CN106906524B - 一种抵抗紫外线穿透的窗纱及其制备方法 - Google Patents

一种抵抗紫外线穿透的窗纱及其制备方法 Download PDF

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CN106906524B
CN106906524B CN201710105661.4A CN201710105661A CN106906524B CN 106906524 B CN106906524 B CN 106906524B CN 201710105661 A CN201710105661 A CN 201710105661A CN 106906524 B CN106906524 B CN 106906524B
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许云峰
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Suqian Hengda Textile Co.,Ltd.
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Abstract

本发明涉及家庭纺织用品技术领域，具体公开了一种抵抗紫外线穿透的窗纱，由竹纤维、玉米纤维、桑蚕丝、抗紫外线改性聚酯纤维和芳纶纤维制备而成，且窗纱的两侧涂覆有紫外线吸收层，抗紫外线改性聚酯纤维由聚对苯二甲酸乙二醇酯、聚对苯二甲酰对苯二胺、纳米二氧化钛、氧化铈、纳米高岭土、碳酸钙、超细陶瓷粉、乙烯基硅烷偶联剂、粘胶纤维制备而成。本发明的窗纱由紫外线吸收层吸收照射在窗纱表面的紫外线，然后通过抗紫外线改性聚酯纤维与竹纤维、玉米纤和桑蚕丝相互协同强化，进一步减弱紫外线的强度，使窗纱具有显著的抗紫外线性能，可以大大的减弱穿过窗纱的紫外线的强度，保护室内人员健康。

Description

一种抵抗紫外线穿透的窗纱及其制备方法
技术领域
本发明涉及家庭纺织用品技术领域，具体涉及一种抵抗紫外线穿透的窗纱。
背景技术
窗纱一般与窗帘搭配使用，给房间增添柔和、温磬的氛围。窗纱与窗帘相比采光效果好、透气通风，可以增加室内的光亮，既满足房间保护隐私的要求，又能满足人们对待日光、新鲜空气以及敞亮空间的要求。但是因为窗纱的透光性好也使紫外线通过窗纱照入房间内，影响室内人员的健康。中国专利CN105200565A，专利名称一种静电防微尘窗纱，申请日期2015年11月6日，公开了一种采用皮芯双层设计的纤维制备而成的窗纱，其中芯部的基体材料为聚对苯二酸乙二醇酯，以使窗纱具有抗紫外线功能。但是涤纶的抗紫外线功能一般，使窗纱的抗紫外线效果并不突出。
发明内容
针对窗纱的抵抗紫外线的性能一般使紫外线穿过窗纱对室内人员健康造成危害的问题，本发明的目的在于提供一种抵抗紫外线穿透的窗纱，具有良好的抗紫外线能力，可以减弱紫外线穿过窗纱的强度，保护室内人员健康。
本发明提供如下的技术方案：
一种抵抗紫外线穿透的窗纱，所述窗纱由以下重量份的纤维制备而成：竹纤维30～50份、玉米纤维15～20份、桑蚕丝15～20份、抗紫外线改性聚酯纤维80～100份、芳纶纤维30～50份，且窗纱的两侧涂覆有紫外线吸收层。
作为本发明的一种改进，所述抗紫外线改性聚酯纤维由以下重量份组份制备而成：聚对苯二甲酸乙二醇酯100～120份、聚对苯二甲酰对苯二胺50～60份、纳米二氧化钛4～6份、氧化铈2～3份、纳米高岭土2～5份、碳酸钙3～5份、超细陶瓷粉1～3份、乙烯基硅烷偶联剂0.7～1.1份、粘胶纤维0.2～0.5份。
一种抵抗紫外线穿透的窗纱的制备方法，包括以下步骤：
（1）制备抗紫外线改性聚酯纤维：将各原料组份充分混合后送入螺杆挤出机中挤出制得混合母粒，然后经湿法纺丝制成抗紫外线改性聚酯纤维；
（2）将抗紫外线聚酯纤维、竹纤维、玉米纤维、桑蚕丝和芳纶纤维经纺织制成窗纱；
（3）在窗纱两侧喷涂紫外线吸收液并通风干燥形成紫外线吸收层；
（4）将步骤（3）所得窗纱于-10 ℃环境中静置10分钟，再于60 ℃环境中静置10 分钟，如此高低温交替静置3～5次，制成抵抗紫外线穿透的窗纱。
作为本发明的一种改进，步骤（1）中螺杆挤出机各段的温度分别为：一段130～145℃、二段145～155 ℃、三段155～165 ℃、四段165～175 ℃、五段175～180 ℃、六段180～185 ℃，模头温度为175～180 ℃。
作为本发明的一种改进，步骤（1）中湿法纺丝的溶剂为二甲基甲酰胺与硫酸的混合水溶液，其质量分数分别为12%、16%。
作为本发明的一种改进，步骤（3）中所述紫外线吸收液由以下重量份组份制备而成：芦荟凝胶汁10～12份、黄芩苷6～8份、海藻胶1～2份、肉桂酸甲酯0.8～1.2份、紫胶3～5份、去离子水160～180份。
作为本发明的一种改进，步骤（3）中的喷涂密度为8～10 mL/m3，通风速率为3～5m/s，干燥温度23～25 ℃。
本发明的抵抗紫外线穿透的窗纱选择具有良好的抗紫外线能力的竹纤维、玉米纤维、桑蚕丝作为原料纤维，同时对聚对苯二甲酸乙二醇酯进行抗紫外线改性，提升聚对苯二甲酸乙二醇酯的抗紫外线能力，使窗纱能够有效降低穿过的紫外线的强度。抗紫外线改性聚酯纤维中的纳米二氧化钛、氧化铈、纳米高岭土、碳酸钙和超细陶瓷粉互相协同，可以有效吸收紫外线，减弱穿过窗纱的紫外线的强度。而紫外线吸收液中的芦荟凝胶、黄芩苷、海藻胶和肉桂酸甲酯在紫胶的作用下在窗纱表面形成薄膜，即紫外线吸收层，可吸收光照中的紫外线，减弱穿过窗纱的紫外线的强度，因此在本发明的窗纱上形成多层抗紫外线防护，首先是紫外线吸收层吸收照射在窗纱表面的紫外线，降低紫外线的照射强度，然后作为主要原料的抗紫外线改性聚酯纤维进一步吸收穿过紫外线吸收层的紫外线，进一步降低紫外线强度，并与竹纤维、玉米纤和桑蚕丝相互协同强化，使本发明的窗纱具有显著的抗紫外线性能，可以大大的减弱穿过窗纱的紫外线的强度。
本发明的有益效果如下：
本发明的抵抗紫外线穿透的窗纱，首先由紫外线吸收层吸收照射在窗纱表面的紫外线，降低紫外线的照射强度，然后通过抗紫外线改性聚酯纤维与竹纤维、玉米纤和桑蚕丝相互协同强化，进一步减弱紫外线的强度，使本发明的窗纱具有显著的抗紫外线性能，可以大大的减弱穿过窗纱的紫外线的强度，保护室内人员健康。
具体实施方式
下面就本发明的具体实施方式作进一步说明。
如无特别说明，本发明中所采用的原料均可从市场上购得或是本领域常用的，如无特别说明，下述实施例中的方法均为本领域的常规方法。
实施例1
一种抵抗紫外线穿透的窗纱，由以下纤维制备而成：竹纤维30 g、玉米纤维15 g、桑蚕丝15 g、抗紫外线改性聚酯纤维80 g、芳纶纤维30 g，且窗纱的两侧涂覆有紫外线吸收层，其中抗紫外线改性聚酯纤维由以下组份制备而成：聚对苯二甲酸乙二醇酯100 g、聚对苯二甲酰对苯二胺50 g、纳米二氧化钛4 g、氧化铈2 g、纳米高岭土2 g、碳酸钙3 g、超细陶瓷粉1 g、乙烯基硅烷偶联剂0.7 g、粘胶纤维0.2 g。
一种抵抗紫外线穿透的窗纱的制备方法，包括以下步骤：
（1）制备抗紫外线改性聚酯纤维：将各原料组份充分混合后送入螺杆挤出机中挤出制得混合母粒，然后经湿法纺丝制成抗紫外线改性聚酯纤维，其中螺杆挤出机各段的温度分别为：一段130～145 ℃、二段145～155 ℃、三段155～165 ℃、四段165～175 ℃、五段175～180 ℃、六段180～185 ℃，模头温度为175～180 ℃，湿法纺丝的溶剂为二甲基甲酰胺与硫酸的混合水溶液，质量分数分别为12%、16%；
（2）将抗紫外线聚酯纤维、竹纤维、玉米纤维、桑蚕丝和芳纶纤维经纺织制成窗纱；
（3）在窗纱两侧喷涂紫外线吸收液并通风干燥形成紫外线吸收层，紫外线吸收液的喷涂密度为8 mL/m3，通风速率为3 m/s，干燥温度23 ℃其中紫外线吸收液由以下组份制备而成：芦荟凝胶汁10 g、黄芩苷6 g、海藻胶1 g、肉桂酸甲酯0.8 g、紫胶3 g、去离子水160g；
（4）将步骤（3）所得窗纱于-10 ℃环境中静置10分钟，再于60 ℃环境中静置10 分钟，如此高低温交替静置3次，制成抵抗紫外线穿透的窗纱。
实施例2
一种抵抗紫外线穿透的窗纱，由以下纤维制备而成：竹纤维40 g、玉米纤维17.5g、桑蚕丝17.5 g、抗紫外线改性聚酯纤维90 g、芳纶纤维40 g，且窗纱的两侧涂覆有紫外线吸收层，其中抗紫外线改性聚酯纤维由以下组份制备而成：聚对苯二甲酸乙二醇酯110 g、聚对苯二甲酰对苯二胺55 g、纳米二氧化钛5 g、氧化铈2.5 g、纳米高岭土3.5 g、碳酸钙4g、超细陶瓷粉2 g、乙烯基硅烷偶联剂0.9 g、粘胶纤维0.35 g。
一种抵抗紫外线穿透的窗纱的制备方法，包括以下步骤：
（1）制备抗紫外线改性聚酯纤维：将各原料组份充分混合后送入螺杆挤出机中挤出制得混合母粒，然后经湿法纺丝制成抗紫外线改性聚酯纤维，其中螺杆挤出机各段的温度分别为：一段130～145 ℃、二段145～155 ℃、三段155～165 ℃、四段165～175 ℃、五段175～180 ℃、六段180～185 ℃，模头温度为175～180 ℃，湿法纺丝的溶剂为二甲基甲酰胺与硫酸的混合水溶液，质量分数分别为12%、16%；
（2）将抗紫外线聚酯纤维、竹纤维、玉米纤维、桑蚕丝和芳纶纤维经纺织制成窗纱；
（3）在窗纱两侧喷涂紫外线吸收液并通风干燥形成紫外线吸收层，紫外线吸收液的喷涂密度为9 mL/m3，通风速率为4 m/s，干燥温度24 ℃，其中紫外线吸收液由以下组份制备而成：芦荟凝胶汁11 g、黄芩苷7 g、海藻胶1.5 g、肉桂酸甲酯1.0 g、紫胶4 g、去离子水170 g；
（4）将步骤（3）所得窗纱于-10 ℃环境中静置10分钟，再于60 ℃环境中静置10 分钟，如此高低温交替静置4次，制成抵抗紫外线穿透的窗纱。
实施例3
一种抵抗紫外线穿透的窗纱，由以下纤维制备而成：竹纤维50 g、玉米纤维20 g、桑蚕丝20 g、抗紫外线改性聚酯纤维100 g、芳纶纤维30 g，且窗纱的两侧涂覆有紫外线吸收层，其中抗紫外线改性聚酯纤维由以下组份制备而成：聚对苯二甲酸乙二醇酯120 g、聚对苯二甲酰对苯二胺60 g、纳米二氧化钛6 g、氧化铈3 g、纳米高岭土5 g、碳酸钙5 g、超细陶瓷粉3 g、乙烯基硅烷偶联剂1.1 g、粘胶纤维0.5 g。
一种抵抗紫外线穿透的窗纱的制备方法，包括以下步骤：
（1）制备抗紫外线改性聚酯纤维：将各原料组份充分混合后送入螺杆挤出机中挤出制得混合母粒，然后经湿法纺丝制成抗紫外线改性聚酯纤维，其中螺杆挤出机各段的温度分别为：一段130～145 ℃、二段145～155 ℃、三段155～165 ℃、四段165～175 ℃、五段175～180 ℃、六段180～185 ℃，模头温度为175～180 ℃，湿法纺丝的溶剂为二甲基甲酰胺与硫酸的混合水溶液，质量分数分别为12%、16%；
（2）将抗紫外线聚酯纤维、竹纤维、玉米纤维、桑蚕丝和芳纶纤维经纺织制成窗纱；
（3）在窗纱两侧喷涂紫外线吸收液并通风干燥形成紫外线吸收层，紫外线吸收液的喷涂密度为10 mL/m3，通风速率为5 m/s，干燥温度25 ℃，其中紫外线吸收液由以下组份制备而成：芦荟凝胶汁12 g、黄芩苷8 g、海藻胶2 g、肉桂酸甲酯1.2 g、紫胶5 g、去离子水180 g；
（4）将步骤（3）所得窗纱于-10 ℃环境中静置10分钟，再于60 ℃环境中静置10 分钟，如此高低温交替静置5次，制成抵抗紫外线穿透的窗纱。

Claims (2)

1.一种抵抗紫外线穿透的窗纱，其特征在于：所述窗纱由以下重量份的纤维制备而成：竹纤维30～50份、玉米纤维15～20份、桑蚕丝15～20份、抗紫外线改性聚酯纤维80～100份、芳纶纤维30～50份，且窗纱的两侧涂覆有紫外线吸收层；
所述抗紫外线改性聚酯纤维由以下重量份组份制备而成：聚对苯二甲酸乙二醇酯100～120份、聚对苯二甲酰对苯二胺50～60份、纳米二氧化钛4～6份、氧化铈2～3份、纳米高岭土2～5份、碳酸钙3～5份、超细陶瓷粉1～3份、乙烯基硅烷偶联剂0.7～1.1份、粘胶纤维0.2～0.5份；
所述紫外线吸收层由紫外线吸收液喷涂而成，所述紫外线吸收液由以下重量份组份制备而成：芦荟凝胶汁10～12份、黄芩苷6～8份、海藻胶1～2份、肉桂酸甲酯0.8～1.2份、紫胶3～5份、去离子水160～180份。
2.一种如权利要求1所述的抵抗紫外线穿透的窗纱的制备方法，包括以下步骤：
(1)制备抗紫外线改性聚酯纤维：将各原料组份充分混合后送入螺杆挤出机中挤出制得混合母粒，然后经湿法纺丝制成抗紫外线改性聚酯纤维；
(2)将抗紫外线聚酯纤维、竹纤维、玉米纤维、桑蚕丝和芳纶纤维经纺织制成窗纱；
(3)在窗纱两侧喷涂紫外线吸收液并通风干燥形成紫外线吸收层；
(4)将步骤(3)所得窗纱于-10℃环境中静置10分钟，再于60℃环境中静置10分钟，如此高低温交替静置3～5次，制成抵抗紫外线穿透的窗纱；
步骤(1)中螺杆挤出机各段的温度分别为：一段130～145℃、二段145～155℃、三段155～165℃、四段165～175℃、五段175～180℃、六段180～185℃，模头温度为175～180℃；湿法纺丝的溶剂为二甲基甲酰胺与硫酸的混合水溶液，其质量分数分别为12％、16％；
步骤(3)中所述紫外线吸收液由以下重量份组份制备而成：芦荟凝胶汁10～12份、黄芩苷6～8份、海藻胶1～2份、肉桂酸甲酯0.8～1.2份、紫胶3～5份、去离子水160～180份；紫外线吸收液的喷涂密度为8～10mL/m3，通风速率为3～5m/s，干燥温度23～25℃。
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003918A (zh) * 2007-01-12 2007-07-25 东华大学 一种纳米氮化钛抗紫外聚酯纤维
CN201106076Y (zh) * 2007-09-06 2008-08-27 洪桂焕 抗紫外线竹涤织物
CN103554847A (zh) * 2013-11-15 2014-02-05 中国纺织科学研究院 抗紫外线聚酯纤维母粒、其制备方法及包含其的聚酯纤维的生产方法
CN103668713A (zh) * 2013-12-19 2014-03-26 苏州丽绣纺织有限公司 一种抗紫外线绒面料
CN105780249A (zh) * 2014-12-13 2016-07-20 南通建伟色织服装有限公司 一种多纤维混纺面料

Family Cites Families (1)

* Cited by examiner, † Cited by third party
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JP4043358B2 (ja) * 2002-12-18 2008-02-06 帝人テクノプロダクツ株式会社 耐熱性布帛

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003918A (zh) * 2007-01-12 2007-07-25 东华大学 一种纳米氮化钛抗紫外聚酯纤维
CN201106076Y (zh) * 2007-09-06 2008-08-27 洪桂焕 抗紫外线竹涤织物
CN103554847A (zh) * 2013-11-15 2014-02-05 中国纺织科学研究院 抗紫外线聚酯纤维母粒、其制备方法及包含其的聚酯纤维的生产方法
CN103668713A (zh) * 2013-12-19 2014-03-26 苏州丽绣纺织有限公司 一种抗紫外线绒面料
CN105780249A (zh) * 2014-12-13 2016-07-20 南通建伟色织服装有限公司 一种多纤维混纺面料

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