CN106942232A - Fungicidal composition containing cyflufenamid - Google Patents
Fungicidal composition containing cyflufenamid Download PDFInfo
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- CN106942232A CN106942232A CN201710247503.2A CN201710247503A CN106942232A CN 106942232 A CN106942232 A CN 106942232A CN 201710247503 A CN201710247503 A CN 201710247503A CN 106942232 A CN106942232 A CN 106942232A
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- Prior art keywords
- fungicidal composition
- cyflufenamid
- composition
- agent
- active components
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/52—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing groups, e.g. carboxylic acid amidines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
Abstract
The invention provides a kind of Synergistic fungicidal composition containing cyflufenamid, it is characterized in that including active components A and B, wherein, A is cyflufenamid, B is one or more kinds of combinations in fludioxonil, nuarimol, also include the auxiliary agent that can be used in Pesticide formulation, conventional pesticidal preparations are made, and applied to preventing and treating fungal diseases of plants.
Description
Technical field
The invention belongs to pesticides application technical field, it is related to a kind of composition pesticide, specifically a kind of bacterium of fluorine containing ring
The Fungicidal composition of amine, applied to preventing and treating fungal diseases of plants.
Background technology
In agricultural production process, fungal diseases of plants (sac fungus, basidiomycetes, Fungi Imperfecti, oomycetes cause disease) occurs
Seriously, the organ of multiplication positions such as the nutrition organs such as axis, leaf, and fruit, seed, stem tuber are endangered, Plant Light cooperation is influenceed
With influence Leaf-feeding insects outward appearance makes crop yield fall sharply, quality decline is serious.When disease occurs serious, crop is caused to be had no harvest.
Therefore, fungal diseases of plants has important meaning of preventing and treating in produce reality, and bactericide is to prevent and treat fungal diseases of plants most
For economic, quick and effective method.
Single bactericide is limited using easily developing immunity to drugs or preventing and treating spectrum, can not solve well in produce reality
Fungal diseases of plants endangers.Mixture bactericide, which has, can expand preventing and treating spectrum, enhancing preventive effect, delay the phytopathogen resistance to the action of a drug etc. excellent
Gesture, turns into most popular application form in production practices.Especially there is the bactericide of synergy, bactericide is each effectively
Component interphase interaction, makes combination aging fruit to be played better than the theoretical summation that effect is used alone, thus when actually used
The effect got twice the result with half the effort, is more favored by user.
Cyflufenamid (cyflufenamid) is Tso Tat Co., Ltd., Japan's exploitation, with the existing bactericide mechanism of action not
A kind of same bactericide.With prevention, therapeutic action, and there is good infiltration conduction and fumigation action, but interior inhale passes
Lead activity poor.Haustorium formation can be prevented and developed, and then influence mycelium growth and sporulation.It is mainly used in preventing and treating wheat, fruit tree
With the powdery mildew and peach brown rot on vegetables.CAS accession number is 180409-60-3.Its structural formula is as follows：
Fludioxonil (fludioxonil), nuarimol (nuarimol) are the bactericide of two kinds of broad spectrum activities, are made to a variety of
Fungal diseases of plants on thing shows excellent preventive effect.
The present invention is studied by substantial amounts of formulation screening test and found, when in cyflufenamid and fludioxonil, nuarimol
One or more kinds of medicaments any combination when, show surprising bactericidal effect, that is, show good collaboration and make
With actual bactericidal effect is substantially better than the theoretical summation of exclusive use, has application prospect widely in production.
The content of the invention
The present invention relates to Synergistic fungicidal composition, including active components A and B, described active components A is cyflufenamid
(cyflufenamid), described active component B is one or more kinds of combinations in fludioxonil, nuarimol.In addition,
Also include the auxiliary agent that can be used in Pesticide formulation.
The composition especially good effect can be used to prevent and treat the fungal diseases of plants in various useful crops, described
Useful crop includes but is not limited to conventional breeding crop, genetically modified crops, asexually propagated crop and asexual propagation material, domestication and planted
Wild plant of training etc., is particularly suitable for use in preventing and treating wheat, cucumber, watermelon, muskmelon, capsicum, eggplant, strawberry, tomato, Chinese cabbage, apple
Really, the crop disease such as peach, cherry, grape, Lee, tobacco, rose, soybean, rape.
The instantiation that can be mentioned that can use the representative fungal diseases of plants of composition for preventing and controlling of the invention for some, described
Example is not limited to specified genus kind.It should be noted that the invention is not limited in example in detail below, can also be with phase Tongfang
Formula extends to other fungal diseases of plants, and bracket indicates its cause of disease Latin name：
Wheat powdery mildew (Blumeria graminis), cucumber and melon powdery mildew (Sphaerotheca
Fuliginea), watermelon powdery mildew (Sphaerotheca cucurbitae), powdery mildew of strawberry (Podosphaera
Aphanis), pepper powdery mildew (Leveillula taurica), eggplant powdery mildew (Oidium neolycopersici), apple
Fruit powdery mildew (Podosphaera leucotricha), cherry powdery mildew (Podosphaera clandestina), grape are white
Powder disease (Uncinula necate), Powdery Mildew in Tobacco (Erysiphe cichoracearum), rose and Japanese plum powdery mildew
(Sphaerotheca pannosa), peach brown rot (Monilinia fructicola), sweet cherry brown rot (Monilinia
Laxa), apple peels and cores (Alternaria mali), cucurbitaceae vegetable rod method leaf spot (Alternaria
Cucumerina), early blight of tomato (Alternaria alternata), Cabbage Leaf Spot (Alternaria
Brassicae), vegetables and grey mould of fruit trees (Botrytis cinerea), rape and soybean sclerotinia crown rot (Sclerotinia
Sclerotiorum), fusarium disease (Fusarium spp.)：Such as wheat scab (Fusarium graminearum), greatly
Beans root rot (Fusarium oxysporum) etc., rhizoctonia disease (Rhizoctonia spp.)：Such as wheat sharp eyespot
(Rhizoctonia cerealis) etc..
In order to solve the above-mentioned technical problem, the present invention, which is adopted the following technical scheme that, is achieved：
The present composition component A and B can be with arbitrary proportion mixtures, and a kind of usual active component content is higher than rest activity
Composition, preferably mixing ratio are 100：1 to 1：100 or 50：1 to 1：50.
The present composition can be by the way that active component be mixed with the auxiliary agent that can be used in Pesticide formulation, with known
Method is prepared as conventional preparation, such as missible oil, wettable powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, granule
Deng.The active component of the active component of 0.1~95% weight, preferably 0.5~90% weight is typically contained in preparation.
The auxiliary agent that can be used in Pesticide formulation includes but is not limited to：Water, solvent, filler, various surfactants
(emulsifying agent, dispersant, wetting agent etc.), adhesive, film forming agent, colouring agent, antifreezing agent, thickener, suspending agent, disintegrant, disappear
Infusion, bleeding agent, synergist, stabilizer, wall capsule material, pH adjusting agent, preservative etc..Also, suitably, in order to improve to spy
Ordered goods tolerance, can be properly added safener；Or sometimes for crop growth is promoted, can add in mixture composition
Plus conventional agriculture fertilizer, medicament-fertilizer mixture is made.These auxiliary agents are all the compositions commonly used in pesticidal preparations or allow to use, and have no spy
Do not limit, one or more auxiliary agent may be selected and constitutes, specific composition and consumption are according to recipe requirements by simply testing
It is determined that.It should be strongly noted that being showed according to the physicochemical property of this composition and preventive effect, it is not necessary to utilize rilanit special etc.
Vegetable oil is processed into oil-based suspension.
The production technology of the various application forms of composition belongs to existing known technology, will not be repeated here.
The present composition can be used in a variety of ways, be such as watered spraying in a usual manner and used, or directly spread fertilizer over the fields or ditch
Apply, or mix pesticide-clay mixture and spread fertilizer over the fields, when plant seeding, emerge before, emerge after vegetative growth phase and reproductive stage can be used.With
Dose can change in relative broad range, and depending on the situation of soil, application method, crop, plant mycosis to be prevented and treated
Evil species and seedling age size, weather conditions at that time and other factors.The present composition is generally with 0.001~0.5kg activity
The consumption of constituents mixt/hectare is applied, it is further preferable that being applied with the consumption of 0.01~0.2kg mixture of active principles/hectare
With.
The present invention compared with prior art, has the following technical effect that：
1st, mixture composition has good synergy, and application effect is substantially better than single dose theoretical effect summation, that is, had
There is super superposition, fungal diseases of plants occurrence injury can be better controled over；
2nd, there is good complementarity in fungal diseases of plants preventing and treating spectrum between mixture composition active component, can be fine
Expand preventing and treating spectrum, it is comprehensive effectively to control various fungal diseases of plants occurrence injuries；
3rd, mixture composition has good synergy, can reduce medicament usage amount, and reduction use cost and environment are dirty
Dye, improves the security to crop.
Embodiment
Specific embodiment of the invention given below is, it is necessary to which explanation is that the invention is not limited in implement in detail below
Example, all equivalents done on the basis of technical scheme each fall within protection scope of the present invention.
Embodiment 1：20% missible oil
Being formulated composition is：Active components A is 8%, and active component B is 12%, emulsifying agent aerosol-OT salt
4%, emulsifying agent styrylphenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether 5%, solvent xylene complements to 100%.
Preparation method is：All materials are put into batching kettle, stirring and dissolving after chemical examination is qualified, is shifted to fully transparent
It is filling to storage tank.
Embodiment 2：16% suspending agent
Being formulated composition is：Active components A is 6%, and active component B is 10%, wetting agent APES formaldehyde
Condensate sulfate 4%, dispersant calcium lignosulfonate 3%, antifreezing agent propane diols 4%, thickener xanthans 0.2%, water is mended
Enough to 100%.
Preparation method is：By in active component and wetting agent, dispersant, antifreezing agent and water input stirred tank, it is sufficiently stirred for
Afterwards, material is pumped into sand mill and be fully ground, after the completion of grinding, be pumped into high-speed shearing machine, add after thickener, enter
Row high speed shear, is made suspending agent after the completion of shearing.
Embodiment 3：48% water dispersible granules
Being formulated composition is：Active components A is 16%, and active component B is 32%, wetting agent calcium dodecyl benzene sulfonate 5%,
Dispersant EO-PO block polyethers 6%, disintegrant ammonium sulfate 3%, adhesive polyethylene glycol 0.4%, filler diatomite is complemented to
100%.
Preparation method is：After all materials are well mixed, crush, be well mixed again through airslide disintegrating mill, then, plus
Enter a certain amount of water to mediate this mixture, extruder grain, through drying screening, that is, obtain water dispersible granules.
Embodiment 4：22% aqueous emulsion
Being formulated composition is：Active components A is 6%, and active component B is 16%, solvent xylene 10%, emulsifying agent fatty alcohol
APEO 6%, emulsifying agent APES formaldehyde condensation product 3%, antifreezing agent glycerine 5%, water is complemented to
100%.
Preparation method is：After active components A and B solvents are fully dissolved, input emulsifying agent forms oil after being sufficiently stirred for
Phase；Antifreezing agent is added to the water dissolving, aqueous phase is formed；Aqueous phase is slowly added in oil phase, sheared using high-speed shearing machine, you can
Obtain aqueous emulsion.
Embodiment 5：28% microemulsion
Being formulated composition is：Active components A is 8%, and active component B is 20%, solvent xylene 7%, cyclohexanone 4%, breast
Agent styrylphenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether 8%, emulsifying agent disecoctylmaleate sodium sulfonate
7%, antifreeze glycol 4%, water complements to 100%.
Preparation method is：After active components A and B solvents are fully dissolved, input emulsifying agent and antifreezing agent are well mixed,
Deionized water is eventually adding, high speed shear is carried out, you can microemulsion is obtained.
Embodiment 6：52% wettable powder
Being formulated composition is：Active components A is 18%, and active component B is 34%, wetting agent APES formaldehyde
Condensate sulfate 6%, dispersant sodium lignin sulfonate 5%, filler diatomite complements to 100%.
Preparation method is：Active component and each auxiliary agent are well mixed, carry out just smashing in the mechanical disintegrating machine of input, afterwards
Crushed through airslide disintegrating mill, remix uniform, i.e., obtained wettable powder.
Embodiment 7：6% granule
Being formulated composition is：Active components A is 2%, and active component B is 4%, wetting agent dialkyl succinylsuccinate ester sodium sulfonate
0.7%, the phenethyl phenol polyoxyethylene ether phosphate 0.9% of dispersant three, colouring agent carbon black 0.3%, filler bentonite is complemented to
100%.
Preparation method is：After all materials are well mixed, add a certain amount of water and mediate this mixture, extruding is made
Grain, through drying screening, that is, obtains granule.
Application effect example：
1st, test method
(1) to the bioactivity of cucumber powdery mildew's pathogen
Reference《The part of NYT 1156.11-2008 farm-chemical indoor determination test rules bactericide the 11st：Preventing and treating is melon
Powdery mildew experiment basin cuts out method》Carry out.
It is, for examination germ, to be adopted from the sick leaf of field cucumber with cucumber powdery mildew's pathogen (Sphaerotheca fuliginea)
Collection, indoor inoculation expands numerous standby on fresh cucumber seedling.
It is that laboratory is potted plant, seedling length to 2~4 leaf periods for studying thing with cucumber susceptible variety " the close thorn in Xintai City "
It is standby.
The decoction prepared is uniformly sprayed in " the close thorn in Xintai City " blade face to whole wettings.Pathogen is inoculated with after dispenser 24h.
Choose and expand numerous use incidence of leaf, with the pure water added with a small amount of 0.1% Tween-80, Fresh spores, eluent are eluted from sick leaf
Filtered with double gauze, it is 1 × 10 that concentration, which is made,5Individual spore/mL spore suspension, by its spray inoculation in the Huang of dispenser
On melon blade.Then cultivated under the conditions of 20 DEG C, 12h alternation of light and darkness.Often processing sets 4 repetitions, often repeatedly 5 basin, per basin 2
Strain, and set the processing without medicament and make blank control.When the sick leaf rate of blank control reaches more than 80%, each processing of classification investigation
Incidence.Calculate the disease index and prevention effect of each processing.
Disease index is calculated by formula (1), and prevention effect is calculated by formula (2), and result of calculation retains 2 significant digits.
In formula：
X-disease index；
Ni- sick the number of sheets at different levels；
I-relative value of series；
N-investigation total number of sheets；
11-highest value of series.
In formula：
P-prevention effect, unit is percentage (%)；
CK-blank control disease index；
PT-chemicals treatment disease index.
(2) to the bioactivity of wheat powdery mildew
Reference《The part of NYT 1156.4-2006 farm-chemical indoor determination test rules bactericide the 4th：Prevent and treat white wheat
Powder disease experiment pot-culture method》Carry out.
It is that laboratory is seeded on fresh wheat seedling for examination germ with wheat powdery mildew (Blumeria graminis)
Expand numerous standby.
With wheat susceptible variety " Zheng wheat 9023 " is that for studying thing, 20 seeds are broadcast per basin, and wherein 10 plants are selected after emerging,
Length is standby to 2 leaves~3 leaf phases.
The decoction prepared is uniformly sprayed in " the blade face of Zheng wheat 9023 " to whole wettings.24h is inoculated with pathogen after dispenser.
Choose and expand numerous use incidence of leaf, the wheat powdery mildew Fresh spores produced in 24h were uniformly shaken off to the leaf phase of 2 leaves~3 and applied
On the wheat seedling of medicine.Then 18 DEG C, humidity be 70%, light application time be 16h, interlunation be constant incubator under the conditions of 8h
Interior culture.Often processing sets 4 repetitions, often repeatedly 3 basin, and sets the processing without medicament and make blank control.When blank control hair
When sick rate reaches more than 80%, incidence is managed in classification investigation everywhere.Calculate the disease index and prevention effect of each processing.
Disease index is calculated by formula (3), and prevention effect is calculated by formula (2), and result of calculation retains 2 significant digits.
In formula：
X-disease index；
Ni- sick the number of sheets at different levels；
I-relative value of series；
N-investigation total number of sheets；
9-highest value of series.
(3) to Monilinia fructicola and the bioactivity of pathogen of soybean root rot
Reference《NYT 1156.2-2006 farm-chemical indoor determination test rule bactericide part 2s：Suppress cause of disease true
Bacterium mycelial growth tests Plating》Carry out.
With Monilinia fructicola (Monilinia fructicola) or pathogen of soybean root rot (Fusarium oxysporum)
For for examination pathogen.
Monilinia fructicola gathers disease fruit from field, and pathogen of soybean root rot gathers old complaint from field, and laboratory isolates and purifies, connect
Plant and cultivated in PDA culture medium, culture to colony diameter is standby up to 6cm or so.
It is standby after the sterilizings such as PDA culture medium, deionized water, line triangular flask, culture dish, pipette tips, card punch, inoculator.
Under aseptic technique, the sterilizing PDA culture medium for advance thawing being cooled into about 50 DEG C is quantitatively adding sterilizing and drawn
In wire triangle bottle, make culture medium concordant with (60mL) at line, then draw 600 μ L decoctions successively from low concentration to high concentration,
It is separately added into above-mentioned triangular flask, fully shakes up, rear equivalent is poured into 4 culture dishes (Φ 9cm), and 5 concentration gradient bands are made
Medicine flat board.And set the processing without medicament and make blank control.Will in PDA culture medium cultured pathogen, in aseptic condition
It is lower to cut bacteria cake from the same circumference of colony edge with sterilization punchers (Φ 5mm), pure culture biscuits involvng inoculation is put down in pastille with inoculator
Plate center, mycelia down, covers ware lid, the dark culturing in 25 DEG C of incubators.According to mycelial growth feelings in blank control ware
Condition, uses kind of calliper colony diameter.Each bacterium colony uses crossing method vertical survey, takes its average value, calculates and mycelia is given birth to
Long inhibiting rate.
Inhibiting rate of each concentration for the treatment of to mycelial growth is calculated by formula (4), (5), unit is percentage (%), calculates knot
Fruit retains 2 significant digits.
D=D1-D2…………………………………………(4)
In formula：
D-bacterium colony increases diameter, and unit is millimeter (mm)；
D1- colony diameter, unit is millimeter (mm)；
D2- bacteria cake diameter, unit is millimeter (mm).
In formula：
I-mycelial growth inhibition rate, unit is percentage (%)；
D0- blank control bacterium colony increases diameter, and unit is millimeter (mm)；
Dt- chemicals treatment bacterium colony increases diameter, and unit is millimeter (mm).
(4) compositions contemplated activity judges
Judge bactericide in the transnational agricultural chemicals enterprise formulation patents such as compositions contemplated activity reference Bayer, elder generation just reach, Tao Shi
The method (COLBY methods) of compositions contemplated activity：COLBY, S.R.：“Calculating Synergistic and
Antagonistic Responses of Herbicide Combinations ", Weeds 15, p.20~22,1967 are carried out.
Compositions contemplated activity is calculated by (6) formula：
In formula：
Preventive effect or inhibiting rate when the consumption of X-bactericide 1 is P；
Preventive effect or inhibiting rate when the consumption of Y-bactericide 2 is Q；
Actual preventive effect or inhibiting rate after E-bactericide 1 is mixed according to the above ratio with bactericide 2, i.e. mixture bactericide
Substantial activity；
E0The consumption of-bactericide 1 is the theoretical preventive effect or inhibiting rate, i.e. mixture bactericide when the consumption of P+ bactericide 2 is Q
Expection activity.
As E ＞ E0When, if that is, the substantial activity of Mixed Pharmacy exceedes calculated expection activity, the combination just has
Super superposition, that is, act synergistically.
2nd, result of the test
Result of the test refers to table 1~4, it is seen then that active components A (cyflufenamid) is with being selected from active component B (fluorobenzene pyrimidines
Alcohol, fludioxonil) medicament mixture after, substantial activity is all higher than expection activity, illustrates the medicament in cyflufenamid and active component B
Mixture has synergy.
The cyflufenamid of table 1 and synergy effect of the nuarimol mixture to cucumber powdery mildew's pathogen
The cyflufenamid of table 2 and synergy effect of the nuarimol mixture to wheat powdery mildew
The cyflufenamid of table 3 and synergy effect of the fludioxonil mixture to Monilinia fructicola
The cyflufenamid of table 4 and synergy effect of the fludioxonil mixture to pathogen of soybean root rot
Claims (6)
1. Fungicidal composition, it is characterised in that including active components A and B.
2. Fungicidal composition as claimed in claim 1, it is characterised in that described active components A is cyflufenamid.
3. Fungicidal composition as claimed in claim 1, it is characterised in that described active component B is fludioxonil, fluorobenzene is phonetic
One or more kinds of combinations in pyridine alcohol.
4. the Fungicidal composition as described in claim 1,2 or 3, it is characterised in that in addition to active components A and B, also include
The auxiliary agent that can be used in Pesticide formulation, is made conventional pesticidal preparations.
5. Fungicidal composition as claimed in claim 4, is not processed into oil-based suspension.
6. the Fungicidal composition as described in claim 1,2,3,4 or 5, it is characterised in that be applied to preventing and treating plant true
Fungus diseases.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710247503.2A CN106942232A (en) | 2017-04-17 | 2017-04-17 | Fungicidal composition containing cyflufenamid |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710247503.2A CN106942232A (en) | 2017-04-17 | 2017-04-17 | Fungicidal composition containing cyflufenamid |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004091298A1 (en) * | 2003-04-16 | 2004-10-28 | Basf Aktiengesellschaft | Fungicidal mixtures |
| CN102308808A (en) * | 2011-10-10 | 2012-01-11 | 海利尔药业集团股份有限公司 | Antibacterial composition containing cyflufenamid and triazole bactericides |
| CN104430358A (en) * | 2013-09-17 | 2015-03-25 | 南京农业大学 | composition containing fludioxonil and kresoxim-methyl |
-
2017
- 2017-04-17 CN CN201710247503.2A patent/CN106942232A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004091298A1 (en) * | 2003-04-16 | 2004-10-28 | Basf Aktiengesellschaft | Fungicidal mixtures |
| CN102308808A (en) * | 2011-10-10 | 2012-01-11 | 海利尔药业集团股份有限公司 | Antibacterial composition containing cyflufenamid and triazole bactericides |
| CN104430358A (en) * | 2013-09-17 | 2015-03-25 | 南京农业大学 | composition containing fludioxonil and kresoxim-methyl |
Non-Patent Citations (1)
| Title |
|---|
| 程志明: "杀菌剂环氟菌胺的开发", 《世界农药》 * |
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Application publication date: 20170714 |
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