CN1069296C - Silicon fertilizer, silicon compound fertilizer and production method thereof - Google Patents
Silicon fertilizer, silicon compound fertilizer and production method thereof Download PDFInfo
- Publication number
- CN1069296C CN1069296C CN97108994A CN97108994A CN1069296C CN 1069296 C CN1069296 C CN 1069296C CN 97108994 A CN97108994 A CN 97108994A CN 97108994 A CN97108994 A CN 97108994A CN 1069296 C CN1069296 C CN 1069296C
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- silicon
- phosphate
- siliceous
- sodium silicate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 61
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000010703 silicon Substances 0.000 title claims abstract description 25
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 150000003377 silicon compounds Chemical class 0.000 title abstract 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 15
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 13
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004021 humic acid Substances 0.000 claims abstract description 12
- 239000000618 nitrogen fertilizer Substances 0.000 claims abstract description 9
- 239000002686 phosphate fertilizer Substances 0.000 claims abstract description 9
- 239000011573 trace mineral Substances 0.000 claims abstract description 9
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011591 potassium Substances 0.000 claims abstract description 5
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 239000011574 phosphorus Substances 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 229940072033 potash Drugs 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- 235000015320 potassium carbonate Nutrition 0.000 claims description 6
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- 239000005696 Diammonium phosphate Substances 0.000 claims description 4
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 4
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 4
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 4
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 4
- 239000006012 monoammonium phosphate Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical group [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 3
- YMKIRWHSXOBLCF-UHFFFAOYSA-N [Mg].[P].[Ca] Chemical compound [Mg].[P].[Ca] YMKIRWHSXOBLCF-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 235000015097 nutrients Nutrition 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 208000006558 Dental Calculus Diseases 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical group [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 claims description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 239000003077 lignite Substances 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 235000019691 monocalcium phosphate Nutrition 0.000 claims description 2
- 239000003415 peat Substances 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000002689 soil Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 239000010881 fly ash Substances 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a silicon fertilizer containing liquid sodium silicate, a silicon compound fertilizer and a manufacturing method thereof. Mixing and stirring two materials in a weight ratio of liquid sodium silicate to humic acid of 0.5-3: 1, and then granulating and drying to obtain the silicon fertilizer. The silicon fertilizer is mixed and stirred according to the requirements of 10-35 percent of silicon fertilizer, 30-35 percent of nitrogen fertilizer, 10-25 percent of phosphate fertilizer, 1 percent of potassium fertilizer and trace elements in weight ratio. The silicon fertilizer and the silicon compound fertilizer are easy to dissolve in water, have high effective silicon content, are easy to be absorbed by plants, and have the advantages of enhancing the plant resistance, increasing the yield, improving the quality, improving the soil and the like. The production process of the product is simple and the fertilizer efficiency is high.
Description
The invention belongs to compound manure, relate to a kind of siliceous fertilizer, silicon composite fertilizer and production method thereof.
As everyone knows, silicon is the fourth-largest element of crop growth after nitrogen, phosphorus, potassium, and siliceous fertilizer is rising star in the middle of the chemical fertilizer.Existing siliceous fertilizer is normally a kind of, and they can directly adopt flyash to make to contain the mineral manure of Calucium Silicate powder, also can use phosphorus ore tailing to make.Although silicon-dioxide SiO in flyash or the phosphorus ore tailing
2Content can be up to 50～60%, but soluble silicon only accounts for 1～2%, are difficult for being utilized by plant absorbing, cause the big and fertilizer efficiency difference phenomenon of siliceous fertilizer consumption.Thereby, improve the key that soluble silicon content has just become to improve the siliceous fertilizer fertilizer efficiency.
The also useful water glass (Na of prior art
2SiO
3) directly use as siliceous fertilizer, but be subjected to condition restriction.If use the then easy caking of sodium silicate solid of sodium silicate solid itself, inconvenience is used; If use liquid sodium silicate, then cause transportation and the inconvenience of using.
The purpose of this invention is to provide the higher instantly-soluble siliceous fertilizer of a kind of available silicon content, can overcome simultaneously the drawback of directly using water glass and being produced.
For reaching goal of the invention, the invention provides a kind of siliceous fertilizer, silicon composite fertilizer and production method thereof.Siliceous fertilizer of the present invention, composition are liquid sodium silicate and humic acid, and both weight ratios are: liquid sodium silicate: humic acid=0.5-3: 1; Described humic acid substance can be peat, brown coal, weathered coal, and fineness is not less than 200 orders.
The production method of above-mentioned siliceous fertilizer is: mixed stirring with liquid sodium silicate after humic acid substance is pulverized 200 mesh sieves, through the tablets press granulation, drying gets siliceous fertilizer again.
Silicon composite fertilizer provided by the invention is equipped with nitrogenous fertilizer, phosphate fertilizer, potash fertilizer again, is formed micro-the mixing by above-mentioned siliceous fertilizer; The weight percent of each component is: siliceous fertilizer: nitrogenous fertilizer: phosphate fertilizer: potash fertilizer: trace element=10-35%: 30-35%: 20-35%: 10-25%: 1%; Described nitrogenous fertilizer can be urea, ammonium chloride; Phosphate fertilizer can be calcium superphosphate, calcium magnesium phosphorus, monoammonium phosphate, diammonium phosphate; Potash fertilizer can be Repone K, vitriolate of tartar; Trace element can be boron, molybdenum, zinc, sulphur; Monoammonium phosphate and diammonium phosphate also can enter prescription as nitrogenous fertilizer and phosphate fertilizer simultaneously.
The production method of above-mentioned silicon composite fertilizer is humic acid substance to be pulverized 200 mesh sieves and mix stirring with liquid sodium silicate, behind granulation, dry siliceous fertilizer, add nitrogen, phosphorus, potassium and trace element fertilizer mixing and stirring more simultaneously, promptly make the comprehensive silicon composite fertilizer of nutrient.
Siliceous fertilizer provided by the invention and the silicon composite fertilizer following outstanding advantage of having compared with existing siliceous fertilizer: liquid sodium silicate and humic acid substance effect form silicic acid, and the available silicon content height is soluble in water, are easy to plant root and absorb.After cooperating nitrogen, phosphorus, potassium and trace element to make silicon composite fertilizer, nutrient is more comprehensive.Have strengthen stress resistance of plant, the infringement of disease-resistant worm, increase crop sugar part, improve output, improvement quality, advantage such as improve the soil.
Below be embodiments of the invention:
Embodiment 1: with 500 kilograms of weathered coals, drop into tablets press behind 200 mesh sieves excessively, spray into 500 kilograms of liquid sodium silicates while rotating.Made particle in about 5 minutes, the particle siliceous fertilizer is promptly made in the oven dry of drying machine.
Embodiment 2: takes by weighing 100 kilograms of the siliceous fertilizers that embodiment 1 makes, gets 300 kilograms in urea, 350 kilograms in calcium magnesium phosphorus, 250 kilograms in Repone K again, and 10 kilograms of trace elements, it is even to drop into stirrer for mixing, promptly makes silicon composite fertilizer.
Claims (4)
1, a kind of siliceous fertilizer is characterized in that said siliceous fertilizer composition is liquid sodium silicate and humic acid, and both weight ratios are: liquid sodium silicate: humic acid=0.5～3: 1;
Described humic acid substance can be peat, brown coal, weathered coal, and fineness is not less than 200 orders.
2, the production method of the described siliceous fertilizer of a kind of claim 1 is mixed stirring with liquid sodium silicate after it is characterized in that humic acid substance pulverized 200 mesh sieves, and through the tablets press granulation, drying gets siliceous fertilizer again.
3. a silicon composite fertilizer is characterized in that said silicon composite fertilizer is equipped with nitrogenous fertilizer, phosphate fertilizer, potash fertilizer again, is formed micro-the mixing by the described siliceous fertilizer of claim 1; The weight percent of each component is: siliceous fertilizer: nitrogenous fertilizer: phosphate fertilizer: potash fertilizer: trace element=10-35%: 30-35%: 20-35%: 10-25%: 1%;
Described nitrogenous fertilizer can be urea, ammonium chloride; Phosphate fertilizer can be calcium superphosphate, calcium magnesium phosphorus, monoammonium phosphate, diammonium phosphate; Potash fertilizer can be Repone K, vitriolate of tartar; Trace element can be boron, molybdenum, zinc, sulphur; Monoammonium phosphate and diammonium phosphate also can enter prescription as nitrogenous fertilizer and phosphate fertilizer simultaneously.
4, the production method of the described silicon composite fertilizer of a kind of claim 3, it is characterized in that humic acid substance pulverized 200 mesh sieves and mix stirring with liquid sodium silicate, behind granulation, thousand dry siliceous fertilizers, add nitrogen, phosphorus, potassium and trace element fertilizer mixing and stirring more simultaneously, promptly make the comprehensive silicon composite fertilizer of nutrient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97108994A CN1069296C (en) | 1997-07-18 | 1997-07-18 | Silicon fertilizer, silicon compound fertilizer and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97108994A CN1069296C (en) | 1997-07-18 | 1997-07-18 | Silicon fertilizer, silicon compound fertilizer and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1176951A CN1176951A (en) | 1998-03-25 |
| CN1069296C true CN1069296C (en) | 2001-08-08 |
Family
ID=5170822
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97108994A Expired - Fee Related CN1069296C (en) | 1997-07-18 | 1997-07-18 | Silicon fertilizer, silicon compound fertilizer and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1069296C (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805219A (en) * | 2010-03-26 | 2010-08-18 | 常熟市陆富新型肥料研发有限公司 | Four-component fertilizer with nitrogen, phosphorus, potassium and silicon and preparation method thereof |
| CN102010270B (en) * | 2010-12-10 | 2013-03-13 | 绵阳台沃农业科技有限责任公司 | Rice field base application multi-effect nutrient |
| CN102153401B (en) * | 2010-12-14 | 2013-06-12 | 绵阳台沃农业科技有限责任公司 | Multi-effect nutritional agent for seedling raising of paddy field |
| CN102649648B (en) * | 2012-04-16 | 2013-12-25 | 中国冶金矿业长春矿产资源开发有限公司 | Solid water ball silicon composite fertilizer and preparation process |
| CN103539512A (en) * | 2013-01-24 | 2014-01-29 | 杜新明 | Humic acid organic silicon fertilizer |
| CN103304297B (en) * | 2013-05-29 | 2015-05-13 | 深圳市芭田生态工程股份有限公司 | Water-soluble silicon fertilizer |
| CN103739386B (en) * | 2013-12-30 | 2016-04-06 | 深圳市芭田生态工程股份有限公司 | Compound manure of a kind of containing water-soluble silicon and preparation method thereof |
| CN104151100A (en) * | 2014-07-15 | 2014-11-19 | 安徽辉隆集团五禾生态肥业有限公司 | Production method for adding humic acid and sodium silicate into compound fertilizer |
| CN104151099A (en) * | 2014-07-15 | 2014-11-19 | 安徽辉隆集团五禾生态肥业有限公司 | Production method of organic-inorganic mixed fertilizer with humic acid and sodium silicate |
| CN104151041A (en) * | 2014-07-15 | 2014-11-19 | 安徽辉隆集团五禾生态肥业有限公司 | Production method for adding humic acid and sodium silicate in blended fertilizer |
| CN106316490A (en) * | 2015-06-16 | 2017-01-11 | 孙建和 | Silicon fertilizer, silicon compound fertilizer and production method thereof |
| CN105347853A (en) * | 2015-12-08 | 2016-02-24 | 武汉瑞阳生物科技有限公司 | Liquid silicon fertilizer prepared from sodium metasilicate pentahydrate |
| CN108424211A (en) * | 2017-02-15 | 2018-08-21 | 至善治禾（唐山）生物肥料有限公司 | A kind of high concentration silicon potassium water soluble fertilizer |
| CN107459417B (en) * | 2017-06-15 | 2020-11-20 | 江苏大学 | Method for preparing liquid silicon fertilizer by using monocrystalline silicon solar cell texturing waste liquid |
| CN108164359A (en) * | 2017-12-29 | 2018-06-15 | 广东拉多美化肥有限公司 | A kind of humic acid Si composite fertilizer and preparation method thereof |
| CN112299916A (en) * | 2019-07-30 | 2021-02-02 | 陈信行 | Active silicon preparation |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040019A (en) * | 1988-08-04 | 1990-02-28 | 南京农业大学 | The production method of high effective silica fertilizer |
| SU1675301A1 (en) * | 1989-02-10 | 1991-09-07 | Институт химии древесины АН ЛатвССР | Method for preparation lignosilium manure |
| CN1056863A (en) * | 1990-05-31 | 1991-12-11 | 四川省国营忠县水泥厂 | Method for making silicon fertilizer |
| CN1112536A (en) * | 1995-03-09 | 1995-11-29 | 南通市土壤肥料站 | Multi-effect siliceous fertilizer and its producing process |
-
1997
- 1997-07-18 CN CN97108994A patent/CN1069296C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040019A (en) * | 1988-08-04 | 1990-02-28 | 南京农业大学 | The production method of high effective silica fertilizer |
| SU1675301A1 (en) * | 1989-02-10 | 1991-09-07 | Институт химии древесины АН ЛатвССР | Method for preparation lignosilium manure |
| CN1056863A (en) * | 1990-05-31 | 1991-12-11 | 四川省国营忠县水泥厂 | Method for making silicon fertilizer |
| CN1112536A (en) * | 1995-03-09 | 1995-11-29 | 南通市土壤肥料站 | Multi-effect siliceous fertilizer and its producing process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1176951A (en) | 1998-03-25 |
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