CN106902547B - One kind extracting nickel sulfate novel energy-saving extraction equipment from old and useless battery - Google Patents

One kind extracting nickel sulfate novel energy-saving extraction equipment from old and useless battery Download PDF

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Publication number
CN106902547B
CN106902547B CN201710230256.5A CN201710230256A CN106902547B CN 106902547 B CN106902547 B CN 106902547B CN 201710230256 A CN201710230256 A CN 201710230256A CN 106902547 B CN106902547 B CN 106902547B
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extractor
extraction equipment
helical spring
cylinder
cross bar
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CN106902547A (en
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不公告发明人
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Quannan Ruilong Technology Co ltd
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Quannan Ruilong Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/04Solvent extraction of solutions which are liquid
    • B01D11/0476Moving receptacles, e.g. rotating receptacles
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/003Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/10Sulfates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

The present invention relates to a kind of extraction equipments, more particularly to one kind, and nickel sulfate novel energy-saving extraction equipment is extracted from old and useless battery.The technical problem to be solved in the present invention is to provide one kind to extract nickel sulfate novel energy-saving extraction equipment from old and useless battery.In order to solve the above-mentioned technical problems, the present invention provides such a to extract nickel sulfate novel energy-saving extraction equipment from old and useless battery, includes left extraction equipment, right extraction equipment and shaking mixing arrangement etc.;Right extraction equipment is provided on the right side of mixing arrangement shaking, left extraction equipment and right extraction equipment are symmetrical setting.One kind provided by the present invention extracts nickel sulfate novel energy-saving extraction equipment from old and useless battery, has unique structure, mixed liquor can be mixed by the relative motion of two extraction equipments.

Description

One kind extracting nickel sulfate novel energy-saving extraction equipment from old and useless battery
Technical field
The present invention relates to a kind of extraction equipments, more particularly to one kind, and nickel sulfate novel energy-saving is extracted from old and useless battery Extraction equipment.
Background technique
Nickel sulfate has three kinds of anhydride, six water objects and seven water objects.Commodity are mostly six water objects, there is α-type and two kinds of β-type changes Body, the former is the crystallization of blue four directions, and the latter is green monoclinic crystal.It is heated to losing six crystallizations water at 103 °C.It is soluble in Water, is slightly soluble in ethyl alcohol, methanol, and aqueous solution is slightly soluble in acid, ammonium hydroxide in acidity.Extraction, also known as solvent extraction or liquid-liquid extraction, It also known as extracts, is to there is different solubility to operate come the unit of separating mixture in a solvent using component in system.It is benefit With substance in two kinds of immiscible or sl. sol. solvents solubility or the difference of distribution coefficient, make solute substance from a kind of solvent The method being inside transferred in another solvent.Energy conservation is exactly to be reduced as far as energy-output ratio, is produced and original same The product of quantity, same quality;Either with original same amount of energy-output ratio, produce than original more or number Measure the better product of equal mass.Energy conservation be exactly in application technology reality it is reliable, viable economically rationally, environment and society all may be used In the method for receiving, the energy is effectively utilized, improves the energy utilization efficiency with energy equipment or technique.Energy conservation is that China is sustainable One Long-term Development Strategy of development, is the fundamental state policy in China.Broad sense says that energy conservation refers in addition to narrow sense energy conservation content Power-economizing method, such as save material consumption, improves product quality, labor productivity, reduces manpower consumption, improves using energy source effect Rate etc..Narrow sense says that energy conservation, which refers to, saves the energy such as coal, petroleum, electric power, natural gas.
It is existing that nickel sulfate extraction equipment is extracted from old and useless battery, traditional structure is generallyd use, needs to pass through machine Mixed liquor is mixed in device power, and energy consumption is serious, is easy to pollute the environment, not only increase enterprise at This expenditure is also unfavorable for the production and development of enterprise.
Summary of the invention
(1) technical problems to be solved
The present invention generallys use traditional knot to overcome the existing extraction nickel sulfate extraction equipment from old and useless battery Structure needs that mixed liquor is mixed by machine power, the serious disadvantage of energy consumption, the invention solves technology Problem is to provide one kind and extracts nickel sulfate novel energy-saving extraction equipment from old and useless battery.
(2) technical solution
In order to solve the above-mentioned technical problems, the present invention provides such a from old and useless battery extracts nickel sulfate with new-type Energy-saving extraction equipment includes left extraction equipment, right extraction equipment and shaking mixing arrangement;It is set on the right side of left extraction equipment It is equipped with shaking mixing arrangement, is provided with right extraction equipment, left extraction equipment and right extraction equipment on the right side of mixing arrangement shaking For symmetrical expression setting.
Preferably, left extraction equipment include left extractor, left inlet tube, upper left valve, left outlet tube, lower-left valve, Lower-left helical spring and left receipts fluid cylinder;Left inlet tube is provided with above left extractor, left inlet tube is connected with left extractor It connects, upper left valve is provided on left inlet tube;Left outlet tube, left outlet tube and left extraction are provided on the left of left extractor The lower-left skew wall of tank is connected, and lower-left valve is provided on left outlet tube;Lower-left spiral is provided with below left extractor Spring, left extractor are connected with lower-left helical spring;Left receipts fluid cylinder, left receipts fluid cylinder setting are provided with below left extractor In the lower section of left outlet tube.
Preferably, right extraction equipment include right extractor, right inlet tube, upper right valve, right outlet tube, bottom right valve, Bottom right helical spring and right receipts fluid cylinder;Right inlet tube is provided with above right extractor, right inlet tube is connected with right extractor It connects, upper right valve is provided on right inlet tube;Right outlet tube, right outlet tube and right extraction are provided on the right side of right extractor The bottom right skew wall of tank is connected, and bottom right valve is provided on right outlet tube;Bottom right spiral is provided with below right extractor Spring, right extractor are connected with bottom right helical spring;Right receipts fluid cylinder, right receipts fluid cylinder setting are provided with below right extractor In the lower section of right outlet tube.
Preferably, shake mixing arrangement include right fixed ring, pedestal, support rod, spill connection frame, cross bar, Zuo Lasheng, Left hook, left fixed ring, right drawstring and right hook;The top of pedestal, the right end of right fixed ring and pedestal is arranged in right fixed ring Top is set as being fixedly connected;Support rod is provided with above pedestal, support rod is set as rectilinear with pedestal and is fixedly connected; Spill connection frame is provided with above support rod, spill connection frame is set as being fixedly connected with support rod;In spill connection frame It is inside provided with cross bar, the intermediate position of cross bar is set as being rotatablely connected by axis and spill connection frame;Cross bar is arranged in left extraction Between tank and right extractor, the left end of cross bar is set as being fixedly connected with left extractor, and the right end of cross bar and right extractor are arranged To be fixedly connected;Zola's rope is provided with below cross bar, Zola's rope is connected with cross bar, and Zola, which restricts, is arranged in a left side for support rod Side is provided with left hook in the lower section of Zola's rope, and Zola's rope is connected with left hook;Left fixation is provided with below left hook Ring, left hook are set as being flexibly connected with left fixed ring;The top of pedestal, a left side for left fixed ring and pedestal is arranged in left fixed ring End top is set as being fixedly connected, and left fixed ring and right fixed ring are symmetrical setting;The right side is provided with above right fixed ring Hook, right hook are set as being flexibly connected with right fixed ring;Right drawstring, right hook and right drawstring are provided with above right hook It is connected, the right side of support rod is arranged in right drawstring, and the lower section of cross bar is arranged in right drawstring, and right drawstring is connected with cross bar.
It preferably, further include having counter weight device, counter weight device is arranged between left extraction equipment and right extraction equipment, counterweight The top for shaking mixing arrangement is arranged in device, and counter weight device includes right baffle-plate, guide rod, upper left helical spring, sphere, the right side Upper helical spring and right shell body;Right baffle-plate is located at the top of cross bar, and right baffle-plate is set as rectilinear with cross bar and is fixedly connected;On a left side Guide rod is provided on the right side of baffle, right baffle-plate is set as being fixedly connected with guide rod;It is cased with upper left spiral bullet on the guide bar The left end of spring, upper left helical spring is set as being fixedly connected with right baffle-plate;It is provided with sphere on the right side of the helical spring of upper left, Through-hole is provided on sphere, sphere is covered on the guide bar by through-hole, and sphere is set as being flexibly connected with guide rod, sphere and a left side Upper helical spring is set as being flexibly connected;Upper right helical spring is provided on the right side of sphere, upper right spiral spring cover is being oriented to On bar, sphere is set as being flexibly connected with upper right helical spring;Right shell body, upper right spiral shell are provided on the right side of upper right helical spring The right end of rotation spring is set as being fixedly connected with right shell body;The top of cross bar is arranged in right shell body, and right shell body is set as with cross bar It is rectilinear to be fixedly connected.
It preferably, further include having right cylinder, right pallet, left cylinder and left pallet;Right support is provided on the left of right cylinder Disk, right cylinder are connected with right pallet, and the right lower section for receiving fluid cylinder is arranged in right pallet, and right receipts fluid cylinder and right pallet are set as activity Connection, is provided with left pallet, left cylinder is connected with left pallet, and left pallet is arranged under left receipts fluid cylinder on the right side of left cylinder Side, left receipts fluid cylinder are set as being flexibly connected with left pallet.
Preferably, the cylinder diameter of right cylinder and left cylinder is set as 30-50mm, and the stroke of right cylinder and left cylinder is set as 3- 8m。
Working principle: in the present apparatus, because including left extraction equipment, right extraction equipment and shaking mixing arrangement;? It is provided with shaking mixing arrangement on the right side of left extraction equipment, is provided with right extraction equipment, Zuo Cui on the right side of mixing arrangement shaking Take device and right extraction equipment for symmetrical setting, so staff can be in advance by solution and extractant containing nickel sulfate Solution is all added in left extraction equipment, and then the solution containing nickel sulfate and extraction agent solution are all added to by staff again In right extraction equipment, shaking mixing arrangement is recycled to teetertotter the mixed liquor in left extraction equipment and right extraction equipment Mixing only needs manually a little auxiliary, does not consume the energy, in the case where meeting the requirement being mixed, reached energy-efficient purpose.
Because left extraction equipment includes left extractor, left inlet tube, upper left valve, left outlet tube, lower-left valve, lower-left Then helical spring and left receipts fluid cylinder first pass through the solution containing nickel sulfate so staff can open upper left valve Left inlet tube is added in left extractor, then extraction agent solution is added in left extractor again, staff turns off a left side Upper valve.After the solution containing nickel sulfate and extraction agent solution hybrid reaction in left extractor, staff can be with It opens lower-left valve the solution after reaction is discharged to respectively in left receipts fluid cylinder by left outlet tube, be arranged in left extraction pot bottom Lower-left helical spring can provide resilient support for left extractor, assist left extractor to teetertotter.
Because right extraction equipment includes right extractor, right inlet tube, upper right valve, right outlet tube, bottom right valve, bottom right Then helical spring and right receipts fluid cylinder first pass through the solution containing nickel sulfate so staff can open upper right valve Right inlet tube is added in right extractor, then extraction agent solution is added in right extractor again, staff turns off the right side Upper valve.After the solution containing nickel sulfate and extraction agent solution hybrid reaction in right extractor, staff can be with It opens bottom right valve the solution after reaction is discharged to respectively in right receipts fluid cylinder by right outlet tube, be arranged in right extraction pot bottom Bottom right helical spring can provide resilient support for right extractor, assist right extractor to teetertotter.
Because shaking mixing arrangement includes right fixed ring, pedestal, support rod, spill connection frame, cross bar, Zuo Lasheng, a left side Hook, left fixed ring, right drawstring and right hook, so when phase has been added in left extractor and right extractor respectively in staff After the mixed liquor of same amount, staff applies certain power to left extractor or right extractor, drives left extractor or right extraction Tank moves up and down, and the mixed liquor in left extractor and right extractor is mixed stirring in up and down motion, starts to carry out anti- It answers.When left extractor or right extractor move to lower section, lower-left helical spring or bottom right helical spring bottom out and start to rebound, respectively Left extractor or right extractor is driven to carry out bounce motion, so that right extractor or left extractor be driven reversely to be transported respectively It is dynamic, and pass through the cooperation of spill connection frame and cross bar, it constantly moves up and down, thus in right extractor and left extractor Mixed liquor carry out preferably shake mixing, without motor drive agitating paddle be stirred, unique structure, the energy saving energy, for enterprise Industry saves the spending of writing.After shaking the regular hour to right extractor and left extractor, staff can respectively by It is left hook or it is right hang in left fixed ring or right fixed ring, thus in right extractor and left extractor mixed liquor standing Regular hour, the nickel sulfate in the solution containing nickel sulfate are extracted the absorption of the extractant in agent solution, and mass transport process finishes Afterwards, the extract liquor containing nickel sulfate forms significantly upper lower leaf with the raffinate for losing nickel sulfate, and then staff divides again Processing is not discharged it.
Because further including having counter weight device, counter weight device is arranged between left extraction equipment and right extraction equipment, with refitting It installs in the top for shaking mixing arrangement, counter weight device includes right baffle-plate, guide rod, upper left helical spring, sphere, upper right Helical spring and right shell body, so during shaking mixing arrangement to left extraction equipment and the shaking of right extraction equipment, sphere Under the effect of the elastic force of upper left helical spring and upper right helical spring, left extraction equipment or right extraction equipment can be applied respectively Pressure increases separately the counterweight of left extraction equipment or right extraction equipment, provides the shaking to left extraction equipment and right extraction equipment Effect improves hybrid reaction efficiency.
Because further including having right cylinder, right pallet, left cylinder and left pallet, right cylinder is connected with right pallet, right receipts liquid Cylinder is set as being flexibly connected with right pallet, and left cylinder is connected with left pallet, and left receipts fluid cylinder is set as being flexibly connected with left pallet, So right cylinder can be respectively started by staff and left cylinder acts, right cylinder is able to drive right pallet and right receipts fluid cylinder Side-to-side movement is carried out, and right receipts fluid cylinder is driven to the position of needs, left cylinder is able to drive left pallet and left receipts fluid cylinder carries out Side-to-side movement, and left receipts fluid cylinder is driven to the position of needs.
Because the cylinder diameter of right cylinder and left cylinder is set as 30-50mm, the stroke of right cylinder and left cylinder is set as 3-8m, So present apparatus movement is steady reliable, manpower is saved, is had a wide range of application.
(3) beneficial effect
One kind provided by the present invention extracts nickel sulfate novel energy-saving extraction equipment from old and useless battery, has uniqueness Structure, mixed liquor can be mixed by the relative motion of two extraction equipments, only need worker to carry out few Auxiliary, is stirred without machine power, saves the energy, will not pollute to ambient enviroment, structure is simple, operation side Just, maintenance easy to maintain.
Detailed description of the invention
Fig. 1 is main view schematic diagram of the invention.
Fig. 2 is the main view schematic diagram of left extraction equipment and right extraction equipment of the invention.
Fig. 3 is the main view schematic diagram of right cylinder of the invention.
The label in accompanying drawing is: the left extraction equipment of 1-, the right extraction equipment of 2-, 3- shake mixing arrangement, 4- counter weight device, 5- Right cylinder, the right pallet of 6-, 7- left cylinder, the left pallet of 8-, the left extractor of 11-, the left inlet tube of 12-, the upper left 13- valve, the left side 14- goes out Liquid pipe, the lower-left 15- valve, the lower-left 16- helical spring, the left receipts fluid cylinder of 17-, the right extractor of 21-, the right inlet tube of 22-, 23- upper right Valve, the right outlet tube of 24-, the bottom right 25- valve, the bottom right 26- helical spring, the right receipts fluid cylinder of 27-, the right fixed ring of 30-, 31- pedestal, 32- support rod, 33- spill connection frame, 34- cross bar, 35- Zola rope, the left hook of 36-, the left fixed ring of 37-, the right drawstring of 38-, 39- Right hook, 41- right baffle-plate, 42- guide rod, the upper left 43- helical spring, 44- sphere, 45- upper right helical spring, 46- right shell body.
Specific embodiment
The present invention is further illustrated with reference to the accompanying drawings and examples.
Embodiment 1
One kind extracting nickel sulfate novel energy-saving extraction equipment from old and useless battery, as shown in Figure 1-3, include left extraction It takes device 1, right extraction equipment 2 and shakes mixing arrangement 3;It is provided on the right side of left extraction equipment 1 and shakes mixing arrangement 3, The right side for shaking mixing arrangement 3 is provided with right extraction equipment 2, and left extraction equipment 1 is symmetrical setting with right extraction equipment 2.
Embodiment 2
One kind extracting nickel sulfate novel energy-saving extraction equipment from old and useless battery, as shown in Figure 1-3, include left extraction It takes device 1, right extraction equipment 2 and shakes mixing arrangement 3;It is provided on the right side of left extraction equipment 1 and shakes mixing arrangement 3, The right side for shaking mixing arrangement 3 is provided with right extraction equipment 2, and left extraction equipment 1 is symmetrical setting with right extraction equipment 2.
Left extraction equipment 1 includes left extractor 11, left inlet tube 12, upper left valve 13, left outlet tube 14, lower-left valve 15, lower-left helical spring 16 and left receipts fluid cylinder 17;The top of left extractor 11 is provided with left inlet tube 12, left inlet tube 12 with Left extractor 11 is connected, and is provided with upper left valve 13 on left inlet tube 12;The left side of left extractor 11 is provided with a left side to go out Liquid pipe 14, left outlet tube 14 are connected with the lower-left skew wall of left extractor 11, are provided with lower-left valve 15 on left outlet tube 14; The lower section of left extractor 11 is provided with lower-left helical spring 16, left extractor 11 is connected with lower-left helical spring 16;On a left side The lower section of extractor 11 is provided with left receipts fluid cylinder 17, the left lower section received fluid cylinder 17 and left outlet tube 14 is arranged in.
Embodiment 3
One kind extracting nickel sulfate novel energy-saving extraction equipment from old and useless battery, as shown in Figure 1-3, include left extraction It takes device 1, right extraction equipment 2 and shakes mixing arrangement 3;It is provided on the right side of left extraction equipment 1 and shakes mixing arrangement 3, The right side for shaking mixing arrangement 3 is provided with right extraction equipment 2, and left extraction equipment 1 is symmetrical setting with right extraction equipment 2.
Left extraction equipment 1 includes left extractor 11, left inlet tube 12, upper left valve 13, left outlet tube 14, lower-left valve 15, lower-left helical spring 16 and left receipts fluid cylinder 17;The top of left extractor 11 is provided with left inlet tube 12, left inlet tube 12 with Left extractor 11 is connected, and is provided with upper left valve 13 on left inlet tube 12;The left side of left extractor 11 is provided with a left side to go out Liquid pipe 14, left outlet tube 14 are connected with the lower-left skew wall of left extractor 11, are provided with lower-left valve 15 on left outlet tube 14; The lower section of left extractor 11 is provided with lower-left helical spring 16, left extractor 11 is connected with lower-left helical spring 16;On a left side The lower section of extractor 11 is provided with left receipts fluid cylinder 17, the left lower section received fluid cylinder 17 and left outlet tube 14 is arranged in.
Right extraction equipment 2 includes right extractor 21, right inlet tube 22, upper right valve 23, right outlet tube 24, bottom right valve 25, bottom right helical spring 26 and right receipts fluid cylinder 27;The top of right extractor 21 is provided with right inlet tube 22, right inlet tube 22 with Right extractor 21 is connected, and is provided with upper right valve 23 on right inlet tube 22;The right side of right extractor 21 is provided with the right side to go out Liquid pipe 24, right outlet tube 24 are connected with the bottom right skew wall of right extractor 21, are provided with bottom right valve 25 on right outlet tube 24; The lower section of right extractor 21 is provided with bottom right helical spring 26, right extractor 21 is connected with bottom right helical spring 26;On the right side The lower section of extractor 21 is provided with right receipts fluid cylinder 27, the right lower section received fluid cylinder 27 and right outlet tube 24 is arranged in.
Embodiment 4
One kind extracting nickel sulfate novel energy-saving extraction equipment from old and useless battery, as shown in Figure 1-3, include left extraction It takes device 1, right extraction equipment 2 and shakes mixing arrangement 3;It is provided on the right side of left extraction equipment 1 and shakes mixing arrangement 3, The right side for shaking mixing arrangement 3 is provided with right extraction equipment 2, and left extraction equipment 1 is symmetrical setting with right extraction equipment 2.
Left extraction equipment 1 includes left extractor 11, left inlet tube 12, upper left valve 13, left outlet tube 14, lower-left valve 15, lower-left helical spring 16 and left receipts fluid cylinder 17;The top of left extractor 11 is provided with left inlet tube 12, left inlet tube 12 with Left extractor 11 is connected, and is provided with upper left valve 13 on left inlet tube 12;The left side of left extractor 11 is provided with a left side to go out Liquid pipe 14, left outlet tube 14 are connected with the lower-left skew wall of left extractor 11, are provided with lower-left valve 15 on left outlet tube 14; The lower section of left extractor 11 is provided with lower-left helical spring 16, left extractor 11 is connected with lower-left helical spring 16;On a left side The lower section of extractor 11 is provided with left receipts fluid cylinder 17, the left lower section received fluid cylinder 17 and left outlet tube 14 is arranged in.
Right extraction equipment 2 includes right extractor 21, right inlet tube 22, upper right valve 23, right outlet tube 24, bottom right valve 25, bottom right helical spring 26 and right receipts fluid cylinder 27;The top of right extractor 21 is provided with right inlet tube 22, right inlet tube 22 with Right extractor 21 is connected, and is provided with upper right valve 23 on right inlet tube 22;The right side of right extractor 21 is provided with the right side to go out Liquid pipe 24, right outlet tube 24 are connected with the bottom right skew wall of right extractor 21, are provided with bottom right valve 25 on right outlet tube 24; The lower section of right extractor 21 is provided with bottom right helical spring 26, right extractor 21 is connected with bottom right helical spring 26;On the right side The lower section of extractor 21 is provided with right receipts fluid cylinder 27, the right lower section received fluid cylinder 27 and right outlet tube 24 is arranged in.
Shaking mixing arrangement 3 includes right fixed ring 30, pedestal 31, support rod 32, spill connection frame 33, cross bar 34, a left side Drawstring 35, left hook 36, left fixed ring 37, right drawstring 38 and right hook 39;The top of pedestal 31 is arranged in right fixed ring 30, right It is set as being fixedly connected at the top of fixed ring 30 and the right end of pedestal 31;The top of pedestal 31 is provided with support rod 32, support rod 32, which are set as rectilinear with pedestal 31, is fixedly connected;The top of support rod 32 is provided with spill connection frame 33, spill connection frame 33 are set as being fixedly connected with support rod 32;Cross bar 34 is provided in spill connection frame 33, the intermediate position of cross bar 34 passes through Axis is set as being rotatablely connected with spill connection frame 33;Cross bar 34 is arranged between left extractor 11 and right extractor 21, cross bar 34 Left end be set as being fixedly connected with left extractor 11, the right end of cross bar 34 is set as being fixedly connected with right extractor 21;In cross The lower section of bar 34 is provided with Zola's rope 35, and Zola's rope 35 is connected with cross bar 34, and the left side of support rod 32 is arranged in Zola's rope 35, The lower section of Zola's rope 35 is provided with left hook 36, Zola's rope 35 is connected with left hook 36;It is arranged in the lower section of left hook 36 There is left fixed ring 37, left hook 36 is set as being flexibly connected with left fixed ring 37;The top of pedestal 31 is arranged in left fixed ring 37, It is set as being fixedly connected at the top of left fixed ring 37 and the left end of pedestal 31, left fixed ring 37 is set with right fixed ring 30 for symmetrical expression It sets;The top of right fixed ring 30 is provided with right hook 39, right hook 39 is set as being flexibly connected with right fixed ring 30;In right extension The top of hook 39 is provided with right drawstring 38, and right hook 39 is connected with right drawstring 38, and the right side of support rod 32 is arranged in right drawstring 38 The lower section of cross bar 34 is arranged in side, right drawstring 38, and right drawstring 38 is connected with cross bar 34.
It further include having counter weight device 4, counter weight device 4 is arranged between left extraction equipment 1 and right extraction equipment 2, with refitting Set 4 be arranged in shake mixing arrangement 3 tops, counter weight device 4 include right baffle-plate 41, guide rod 42, upper left helical spring 43, Sphere 44, upper right helical spring 45 and right shell body 46;Right baffle-plate 41 is located at the top of cross bar 34, and right baffle-plate 41 and cross bar 34 are arranged It is fixedly connected to be rectilinear;The right side of right baffle-plate 41 is provided with guide rod 42, right baffle-plate 41 is set as fixed with guide rod 42 Connection;Upper left helical spring 43 is cased on guide rod 42, left end and the right baffle-plate 41 of upper left helical spring 43 are set as fixed Connection;In upper left, the right side of helical spring 43 is provided with sphere 44, and through-hole is provided on sphere 44, and sphere 44 passes through through-hole set On guide rod 42, sphere 44 is set as being flexibly connected with guide rod 42, and sphere 44 and upper left helical spring 43 are set as activity Connection;The right side of sphere 44 is provided with upper right helical spring 45,45 sets of upper right helical spring on guide rod 42, sphere 44 with Upper right helical spring 45 is set as being flexibly connected;The right side of upper right helical spring 45 is provided with right shell body 46, upper right spiral bullet The right end of spring 45 is set as being fixedly connected with right shell body 46;The top of cross bar 34, right shell body 46 and cross bar is arranged in right shell body 46 34, which are set as rectilinear, is fixedly connected.
It further include having right cylinder 5, right pallet 6, left cylinder 7 and left pallet 8;The left side of right cylinder 5 is provided with right pallet 6, right cylinder 5 is connected with right pallet 6, and the right lower section for receiving fluid cylinder 27 is arranged in right pallet 6, and right receipts fluid cylinder 27 is set with right pallet 6 It is set to flexible connection, the right side of left cylinder 7 is provided with left pallet 8, left cylinder 7 is connected with left pallet 8, and left pallet 8 is arranged In the left lower section for receiving fluid cylinder 17, left receipts fluid cylinder 17 is set as being flexibly connected with left pallet 8.
The cylinder diameter of right cylinder 5 and left cylinder 7 is set as 30-50mm, and the stroke of right cylinder 5 and left cylinder 7 is set as 3-8m.
Working principle: in the present apparatus, because including left extraction equipment 1, right extraction equipment 2 and shaking mixing arrangement 3; It is provided on the right side of left extraction equipment 1 and shakes mixing arrangement 3, the right side for shaking mixing arrangement 3 is provided with right extraction equipment 2, left extraction equipment 1 is symmetrical setting with right extraction equipment 2, so staff can be in advance by the solution containing nickel sulfate It is all added in left extraction equipment 1 with extraction agent solution, then staff is molten by the solution containing nickel sulfate and extractant again Liquid is all added in right extraction equipment 2, recycles the mixing shaken in 3 pairs of mixing arrangement left extraction equipments 1 and right extraction equipment 2 Liquid carries out the mixing that teetertotters, and only needs manually a little auxiliary, does not consume the energy, in the case where meeting the requirement being mixed, reach Energy-efficient purpose.
Because left extraction equipment 1 includes left extractor 11, left inlet tube 12, upper left valve 13, left outlet tube 14, lower-left Then valve 15, lower-left helical spring 16 and left receipts fluid cylinder 17 will first contain so staff can open upper left valve 13 The solution of nickel sulfate is added in left extractor 11 by left inlet tube 12, and extraction agent solution is then added to left extractor again In 11, staff turns off upper left valve 13.When the solution containing nickel sulfate and extraction agent solution mix in left extractor 11 It closes after completion of the reaction, staff can open lower-left valve 15 and is discharged to the solution after reaction respectively by left outlet tube 14 In left receipts fluid cylinder 17, the lower-left helical spring 16 that left 11 bottom of extractor is arranged in can provide elastic branch for left extractor 11 Support, assists left extractor 11 to teetertotter.
Because right extraction equipment 2 includes right extractor 21, right inlet tube 22, upper right valve 23, right outlet tube 24, bottom right Then valve 25, bottom right helical spring 26 and right receipts fluid cylinder 27 will first contain so staff can open upper right valve 23 The solution of nickel sulfate is added in right extractor 21 by right inlet tube 22, and extraction agent solution is then added to right extractor again In 21, staff turns off upper right valve 23.When the solution containing nickel sulfate and extraction agent solution mix in right extractor 21 It closes after completion of the reaction, staff can open bottom right valve 25 and is discharged to the solution after reaction respectively by right outlet tube 24 In right receipts fluid cylinder 27, the bottom right helical spring 26 that right 21 bottom of extractor is arranged in can provide elastic branch for right extractor 21 Support, assists right extractor 21 to teetertotter.
Because shaking mixing arrangement 3 includes right fixed ring 30, pedestal 31, support rod 32, spill connection frame 33, cross bar 34, Zola's rope 35, left hook 36, left fixed ring 37, right drawstring 38 and right hook 39, so when staff is respectively in left extraction After good same amount of mixed liquor is added in tank 11 and right extractor 21, staff applies left extractor 11 or right extractor 21 Certain power drives left extractor 11 or right extractor 21 to move up and down, mixed in left extractor 11 and right extractor 21 It closes liquid and is mixed stirring in up and down motion, start to be reacted.When left extractor 11 or right extractor 21 move to lower section, a left side Lower helical spring 16 or bottom right helical spring 26, which bottom out, to be started to rebound, and left extractor 11 or right extractor 21 is driven to carry out bullet respectively Jump movement so that right extractor 21 or left extractor 11 be driven to carry out counter motion respectively, and passes through spill connection frame 33 and cross The cooperation of bar 34, constantly moves up and down, to carry out to the mixed liquor in right extractor 21 and left extractor 11 more preferable Shaking mixing, without motor drive agitating paddle be stirred, unique structure, the energy saving energy, for enterprise save writing open Branch.After shaking the regular hour to right extractor 21 and left extractor 11, staff can be respectively by left hook 36 or the right side Hook 39 is hung in left fixed ring 37 or right fixed ring 30, to stand to the mixed liquor in right extractor 21 and left extractor 11 Regular hour, the nickel sulfate in the solution containing nickel sulfate are extracted the absorption of the extractant in agent solution, and mass transport process finishes Afterwards, the extract liquor containing nickel sulfate forms significantly upper lower leaf with the raffinate for losing nickel sulfate, and then staff divides again Processing is not discharged it.
Because further including having counter weight device 4, counter weight device 4 is arranged between left extraction equipment 1 and right extraction equipment 2, matches Refitting sets 4 and the top for shaking mixing arrangement 3 is arranged in, and counter weight device 4 includes right baffle-plate 41, guide rod 42, upper left spiral bullet Spring 43, sphere 44, upper right helical spring 45 and right shell body 46, so shaking 3 pairs of mixing arrangement left extraction equipments 1 and right extraction During device 2 shakes, sphere 44 can be distinguished under the effect of the elastic force of upper left helical spring 43 and upper right helical spring 45 Pressure is applied to left extraction equipment 1 or right extraction equipment 2, the counterweight of left extraction equipment 1 or right extraction equipment 2 is increased separately, mentions For the flicker effect to left extraction equipment 1 and right extraction equipment 2, hybrid reaction efficiency is improved.
Because further including having right cylinder 5, right pallet 6, left cylinder 7 and left pallet 8, right cylinder 5 is connected with right pallet 6, Right receipts fluid cylinder 27 is set as being flexibly connected with right pallet 6, and left cylinder 7 is connected with left pallet 8, left receipts fluid cylinder 17 and left pallet 8 It is set as being flexibly connected, so right cylinder 5 can be respectively started by staff and left cylinder 7 acts, right cylinder 5 being capable of band It moves right pallet 6 and right receipts fluid cylinder 27 carries out side-to-side movement, and right receipts fluid cylinder 27 is driven to the position needed, left cylinder 7 can It drives left pallet 8 and left receipts fluid cylinder 17 to carry out side-to-side movement, and left receipts fluid cylinder 17 is driven to the position needed.
Because the cylinder diameter of right cylinder 5 and left cylinder 7 is set as 30-50mm, the stroke of right cylinder 5 and left cylinder 7 is set as 3-8m saves manpower, has a wide range of application so present apparatus movement is steady reliable.
The preferred embodiment of the present invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the inventive concept of the premise, several deformations can also be made, improves and substitutes, these belong to this hair Bright protection scope.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.

Claims (4)

1. one kind extracts nickel sulfate novel energy-saving extraction equipment from old and useless battery, which is characterized in that include left extraction Device (1), right extraction equipment (2) and shaking mixing arrangement (3);Shaking mixing dress is provided on the right side of left extraction equipment (1) (3) are set, are provided with right extraction equipment (2) on the right side of mixing arrangement (3) shaking, left extraction equipment (1) and right extraction equipment (2) For symmetrical expression setting;Left extraction equipment (1) includes left extractor (11), left inlet tube (12), upper left valve (13), left liquid out Manage (14), lower-left valve (15), lower-left helical spring (16) He Zuoshou fluid cylinder (17);It is provided with above left extractor (11) Left inlet tube (12), left inlet tube (12) are connected with left extractor (11), are provided with upper left valve on left inlet tube (12) (13);It is provided on the left of left extractor (11) left outlet tube (14), the lower-left of left outlet tube (14) and left extractor (11) Skew wall is connected, and lower-left valve (15) are provided on left outlet tube (14);Lower-left is provided with below left extractor (11) Helical spring (16), left extractor (11) are connected with lower-left helical spring (16);It is provided with below left extractor (11) Left receipts fluid cylinder (17) is left to receive fluid cylinder (17) setting in the lower section of left outlet tube (14);Right extraction equipment (2) includes right extractor (21), right inlet tube (22), upper right valve (23), right outlet tube (24), bottom right valve (25), bottom right helical spring (26) and the right side It receives fluid cylinder (27);It is provided with above right extractor (21) right inlet tube (22), right inlet tube (22) and right extractor (21) It is connected, upper right valve (23) is provided on right inlet tube (22);Right outlet tube is provided on the right side of right extractor (21) (24), right outlet tube (24) is connected with the bottom right skew wall of right extractor (21), is provided with bottom right valve on right outlet tube (24) Door (25);It is provided with below right extractor (21) bottom right helical spring (26), right extractor (21) and bottom right helical spring (26) it is connected;Right receipts fluid cylinder (27) is provided with below right extractor (21), right receipts fluid cylinder (27) is arranged in right outlet tube (24) lower section;Shaking mixing arrangement (3) includes right fixed ring (30), pedestal (31), support rod (32), spill connection frame (33), cross bar (34), Zola's rope (35), left hook (36), left fixed ring (37), right drawstring (38) and right hook (39);The right side is solid Determine ring (30) setting to be set as being fixedly connected at the top of the top of pedestal (31), right fixed ring (30) and the right end of pedestal (31); It is provided with above pedestal (31) support rod (32), support rod (32) is set as rectilinear with pedestal (31) and is fixedly connected;? It is provided with above support rod (32) spill connection frame (33), spill connection frame (33) and support rod (32) are set as fixed company It connects;It is provided with cross bar (34) in spill connection frame (33), the intermediate position of cross bar (34) passes through axis and spill connection frame (33) It is set as being rotatablely connected;Cross bar (34) be arranged between left extractor (11) and right extractor (21), the left end of cross bar (34) and Left extractor (11) is set as being fixedly connected, and the right end of cross bar (34) is set as being fixedly connected with right extractor (21);In cross bar (34) it is provided with Zola below to restrict (35), Zola's rope (35) is connected with cross bar (34), and Zola restricts (35) setting in support rod (32) left side, is provided with left hook (36) below Zola's rope (35), and Zola's rope (35) is connected with left hook (36);? It is provided with left fixed ring (37) below left hook (36), left hook (36) is set as being flexibly connected with left fixed ring (37);It is left Fixed ring (37) setting is set as fixed company at the top of the top of pedestal (31), left fixed ring (37) and the left end of pedestal (31) It connects, left fixed ring (37) and right fixed ring (30) are symmetrical setting;Right hook is provided with above right fixed ring (30) (39), right hook (39) is set as being flexibly connected with right fixed ring (30);Right drawstring is provided with above right hook (39) (38), right hook (39) is connected with right drawstring (38), and right drawstring (38) is arranged in the right side of support rod (32), right drawstring (38) Lower section in cross bar (34) is set, and right drawstring (38) is connected with cross bar (34).
2. one kind according to claim 1 extracts nickel sulfate novel energy-saving extraction equipment from old and useless battery, special Sign is, further includes having counter weight device (4), and counter weight device (4) is arranged between left extraction equipment (1) and right extraction equipment (2), In the top for shaking mixing arrangement (3), counter weight device (4) includes right baffle-plate (41), guide rod for counter weight device (4) setting (42), upper left helical spring (43), sphere (44), upper right helical spring (45) and right shell body (46);Right baffle-plate (41) is located at cross The top of bar (34), right baffle-plate (41) are set as rectilinear with cross bar (34) and are fixedly connected;It is arranged on the right side of right baffle-plate (41) Have guide rod (42), right baffle-plate (41) is set as being fixedly connected with guide rod (42);Upper left spiral is cased on guide rod (42) The left end of spring (43), upper left helical spring (43) is set as being fixedly connected with right baffle-plate (41);Helical spring (43) in upper left Right side be provided with sphere (44), through-hole is provided on sphere (44), sphere (44) is covered on guide rod (42) by through-hole, Sphere (44) is set as being flexibly connected with guide rod (42), and sphere (44) is set as being flexibly connected with upper left helical spring (43); It is provided on the right side of sphere (44) upper right helical spring (45), upper right helical spring (45) covers on guide rod (42), sphere (44) it is set as being flexibly connected with upper right helical spring (45);Right shell body is provided on the right side of upper right helical spring (45) (46), the right end of upper right helical spring (45) is set as being fixedly connected with right shell body (46);Right shell body (46) is arranged in cross bar (34) top, right shell body (46) are set as rectilinear with cross bar (34) and are fixedly connected.
3. one kind according to claim 2 extracts nickel sulfate novel energy-saving extraction equipment from old and useless battery, special Sign is, further includes having right cylinder (5), right pallet (6), left cylinder (7) and left pallet (8);It is arranged in the left side of right cylinder (5) Have right pallet (6), right cylinder (5) is connected with right pallet (6), and right pallet (6) setting is in the right lower section for receiving fluid cylinder (27), right receipts Fluid cylinder (27) is set as being flexibly connected with right pallet (6), is provided on the right side of left cylinder (7) left pallet (8), left cylinder (7) It is connected with left pallet (8), in the left lower section for receiving fluid cylinder (17), left receipts fluid cylinder (17) sets with left pallet (8) for left pallet (8) setting It is set to flexible connection.
4. one kind according to claim 3 extracts nickel sulfate novel energy-saving extraction equipment from old and useless battery, special Sign is that the cylinder diameter of right cylinder (5) and left cylinder (7) is set as 30-50mm, the stroke setting of right cylinder (5) and left cylinder (7) For 3-8m.
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CN107858206A (en) * 2017-11-22 2018-03-30 佛山市因诺维生物科技有限公司 A kind of stagewise biomass extraction equipment
CN111150655A (en) * 2020-01-10 2020-05-15 李涛 Otolaryngology treatment is with mixing device of dosing
CN113373310B (en) * 2021-06-08 2023-04-11 安徽惠宏科技有限公司 Uniform nickel sulfate extraction equipment based on waste battery metal recovery process

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