CN106928908A - A kind of new aeroge multifunctional material and preparation method thereof - Google Patents

Abstract

The invention provides a kind of new aeroge multifunctional composite and preparation method thereof.Use gellan gum of the invention, hyaluronic acid and its derivative of the two or the raw material such as their mixture, aeroge, new light-sensitive material, novel dissolvent or novel ion liquid or the new mixed solvent or essential oil of the formation of these solvents, Multifunctional, air gel composite is prepared using high energy photocuring processes.The composite has that density is light, thermal conductivity factor is low, weatherability is strong, environmental protection the features such as, there is good heat-insulated, insulation, cold-storage, moisturizing, protection against the tide, water lock and anti-fog haze characteristic through the function carrier or functional material of material cladding treatment, and characteristic and use scope of these materials etc. can be improved.The multifunctional material application is extremely wide, can be widely used for haze preventing and treating, medical diagnosis on disease treatment, medicine, military project, chemical industry, space flight, navigation, aviation, high ferro, papermaking, printing, water process, farming animals herd, the field such as cold chain system, food and cosmetics safety.

Description

A kind of new aeroge multifunctional material and preparation method thereof

Technical field

The invention belongs to chemical classes are heat-insulated, insulation, cold-storage, moisturizing, protective materials field, and in particular to a kind of new storage Energy, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, water lock, protective multifunction material and preparation method thereof..

Background technology

Gellan gum is to integrate thickening, suspension, emulsification, stabilization, antibacterial, controlled release, the food of superior performance in the world at present One of product glue, with high commercial profit and market prospects.Gellan gum is that the polysaccharide colloid obtained with biofermentation method is coagulated Jelly, has the advantages that consumption is low, transparency is high, fragrance releasability is strong, acidproof, alkaline-resisting, with antimicrobial and resistance to enzymolysis Effect, so the gel being made of gellan gum can in right amount reduce addition preservative, not only saves production cost, and can improve Product quality, there is extensive purposes in food service industry, pharmaceuticals industry, Chinese daily chemical articles industry and paper industry.Gellan gum is Another Microbial exopolysaccharides that Kelco companies of the U.S. succeed in developing after xanthans, past attempts claim heteroglycan PS-60, Find just there is relevant gellan gum laboratory scale fermenting and producing successfully to report until 1982 in late 1970s.Knot The producing strains Sphingomonas paucimobilis (Sphingomonaspaucimobilis ATCC 31461) of cold glue, past attempts claim Yi Le Pseudomonad (Pseudomonas eloder ATCC 31461), is that a kind of aerobic leather orchid for obtaining is separated from plant Negative bacterium.Carbon source can made with carbohydrates such as glucose, sucrose, maltose, containing inorganic or organic nitrogen source and phosphate and micro unit Grown in the culture medium of element, its most suitable cultivation temperature is 30 DEG C.Gellan gum can divide according to the difference of acyl group content on molecular backbone It is high acyl gellan gum（HA, natural gellan gum）And low-acyl gellan gum（LA, deacylated gellan gum）.

Gellan gum is the anion linear polysaccharide that a kind of molecular weight is up to 1.5 × 106 dalton, and it is tied from molecular level Structure carries out understanding the more preferable application for contributing to people to it.The basic structure of gellan gum molecule is a main chain, by the four of repetition Sugar unit is constituted, as shown in Figure 1.The monose for participating in being formed has glucose, glucuronic acid and rhamnose, mol ratio 2：1：1. In the native form of this polysaccharide, per unit there are about 1.5 O- carboxyl groups, wherein existing O- acyl substituents, there is O- again Glyceroyl replaces base, and the latter is more than the former, and glyceroyl is located at 2 of the glucose residue of 3- connection bondings, and acetyl group then exists On 6.O- acyl groups are easy to be removed by alkali, so as to obtain the product of deacylated form by the gellan gum of native form.With this phase Right, the gellan gum of native form is alternatively referred to as acyl group product high.

After gellan gum is dissolved in selected solvent, can assemble to form double-spiral structure automatically between molecule, stabilization double-spiral structure Active force be mainly intermolecular hydrogen bonding, further aggregation can form tridimensional network to double helix, be easy to retain solvent molecule And produce gelatin phenomenon.The gelling performance of formation is remarkable, does not have toxicity, acid and alkali-resistance, not mutability, temperature lag significantly, group Knit compatibility and compatibility is good, stability is preferable, and the various fields such as pharmacy, food, chemical industry are widely used in recent years.

Aeroge is a kind of new heat-insulation and heat-preservation energy storage material, low with thermal conductivity factor, can reach 0.015w/m.k's Thermal conductivity factor, with the incomparable heat-insulation and heat-preservation cold accumulation effects of other materials, and density is light, typically in 0.005~2.3g/ cm³, water proof fire retardant, anti-soda acid, corrosion-resistant, non-aging, long service life, the features such as environmental protection.With very high additional Value, therefore it is referred to as super insulation material.Aeroge is one of representative of new and high technology in the world.By initial frangible, useless Physical development turn into present soft or rigid revolution insulation cool storage material.Stored with to high-performance insulation Can demand constantly increase, can be used for decoration new liquid wallpaper, medical diagnosis on disease, haze, sewage disposal, food, medicine, The fields such as chemical industry, biology, space flight, electronics, building, decoration, automobile, household product and clothes.

Aeroge has following characteristic：

■ ultralow thermal conductivity factor ensures outstanding effect of heat insulation

■ hydrophobic, air-permeabilities, suppress the corrosion phenomenon under insulation（CUI）

■ inorganic material, service life is long, and fire protecting performance reaches A1 grades

■ reduces the thickness of thermal insulation layer, reduces heat waste

■ is readily transported, and saves logistics cost and storage area

■ excellent structural capacity, resistance to compression, tensile strength ensure long-term durable, in order

■ is easily operated, reduces labour and time needed for installing

■ Environmental Safety, is easily processed

■ is applied widely, particularly suitable for narrow space

■ improves efficiency, reducing energy consumption

■ capillarities, act on selective absorption and anti-fog haze.

Hyaluronic acid（hyaluronic acid, HA）, a kind of naturally occurring linearly glutinous polysaccharide, is by D-Glucose aldehyde Acid and 2-Acetamido-2-deoxy-D-glucose dissacharide units repeat what is connected into.Early in, Bernard Weissman and Karl in 1954 Meyer determines the basic chemical structure of HA first.In order to confirm the structure of HA, Meyer and his assistant have carried out a series of Chemical reaction, including：The esterification of disaccharides, aminoglucose saccharide residue are oxidized to glucosaminicacid, glucose aldehydo-ester also It is former into glucose residue etc..By there is acetyl on the residue after hydrolyzed under acidic conditions and other factors inference Glucosamine Substrate section, the as acetyl group on 2-Acetamido-2-deoxy-D-glucose；The optical activity of polymer is the company between [α] D -70 ° of inference monose It is connected in beta comfiguration.In addition, the size distribution rule of the oligosaccharides isolated from the catabolite of enzyme draws：HA has been free from other Side chain or a kind of linear single-stranded macromolecular almost without branch polymer.It is final draw HA primary structure be by N- acetyl group- The linear poly- polysaccharide that D- Glucosamines and D-Glucose aldehydic acid are alternately connected by β 1,3 and β Isosorbide-5-Nitraes glycosidic bond, structure is [- β (1,4)-D-Glucose aldehydic acid-β (1,3) -2-Acetamido-2-deoxy-D-glucose] n.

With the structure of HA and using upper progress, it is found that HA also has other more complicated structures, for example： Two grades and tertiary structure.In dilute solution, the functional group of HA molecules for example forms intramolecular to HA molecules between NH, OH, and C=O Hydrogen bond, these intramolecular hydrogen bonds make HA strands more stablize and firm.In addition, each disaccharide unit is with 180 ° of Torsion coil Form the single coil configuration of HA, the i.e. secondary structure of HA.The hydrogen bond that HA is formed in the aqueous solution with anhydrous environment is different, this hair It is bright exactly to make use of this characteristic.

When the concentration of HA solution is higher, it is found that HA forms network structure, i.e. tertiary structure again.Different HA molecules Intermolecular hydrogen bonding can be formed between acid amides and carboxylic group.In addition, Scott is according to finding under wherein rotation shadow microscope, Using means such as computer simulations, each trisaccharide unit contains one piece of hydrophobic region, these hydrophobic regions in proposing HA molecules Also it is proved exist in experiment afterwards.In high concentration, the interaction of the intermolecular hydrophobic regions of HA and intermolecular Hydrogen bond strengthens the double-spiral structure of HA, and the interaction of intermolecular polymerization constitutes the network structure of HA.

Fig. 2 demonstrates one, two, three structure and microstructure of HA.

Hyaluronic acid（Hyaluronic acid, HA）It is as a kind of glutinous polysaccharide for being widely present in nature, by [(1 → 3)-β-D- n acetylglucosamine ns-(1 → 4)-β-D- uronic acids] dissacharide units of composition repeat connection composition.HA is widely present In vertebrate connective tissue and body fluid, such as knuckle synovia, vitreum, umbilical cord, skin.HA has unique viscoelasticity With excellent water-retaining property, histocompatbility and non-immunogenic, and with important physiological function and biological action, thus Clinically have a wide range of applications.Balazs classifies as some current applications：Viscoelasticity is performed the operation（Viscosurgery）, it is glutinous Elastic replacement therapy（Viscosupplementation）, viscoelasticity filling（Viscoaugmentation）, viscoelasticity intercept （Viscoseparation, that is, prevent adhesion）Protected with viscoelasticity（Viscoprotection）.In addition, HA is in drug delivery and group The aspects such as weaver's journey also have application.It is mainly used to moisturizing water lock, radioresistance etc. in terms of cosmetics.

At present, for gellan gum, hyaluronic acid and aeroge research and application focuses primarily upon gellan gum and gellan gum Each gellike and spiral net-shaped structure, aeroge and its heat-insulation and heat-preservation being collectively forming with other raw materials, the moisturizing of hyaluronic acid Effect and double-spiral structure, the research used for gellan gum, hyaluronic acid and aeroge triplicity and application are few.Wherein Patent《New silica aerogel material and preparation method thereof, purposes and application structure》（Application number： CN201210425004.5）Describe it is preforming in the mould cavity of a kind of use reinforcing fiber or pore structure framework material, do The wet gel of aging shaping is made after dry；Finally, in the wet gel material of shaping being moved into drying equipment, supercritical drying is carried out It is dry, obtain the enhanced silica aerogel material；And patent《A kind of system of the excellent purple light solidified aqueous coating of adhesive force Preparation Method》Describe a kind of Water-soluble product, sensitising agent, pure water, thickener, colorant；By Water-soluble product with Sensitising agent is pre-mixed, and obtains mixed liquor A；Pure water and thickener are pre-mixed, mixed liquid B is obtained；The mixed liquor A is infrared 50 DEG C are heated to, after being kept for 5 minutes, the mixed liquid B is poured into, infrared heating pours into colorant to 98 DEG C after being well mixed, mixed Uniformly, room temperature is down to after being kept for 5 minutes, semi-finished product are obtained, semi-finished product is carried out with ultraviolet irradiation, kept for 5 minutes, obtained into Product.These methods are required for heating stepses, cumbersome, are related to face small, and the scope of application is narrow, and to functional molecular or material work( Can cladding applications it is few, easy dust or shedding.And this patent is in view of gellan gum gelling temp hysteresis quality characteristic and spiral net Shape architectural characteristic, the moisturizing film forming characteristics of hyaluronic acid and double helix mechanism, new photosensitive adhesive or new type photosensitive resin or The photocuring or hardening with radiation characteristic of new light-sensitive material and the heat-insulated of aeroge, insulation energy storage, low-gravity characteristic, hydrophobic property And weatherability, with reference to various functions carrier or functional material self character, the tool that they are prepared by simple method Have the energy storage of porous or covering property or blending, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing and protection aerogel composite or The functional material or carrier material of this material are coated, practical with applied widely, safety and environmental protection can be used extensively Stored and transport product in in-vitro diagnosis product packaging, Novel cold chain, and can be applied to decoration new liquid wallpaper, soil and changed Good, soil moisturizing, pesticide synergistic, pesticide action-controlling, sewage disposal, haze improvement, Aero-Space navigation, home air purification, electricity Son, food, papermaking, printing, biology, medicine, chemical industry, environment, agriculture livestock products, the energy, catalysis, optics, anti-fog haze cosmetics And skincare product, anti-fog haze infant article, anti-ageing field of waiting for a long time are for energy-storage thermal-insulating, insulation, cold-storage, protection against the tide, moisturizing, lock Water, protection have important application prospect.

The content of the invention

The invention solves the problems that a technical problem be to provide a kind of new multifunctional material, it is therefore an objective to energy storage, it is heat-insulated, Insulation, cold-storage, protection against the tide, moisturizing, water lock, protection, while the function carrier for being wrapped by or being admixed or functional material can be strengthened Self-protection and performance, can strengthen its performance, improve its stability and expand its range of application.The invention solves the problems that another Technical problem is to provide a kind of energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, water lock, the preparation of protective multifunction material The method that method and this method are combined with functional material or function carrier.

Energy storage of the invention, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protection aeroge multifunctional material and its preparation side The main flow of method is that gellan gum, hyaluronic acid and aeroge homogenize under normal temperature state, and solid with light-sensitive material or light Homogenized after agent, solvent mixing, be coated in functional material or cladding function carrier surface or be doped in functional material and carry out Homogenize process, act on finally by photocuring, and solidification is obtained energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing protective materials after drying And the functional material of cladding or the material that adulterates, and further subsequent treatment is done as needed.

Energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing protective materials of the invention, is characterized in, described energy-storage thermal-insulating insulation Cold-storage protection against the tide moisturizing protective materials includes that the weight/mass percentage composition of gellan gum is 0.0001%~19.0%；Hyaluronic acid quality percentage Content is 0.0001%~19.0%；Aerogel powder content 0.04~99.7%；The quality percentage of photocuring adhesive and solvent contains It is 0.1%~99.0% to measure, and the mixed proportion of the two is 1~1000:1~1000, relatively the 1~500 of optimization:1~500, optimize Be 1~100:1~100；Described gellan gum is high acyl gellan gum, low-acyl gellan gum or the mixture of the two；It is described Hyaluronic acid spread out for low-molecular-weight hyaluronic acid or high molecular weight hyaluronic acid or oligomerization hyaluronic acid or other hyaluronic acids Biological or their mixture；Described aeroge is silica aerogel powder or silica aerogel particles or dioxy SiClx aeroge coating commodity or graphene aerogel or carbon aerogels or metal aerogel or other inorganic, organic aerogels； Described photocuring adhesive is including but not limited to extensive stock light-sensitive material, photosensitive resin, UV adhesives etc., and this patent is preferred Be commodity UV-803 photocurings adhesive, UV-903 photocurings adhesive and UEV-2002UV803 photocurings adhesive, photosensitive Epoxy resin etc.；Described solvent is isobutyl acetate or hexahydrophthalic acid bisglycidyl ester or poly-（Methyl ethylene Ether/maleic acid）Half-ester copolymerization thing is poly-（Methyl vinyl ether/maleic anhydride）Half-ester copolymerization thing or double ((3,4- epoxy hexamethylenes Base) methyl) adipate ester or isobornyl methacrylate or isobornyl acrylate or essential oil or fluorous solvent or ionic liquid Or the mixed solvent that these solvents are formed.Described function carrier or functional material including but not limited to above-mentioned glass fibre, Polyester fiber, engineering plastics, various resistance to fibers, heat-stable ceramic, various functions material or additive, its usage amount are special according to material Property and protection using needing to be determined, the preferred usage amount of functional material and energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing protection material Material composite proportioning can be 1~1000:1000~1, it is more preferably 1~500:500~1, most preferably 1~100: 100~1.

The preparation method of energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing protective materials of the invention, is characterized in, including following Step.

A. knot gellan gum, hyaluronic acid and aeroge mixture are prepared, gellan gum, hyaluronic acid and aerogel powder is pressed Ratio is mixed after weighing with physical method, mixed including but not limited to air-flow crushing mixing, stirring mixing, ultrasonic wave mixing, grinding Conjunction, high-pressure homogenization etc., that is, obtain light compounds, and this mixture is preserved under low humidity airtight condition.

B. photosensitive aeroge mixture is prepared, the light compounds that step a is obtained glue with the photocuring that ratio is weighed Ground under the conditions of jelly, the function carrier of pretreatment or functional material, above-mentioned solvent lucifuge and homogenized, it is static to obtain photosensitive afterwards Aeroge mixture.

C. energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing protective materials, the photosensitive aeroge mixture obtained to step b are prepared Solidification dried process is carried out, the energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing protective materials of mould institute figuration shape, this material is obtained Can be coated or covered with different carriers or functional material by adhesive agent or refer and synthesize solidification drying.

The solidification drying method described in drying method c described in step c is high energy UV rapid curing Drying means or the slow solidifying and drying method of room temperature natural light, obtain the energy-storage thermal-insulating moistureproof guarantor of insulation cold-storage of mould institute figuration shape Wet protective materials or be coated or covered with or admix aeroge meet thing energy-storage thermal-insulating insulation cold-storage protection against the tide moisture-keeping functions material or Function carrier.

High energy UV rapid curing drying means or the slow solidifying and drying method of room temperature natural light are first by gellan gum Aeroge homogenised mix mixes and homogenizes with light-sensitive material, the functional material of pretreatment or function carrier material, solvent, Solvent is removed after photocuring reaction, and the aeroge energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing protection for obtaining mould institute figuration shape is multiple Condensation material or cladding aeroge meet the energy-storage thermal-insulating insulation cold-storage protection against the tide moisture-keeping functions material or carrier material of thing.This law is signified Carrier refer to that can carry the aeroge energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing protection glass of composite, glass plate, have Machine plastic products, woodwork, product, non-woven fabrics etc., signified functional material is main to refer to each Plant Extracts, essential oil, chemistry Auxiliary agent, thickener, adhesive, various nutrients, protein, fat, electrolyte, preservative etc..

Photocuring solvent is isobutyl acetate or hexahydrophthalic acid bisglycidyl ester or poly-（Methyl vinyl ether/ Maleic acid）Half-ester copolymerization thing is poly-（Methyl vinyl ether/maleic anhydride）Half-ester copolymerization thing or double ((3,4- epoxycyclohexyls) first Base) adipate ester or isobornyl methacrylate or isobornyl acrylate or essential oil or fluorous solvent or ionic liquid or these The mixed solvent that solvent is formed.

Because solvent is light-sensitive material reactive solvents or the solvent removed that easily heats up in photocuring drying process, due to boundary Face effect is small, typically will not produce influence to the structure of gel, can as needed adjust solvent total amount, with realize preferably into Type, it is coated or covered with.But various carrier materials or functional material are to aerogel-containing composite materials compatibility very different, so typically needing Surface preparation is carried out to carrier material or functional material.In photocuring drying process, the course of reaction of solvent has one Fixed surface tension, therefore the aerogel composite for obtaining shrinks larger, pore structure changes with quantity of solvent size, can be with root Solvent adjustment is carried out according to carrier material characteristic and functional material property, so that the energy-storage thermal-insulating insulation cold-storage that photocuring is dried to obtain Moistureproof moisturizing protective materials shrinks smaller, pore structure more fine uniform.Therefore, dried using high energy UV rapid curing It is the preferred technical solution of the present invention that method or the slow solidifying and drying method of room temperature natural light are dried treatment, if necessary high temperature Calcination can obtain resistant to elevated temperatures aerogel material.

Energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing protective materials of the invention, density is typically in the range of 0.005~2.3g/cm³, Thermal conductivity factor is less than 0.035w/（m·k）, with three-dimensional netted microcellular structure, material homogeneity is good, good moldability, can be applied to The exterior and interior packing of medical diagnosis on disease product and storage, transport product and protective articles, and it is applied to soil improvement, soil moisturizing, agriculture Medicine synergy, chemical fertilizer potentiating, pesticide action-controlling, space flight and aviation navigation, electronics, food, biology, medicine, chemical industry, the energy, environment, urge Change, optics, decoration, architectural engineering, sewage disposal, water purification, household purification, anti-fog haze cosmetics and skincare product, anti-fog haze baby The fields such as children article；Energy-storage thermal-insulating of the invention is incubated cold-storage protection against the tide moisturizing preparation method, and there is process is simple, raw material to be easy to get, Short preparation period, environmental protection safety the features such as, material has that low-density, corrosion-resistant, thermal conductivity factor be low, cold insulation effect Significantly, tension, compression strength it is high, it is hydrophobic good the features such as, be a kind of new environment-friendly and green material.It is coated or covered with through the material The function carrier or functional material for the treatment of have good heat-insulated, insulation, cold-storage, moisturizing, moistureproof and anti-fog haze, water lock characteristic, The performance of function carrier characteristic in itself and enhancing functional material, stability can be improved, scope and effective utilization is used.

Brief description of the drawings

Fig. 1 is raw material gellan gum effect of the present invention and characteristic list figure.

Fig. 2 is one, two, three structure and microstructure schematic diagram of hyaluronic acid.

Fig. 3 prepares aeroge multifunctional material basic flow sheet for the present invention.

Fig. 4 is " E " all-glass paper technical indicator list figure of the present invention.

Fig. 5 is material structure schematic diagram prepared by the embodiment of the present invention one.

Fig. 6 is the hydroscopic high-molecular resin technical indicator involved by the embodiment of the present invention two.

Fig. 7 is the chopped yarn technical target of the product of silica high involved by the embodiment of the present invention two.

Fig. 8 is the component table 1 involved by the embodiment of the present invention two.

Fig. 9 is that the aeroge blended materials material object described in the embodiment of the present invention two is not heat-treated figure.

Figure 10 is the heat-insulation and heat-preservation cold-storage moisturizing protective materials described in the embodiment of the present invention two（Aeroge multifunctional material） Molecular schematic diagram.

Figure 11 is the polymethyl vinyl ether/copolymer-maleic anhydride chemistry knot involved by embodiment of the present invention three Structure formula.

Figure 12 is that the polymethyl vinyl ether/copolymer-maleic anhydride technology involved by embodiment of the present invention three refers to Mark.

Figure 13 is the component table 2 involved by the embodiment of the present invention three.

Figure 14 is the hexahydrophthalic acid bisglycidyl ester specification involved by example IV of the present invention.

Figure 15 is poly- involved by example IV of the present invention（Methyl vinyl ether-maleic acid）Half-ester copolymerization thing skill Art index.

Figure 16 is the component table 3 involved by the embodiment of the present invention four.

Figure 17 is the hexahydrophthalic acid bisglycidyl ester structure formula involved by embodiment of the present invention five.

Figure 18 is the component table 4 involved by the embodiment of the present invention five.

Figure 19 is double ((3,4- epoxycyclohexyls) methyl) the adipate ester structural formulas involved by the embodiment of the present invention six.

Figure 20 is double ((3,4- epoxycyclohexyls) methyl) the adipate ester quality index involved by the embodiment of the present invention six.

Figure 21 is the PVPP chemical structural formula involved by the embodiment of the present invention six.

Figure 22 is the PVPP specification involved by the embodiment of the present invention six.

Figure 23 is the copolyvidone chemical structural formula involved by the embodiment of the present invention six.

Figure 24 is the copolyvidone specification involved by the embodiment of the present invention six.

Figure 25 is the component table 5 involved by the embodiment of the present invention six.

Figure 26 is the component table 6 involved by the embodiment of the present invention seven.

Specific embodiment

The present invention is further elaborated by the following examples.But the invention is not limited in this, the specialty in the field Technical staff, engineer can make some nonessential modifications and adaptations with the above of the invention to the present invention, can be with The present invention is realized by reference to the method different from specific examples below.

Operating method used in following embodiments unless otherwise specified, be traditional medicine, farming animals herd, electronics, change The conventional method of work, food, cosmetics, building, decoration, reagent article, biological products and functional material preparation field.

Various carrier materials used in following embodiments, functional material, chemical reagent, additive, various auxiliary agents etc., Unless otherwise specified, commercially obtain.

Embodiment one.

As shown in Figure 3.

Step a is first pressed, further according to needs and step b, step c combination operations, energy-storage thermal-insulating insulation cold-storage protection against the tide is prepared and is protected The basic step of wet protective materials is as follows.

Step a11, from commercially available high acyl gellan gum product, the commercial goods for obtaining is extracted by microculture.It is commercially available Silica aerogel powder, by the one kind in tetraethyl orthosilicate, methyl silicate, Ludox, silicate, siloxanes, silicon ether Or prepared by several mixed solutions.The present embodiment, from commodity dioxy prepared by the mixed solution of Ludox and tetraethyl orthosilicate SiClx aerogel powder.The hyaluronic acid that this example is selected is high molecular weight sodium hyaluronate, is extracted by microculture and obtained Commercial goods.

Step a12, weighs the quality that high acyl gellan gum and high molecular weight sodium hyaluronate respectively account for mass percent total amount The 0.0001%~19.0% of percentage total amount, relatively optimization is 0.003%~10.0%, and optimization is 0.005%~0.3%；Again 0.04~99.5% silica aerogel powder for accounting for mass percent total amount is weighed, relatively optimization is 0.2%~97.5%, most Optimization is 0.4%~90.5%, and room temperature is closed after mixing saves backup.

Step a13, the ball milling instrument with cooling function is added by mixture described in a12, is ground with zirconium oxide bead and homogenized, Form gellan gum, hyaluronic acid and aeroge mixture；

Step a21, from commercially available UV-803 photocurings adhesive, methacrylic acid norbornene ester, UV-803 photocurings therein glue Jelly is moderately viscous photocuring adhesive, and methacrylic acid norbornene ester purity is more than 99.5%.

Step a22, weighs UV-803 photocurings adhesive and methacrylic acid norbornene ester respectively accounts for mass percent total amount 0.5%~99.0%, the mixed proportion of the two is 1~100:1~100, relatively the 1~50 of optimization:1~50, optimization for 1~ 10:1~10, this example selects ratio between two 4:1 mixing, the closed room temperature of this mixture or Cord blood are standby.

Step a31, respectively from roofing and waterproof roll glass fibre mat, fiberglass surfacing mat, lead acid storage battery Pond dividing plate glass mat, printed board " E " all-glass paper, glass fiber facing felt commodity.

" E " all-glass paper technical indicator（Fig. 4）.

What this example implemented selection is EMP-105-127 " E " all-glass papers as bottom, EMP-50-1270E " glass Fibrous paper makees surface layer.

Step a32 is by EMP-105-127 " E " all-glass papers and EMP-50-1270E " all-glass paper is cut into 120cm × 90cm sizes are standby.

Step a33, weighs triton x-100 accounts for mass percent total amount 0.005%~11.0%, and relatively optimization is 0.025%~3.0%, optimization is 0.05%~0.3%；2,4,7,9- tetramethyl -5- decine -4 are weighed again, and 7- glycol accounts for quality The 0.005%~11.0% of percentage total amount, relatively optimization is 0.025%~3.0%, and optimization is 0.05%~0.3%；The two is mixed After being dissolved with 95% ethanol after conjunction, EMP-105-127 " E " all-glass papers and EMP-50-1270E prepared by step a32 " glass Glass fibrous paper is soaked in wherein, drying for standby after infiltration, and this dry product room temperature cool place sealing preserve can be stablized the several years.

Step b11, after step a13 and step a22 prepared products are mixed, in ball milling instrument of the addition with cooling function, Ground with zirconium oxide bead under the conditions of lucifuge and homogenized, form gellan gum, hyaluronic acid, aeroge, photocuring adhesive and solvent Homogenised mix is standby, and this mixture should avoid high temperature and illumination, obtains energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing protection material Material.

Step c11, EMP-105-1270 " E " all-glass paper that step a33 is obtained is put into and adjusts parameter coating machine In, the mixture prepared with step b11 even spread on glass under the conditions of lucifuge, coating thickness control 0.075~ 6.0mm, covers EMP-50-1270 " E " all-glass paper again after the completion of coating.

Step c12, EMP-105-127 " E " all-glass papers and EMP-50-1270E that step c11 is obtained " glass fibers Dimension paper high energy ultraviolet irradiates solidification drying, obtains energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing water lock material coating glass fiber paper, The paper can be used for the manufacture of the package packing supplies such as diagnostic reagent, medicine, food, cosmetics, can play heat-insulated, guarantor to these articles Temperature, cold-storage, protection against the tide, water lock effect.

Fig. 5 illustrates the material structure schematic diagram of the preparation of embodiment one.

Embodiment two.

As shown in figure 3, first pressing step a, further according to needs and step b, step c combination operations, energy-storage thermal-insulating insulation is prepared The basic step of cold-storage protection against the tide moisturizing water lock material is as follows.

Step a11, from commercially available low-acyl gellan gum product, the commercial goods for obtaining is extracted by microculture.It is commercially available Silica aerogel powder, by the one kind in tetraethyl orthosilicate, methyl silicate, Ludox, silicate, siloxanes, silicon ether Or prepared by several mixed solutions.The present embodiment, from commodity dioxy prepared by the mixed solution of Ludox and tetraethyl orthosilicate SiClx aerogel powder.The hyaluronic acid that this example is selected is the Sodium Hyaluronate of special affinity, is extracted by microculture The commercial goods of acquisition.

Step a12, the Sodium Hyaluronate for weighing low-acyl gellan gum and special affinity respectively accounts for mass percent total amount The 0.0001%~19.0% of mass percent total amount, relatively optimization is 0.003%~10.0%, optimization for 0.005%~ 0.3%；Weigh 0.005~99.5% silica aerogel powder for accounting for mass percent total amount again, relatively optimization for 0.01%~ 96.5%, optimization is 0.05%~91.5%, and room temperature is closed after mixing saves backup.

Step a13, adds airslide disintegrating mill to crush in mixture described in a12, is homogenized by air-flow crushing, forms knot cold Glue, hyaluronic acid and aeroge mixture.

Step a21, from commercially available UV-903 photocurings adhesive, isobornyl acrylate, UV-903 photocurings therein Adhesive is the high viscosity commodity photocuring adhesive of customization, and isobornyl acrylate purity is more than 99.5%.

Step a22, weighs UV-903 photocurings adhesive and isobornyl acrylate and respectively accounts for mass percent total amount 0.05%~90.0%, the mixed proportion of the two is 1~100:1~100, relatively the 1~50 of optimization:1~50, optimization for 1~ 10:1~10, this example selects ratio between two 2:1 mixing, the closed room temperature of this mixture or Cord blood are standby.

Step a31, from commodity silica high chopped yarn, hydroscopic high-molecular resin, dodecyldimethylamine base glycine betaine, 14 Alkyl dimethyl betaine, eucalyptus oil, menthol, jasmine oil, tea oil.

Hydroscopic high-molecular resin technical indicator（Fig. 6）.

What this example implemented selection is that hydroscopic high-molecular resin is KL-6Ha and KL-3Ha.

The chopped yarn technical target of the product of silica high（Fig. 7）.

Step a32 is that KL-6Ha hydroscopic high-molecular resins, KL-3Ha hydroscopic high-molecular resins, dodecyldimethylamine base is sweet Dish alkali, eucalyptus oil, peppermint oil, jasmine oil, tea oil, sweet benevolence oil weigh mixing for standby use by the mass percent of component table 1.

Component table 1（Fig. 8）.

Step a33, with grinder by step a32 prepared products, 400 revs/min, grinds 60 minutes, standby after homogenizing, this Homogeneous thing room temperature cool place sealing preserve can be stablized the several years.

Step b11, after step a13 and step a22 prepared products are mixed, in ball milling instrument of the addition with cooling function, Ground with zirconium oxide bead under the conditions of lucifuge and homogenized, form gellan gum, hyaluronic acid, aeroge, photocuring adhesive and solvent Homogenised mix is standby, and this mixture should avoid high temperature and illumination, obtain energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, Protection aeroge multifunctional material.

Aeroge blended materials material object is not heat-treated figure（Fig. 9）.

Step c11, the mixture that the hydroscopic high-molecular resin uniform homogeneous blend that step a33 is obtained is prepared with step b11 By 1~1000:1000~1, more preferably by 1~500:500~1, most preferably by 1~100:100~1, this example presses 8: 2, after mixing in grinder under the conditions of lucifuge, mould molding or directly carry out follow-up process step that addition is selected.

Step c12, obtains step c11 hydroscopic high-molecular resin article shaped or homogeneous thing high energy ultraviolet and irradiates solidification Dry, energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, the protection multi-functional material of aeroge are obtained after the demoulding or the dispersion that homogenizes Material, the material can be used for the packed and transporteds such as decoration new liquid wallpaper, diagnostic reagent, medicine, food, cosmetics efficiently storage Freezing ice bag, cold-storage filler, the manufacture of high temperature resistant heat insulation product, can play to the heat-insulated of these articles, insulation, cold-storage, protection against the tide, water suction Effect, it can also be used to household sopping rag, high-grade urine pants urine patch, agricultural water-absorbing water-retaining agent, efficient deoxidation drying agent, warm warming patch Poultry thermit powder, soil moisturizing, fertilizer additive（The special water-loss reducer of chemical fertilizer, fertilizer synergistic agent, chemical fertilizer delay controlled-release of additives）, plastics protect Warm product filler, cold chain accumulation of energy agent, formaldehyde absorbing remove articles for use, water suction foam, hydrogel Medical cold application, functional formization pillow It is prepared by core, crystal mask, environmentally friendly haze dust suppressant, liquid wallpaper, controlled release washing ball, toilet deodorant agent, anti-fog haze product etc..

Heat-insulation and heat-preservation cold-storage moisturizing protective materials molecular schematic diagram（Figure 10）.

Embodiment three.

As shown in figure 3, first pressing step a, further according to needs and step b, step c combination operations, energy-storage thermal-insulating insulation is prepared The basic step of cold-storage protection against the tide moisturizing water lock material is as follows：

Step a11, from commercially available high acyl gellan gum product, the commercial goods for obtaining is extracted by microculture.Commercially available dioxy SiClx aerogel powder, by the one kind or several in tetraethyl orthosilicate, methyl silicate, Ludox, silicate, siloxanes, silicon ether It is prepared by the mixed solution planted.The present embodiment, from commodity silica prepared by the mixed solution of Ludox and tetraethyl orthosilicate Aerogel powder.The hyaluronic acid that this example is selected is hyaluronic acid elastomer（Hyacross）, extracted by microculture and obtained The commercial goods for obtaining, Hyacross is NMF hyaluronic acid（HA）To the new product that super high molecular weight develops, skin sense Soft and smooth and high resilience.Hyacross is fine and close 3 D stereo network structure, and energy uniform fold forms one layer in skin surface Breathable films, can strengthen skin barrier function, reduce the evaporation of skin internal moisture, while resisting ultraviolet, dust, haze etc. Invasion and attack of the external environment to skin.Additionally, Hyacross has more preferable hyaluronidase tolerance, compared with common HA, Hyacross is more stable in the diaphragm that skin surface is formed, and acts on more longlasting.Hyacross has super high molecular weight, HA molecules Local height aggregation is folded, and can combine more hydrones, is formed " miniature tank ", continues Glycerin, result of the test card Bright Hyacross has the superpower moisture-retaining capacities of 24h.Clinical test finds to be represented more than the Hyacross frost triers of half, and right Compared according to group, significantly, skin more moistens smooth, high resilience to Hyacross skin care effects.Hyacross moisturizings, one step of protection In place, it is adaptable to the exploitation of type products such as moisturizing, anti-aging, anti-haze antipollution and use.

Step a12, weighing the Sodium Hyaluronate oligosaccharides of high acyl gellan gum and special affinity, respectively to account for mass percent total The 0.0001%~19.0% of the mass percent total amount of amount, relatively optimization is 0.003%~10.0%, optimization for 0.005%~ 0.3%；Weigh 0.005~99.5% silica aerogel powder for accounting for mass percent total amount again, relatively optimization for 0.01%~ 96.5%, optimization is 0.05%~91.5%, and room temperature is closed after mixing saves backup.

Step a13, crushes during mixture described in a12 is added into medicinal herb grinder, is homogenized by zirconia media, is formed Gellan gum, hyaluronic acid and aeroge mixture.

Step a21, from commercially available UVE-2002 photocurings adhesive, grape-kernel oil, UVE-2002 photocurings therein glue Jelly is the low viscosity commodity photocuring adhesive of customization.

Step a22, weigh UVE-2002 photocurings adhesive and grape-kernel oil respectively account for mass percent total amount 0.05%~ 90.0%, the mixed proportion of the two is 1~100:1~100, relatively the 1~50 of optimization:1~50, optimization is 1~10:1~ 10, this example selects ratio between two 8:1 mixing, the closed room temperature of this mixture or Cord blood are standby.

Step a31, from commodity polymethyl vinyl ether/copolymer-maleic anhydride, Seabuckthorn Oil, polyvinylpyrrolidone K90, PVP K30, HP-β-CD, eucalyptus oil, menthol, 90%UV tribulus terrestris are oily, withania somnifera is oily, Wilsonii oil, hippophae rhamnoides, rose hip oil, purple potato extract, jasmine oil, peppermint oil, 10%HPLC tomato extracts, 35% UV ivies extract, 26%HPLC licorices, 3', 4', 5,7- kaempferol（Cyanidenon）, bergamot oil, ocean it is sweet Elecampane oil, tremella polysaccharides, 40% Fructus lycii P.E（LBP-X）, serotonine acid, 0.3% Hypericum Perforatum P.E（Spun gold Peach element）, 5% UV passionflower oils, garlic oil, lavender oil, attar of rose, pelargonium oil, Angelica oil, 10:1 Semen Sesami Nigrum extract, Agate card oil, 5:1 Herba Cynomorii extract, tea oil, Sweet Almond Oil, lemon oil, aloe, azone, rosemary oil, sandalwood oil, Europe are thin Lotus oil；Polymethyl vinyl ether therein/copolymer-maleic anhydride technical indicator is as follows.

First, name of product：Polymethyl vinyl ether/copolymer-maleic anhydride.

2nd, chemical descriptor：The alternate copolymer of methyl vinyl ether and maleic anhydride.

3rd, CAS №：9011-16-9.

4th, polymethyl vinyl ether/copolymer-maleic anhydride chemical structural formula（Figure 11）.

5th, main character：Water insoluble, aliphatic hydrocarbon and halogenated hydrocarbons etc., are dissolved in esters etc.；It is slow in water under felicity condition It is slow that hydrolysis generation diacid occurs, form sticking clear solution；There is esterification in alcohol and produce half ester product.

6th, purposes：Can based on polymer prepare biological denture adhesives.It is alternatively arranged as sealant, fixative and anti- Agent is answered to use.

7th, polymethyl vinyl ether/copolymer-maleic anhydride technical indicator（Figure 12）, what this example implemented selection is poly- first Base vinyl ether/maleic anhydride copolymer is AP250.

Step a32 is that the functional material for selecting a31 weighs mixing for standby use by the mass percent of component table 2.

Component table 2（Figure 13）.

Step a33, with grinder by step a32-1 prepared products and a32-2 prepared products, 600 revs/min, grinds 30 minutes, A32-1 prepared products are slowly added in a32-2 prepared products, side edged homogenizes, continue to mix the two after adding and homogenize 15 After minute, polymeric PTC materials mixture is obtained, this homogeneous thing room temperature cool place sealing preserve can be stablized the several years.

Step b11, after step a13 and step a22 prepared products are mixed, in ball milling instrument of the addition with cooling function, Ground with zirconium oxide bead under the conditions of lucifuge and homogenized, form gellan gum, hyaluronic acid, aeroge, photocuring adhesive and solvent Homogenised mix is standby, and this mixture should avoid high temperature and illumination, obtains energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing mixing material Material.

Step c11, the aeroge that the polymeric PTC materials uniform homogeneous blend that step a33 is obtained is prepared with step b11 is mixed Thing presses 1~1000:1000~1, more preferably by 1~500:500~1, most preferably by 1~100:100~1, this example is pressed 1:5, after mixing in grinder under the conditions of lucifuge, mould molding or directly carry out follow-up process step that addition is selected.

Step c12, obtains step c11 article shaped or homogeneous thing high energy ultraviolet and irradiates solidification drying, the demoulding or equal Energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protection aeroge multifunctional material cladding or doping are obtained after matterization dispersion Functional material, the functional material can be used for haze function mouth mask, home air purification, the net taste of toilet deodorization, the net taste of toilet, anti- Worm mosquito repellent, stacte, burn incense, refrigerator eliminates the unusual smell, function pillow, formaldehyde absorbing remove articles for use, wardrobe eliminate the unusual smell, it is the net taste of automobile, anti- The exploitations of controlled release type products such as aging, anti-haze antipollution and use, material has safety, environmental protection, stabilization, there is certain Enhancing Abwehrkraft des Koepers, fatigue-relieving, diseases prevention is degerming, eliminate the unusual smell, anti-haze antipollution, anti-aging the characteristics of.

Example IV.

As shown in figure 3, first pressing step a, further according to needs and step b, step c combination operations, energy-storage thermal-insulating insulation is prepared The basic step of cold-storage protection against the tide moisturizing water lock material is as follows.

Step a11, from commercially available low-acyl gellan gum product, the commercial goods for obtaining is extracted by microculture.It is commercially available Silica aerogel powder, by the one kind in tetraethyl orthosilicate, methyl silicate, Ludox, silicate, siloxanes, silicon ether Or prepared by several mixed solutions.The present embodiment, from Ludox：Silicate 1：1 mixture is molten with the mixing of tetraethyl orthosilicate Commodity silica aerogel powder prepared by liquid.The hyaluronic acid that this example is selected is Sodium Hyaluronate oligosaccharides（Sodium Hyaluronate oligosaccharides, abbreviation o-HA）, the commercial goods for obtaining, the product are extracted by microculture Relative molecular mass<10⁴KDa, monosaccharide residue quantity are 2~40（Generally 4~16）HA molecule fragments.O-HA belongs to small point Sub- polysaccharide, its property is very different with common HA, with Angiogensis, promotes wound healing, antitumor and immunological regulation Etc. bioactivity.

Step a12, weighs low-acyl gellan gum and Sodium Hyaluronate oligosaccharides respectively accounts for the quality percentage of mass percent total amount Than the 0.0001%~19.0% of total amount, relatively optimization is 0.003%~10.0%, and optimization is 0.005%~0.3%；Weigh again 0.005~99.5% silica aerogel powder of mass percent total amount is accounted for, relatively optimization is 0.01%~96.5%, optimal What is changed is 0.05%~91.5%, and room temperature is closed after mixing saves backup.

Step a13, by mixture addition grinder described in a12, is homogenized by zirconia media, formation gellan gum, Hyaluronic acid and aeroge mixture.

Step a21, this example light curing agent is selected commercially available hexahydrophthalic acid bisglycidyl ester, is gathered（Methyl second Alkene ether/maleic acid）Half-ester copolymerization thing and double ((3,4- epoxycyclohexyls) methyl) adipate esters 1:1:1 mixture.It is therein Hexahydrophthalic acid bisglycidyl ester technical indicator is as follows.

First, name of product：Hexahydrophthalic acid bisglycidyl ester

English name：Diglycidyl 1,2-cyclohexanedicarboxylate .

2nd, CAS NO.:5493-45-8.

3rd, molecular formula： C14H20O6

Molecular weight：284.3

4th, purposes：It is mainly used in coating, composite, bonding agent, electron trade etc..

5th, property

Boiling point： 200-205 °C2 mm Hg(lit.)

Density： 1.22 g/mL at 25 °C(lit.)

Refractive index n20/D：1.487(lit.)

Flash-point：>110℃.

6th, product introduction：This product has saturated structures, and weatherability is outstanding, and finished product will not ftracture or xanthochromia, electrically decomposes When produce carbon dioxide and water, rather than aromatic resin produce graphite cause short circuit,

The big good toughness of solidfied material crosslink density, UV resistant and arc resistance are good, and heat endurance is good, 82-108 DEG C of Martin heat resistance, Tensile strength 75.5-83.7, bending strength 147-170.

Viscosity is low, good fluidity, can lack during processing with or without organic solvent, and chlorinty is low, is particularly suitable for electric Performance requirement insulating materials high, high-temperature insulating quality is good, and the resistance to electric leakage trace of arc resistance is strong.

Thermal curable, also photocurable, quick solidifying, cure shrinkage is low, and solidfied material crosslink density is big, 200 °C of Tg ＞.

LED encapsulation is mainly used in, insulation encapsulated, die casting, metal surface is cohered, and adhesive, composite, light is solid Carburetion ink and coating etc..

7th, hexahydrophthalic acid bisglycidyl ester specification（Figure 14）.

Step a22, weighs hexahydrophthalic acid bisglycidyl ester, gathers（Methyl vinyl ether/maleic acid）Half ester is total to Polymers and double ((3,4- epoxycyclohexyls) methyl) adipate esters 1:1:1 mixture account for mass percent total amount 0.001%~ 90.0%, relatively optimization 0.005%~90.0%, optimization is 0.05%~19.0%, and the closed room temperature of this mixture or Cord blood are standby With.

Step a31, it is poly- from commodity（Methyl vinyl ether/maleic acid）Half-ester copolymerization thing, Seabuckthorn Oil, polyvinylpyrrolidine Ketone K30, polyvinylpyrrolidone K15, HP-β-CD, eucalyptus oil, menthol, 90%UV tribulus terrestris oil, withania somnifera Oil, wilsonii oil, hippophae rhamnoides, rose hip oil, purple potato extract, jasmine oil, peppermint oil, 10%HPLC tomato extracts, 35%UV ivies extract, 26%HPLC licorices, 3', 4', 5,7- kaempferol（Cyanidenon）, bergamot oil, Oil of chamomile, tremella polysaccharides, 40% Fructus lycii P.E（LBP-X）, serotonine acid, 0.3% Hypericum Perforatum P.E （Hypericin）, 5% UV passionflower oils, garlic oil, lavender oil, attar of rose, pelargonium oil, Angelica oil, 10:1 Semen sesami nigrum carries Take thing, agate card oil, 5:1 Herba Cynomorii extract, tea oil, Sweet Almond Oil, lemon oil, aloe, azone, rosemary oil, sandalwood oil, Oleum menthae piperitae；It is therein poly-（Methyl vinyl ether/maleic acid）Half-ester copolymerization thing technical indicator is as follows.

First, name of product：It is poly-（Methyl vinyl ether/maleic acid）Half-ester copolymerization thing.

2nd, chemical descriptor：The hemiester product that methyl vinyl ether and maleic anhydride alternate copolymer are formed with alcohol esterification.

3rd, main character：Transparent sticking liquid, the cohesive with high intensity.

4th, purposes：In aerosol and pump type setting agent, gel, mousse, moulding emulsion/face cream, moulding spray（Non- gas Solution）Used with fashion series of products.

5th, gather（Methyl vinyl ether-maleic acid）Half-ester copolymerization thing technical indicator（Figure 15）, this example implement select be It is poly-（Methyl vinyl ether/maleic acid）Half-ester copolymerization thing is EP225.

Step a32 is that the functional material for selecting a31 weighs mixing for standby use by the mass percent of component table 3.

Figure 16 component tables 3.

Step a33, with grinder by step a32-1 prepared products and a32-2 prepared products, 600 revs/min, grinds 30 minutes, A32-1 prepared products are slowly added in a32-2 prepared products, side edged homogenizes, continue to mix the two after adding and homogenize 15 After minute, polymeric PTC materials mixture is obtained, this homogeneous thing room temperature cool place sealing preserve can be stablized the several years.

Step b11, after step a13 and step a22 prepared products are mixed, in ball milling instrument of the addition with cooling function, Ground with zirconium oxide bead under the conditions of lucifuge and homogenized, form gellan gum, hyaluronic acid, aeroge, photocuring adhesive and solvent Homogenised mix is standby, and this mixture should avoid high temperature and illumination, obtains energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing mixing material Material.

Step c11, the aeroge that the polymeric PTC materials uniform homogeneous blend that step a33 is obtained is prepared with step b11 is mixed Thing presses 1~1000:1000~1, more preferably by 1~500:500~1, most preferably by 1~100:100~1, this example is pressed 1:8, after mixing in grinder under the conditions of lucifuge, mould molding or directly carry out follow-up process step that addition is selected.

Step c12, obtains step c11 article shaped or homogeneous thing high energy ultraviolet and irradiates solidification drying, the demoulding or equal Energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protection aeroge multifunctional material cladding or doping are obtained after matterization dispersion Functional material, the functional material can be used for decoration new liquid wallpaper, haze function mouth mask, home air purification, lavatory Deodorant net taste, the net taste of toilet, Vermins-proof and mosquito-driving, stacte, burn incense, refrigerator eliminates the unusual smell, function pillow, formaldehyde absorbing remove articles for use, clothing Cabinet eliminates the unusual smell, the net taste of automobile, anti-fog haze, anti-ageing controlled release product of waiting for a long time, material has safety, environmental protection, stabilization, there is certain increasing Strong Abwehrkraft des Koepers, fatigue-relieving, diseases prevention is degerming, the characteristics of eliminate the unusual smell.

Embodiment five

As shown in figure 3, first pressing step a, further according to needs and step b, step c combination operations, energy-storage thermal-insulating insulation cold-storage is prepared The basic step of moistureproof moisturizing water lock material is as follows.

Step a11, from commercially available low-acyl gellan gum product, the commercial goods for obtaining is extracted by microculture.It is commercially available Silica aerogel powder or silica flatting silica, hexahydrophthalic acid bisglycidyl ester or poly-（Methyl ethylene Ether/maleic acid）Half-ester copolymerization thing or double ((3,4- epoxycyclohexyls) methyl) adipate esters or their 1:1:1 mixture, silicon It is prepared by the mixed solution of one or more in colloidal sol, silicate, siloxanes, silicon ether.The present embodiment, from Ludox：Dioxy SiClx flatting silica 1：It is 1 mixture and hexahydrophthalic acid bisglycidyl ester, poly-（Methyl vinyl ether/maleic acid）Half ester is total to Polymers and double ((3,4- epoxycyclohexyls) methyl) adipate esters 1:1:1 mixture prepares silica aerogel powder.This reality The hyaluronic acid that example is selected is low molecular weight sodium hyaluronate, and the commercial goods for obtaining, the product phase are extracted by microculture It is 10 kDa~1,000 kDa to molecular weight.

Step a12, weighs the quality that low-acyl gellan gum and low molecular weight sodium hyaluronate respectively account for mass percent total amount The 0.0001%~19.0% of percentage total amount, relatively optimization is 0.003%~10.0%, and optimization is 0.005%~0.3%；Again 0.005~99.5% silica aerogel powder for accounting for mass percent total amount is weighed, relatively optimization is 0.01%~96.5%, What is optimized is 0.05%~91.5%, and room temperature is closed after mixing saves backup.

Step a13, by mixture addition grinder described in a12, is homogenized by zirconia media, formation gellan gum, Hyaluronic acid and aeroge mixture.

Step a21, this example light curing agent selects commercially available hexahydrophthalic acid bisglycidyl ester and double ((3,4- Epoxycyclohexyl) methyl) adipate ester 1:1 mixture.Hexahydrophthalic acid bisglycidyl ester technical indicator therein is such as Under.

First, name of product：Hexahydrophthalic acid bisglycidyl ester

English name：Diglycidyl 1,2-cyclohexanedicarboxylate bis-, CAS NO.:5493-45-8.

2nd, hexahydrophthalic acid bisglycidyl ester structure formula（Figure 17）.

3rd, molecular formula：C14H20O6

Molecular weight：284.3

5th, purposes：It is mainly used in coating, composite, bonding agent, electron trade etc..

6th, property

Boiling point： 200-205 °C 2mm Hg(lit.)

Density： 1.22 g/mL at 25 °C(lit.)

Refractive index n20/D：1.487(lit.)

Flash-point：>110℃.

7th, product introduction：This product has saturated structures, and weatherability is outstanding, and finished product will not ftracture or xanthochromia, electrically decomposes When produce carbon dioxide and water, rather than aromatic resin produce graphite cause short circuit,

The big good toughness of solidfied material crosslink density, UV resistant and arc resistance are good, and heat endurance is good, 82-108 DEG C of Martin heat resistance, Tensile strength 75.5-83.7, bending strength 147-170.

Viscosity is low, good fluidity, can lack during processing with or without organic solvent, and chlorinty is low, is particularly suitable for electric Performance requirement insulating materials high, high-temperature insulating quality is good, and the resistance to electric leakage trace of arc resistance is strong.

Thermal curable, also photocurable, quick solidifying, cure shrinkage is low, and solidfied material crosslink density is big, 200 °C of Tg ＞.

LED encapsulation is mainly used in, insulation encapsulated, die casting, metal surface is cohered, and adhesive, composite, light is solid Carburetion ink and coating etc..

8th, hexahydrophthalic acid bisglycidyl ester specification（Figure 14）.

Step a22, weigh hexahydrophthalic acid bisglycidyl ester and double ((3,4- epoxycyclohexyl) methyl) oneself two Acid esters 1:1 mixture accounts for the 0.001%~90.0% of mass percent total amount, relatively optimization 0.005%~80.0%, and optimization is 0.05%~19.0%, the closed room temperature of this mixture or Cord blood are standby.

Step a31, from commerical hydroxypropylmethyl cellulose, gum arabic, polyvinylpyrrolidone K17, tween- 20th, 2,4,7,9- tetramethyl -5- decine -4, it is 7- glycol, trimethyl amine oxide, double（Methylol）Imidazolidinyl urea, myristyl Dimethyl betaine, iodine propilolic alcohol butyl mephenesin Carbamate, xanthans, albumin.The albumin of this example choosing is paddy rice expression Human serum albumins.

Step a32 is that the functional material for selecting a31 weighs mixing for standby use by the mass percent of component table 4.

Component table 4（Figure 18）.

Step a33, with grinder by step a32 prepared products, 600 revs/min, grinds 30 minutes, obtains macromolecule blending Mixture, this homogeneous thing room temperature cool place sealing preserve can be stablized the several years.

Step b11, after step a13 and step a22 prepared products are mixed, in ball milling instrument of the addition with cooling function, Ground with zirconium oxide bead under the conditions of lucifuge and homogenized, form gellan gum, hyaluronic acid, aeroge, photocuring adhesive and solvent Homogenised mix is standby, and this mixture should avoid high temperature and illumination, obtains energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing mixing material Material.

Step c11, aeroge mixture prepared by macromolecule blending mixture and the step b11 that step a33 is obtained presses 1 ~1000:1000~1, more preferably by 1~500:500~1, most preferably by 1~100:100~1, this example presses 1:5, After mixing in grinder under the conditions of lucifuge, mould molding or directly carry out follow-up process step that addition is selected.

Step c12, obtains step c11 article shaped or homogeneous thing high energy ultraviolet and irradiates solidification drying, the demoulding or equal Obtained after matterization dispersion aeroge energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protection aeroge multifunctional material coat or The functional material of doping, the functional material is used mainly as instant external diagnosis reagent sealer, preservative, stabilizer, With to antigen, antibody, activated protein（Such as enzyme）, unstable small-molecule substance, plasma proteins etc. make with good stabilization With；And there is fabulous suspension stability and sealing process to in-vitro diagnosis sensitizing latex；The material is alternatively arranged as in-vitro diagnosis Reagent sample pad, ELISA Plate, luminescence-producing reaction plate, the pretreatment of marking articles for use, glass pretreatment, strengthen their hydrophily and reduction Non-specific adsorption.The material is also recommended for anti-fog haze cosmetics, skin care and hair shampoo article etc., and material has safety, green Environmental protection, stabilization, the characteristics of with water lock, fungi-proofing, moisturizing.

Embodiment six.

As shown in figure 3, first pressing step a, further according to needs and step b, step c combination operations, energy-storage thermal-insulating insulation is prepared The basic step of cold-storage protection against the tide moisturizing water lock material is as follows.

Step a11, from commercially available high acyl gellan gum product, the commercial goods for obtaining is extracted by microculture；Dioxy SiClx aerogel powder, by hexahydrophthalic acid bisglycidyl ester with it is poly-（Methyl vinyl ether/maleic acid）Half-ester copolymerization Thing or their 1:It is prepared by 1 mixture, the mixed solution of one or more in Ludox, silicate, siloxanes, silicon ether, this Embodiment, from Ludox：Silica flatting silica 3：1 mixture and hexahydrophthalic acid bisglycidyl ester with it is poly-（First Base vinyl ethers/maleic acid）Half-ester copolymerization thing 1:1 mixture prepares silica aerogel powder；It is transparent that this example is selected Matter acid is acetylation Sodium Hyaluronate, and the commercial goods for obtaining are extracted by microculture.

Step a12, weighs low-acyl gellan gum and the extra small numerator sodium hyaluronate of high activity respectively accounts for mass percent total amount Mass percent total amount 0.0001%~19.0%, relatively optimization is 0.003%~10.0%, optimization for 0.005%~ 0.3%；Weigh 0.005~99.5% silica aerogel powder for accounting for mass percent total amount again, relatively optimization for 0.01%~ 96.5%, optimization is 0.05%~91.5%, and room temperature is closed after mixing saves backup.

Step a13, by mixture addition grinder described in a12, is homogenized by zirconia media, formation gellan gum, Hyaluronic acid and aeroge mixture.

Step a21, this example light curing agent selects commercially available UV-803 photocurings adhesive and double ((3,4- epoxy hexamethylenes Base) methyl) adipate ester 1:1 mixture.Double ((3,4- epoxycyclohexyls) methyl) adipate ester technical indicators therein are as follows.

First, name of product：Double ((3,4- epoxycyclohexyls) methyl) adipate esters

Alias：Double (7- oxabicyclos [4,1,0] 3- methyl in heptan) adipate esters

English name：bis[(3,4-epoxycyclohexyl)methyl]adipate.

2nd, CAS NO.: 3130-19-6.

3rd, double ((3,4- epoxycyclohexyls) methyl) adipate ester structural formulas（Figure 19）.

4th, molecular formula：C20H30O6, molecular weight：366.45.

5th, purposes：Special epoxy resin, cycloaliphatic epoxy resin.

6th, property：

Density： 1.149 g/mL at 25 °C(lit.)

Refractive index n20/D： 1.493(lit.)

Flash-point：>110 ℃.

7th, double ((3,4- epoxycyclohexyls) methyl) adipate ester quality index（Figure 20）.

8th, performance characteristics：This product viscosity is low, good fluidity, can lack with or without organic solvent during processing.Saturation knot Structure, weatherability is outstanding, and finished product will not ftracture or xanthochromia, carbon dioxide and water is produced when electrically decomposing, rather than fragrant family tree Fat produces graphite to cause short circuit.Chlorinty is low, is particularly suitable for the insulating materials high to electrical performance demands, and high-temperature insulating quality is good, The resistance to electric leakage trace of arc resistance is strong.Thermal curable, also photocurable, quick solidifying, cure shrinkage are low.Solidfied material crosslink density Greatly, with excellent pliability.Heat endurance is good, and Tg is higher than 200 degrees Celsius.

Step a22, weighs UV-803 photocurings adhesive with double ((3,4- epoxycyclohexyl) methyl) adipate esters 1:1 mixes Compound accounts for the 0.001%~90.0% of mass percent total amount, relatively optimization 0.005%~80.0%, optimization for 0.05%~ 19.0%, the closed room temperature of this mixture or Cord blood are standby.

Step a31, from commodity acetylation Sodium Hyaluronate, polyvinylpyrrolidone K60,2,4,7,9- tetramethyl -5- Decine -4,7- glycol, copolyvidone, PVPP.PVPP therein and copolyvidone performance indications are as follows.

First, PVPP performance indications

Name of product：PVPP

Pharmacopeia title：PVPP

Chemical name:PVPP, PVPP, Crospovidone

INCI/CTFA:Insoluble PVP

CAS:9003-39-8,25249-54-1.

PVPP chemical structural formula（Figure 21）.

Product performance：White or micro-yellow powder, without special odor, the conventional organic solvent such as water insoluble, sour, alkali.But There is very strong swelliong power not produce gel-like substance, and energy and polypeptide, hydroxy acid and other low molecule quantizations and thing in water Complexing.PVPP is the first-selected disintegrant of high-grade tablet medicine, is particularly well-suited to instant, the formula of chewing class medicine.

Purposes：In view of PVPP is water insoluble and other solvents and meets the characteristic of water expansion rapidly, in pharmaceuticals industry, It is widely used in：1）Disintegrant, 2）Suspension stabilizer, 3）Moisture absorber, 4）In plant extracts or plant-based medicine The complexing agent of tannin and polyphenol substance.

PVPP specification（Figure 22）.

2nd, copolyvidone

Name of product：Copolyvidone

Chemical name：Vinylpyridine network alkanone and acetate ethylene copolymer

INCI/CTFA:VP/VA copolymers

Pharmacopeia title：Copolyvidone

No. CAS：25086-89-9.

Copolyvidone chemical structural formula（Figure 23）.

Product performance：To off-white powder, the easy moisture absorption is dissolved in water, ethanol and other organic solvents, with good to white Film forming, caking property and surface-active.Purposes：Copolyvidone can be used for wet granulation and direct tablet compressing production in pharmaceutical field In water-soluble binder and dry binder, and can be used as filmogen.

Copolyvidone specification（Figure 24）.

Step a32 is that the functional material for selecting a31 weighs mixing for standby use by the mass percent of component table 5.

Component table 5（Figure 25）.

Step a33, with grinder by step a32 prepared products, 600 revs/min, grinds 30 minutes, obtains macromolecule blending Mixture, this homogeneous thing room temperature cool place sealing preserve can be stablized the several years.

Step b11, after step a13 and step a22 prepared products are mixed, in ball milling instrument of the addition with cooling function, Ground with zirconium oxide bead under the conditions of lucifuge and homogenized, form gellan gum, hyaluronic acid, aeroge, photocuring adhesive and solvent Homogenised mix is standby, and this mixture should avoid high temperature and illumination, obtains energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing mixing material Material.

Step c11, aeroge mixture prepared by macromolecule blending mixture and the step b11 that step a33 is obtained presses 1 ~1000:1000~1, more preferably by 1~500:500~1, most preferably by 1~100:100~1, this example presses 1:6, After mixing in grinder under the conditions of lucifuge, mould molding or directly carry out follow-up process step that addition is selected.

Step c12, obtains step c11 article shaped or homogeneous thing high energy ultraviolet and irradiates solidification drying, the demoulding or equal Obtained after matterization dispersion aeroge energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protection aeroge multifunctional material coat or The functional material of doping, the functional material makes mainly as disintegrant, dispersant, stabilizer, leavening agent, anticaking agent, adsorbent With can be applied to decoration new liquid wallpaper, external diagnosis reagent, pharmaceuticals, food, cosmetics, anti-fog haze product, essential oil system Product, building decoration product, ink, paint, coating etc..

Aeroge energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protection aeroge multifunctional material that step c12 is obtained Cladding or the functional material of doping, after being processed through high temperature sintering, by controlling temperature and time to continue to obtain, quality is lighter, heat Stability more preferably, moisturizing water lock more preferably, the more preferable functional material of heat-insulated cold accumulation effects.Fig. 6 illustrates heat-insulation and heat-preservation cold-storage moisturizing Situation of change of the protective materials under the conditions of combustion gas calcination.

Embodiment seven.

As shown in figure 3, first pressing step a, further according to needs and step b, step c combination operations, energy-storage thermal-insulating insulation is prepared The basic step of cold-storage protection against the tide moisturizing water lock material is as follows.

Step a11, from commercially available high acyl gellan gum product, the commercial goods for obtaining is extracted by microculture；Dioxy SiClx aeroge, by hexahydrophthalic acid bisglycidyl ester, 1,3-BDO diacrylate and poly-（Methyl ethylene Ether/maleic acid）Half-ester copolymerization thing or their 1:1:One kind or several in 1 mixture, Ludox, silicate, siloxanes, silicon ether It is prepared by the mixed solution planted.The present embodiment, from Ludox：Silica flatting silica 5：1 mixture and hexahydrophthalic acid Bisglycidyl ester, 1,3 butyleneglycol diacrylate with it is poly-（Methyl vinyl ether/maleic acid）Half-ester copolymerization thing 1:1:1 mixing Thing prepares aerosil.The hyaluronic acid that this example is selected is the extra small numerator sodium hyaluronate of high activity, by microorganism The commercial goods for obtaining are extracted in culture, and the product relative molecular weight is 3 kDa~10 kDa.

Step a12, weighs low-acyl gellan gum and the extra small numerator sodium hyaluronate of high activity respectively accounts for mass percent total amount Mass percent total amount 0.0001%~19.0%, relatively optimization is 0.003%~10.0%, optimization for 0.005%~ 0.3%；Weigh 0.005~99.5% silica aerogel powder for accounting for mass percent total amount again, relatively optimization for 0.01%~ 96.5%, optimization is 0.05%~91.5%, and room temperature is closed after mixing saves backup.

Step a13, by mixture addition grinder described in a12, is homogenized by zirconia media, formation gellan gum, Hyaluronic acid and aeroge mixture.

Step a21, this example light curing agent selects commercially available UV-903 photocurings adhesive and double ((3,4- epoxy hexamethylenes Base) methyl) adipate ester 3:1 mixture.Double ((3,4- epoxycyclohexyls) methyl) adipate ester technical indicators therein are as follows.

First, name of product：Double ((3,4- epoxycyclohexyls) methyl) adipate esters

Alias：Double (7- oxabicyclos [4,1,0] 3- methyl in heptan) adipate esters

English name：bis[(3,4-epoxycyclohexyl)methyl]adipate.

2nd, CAS NO.:3130-19-6.

3rd, double ((3,4- epoxycyclohexyls) methyl) adipate ester structural formulas.

4th, molecular formula：C20H30O6, molecular weight：366.45.

5th, purposes：Special epoxy resin, cycloaliphatic epoxy resin.

6th, property：

Density： 1.149 g/mL at 25 °C(lit.)

Refractive index n20/D： 1.493(lit.)

Flash-point：>110 ℃.

7th, quality index：Double ((3,4- epoxycyclohexyls) methyl) adipate ester quality index.

8th, performance characteristics：This product viscosity is low, good fluidity, can lack with or without organic solvent during processing.Saturation knot Structure, weatherability is outstanding, and finished product will not ftracture or xanthochromia, carbon dioxide and water is produced when electrically decomposing, rather than fragrant family tree Fat produces graphite to cause short circuit.Chlorinty is low, is particularly suitable for the insulating materials high to electrical performance demands, and high-temperature insulating quality is good, The resistance to electric leakage trace of arc resistance is strong.Thermal curable, also photocurable, quick solidifying, cure shrinkage are low.Solidfied material crosslink density Greatly, with excellent pliability.Heat endurance is good, and Tg is higher than 200 degrees Celsius.

Step a22, weighs UV-903 photocurings adhesive with double ((3,4- epoxycyclohexyl) methyl) adipate esters 3:1 mixes Compound accounts for the 0.001%~90.0% of mass percent total amount, relatively optimization 0.005%~80.0%, optimization for 0.05%~ 19.0%, the closed room temperature of this mixture or Cord blood are standby.

Step a31, from commodity poly (l-lactic acid), mean molecule quantity 1.5-3 Mw（Ten thousand）；PVP K90,2, 4,7,9- tetramethyl -5- decine -4,7- glycol, copolyvidone.

Copolyvidone performance indications therein are as follows：

Name of product：Copolyvidone

Chemical name：Vinylpyridine network alkanone and acetate ethylene copolymer

INCI/CTFA:VP/VA copolymers

Pharmacopeia title：Copolyvidone

No. CAS：25086-89-9.

Copolyvidone chemical structural formula.

Product performance：To off-white powder, the easy moisture absorption is dissolved in water, ethanol and other organic solvents, with good to white Film forming, caking property and surface-active.

Purposes：Water-soluble binder of the copolyvidone in pharmaceutical field can be used for wet granulation and direct tablet compressing production And dry binder, and can be used as filmogen.

Copolyvidone specification.

Step a32 is that the functional material for selecting a31 weighs mixing for standby use by the mass percent of component table 6.

Component table 6（Figure 26）.

, be fully ground for step a32 prepared products with high speed nano-level grinder by step a33, obtains macromolecule blending mixture, This homogeneous thing room temperature cool place sealing preserve can be stablized the several years.

Step b11, after step a13 and step a22 prepared products are mixed, in ball milling instrument of the addition with cooling function, Ground with zirconium oxide bead under the conditions of lucifuge and homogenized, form gellan gum, hyaluronic acid, aeroge, photocuring adhesive and solvent Homogenised mix is standby, and this mixture should avoid high temperature and illumination, obtains energy-storage thermal-insulating insulation cold-storage protection against the tide moisturizing mixing material Material.

Step c11, aeroge mixture prepared by macromolecule blending mixture and the step b11 that step a33 is obtained presses 1 ~1000:1000~1, more preferably by 1~500:500~1, most preferably by 1~100:100~1, this example presses 4:1, After mixing in grinder under the conditions of lucifuge, mould molding or directly carry out follow-up process step that addition is selected.

Step c12, obtains step c11 article shaped or homogeneous thing high energy ultraviolet and irradiates solidification drying, the demoulding or equal Obtained after matterization dispersion aeroge energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protection aeroge multifunctional material coat or The functional material of doping, the functional material is mainly used in novel heat insulation and preservation poly-bag, label, carton；Medical gloves, medicine control Release, novel heat insulation and preservation cold-storage foam or filler particles, can also be applied to external diagnosis reagent, food, cosmetics, anti-fog haze The shielding of product, essential oil preparation, building decoration product etc..

Aeroge energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protection aeroge multifunctional material that step c12 is obtained Cladding or the functional material of doping, after being processed through high temperature sintering, by controlling temperature and time to continue to obtain, quality is lighter, heat Stability more preferably, moisturizing water lock more preferably, the more preferable functional material of heat-insulated cold accumulation effects.

Claims (9)

1. a kind of energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protective multifunction new material, it is characterised in that described Energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protective multifunction material include the mixing of gellan gum, hyaluronic acid and aeroge Thing, new photocuring adhesive or light-sensitive material and solvent；The weight/mass percentage composition of gellan gum is 0.0001%~19.0%；It is transparent Matter acid weight/mass percentage composition is 0.0001%~19.0%；Aerogel powder content 0.04~99.7%；Photocuring adhesive is photosensitive The weight/mass percentage composition of material and solvent is 0.001%~99.0%, and the mixed proportion of the two is 1~1000:1~1000, it is more excellent 1~500 for changing:1~500, optimization is 1~100:1~100；Described gellan gum is high acyl gellan gum, low acyl group knot Cold glue or the mixture of the two；Described hyaluronic acid is that low-molecular-weight hyaluronic acid or high molecular weight hyaluronic acid or oligomerization are saturating Bright matter acid or other derivatives of hyaluronic acids or their mixture；Described aeroge is silica aerogel powder or two Silica aerogel particles or aerosil coating commodity or graphene aerogel or carbon aerogels or metal aerogel Or other inorganic, organic aerogels or aerogel precursor material；Described new photocuring adhesive is including but not limited to various New commodity light-sensitive material, new type photosensitive resin, UV adhesives etc., this patent are preferably new commodity UV-803 photocurings and glue Jelly, UV-903 photocurings adhesive and UEV-2002UV803 photocurings adhesive, new photosensitive epoxy resin or new photosensitive Material etc.；Described novel environment friendly solvent is isobutyl acetate or hexahydrophthalic acid bisglycidyl ester or poly-（Methyl second Alkene ether/maleic acid）Half-ester copolymerization thing is poly-（Methyl vinyl ether/maleic anhydride）Half-ester copolymerization thing or double ((3,4- epoxide rings Hexyl) methyl) adipate ester or isobornyl methacrylate or isobornyl acrylate or essential oil or fluorous solvent or ionic liquid The mixed solvent that body or these solvents are formed.

2. energy storage described in a kind of claim 1, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, the protection multi-functional composite wood of aeroge The preparation method of material, it is characterised in that comprise the following steps：

A. knot gellan gum, hyaluronic acid and aeroge mixture are prepared, by gellan gum, hyaluronic acid and aerogel powder or precursor Material mixes method after weighing in proportion with physics, is mixed including but not limited to air-flow crushing mixing, mechanical agitation mixing, ultrasonic wave Conjunction, ground and mixed etc., that is, obtain light compounds, and this mixture is preserved under low humidity airtight condition；

B. photosensitive aeroge mixture is prepared, the light compounds that step a is obtained, the photocuring adhesive weighed with ratio, Ground and mixed under the conditions of function carrier or functional material, the abundant lucifuge of above-mentioned solvent of pretreatment, it is static to obtain photosensitive gas afterwards Gel mixture；

C. energy storage, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protective multifunction composite are prepared, what step b was obtained is photosensitive Aeroge functional mixture carries out solidification dried process, obtain the energy storage of mould institute figuration shape, heat-insulated, insulation, cold-storage, protection against the tide, Moisturizing, protective multifunction material, this material can also be coated or covered with different carriers or functional material by adhesive agent or Doping posterior photocuring is dried.

3. energy storage according to claim 2, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protective materials preparation method, it is special Levy and be：Solidification drying method described in step c is high energy UV rapid curing drying means or room temperature natural light Slow solidifying and drying method or high-energy irradiation solidification.

4. prepared by energy storage according to claim 3, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protective multifunction composite Method, it is characterised in that：Described high energy UV rapid curing drying means is that above-mentioned aerogel-containing composite materials are quickly solid Change drying, remove solvent, obtain the energy storage of mould institute figuration shape, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protect aeroge many Functional composite material or be coated or covered with selected carrier or functional material or the Multifunctional, air gel complex material that adulterates after Photocuring is dried.

5. energy storage according to claim 3, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protective multifunction material preparation side Method, it is characterised in that：Described high energy UV rapid curing drying means or the slow solidifying and drying method of room temperature natural light It is that first aerogel-containing composite materials are sufficiently mixed with photocuring solvent or with pretreating agent, material is made with light curable solvent or light-sensitive material Material is homogenized, and then photocuring is dried or hardening with radiation is dried in particular mold or carrier material, obtains mould institute figuration shape Or the functional material of aerogel-containing composite materials is coated with, then carry out follow-up functionalization.

6. prepared by energy storage according to claim 5, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protective multifunction composite Method, it is characterised in that：Described curing agent is light-sensitive material, such as various photosensitive resins, photocuring adhesive or theirs is mixed Compound；Novel dissolvent used is various new organic solvent, essential oil or pretreatment purified water, and such as isobutyl acetate or hexahydro is adjacent Phthalic acid bisglycidyl ester is poly-（Methyl vinyl ether/maleic acid）Half-ester copolymerization thing is poly-（Methyl vinyl ether/Malaysia Acid anhydrides）Half-ester copolymerization thing or double ((3,4- epoxycyclohexyls) methyl) adipate esters or isobornyl methacrylate or acrylic acid The mixed solvent that isobornyl thiocyanoacetate or essential oil or fluorous solvent or ionic liquid or these solvents are formed.

7. energy storage according to claim 6, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protective multifunction material preparation side Method, it is characterised in that：When using, the light compounds and new light-cured resin or new photocuring that can be obtained by above-mentioned a Adhesive, novel dissolvent group difference low-temp storage, face the used time mix with function carrier or functional material after illumination curing or irradiation Solidification drying.

8. energy storage according to claim 7, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protective multifunction aeroge composite wood Preparation method for material, it is characterised in that：With degradable high polymer material, adsorbent, filter aid, water retention agent, bactericide, desinsection Agent, enzyme, protein, thickener, adhesive, emulsifying agent, nutrition fortifier, preservative, mineral matter, inorganic salts, plastics, soda acid Degree conditioning agent is used in combination or is coated on these materials, can protect and strengthen the effect of these materials and expand it using scope, Strengthen its stability, can be used for Aeronautics and Astronautics, navigation, soil moisturizing improvement, food fresh keeping, crops insect prevention, fertilizer synergistic, Active component stabilization, medicine controlled release, spices controlled release, ink synergy, pesticide action-controlling, agriculture livestock products preserve transport, soil moisturizing, Soil improvement, except haze, except formaldehyde, water purification, papermaking, printing etc., these degradable high polymer materials and functional material or function Carrier is including but not limited to various essential oils, glycol divinyl ether, 4- hydroxy butyl vinyl ethers, acrylic ether, 1,1,3,3- Tetramethoxy propane, 3,4- 7-oxa-bicyclo[4.1.0s carboxylate methyl ester, 4,5- 7-oxa-bicyclo[4.1.0-1,2- dicarboxylic acid diglycidyl esters, four It is hydrogen phthalic acid bisglycidyl ester, hexahydrophthalic acid bisglycidyl ester, poly-（Methyl vinyl ether/maleic acid）Half It is ester copolymer, poly-（Methyl vinyl ether/maleic anhydride）Half-ester copolymerization thing, double ((3,4- epoxycyclohexyls) methyl) adipic acids Ester, polyglycerine, hyaluronic acid and its derivative, oligomerization hyaluronic acid, Chitosan-phospholipid complex, art post paperboard, brown paper, It is ceramic, ceramic powders, stainless steel, plank, glass, lucite, aluminium alloy, titanium alloy, poly-（Methyl vinyl ether/horse Come sour）Copolymer free acid, the methoxy ethylene of copolymer, marine alga oligosaccharide, benzophenone, methoxy ethylene and maleic anhydride With calcium/sodium mixture, PVP-I, the PVP of maleic anhydride linear copolymer, methoxy ethylene and copolymer-maleic anhydride In vain, vinyl pyrrolidone and acetate ethylene copolymer, PVPP, glass fibre, non-woven fabrics, acetic acid it is fine Dimension, marine alga saccharide oligomers, starch and its derivative, dextrin, cellulose and its derivates, gelatin and its derivative, protein and Its derivative, amino acid and its derivative, lacticin, Natamycin, neomycin, streptomysin, hydroxypropyl acrylate, epoxy （Methyl）Acrylate, penicillin, gentamicin, BIOLOGICAL CALCIUM, calcium lactate, polyketone resin, calcium phosphate, gluconic acid- ca, marine alga Hydrochlorate, zinc gluconate, hippophae rhamnoides, Seabuckthorm Seed Oil, flatting silica, ultra-violet absorber, wire netting, copper mesh, cotton, nitre Change cotton, cement, Seabuckthorn Oil, deep sea fish oil, saualane, unrighted acid, aliphatic acid, triglycerides and its derivative, courage solid Alcohol and its derivative, vitamin C and its derivative, ursin and its derivative, PFPE oligomer, 1,3 butylene glycol dipropyl Olefin(e) acid ester, retardant cotton, antibiosis anti-acarien deodorization cotton, anion cotton, silk, edetate, hydrofluoric acid, fluorous solvent, 12 Alkyl amine oxide, phytic acid, pantothenic acid, tranexamic acid, tocopherol, hypophosphites, malt polysaccharide, maltose, isobornyl acid It is ester, zein, albumin, benzoyl peroxide, peroxidating carbon, urea peroxide, chlorine dioxide, sulfur dioxide, diatomite, white Potter's clay, activated carbon, niacinamide, Eleutheroside B+E, sodium sulfite, sodium hydrogensulfite, 1,6 hexanediol diacrylate, winestone Acid, malic acid, citric acid, neopelex, sarcosyl, marine alga carbohydrates and their derivative, chitin, ten Tetraalkyl trimethyl ammonium chloride, decyl trimethyl ammonium chloride, agar, benzoin ethyl ether, caseinate, Arabic gum, card Draw glue, guar gum and its derivative, acetone, cyclodextrin and its derivative, soybean lecithin and its derivative, phosphatide and its derivative Thing, tripotassium phosphate, tertiary sodium phosphate, disodium hydrogen phosphate, sodium dihydrogen phosphate, sodium pyrophosphate, sodium tripolyphosphate, metaphosphate, stomach egg White enzyme, chymotrypsin, pancreatin, amylase, papain, renin, pectase, food bacterium, paraffin, lac, kaolin, breast SiClx oil, Tween-20, Qula logical -100, Tween-80, Brij-35, Bu Lijie -98, Qula logical -405, other nonionic tables Face activating agent, triphenylphosphine oxide, tributylphosphine, resin cation, resin anion (R.A.), chelating resin, hybrid resin, asphalt mixtures modified by epoxy resin Fat, sapn, glycine betaine and its derivative, potassium ferrocyanide, the potassium ferricyanide, xanthans, essential oil, edible oil, olive oil, polyethylene Alcohol, polyacrylamide, acrylic acid and methacrylate polymer, polyethylene glycol and its derivative, polyethylene glycol oxide, poly- Malaysia Acid, PLA, water soluble polyurethane resin, polyethers and its derivative, polyvinylpyrrolidone, glycyrrhetate, ethanol, glycerine, Sugarcane carbohydrates and their derivative, propane diols, propylene glycol block polyether, AEO, APES, aliphatic acid It is polyoxyethylene ester, castor oil polyoxyethylene ether, aliphatic amine polyoxyethylene ether, froth breaking king FAG470, environment-friendly type penetrating agent JFC, double Carbonamidine emulsifying agent 3201, malathion emulsifying agent HSH431, Quizalotop-ethyl emulsifying agent HSH432, triazolone emulsifying agent HSH433, 5a,6,9,9a-hexahydro-6,9-methano-2,4 emulsifying agent HSH434, chlopyrifos emulsifying agent HSH435, glyphosate and its isopropyl amine salt emulsifying agent HSH436, napropamide emulsification Agent HSH437, phosphate (sylvite), methyl allyl polyoxyethylene ether HPEG（Also known as modified polyether-TPEG）, calcium carbonate, carbonic acid Magnesium, carborundum, carbon black, n-hexane, normal heptane, petroleum ether, sodium sulfate of polyethenoxy ether of fatty alcohol, hexylene glycol, ethylene glycol, butyl BHA, propylgallate, dibutyl hydroxy toluene, Aspartame, honey element, agate card extract, maca ene, matrimony vine Juice powder, rhodiola plant extract, HCA plant extracts, cherry plant extracts, fleece-flower root plant extracts, balsam pear are planted Thing extract, kudzu root extract, hydroxycitric acid, pomegranate rind extract, Shorthorned Epimedium P.E, lycium plant extract, cynomorium songaricum Plant extracts, hydroxytyrosol, tribulus terrestris extraction, Glucosinolates, hydroxyapatite, Nanoalloy particulate, hydroxycitric acid, stone Pomegranate bark extract, Shorthorned Epimedium P.E, Black Cohosh P.E, sanguinarine, 5-ALA hydrochloride, rosemary are extracted Thing, seed of Sesamum indicum L. extract, ivy extract, macamide, fourth butyrolactone, ethylmaltol, fruit carbohydrates and their derivative, prestox Cyclotetrasiloxane, polyglyceryl fatty acid ester, titanium oxide, zinc oxide, calcium oxide, Rosmarinus officinalis extract, tert-butylhydroquinone, wine Stone potassium hydrogen phthalate, sodium acid carbonate, alum, natrium nitrosum, white oil, sulfhydryl oxidase sodium, sulfhydryl oxidase zinc, stearic acid, ammoniacal liquor, three Monoethanolamine, diethanol amine, TMAH, taurine, benzoic acid, oleic acid, leukotrienes, linoleic acid, sorbic acid, sweet dew Alcohol, calcium chloride, xylitol, potassium permanganate, ethyl caprilate, peppermint oil, camphor, attar of rose, lavender oil, sweet apricot oil, aloe, It is pelargonium oil, safflower oil, wheat-germ oil, evening primrose oil, wintergreen, thyme linaloe oil, vetiver oil, cade oil, marjoram oil, small Fennel oil, You Jiali oil, myrrh oil, orange oil, sage oil, Java Cananga Oil, You Jiali oil, cypress oil, camphorated oil, basil, Bergamot oil, black pepper oil, oleum menthae piperitae, grape-kernel oil, glycine betaine, CAB-35, OP-10, dodecyldimethylammonium hydroxide inner salt, Dodecyldimethylamine base glycine betaine, glyphosate, ginger oil, eucalyptus oil, patchouli oil, lemon oil, menthol, cinnamon oil, jasmine oil, Tea oil, Blumea oil, amine oxide and its derivative, taxane and its derivative, adenosine and its derivative, qinghaosu and its derivative Thing, laurolitsine, linoleic acid, tetraethyl orthosilicate, brucealin, alumina silicate micro mist, mangostin, gypsum, full five acid, furans Ether, furans glycol, Hericium erinaceus extract, erinacine, ginkgol, ginkgolide, calcium sulfate, fine silica powder, isopropyl Alcohol, life saponin, pydidine alkaloid, lignanoid, 6-Hydroxyluteolin, 2- methylols anthraquinone, 4- hydroxyls -3-（3- methyl -2- Butenyloxy）-5-（3- methyl-2-butene bases）- benzoic acid, papper oil, ammonium dihydrogen phosphate, hook-shaped pepper, Mexico's sandwort Careless oil, 2,4,7,9- tetramethyl -5- decine -4,7- glycol, trimethyl amine oxide, 3,6- dimethyl -1- heptyne -3- alcohol, azone, Porous foam metal, conductive non-woven fabrics, 3,6- dimethyl -4- octyne -3,6- glycol, Kenya silk tree oil, phloroglucin, Brazil Hypericum oil, hypolaetin -8- oxygen-glycoside, secondary clothing grass element, ilex pubescens glucoside first, Ilex pubescens extract, cogongrass alkene, India Cogongrass extract, inulin, azide, different other alantolactone, isochlorogenic acid, Rabdosia amethystoides acid, foreign glycosides elecampane oil, Jojoba Oil, Angelica oil, Fructificatio Tricholomatis Matsutakis extract, meadow fescue extract, jujube saponin, soap leaf extract, methylbutanoic acid -3,14- dehydrogenation-Z- coltsfoots Plain ester, coltsfoot extract, Flos Tagetis Erectae extract, myristicin, red gold ear ring extract, sulfate, nitrite, lotus heart alkali, Neoabietic acid, the acid of the new fruit of Chinese magnoliavine, olive bark extract, the algae peptide that quivers, quiver algae acid amides, A Shi quiver algae extract, Imperatorin, poly- PAA, acrylic acid and various of monomer copolymer, sieve denier plum bark extract, plumericin, Indian beech alcohol, alpha-cyanoacrylate Ester gum, aluminum foil glue adhesive tape, distilled water, purified water, drinking water, grey green soy bean root extract, Polygonatum prattii Baker glucoside, Polygonatum prattii Baker root are extracted Thing, engineering plastics, shogaol, spiradine, grape seed extract, japanese spiraea root extract, lycopene, dark sieve alcohol, dark sieve Stem-leaf extract, moutan root bark extract, sweet tea phenol, acetyl chitosamine, polyglutamic acid sodium, GABA, pyroceram Fiber sleeve, glass fiber tape, fiberglass needled mat, nylon wire, nylon cloth, high silica glass cloth, hydroxypropyl methyl Cellulose, E glass fiber papers, grid cloth, casting screen pack, multiaxial fabric, pipeline felt, surface felt, alkali-free glass fibre screen cloth, silicon high Oxygen be chopped yarn, alkali-free glass fibre industrial cloth, molding grating, nanometer citric acid collargol, AA-E alcohol copolymer, Polyvinyl alcohol crosslinked polymer, hexamethyldisiloxane, silica high are chopped yarn, silicon rubber or methyl vinyl phenyl silicon rubber, first Hyrazin, ascorbic acid glucoside, soybean lecithin, cephalin, purple potato extract, Tribuloside, siberian Ginseng P.E, South Africa Liquor-saturated eggplant extract, rose berry extract, gadol extract, wheat seedling extraction, milkwort extract, tribulus terrestris Total saponin, west kind Lotus extract, Fructus piperis nigrum extract, Hypericum Perforatum P.E, α-cyanoacrylatealkyl, 90%UV tribulus terrestris oil, South Africa are liquor-saturated Eggplant oil, wilsonii oil, rose hip oil, purple potato extract, 10%HPLC tomato extracts, 35%UV ivies extract, 26% HPLC licorices, 3', 4', 5,7- kaempferol（Cyanidenon）, tremella polysaccharides, 40% Fructus lycii P.E（Matrimony vine is more Sugar）, serotonine acid, 0.3% Hypericum Perforatum P.E（Hypericin）, 5% UV passionflower oils, garlic oil, Angelica oil, 10: 1 Semen Sesami Nigrum extract, agate card oil, 5:1 Herba Cynomorii extract, Symwhite-337, benzoic acid, 4 amino-antipyrines, periodic acid It is potassium, sodium iodide, hydroxycarbamide, alum, aluminum sulfate, Citric Acid Mono, phosphotungstic acid, lithium carbonate, reddish black, orange, BG, solid Green, n- dodecyl mereaptan, propylene glycol methyl ether acetate, dimethyl carbonate, Porous deproteinized bone solvent naphtha D80, N- ethyl-N- (3- sulphurs third Base) -3- methylanilines sodium salt, HAEMATOXYLIN, imidazolidinyl urea, trishydroxymethylaminomethane, 1- thioglycerols, ethylenediamine tetrem It is acid disodium salt, imidazolidinyl urea, iodine propilolic alcohol butyl mephenesin Carbamate, pyrrolidone sodium carboxylate, PEG400, double（Hydroxyl first Base）Imidazolidinyl urea, formaldehyde, glutaraldehyde, carbodiimide and its derivative, 4- HEPESs, mannitol, sorb Alcohol, proline and derivative, dithiothreitol (DTT), bovine serum albumin(BSA), vitamin C-β-glucose, azide, beta glucan And derivative, matrine, Rhizoma Polygonati extract, sealwort glucosides, DHPG, Pfansteihl, PLA and its derivative, poly rely ammonia Sour, many poly-aspartic-acids, poly paddy amino acid, acid fiber by polylactic, boiled silk, soluble lyophilized silk-fibroin, anti-tnfa are received The therapeutic monoclonal antibodies such as body monoclonal antibody, hematopoietin, lysozyme, digitalis glucoside, 2- methylacryoyloxyethyls The chloro- 2- oxygen of phosphocholine, Choline Chloride, 2- closes -1,3,2- dioxaphospholane（COP）, the chloro- 1,3,2- dioxies phosphorus heterocycles of 2- Pentane（2-chloro-1,3,2-dioxaphospholane）(CDP), phosphatidylserine, chenodeoxycholic acid, pig deoxidation courage Acid, injection soybean lecithin, qinghaosu, alkene phosphatid ylcholine, glycerolphosphocholine, serinephosphatide, trimethylene carbonic acid Ester（TMC）Deng and its above material composition.

9. energy storage according to claim 8, heat-insulated, insulation, cold-storage, protection against the tide, moisturizing, protection the multi-functional composite wood of aeroge Preparation method for material, it is characterised in that：Using gellan gum gelation and temperature lag, hyaluronic acid moisturizing film forming, and it Two-dimentional, three-dimensional spiral shell and network structure provide aeroge flexible skeletal structure, stablize its conformation, without pressurization, heating stepses And CO₂Supercritical extract is dried, energy-conserving and environment-protective, green safety, with simple to operate, the features such as applied widely, and gellan gum This composite of hyaluronic acid aeroge has the functions such as heat-insulated, insulation, cold-storage, moisturizing, moistureproof and anti-fog haze, is coated on load Body material or functional material, contribute to the performance boost of these materials, expand it and use scope and effective utilization etc., are a kind of complete New new green environment protection multifunctional material, can be widely used for decoration new liquid wallpaper, medical diagnosis on disease, prevention from suffering from the diseases, life Thing is anti-probably, quarantine and examination analysis, haze improvement, water purification, sewage disposal, soil improvement, aviation, navigation, space flight, medicine, food, It is chemical industry, cosmetics, electronic information, medicine equipment, agriculture livestock products, building decoration, petroleum and petrochemical industry, papermaking, printing, ink, anti- The field such as haze cosmetics and skincare product, anti-fog haze infant article, anti-aging, gene sequencing.