CN106933402B - Yellow light manufacturing process of touch screen and protective alkali-removing ink used in manufacturing process - Google Patents

Yellow light manufacturing process of touch screen and protective alkali-removing ink used in manufacturing process Download PDF

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CN106933402B
CN106933402B CN201511033670.4A CN201511033670A CN106933402B CN 106933402 B CN106933402 B CN 106933402B CN 201511033670 A CN201511033670 A CN 201511033670A CN 106933402 B CN106933402 B CN 106933402B
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touch screen
ink
yellow light
alkali
black
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CN106933402A (en
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夏运海
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DONGGUAN ANSTEED ELECTRONIC CO LTD
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DONGGUAN ANSTEED ELECTRONIC CO LTD
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    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • G06F3/0412Digitisers structurally integrated in a display
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207Heat-activated adhesive
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/103Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/104Polyesters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B2037/1269Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives multi-component adhesive
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F2203/00Indexing scheme relating to G06F3/00 - G06F3/048
    • G06F2203/041Indexing scheme relating to G06F3/041 - G06F3/045
    • G06F2203/04103Manufacturing, i.e. details related to manufacturing processes specially suited for touch sensitive devices

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Human Computer Interaction (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Materials For Photolithography (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Optical Filters (AREA)

Abstract

The invention discloses a yellow light manufacturing process of a touch screen and protective alkali-removing ink used in the manufacturing process. The yellow light process of the touch screen sequentially comprises the following steps: the method comprises the steps of gluing, exposing, developing, drying, etching, stripping and detecting, wherein before the gluing process, black protective alkali-stripping ink is printed on the surface of the touch screen which is subjected to pretreatment. The technical scheme adopted by the invention is that black protective alkali de-inking is additionally printed before gluing to replace the previous protective film, and the glass sheet can be protected from being corroded by light resistance ink or UV light after being treated in the previous stage by adopting the mode. The light shielding effect is achieved during exposure, the developing solution is buffered during development, the bottom glass can be protected, and finally the glass is removed before detection, so that the detection result cannot be influenced.

Description

Yellow light manufacturing process of touch screen and protective alkali-removing ink used in manufacturing process
The technical field is as follows:
the invention relates to the technical field of a yellow light processing process of a touch screen, in particular to a yellow light processing process of the touch screen and protective alkali-removing ink used in the processing process.
Background art:
the yellow light process is currently the most popular manufacturing process in the TP (touch panel) industry, and has been commonly used in the production process of touch panel manufacturers. The principle of the yellow light process is a photolithography technique, in which a main pattern on a photomask is first transferred onto a photosensitive material, light is irradiated onto the photosensitive material through the photomask, and then the irradiated portion of the photosensitive material is dissolved or retained by soaking in a solvent, so that the formed photoresist pattern is completely the same as or complementary to the photomask. Since the photolithography process is performed in a yellow light environment rather than the red light of a conventional darkroom, this part of the process is often referred to as "yellow light".
The current yellow light process mainly comprises the following steps: gluing, exposing, developing, drying, etching, stripping and detecting. In the yellow process, it is usually necessary to protect the bottom glass, including the pre-treated ITO, PI, etc., from the direct UV light during exposure, to block light, and to avoid the erosion of the photoresist ink. The conventional protection method is to apply a protective film for protection, and then to tear off the protective film together in the later film stripping process. However, the protection mode mostly adopts manual operation, and along with the increase of the size of the touch screen at present, the degree of automation operation is continuously improved, the protection measure of attaching the protection film cannot adapt to the existing production requirement, and meanwhile, for the large-size touch screen glass, the cost of the product can be greatly increased by the attaching film for protection. Therefore, the present inventors have made extensive research and development to solve the above problems and propose the following improved technical solutions.
The invention content is as follows:
the invention aims to overcome the defects of the prior art and provides a yellow light process of a touch screen and protective alkali-removing ink used in the process.
In order to solve the technical problems, the invention adopts the following technical scheme: the yellow light process of the touch screen sequentially comprises the following steps: the method comprises the steps of gluing, exposing, developing, drying, etching, stripping and detecting, wherein before the gluing process, black protective alkali-stripping ink is printed on the surface of the touch screen which is subjected to pretreatment.
Further, in the above technical scheme, the protected alkali ink comprises 20-40% of anhydride copolymer resin, 1-10% of black pigment, 20-30% of polyester resin, 1-5% of curing agent, 0.1-0.3% of defoaming agent, 0.5-2.0% of flatting agent, 0.7-3.0% of coupling agent and 10-30% of solvent.
Further, in the above technical scheme, before the glue coating process, black protective alkali de-inking is firstly silk-screened on the surface of the touch screen through a 280-mesh polyester net, and then curing is completed after 15-20 minutes at the temperature of 150-.
Further, in the above technical solution, the thickness of the black protective alkali-removed ink screen is 25 to 35 μm.
Further, in the above technical solution, the black protective alkali-removed ink is removed by a developing solution in a developing process.
In addition, in the alkali-protecting and degreasing ink used in the yellow light process of the touch screen, any one of the following acid anhydride copolymer resins is used: copolymer resin of maleic anhydride and epoxy acrylic acid, and phenolic aldehyde epoxy acrylic acid copolymer resin.
Furthermore, the black pigment is used in the alkali-protecting de-inking ink in the yellow light process of the touch screen, and any one of the following pigments is adopted: copper chromium black, glass black, carbon black.
Furthermore, the alkali-protecting and oil-removing ink is used in a yellow light process of a touch screen, and the curing agent adopts an isocyanate curing agent.
Furthermore, the solvent is used in the protective alkali-removed ink in the yellow light process of the touch screen, and any one of the following solvents is adopted: DBE solvent and isophorone solvent.
The technical scheme adopted by the invention is that black protective alkali de-inking is additionally printed before gluing to replace the previous protective film, and the treatment of the glass sheet, such as ITO, PI and the like, in the previous stage can be protected from being corroded by light resistance ink or UV light. During exposure, the alkali-stripping ink is protected to be black, so that substances on the bottom layer can be protected from being corroded by strong light, a shading effect is achieved, a buffer effect is achieved for a developing solution during development, bottom glass can be protected, and finally the alkali-stripping ink is stripped before detection, so that a detection result cannot be influenced.
In addition, the protective alkali-removing ink can be attached to the surface of the glass plate by adopting a silk-screen printing method, so that the protective alkali-removing ink can directly and fully utilize the existing machine, is suitable for various types of glass, and can reduce the cost and improve the efficiency.
Finally, the alkali deprotection printing ink can be removed along with the photoresist printing ink, so that the steps of sticking and tearing the film are reduced, and the production efficiency can be further improved.
The specific implementation mode is as follows:
the present invention is further illustrated by the following specific examples.
The existing yellow light manufacturing process of the touch screen sequentially comprises the following steps: gluing, exposing, developing, drying, etching, stripping and detecting. Before this, it is necessary to perform ITO (conductive glass) processing on the glass sheet, and to use a sputtered ITO film layer. Then, a yellow light process is performed. The glue coating is a coating photoresist which is a photosensitive chemical material. Then, the property of the photosensitive material in the photoresist is changed through exposure, and the exposed pattern is processed through a developing device so as to clearly show the pattern. And then drying, etching, stripping and finally detecting to finish the ITO yellow light graph processing. The invention adds a process before gluing. Specifically, before the gluing process, black protective alkali-stripping ink is printed on the surface of the touch screen which is subjected to the pretreatment.
Before the gluing process, black protective alkali de-inking is firstly silk-screened on the surface of the touch screen through a 280-mesh polyester net, and then curing is completed after 15-20 minutes in the environment of 150-. After curing, the thickness of the black protective alkali ink-removing screen printing is 25-35 microns.
And finally, removing the black protective alkali-removed ink by using a developing solution in a developing process.
The protected alkali ink of the present invention is composed of,
Figure BDA0000898350720000041
in the above-mentioned components, the described acid anhydride copolymerized resin is various acid anhydrides, for example, copolymerized resin of maleic anhydride and epoxy acrylic acid, phenol aldehyde epoxy acrylic acid copolymer, etc.
The black pigment can be prepared from the following components: copper chromium black, glass black, carbon black, and the like.
The polyester resin is soft resin with low Tg point, such as OLESTERQ212 of Mitsui Japan, and Uralac SN833 and SN820 of DSM Dismann saturated polyester resin. Korea sk saturated polyester resin SKYBON ES-300, etc.
The curing agent is generally an isocyanate curing agent, such as Tridak D-204T-3, D-208T, and the like.
The defoaming agent is BYK-051, 053 polymer defoaming agent and the like.
The leveling agent is BYK-110, 111 and the like.
The coupling agent is, for example, a silane coupling agent KH550, KH560 or the like.
The solvent is high boiling point solvent such as DBE solvent, isophorone solvent, etc.
The composition of the protected alkali ink in example 1 was as follows, 40% of a copolymer resin of maleic anhydride and epoxy acrylic acid, 8% of carbon black, OLESTER Q212 from Mitsui Japan: 25 percent, 3 percent of curing agent, 0.3 percent of defoaming agent, 1 percent of flatting agent, 2 percent of coupling agent and the balance of solvent.
It should be understood that the above description is only exemplary of the present invention, and is not intended to limit the scope of the present invention, which is defined by the appended claims.

Claims (8)

1. A yellow light manufacturing process of a touch screen sequentially comprises the following steps: gluing, exposing, developing, drying, etching, stripping and detecting, and is characterized in that: before the gluing process, firstly, screen-printing black protective alkali de-inking ink on the surface of the touch screen which is subjected to the pretreatment; the black protective alkali de-inking ink is removed by a developing solution in a developing process;
the composition of the protective alkali-removing ink is as follows,
Figure FDA0002223018990000011
2. the yellow light process of claim 1, wherein: before the gluing process, black protective alkali de-inking is firstly silk-screened on the surface of the touch screen through a 280-mesh polyester net, and then curing is completed after 15-20 minutes in the environment of 150-.
3. The yellow light process of claim 2, wherein: the thickness of the black protective alkali-removed ink screen printing is 25-35 microns.
4. A protective alkali-removing ink for a yellow light process of a touch screen is characterized in that: the composition of the protective alkali-removing ink is as follows,
Figure FDA0002223018990000012
Figure FDA0002223018990000021
the protective alkali-stripping ink is black and is stripped by a developing solution in a developing process.
5. The protective alkali-release ink for use in a yellow light process of a touch screen of claim 4, wherein: the anhydride copolymer resin adopts any one of the following components: copolymer resin of maleic anhydride and epoxy acrylic acid, and phenolic aldehyde epoxy acrylic acid copolymer resin.
6. The protective alkali-release ink for use in a yellow light process of a touch screen of claim 4, wherein: the black pigment adopts any one of the following components: copper chromium black, glass black, carbon black.
7. The protective alkali-release ink for use in a yellow light process of a touch screen of claim 4, wherein: the curing agent adopts an isocyanate curing agent.
8. The protective alkali-release ink for use in a yellow light process of a touch screen of claim 4, wherein: the solvent adopts any one of the following solvents: DBE solvent and isophorone solvent.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102532483A (en) * 2010-11-30 2012-07-04 东洋油墨Sc控股株式会社 Thermosetting resin compound containing carboxyl modified polyurethane resin
CN102854744A (en) * 2011-06-29 2013-01-02 东洋油墨Sc控股株式会社 Photosensitive resin composition, cured product thereof, and method for producing photosensitive resin
CN103425372A (en) * 2013-07-25 2013-12-04 浙江金指科技有限公司 Metal etching process of capacitive touch screens
CN104035622A (en) * 2014-06-25 2014-09-10 深圳市点燃科技有限公司 Manufacturing method for touchscreen sensor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102532483A (en) * 2010-11-30 2012-07-04 东洋油墨Sc控股株式会社 Thermosetting resin compound containing carboxyl modified polyurethane resin
CN102854744A (en) * 2011-06-29 2013-01-02 东洋油墨Sc控股株式会社 Photosensitive resin composition, cured product thereof, and method for producing photosensitive resin
CN103425372A (en) * 2013-07-25 2013-12-04 浙江金指科技有限公司 Metal etching process of capacitive touch screens
CN104035622A (en) * 2014-06-25 2014-09-10 深圳市点燃科技有限公司 Manufacturing method for touchscreen sensor

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