CN106894605A - Nanometer imitated wood floor board and its manufacture method - Google Patents

Nanometer imitated wood floor board and its manufacture method Download PDF

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Publication number
CN106894605A
CN106894605A CN201710101826.0A CN201710101826A CN106894605A CN 106894605 A CN106894605 A CN 106894605A CN 201710101826 A CN201710101826 A CN 201710101826A CN 106894605 A CN106894605 A CN 106894605A
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parts
powder
nanometer
floor board
wood floor
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CN201710101826.0A
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CN106894605B (en
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何新桥
何山
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/10Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials

Abstract

The present invention discloses a kind of nanometer imitated wood floor board and its manufacture method, and the floor is calculated with parts by weight, including following component:26 parts of diatomite;13 parts of nano silicon;0.1 1 parts of zirconium oxide;0.1 1 parts of zinc oxide;5 15 parts of titanium dioxide powder;0.1 1 parts of silver oxide;10 30 parts of magnesium chloride;24 parts of 10 30 parts of magnesia and modifying agent.By the combination of each functional material, so as to reached environmentally friendly, attractive in appearance, sterilized imitated wood floor board, mosquito repellent, drive roach, drive ant, fire prevention, it is moistureproof, weather-proof, will not deform, zero formaldehyde and recyclable regeneration, environment friendly and pollution-free function, the performance of existing imitated wood floor board can significantly be optimized, had profound historical significance and market value.Imitated wood floor board manufacturing approach craft flow of the invention is simple, require that equipment is low and workable, can be widely available popularization and application.

Description

Nanometer imitated wood floor board and its manufacture method
Technical field
The present invention relates to the technical field of building materials, more particularly to a kind of nanometer imitated wood floor board and its manufacture method.
Background technology
At present, ceramics, mixed mud, marble, log, composite wood are used the flooring material decorated with office space at home more Material etc., traditional floor is in process of production both not environmentally(Dust granule pollutes), highly energy-consuming, high cost(Transport), service life It is short, once make moist, be squeezed, junk or high/low temperature are easy for ftractureing, deform.With the development in epoch, the progress of science and technology, environmental protection The enhancing of consciousness, people require more and more higher for office, work, inhabitation, activity, Leisure Environment comfort level, to health and life The demand for ordering safety is increasingly paid attention to, and the protection of environment and sustainable development economy are more and more important, traditional all kinds of floors(Bag Include ceramics), highly energy-consuming, maximum discharge, high pollution, high cost during production, service life is long, and can not recycling, therefore, Invent a kind of novel environment friendly, green health, replace with functional " nano-functional floor " it is traditional ceramic, wooden, multiple Floor is closed, is had profound historical significance and market value.
The content of the invention
For weak point present in above-mentioned technology, the present invention provides receiving for a kind of zero formaldehyde and recyclable regeneration Rice imitated wood floor board and its manufacture method.
In order to achieve the above object, a kind of nanometer imitated wood floor board of the invention, is calculated with parts by weight, including following component:
Diatomite 2-6 parts;
Nano silicon 1-3 parts;
Zirconium oxide 0.1-1 parts;
Zinc oxide 0.1-1 parts;
Titanium dioxide powder 5-15 parts;
Silver oxide 0.1-1 parts;
Magnesium chloride 10-30 parts;
Magnesia 10-30 parts;
And modifying agent 2-4 parts.
Wherein, the imitated wood floor board is also including Folium Artemisiae Argyi powder 2-4 parts, Herba Menthae powder 1-3 parts, 1-3 parts of leaf of Cortex cinnamomi camphorae powder and mosquito repellent Grass meal 1-3 parts.
Wherein, the imitated wood floor board also includes lemon powder 0.1-1 parts, lavender powder 0.1-1 parts, ginger powder 0.1-1 parts, borneol 1-2 parts of powder 0.1-1 parts, 0.1-1 parts of borax powder and sea salt powder.
Wherein, the zirconium oxide, nano silicon, zinc oxide, Folium Artemisiae Argyi powder, Herba Menthae powder, leaf of Cortex cinnamomi camphorae powder, Mozzie buster Powder, lemon powder, lavender powder, ginger powder, borneol powder, borax powder and sea salt powder are formed by grinding and mechanical milling process and received Ground rice last current state.
Wherein, this nanometer of imitated wood floor board is also including 15-20 parts of leaf of Cortex cinnamomi camphorae powder.
The present invention discloses a kind of nanometer of manufacture method of imitated wood floor board, comprises the following steps:
S1, raw material mixing:By 2-6 parts of diatomite, 1-3 parts of nano silicon, 0.1-1 parts of zirconium oxide, 0.1-1 part Zinc oxide, 5-15 part of titanium dioxide powder, 0.1-1 parts of silver oxide, 10-30 parts of magnesium chloride, 10-30 parts of magnesia, 2-4 The modifying agent and 15-20 parts of leaf of Cortex cinnamomi camphorae powder or stalk of part carry out the abundant of raw material in adding batch mixer according to sequencing Mixing;
S2, pour into material tube:Mixed material in batch mixer is transported in the medium mould to be implanted of material tube;
S3, roll-forming:It is automatic that material roll-in is smooth using roller to mixed material is injected in mould;
S4, coating glue:Fire prevention glue is coated on the floor being molded using laminating machine, then sticks formed objects Wooden PLASTIC LAMINATED or natural veneer, by extrusion forming;
S5, cutting edging:Pressed sheet is cut according to the size of adjustment, and the sheet material that will have been cut is according to the moulding on floor Bilateral fluting is carried out with bilateral edging.
Wherein, in S1 first by 1-3 parts of nano silicon, 0.1-1 parts of zirconium oxide, 0.1-1 parts of zinc oxide, 1-3 parts of Herba Menthae powder, 1-3 parts of leaf of Cortex cinnamomi camphorae powder, 1-3 parts of mosquito repellent grass meal, 0.1-1 parts of lemon powder, 0.1-1 parts smoke clothing Grass meal, 0.1-1 part of ginger powder, 0.1-1 parts of borneol powder, 0.1-1 parts of borax powder and 0.1-1 parts of sea salt powder are by powder The process of broken, grinding and ball milling forms nanometer powder, and above nanometer powder and 2-6 parts of diatomite are poured into mixer Mix, and mixture is toasted in the environment of 80-100 DEG C, to cause that nanometer powder is filled into diatomaceous space, The mixing of remaining material in S1 is carried out again.
Wherein, during the roll-forming of S3, before mixed material injection mould, it is additionally included in spraying on mould de- Mould agent, and enclose the process of layer of glass.
Wherein, in the cutting edging of S5, after pressed sheet is cut, the sheet material of forming is placed on material frame and is sent Entering thermostatic chamber carries out 12 hours thermostatic curings, then carries out edging treatment.
Wherein, the manufacture method also floor maintenance process including S6, the floor that groove is held on milled side successfully is placed in automatic clear Washing/drying machine is cleaned and dried;To be molded again the floor that cleans up be placed in UV production lines carry out UV overlay films, at illumination Reason, to strengthen the finish and wearability on floor.
The beneficial effects of the invention are as follows:
Compared with prior art, nanometer imitated wood floor board of the invention, nano silicon have absorption property strong, fire prevention, it is heat-insulated, Resistant to elevated temperatures feature;Diatomite in powder has unique pore structure, and body weight is light and soft, and porosity is big, the characteristics of absorption property is strong;Receive Rice titanium dioxide powder has uvioresistant antibacterial, sterilization, anti-aging performance;Zinc oxide has high-strength, bloom, high abrasion, anti-ageing The special function of change;Zirconium oxide has the features such as thermal shock resistance is strong, high temperature resistant, chemical stability are good, Material cladding is protruded;Change Property agent there is the effect of cladding crystal and protection crystal, be the solvent that must be added when magnesium chloride, magnesia and water react;By oxygen Change zirconium to be combined with above-mentioned material, the performance parameter of material can be greatly enhanced, improve its fracture toughness, bending strength etc..Through Cross the combination of each functional material, so as to reached environmentally friendly, attractive in appearance, sterilized imitated wood floor board, mosquito repellent, drive roach, drive ant, fire prevention, prevent It is damp, weather-proof, will not deform, zero formaldehyde and recyclable regeneration, environment friendly and pollution-free function, can significantly optimize existing imitation wood The performance on floor, has profound historical significance and market value.Imitated wood floor board manufacturing approach craft flow of the invention is simple, It is required that equipment is low and workable, popularization and application can be widely available.
Brief description of the drawings
Fig. 1 is the flow chart of the manufacture method of nanometer imitated wood floor board of the present invention.
Specific embodiment
In order to more clearly state the present invention, the present invention is further described below in conjunction with the accompanying drawings.
Refering to Fig. 1, the invention discloses a kind of nanometer of manufacture method of imitated wood floor board, comprise the following steps:
S1, raw material mixing:First by 1-3 parts of nano silicon, 0.1-1 parts of zirconium oxide, 0.1-1 parts of zinc oxide, 1-3 The Herba Menthae powder, 1-3 parts of leaf of Cortex cinnamomi camphorae powder, 1-3 parts of mosquito repellent grass meal, 0.1-1 parts of lemon powder, 0.1-1 parts of lavender of part Powder, 0.1-1 part of ginger powder, 0.1-1 parts of borneol powder, 0.1-1 parts of borax powder and 0.1-1 parts of sea salt powder are by powder The process of broken, grinding and ball milling forms nanometer powder, and above nanometer powder and 2-6 parts of diatomite are poured into mixer Mix, and mixture is toasted in the environment of 80-100 DEG C, to cause that nanometer powder is filled into diatomaceous space, Again by diatomaceous mixture, 5-15 parts of titanium dioxide powder, 0.1-1 parts of silver oxide, 10-30 parts of magnesium chloride, 10-30 parts Magnesia, 2-4 parts of modifying agent and 15-20 parts of leaf of Cortex cinnamomi camphorae powder or stalk enter in adding batch mixer according to sequencing Row raw material is sufficiently mixed;
S2, pour into material tube:Releasing agent is sprayed on mould, and encloses layer of glass, by the mixed material in batch mixer It is transported in the medium mould to be implanted of material tube;
S3, roll-forming:It is automatic that material roll-in is smooth using roller to mixed material is injected in mould;
S4, coating glue:Fire prevention glue is coated on the floor being molded using laminating machine, then sticks formed objects Wooden PLASTIC LAMINATED or natural veneer, by extrusion forming;
S5, cutting edging:Pressed sheet is cut according to the size of adjustment, the sheet material of forming is placed on material frame and is sent into Thermostatic chamber carries out 12 hours thermostatic curings, and the sheet material that will have been cut carries out bilateral fluting and two-sided grinding according to the moulding on floor Side;
S6, floor maintenance:The floor that groove is held on milled side successfully is placed in into automatic washer-drier to be cleaned and dried;Again will shaping The floor for cleaning up is placed in carries out UV overlay films, photo-irradiation treatment in UV production lines, to strengthen the finish and wearability on floor.
Diatomite:It is a kind of biogenic silicastone, it is mainly made up of the remains of ancient times diatom.Its chemistry Composition can represent that mineralogical composition is protein and its mutation based on SiO2 with SiO2 nH2O.Kieselguhr wall material is to moisture Absorption and release can produce waterfall effect, by water-molecule dissociation into negative ions.Due to hydrone be wrapped, formed it is positive and negative from Subgroup, then with hydrone as carrier, swims everywhere in atmosphere, possesses sterilizing ability.That swims everywhere in atmosphere is positive and negative Cluster ion encounters the harmful substance such as allergin and other bacteriums, mould, just can immediately be surrounded and be isolated.So Afterwards, the most active hydroxide ion of performance carries out violent chemical reaction with these harmful substances in negative ions group, finally will They are completely decomposed into the harmless objects such as hydrone.
Titanium dioxide:It was verified that HeLa cell can thoroughly be killed with the dichloride in anatase type TiO2 of 0.1mg/cm3 concentration, Killing rate to hay bacillus, Pseudomonas aeruginosa, Escherichia coli, gold-coloured staphylococci, salmonella, tooth branch bacterium and Aspergillus reaches More than 98%, in the presence of fluorescent lamp or ultraviolet, activate TiO2 and generate the free radical with high catalytic activity, energy Very strong photooxidation and reducing power are produced, can be catalyzed, photodissociation is attached to the organic matters such as the various formaldehyde of body surface, inorganic Thing, can play a part of to purify the air of a room.
Leaf of Cortex cinnamomi camphorae powder:Not only can with expelling parasite but also can as packing material, mitigate sheet material weight.
Nano phase ag_2 o:Nano phase ag_2 o can kill 600 various bacterias and virus;
Magnesium chloride:Magnesium chloride is made up of seawater, salt lake and salt well water by evaporation purification, and China has abundant magnesium chloride money Source;
Magnesia:Magnesia is the oxide of magnesium, a kind of ionic compound, in there is nature in periclase form;
Modifying agent:To be composited by various macromolecular materials, with cladding crystal and protection crystal effect, be magnesium chloride, The solvent that magnesia and water must be added when reacting.
First implements
A kind of nanometer imitated wood floor board of the present invention, is calculated with parts by weight, including following component:
4 parts of diatomite, 2 parts of nano silicon, 0.5 part of zirconium oxide, 0.5 part of zinc oxide, 0.5 part of silver oxide, 3 parts of Folium Artemisiae Argyi powder, 2 parts of Herba Menthae powder, 2 parts of leaf of Cortex cinnamomi camphorae powder, 2 parts of mosquito repellent grass meal, 0.5 part of lemon powder, 0.5 part of lavender powder, 0.5 part of ginger powder, ice 0.5 part of piece powder, 0.5 part of borax powder, 1.5 parts of sea salt powder, 10 parts of nanometer titanium dioxide titanium valve, 20 parts of magnesium chloride, 20 parts of magnesia, with And 17 parts of 3 parts of modifying agent, leaf of Cortex cinnamomi camphorae powder or stalk.
Second embodiment
A kind of nanometer imitated wood floor board of the present invention, is calculated with parts by weight, including following component:
2 parts of diatomite, 1 part of nano silicon, 0.1 part of zirconium oxide, 0.1 part of zinc oxide, 2 parts of Folium Artemisiae Argyi powder, 1 part of Herba Menthae powder, perfume 1 part of camphortree leaf powder, 1 part of mosquito repellent grass meal, 0.1 part of lemon powder, 0.1 part of lavender powder, 0.1 part of ginger powder, 0.1 part of borneol powder, boron 0.1 part of emery dust, 1 part of sea salt powder, 5 parts of nanometer titanium dioxide titanium valve, 0.1 part of silver oxide, 10 parts of magnesium chloride, 10 parts of magnesia and 15 parts of 2 parts of modifying agent, leaf of Cortex cinnamomi camphorae powder or stalk.
3rd embodiment
A kind of nanometer imitated wood floor board of the present invention, is calculated with parts by weight, including following component:
6 parts of diatomite, 3 parts of nano silicon, 1 part of zirconium oxide, 1 part of zinc oxide, 4 parts of Folium Artemisiae Argyi powder, 3 parts of Herba Menthae powder, cinnamomum camphora tree 3 parts of leaf powder, 3 parts of mosquito repellent grass meal, 1 part of lemon powder, 1 part of lavender powder, 1 part of ginger powder, 1 part of borneol powder, 1 part of borax powder, sea salt 2 parts of powder, 30 parts of nano diatomite, 15 parts of nanometer titanium dioxide titanium valve, 1 part of silver oxide, 30 parts of magnesium chloride, 30 parts of magnesia and 20 parts of 4 parts of modifying agent, leaf of Cortex cinnamomi camphorae powder or stalk.
Disclosed above is only several specific embodiments of the invention, but the present invention is not limited to this, any ability What the technical staff in domain can think change should all fall into protection scope of the present invention.

Claims (10)

1. a kind of nanometer imitated wood floor board, it is characterised in that calculated with parts by weight, including following component:
Diatomite 2-6 parts;
Nano silicon 1-3 parts;
Zirconium oxide 0.1-1 parts;
Zinc oxide 0.1-1 parts;
Titanium dioxide powder 5-15 parts;
Silver oxide 0.1-1 parts;
Magnesium chloride 10-30 parts;
Magnesia 10-30 parts;
And modifying agent 2-4 parts.
2. according to claim 1 nanometer of imitated wood floor board, it is characterised in that the imitated wood floor board also include Folium Artemisiae Argyi powder 2-4 parts, 1-3 parts of Herba Menthae powder 1-3 parts, 1-3 parts of leaf of Cortex cinnamomi camphorae powder and mosquito repellent grass meal.
3. according to claim 2 nanometer of imitated wood floor board, it is characterised in that the imitated wood floor board also includes lemon powder 0.1-1 1-2 parts of part, lavender powder 0.1-1 parts, ginger powder 0.1-1 parts, 0.1-1 parts of borneol powder, 0.1-1 parts of borax powder and sea salt powder.
4. according to claim 3 nanometer of imitated wood floor board, it is characterised in that the zirconium oxide, nano silicon, oxidation Zinc, Folium Artemisiae Argyi powder, Herba Menthae powder, leaf of Cortex cinnamomi camphorae powder, mosquito repellent grass meal, lemon powder, lavender powder, ginger powder, borneol powder, borax powder and Sea salt powder forms nanometer powder state by grinding and mechanical milling process.
5. according to claim 1 nanometer of imitated wood floor board, it is characterised in that this nanometer of imitated wood floor board also includes 15-20 parts Leaf of Cortex cinnamomi camphorae powder.
6. a kind of nanometer of manufacture method of imitated wood floor board, it is characterised in that comprise the following steps:
S1, raw material mixing:By 2-6 parts of diatomite, 1-3 parts of nano silicon, 0.1-1 parts of zirconium oxide, 0.1-1 part Zinc oxide, 5-15 part of titanium dioxide powder, 0.1-1 parts of silver oxide, 10-30 parts of magnesium chloride, 10-30 parts of magnesia, 2-4 The modifying agent and 15-20 parts of leaf of Cortex cinnamomi camphorae powder or stalk of part carry out the abundant of raw material in adding batch mixer according to sequencing Mixing;
S2, pour into material tube:Mixed material in batch mixer is transported in the medium mould to be implanted of material tube;
S3, roll-forming:It is automatic that material roll-in is smooth using roller to mixed material is injected in mould;
S4, coating glue:Fire prevention glue is coated on the floor being molded using laminating machine, then sticks formed objects Wooden PLASTIC LAMINATED or natural veneer, by extrusion forming;
S5, cutting edging:Pressed sheet is cut according to the size of adjustment, and the sheet material that will have been cut is according to the moulding on floor Bilateral fluting is carried out with bilateral edging.
7. the according to claim 6 nanometer of manufacture method of imitated wood floor board, it is characterised in that first by 1-3 parts in S1 Nano silicon, 0.1-1 parts of zirconium oxide, 0.1-1 parts of zinc oxide, 1-3 parts of Herba Menthae powder, 1-3 parts of leaf of Cortex cinnamomi camphorae Powder, 1-3 part of mosquito repellent grass meal, 0.1-1 parts of lemon powder, 0.1-1 parts of lavender powder, 0.1-1 parts of ginger powder, 0.1-1 parts Borneol powder, the sea salt powder of 0.1-1 parts of borax powder and 0.1-1 parts by crushing, the process of grinding and ball milling forms and receives Ground rice end, stirrer for mixing stirring is poured into by above nanometer powder and 2-6 parts of diatomite, and by mixture in 80-100 Toasted in the environment of DEG C, to cause that nanometer powder is filled into diatomaceous space, then the mixing for carrying out remaining material in S1.
8. the according to claim 6 nanometer of manufacture method of imitated wood floor board, it is characterised in that in the roll-forming process of S3 In, before mixed material injection mould, it is additionally included in and releasing agent is sprayed on mould, and enclose the process of layer of glass.
9. the according to claim 6 nanometer of manufacture method of imitated wood floor board, it is characterised in that in the cutting edging procedure of S5 In, after pressed sheet is cut, the sheet material of forming is placed in into feeding thermostatic chamber on material frame carries out 12 hours thermostatic curings, Edging treatment is carried out again.
10. the according to claim 6 nanometer of manufacture method of imitated wood floor board, it is characterised in that the manufacture method also includes The floor maintenance process of S6, is placed in the floor that groove is held on milled side successfully automatic washer-drier and is cleaned and dried;Again will be into The floor that type is cleaned up is placed in carries out UV overlay films, photo-irradiation treatment in UV production lines, to strengthen the finish and wearability on floor.
CN201710101826.0A 2016-11-14 2017-02-24 Nanometer imitated wood floor board and its manufacture method Active CN106894605B (en)

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CN201610999362 2016-11-14

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107746469A (en) * 2017-09-26 2018-03-02 杭州上匠装饰设计有限公司 A kind of house decoraton metope of health environment-friendly and preparation method thereof
CN108308176A (en) * 2018-01-12 2018-07-24 中国建筑材料科学研究总院有限公司 Diatom soil matrix plants antimicrobial composite material and preparation method
CN110423091A (en) * 2019-09-02 2019-11-08 范斌 A kind of preparation method of alkali magnesium cement fire prevention cockroach proof humidity conditioning function wardrobe plate
CN110683825A (en) * 2018-07-06 2020-01-14 江苏吉福新材料股份有限公司 Decorative plate and manufacturing method thereof
CN110683824A (en) * 2018-07-06 2020-01-14 江苏吉福新材料股份有限公司 Decorative plate and manufacturing method thereof

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US20110165356A1 (en) * 2010-01-07 2011-07-07 Lion Copolymer, Llc Compatibilized silica in nitrile rubber and blends of nitrile rubber and styrene butadiene rubber compositions
CN104031417A (en) * 2014-05-20 2014-09-10 凤台精兴生物科技有限公司 Modified calcium carbonate with heat-isolating heat-insulating effect and preparation method thereof
CN104845480A (en) * 2015-04-23 2015-08-19 铜陵祥云消防科技有限责任公司 Nontoxic environmentally-friendly novel fireproof coating

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110165356A1 (en) * 2010-01-07 2011-07-07 Lion Copolymer, Llc Compatibilized silica in nitrile rubber and blends of nitrile rubber and styrene butadiene rubber compositions
CN104031417A (en) * 2014-05-20 2014-09-10 凤台精兴生物科技有限公司 Modified calcium carbonate with heat-isolating heat-insulating effect and preparation method thereof
CN104845480A (en) * 2015-04-23 2015-08-19 铜陵祥云消防科技有限责任公司 Nontoxic environmentally-friendly novel fireproof coating

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107746469A (en) * 2017-09-26 2018-03-02 杭州上匠装饰设计有限公司 A kind of house decoraton metope of health environment-friendly and preparation method thereof
CN108308176A (en) * 2018-01-12 2018-07-24 中国建筑材料科学研究总院有限公司 Diatom soil matrix plants antimicrobial composite material and preparation method
CN110683825A (en) * 2018-07-06 2020-01-14 江苏吉福新材料股份有限公司 Decorative plate and manufacturing method thereof
CN110683824A (en) * 2018-07-06 2020-01-14 江苏吉福新材料股份有限公司 Decorative plate and manufacturing method thereof
CN110423091A (en) * 2019-09-02 2019-11-08 范斌 A kind of preparation method of alkali magnesium cement fire prevention cockroach proof humidity conditioning function wardrobe plate

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