CN106841583B - A kind of rubber oil-resistant detection standard oil and preparation method thereof - Google Patents
A kind of rubber oil-resistant detection standard oil and preparation method thereof Download PDFInfo
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- CN106841583B CN106841583B CN201710174466.7A CN201710174466A CN106841583B CN 106841583 B CN106841583 B CN 106841583B CN 201710174466 A CN201710174466 A CN 201710174466A CN 106841583 B CN106841583 B CN 106841583B
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- oil
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- naphthenic
- oils
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 95
- 239000005060 rubber Substances 0.000 title claims abstract description 95
- 238000001514 detection method Methods 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 5
- 239000003921 oil Substances 0.000 claims abstract description 136
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 claims abstract description 30
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 19
- QAPZDZDRMADDOM-UHFFFAOYSA-N 1,2-bis(3-methylbutyl)naphthalene Chemical compound C1=CC=CC2=C(CCC(C)C)C(CCC(C)C)=CC=C21 QAPZDZDRMADDOM-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920002367 Polyisobutene Polymers 0.000 claims description 11
- 239000010687 lubricating oil Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 230000008676 import Effects 0.000 abstract description 3
- 238000011160 research Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 101000648997 Homo sapiens Tripartite motif-containing protein 44 Proteins 0.000 abstract 1
- 102100028017 Tripartite motif-containing protein 44 Human genes 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 14
- 238000002474 experimental method Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/44—Resins; Plastics; Rubber; Leather
- G01N33/445—Rubber
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of rubber oil-resistant detection standard oil and preparation method thereof, the standard oil is made up of the component of following weight proportion：Diisopropylbenzene (DIPB) 0.1 1%, diisoamyl naphthalene 1 5%, KN4010 naphthenic rubbers oil 10 30%, KN4006 naphthenic rubbers oil 20 50%, the rubber oils 10 20% of KG 12, the rubber oils 15 35% of KG 06, antioxidant T501 0.1 0.5%.Independent research formula of the present invention, available for No. 901 standard oils of IRM for substituting imported from America, and the raw material used domestic can be bought, and is avoided import, is effectively reduced cost.
Description
Technical field
The invention belongs to rubber detection field, and in particular to a kind of standard working solution for rubber oil-resistant detection.
Background technology
Rubber oil-resistant performance is the important performance indexes of oil resistant rubber.Ke Biao inspection centers provide according to GB, HB, ISO,
The standards such as ASTM, EN provide rubber oil-resistant test, and provide report.In existing detection, the ASTM standards pair for using the U.S. more
Rubber carries out oil resistant test.
Because current U.S. ASTM new standards are adjusted to the quality of its oil product, and in new standard by original 1,2,
3rd, No. 5 experiments are upgraded to IRM 901, IRM902, IRM903, IRM905 with standard oil.Main application product：Oil sealing, O-ring,
Sebific duct class product test.IRM 901 be oil resistant rubber plastic product carry out oil resistant swell test standard oil, ASTM IRM
903 experiment oil are mainly used in rubber seal product oil resistant test, such as oil sealing class product-NBR nitrile rubber oil sealings, ACM acrylic acid
The oil resistants such as ester oil envelope test different elastomeric materials, can be done according to U.S.'s ASTM D471 standards, the different qualities of each money test oil
Test.
But, it is necessary to each money test standard oil IRM used when being tested using U.S.'s ASTM D471 standards
901st, IRM902, IRM903, IRM905, domestic product and formula without corresponding to, are required to from imported from America, expensive, increase
Cost is added.Therefore it is badly in need of researching and developing a experiment standard oil for meeting U.S.'s ASTM D471 standards, instead of the standard of import
Oil.
The content of the invention
The invention aims to solve defect present in prior art, there is provided one kind can effectively substitute IRM
901 rubber oil-resistant detection experiment oil.
In order to achieve the above object, the invention provides a kind of rubber oil-resistant detection standard oil, by following weight proportion
Component composition：Diisopropylbenzene (DIPB) 0.1-1%, diisoamyl naphthalene 1-5%, KN4010 naphthenic rubber oil 10-30%, KN4006 ring
Alkyl rubber oil 20-50%, KG-12 rubber oil 10-20%, KG-06 rubber oil 15-35%, antioxidant T501 0.1-0.5%.
The preferred ingredient weight proportion of standard oil of the present invention is：Diisopropylbenzene (DIPB) 0.1-1%, diisoamyl naphthalene 1-5%,
KN4010 naphthenic rubber oil 10-30%, KN4006 naphthenic rubber oil 20-45%, KG-12 rubber oils 10-20%, KG-06
Rubber oil 15-30%, antioxidant T501 0.1-0.5%, polyisobutene 0-2 %.Best composition weight proportion is：Diisopropylbenzene (DIPB)
0.1%th, diisoamyl naphthalene 3%, KN4010 naphthenic rubbers oil 25%, KN4006 naphthenic rubbers oil 30%, KG-12 rubber oils
15%th, KG-06 rubber oils 26%, antioxidant T501 0.3%, polyisobutene 0.6%.
Wherein, KN4010 and KN4006 naphthenic rubbers oil is respectively selected from the production of Kelamayi lubricating oil plant of CNPC
The high-quality naphthenic rubber oil of KN4010 and KN4006；KG-12 and KG-06 rubber oils are respectively selected from the prosperous profit limited public affairs of petrochemical industry in Xiamen
KG12 the and KG06 rubber oils of department；Antioxidant T501 is selected from the antioxidant T501 of Nanjing Datang chemical industry Co., Ltd.
Present invention also offers the preparation method of above-mentioned standard oil, step are as follows：By diisopropylbenzene (DIPB), diisoamyl naphthalene,
KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers oil, KG-12 rubber oils, KG-06 rubber oils, antioxidant T501 press than
After example is well mixed, its viscosity is detected, then adds polyisobutene, viscosity of the standard oil at 99 DEG C is reached 18.7-18.9
mm2/s。
The present invention has advantages below compared with prior art：
1st, diisopropylbenzene (DIPB), diisoamyl naphthalene, KN4010 naphthenic rubbers oil, the KN4006 rings that the present invention passes through specific proportioning
Alkyl rubber oil, KG-12 rubber oils, KG-06 rubber oils adjust the aniline point of oil product of the present invention, while utilize KN4010 cycloalkyl
The naphthene content of rubber oil, KN4006 naphthenic rubbers oil regulation oil product, is matched somebody with somebody by KG-12 rubber oils, KG-06 rubber oils
Than the content of regulation cycloalkane and alkane；Strengthen the antioxygenic property of oil product by antioxidant T501, by adding polyisobutene
Viscosity as thickener, improvement product.
2nd, by the research to formula composition and each group distribution ratio, the product formula finally determined can fully meet the present invention
Requirement of U.S.'s ASTM D471 standards to experiment oil, suitable for testing rubber oil-resistant.
3rd, independent research formula of the present invention, available for No. 901 standard oils of IRM for substituting imported from America, and the raw material used
It domestic can buy, avoid import, effectively reduce cost.
Embodiment
With reference to specific embodiment, the present invention is described in detail.
Naphthenic rubber oil KN4010 and KN4006 are purchased from Kelamayi lubricating oil plant of CNPC；Rubber oil KG-12 and
KG-06 is purchased from Xiamen Heng Run petrochemical industry Co., Ltd；Antioxidant T501 is purchased from Nanjing Datang chemical industry Co., Ltd.
Embodiment 1
The composition weight proportioning that rubber liquid of the present invention influences experiment standard oil is as follows：
Diisopropylbenzene (DIPB) 0.1kg, diisoamyl naphthalene 3kg, KN4010 naphthenic rubber oil 25kg, KN4006 naphthenic rubber
Oily 30kg, KG-12 rubber oil 15kg, KG-06 rubber oil 26kg, antioxidant T501 0.3kg.
By above-mentioned diisopropylbenzene (DIPB), diisoamyl naphthalene, KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers oil, KG-12
Rubber oil, KG-06 rubber oils, antioxidant T501 are well mixed.
Embodiment 2
The composition weight proportioning that rubber liquid of the present invention influences experiment standard oil is as follows：
Diisopropylbenzene (DIPB) 0.1kg, diisoamyl naphthalene 3kg, KN4010 naphthenic rubber oil 25kg, KN4006 naphthenic rubber
Oily 30kg, KG-12 rubber oil 15kg, KG-06 rubber oil 26kg, antioxidant T5010.3kg, polyisobutene 0.6kg.
By above-mentioned diisopropylbenzene (DIPB), diisoamyl naphthalene, KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers oil, KG-12
Rubber oil, KG-06 rubber oils, antioxidant T501, polyisobutene are well mixed.
Embodiment 3
It is as follows with standard oil configuration process that rubber liquid of the present invention influences experiment：
Take diisopropylbenzene (DIPB) 0.1kg, diisoamyl naphthalene 3kg, KN4010 naphthenic rubber oil 20kg, KN4006 cycloalkyl rubber
Glue oil 35kg, KG-12 rubber oil 15kg, KG-06 rubber oil 26kg, antioxidant T501 0.3kg are well mixed, after testing its
Viscosity is 18.22, adds polyisobutene 0.6kg, well mixed to produce.
Embodiment 4
It is as follows with standard oil configuration process that rubber liquid of the present invention influences experiment：
Take diisopropylbenzene (DIPB) 0.9kg, diisoamyl naphthalene 4kg, KN4010 naphthenic rubber oil 25kg, KN4006 cycloalkyl rubber
Glue oil 37kg, KG-12 rubber oil 12kg, KG-06 rubber oil 22kg, antioxidant T501 0.2kg are well mixed, after testing its
Viscosity is 18.43, adds polyisobutene 1kg, well mixed to produce.
The particular product performance parameters that the present invention is prepared and the performance comparison of IRM901 standard oils are as shown in table 1 below：
The performance comparison of 1 standard oil of the present invention of table and IRM901 standard oils
As can be seen from Table 1, the standard oil performance indications that the present invention is prepared reach requirement, are entirely capable of substituting
IRM901 standard oils carry out rubber oil-resistant test.
The standard oil that various embodiments of the present invention are prepared carries out performance test, as a result as shown in table 2 below：
Standard oil performance comparison prepared by the various embodiments of the present invention of table 2
As can be seen from Table 2, the standard oil performance indications that the present invention is prepared reach requirement, are entirely capable of substituting
IRM901 standard oils carry out rubber oil-resistant test.And the standard oil performance that embodiment 2 is prepared is optimal.
Claims (4)
1. a kind of rubber oil-resistant detection standard oil, it is characterised in that the standard oil is made up of the component of following weight proportion：
Diisopropylbenzene (DIPB) 0.1-1%, diisoamyl naphthalene 1-5%, KN4010 naphthenic rubber oil 10-30%, KN4006 naphthenic rubber oil
20-45%, KG-12 rubber oil 10-20%, KG-06 rubber oil 15-30%, antioxidant T501 0.1-0.5%, polyisobutene 0-2
%。
2. standard oil according to claim 1, it is characterised in that KN4010 the and KN4006 naphthenic rubbers oil is other
The high-quality naphthenic rubber oil of KN4010 and KN4006 selected from the production of Kelamayi lubricating oil plant of CNPC；Described KG-12
KG12 the and KG06 rubber oils of Xiamen Heng Run petrochemical industry Co., Ltd are respectively selected from KG-06 rubber oils；Described antioxidant T501
Antioxidant T501 selected from Nanjing Datang chemical industry Co., Ltd.
3. standard oil according to claim 2, it is characterised in that the standard oil by following weight proportion component group
Into：Diisopropylbenzene (DIPB) 0.1%, diisoamyl naphthalene 3%, KN4010 naphthenic rubbers oil 25%, KN4006 naphthenic rubbers oil 30%,
KG-12 rubber oils 15%, KG-06 rubber oils 26%, antioxidant T501 0.3%, the % of polyisobutene 0.6.
4. the preparation method of the standard oil of claim 1 or 2, it is characterised in that the standard oil is prepared by the following method：
By diisopropylbenzene (DIPB), diisoamyl naphthalene, KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers oil, KG-12 rubber oils, KG-06
After rubber oil, antioxidant T501 are mixed in proportion, its viscosity is detected, then adds polyisobutene, the standard oil is existed
Viscosity at 99 DEG C reaches 18.7-18.9 mm2/s。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710174466.7A CN106841583B (en) | 2017-03-22 | 2017-03-22 | A kind of rubber oil-resistant detection standard oil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710174466.7A CN106841583B (en) | 2017-03-22 | 2017-03-22 | A kind of rubber oil-resistant detection standard oil and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106841583A CN106841583A (en) | 2017-06-13 |
| CN106841583B true CN106841583B (en) | 2018-01-12 |
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Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1404660A (en) * | 1971-11-26 | 1975-09-03 | Standard Oil Co | Five-grade motor oil for internal combustion engines |
| WO2010125144A1 (en) * | 2009-05-01 | 2010-11-04 | Shell Internationale Research Maatschappij B.V. | Functional fluid compositions with improved seal swell properties |
| CN104212488B (en) * | 2013-06-05 | 2016-11-09 | 中国石油天然气股份有限公司 | A kind of environment-friendly rubber oil and preparation method thereof |
| CN106280037B (en) * | 2016-08-09 | 2018-10-16 | 深圳市前海龙达新能源有限公司 | A kind of modified rubber oil additive, preparation method and its modified rubber oil |
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2017
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