CN106930110A - A kind of method for improving polypyrrole wool conductive fabric electric conductivity - Google Patents
A kind of method for improving polypyrrole wool conductive fabric electric conductivity Download PDFInfo
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- CN106930110A CN106930110A CN201710201684.5A CN201710201684A CN106930110A CN 106930110 A CN106930110 A CN 106930110A CN 201710201684 A CN201710201684 A CN 201710201684A CN 106930110 A CN106930110 A CN 106930110A
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- wool
- polypyrrole
- conductive fabric
- electric conductivity
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- 239000004744 fabric Substances 0.000 title claims abstract description 60
- 210000002268 wool Anatomy 0.000 title claims abstract description 60
- 229920000128 polypyrrole Polymers 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 23
- 239000000243 solution Substances 0.000 claims abstract description 59
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 49
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 33
- 239000011651 chromium Substances 0.000 claims abstract description 33
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims abstract description 28
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 28
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 239000007864 aqueous solution Substances 0.000 claims abstract description 6
- 230000035484 reaction time Effects 0.000 claims description 13
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 description 21
- 238000001514 detection method Methods 0.000 description 8
- 238000001035 drying Methods 0.000 description 5
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920001940 conductive polymer Polymers 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 206010011224 Cough Diseases 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000003980 solgel method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000010041 electrostatic spinning Methods 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000005424 photoluminescence Methods 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- -1 polyparaphenylene Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0605—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0611—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only one nitrogen atom in the ring, e.g. polypyrroles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of method for improving polypyrrole wool conductive fabric electric conductivity, wool cloth is immersed in pure liquefied ammonia process 20 60 seconds first, dried after taking-up；To be immersed in the chromium solution of 0.02 0.1mol/L through the wool cloth of Liquid Ammonia Treatment；The ferric chloride in aqueous solution of 0.02 0.2mol/L is added dropwise to while stirring, is reacted 16 hours；Rinse well and be vacuum dried at room temperature.Electric conductivity the beneficial effects of the invention are as follows the polypyrrole wool conductive fabric of the wool after treatment is good.
Description
Technical field
The invention belongs to textile fiber technology field, it is related to a kind of side for improving polypyrrole wool conductive fabric electric conductivity
Method.
Background technology
Conductive fiber is widely used in the life of people, including for prevent electromagnetic radiation pollution, electromagnetic-wave leakage,
The electromagnetic shielding material of the aspects such as protection human body health, and for treating chronic wounds as supplementary mode using electro photoluminescence
Conductive material.Conductive material is typically, using metal material as filler, conductive fabric to be prepared by top finish method.But
The conductive fabric of the top finish of this use metal packing, can make the hydraulic performance decline such as fabric feeling, washable, antifriction, perspiration resistance.
And using the conductive fabric of conductive polymer polymer, it is frivolous, saturating with feel compared with the conductive fabric that metal coating is arranged
The advantages of gas is good, advantage is had more than metal shield materials.
The representative conducting polymer of synthesis has polyacetylene, polyparaphenylene, polyaniline, polythiophene, polyphenyl at present
Acetylene and polypyrrole etc..Wherein, polypyrrole is a kind of typically conducting polymer with big conjugated double bond structures, is led with height
The advantages of stable and easily prepared in electric rate, air, thus it is widely used in electrochemistry, electrode material, optics and conduction material
The aspects such as material.Preparing the method for Polypyrrole Conducting Materials has chemical oxidising polymerisation and electrochemical polymerization, develops again on this basis
Template sol-gel process and method of electrostatic spinning.Wherein chemical oxidization method synthesis polypyrrole is relatively easy, easy, is conventional
One of method.But the electric conductivity of the polypyrrole wool conductive fiber of the wool of current non-Liquid Ammonia Treatment is poor, and has waste water
Produce.
The content of the invention
It is an object of the invention to provide a kind of method for improving polypyrrole wool conductive fabric electric conductivity, solve at present
The poor problem of the electric conductivity of the polypyrrole wool conductive fabric of the wool of non-Liquid Ammonia Treatment.
The technical solution adopted in the present invention is to follow the steps below：
Step 1：Wool cloth is immersed in pure liquefied ammonia and is processed 20-60 seconds, dried after taking-up；
Step 2：Processed being immersed in the chromium solution of 0.02-0.1mol/L through the wool cloth of Liquid Ammonia Treatment；
Step 3：The ferric chloride in aqueous solution of 0.02-0.2mol/L is added dropwise to while stirring, is reacted 1-6 hours；
Step 4：Rinse well and be vacuum dried at room temperature.
Further, wool cloth is immersed in pure liquefied ammonia in the step 1 and is processed 30 seconds.
Further, chromium solution concentration is 0.06mol/L in the step 2, and process time is 20 minutes.
Further, ferric chloride in aqueous solution concentration is 2 times of chromium solution concentration in the step 3.
Further, the reaction time is 4 hours in the step 3.
Polypyrrole wool conductive fabric electric conductivity the beneficial effects of the invention are as follows the wool after treatment is good.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.
The present invention improves the electric conductivity of polypyrrole wool conductive fabric using Liquid Ammonia Treatment wool cloth.Wool cloth is soaked first
Enter to process in pure liquefied ammonia 20-60 second, preferably 30 seconds, drying after taking-up；Chromium solution will be immersed in through the wool cloth of Liquid Ammonia Treatment
In (0.02-0.1mol/L, preferential 0.06mol/L) treatment, be added dropwise to while stirring ferric chloride in aqueous solution (0.02-0.2mol/L,
Preferred content is 2 times of chromium solution concentration), react 1-6 hours, preferably 4 hours, rinse well and vacuum is done at room temperature
It is dry, the preparation of the excellent polypyrrole wool conductive fabric of electric conductivity is completed, detect its surface resistivity.
Embodiment 1
The wool cloth of 4g is immersed and is processed 20,30,40,50 and 60 seconds in pure liquefied ammonia, then take out drying.Will without and warp
The wool cloth of Liquid Ammonia Treatment is immersed in (0.02mol/L) in the chromium solution of 200mL and processes 20 minutes, stirring, be slowly added dropwise into
The ferric chloride solution of the 0.04mol/L of 20mL carries out home position polymerization reaction, and reaction is maintained 2 hours.Then polypyrrole wool is led
Electric cloth takes out, and is vacuum dried at room temperature after being rinsed well with water.
Dried polypyrrole wool conductive fabric is carried out into surface resistivity detection, each sample detection 5 times, and be averaged
Value, the results are shown in Table 1.Surface resistivity is higher to represent that its electric conductivity is poorer.Through the polypyrrole wool of Liquid Ammonia Treatment in table 1
The surface resistivity of conductive fabric is lower than the surface resistivity without Liquid Ammonia Treatment, shows that Liquid Ammonia Treatment can reduce polypyrrole wool and lead
The surface resistivity of electric cloth, and through Liquid Ammonia Treatment 30 seconds after, in 0.02mol/L chromium solutions 2 hours polymerization prepare poly- pyrrole
The surface resistivity for coughing up wool conductive fabric is minimum, it was demonstrated that its electric conductivity is optimal.
The surface resistivity of polypyrrole wool conductive fabric prepared by the different Liquid Ammonia Treatment times of table 1.
| Liquid Ammonia Treatment | Surface resistivity (Ω/cm-2) |
| Without liquefied ammonia pre-treatment | 465.28 |
| Liquid Ammonia Treatment 20 seconds | 326.13 |
| Liquid Ammonia Treatment 30 seconds | 254.73 |
| Liquid Ammonia Treatment 40 seconds | 289.26 |
| Liquid Ammonia Treatment 50 seconds | 302.84 |
| Liquid Ammonia Treatment 60 seconds | 322.68 |
Embodiment 2
The wool cloth of 4g is immersed in pure liquefied ammonia and is processed 30 seconds, then take out drying.To be soaked through the wool cloth of Liquid Ammonia Treatment
Enter in the chromium solution of 200mL (0.02mol/L) to process 20 minutes, stirring is slowly added dropwise the chlorine of the 0.04mol/L into 20mL
Changing ferrous solution carries out home position polymerization reaction, and reaction is maintained 1,2,3,4,5 and 6 hour.Then polypyrrole wool conductive fabric is taken out,
It is vacuum dried at room temperature after being rinsed well with water.
Dried polypyrrole wool conductive fabric is carried out into surface resistivity detection, each sample detection 5 times, and be averaged
Value, the results are shown in Table 2.Surface resistivity is higher to represent that its electric conductivity is poorer.4 hours samples of polymerization reaction time in table 2
Surface resistivity it is low minimum, although when the surface resistivity of the polymerization reaction time sample of 5 hours and 6 hours and polymerisation
Between 4 hours samples it is close, it is considered to combined coefficient and cost factor, determine that polymerization reaction time 4 hours is optimal polymerisation
Time.
The different polymerization reaction times of table 2. prepare the surface resistivity of polypyrrole wool conductive fabric
| Polymerization reaction time | Surface resistivity (Ω/cm-2) |
| Polymerization reaction time 1 hour | 327.58 |
| Polymerization reaction time 2 hours | 254.73 |
| Polymerization reaction time 3 hours | 224.65 |
| Polymerization reaction time 4 hours | 203.98 |
| Polymerization reaction time 5 hours | 206.04 |
| Polymerization reaction time 6 hours | 205.41 |
Embodiment 3
The wool cloth of 4g is immersed in pure liquefied ammonia and is processed 30 seconds, then take out drying.To be soaked through the wool cloth of Liquid Ammonia Treatment
Enter in the chromium solution of 200mL (0.02,0.04,0.06,0.08 and 0.10mol/L) to process 20 minutes, stirring, accordingly
It is slowly added dropwise 0.04 into 20mL, the ferric chloride solution of 0.08,0.12,0.16 and 0.2mol/L (the i.e. concentration of ferric chloride solution
It is 2 times of chromium solution concentration) home position polymerization reaction is carried out, reaction is maintained 4 hours.Then polypyrrole wool conductive fabric is taken
Go out, be vacuum dried at room temperature after being rinsed well with water.
Dried polypyrrole wool conductive fabric is carried out into surface resistivity detection, each sample detection 5 times, and be averaged
Value, the results are shown in Table 3.Surface resistivity is higher to represent that its electric conductivity is poorer.0.06mol/L chromium solutions polymerization in table 3
The surface resistivity of the polypyrrole wool conductive fabric being made is low minimum, although being the pyrrole of 0.08mol/L and 0.10mol/L in concentration
The surface resistivity for coughing up the polypyrrole wool conductive fabric being made in solution is close with the sample of 0.06mol/L chromium solutions, it is considered to
Combined coefficient and cost factor, determine that the concentration of chromium solution is optimal polymerisation concentration for 0.06mol/L.
The surface resistivity of polypyrrole wool conductive fabric prepared by the polymerization of the various concentrations chromium solution of table 3.
| Chromium solution concentration | Ferric chloride solution concentration | Surface resistivity (Ω/cm-2) |
| 0.02mol/L chromium solutions | 0.04mol/L ferric chloride solutions | 203.98 |
| 0.04mol/L chromium solutions | 0.08mol/L ferric chloride solutions | 194.23 |
| 0.06mol/L chromium solutions | 0.12mol/L ferric chloride solutions | 180.46 |
| 0.08mol/L chromium solutions | 0.16mol/L ferric chloride solutions | 181.98 |
| 0.10mol/L chromium solutions | 0.20mol/L ferric chloride solutions | 182.04 |
Embodiment 4
The wool cloth of 4g is immersed in pure liquefied ammonia and is processed 30 seconds, then take out drying.To be soaked through the wool cloth of Liquid Ammonia Treatment
Enter the 0.06mol/L in the chromium solution of 200mL) treatment 20 minutes, stirring is slowly added dropwise 0.04 into 20mL respectively, and 0.08,
The ferric chloride solution of 0.12,0.16 and 0.2mol/L carries out home position polymerization reaction, and reaction is maintained 4 hours.Then by polypyrrole sheep
Hair conductive fabric takes out, and is vacuum dried at room temperature after being rinsed well with water.
Dried polypyrrole wool conductive fabric is carried out into surface resistivity detection, each sample detection 5 times, and be averaged
Value, the results are shown in Table 4.Surface resistivity is higher to represent that its electric conductivity is poorer.In table 4 in 0.06mol/L chromium solutions
The surface resistivity for being added dropwise to the polypyrrole wool conductive fabric that the polymerization of 0.12mol/L ferric chloride solutions is made is low minimum, although
The surface resistivity of the polypyrrole wool conductive fabric that concentration is made for the ferric chloride solution of 0.16mol/L and 0.20mol/L is added dropwise
Sample with 0.12mol/L ferric chloride solutions is close, it is considered to combined coefficient and cost factor, and the concentration for determining ferric chloride solution is
0.12mol/L is that 2 times that optimal polymerisation concentration, the i.e. concentration of ferric chloride solution are chromium solution concentration are most preferably to compare
Example.
The surface resistivity of polypyrrole wool conductive fabric prepared by the polymerization of the various concentrations ferric chloride solution of table 4.
| Chromium solution concentration | Ferric chloride solution concentration | Surface resistivity (Ω/cm-2) |
| 0.06mol/L chromium solutions | 0.04mol/L ferric chloride solutions | 253.62 |
| 0.06mol/L chromium solutions | 0.08mol/L ferric chloride solutions | 215.59 |
| 0.06mol/L chromium solutions | 0.12mol/L ferric chloride solutions | 180.46 |
| 0.06mol/L chromium solutions | 0.16mol/L ferric chloride solutions | 189.07 |
| 0.06mol/L chromium solutions | 0.20mol/L ferric chloride solutions | 191.33 |
The present invention improves the electric conductivity of polypyrrole wool conductive fabric, liquefied ammonia after treatment by wool liquefied ammonia pre-treating method
Easy recycling, reduces pollution；Electric conductivity by the polypyrrole wool conductive fabric of the inventive method Liquid Ammonia Treatment is good
It is good, and produced without waste water.
The above is only, to better embodiment of the invention, any formal limit not to be made to the present invention
System, every any simple modification made to embodiment of above according to technical spirit of the invention, equivalent variations and modification,
Belong in the range of technical solution of the present invention.
Claims (5)
1. it is a kind of improve polypyrrole wool conductive fabric electric conductivity method, it is characterised in that follow the steps below：
Step 1：Wool cloth is immersed in pure liquefied ammonia and is processed 20-60 seconds, dried after taking-up；
Step 2：Processed being immersed in the chromium solution of 0.02-0.1mol/L through the wool cloth of Liquid Ammonia Treatment；
Step 3：The ferric chloride in aqueous solution of 0.02-0.2mol/L is added dropwise to while stirring, is reacted 1-6 hours；
Step 4：Rinse well and be vacuum dried at room temperature.
2. according to a kind of method for improving polypyrrole wool conductive fabric electric conductivity described in claim 1, it is characterised in that：It is described
Wool cloth is immersed in pure liquefied ammonia in step 1 is processed 30 seconds.
3. according to a kind of method for improving polypyrrole wool conductive fabric electric conductivity described in claim 1, it is characterised in that：It is described
Chromium solution concentration is 0.06mol/L in step 2, and process time is 20 minutes.
4. according to a kind of method for improving polypyrrole wool conductive fabric electric conductivity described in claim 1, it is characterised in that：It is described
Ferric chloride in aqueous solution concentration is 2 times of chromium solution concentration in step 3.
5. according to a kind of method for improving polypyrrole wool conductive fabric electric conductivity described in claim 1, it is characterised in that：It is described
The reaction time is 4 hours in step 3.
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| CN201710201684.5A CN106930110B (en) | 2017-03-30 | 2017-03-30 | A method of improving polypyrrole wool conductive fabric electric conductivity |
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| CN201710201684.5A CN106930110B (en) | 2017-03-30 | 2017-03-30 | A method of improving polypyrrole wool conductive fabric electric conductivity |
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| CN106930110B CN106930110B (en) | 2019-08-20 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110656497A (en) * | 2019-09-05 | 2020-01-07 | 浙江省检验检疫科学技术研究院 | Preparation method of poly (3, 4-ethylenedioxythiophene)/cotton composite fabric |
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| CN103276500A (en) * | 2013-05-31 | 2013-09-04 | 江阴福斯特纺织有限公司 | Super cotton-like cashmere double-side fabric and production process thereof |
| CN103981719A (en) * | 2014-05-23 | 2014-08-13 | 青岛大学 | Method for preparing anti-ultraviolet polyaniline titanium dioxide conductive fabric |
| CN104562403A (en) * | 2014-12-31 | 2015-04-29 | 宁波天亚服装有限公司 | Environment-friendly soft anti-wrinkle knitted fabric and production method thereof |
| CN105088797A (en) * | 2015-09-07 | 2015-11-25 | 江苏阳光股份有限公司 | Non-ironing treatment method capable of improving strength of wool fabric |
| CN106758240A (en) * | 2016-12-01 | 2017-05-31 | 西南大学 | The preparation method of polypyrrole conduction wool fabric |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103276500A (en) * | 2013-05-31 | 2013-09-04 | 江阴福斯特纺织有限公司 | Super cotton-like cashmere double-side fabric and production process thereof |
| CN103981719A (en) * | 2014-05-23 | 2014-08-13 | 青岛大学 | Method for preparing anti-ultraviolet polyaniline titanium dioxide conductive fabric |
| CN104562403A (en) * | 2014-12-31 | 2015-04-29 | 宁波天亚服装有限公司 | Environment-friendly soft anti-wrinkle knitted fabric and production method thereof |
| CN105088797A (en) * | 2015-09-07 | 2015-11-25 | 江苏阳光股份有限公司 | Non-ironing treatment method capable of improving strength of wool fabric |
| CN106758240A (en) * | 2016-12-01 | 2017-05-31 | 西南大学 | The preparation method of polypyrrole conduction wool fabric |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110656497A (en) * | 2019-09-05 | 2020-01-07 | 浙江省检验检疫科学技术研究院 | Preparation method of poly (3, 4-ethylenedioxythiophene)/cotton composite fabric |
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