CN106633241A - High temperature resistant oil resistant hose lining material for oil delivery hose - Google Patents
High temperature resistant oil resistant hose lining material for oil delivery hose Download PDFInfo
- Publication number
- CN106633241A CN106633241A CN201610965665.5A CN201610965665A CN106633241A CN 106633241 A CN106633241 A CN 106633241A CN 201610965665 A CN201610965665 A CN 201610965665A CN 106633241 A CN106633241 A CN 106633241A
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- Prior art keywords
- parts
- oil
- high temperature
- temperature resistant
- resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high temperature resistant oil resistant hose lining material for an oil delivery hose. The high temperature resistant oil resistant hose lining material is prepared from, by weight, 140-175 parts of NBR, 50-55 parts of isoprene rubber, 20-25 parts of chlorosulfonated polyethylene rubber, 10-16 parts of antioxidant, 8-10 parts of trifluoromethyl lithium sulfonate, 15-20 parts of polyvinyl alcohol, 2-6 parts of cross-linking agent, 10-12 parts of vinyl triethoxy silane, 4-8 parts of sodium dodecyl benzene sulfonate, 6-9 parts of m-xylylenediamine, 2-6 parts of potassium sulfate, 5-9 parts of triphenyl phosphate, 1-5 parts of promoter and 4-8 parts of plasticizer. The high temperature resistant oil resistant hose lining material for the oil delivery hose has good high temperature resistance, can adapt to an environment higher in temperature, meanwhile has good solution resistance and is free of solvent leakage, and accordingly the environment is not polluted.
Description
Technical field
The invention belongs to polymeric material field, and in particular to a kind of oil hose glue material in high temperature resistant oil resistant.
Technical background
Rubber hose, refers to wire braided hose, and it is typically made up of inner glue layer, layer of steel wire braiding layer and outer glue-line.
Suitable for delivering hydraulic fluid, such as alcohol, fuel oil, lubricating oil, emulsion etc..Mutually distinguish with hard tube,（Rubber）Flexible pipe maximum
It is characterized in that flexible.Compare civilian（Rubber）Flexible pipe, industrial operations environment is more complicated, more severe, equipment is wanted to delivery pipe
Ask also harsher, therefore industry（Rubber）Flexible pipe has from design, to choose production, transport or even the final storage of material
Strict codes and standards.Varied according to the design of applying working condition and the difference flexible pipe of performance requirement, industry（Rubber）It is soft
The optional scope of size of pipe is wider, and P-T region is vast, and chemical-resistance is higher.Industry（Rubber）Flexible pipe application is contained
Each industrial production manufacture and the field of circulation are covered, has been the physics and electrochemical conditions for adapting to every profession and trade operation, generally industry（Rubber
Glue）Flexible pipe has very strict execution standard on the chemical raw material and technique of inside and outside colloid.Such as：Oil hose is mainly used in
The aspects such as fuel, diesel oil, kerosene, oil.
NBR NBR, resistance to mineral oil product, grease resistance and fuel, low temperature resistant low concentration inorganic acid.NBR NBR
(NitrileRubber) formed with butadiene copolymer by acrylonitrile, acrylonitrile content is by 18% ~ 50%, and acrylonitrile content is higher, right
Better, but cryogenic property is then deteriorated the repellence of petrochemical industry oil product hydrocarbon fuel oil, generally uses temperature range for -25 ~ 100 DEG C.
NBR advantage：The characteristic of the good oil resistant of tool, water resistant, anti-solvent and anti-hydraulic oil, has good compressibility, wear-resistant and elongation
Power.Shortcoming：Lower temperature resistance is poor, ozone resistance is poor, and insulating properties are inferior, and elasticity is slightly lower.For this purpose, our filling a prescription from product
Hand, the formula design of rubber hose will according to the compatibility of the performance of rubber hose, structure, purposes, auxiliary agent and resin, all kinds of help
Influencing each other between agent and cooperative effect, and the characteristics of former, the forming factors of comprehensive each side carry out resin model
And the selection of various addition auxiliary agents.In order to meet high request of the market to rubber hose, develop a kind of various performances compared with
Good oil hose glue material in high temperature resistant oil resistant.
The content of the invention
To achieve these goals, the invention provides a kind of oil hose glue material in high temperature resistant oil resistant.
The purpose of the present invention is achieved through the following technical solutions：
A kind of oil hose glue material in high temperature resistant oil resistant, is prepared by the raw materials in：NBR140-175 parts, isoamyl
Rubber 50-55 parts, CSM 20-25 parts, antioxidant 10-16 parts, trifluoromethyl sulfonic acid lithium 8-10 parts, poly- second
Enol 15-20 parts, crosslinking agent 2-6 parts, VTES 10-12 parts, pelopon A 4-8 parts,
Benzene dimethylamine 6-9 parts, potassium peroxydisulfate 2-6 parts, triphenyl phosphite 5-9 parts, accelerator 1-5 parts, plasticizer 4-8 parts.
The antioxidant be BHT or 2,4,6- tri-butyl-phenols.
The accelerator is dithio-bis-benzothiazole.
The plasticizer includes tributyl 2-acetylcitrate, synthesis vegetable esters.
Described crosslinking agent is selected from TAC, divinylbenzene, dially phthalate and propylene
One or more in sour N-butyl.
Beneficial effect：Glue material has good heat-resisting quantity in the oil hose high temperature resistant oil resistant of the present invention, can fit
The working environment that temperature is higher is answered, while resisting molten dissolubility good, can be spilt without solvent, therefore do not polluted the environment.
Specific embodiment
Embodiment 1
A kind of oil hose glue material in high temperature resistant oil resistant, is prepared by the raw materials in：NBR140 parts, isoprene rubber
50 parts, 20 parts of CSM, 10 parts of antioxidant, 8 parts of trifluoromethyl sulfonic acid lithium, 15 parts of polyvinyl alcohol, crosslinking agent 2
Part, 10 parts of VTES, 4 parts of pelopon A, 6 parts of m-xylene diamine, 2 parts of potassium peroxydisulfate, Asia
5 parts of triphenyl phosphate, 1 part of accelerator, 4 parts of plasticizer.
The antioxidant be BHT or 2,4,6- tri-butyl-phenols.
The accelerator is dithio-bis-benzothiazole.
The plasticizer includes tributyl 2-acetylcitrate, synthesis vegetable esters.
Described crosslinking agent is selected from TAC, divinylbenzene, dially phthalate and propylene
One or more in sour N-butyl.
Embodiment 2
A kind of oil hose glue material in high temperature resistant oil resistant, is prepared by the raw materials in：NBR175 parts, isoprene rubber
55 parts, 25 parts of CSM, 16 parts of antioxidant, 10 parts of trifluoromethyl sulfonic acid lithium, 20 parts of polyvinyl alcohol, crosslinking agent
6 parts, it is 12 parts of VTES, 8 parts of pelopon A, 9 parts of m-xylene diamine, 6 parts of potassium peroxydisulfate, sub-
9 parts of triphenyl phosphate, 5 parts of accelerator, 8 parts of plasticizer.
The antioxidant be BHT or 2,4,6- tri-butyl-phenols.
The accelerator is dithio-bis-benzothiazole.
The plasticizer includes tributyl 2-acetylcitrate, synthesis vegetable esters.
Described crosslinking agent is selected from TAC, divinylbenzene, dially phthalate and propylene
One or more in sour N-butyl.
Embodiment 3
A kind of oil hose glue material in high temperature resistant oil resistant, is prepared by the raw materials in：NBR165 parts, isoprene rubber
53 parts, 23 parts of CSM, 13 parts of antioxidant, 9 parts of trifluoromethyl sulfonic acid lithium, 17 parts of polyvinyl alcohol, crosslinking agent 4
Part, 11 parts of VTES, 6 parts of pelopon A, 7 parts of m-xylene diamine, 5 parts of potassium peroxydisulfate, Asia
8 parts of triphenyl phosphate, 3 parts of accelerator, 6 parts of plasticizer.
The antioxidant be BHT or 2,4,6- tri-butyl-phenols.
The accelerator is dithio-bis-benzothiazole.
The plasticizer includes tributyl 2-acetylcitrate, synthesis vegetable esters.
Described crosslinking agent is selected from TAC, divinylbenzene, dially phthalate and propylene
One or more in sour N-butyl.
Making sample by raw material in enforcement row formula carries out testing inspection, and the performance formula in above-described embodiment 1-3 is such as
Under：Tensile strength（Mpa）14.56、15.56、13.28；Elongation at break（%）450.83、435.46、436.49；Resistance to flexion tortoise
40,000 times are split without breach, without breach, without breach；1600 hours color fastness of neon lamp accelerated ageing are 5 grades, 5 grades, 5 grades；Wear rate is
0.54%、0.58%、0.56%。
Claims (5)
1. a kind of oil hose glue material in high temperature resistant oil resistant, it is characterised in that be prepared by the raw materials in：
NBR140-175 parts, isoprene rubber 50-55 parts, CSM 20-25 parts, antioxidant 10-16 parts, trifluoromethyl
Sulfonic Lithium 8-10 parts, polyvinyl alcohol 15-20 parts, crosslinking agent 2-6 parts, VTES 10-12 parts, detergent alkylate
Sulfonate sodium 4-8 parts, m-xylene diamine 6-9 parts, potassium peroxydisulfate 2-6 parts, triphenyl phosphite 5-9 parts, accelerator 1-5 parts, increasing
Modeling agent 4-8 parts.
2. a kind of oil hose glue material in high temperature resistant oil resistant according to claim 1, it is characterised in that：It is described anti-oxidant
Agent be BHT or 2,4,6- tri-butyl-phenols.
3. a kind of oil hose glue material in high temperature resistant oil resistant according to claim 1, it is characterised in that：The accelerator
For dithio-bis-benzothiazole.
4. a kind of oil hose glue material in high temperature resistant oil resistant according to claim 1, it is characterised in that：The plasticizer
Including tributyl 2-acetylcitrate, synthesis vegetable esters.
5. a kind of oil hose glue material in high temperature resistant oil resistant according to claim 1, it is characterised in that：Described crosslinking
Agent be the one kind in TAC, divinylbenzene, dially phthalate and n-butyl acrylate or
It is several.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610965665.5A CN106633241A (en) | 2016-10-28 | 2016-10-28 | High temperature resistant oil resistant hose lining material for oil delivery hose |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610965665.5A CN106633241A (en) | 2016-10-28 | 2016-10-28 | High temperature resistant oil resistant hose lining material for oil delivery hose |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106633241A true CN106633241A (en) | 2017-05-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610965665.5A Pending CN106633241A (en) | 2016-10-28 | 2016-10-28 | High temperature resistant oil resistant hose lining material for oil delivery hose |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189129A (en) * | 2017-06-26 | 2017-09-22 | 江苏长风波纹管有限公司 | A kind of modified oil resistant rubber bellows of used oil refiner |
| CN110237353A (en) * | 2019-07-17 | 2019-09-17 | 重庆市垫江县中医院 | Micro pump and connecting tube |
| WO2023278572A1 (en) * | 2021-06-30 | 2023-01-05 | Avient Corporation | Thermoset articles comprising nitrile butadiene rubber |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2143984A1 (en) * | 2008-07-08 | 2010-01-13 | Eaton Fluid Power GmbH | Reinforced flexible hose |
| CN104277348A (en) * | 2014-10-31 | 2015-01-14 | 柳州市中配橡塑配件制造有限公司 | Preparation method of rubber for outer glue layer of power steering tube of automobile |
| CN104672646A (en) * | 2015-01-29 | 2015-06-03 | 柳州市中配橡塑配件制造有限公司 | Synthetic rubber for high-speed tire |
| CN104877189A (en) * | 2015-06-19 | 2015-09-02 | 江苏华神特种橡胶制品股份有限公司 | High-toughness wear-resisting rubber |
| CN105315514A (en) * | 2015-12-04 | 2016-02-10 | 沈阳赛亚橡胶制品有限公司 | Inner rubber layer of energy-saving environment-friendly rubber hose |
-
2016
- 2016-10-28 CN CN201610965665.5A patent/CN106633241A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2143984A1 (en) * | 2008-07-08 | 2010-01-13 | Eaton Fluid Power GmbH | Reinforced flexible hose |
| CN104277348A (en) * | 2014-10-31 | 2015-01-14 | 柳州市中配橡塑配件制造有限公司 | Preparation method of rubber for outer glue layer of power steering tube of automobile |
| CN104672646A (en) * | 2015-01-29 | 2015-06-03 | 柳州市中配橡塑配件制造有限公司 | Synthetic rubber for high-speed tire |
| CN104877189A (en) * | 2015-06-19 | 2015-09-02 | 江苏华神特种橡胶制品股份有限公司 | High-toughness wear-resisting rubber |
| CN105315514A (en) * | 2015-12-04 | 2016-02-10 | 沈阳赛亚橡胶制品有限公司 | Inner rubber layer of energy-saving environment-friendly rubber hose |
Non-Patent Citations (5)
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| 吴江出入境检验检疫局编: "《锂离子电池系统检测与评估》", 31 January 2014, 清华大学出版社 * |
| 山西省化工研究所编: "《塑料橡胶加工助剂 第2版》", 31 October 2002, 化学工业出版社 * |
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| 禹茂章主编: "《新编世界精细化学品手册》", 30 April 2000, 国家药品监督管理局信息中心 * |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189129A (en) * | 2017-06-26 | 2017-09-22 | 江苏长风波纹管有限公司 | A kind of modified oil resistant rubber bellows of used oil refiner |
| CN110237353A (en) * | 2019-07-17 | 2019-09-17 | 重庆市垫江县中医院 | Micro pump and connecting tube |
| WO2023278572A1 (en) * | 2021-06-30 | 2023-01-05 | Avient Corporation | Thermoset articles comprising nitrile butadiene rubber |
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Application publication date: 20170510 |