spray value is 200~500L/ hm in the step S22, atomisation pressure is 0.3~0.8kPa, Spraying times are 1~2 time.
Embodiment two
Guaiacol, Mancozeb single dose are determined using Plating, and two kinds of single doses press 1: 10,1: 5,1: 3,1: 2,1: 1,2: 1st, antibacterial work of the 9 kinds of mixture samples of 3: 1,5: 1,10: 1 ratio composition to alternaria leaf spot of crucifers pathogenic bacteria mycelial growth Power, records and compares the bacteriostasis rate that each drug concentration suppresses alternaria leaf spot of crucifers pathogenic bacteria mycelial growth.
Result of the test shows that Mancozeb has preferable antibacterial work to the mycelial growth of alternaria leaf spot of crucifers pathogenic bacteria Property, and guaiacol is relatively low to the bacteriostatic activity of alternaria leaf spot of crucifers pathogenic bacteria.Mancozeb is caused to alternaria leaf spot of crucifers The bacteriostatic activity of germ is significantly higher than the bacteriostatic activity of guaiacol.
With probit analysis, calculate Mancozeb, guaiacol and its mixture and suppress alternaria leaf spot of crucifers pathogenic bacteria The toxicity regression formula of mycelial growth.Result of calculation shows that Mancozeb has to the mycelial growth of alternaria leaf spot of crucifers pathogenic bacteria Preferable inhibitory activity, guaiacol is substantially less than maneb to the inhibitory activity of alternaria leaf spot of crucifers pathogenic bacteria mycelial growth Zinc.
With the EC of each mixture50Value is calculated the co-toxicity coefficient of mixture by the abundant methods of Sun Yun, is as a result shown, when Mancozeb is with more creating When wooden phenol is with 1: 10 mixture, the CTC values of its mixture are less than 80, illustrate its mixture Mancozeb with guaiacol by 1: 10 mixture pair The bacteriostatic activity of alternaria leaf spot of crucifers pathogenic bacteria shows as antagonism;When Mancozeb and guaiacol are with 1: 5,1: 3,1: 2nd, 1: 1,2: 1,3: 1, during 5: 1 mixture, the CTC values of its mixture are all higher than 120, and are highest with 1: 3, illustrate Mancozeb with more The wooden phenol of wound shows as synergistic effect in these ratio mixtures to the bacteriostatic activity of alternaria leaf spot of crucifers pathogenic bacteria;Work as Mancozeb During with guaiacol with 10: 1 mixture, the CTC values of its mixture are more than 80 and less than 120, illustrate that Mancozeb is pressed with guaiacol 10: 1 ratio mixtures show as summation action to the bacteriostatic activity of alternaria leaf spot of crucifers pathogenic bacteria, therefore, configure guaiaci lignum Both compositions ratio of phenol Mancozeb treatment alternaria leaf spot of crucifers 1: 5,1: 3,1: 2,1: 1,2: 1,3: 1,5: 1 it Middle to choose, bactericidal activity is higher, wherein being optimum proportioning with 1: 3.
Preferred embodiments of the present invention are these are only, therefore the scope that the present invention is implemented can not be limited according to this, i.e., according to the present invention Equivalence changes and decoration that description is made, should all belong in the range of present invention covering.

Claims (8)

1. a kind of composition that alternaria leaf spot of crucifers is treated based on guaiacol, it is characterised in that:Including guaiacol and generation Gloomy MnZn, the mass ratio of the guaiacol and Mancozeb is 1/10-10.
2. the composition as claimed in claim 1 that alternaria leaf spot of crucifers is treated based on guaiacol, it is characterised in that:It is described Guaiacol and Mancozeb ratio are 1/3-3.
3. the composition as claimed in claim 2 that alternaria leaf spot of crucifers is treated based on guaiacol, it is characterised in that:Wherein Determination of Guaiacol is 30%, and Mancozeb content is 10%.
4. the composition as claimed in claim 3 that alternaria leaf spot of crucifers is treated based on guaiacol, it is characterised in that:Also wrap Include the one or more in dispersant, sticker, bleeding agent, emulsifying agent, preservative, antifreezing agent.
5. the composition as claimed in claim 4 that alternaria leaf spot of crucifers is treated based on guaiacol, it is characterised in that:It is described Mancozeb and guaiacol mixture are processed into one kind in suspending agent, aqua, soluble liquid.
6. the composition as claimed in claim 5 that alternaria leaf spot of crucifers is treated based on guaiacol, it is characterised in that:It is described Suspending agent includes sodium alginate 0.1%-25%, anion surfactant;The anion surfactant includes lignin Sulfonate 0.1%-25%.
7. a kind of application process of the composition as claimed in claim 6 that alternaria leaf spot of crucifers is treated based on guaiacol; Comprise the following steps:
S1., the Mancozeb and guaiacol mixture are processed into one kind in suspending agent, aqua, soluble liquid;
S2. dispenser, takes the guaiacol decoction that step S1 is configured to carry out spray pesticide to brassicaceous vegetable.
8. a kind of application process of the composition as claimed in claim 7 that alternaria leaf spot of crucifers is treated based on guaiacol; Atomisation pressure is 0.3~0.8kPa in the step S2, and spraying times are 1~2 time.
CN201710235353.3A 2017-04-12 2017-04-12 A kind of composition and application process that alternaria leaf spot of crucifers is treated based on guaiacol Withdrawn CN106942250A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0748217A (en) * 1993-08-04 1995-02-21 Matsukaade:Kk Antibacterial agent
CN103583560A (en) * 2012-08-13 2014-02-19 陕西美邦农药有限公司 Sterilization composition containing simeconazole and thiocarbamates
CN104521957A (en) * 2014-12-09 2015-04-22 安徽扬子化工有限公司 Applications of guaiacol in rice stripe disease

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0748217A (en) * 1993-08-04 1995-02-21 Matsukaade:Kk Antibacterial agent
CN103583560A (en) * 2012-08-13 2014-02-19 陕西美邦农药有限公司 Sterilization composition containing simeconazole and thiocarbamates
CN104521957A (en) * 2014-12-09 2015-04-22 安徽扬子化工有限公司 Applications of guaiacol in rice stripe disease

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Application publication date: 20170714

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