CN106928825A - High-dyeing-propertyalcohol alcohol acid paint vehicle - Google Patents
High-dyeing-propertyalcohol alcohol acid paint vehicle Download PDFInfo
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- CN106928825A CN106928825A CN201710192773.8A CN201710192773A CN106928825A CN 106928825 A CN106928825 A CN 106928825A CN 201710192773 A CN201710192773 A CN 201710192773A CN 106928825 A CN106928825 A CN 106928825A
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- alcohol acid
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to paint vehicle technical field, and in particular to a kind of High-dyeing-propertyalcohol alcohol acid paint vehicle, High-dyeing-propertyalcohol alcohol acid paint vehicle is composed of the following components by weight：Alkyd resin, silica ink absorbent, polyvinyl alcohol, guar gum, toluene di-isocyanate(TDI), dimethylbenzene, emulsifying agent, boiled wood oil, neopentyl glycol, thickener, surfactant, drier and water are raw material, the beneficial effects of the invention are as follows：The present invention is modified using toluene diisocynate to alkyd resin, with the alkyd paint vehicle that modified alkyd resin is prepared as raw material, there is high coloring, fast drying, guar gum is used as the raw material for preparing alkyd paint, the alkyd paint of preparation will not be made to produce clustering phenomena, the quality of alkyd paint is ensure that, the adhesive force of alkyd paint can be strengthened as thickener from sodium carboxymethylcellulose, improve the coloring of alkyd paint.Drier can allow the moisture of alkyd paint to accelerate evaporation, shorten the drying time of alkyd paint.
Description
Technical field
The present invention relates to paint vehicle technical field, and in particular to a kind of High-dyeing-propertyalcohol alcohol acid paint vehicle.
Background technology
Alkyd paint alias alkyd resin coating or phthalic resin coating, are mainly made up of alkyd resin, are domestic at present raw
The maximum class coating of yield.It is plentiful hard, durable with cheap, simple, film less demanding to construction environment of constructing
Property and weatherability preferably, the advantages of ornamental and protectiveness is all relatively good.Alkyd paint is mainly used in general woodenware, furniture and family
The application of finishing, the application of common metal decoration, less demanding anti-corrosion of metal application, general agricultural machinery, automobile, instrument and meter, work
The aspects such as the application of industry equipment.Alkyd resin be with polyalcohol, polyacid and aliphatic acid as primary raw material, it is anti-by polycondensation
Should prepared by a kind of polymer because synthetic technology is ripe, raw material is easy to get, resin coating film good combination property, alkyd resin into
It is one of most wide kind of consumption maximum, purposes in synthetic resin.Alkyd paint includes solvent-borne alkyd paint and water-soluble alcohol acid paint
Two classes, traditional phthalic resin coating a large amount of solvents for solvent-borne type contains, main component be alkyd resin, No. 200 industrial napthas,
Drier anti skinning agent.Colored paint also contains pigment etc..The body of meeting serious harm environment and operating personnel during production and construction
Body health.In recent years, countries in the world environmental regulation is increasingly strict, and traditional solvent based coating is subject to increasing challenge.Apply
The Water-borne modification of material, high solid trend are increasingly apparent.Water soluble paint is to introduce hydrophilic or water in film forming polymer to increase
Molten group, become can be with water as dissolving medium a kind of coating, due to its advantage substantially, the water miscible research of coating should
Widely paid close attention to and achieve impressive progress with having caused.Water soluble alkyd resin coating is new development trend, is obtained
Substantial amounts of research and development.
The shortcoming of the paint vehicle that prior art is prepared is：Drying is not strong compared with slow, coloring, fineness is big and viscosity is small, uncomfortable
In the occasion of high-decoration.
The content of the invention
For above-mentioned problem, the present invention proposes a kind of High-dyeing-propertyalcohol alcohol acid paint vehicle, with high coloring, drying
Hurry up, small fineness and the characteristics of big viscosity.
To achieve the above object, the present invention uses following technical scheme：
A kind of High-dyeing-propertyalcohol alcohol acid paint vehicle, it is composed of the following components by weight：Alkyd resin 110-130, titanium dioxide
Silicon ink absorbent 80-150, polyvinyl alcohol 4.0-6.0, guar gum 5.0-8.0, toluene di-isocyanate(TDI) 2.6-3.2, dimethylbenzene 2.1-
2.8th, emulsifying agent 1.5-2.0, boiled wood oil 1.0-1.8, neopentyl glycol 2.4-3.0, thickener 0.8-1.3, surfactant 0.7-
1.5th, water 150-180, drier 3-5.
Preferably, described High-dyeing-propertyalcohol alcohol acid paint vehicle, its manufacture craft is comprised the following steps：
(1) preparation of modified alkyd resin, step is：
S1：Boiled wood oil, alkyd resin, neopentyl glycol three are mixed, mixture is designated as A；
S2：It is the lithium hydroxide of three times A that quality is added when A temperature is increased into 130-145 DEG C, promotes alcoholysis, in 200-
Reaction 120-150min, mixture is kept to be denoted as B under conditions of 230 DEG C；
S3：By toluene di-isocyanate(TDI) and dimethylbenzene with volume ratio 1：2 ratio mixing, stirs, and mixture is designated as
C；
S4：C is slowly added dropwise after B is cooled into 30-40 DEG C thereto, 40- is incubated after adding under the conditions of 50-60 DEG C
60min, then in 80-100 DEG C of insulation reaction 60-120min, mixture is designated as D；
S5：D is cooled to 55-65 DEG C, it is the butanol of D twices to add quality, is stirred under the rotating speed of 600-800r/min
Filtered after 30-50min, obtain modified alkyd resin；
(2) preparation of High-dyeing-propertyalcohol alcohol acid paint vehicle, step is：
S1：By silica ink absorbent, polyvinyl alcohol, guar gum, emulsifying agent, thickener, surfactant and drier
Add in modified alkyd resin, be warming up to 40-60 DEG C, heat while stirring, 30- is stirred under the rotating speed of 640-760r/min
45min, mixture is designated as E；
S2：In adding water to E, and pH is adjusted for 6-8, by temperature control at 45-60 DEG C, in the rotating speed of 800-900r/min
Lower stirring 40-50min, you can obtain High-dyeing-propertyalcohol alcohol acid paint vehicle.
Preferably, the guar gum is cation guar gum.
Preferably, the surfactant selects benzalkonium bromide.
Preferably, the thickener selects sodium carboxymethylcellulose.
Preferably, the emulsifying agent selects Arabic gum.
Preferably, the drier selects aqueous polyurethane.
Using above-mentioned technical scheme, the beneficial effect that the present invention reaches is：
The present invention is modified using toluene di-isocyanate(TDI) to alkyd resin, synthesizes the alkyd tree containing urethane structure
Fat, it is formed by toluene di-isocyanate(TDI) substitution part phthalic anhydride with the monoglyceride reaction of vegetable oil, i.e., first by phthalic anhydride and plant
The monoglyceride of oil carries out esterification, and generation end group is the alkyd resin oligomer of-OH structures, is subsequently adding toluene two different
Cyanate, using the reaction of-OH and-NCO, toluene di-isocyanate(TDI) is introduced into Structure Detemination of Alkyd Resins.Realize to alkyd tree
Modified, the alkyd paint vehicle that modified alkyd resin is prepared for raw material of fat, has the advantages that high coloring, fast drying, Guar
Glue will not make the alkyd paint of preparation produce clustering phenomena as the raw material for preparing alkyd paint, improve manufacture and production operation
Convenience, it is ensured that the quality of alkyd paint, the adhesive force of alkyd paint can be strengthened as thickener from sodium carboxymethylcellulose,
Improve the coloring of alkyd paint.Drier can allow the moisture of alkyd paint to accelerate evaporation, shorten the drying time of alkyd paint.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described.Based on embodiments of the invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model of present invention protection
Enclose.
Embodiment 1：
Preferably, described High-dyeing-propertyalcohol alcohol acid paint vehicle, its manufacture craft is comprised the following steps：
(1) preparation of modified alkyd resin, step is：
S1：Boiled wood oil, alkyd resin, neopentyl glycol three are mixed, mixture is designated as A；
S2：It is the lithium hydroxide of three times A that quality is added when A temperature is increased into 130 DEG C, promotes alcoholysis, in 200 DEG C of bar
Reaction 120min, mixture is kept to be denoted as B under part；
S3：By toluene di-isocyanate(TDI) and dimethylbenzene with volume ratio 1：2 ratio mixing, stirs, and mixture is designated as
C；
S4：C is slowly added dropwise after B is cooled into 30 DEG C, 40min is incubated after adding under the conditions of 50 DEG C, then in 80 DEG C of guarantors
Temperature reaction 60min, mixture is designated as D；
S5：D is cooled to 55 DEG C, it is the butanol of D twices to add quality, after stirring 30min under the rotating speed of 600r/min
Filtering, that is, complete to be modified alkyd resin；
(2) preparation of High-dyeing-propertyalcohol alcohol acid paint vehicle, step is：
S1：By silica ink absorbent, polyvinyl alcohol, guar gum, emulsifying agent, thickener, surfactant and drier
Add in modified alkyd resin, be warming up to 40 DEG C, heat while stirring, 30min, mixture are stirred under the rotating speed of 640r/min
It is designated as E；
S2：In adding water to E, and it is 6 to adjust pH, by temperature control at 45 DEG C, is stirred under the rotating speed of 800r/min
40min, you can obtain High-dyeing-propertyalcohol alcohol acid paint vehicle.
Embodiment 2：
Preferably, described High-dyeing-propertyalcohol alcohol acid paint vehicle, its manufacture craft is comprised the following steps：
(1) preparation of modified alkyd resin, step is：
S1：Boiled wood oil, alkyd resin, neopentyl glycol three are mixed, mixture is designated as A；
S2：It is the lithium hydroxide of three times A that quality is added when A temperature is increased into 135 DEG C, promotes alcoholysis, in 215 DEG C of bar
Reaction 130min, mixture is kept to be denoted as B under part；
S3：By toluene di-isocyanate(TDI) and dimethylbenzene with volume ratio 1：2 ratio mixing, stirs, and mixture is designated as
C；
S4：C is slowly added dropwise after B is cooled into 33 DEG C, 45min is incubated after adding under the conditions of 54 DEG C, then in 85 DEG C of guarantors
Temperature reaction 80min, mixture is designated as D；
S5：D is cooled to 58 DEG C, it is the butanol of D twices to add quality, after stirring 38min under the rotating speed of 670r/min
Filtering, that is, complete to be modified alkyd resin；
(2) preparation of High-dyeing-propertyalcohol alcohol acid paint vehicle, step is：
S1：By silica ink absorbent, polyvinyl alcohol, guar gum, emulsifying agent, thickener, surfactant and drier
Add in modified alkyd resin, be warming up to 45 DEG C, heat while stirring, 35min, mixture are stirred under the rotating speed of 680r/min
It is designated as E；
S2：In adding water to E, and it is 6.8 to adjust pH, by temperature control at 51 DEG C, is stirred under the rotating speed of 830r/min
43min, you can obtain High-dyeing-propertyalcohol alcohol acid paint vehicle.
Embodiment 3：
Preferably, described High-dyeing-propertyalcohol alcohol acid paint vehicle, its manufacture craft is comprised the following steps：
(1) preparation of modified alkyd resin, step is：
S1：Boiled wood oil, alkyd resin, neopentyl glycol three are mixed, mixture is designated as A；
S2：It is the lithium hydroxide of three times A that quality is added when A temperature is increased into 140 DEG C, promotes alcoholysis, in 225 DEG C of bar
Reaction 140min, mixture is kept to be denoted as B under part；
S3：By toluene di-isocyanate(TDI) and dimethylbenzene with volume ratio 1：2 ratio mixing, stirs, and mixture is designated as
C；
S4：C is slowly added dropwise after B is cooled into 38 DEG C, 55min is incubated after adding under the conditions of 58 DEG C, then in 94 DEG C of guarantors
Temperature reaction 108min, mixture is designated as D；
S5：D is cooled to 62 DEG C, it is the butanol of D twices to add quality, after stirring 46min under the rotating speed of 750r/min
Filtering, that is, complete to be modified alkyd resin；
(2) preparation of High-dyeing-propertyalcohol alcohol acid paint vehicle, step is：
S1：By silica ink absorbent, polyvinyl alcohol, guar gum, emulsifying agent, thickener, surfactant and drier
Add in modified alkyd resin, be warming up to 55 DEG C, heat while stirring, 40min, mixture are stirred under the rotating speed of 720r/min
It is designated as E；
S2：In adding water to E, and it is 7.5 to adjust pH, by temperature control at 57 DEG C, is stirred under the rotating speed of 880r/min
47min, you can obtain High-dyeing-propertyalcohol alcohol acid paint vehicle.
Embodiment 4：
Preferably, described High-dyeing-propertyalcohol alcohol acid paint vehicle, its manufacture craft is comprised the following steps：
(1) preparation of modified alkyd resin, step is：
S1：Boiled wood oil, alkyd resin, neopentyl glycol three are mixed, mixture is designated as A；
S2：It is the lithium hydroxide of three times A that quality is added when A temperature is increased into 145 DEG C, promotes alcoholysis, in 230 DEG C of bar
Reaction 150min, mixture is kept to be denoted as B under part；
S3：By toluene di-isocyanate(TDI) and dimethylbenzene with volume ratio 1：2 ratio mixing, stirs, and mixture is designated as
C；
S4：C is slowly added dropwise after B is cooled into 40 DEG C, 60min is incubated after adding under the conditions of 60 DEG C, then in 100 DEG C of guarantors
Temperature reaction 120min, mixture is designated as D；
S5：D is cooled to 65 DEG C, it is the butanol of D twices to add quality, after stirring 50min under the rotating speed of 800r/min
Filtering, that is, complete to be modified alkyd resin；
(2) preparation of High-dyeing-propertyalcohol alcohol acid paint vehicle, step is：
S1：By silica ink absorbent, polyvinyl alcohol, guar gum, emulsifying agent, thickener, surfactant and drier
Add in modified alkyd resin, be warming up to 60 DEG C, heat while stirring, 45min, mixture are stirred under the rotating speed of 760r/min
It is designated as E；
S2：In adding water to E, and it is 8 to adjust pH, by temperature control at 60 DEG C, is stirred under the rotating speed of 900r/min
50min, you can obtain High-dyeing-propertyalcohol alcohol acid paint vehicle.
The High-dyeing-propertyalcohol alcohol acid paint vehicle that will be obtained using embodiment of the present invention preparation method is with commercially available alkyd paint vehicle identical
Under the conditions of contrasted, indices data such as following table：
Note：It by alkyd paint to the absorptivity of paint ink is evaluation index that coloring is.
From data in table, the High-dyeing-propertyalcohol alcohol acid paint vehicle that the present invention is produced drying time, coloring, viscosity and
The aspects such as fineness are superior to commercially available alkyd paint vehicle, show that preparation technology of the present invention is more perfect, and product overall performance is than control group more
It is good, it is worthy to be popularized.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention has been described in detail, it will be understood by those within the art that：It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic；And these modification or
Replace, do not make the spirit and scope of the essence disengaging various embodiments of the present invention technical scheme of appropriate technical solution.
Claims (7)
1. a kind of High-dyeing-propertyalcohol alcohol acid paint vehicle, it is characterised in that composed of the following components by weight：Alkyd resin 110-
130th, silica ink absorbent 80-150, polyvinyl alcohol 4.0-6.0, guar gum 5.0-8.0, toluene di-isocyanate(TDI) 2.6-3.2,
Dimethylbenzene 2.1-2.8, emulsifying agent 1.5-2.0, boiled wood oil 1.0-1.8, neopentyl glycol 2.4-3.0, thickener 0.8-1.3, surface
Activating agent 0.7-1.5, water 150-180, drier 3-5.
2. High-dyeing-propertyalcohol alcohol acid paint vehicle according to claim 2, its manufacture craft is comprised the following steps：
(1) preparation of modified alkyd resin, step is：
S1：Boiled wood oil, alkyd resin, neopentyl glycol three are mixed, mixture is designated as A；
S2：It is the lithium hydroxide of three times A that quality is added when A temperature is increased into 130-145 DEG C, promotes alcoholysis, at 200-230 DEG C
Under conditions of keep reaction 120-150min, mixture is denoted as B；
S3：By toluene di-isocyanate(TDI) and dimethylbenzene with volume ratio 1：2 ratio mixing, stirs, and mixture is designated as C；
S4：C is slowly added dropwise after B is cooled into 30-40 DEG C thereto, 40-60min is incubated after adding under the conditions of 50-60 DEG C, so
Afterwards in 80-100 DEG C of insulation reaction 60-120min, mixture is designated as D；
S5：D is cooled to 55-65 DEG C, it is the butanol of D twices to add quality, and 30- is stirred under the rotating speed of 600-800r/min
Filtered after 50min, obtain modified alkyd resin；
(2) preparation of High-dyeing-propertyalcohol alcohol acid paint vehicle, step is：
S1：Silica ink absorbent, polyvinyl alcohol, guar gum, emulsifying agent, thickener, surfactant and drier are added
In modified alkyd resin, 40-60 DEG C is warming up to, heated while stirring, 30-45min is stirred under the rotating speed of 640-760r/min,
Mixture is designated as E；
S2：In adding water to E, and pH is adjusted for 6-8, by temperature control at 45-60 DEG C, stirred under the rotating speed of 800-900r/min
Mix 40-50min, you can obtain High-dyeing-propertyalcohol alcohol acid paint vehicle.
3. High-dyeing-propertyalcohol alcohol acid paint vehicle according to claim 1, it is characterised in that：The guar gum is cation Guar
Glue.
4. High-dyeing-propertyalcohol alcohol acid paint vehicle according to claim 1, it is characterised in that：The surfactant pricks bromine from benzene
Ammonium.
5. High-dyeing-propertyalcohol alcohol acid paint vehicle according to claim 1, it is characterised in that：The thickener selects carboxymethyl cellulose
Plain sodium.
6. High-dyeing-propertyalcohol alcohol acid paint vehicle according to claim 1, it is characterised in that：The emulsifying agent selects Arabic gum.
7. High-dyeing-propertyalcohol alcohol acid paint vehicle according to claim 1, it is characterised in that：The drier selects aqueous poly- ammonia
Ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710192773.8A CN106928825B (en) | 2017-03-28 | 2017-03-28 | High-dyeing-propertyalcohol alcohol acid paint vehicle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710192773.8A CN106928825B (en) | 2017-03-28 | 2017-03-28 | High-dyeing-propertyalcohol alcohol acid paint vehicle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106928825A true CN106928825A (en) | 2017-07-07 |
| CN106928825B CN106928825B (en) | 2019-05-07 |
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ID=59424912
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710192773.8A Active CN106928825B (en) | 2017-03-28 | 2017-03-28 | High-dyeing-propertyalcohol alcohol acid paint vehicle |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108300207A (en) * | 2017-08-09 | 2018-07-20 | 安徽红桥金属制造有限公司 | With high coloring and weatherability electrification box paint vehicle and preparation method thereof |
| CN113524933A (en) * | 2021-08-09 | 2021-10-22 | 昆山兴昆彩印有限公司 | Green and environment-friendly printing process method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050137294A1 (en) * | 2003-12-23 | 2005-06-23 | Capstone Engineering Ltd. | Water-soluble alkyd resin composition and paint produced using the same |
| CN101724139A (en) * | 2008-10-23 | 2010-06-09 | 广东巴德士化工有限公司 | Light alkyd resin for interior decoration and furniture coating and preparation method thereof |
| CN103254747A (en) * | 2013-05-13 | 2013-08-21 | 重庆知德文化传播有限公司 | High-dyeing-property alkyd paint and application thereof |
| CN103756544A (en) * | 2014-01-26 | 2014-04-30 | 一远电子科技有限公司 | Polyurethane three-proofing coating |
-
2017
- 2017-03-28 CN CN201710192773.8A patent/CN106928825B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050137294A1 (en) * | 2003-12-23 | 2005-06-23 | Capstone Engineering Ltd. | Water-soluble alkyd resin composition and paint produced using the same |
| CN101724139A (en) * | 2008-10-23 | 2010-06-09 | 广东巴德士化工有限公司 | Light alkyd resin for interior decoration and furniture coating and preparation method thereof |
| CN103254747A (en) * | 2013-05-13 | 2013-08-21 | 重庆知德文化传播有限公司 | High-dyeing-property alkyd paint and application thereof |
| CN103756544A (en) * | 2014-01-26 | 2014-04-30 | 一远电子科技有限公司 | Polyurethane three-proofing coating |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108300207A (en) * | 2017-08-09 | 2018-07-20 | 安徽红桥金属制造有限公司 | With high coloring and weatherability electrification box paint vehicle and preparation method thereof |
| CN113524933A (en) * | 2021-08-09 | 2021-10-22 | 昆山兴昆彩印有限公司 | Green and environment-friendly printing process method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106928825B (en) | 2019-05-07 |
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