CN106927697A - A kind of ground glass - Google Patents
A kind of ground glass Download PDFInfo
- Publication number
- CN106927697A CN106927697A CN201710114173.XA CN201710114173A CN106927697A CN 106927697 A CN106927697 A CN 106927697A CN 201710114173 A CN201710114173 A CN 201710114173A CN 106927697 A CN106927697 A CN 106927697A
- Authority
- CN
- China
- Prior art keywords
- parts
- ground glass
- glass layer
- pvb films
- frosted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Joining Of Glass To Other Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to glass technology field, and in particular to a kind of ground glass.It is composited by PVB films by glass-base and ground glass layer, the raw material of the ground glass layer includes by weight：70 parts of quartz sand, 10 15 parts of soda ash, 35 parts of calcite, 1 1.5 parts of fluorite, 23 parts of saltcake, 10 15 parts of sodium nitrate, 56 parts of manganese powder, 0.1 0.3 parts of antimony oxide, 0.5 1 parts of bamboo carbon powder, 35 parts of borax, 0.5 1 parts of fluotitanic acid calcium, 24 parts of zinc oxide, 0.5 1 parts of carborundum, 0.5 1 parts of ferroso-ferric oxide.The ground glass that the present invention is provided has intensity higher, can improve overall toughness by the characteristic of PVB films.The ground glass layer of the ground glass processes relatively difficult problem for machinery frosted at present, is understood from formula certainly, reduces the difficulty of mechanical frosted treatment, frosted finish effect that can be fine and smooth at treatment on ground glass layer with comparalive ease.
Description
Technical field
The present invention relates to glass technology field, and in particular to a kind of ground glass.
Background technology
Ground glass makes light produce diffusing reflection due to rough surface, the characteristics of perspective with printing opacity, and makes room light
Line is soft.It is commonly used for the cut-off of toilet, bathroom, lavatory, office, corridor etc., can also make the plate face of blackboard, typically
Ground glass be made up of quartz sand, soda ash, lime stone and saltcake raw material, this ground glass intensity is not high, is slightly hit
Hit and crack.
In addition, current ground glass is difficult to form finer and smoother frosted finish effect when using hydrofluoric acid treatment, adopting
When being processed with machinery hair, glass surface can be caused excessively crisp again, treatment quality cannot be ensured.
The content of the invention
The invention aims to solve the above problems, there is provided a kind of ground glass.
In order to reach foregoing invention purpose, the present invention uses following technical scheme：
A kind of ground glass, is composited by glass-base and ground glass layer by PVB films, the original of the ground glass layer
Material includes by weight：70 parts of quartz sand, soda ash 10-15 parts, calcite 3-5 parts, fluorite 1-1.5 parts, saltcake 2-3 parts, nitre
Sour sodium 10-15 parts, manganese powder 5-6 parts, antimony oxide 0.1-0.3 parts, bamboo carbon powder 0.5-1 parts, borax 3-5 parts, fluotitanic acid calcium 0.5-1
Part, zinc oxide 2-4 parts, carborundum 0.5-1 parts, ferroso-ferric oxide 0.5-1 parts.
Used as preferred scheme, the raw material of the ground glass layer includes by weight：70 parts of quartz sand, soda ash 10
Part, 5 parts of calcite, 1 part of fluorite, 3 parts of saltcake, 10 parts of sodium nitrate, 6 parts of manganese powder, 0.1 part of antimony oxide, 1 part of bamboo carbon powder, borax 3
Part, 1 part of fluotitanic acid calcium, 2 parts of zinc oxide, 1 part of carborundum, 0.5 part of ferroso-ferric oxide.
Used as preferred scheme, PVB films used are prepared from by each component of following parts by weight：Polyvinyl alcohol contracts
100 parts of butyraldehyde, 15 parts of makrolon, 8 parts of maleimide, 5 parts of allyl glycidyl ether, bisphenol A diglycidyl ether 1.5
Part, 0.5 part of potassium fluorozirconate, 2 parts of diisopropyl ethanolamine, 5 parts of polybutylene terephthalate (PBT), 3 parts of auxiliary addition agent, polyethylene
3 parts of alcohol, 5 parts of disodium hydrogen phosphate, 0.3 part of ferroso-ferric oxide, maleic anhydride 2 parts of compatilizer of grafting.
Used as preferred scheme, PVB films used also include styrene 40-43 parts.
Used as preferred scheme, PVB films used also include high temperature modified dose 3-5 parts, and described high temperature modified dose by weight
Amount number meter includes：Chlorinated biphenyl 3-5 parts, sldium lauryl sulfate 1-3 parts, 4,4'- DADPS 0.5-2 parts, poly- methyl
Methyl acrylate 1-2 parts.
Due to this case use glass-base and ground glass layer carry out it is compound after mode be prepared into ground glass,
Therefore, in order that obtaining ground glass layer can more easily carry out frosted treatment, formula has specially been carried out to ground glass changes
Enter, the ground glass that the present invention is provided can adapt to hydrofluoric acid and mechanical treatment obtains frosted finish effect, particular for mechanical treatment
When, surface of ordinary glass is more crisp, solves the problems, such as the finer and smoother effect in the not disposable place of simple glass.
The adhesion problem of the latter two is combined with glass-base in order to solve ground glass layer, specifically provide it is a kind of practical and
The PVB films that the ground glass layer that the present invention is provided is combined with glass-base, the PVB films are directed to frosted glass of the invention
The feature of glass layer, is improved current PVB film formulas, by the way that after improvement, the PVB films can be ageing-resistant, buffering
Effect preferably, can eliminate the part stress of glass surface, it is to avoid ground glass layer causes whole glass in frosted processing procedure
Glass is damaged；Certainly, on the one hand it is because ground glass layer disclosure satisfy that mechanical frosted treatment why using ground glass layer
Need, on the other hand because its cost is improved, its thickness certainly will be reduced, therefore the breakage of frosted process can be caused, and coordinate this
The PVB films for providing are provided, the problem can be solved.The PVB films well can enter glass-base with ground glass layer
Row is combined, and by the high tenacity of PVB itself, the external force that will be put on ground glass layer is discharged, right to a certain extent
Whole ground glass plays a part of protection.
Compared with prior art, beneficial effect is the present invention：The ground glass that the present invention is provided has intensity higher, energy
Overall toughness is enough improved by the characteristic of PVB films.The ground glass layer of the ground glass is for the treatment of machinery frosted at present
Relatively difficult problem, is understood certainly from formula, reduces the difficulty of mechanical frosted treatment, can with comparalive ease in mill
Frosted finish effect fine and smooth at treatment on sand glass layer.
Specific embodiment
Explanation is further described to technical scheme below by specific embodiment.
If without specified otherwise, the raw material employed in embodiments of the invention is raw material commonly used in the art, implements
Method employed in example, is the conventional method of this area.
Embodiment 1：
A kind of ground glass, is composited by glass-base and ground glass layer by PVB films, the original of the ground glass layer
Material meter by weight includes：70 parts of quartz sand, 10 parts of soda ash, 5 parts of calcite, 1 part of fluorite, 3 parts of saltcake, 10 parts of sodium nitrate,
6 parts of manganese powder, 0.1 part of antimony oxide, 1 part of bamboo carbon powder, 3 parts of borax, 1 part of fluotitanic acid calcium, 2 parts of zinc oxide, 1 part of carborundum, four oxidations
0.5 part of three-iron.
Embodiment 2：
A kind of ground glass, is composited by glass-base and ground glass layer by PVB films, the original of the ground glass layer
Material includes by weight：50 parts of quartz sand, 15 parts of soda ash, 3 parts of calcite, 1.5 parts of fluorite, 2 parts of saltcake, 15 parts of sodium nitrate,
5 parts of manganese powder, 0.3 part of antimony oxide, 0.5 part of bamboo carbon powder, 5 parts of borax, 0.5 part of fluotitanic acid calcium, 4 parts of zinc oxide, 0.5 part of carborundum,
1 part of ferroso-ferric oxide.
Embodiment 3：
A kind of ground glass, is composited by glass-base and ground glass layer by PVB films, the original of the ground glass layer
Material includes by weight：50 parts of quartz sand, 10 parts of soda ash, 5 parts of calcite, 1 part of fluorite, 3 parts of saltcake, 10 parts of sodium nitrate, manganese
6 parts of powder, 0.1 part of antimony oxide, 1 part of bamboo carbon powder, 3 parts of borax, 1 part of fluotitanic acid calcium, 2 parts of zinc oxide, 1 part of carborundum, four oxidations three
0.5 part of iron.
Embodiment 4：
The ground glass of embodiment 1-3, the PVB films for being used
It is prepared from by following each component：100 parts of polyvinyl butyral resin, 15 parts of makrolon, 8 parts of maleimide, allyl
5 parts of base glycidol ether, 1.5 parts of bisphenol A diglycidyl ether, 0.5 part of potassium fluorozirconate, 2 parts of diisopropyl ethanolamine gathers to benzene
5 parts of dioctyl phthalate butanediol ester, 3 parts of auxiliary addition agent, 3 parts of polyvinyl alcohol, 5 parts of disodium hydrogen phosphate, 0.3 part of ferroso-ferric oxide, Malaysia
Acid anhydrides is grafted 2 parts of compatilizer.
Embodiment 5：
On the basis of embodiment 4,40 parts of styrene is added.
Embodiment 6：
On the basis of embodiment 4 or 5, high temperature modified dose 3 parts are added, wherein, high temperature modified dose of the component for including and specific
Match and be：3 parts of chlorinated biphenyl, 3 parts of sldium lauryl sulfate, 4,4'- 0.5 part of DADPSs, polymethyl methacrylate 1-2
Part.
Embodiment 7：
On the basis of embodiment 4 or 5, high temperature modified dose 5 parts are added, wherein, high temperature modified dose of the component for including and specific
Match and be：5 parts of chlorinated biphenyl, 1 part of sldium lauryl sulfate, 4,4'- 2 parts of DADPSs, polymethyl methacrylate 1-2
Part.
Ground glass layer is used as by the glass prepared using embodiment 1-3, compared to simple glass, is used on its surface
Mechanical system carries out frosted intractability reduction, further, it is possible to carry out finer and smoother frosted finish effect treatment.By preparing appearance
The glass of frosted treatment is easily carried out, ground glass layer can be carried out being compounded to form frosted glass with other any type of glass
Glass, makes entirety reach frosted finish effect.Also, using the PVB films of embodiment 4-7, can preferably protect ground glass layer not
It is damaged, improves the service life of ground glass layer.
Compared with embodiment 4 and 5, the PVB films of embodiment 6 and 7 use accelerated aging test, its heat resistant time
It is 600h, and under similarity condition, the ageing-resistant time of the PVB films of embodiment 4 and 5 is only 500-550h, and in the condition
Under the heat resistant time only 350-400h of common PVB films that carries out.
For the caking property of PVB films of the present invention, its adhesion strength compares common PVB films and improves 15-20%, thus,
The thickness of PVB films can be reduced, performance impact of the PVB films to overall glass is reduced as far as possible.
Claims (5)
1. a kind of ground glass, it is characterised in that be composited by PVB films by glass-base and ground glass layer, it is described
The raw material of ground glass layer includes by weight：50 parts of quartz sand, soda ash 10-15 parts, calcite 3-5 parts, fluorite 1-1.5
Part, saltcake 2-3 parts, sodium nitrate 10-15 parts, manganese powder 5-6 parts, antimony oxide 0.1-0.3 parts, bamboo carbon powder 0.5-1 parts, borax 3-5 parts,
0.5-1 parts, zinc oxide 2-4 parts, carborundum 0.5-1 parts, ferroso-ferric oxide 0.5-1 parts of fluotitanic acid calcium.
2. a kind of ground glass according to claim 1, it is characterised in that the raw material of the ground glass layer is by weight
Meter includes：50 parts of quartz sand, 10 parts of soda ash, 5 parts of calcite, 1 part of fluorite, 3 parts of saltcake, 10 parts of sodium nitrate, 6 parts of manganese powder, oxidation
0.1 part of antimony, 1 part of bamboo carbon powder, 3 parts of borax, 1 part of fluotitanic acid calcium, 2 parts of zinc oxide, 1 part of carborundum, 0.5 part of ferroso-ferric oxide.
3. a kind of ground glass according to claim 1 and 2, it is characterised in that PVB films used are by following weight portion
Several each components are prepared from：100 parts of polyvinyl butyral resin, 15 parts of makrolon, 8 parts of maleimide, allyl glycidyl
5 parts of glycerin ether, 1.5 parts of bisphenol A diglycidyl ether, 0.5 part of potassium fluorozirconate, 2 parts of diisopropyl ethanolamine, poly terephthalic acid
5 parts of butanediol ester, 3 parts of auxiliary addition agent, 3 parts of polyvinyl alcohol, 5 parts of disodium hydrogen phosphate, 0.3 part of ferroso-ferric oxide, maleic anhydride connects
2 parts of compatilizer of branch.
4. a kind of ground glass according to claim 3, it is characterised in that also including styrene 40-43 parts.
5. a kind of ground glass according to claim 3, it is characterised in that also including high temperature modified dose 3-5 parts, the height
Warm modifying agent count by weight including：Chlorinated biphenyl 3-5 parts, sldium lauryl sulfate 1-3 parts, 4,4'- DADPSs
0.5-2 parts, polymethyl methacrylate 1-2 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710114173.XA CN106927697A (en) | 2017-02-28 | 2017-02-28 | A kind of ground glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710114173.XA CN106927697A (en) | 2017-02-28 | 2017-02-28 | A kind of ground glass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106927697A true CN106927697A (en) | 2017-07-07 |
Family
ID=59423644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710114173.XA Pending CN106927697A (en) | 2017-02-28 | 2017-02-28 | A kind of ground glass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106927697A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112208810A (en) * | 2020-10-28 | 2021-01-12 | 漳州市燕南工贸有限公司 | Glue production line and production method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205115A (en) * | 2006-12-22 | 2008-06-25 | 陈庆雄 | Yellow transparent glass |
| CN101939267A (en) * | 2008-02-08 | 2011-01-05 | 康宁股份有限公司 | Damage resistant chemically-toughened protective cover glass |
| CN105669028A (en) * | 2016-01-20 | 2016-06-15 | 广西丛欣实业有限公司 | Ground glass |
| CN106277853A (en) * | 2016-08-08 | 2017-01-04 | 常熟市赛蒂镶嵌玻璃制品有限公司 | Laminated glass |
| CN106273916A (en) * | 2016-08-04 | 2017-01-04 | 浙江飞越洁具制造有限公司 | A kind of bulletproof glass |
-
2017
- 2017-02-28 CN CN201710114173.XA patent/CN106927697A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205115A (en) * | 2006-12-22 | 2008-06-25 | 陈庆雄 | Yellow transparent glass |
| CN101939267A (en) * | 2008-02-08 | 2011-01-05 | 康宁股份有限公司 | Damage resistant chemically-toughened protective cover glass |
| CN105669028A (en) * | 2016-01-20 | 2016-06-15 | 广西丛欣实业有限公司 | Ground glass |
| CN106273916A (en) * | 2016-08-04 | 2017-01-04 | 浙江飞越洁具制造有限公司 | A kind of bulletproof glass |
| CN106277853A (en) * | 2016-08-08 | 2017-01-04 | 常熟市赛蒂镶嵌玻璃制品有限公司 | Laminated glass |
Non-Patent Citations (1)
| Title |
|---|
| 白振中 等编著: "《工程玻璃深加工技术手册》", 30 April 2014, 北京：中国建材工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112208810A (en) * | 2020-10-28 | 2021-01-12 | 漳州市燕南工贸有限公司 | Glue production line and production method |
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Application publication date: 20170707 |
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