CN106913136A - A kind of silk quilt with lasting thermal effect and preparation method thereof - Google Patents
A kind of silk quilt with lasting thermal effect and preparation method thereof Download PDFInfo
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- CN106913136A CN106913136A CN201710241741.2A CN201710241741A CN106913136A CN 106913136 A CN106913136 A CN 106913136A CN 201710241741 A CN201710241741 A CN 201710241741A CN 106913136 A CN106913136 A CN 106913136A
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/02—Bed linen; Blankets; Counterpanes
- A47G9/0207—Blankets; Duvets
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic System
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/57—Sulfates or thiosulfates of elements of Groups 3 or 13 of the Periodic System, e.g. alums
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
- D06M11/65—Salts of oxyacids of nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A kind of silk quilt with lasting thermal effect and preparation method thereof, is related to home textile technical field.A kind of preparation method of the silk quilt with lasting thermal effect, it includes：Temperature be 30~50 DEG C, pH be 2~5 under the conditions of, after adding the 30~60min of fixative cocoon cooking for carrying out Sericin Gumming treatment to silk, through washing obtain the first silk fiber；Fixative includes sticking agent and accelerator, and sticking agent includes the compound containing rare earth ion, and accelerator includes ammonium class compound；The second silk fiber is obtained after first silk fiber is mixed with refining agent；Second silk fiber is organized into the first mulberry silk layer.The present invention also proposes a kind of silk quilt with lasting thermal effect, is made up of above-mentioned preparation method.The preparation method is simple, can make pro-skin, silk quilt wear-resistant, with lasting thermal effect.
Description
Technical field
The present invention relates to home textile technical field, and more particularly to a kind of silk quilt and its making with lasting thermal effect
Method.
Background technology
Silk quilt, it is most ancient as China and follow traditional bedroom quilt so far, in existing more than the 5500 years history of China.Silk
By with natural silk fiber as raw material, due to having health-care efficacy to human body skin and angiocarpy, with it is excellent it is warming, ventilative,
The characteristics such as moisture absorption, softness, it is deep to be welcome by domestic and international consumer, it is also China's Traditional Silk product and important product commodity.
Contain a certain amount of silk gum in silk fiber, because silk gum performance is active, the silk quilt of traditional handicraft processing, for a long time
Easy hardened jaundice after use, elasticity, warmth retention property decline.
The content of the invention
It is an object of the invention to provide a kind of preparation method of the silk quilt with lasting thermal effect, the preparation method
Simply, pro-skin, persistently warming, anti abrasive silk quilt can be made.
Another object of the present invention is to provide a kind of silk quilt with lasting thermal effect, the silk quilt is by above-mentioned system
Obtained as method, the silk quilt has a wear-resistant, good warmth retention effect, the characteristics of warming time is long.
The present invention is solved its technical problem and is realized using following technical scheme.
The present invention proposes a kind of preparation method of the silk quilt with lasting thermal effect, and it includes：Temperature be 30~
50 DEG C, pH be 2~5 under the conditions of, after adding the 30~60min of fixative cocoon cooking for carrying out Sericin Gumming treatment to silk, warp
Washing obtains the first silk fiber；Fixative includes sticking agent and accelerator, and sticking agent includes the compound containing rare earth ion,
Accelerator includes ammonium class compound；The second silk fiber is obtained after first silk fiber is mixed with refining agent；Second silk fiber is whole
Manage into the first mulberry silk layer.
The present invention proposes a kind of silk quilt with lasting thermal effect, is made up of above-mentioned preparation method.
A kind of beneficial effect of silk quilt with lasting thermal effect proposed by the present invention and preparation method thereof is：
In the present invention, a kind of preparation method of the silk quilt with lasting thermal effect, it is main from containing rare earth metal
Ion is sticking agent, is combined with the coordinate bond of polar group on silk gum and fibroin by rare earth ion, reduces silk gum
It is water-soluble.On the one hand the intensity of silk fiber is enhanced, the intensity and thermal property of silk quilt is improved；Another aspect silk gum can be obtained
The reasonable utilization arrived, greatlys save process costs.
Secondly, the connection of silk fiber and silk fiber can be strengthened by wire drawing process by the first mulberry silk layer after Sericin Gumming
Stability, reduces gap, can significantly improve the thermal property of silk quilt.
A kind of silk quilt with lasting thermal effect, is mainly made up of above-mentioned preparation method, and the silk quilt has wear-resisting
Damage, good warmth retention effect, the characteristics of warming time is long.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below will be in the embodiment of the present invention
Technical scheme be clearly and completely described.Unreceipted actual conditions person, builds according to normal condition or manufacturer in embodiment
The condition of view is carried out.Agents useful for same or the unreceipted production firm person of instrument, are the conventional product that can be obtained by commercially available purchase
Product.
A kind of silk quilt with lasting thermal effect of the embodiment of the present invention and preparation method thereof is carried out below specific
Explanation.
A kind of preparation method of silk quilt with lasting thermal effect provided in an embodiment of the present invention, it includes：In temperature
It is 30~50 DEG C to spend, pH be 2~5 under the conditions of, add for Sericin Gumming treatment is carried out to silk fixative cocoon cooking 30~
After 60min, the first silk fiber is obtained through washing；Fixative include sticking agent and accelerator, sticking agent include containing rare earth metal from
The compound of son, accelerator includes ammonium class compound；The second silk fiber is obtained after first silk fiber is mixed with refining agent；By
Two silk fibers are organized into the first mulberry silk layer.
Silk is mainly made up of fibroin with silk gum two parts.Fibroin is a kind of fibrous proteins, and physicochemical property is very steady
It is fixed, water absorption and swelling is only capable of under wet heat condition, it is the main body of cocoon fiber.Silk gum is by 18 kinds of human body institutes such as glycine, serine
The amino acid composition for needing, it is quite similar with human collagen albumen, there is good compatibility with human body skin, it is the height of very high-quality
Molecular material.But albumen is a kind of natural aqueous globulin, and mutability, yellowing under wet heat condition rise to cocoon fiber and embrace
Cooperation is used.
In traditional silk quilt production technology, in order to obtain more soft silk quilt, often using refining process, will about
80% silk gum removal.But in embodiments of the present invention, from being sticking agent containing rare earth ion, ammonium salt compounds are
Set accelerator, is combined, with the coordinate bond of polar group on silk gum and fibroin by rare earth ion so as to reduce silk gum
Water solubility, can not only strengthen the intensity of silk fiber, improve the thermal property of silk quilt, moreover it is possible to rationally utilize silk gum, significantly
Process costs are saved.
Secondly, the surface of the first mulberry silk layer is pulled out into the first silk and by obtaining silk quilt after the operations such as arrangement connection；
Can strengthen the stable connection of silk fiber and silk fiber by wire drawing process by the first mulberry silk layer obtained after Sericin Gumming treatment
Property, reduce gap, further improve the intensity and thermal property of silk quilt.
First mulberry silk layer wire drawing process mode has various, it is preferable that stack multiple first mulberry silk layers, by adjacent first
The first silk that silk layer surface is pulled out is attached.This kind of processing mode, can strengthen the company between adjacent first mulberry silk layer
Connect stability.
Further, in other embodiments of the present invention, the first mulberry silk layer is clipped in two non-organizine in process of cocoon
Between second mulberry silk layer of glue fixation treatment, the first silk that the relative first surface of the first mulberry silk layer and second surface are pulled out
Connected with the second silk that two adjacent the second silk layer surfaces are pulled out respectively.
It should be noted that the second mulberry silk layer is without Sericin Gumming treatment, by commonsense method, namely not using silk gum
And the mulberry silk layer being made；In other words, except not carrying out Sericin Gumming treatment in cocoon cooking, other step methods and the embodiment of the present invention
The method of offer is consistent.
It is to be understood that the first mulberry silk layer is wrapped between two the second mulberry silk layers.Positioned at two second silkworms in outside
Silk layer can not only protect the first mulberry silk layer positioned at inner side not to be destroyed, simultaneously because the first mulberry silk layer by Sericin Gumming at
Reason, the intensity of the first mulberry silk layer is bigger, can not only make the silk quilt made wear-resistant, while silk quilt thermal property is more
It is good.
In this embodiment, the compound containing rare earth ion is the rare earth metal containing cerium ion, lanthanum ion or neodymium ion
Salt.The concentration of the compound of its rare earth ion is preferred for 0.03~0.12g/ml.Wherein, using the change containing rare earth metal
Compound can not only improve the washable rate of silk quilt, and the compound containing rare earth ion can also be reused, and reduce concise dirt
The processing cost of water.Preferably, from the rare earth metal salt containing cerium ion.Accelerator selects ammonium salt compounds, it is preferable that promote
Enter the ammonium sulfate of agent selection.Further, refining agent selects enuatrol.
Further, in preferred embodiments of the present invention, the coating agent containing ceramic is coated on the first silk
On layer.
Ceramic can give off 8-12 μm of far infrared at normal temperatures.After far infrared is absorbed by the body, body can be made
Interior hydrone produces resonance, makes water molecule activation, strengthens its intermolecular adhesion, so that biological big point of activation of protein etc.
Son, makes biological cell be in highest vibration level.Because biological cell produces resonance effects, far infrared heat energy can be delivered to
The subcutaneous deeper part of human body, following deep layer temperature rises, and the warm of generation is distributed from inside to outside.
In an embodiment of the present invention, the coating agent containing ceramic is coated on the first mulberry silk layer, ceramic
Can be strongly adhered on the first mulberry silk layer, and the mode being coated with can cause that ceramic is equably painted on the first silk
On layer, ceramic can give off more uniform far infrared so that the thermal effect of silk quilt is more prominent.
Preferably, the preparation method of coating agent includes：Polymethyl methacrylate is dissolved in benzole soln, at 75-80 DEG C
Water bath condition under heat to obtain mixed liquor, mixed liquor is mixed with ceramic, ceramic and polymethyl methacrylate
Weight ratio is 1:20-50.
Polymethyl methacrylate, is the material of asepsis environment-protecting, is dissolved in organic solvent.Because it has hygroscopicity, therefore
Using preceding carrying out dried process.Polymethyl methacrylate is dissolved in benzole soln, and is added under 75-80 DEG C of water bath condition
Heat, carries out heating water bath in the temperature range, enables to polymethyl methacrylate to be sufficiently and uniformly dispersed in benzene
In solution, ceramic is added in mixed liquor, ceramic has dispersiveness well, can preferably be dispersed in mixing
In liquid, the coating agent containing ceramic is obtained final product.
Because containing polymethyl methacrylate in coating agent, thus with viscosity, in order to ensure coating agent viscosity foot
Reach, preferably ceramic can be bonded on the first mulberry silk layer, therefore selection ceramic and institute's polymethylacrylic acid
The weight ratio of methyl esters is 1:The scheme of 20-50.
Preferably, ceramic and the weight ratio of polymethyl methacrylate are 1:30-40.The proportion is inventor
With reference to the preferred value that itself experience and many experiments are obtained, under the proportioning, the viscosity of coating agent is more preferably.
Due to also containing benzene in the coating agent in the embodiment of the present invention, benzene has volatile feature, is connect for a long time in human body
In the case of touching, certain injury can be caused to body, therefore, in an embodiment of the present invention, will be coated with the first mulberry silk layer
After upper coating agent, also including carrying out radiant heating to the first mulberry silk layer.Benzene in coating agent is volatilized from silk quilt.
It should be noted that the temperature of radiant heating is no more than the temperature that silk can bear.In implementation of the invention
In example, radiant heating can select iodine-tungsten lamp heating, heating by infrared radiation or ceramic heat.It should be noted that at other
In embodiment, can also be using the mode of other radiant heatings, as long as the effect of quick removal benzene solvent can be reached.
The embodiment of the present invention additionally provides a kind of silk quilt with lasting thermal effect, is made up of the above method, the silkworm
Silk is good by warming effect, can continue warming effect.
Feature of the invention and performance are described in further detail with reference to embodiments.
Embodiment 1
A kind of preparation method of the silk quilt with lasting thermal effect is present embodiments provided, it includes：
It is 30 DEG C in temperature, pH is 2, adds fixative (sticking agent：Cerous nitrate；Accelerator：Ammonium sulfate) treatment cocoon cooking
After 30min, the first silk fiber is obtained through washing, after the first silk fiber is mixed with refining agent, alkali cleaning obtains the second silk fiber, profit
The first mulberry silk layer is made with the second silk fiber；Afterwards silk quilt is made using the first mulberry silk layer.
The present embodiment additionally provides a kind of silk quilt with lasting thermal effect, is made up of above-mentioned preparation method.
Embodiment 2
A kind of preparation method of the silk quilt with lasting thermal effect is present embodiments provided, it includes：
In cocoon cooking, keeping temperature is 40 DEG C, and pH is 3, adds fixative (sticking agent：Cerous sulfate；Accelerator：Ammonium sulfate)
Treatment 40min, obtains the first silk fiber after washing；
After first silk fiber is mixed with refining agent enuatrol, the degumming 1h at 90~100 DEG C, bath raio 1:50, alkali afterwards
10min is washed, then obtains the second silk fiber after washing, the first mulberry silk layer is made using the second silk fiber；
Multiple first mulberry silk layers are stacked, the first silk that the first adjacent silk layer surface is pulled out is attached and is made
Silk quilt.
The present embodiment additionally provides a kind of silk quilt with lasting thermal effect, is made up of above-mentioned preparation method.
Embodiment 3
A kind of preparation method of the silk quilt with lasting thermal effect is present embodiments provided, it includes：
In cocoon cooking, keeping temperature is 50 DEG C, and pH is 5, adds fixative (sticking agent：Cerous sulfate；Accelerator：Ammonium sulfate)
Treatment 40min, obtains the first silk fiber after washing；
After first silk fiber is mixed with refining agent, the degumming 1h at 90~100 DEG C, bath raio 1:50, alkali cleaning afterwards
10min, then the second silk fiber is obtained after washing, it is made the first mulberry silk layer using the second silk fiber；
After coating agent containing ceramic is coated on into the first mulberry silk layer, radiant heating is carried out；
The first mulberry silk layer after multiple irradiation is stacked, the first silk that the first adjacent silk layer surface is pulled out is carried out
Connection.
The present embodiment additionally provides a kind of silk quilt with lasting thermal effect, is made up of above-mentioned preparation method.
Embodiment 4
A kind of preparation method of the silk quilt with lasting thermal effect is present embodiments provided, it includes：
In cocoon cooking, keeping temperature is 40 DEG C, and pH is 3, adds fixative (sticking agent：Rare earth metal salt containing lanthanum ion；
Accelerator：Ammonium class compound) treatment 40min, the first silk fiber is obtained after washing；
After first silk fiber is mixed with refining agent, the degumming 1h at 90~100 DEG C, bath raio 1:50, alkali cleaning afterwards
10min, then the second silk fiber is obtained after washing, it is made the first mulberry silk layer using the second silk fiber；
After coating agent containing ceramic is coated on the first mulberry silk layer, radiant heating is carried out；
The first mulberry silk layer after by irradiation is clipped in two in process of cocoon without the second mulberry silk layer of Sericin Gumming treatment
Between, the first silk that the relative first surface of the first mulberry silk layer and second surface are pulled out respectively with two adjacent the second silkworms
The second silk connection that silk layer surface is pulled out.
The present embodiment additionally provides a kind of silk quilt with lasting thermal effect, is made up of above-mentioned preparation method.
Embodiment 5
A kind of preparation method of the silk quilt with lasting thermal effect is present embodiments provided, it includes：
In cocoon cooking, keeping temperature is 40 DEG C, and pH is 3, adds fixative (sticking agent：Cerous sulfate；Accelerator：Ammonium sulfate)
Treatment 40min, obtains the first silk fiber after washing；
After first silk fiber is mixed with refining agent enuatrol, the degumming 1h at 90~100 DEG C, bath raio 1:50, alkali afterwards
10min is washed, then obtains the second silk fiber after washing, the first mulberry silk layer is made using the second silk fiber；
Coating agent containing ceramic is coated on the first mulberry silk layer, radiant heating is carried out；Wherein, the system of coating agent
Preparation Method includes：Polymethyl methacrylate is dissolved in benzole soln, mixed liquor is heated to obtain under 75-80 DEG C of water bath condition,
Mixed liquor is mixed with ceramic, ceramic is 1 with the weight ratio of polymethyl methacrylate:20-50；
The first mulberry silk layer after multiple irradiation is stacked, the first silk that the first adjacent silk layer surface is pulled out is carried out
Connection.
The present embodiment additionally provides a kind of silk quilt with lasting thermal effect, is made up of above-mentioned preparation method.
Embodiment 6
A kind of preparation method of the silk quilt with lasting thermal effect is present embodiments provided, it includes：
In cocoon cooking, keeping temperature is 40 DEG C, and pH is 3, adds fixative (sticking agent：Rare earth metal salt containing neodymium ion；
Accelerator：Ammonium sulfate) treatment 40min, the first silk fiber is obtained after washing；
After first silk fiber is mixed with refining agent enuatrol, the degumming 1h at 90~100 DEG C, bath raio 1:50, alkali afterwards
10min is washed, then obtains the second silk fiber after washing, the first mulberry silk layer is made using the second silk fiber；
Coating agent containing ceramic is coated on the first mulberry silk layer, radiant heating is carried out；Wherein, the system of coating agent
Preparation Method includes：Polymethyl methacrylate is dissolved in benzole soln, mixed liquor is heated to obtain under 75-80 DEG C of water bath condition,
Mixed liquor is mixed with ceramic, ceramic is 1 with the weight ratio of polymethyl methacrylate:20-50；
The first mulberry silk layer after by irradiation is clipped in two in process of cocoon without the second mulberry silk layer of Sericin Gumming treatment
Between, the first silk that the relative first surface of the first mulberry silk layer and second surface are pulled out respectively with two adjacent the second silkworms
The second silk connection that silk layer surface is pulled out.
The present embodiment additionally provides a kind of silk quilt with lasting thermal effect, is made up of above-mentioned preparation method.
The persistently warming power experiment of test example 1
The silk quilt and silk quilt commonly on the market provided embodiment 5 using the mode of human body analog sleeping activity
(control group) carries out interim Wearing Simulated Test (access times abrasion in respectively 1 year, access times abrasion in 2 years, 30 years number of times
Abrasion).
Warmth retention property after current abrasion every time is contrasted.Wherein, silk quilt species, grade, size and use environment
Unanimously；Test number (TN) is more than 100 times, the results are shown in Table 1.
Table 1 simulates lasting warming power result
Can be obtained according to table 1, the silk quilt that embodiment 5 is provided simulates 5 in the simulation persistently experiment of warming power with control group
Temperature drop after year is compared, and the silk quilt that embodiment 5 is provided warming temperature can be maintained at 32 DEG C -34 in 30 years of simulation
DEG C, illustrate that the thermal property of the silk quilt that the embodiment of the present invention 5 is provided is good, while thermal property is persistently, it is wear-resistant.
Embodiments described above is a part of embodiment of the invention, rather than whole embodiments.Reality of the invention
The detailed description for applying example is not intended to limit the scope of claimed invention, but is merely representative of selected implementation of the invention
Example.Based on the embodiment in the present invention, what those of ordinary skill in the art were obtained under the premise of creative work is not made
Every other embodiment, belongs to the scope of protection of the invention.
Claims (10)
1. a kind of preparation method of the silk quilt with lasting thermal effect, it is characterised in that it includes：It is 30~50 in temperature
DEG C, pH be 2~5 under the conditions of, add for silk is carried out Sericin Gumming treatment fixative cocoon cooking process 30~60min after,
The first silk fiber is obtained through washing；The fixative include sticking agent and accelerator, the sticking agent include containing rare earth metal from
The compound of son, the accelerator includes ammonium class compound；Second is obtained after first silk fiber is mixed with refining agent
Fiber；Second silk fiber is organized into the first mulberry silk layer.
2. the preparation method of the silk quilt with lasting thermal effect according to claim 1, it is characterised in that by multiple
First mulberry silk layer is stacked, and the first silk that adjacent the first silk layer surface is pulled out is attached.
3. the preparation method of the silk quilt with lasting thermal effect according to claim 1, it is characterised in that will be described
First mulberry silk layer is stacked between being clipped in two the second mulberry silk layers without Sericin Gumming treatment in process of cocoon, by described first
The first silk that the relative first surface of mulberry silk layer and second surface are pulled out respectively with two adjacent the second mulberry silk layer tables
The second silk connection that face pulls out.
4. the preparation method of the silk quilt with lasting thermal effect according to claim 1, it is characterised in that described to contain
The compound of rare earth ion is the compound containing cerium ion.
5. the preparation method of the silk quilt with lasting thermal effect according to claim 4, it is characterised in that the rush
Enter agent from ammonium class compound.
6. the preparation method of the silk quilt with lasting thermal effect according to claim 1, it is characterised in that the essence
Enuatrol is selected in refining agent.
7. the preparation method of the silk quilt with lasting thermal effect according to claim 1, it is characterised in that obtain institute
After stating the first mulberry silk layer, also including the coating agent containing ceramic is coated on first mulberry silk layer.
8. the preparation method of the silk quilt with lasting thermal effect according to claim 7, it is characterised in that the painting
The preparation method of layer agent includes：Polymethyl methacrylate is dissolved in benzole soln, is heated under 75-80 DEG C of water bath condition
Mixed liquor, the mixed liquor is mixed with the ceramic, the weight of the ceramic and the polymethyl methacrylate
Amount is than being 1:20-50.
9. the preparation method of the silk quilt with lasting thermal effect according to claim 8, it is characterised in that described
After the upper coating agent of first mulberry silk layer coating, also including carrying out radiant heating to first mulberry silk layer.
10. a kind of silk quilt with lasting thermal effect, it is characterised in that having as described in claim any one of 1-9
The preparation method of the silk quilt of lasting thermal effect is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710241741.2A CN106913136A (en) | 2017-04-13 | 2017-04-13 | A kind of silk quilt with lasting thermal effect and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710241741.2A CN106913136A (en) | 2017-04-13 | 2017-04-13 | A kind of silk quilt with lasting thermal effect and preparation method thereof |
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Cited By (1)
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| CN109338482A (en) * | 2018-09-21 | 2019-02-15 | 苏州经贸职业技术学院 | A kind of preparation method of nanocomposite degumming and refining agent |
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Application publication date: 20170704 |