CN106905708B - A kind of replacement IRM902 rubber oil-resistant detection standard oil and preparation method thereof - Google Patents
A kind of replacement IRM902 rubber oil-resistant detection standard oil and preparation method thereof Download PDFInfo
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- CN106905708B CN106905708B CN201710259967.5A CN201710259967A CN106905708B CN 106905708 B CN106905708 B CN 106905708B CN 201710259967 A CN201710259967 A CN 201710259967A CN 106905708 B CN106905708 B CN 106905708B
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 94
- 239000005060 rubber Substances 0.000 title claims abstract description 94
- 238000001514 detection method Methods 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000003921 oil Substances 0.000 claims abstract description 129
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 18
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims abstract description 7
- -1 Diisoamyl naphthalene Chemical compound 0.000 claims abstract description 6
- KEVMYFLMMDUPJE-UHFFFAOYSA-N diisoamyl Natural products CC(C)CCCCC(C)C KEVMYFLMMDUPJE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920002367 Polyisobutene Polymers 0.000 claims description 11
- QAPZDZDRMADDOM-UHFFFAOYSA-N 1,2-bis(3-methylbutyl)naphthalene Chemical compound C1=CC=CC2=C(CCC(C)C)C(CCC(C)C)=CC=C21 QAPZDZDRMADDOM-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 6
- 239000010687 lubricating oil Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 230000008676 import Effects 0.000 abstract description 3
- 238000011160 research Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001924 cycloalkanes Chemical class 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/44—Resins; Plastics; Rubber; Leather
- G01N33/445—Rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Immunology (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Food Science & Technology (AREA)
- Pathology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of standard oil of replacement No. 902 rubber oil-resistant detections of IRM and preparation method thereof, the standard oil is made up of the component of following weight proportion：Diisoamyl naphthalene 11.5 12.5%, KN4010 naphthenic rubbers oil 20 40%, KN4006 naphthenic rubbers oil 30 60%, the rubber oils 5 15% of KG 12, the rubber oils 10 20% of KG 06, antioxidant T501 0.1 0.5%.Independent research formula of the present invention, available for No. 902 standard oils of IRM for substituting imported from America, and the raw material used domestic can be bought, and is avoided import, is effectively reduced cost.
Description
Technical field
The invention belongs to rubber detection field, and in particular to a kind of standard working solution for rubber oil-resistant detection.
Background technology
Rubber oil-resistant performance is the important performance indexes of oil resistant rubber.Ke Biao inspection centers provide according to GB, HB, ISO,
The standards such as ASTM, EN provide rubber oil-resistant test, and provide report.In existing detection, the ASTM standards pair for using the U.S. more
Rubber carries out oil resistant test.
Because current U.S. ASTM new standards are adjusted to the quality of its oil product, and in new standard by original 1,2,
3rd, No. 5 experiments are upgraded to IRM 901, IRM902, IRM903, IRM905 with standard oil.They are mainly used in rubber seal product
Oil resistant test, such as oil sealing（NBR nitrile rubber oil sealings, ACM acrylate oil sealings etc.）, O-ring and sebific duct class product test.
Different elastomeric materials, it can be tested according to the different qualities of U.S.'s ASTM D471 standards and each money test oil.
But, it is necessary to each money test standard oil IRM used when being tested using U.S.'s ASTM D471 standards
901st, IRM902, IRM903, IRM905, domestic product and formula without corresponding to, are required to from imported from America, expensive, increase
Cost is added.Therefore it is badly in need of researching and developing a experiment standard oil for meeting U.S.'s ASTM D471 standards, instead of the standard of import
Oil.
The content of the invention
The invention aims to solve defect present in prior art, there is provided one kind can effectively substitute IRM
902 rubber oil-resistant detection experiment oil.
In order to achieve the above object, the invention provides a kind of rubber oil-resistant detection standard oil, by following weight proportion
Component composition：Diisoamyl naphthalene 11.5-12.5%, KN4010 naphthenic rubber oil 20-40%, KN4006 naphthenic rubber oil
30-60%, KG-12 rubber oil 5-15%, KG-06 rubber oil 10-20%, antioxidant T501 0.1-0.5%.
The preferred ingredient weight proportion of standard oil of the present invention is：Diisoamyl naphthalene 11.5-12.5%, KN4010 cycloalkyl rubber
Glue oil 20-35%, KN4006 naphthenic rubber oil 30-50%, KG-12 rubber oil 5-15%, KG-06 rubber oil 10-20%, resist
Oxygen agent T501 0.1-0.5%, polyisobutene 0-2%.Best composition weight proportion is：Diisoamyl naphthalene 12%, KN4010 cycloalkanes
Base rubber oil 26.2%, KN4006 naphthenic rubbers oil 43%, KG-12 rubber oils 6.6%, KG-06 rubber oils 11.3%, antioxygen
Agent T501 0.3%, polyisobutene 0.6%.
Wherein, KN4010 and KN4006 naphthenic rubbers oil is respectively selected from the production of Kelamayi lubricating oil plant of CNPC
The high-quality naphthenic rubber oil of KN4010 and KN4006；KG-12 and KG-06 rubber oils are respectively selected from the prosperous profit limited public affairs of petrochemical industry in Xiamen
KG12 the and KG06 rubber oils of department；Antioxidant T501 is selected from the antioxidant T501 of Nanjing Datang chemical industry Co., Ltd.
Present invention also offers the preparation method of above-mentioned standard oil, step are as follows：By diisoamyl naphthalene, KN4010 cycloalkyl
After rubber oil, KN4006 naphthenic rubbers oil, KG-12 rubber oils, KG-06 rubber oils, antioxidant T501 are mixed in proportion,
Its viscosity is detected, then adds polyisobutene, viscosity of the standard oil at 99 DEG C is reached 20-21 mm2/s。
The present invention has advantages below compared with prior art：
1st, the diisoamyl naphthalene, KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers that the present invention passes through specific proportioning
Oil, KG-12 rubber oils, KG-06 rubber oils adjust the aniline point of oil product of the present invention；Simultaneously using KN4010 naphthenic rubbers oil,
The naphthene content of KN4006 naphthenic rubbers oil regulation oil product；Pass through the proportioning of KG-12 rubber oils, KG-06 rubber oils respectively
Adjust the content of cycloalkane and alkane；Strengthen the antioxygenic property of oil product by antioxidant T501；Made by adding polyisobutene
For thickener, improve the viscosity of product.
2nd, by the research to formula composition and each group distribution ratio, the product formula finally determined can fully meet the present invention
U.S.'s ASTM D471 standards IRM902 oily to experiment requirement, suitable for testing rubber oil-resistant.
3rd, independent research formula of the present invention, available for No. 902 standard oils of IRM for substituting imported from America, and the raw material used
It domestic can buy, avoid import, effectively reduce cost.
Embodiment
With reference to specific embodiment, the present invention is described in detail.
Naphthenic rubber oil KN4010 and KN4006 are purchased from Kelamayi lubricating oil plant of CNPC；Rubber oil KG-12 and
KG-06 is purchased from Xiamen Heng Run petrochemical industry Co., Ltd；Antioxidant T501 is purchased from Nanjing Datang chemical industry Co., Ltd.
Embodiment 1
The composition weight proportioning that rubber liquid of the present invention influences experiment standard oil is as follows：
Diisoamyl naphthalene 11.7kg, KN4010 naphthenic rubber oil 24kg, KN4006 naphthenic rubber oil 44kg, KG-
12 rubber oil 8kg, KG-06 rubber oil 12kg, antioxidant T501 0.3kg.
By above-mentioned diisoamyl naphthalene, KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers oil, KG-12 rubber oils,
KG-06 rubber oils, antioxidant T501 are well mixed.
Embodiment 2
The composition weight proportioning that rubber liquid of the present invention influences experiment standard oil is as follows：
Diisoamyl naphthalene 12kg, KN4010 naphthenic rubber oil 26.2kg, KN4006 naphthenic rubber oil 43kg, KG-12
Rubber oil 6.6kg, KG-06 rubber oil 11.3kg, antioxidant T501 0.3kg, polyisobutene 0.6kg.
By above-mentioned diisoamyl naphthalene, KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers oil, KG-12 rubber oils,
KG-06 rubber oils, antioxidant T501, polyisobutene are well mixed.
Embodiment 3
It is as follows with standard oil configuration process that rubber liquid of the present invention influences experiment：
Take diisoamyl naphthalene 12.2kg, KN4010 naphthenic rubber oil 27.5kg, KN4006 naphthenic rubber oily
41.4kg, KG-12 rubber oil 7kg, KG-06 rubber oil 11kg, antioxidant T501 0.3kg are well mixed, after testing its viscosity
For 19.63, polyisobutene 0.6kg is added, it is well mixed to produce.
Embodiment 4
It is as follows with standard oil configuration process that rubber liquid of the present invention influences experiment：
Take diisoamyl naphthalene 12.5kg, KN4010 naphthenic rubber oil 30kg, KN4006 naphthenic rubber oil 35kg,
KG-12 rubber oil 10kg, KG-06 rubber oils 11.2kg, antioxidant T501 0.3kg are well mixed, and its viscosity is after testing
19.15, polyisobutene 1kg is added, it is well mixed to produce.
The particular product performance parameters that the present invention is prepared and the performance comparison of IRM902 standard oils are as shown in table 1 below：
The performance comparison of 1 standard oil of the present invention of table and IRM902 standard oils
As can be seen from Table 1, the standard oil performance indications that the present invention is prepared reach requirement, are entirely capable of substituting
IRM902 standard oils carry out rubber oil-resistant test.
The standard oil that various embodiments of the present invention are prepared carries out performance test, as a result as shown in table 2 below：
Standard oil performance comparison prepared by the various embodiments of the present invention of table 2
As can be seen from Table 2, the standard oil performance indications that the present invention is prepared reach requirement, are entirely capable of substituting
IRM902 standard oils carry out rubber oil-resistant test.And the standard oil performance that embodiment 2 is prepared is optimal.
Claims (4)
1. a kind of replacement IRM 902 rubber oil-resistant detection standard oil, it is characterised in that the standard oil is matched somebody with somebody by following weight
The component composition of ratio：Diisoamyl naphthalene 11.5-12.5%, KN4010 naphthenic rubber oil 20-35%, KN4006 naphthenic rubber
Oily 30-50%, KG-12 rubber oil 5-15%, KG-06 rubber oil 10-20%, antioxidant T501 0.1-0.5%, polyisobutene 0-
2%。
2. standard oil according to claim 1, it is characterised in that KN4010 the and KN4006 naphthenic rubbers oil is other
The high-quality naphthenic rubber oil of KN4010 and KN4006 selected from the production of Kelamayi lubricating oil plant of CNPC；Described KG-12
KG12 the and KG06 rubber oils of Xiamen Heng Run petrochemical industry Co., Ltd are respectively selected from KG-06 rubber oils；Described antioxidant T501
Antioxidant T501 selected from Nanjing Datang chemical industry Co., Ltd.
3. standard oil according to claim 2, it is characterised in that the standard oil by following weight proportion component group
Into：Diisoamyl naphthalene 12%, KN4010 naphthenic rubbers oil 26.2%, KN4006 naphthenic rubbers oil 43%, KG-12 rubber oils
6.6%th, KG-06 rubber oils 11.3%, antioxidant T501 0.3%, the % of polyisobutene 0.6.
4. the preparation method of the standard oil of claim 1 or 2, it is characterised in that the preparation method comprises the following steps：Will
The diisoamyl naphthalene, KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers oil, KG-12 rubber oils, KG-06 rubber oils,
After antioxidant T501 is mixed in proportion, its viscosity is detected, then adds polyisobutene, make the standard oil at 99 DEG C
Viscosity reaches 20-21 mm2/s。
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| CN201710259967.5A CN106905708B (en) | 2017-04-20 | 2017-04-20 | A kind of replacement IRM902 rubber oil-resistant detection standard oil and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710259967.5A CN106905708B (en) | 2017-04-20 | 2017-04-20 | A kind of replacement IRM902 rubber oil-resistant detection standard oil and preparation method thereof |
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| CN106905708A CN106905708A (en) | 2017-06-30 |
| CN106905708B true CN106905708B (en) | 2018-01-12 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597513A (en) * | 2009-07-14 | 2009-12-09 | 中国海洋石油总公司 | A kind of environment-friendly rubber oil and preparation method thereof |
| CN101691427A (en) * | 2009-10-21 | 2010-04-07 | 中国海洋石油总公司 | Blending-process method for producing environment-friendly rubber oil |
| CN106280037A (en) * | 2016-08-09 | 2017-01-04 | 深圳市前海龙达新能源有限公司 | A kind of modified rubber oil additive, preparation method and modified rubber oil thereof |
-
2017
- 2017-04-20 CN CN201710259967.5A patent/CN106905708B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597513A (en) * | 2009-07-14 | 2009-12-09 | 中国海洋石油总公司 | A kind of environment-friendly rubber oil and preparation method thereof |
| CN101691427A (en) * | 2009-10-21 | 2010-04-07 | 中国海洋石油总公司 | Blending-process method for producing environment-friendly rubber oil |
| CN106280037A (en) * | 2016-08-09 | 2017-01-04 | 深圳市前海龙达新能源有限公司 | A kind of modified rubber oil additive, preparation method and modified rubber oil thereof |
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| CN106905708A (en) | 2017-06-30 |
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